A simple and green method has been developed for the synthesis of 2-aminocyclohex-l-ene-l- carboxylic esters through a one-pot three-component condensation reaction of primary amines, ethyl acetoacetate and chalcones ...A simple and green method has been developed for the synthesis of 2-aminocyclohex-l-ene-l- carboxylic esters through a one-pot three-component condensation reaction of primary amines, ethyl acetoacetate and chalcones using FeCI3/SiO2 nanoparticles in ethanol. This method has several advantages such as high to excellent product yields in short time, using an inexpensive and reusable catalyst and available starting material.展开更多
合成了表面包覆 Si O2 的超细 Ca CO3 。通过 XPS,XRD对包覆表面层结构的分析 ,证实了 Si O2 以无定形包覆于 Ca CO3 表面 ,并在其表面形成了 Si- O- Ca键。对 Si O2 包覆超细 Ca CO3 的机理分析结果可知 :Na2 Si O3 的加入量是影响包...合成了表面包覆 Si O2 的超细 Ca CO3 。通过 XPS,XRD对包覆表面层结构的分析 ,证实了 Si O2 以无定形包覆于 Ca CO3 表面 ,并在其表面形成了 Si- O- Ca键。对 Si O2 包覆超细 Ca CO3 的机理分析结果可知 :Na2 Si O3 的加入量是影响包覆效率的重要因素 ,由于硅酸易自聚 ,控制 Si O2 与 Ca CO3 的重量比约为4 %～ 5 %时为包覆的最佳点 ;Ca CO3 晶粒度大小影响分散性能 ,进而影响包覆效率 ,分散性能好的包覆效率较高。展开更多
文摘A simple and green method has been developed for the synthesis of 2-aminocyclohex-l-ene-l- carboxylic esters through a one-pot three-component condensation reaction of primary amines, ethyl acetoacetate and chalcones using FeCI3/SiO2 nanoparticles in ethanol. This method has several advantages such as high to excellent product yields in short time, using an inexpensive and reusable catalyst and available starting material.
文摘合成了表面包覆 Si O2 的超细 Ca CO3 。通过 XPS,XRD对包覆表面层结构的分析 ,证实了 Si O2 以无定形包覆于 Ca CO3 表面 ,并在其表面形成了 Si- O- Ca键。对 Si O2 包覆超细 Ca CO3 的机理分析结果可知 :Na2 Si O3 的加入量是影响包覆效率的重要因素 ,由于硅酸易自聚 ,控制 Si O2 与 Ca CO3 的重量比约为4 %～ 5 %时为包覆的最佳点 ;Ca CO3 晶粒度大小影响分散性能 ,进而影响包覆效率 ,分散性能好的包覆效率较高。
