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Tribological properties of textured stator and PTFE-based material in travelling wave ultrasonic motors 被引量:6
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作者 Jinbang LI Shuaishuai ZENG +2 位作者 Shuo LIU Ningning ZHOU Tao QING 《Friction》 SCIE CSCD 2020年第2期301-310,共10页
This study fabricated textures on the stator surface of a traveling wave ultrasonic motor(USM)using laser and investigated the tribological behavior of a polytetrafluoroethylene(PTFE)composite friction material and st... This study fabricated textures on the stator surface of a traveling wave ultrasonic motor(USM)using laser and investigated the tribological behavior of a polytetrafluoroethylene(PTFE)composite friction material and stator.Initially,the effect of textures with different densities was tested.As the results suggested,the generation of large transfer films of PTFE composite was prevented by laser surface texturing,and adhesive wear reduced notably despite the insignificant decrease in load capacity and efficiency.Next,the 100-h test was performed to further study the effects of texture.Worn surface and wear debris were observed to discuss wear mechanisms.After 100 h,the form of wear debris changed into particles.The wear mechanisms of friction material sliding against the textured stator were small size fatigue and slight abrasive wear.The wear height of friction material decreased from 3.8μm to 1.1μm.This research provides a method to reduce the wear of friction materials used in travelling wave USMs. 展开更多
关键词 laser surface texturing ultrasonic motor PTfe-based material FRICTION wear mechanisms
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Cement-Based Thermoelectric Materials, Devices and Applications
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作者 Wanqiang Li Chunyu Du +1 位作者 Lirong Liang Guangming Chen 《Nano-Micro Letters》 2026年第1期750-781,共32页
Cement stands as a dominant contributor to global energy consumption and carbon emissions in the construction industry.With the upgrading of infrastructure and the improvement of building standards,traditional cement ... Cement stands as a dominant contributor to global energy consumption and carbon emissions in the construction industry.With the upgrading of infrastructure and the improvement of building standards,traditional cement fails to reconcile ecological responsibility with advanced functional performance.By incorporating tailored fillers into cement matrices,the resulting composites achieve enhanced thermoelectric(TE)conversion capabilities.These materials can harness solar radiation from building envelopes and recover waste heat from indoor thermal gradients,facilitating bidirectional energy conversion.This review offers a comprehensive and timely overview of cementbased thermoelectric materials(CTEMs),integrating material design,device fabrication,and diverse applications into a holistic perspective.It summarizes recent advancements in TE performance enhancement,encompassing fillers optimization and matrices innovation.Additionally,the review consolidates fabrication strategies and performance evaluations of cement-based thermoelectric devices(CTEDs),providing detailed discussions on their roles in monitoring and protection,energy harvesting,and smart building.We also address sustainability,durability,and lifecycle considerations of CTEMs,which are essential for real-world deployment.Finally,we outline future research directions in materials design,device engineering,and scalable manufacturing to foster the practical application of CTEMs in sustainable and intelligent infrastructure. 展开更多
关键词 Functional cement Thermoelectric materials Device structure Smart building
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Emerging Role of 2D Materials in Photovoltaics:Efficiency Enhancement and Future Perspectives
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作者 Ghulam Dastgeer Muhammad Wajid Zulfiqar +7 位作者 Sobia Nisar Rimsha Zulfiqar Muhammad Imran Swagata Panchanan Subhajit Dutta Kamran Akbar Alberto Vomiero Zhiming Wang 《Nano-Micro Letters》 2026年第1期843-895,共53页
