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掺杂Fe/Ti-HMS纳米光催化剂的合成与表征
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作者 张平 陈君华 朱田生 《浙江化工》 CAS 2009年第3期11-13,共3页
在室温条件下通过溶胶凝胶法,以正硅酸乙酯为硅源,硫酸钛为钛源,三氯化铁为铁源,中性十二胺为模板剂成功合成了DDA-HMS,HMS,Ti-HMS以及Fe/Ti-HMS分子筛。采用粉末X射线(XRD),(FT-IR)、电子扫描显微镜(SEM)等手段对样品进行了表征。结果... 在室温条件下通过溶胶凝胶法,以正硅酸乙酯为硅源,硫酸钛为钛源,三氯化铁为铁源,中性十二胺为模板剂成功合成了DDA-HMS,HMS,Ti-HMS以及Fe/Ti-HMS分子筛。采用粉末X射线(XRD),(FT-IR)、电子扫描显微镜(SEM)等手段对样品进行了表征。结果表明,分子筛的XRD图谱在小角度区出现较强的特征衍射峰,材料具有一维六方中孔结构,表征证实了Fe、Ti同时嵌入了HMS的晶体骨架,具有良好的稳定性。 展开更多
关键词 fe/ti-hms分子筛 光催化剂 表征 十二胺
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Band Gap Control for (Fe, Ti)-Containing Mesoporous Silica Nanoparticles Using the Photo-Assisted Deposition Technique 被引量:1
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作者 R.M. Mohamed A.M. El-Toni F.A. Harraz I.A. Ibrahim 《Journal of Environmental Science and Engineering》 2010年第7期36-40,共5页
It is a great advantage to design advanced materials with outstanding porosity and controllable band gab. In this study, (Fe, Ti)-containing mesoporous silica (x Fe/Ti-HMS) nanoparticles were prepared by a photo-a... It is a great advantage to design advanced materials with outstanding porosity and controllable band gab. In this study, (Fe, Ti)-containing mesoporous silica (x Fe/Ti-HMS) nanoparticles were prepared by a photo-assisted deposition PAD technique, where x is a nominal composition ofFe (l to 4 wt%)). The prepared samples were characterized by DR-UV, XRD, and TEM techniques. The results showed the insertion of Fe into intra-framework of Ti-HMS resulted in a gradual narrowing of the band gap of Ti-HMS samples with increment of Fe wt%. TEM observations reveal that Fe nanoparticles are evenly distributed within Ti-HSM matrix at different Fe wt%. Such results indicate the possibility to control the band gap of a single-site photocatalyst (Ti-HMS) by coupling it with the conventional nano-sized Fe catalysts. 展开更多
关键词 NANOMATERIALS single-site photocatalyst fe/ti-hms
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