The growing global energy demand and worsening climate change highlight the urgent need for clean,efficient and sustainable energy solutions.Among emerging technologies,atomically thin two-dimensional(2D)materials off... The growing global energy demand and worsening climate change highlight the urgent need for clean,efficient and sustainable energy solutions.Among emerging technologies,atomically thin two-dimensional(2D)materials offer unique advantages in photovoltaics due to their tunable optoelectronic properties,high surface area and efficient charge transport capabilities.This review explores recent progress in photovoltaics incorporating 2D materials,focusing on their application as hole and electron transport layers to optimize bandgap alignment,enhance carrier mobility and improve chemical stability.A comprehensive analysis is presented on perovskite solar cells utilizing 2D materials,with a particular focus on strategies to enhance crystallization,passivate defects and improve overall cell efficiency.Additionally,the application of 2D materials in organic solar cells is examined,particularly for reducing recombination losses and enhancing charge extraction through work function modification.Their impact on dye-sensitized solar cells,including catalytic activity and counter electrode performance,is also explored.Finally,the review outlines key challenges,material limitations and performance metrics,offering insight into the future development of nextgeneration photovoltaic devices encouraged by 2D materials. 展开更多
关键词 2D materials Photovoltaics Interface engineering Work function tuning Energy harvesting
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Cu/Ti-doped O3-type cathode materials for high cyclic stability of sodium-ion batteries
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作者 Jingjing Dong Liu Pei +6 位作者 Yifei Wang Yan Liu Xingliang Liu Zhidan Diao Jianling Li Yejing Li Xindong Wang 《International Journal of Minerals,Metallurgy and Materials》 2026年第1期306-314,共9页
The outstanding performance of O3-type NaNi_(1/3)Fe_(1/3)Mn_(1/3)O_(2)(NFM111)at both high and low temperatures coupled with its impressive specific capacity makes it an excellent cathode material for sodium-ion batte... The outstanding performance of O3-type NaNi_(1/3)Fe_(1/3)Mn_(1/3)O_(2)(NFM111)at both high and low temperatures coupled with its impressive specific capacity makes it an excellent cathode material for sodium-ion batteries.However,its poor cycling,owing to highpressure phase transitions,is one of its disadvantages.In this study,Cu/Ti was introduced into NFM111 cathode material using a solidphase method.Through both theoretically and experimentally,this study found that Cu doping provides a higher redox potential in NFM111,improving its reversible capacity and charge compensation process.The introduction of Ti would enhance the cycling stability of the material,smooth its charge and discharge curves,and suppress its high-voltage phase transitions.Accordingly,the NaNi_(0.27)Fe_(0.28)Mn_(0.33)Cu_(0.05)Ti_(0.06)O_(2)sample used in the study exhibited a remarkable rate performance of 142.97 mAh·g^(-1)at 0.1 C(2.0-4.2 V)and an excellent capacity retention of 72.81%after 300 cycles at 1C(1C=150 mA·g^(-1)). 展开更多
关键词 sodium-ion batteries Cu/Ti doping cyclic stability layered cathode material
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High-Entropy Materials:A New Paradigm in the Design of Advanced Batteries
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作者 Yangmei Xin Minmin Zhu +1 位作者 Haizhong Zhang Xinghui Wang 《Nano-Micro Letters》 2026年第1期1-52,共52页
High-entropy materials(HEMs)have attracted considerable research attention in battery applications due to exceptional properties such as remarkable structural stability,enhanced ionic conductivity,superior mechanical ... High-entropy materials(HEMs)have attracted considerable research attention in battery applications due to exceptional properties such as remarkable structural stability,enhanced ionic conductivity,superior mechanical strength,and outstanding catalytic activity.These distinctive characteristics render HEMs highly suitable for various battery components,such as electrodes,electrolytes,and catalysts.This review systematically examines recent advances in the application of HEMs for energy storage,beginning with fundamental concepts,historical development,and key definitions.Three principal categories of HEMs,namely high-entropy alloys,high-entropy oxides,and highentropy MXenes,are analyzed with a focus on electrochemical performance metrics such as specific capacity,energy density,cycling stability,and rate capability.The underlying mechanisms by which these materials enhance battery performance are elucidated in the discussion.Furthermore,the pivotal role of machine learning in accelerating the discovery and optimization of novel high-entropy battery materials is highlighted.The review concludes by outlining future research directions and potential breakthroughs in HEM-based battery technologies. 展开更多
关键词 High entropy alloys High entropy oxides High entropy MXenes High entropy battery materials Machine learning
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Distinctive electrochemical performance of novel Fe-based Li-rich cathode material prepared by molten salt method for lithium-ion batteries 被引量:1
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作者 Taolin Zhao Rixin Ji +5 位作者 Hedi Yang Yuxia Zhang Xiuguo Sun Yanting Li Li Li Renjie Chen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2019年第6期37-45,共9页
For constructing next-generation lithium-ion batteries with advanced performances,pursuit of highcapacity Li-rich cathodes has caused considerable attention.So far,the low discharge specific capacity and serious capac... For constructing next-generation lithium-ion batteries with advanced performances,pursuit of highcapacity Li-rich cathodes has caused considerable attention.So far,the low discharge specific capacity and serious capacity fading are strangling the development of Fe-based Li-rich materials.To activate the extra-capacity of Fe-based Li-rich cathode materials,a facile molten salt method is exploited using an alkaline mixture of LiOH–LiNO3–Li2O2 in this work.The prepared Li1.09(Fe0.2Ni0.3Mn0.5)0.91O2 material yields high discharge specific capacity and good cycling stability.The discharge specific capacity shows an upward tendency at 0.1 C.After 60 cycles,a high reversible specific capacity of ~250 m Ah g-1is delivered.The redox of Fe3+/Fe4+and Mn3+/Mn4+are gradually activated during cycling.Notably,the redox reaction of Fe2+/Fe3+can be observed reversibly below 2 V,which is quite different from the material prepared by a traditional co-precipitation method.The stable morphology of fine nanoparticles(100–300 nm)is considered benefiting for the distinctive electrochemical performances of Li1.09(Fe0.2Ni0.3Mn0.5)0.91O2.This study demonstrates that molten salt method is an inexpensive and effective approach to activate the extra capacity of Fe-based Li-rich cathode material for high-performance lithium-ion batteries. 展开更多
关键词 LITHIUM-ION batteries fe-based material Li-rich cathode Molten salt High capacity
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Low-cost solid FeS lubricant as a possible alternative to MoS2 for producing Fe-based friction materials 被引量:6
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作者 Tao Peng Qing-zhi Yan +2 位作者 Yan Zhang Xiao-jiao Shi Ming-yang Ba 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2017年第1期115-121,共7页
Three reaction systems of MoS_2-Fe, FeS -Fe, and Fe S-Fe-Mo were designed to investigate the use of FeS as an alternative to MoS_2 for producing Fe-based friction materials. Samples were prepared by powder metallurgy,... Three reaction systems of MoS_2-Fe, FeS -Fe, and Fe S-Fe-Mo were designed to investigate the use of FeS as an alternative to MoS_2 for producing Fe-based friction materials. Samples were prepared by powder metallurgy, and their phase compositions, microstructures, mechanical properties, and friction performance were characterized. The results showed that MoS_2 reacts with the matrix to produce iron-sulfides and Mo when sintered at 1050°C. Iron-sulfides produced in the MoS_2-Fe system were distributed uniformly and continuously in the matrix, leading to optimal mechanical properties and the lowest coefficient of friction among the systems studied. The lubricity observed was hypothesized to originate from the iron-sulfides produced. The Fe S-Fe-Mo system showed a phase composition, porosity, and density similar to those of the MoS_2-Fe system, but an uneven distribution of iron-sulfides and Mo in this system resulted in less-optimal mechanical properties. Finally, the Fe S-Fe system showed the poorest mechanical properties among the systems studied because of the lack of Mo reinforcement. In friction tests, the formation of a sulfide layer contributed to a decrease in coefficient of friction(COF) in all of the samples. 展开更多
关键词 friction materials solid lubricants iron sulfides molybdenum sulfides
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Solid FeS lubricant: a possible alternative to MoS2 for Cu–Fe-based friction materials 被引量:3
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作者 Tao Peng Qing-zhi Yan +1 位作者 Xiao-lu Zhang Xiao-jiao Shi 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2017年第11期1278-1283,共6页
Molybdenum disulfide(MoS_2) is one of the most commonly used solid lubricants for Cu–Fe-based friction materials. Nevertheless, MoS_2 reacts with metal matrices to produce metal sulfides(e.g., FeS) and Mo during sint... Molybdenum disulfide(MoS_2) is one of the most commonly used solid lubricants for Cu–Fe-based friction materials. Nevertheless, MoS_2 reacts with metal matrices to produce metal sulfides(e.g., FeS) and Mo during sintering, and the lubricity of the composite may be related to the generation of FeS. Herein, the use of FeS as an alternative to MoS_2 for producing Cu–Fe-based friction materials was investigated. According to the reaction principle of thermodynamics, two composites—one with MoS_2(Fe–Cu–MoS_2 sample) and the other with FeS(FeS–Cu_2S–Cu–Fe–Mo sample), were prepared and their friction behaviors and mechanical properties were compared. The results showed that MoS_2 reacted with the Cu–Fe matrix to produce FeS, metallic ternary sulfides, and Mo when sintered at 1050°C. The MoS_2–Cu–Fe and FeS–Cu_2S–Cu–Fe–Mo samples thereby exhibited similar characteristics with respect to phase composition, density, hardness, and tribological behaviors. Micrographs of the worn surfaces revealed that the stable friction regime for both composites stemmed from the iron sulfides friction layers rather than from the molybdenum sulfides layers. 展开更多
关键词 friction materials SOLID lubricants iron sulfides MOLYBDENUM sulfides
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Glass formation and magnetic properties of Fe-based metallic glasses fabricated by low-purity industrial materials 被引量:2
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作者 Man ZHU Yang FA +5 位作者 Zeng-yun JIAN Li-juan YAO Chang-qing JIN Jun-feng XU Rui-hua NAN Fang-e CHANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2017年第4期857-862,共6页
Fe-based metallic glasses of(Fe74Nb6B20)100?xCrx(x=1,3,5)with high glass forming ability(GFA)and good magneticproperties were prepared using low-purity raw materials.Increasing Cr content does not significantly change... Fe-based metallic glasses of(Fe74Nb6B20)100?xCrx(x=1,3,5)with high glass forming ability(GFA)and good magneticproperties were prepared using low-purity raw materials.Increasing Cr content does not significantly change glass transitiontemperature and onset crystallization temperature,while it enhances liquidus temperature.The addition of Cr improves the GFA ofthe(Fe74Nb6B20)100?xCrx glassy alloys compared to that in Cr-free Fe?Nb?B alloys,in which the supercooled liquid region(ΔTx),Trgandγare found to be50?54K,0.526?0.538,and0.367?0.371,respectively.The(Fe74Nb6B20)100?xCrx glassy alloys exhibit excellentsoft magnetic properties with high saturation magnetization of139?161A·m2/kg and low coercivity of30.24?58.9A/m.PresentFe?Nb?B?Cr glassy alloys exhibiting high GFA as well as excellent magnetic properties and low manufacturing cost make themsuitable for magnetic components for engineering application. 展开更多
关键词 fe-based metallic glasses CR glass forming ability magnetic property
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Development and Characterization of Fe-Based Friction Material Made by Hot Powder Preform Forging for Low Duty Applications 被引量:1
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作者 A.A.S. Ghazi K. Chandra P.S. Misra 《Journal of Minerals and Materials Characterization and Engineering》 2011年第13期1205-1212,共8页
This present paper investigates the friction and wear properties of friction material developed by ‘Hot Powder Preform Forging’ technique. The conventional technique to manufacture Metallo-ceramic brake pads was suc... This present paper investigates the friction and wear properties of friction material developed by ‘Hot Powder Preform Forging’ technique. The conventional technique to manufacture Metallo-ceramic brake pads was successfully and economically tried to replace the above process. Compacting and sintering technology suffers from certain major limitations such as inadequate joining of friction element with backing plate, poor density levels achieved in friction element owing to limited application of pressure during compacting, poor thermal conductivity due to high levels of porosity in the product, poor strength due to segregation of the impurities along prior particle boundaries (PPB’s) and, wide variations in final characteristics due to large number of variables involved. In contrast to these limitations, the present technique can offer brake pads of much simpler chemistry but with improved performance on account of simultaneous application of pressure and temperature and with better control of variables. Fade and recovery studies were carried out on a Krauss machine tester following the Economic Commission for Europe Regulation for replacement brake linings (ECE R-90). μfade, μrecovery, μperformance, % age fade , % age recovery & temperature rise lie within the range for friction materials used for low duty applications. The mechanical properties of these materials were characterized using ASTM standards. 展开更多
关键词 Friction material PREFORM FORGING Brake PADS Fade.
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A review of carbon-based hybrid materials for supercapacitors 被引量:4
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作者 Theodore Azemtsop Manfo Hannu Laaksonen 《新型炭材料(中英文)》 北大核心 2025年第1期81-110,共30页
Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effecti... Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effective energy storage systems.Ad-vances in materials science have led to the develop-ment of hybrid nanomaterials,such as combining fil-amentous carbon forms with inorganic nanoparticles,to create new charge and energy transfer processes.Notable materials for electrochemical energy-stor-age applications include MXenes,2D transition met-al carbides,and nitrides,carbon black,carbon aerogels,activated carbon,carbon nanotubes,conducting polymers,carbon fibers,and nanofibers,and graphene,because of their thermal,electrical,and mechanical properties.Carbon materials mixed with conducting polymers,ceramics,metal oxides,transition metal oxides,metal hydroxides,transition metal sulfides,trans-ition metal dichalcogenide,metal sulfides,carbides,nitrides,and biomass materials have received widespread attention due to their remarkable performance,eco-friendliness,cost-effectiveness,and renewability.This article explores the development of carbon-based hybrid materials for future supercapacitors,including electric double-layer capacitors,pseudocapacitors,and hy-brid supercapacitors.It investigates the difficulties that influence structural design,manufacturing(electrospinning,hydro-thermal/solvothermal,template-assisted synthesis,electrodeposition,electrospray,3D printing)techniques and the latest car-bon-based hybrid materials research offer practical solutions for producing high-performance,next-generation supercapacitors. 展开更多
关键词 Carbon-based hybrid material Structure design Electrode material Specific capacitance SUPERCAPACITORS
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High‑Entropy Electrode Materials:Synthesis,Properties and Outlook 被引量:1
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作者 Dongxiao Li Chang Liu +7 位作者 Shusheng Tao Jieming Cai Biao Zhong Jie Li Wentao Deng Hongshuai Hou Guoqiang Zou Xiaobo Ji 《Nano-Micro Letters》 SCIE EI CAS 2025年第1期472-506,共35页
High-entropy materials represent a new category of high-performance materials,first proposed in 2004 and extensively investigated by researchers over the past two decades.The definition of high-entropy materials has c... High-entropy materials represent a new category of high-performance materials,first proposed in 2004 and extensively investigated by researchers over the past two decades.The definition of high-entropy materials has continuously evolved.In the last ten years,the discovery of an increasing number of high-entropy materials has led to significant advancements in their utilization in energy storage,electrocatalysis,and related domains,accompanied by a rise in techniques for fabricating high-entropy electrode materials.Recently,the research emphasis has shifted from solely improving the performance of high-entropy materials toward exploring their reaction mechanisms and adopting cleaner preparation approaches.However,the current definition of high-entropy materials remains relatively vague,and the preparation method of high-entropy materials is based on the preparation method of single metal/low-or medium-entropy materials.It should be noted that not all methods applicable to single metal/low-or medium-entropy materials can be directly applied to high-entropy materials.In this review,the definition and development of high-entropy materials are briefly reviewed.Subsequently,the classification of high-entropy electrode materials is presented,followed by a discussion of their applications in energy storage and catalysis from the perspective of synthesis methods.Finally,an evaluation of the advantages and disadvantages of various synthesis methods in the production process of different high-entropy materials is provided,along with a proposal for potential future development directions for high-entropy materials. 展开更多
关键词 High-entropy Energy storage Electrode materials
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Carbon-based porous materials for performance-enhanced composite phase change materials in thermal energy storage:Materials,fabrication and applications 被引量:5
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作者 Lei Hu Li Zhang +4 位作者 Wei Cui Qinyou An Ting Ma Qiuwang Wang Liqiang Mai 《Journal of Materials Science & Technology》 2025年第7期204-226,共23页
Latent heat thermal energy storage(TES)effectively reduces the mismatch between energy supply and demand of renewable energy sources by the utilization of phase change materials(PCMs).However,the low thermal conductiv... Latent heat thermal energy storage(TES)effectively reduces the mismatch between energy supply and demand of renewable energy sources by the utilization of phase change materials(PCMs).However,the low thermal conductivity and poor shape stability are the main drawbacks in realizing the large-scale application of PCMs.Promisingly,developing composite PCM(CPCM)based on porous supporting mate-rial provides a desirable solution to obtain performance-enhanced PCMs with improved effective thermal conductivity and shape stability.Among all the porous matrixes as supports for PCM,three-dimensional carbon-based porous supporting material has attracted considerable attention ascribing to its high ther-mal conductivity,desirable loading capacity of PCMs,and excellent chemical compatibility with various PCMs.Therefore,this work systemically reviews the CPCMs with three-dimensional carbon-based porous supporting materials.First,a concise rule for the fabrication of CPCMs is illustrated in detail.Next,the experimental and computational research of carbon nanotube-based support,graphene-based support,graphite-based support and amorphous carbon-based support are reviewed.Then,the applications of the shape-stabilized CPCMs including thermal management and thermal conversion are illustrated.Last but not least,the challenges and prospects of the CPCMs are discussed.To conclude,introducing carbon-based porous materials can solve the liquid leakage issue and essentially improve the thermal conductivity of PCMs.However,there is still a long way to further develop a desirable CPCM with higher latent heat capacity,higher thermal conductivity,and more excellent shape stability. 展开更多
关键词 Thermal energy storage Phase change material Supporting material Carbon-based material Thermal conductivity Shape-stabilized composite
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Research progress of high-entropy cathode materials for sodium-ion batteries 被引量:2
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作者 Fan Wu Shaoyang Wu +2 位作者 Xin Ye Yurong Ren Peng Wei 《Chinese Chemical Letters》 2025年第4期20-33,共14页
In recent years,sodium-ion batteries(SIBs)have become one of the hot discussions and have gradually moved toward industrialization.However,there are still some shortcomings in their performance that have not been well... In recent years,sodium-ion batteries(SIBs)have become one of the hot discussions and have gradually moved toward industrialization.However,there are still some shortcomings in their performance that have not been well addressed,including phase transition,structural degradation,and voltage platform.High entropy materials have recently gained significant attention from researchers due to their effects on thermodynamics,dynamics,structure,and performance.Researchers have attempted to use these materials in sodium-ion batteries to overcome their problems,making it a modification method.This paper aims to discuss the research status of high-entropy cathode materials for sodium-ion batteries and summarize their effects on sodium-ion batteries from three perspectives:Layered oxide,polyanion,and Prussian blue.The infiuence on material structure,the inhibition of phase transition,and the improvement of ion diffusivity are described.Finally,the advantages and disadvantages of high-entropy cathode materials for sodium-ion batteries are summarized,and their future development has prospected. 展开更多
关键词 High-entropy material Sodium-ion battery Cathode materials Phase transition Structure
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Machine Learning-Based Methods for Materials Inverse Design: A Review 被引量:2
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作者 Yingli Liu Yuting Cui +4 位作者 Haihe Zhou Sheng Lei Haibin Yuan Tao Shen Jiancheng Yin 《Computers, Materials & Continua》 2025年第2期1463-1492,共30页
Finding materials with specific properties is a hot topic in materials science.Traditional materials design relies on empirical and trial-and-error methods,requiring extensive experiments and time,resulting in high co... Finding materials with specific properties is a hot topic in materials science.Traditional materials design relies on empirical and trial-and-error methods,requiring extensive experiments and time,resulting in high costs.With the development of physics,statistics,computer science,and other fields,machine learning offers opportunities for systematically discovering new materials.Especially through machine learning-based inverse design,machine learning algorithms analyze the mapping relationships between materials and their properties to find materials with desired properties.This paper first outlines the basic concepts of materials inverse design and the challenges faced by machine learning-based approaches to materials inverse design.Then,three main inverse design methods—exploration-based,model-based,and optimization-based—are analyzed in the context of different application scenarios.Finally,the applications of inverse design methods in alloys,optical materials,and acoustic materials are elaborated on,and the prospects for materials inverse design are discussed.The authors hope to accelerate the discovery of new materials and provide new possibilities for advancing materials science and innovative design methods. 展开更多
关键词 materials inverse design machine learning target properties deep learning new materials discovery
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Impact of pitch fraction oxidation on the structure and sodium storage properties of derived carbon materials 被引量:1
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作者 QI Su-xia YANG Tao +6 位作者 SONG Yan ZHAO Ning LIU Jun-qing TIAN Xiao-dong WU Jin-ru LI Hui LIU Zhan-jun 《新型炭材料(中英文)》 北大核心 2025年第2期421-439,共19页
Pitch produced by the lique-faction of coal was divided into two frac-tions:soluble in toluene(TS)and insol-uble in toluene but soluble in pyridine(TI-PS),and their differences in molecu-lar structure and oxidation ac... Pitch produced by the lique-faction of coal was divided into two frac-tions:soluble in toluene(TS)and insol-uble in toluene but soluble in pyridine(TI-PS),and their differences in molecu-lar structure and oxidation activity were studied.Several different carbon materi-als were produced from them by oxida-tion in air(350℃,300 mL/min)fol-lowed by carbonization(1000℃ in Ar),and the effect of the cross-linked structure on their structure and sodium storage properties was investigated.The results showed that the two pitch fractions were obviously different after the air oxidation.The TS fraction with a low degree of condensation and abundant side chains had a stronger oxidation activity and thus introduced more cross-linked oxygen-containing functional groups C(O)―O which prevented carbon layer rearrangement during the carbonization.As a result,a disordered hard carbon with more defects was formed,which improved the electrochemical performance.Therefore,the carbon materials derived from TS(O-TS-1000)had an obvious disordered structure and a larger layer spacing,giving them better sodium storage perform-ance than those derived from the TI-PS fraction(O-TI-PS-1000).The specific capacity of O-TS-1000 was about 250 mAh/g at 20 mA/g,which was 1.67 times higher than that of O-TI-PS-1000(150 mAh/g). 展开更多
关键词 Pitch fractions Air oxidation Derived carbon materials Na^(+)storage
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Emerging modification strategies for layered Fe-based oxide cathodes toward high-performance sodium-ion batteries 被引量:1
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作者 Zheng-Xiao Li Yi-Meng Wu +6 位作者 Jun-Wei Yin Peng-Fei Wang Zong-Lin Liu Yan-Xuan Wen Jun-Hong Zhang Yan-Rong Zhu Ting-Feng Yi 《Journal of Energy Chemistry》 2025年第8期122-147,共26页
Sodium-ion batteries(SIBs)have the advantages of environmental friendliness,cost-effectiveness,and high energy density,which are considered one of the most promising candidates for lithium-ion batteries(LIBs).The cath... Sodium-ion batteries(SIBs)have the advantages of environmental friendliness,cost-effectiveness,and high energy density,which are considered one of the most promising candidates for lithium-ion batteries(LIBs).The cathode materials influence the cost and energy output of SIBs.Therefore,the development of advanced cathode materials is crucial for the practical application of SIBs.Among various cathode materials,layered transition metal oxides(LTMOs)have received widespread attention owing to their straightforward preparation,abundant availability,and cost-competitiveness.Notably,layered Fe-based oxide cathodes are deemed to be one of the most promising candidates for the lowest price and easy-to-improve performance.Nevertheless,the challenges such as severe phase transitions,sluggish diffusion kinetics and interfacial degradation pose significant hurdles in achieving high-performance cathodes for SIBs.This review first briefly outlines the classification of layered structures and the working principle of layered oxides.Then,recent advances in modification strategies employed to address current issues with layered iron-based oxide cathodes are systematically reviewed,including ion doping,biphasic engineering and surface modification.Furthermore,the review not only outlines the prospects and development directions for layered Fe-based oxide cathodes but also provides novel insights and directions for future research endeavors for SIBs. 展开更多
关键词 Layered fe-based oxide cathodes lon doping Biphasic engineering Surface modification Sodium-ion batteries
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Optimization of Mg-based hydrogen storage materials with multicomponent and high-entropy catalysts 被引量:1
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作者 Yu Sun Jiayi Cheng +2 位作者 Yaru Jiang Yafei Liu Yijing Wang 《International Journal of Minerals,Metallurgy and Materials》 2025年第11期2699-2712,共14页
Novel hydrogen storage materials have propelled progress in hydrogen storage technologies.Magnesium hydride(MgH_(2))is a highly promising candidate.Nevertheless,several drawbacks,including the need for elevated therma... Novel hydrogen storage materials have propelled progress in hydrogen storage technologies.Magnesium hydride(MgH_(2))is a highly promising candidate.Nevertheless,several drawbacks,including the need for elevated thermal conditions,sluggish dehydrogena-tion kinetics,and high thermodynamic stability,limit its practical application.One effective method of addressing these challenges is cata-lyst doping,which effectively boosts the hydrogen storage capability of Mg-based materials.Herein,we review recent advancements in catalyst-doped MgH_(2) composites,with particular focus on multicomponent and high-entropy catalysts.Structure-property relationships and catalytic mechanisms in these doping strategies are also summarized.Finally,based on existing challenges,we discuss future research directions for the development of Mg-based hydrogen storage systems. 展开更多
关键词 magnesium hydride multicomponent materials high-entropy materials hydrogen storage catalyst doping kinetics
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Adjustable corrosion and mechanical properties of Mg-Zn-Ca-Ni alloys for fracturing materials 被引量:2
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作者 Dawei Wang Xiangshuang Jiang +7 位作者 Changxin Chen Xun Zhang Zhong-Zheng Jin Fuyong Cao Jia-Ning Zhu Cheng Wang Yinlong Ma Min Zha 《Journal of Magnesium and Alloys》 2025年第6期2618-2635,共18页
Two sets of alloys,Mg-Zn-Ca-xNi(0≤x≤5),have been developed with tunable corrosion and mechanical properties,optimized for fracturing materials.High-zinc artificial aged(T6)Mg-12Zn-0.5Ca-x Ni(0≤x≤5)series,featuring... Two sets of alloys,Mg-Zn-Ca-xNi(0≤x≤5),have been developed with tunable corrosion and mechanical properties,optimized for fracturing materials.High-zinc artificial aged(T6)Mg-12Zn-0.5Ca-x Ni(0≤x≤5)series,featuring a straightforward preparation method and the potential for manufacturing large-scale components,exhibit notable corrosion rates up to 29 mg cm^(-2)h^(-1)at 25℃ and 643 mg cm^(-2)h^(-1)at 93℃.The high corrosion rate is primary due to the Ni–containing second phases,which intensify the galvanic corrosion that overwhelms their corrosion barrier effect.Low-zinc rolled Mg-1.5Zn-0.2Ca-x Ni(0≤x≤5)series,characterizing excellent deformability with an elongation to failure of~26%,present accelerated corrosion rates up to 34 mg cm^(-2)h^(-1)at 25℃ and 942 mg cm^(-2)h^(-1)at 93℃.The elimination of corrosion barrier effect via deformation contributes to the further increase of corrosion rate compared to the T6 series.Additionally,Mg-Zn-Ca-xNi(0≤x≤5)alloys exhibit tunable ultimate tensile strengths ranging from~190 to~237 MPa,depending on their specific composition.The adjustable corrosion rate and mechanical properties render the Mg-Zn-Ca-x Ni(0≤x≤5)alloys suitable for fracturing materials. 展开更多
关键词 Mg-Zn-Ca alloy Fracturing material Galvanic corrosion Corrosion barrier
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Recent developments in MQL machining of aeronautical materials:A comparative review 被引量:3
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作者 Syed Hammad ALI Yu YAO +7 位作者 Bangfu WU Biao ZHAO Wenfeng DING Muhammad JAMIL Ahmar KHAN Asra BAIG Qi LIU Dongdong XU 《Chinese Journal of Aeronautics》 2025年第1期43-69,共27页
Minimum quantity lubrication(MQL),as a new sustainable and eco-friendly alternative cooling/lubrication technology that addresses the limitations of dry and wet machining,utilizes a small amount of lubricant or coolan... Minimum quantity lubrication(MQL),as a new sustainable and eco-friendly alternative cooling/lubrication technology that addresses the limitations of dry and wet machining,utilizes a small amount of lubricant or coolant to reduce friction,tool wear,and heat during cutting processes.MQL technique has witnessed significant developments in recent years,such as combining MQL with other sustainable techniques to achieve optimum results,using biodegradable lubricants,and innovations in nozzle designs and delivery methods.This review presents an in-depth analysis of machining characteristics(e.g.,cutting forces,temperature,tool wear,chip morphology and surface integrity,etc.)and sustainability characteristics(e.g.,energy consumption,carbon emissions,processing time,machining cost,etc.)of conventional MQL and hybrid MQL techniques like cryogenic MQL,Ranque-Hilsch vortex tube MQL,nanofluids MQL,hybrid nanofluid MQL and ultrasonic vibration assisted MQL in machining of aeronautical materials.Subsequently,the latest research and developments are analyzed and summarized in the field of MQL,and provide a detailed comparison between each technique,considering advantages,challenges,and limitations in practical implementation.In addition,this review serves as a valuable source for researchers and engineers to optimize machining processes while minimizing environmental impact and operational costs.Ultimately,the potential future aspects of MQL for research and industrial execution are discussed. 展开更多
关键词 Aerospace materials Minimum Quantity Lubrication(MQL) CRYOGENIC NANOFLUID GRINDING MILLING Sustainability
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