An effective kinetic resolution of a variety of aryl alkenylcarbinols catalyzed by nonenzymatic acyl transfer catalyst Fe-PIP was developed, affording corresponding unreacted alcohols in good to excellent ee value up ...An effective kinetic resolution of a variety of aryl alkenylcarbinols catalyzed by nonenzymatic acyl transfer catalyst Fe-PIP was developed, affording corresponding unreacted alcohols in good to excellent ee value up to 99% and with selectivity factors up to 24.展开更多
A highly enantioselective intramolecular Michael addition-Lactonization domino reaction of a range of enon acids catalyzed by nuleophilic organocatalyst(Fc-PIP)was developed,furnishing cis-2,3-dihydrobenzofuran deriva...A highly enantioselective intramolecular Michael addition-Lactonization domino reaction of a range of enon acids catalyzed by nuleophilic organocatalyst(Fc-PIP)was developed,furnishing cis-2,3-dihydrobenzofuran derivatives with excellent enantioselecitivities(94%-98%ee)and good diastereoselectivities(up to 99/1).展开更多
文摘An effective kinetic resolution of a variety of aryl alkenylcarbinols catalyzed by nonenzymatic acyl transfer catalyst Fe-PIP was developed, affording corresponding unreacted alcohols in good to excellent ee value up to 99% and with selectivity factors up to 24.
基金The authors are grateful to the Fundamental Research Funds for the Central Universities,the National Natural Science Foundation of China(No.21372074).
文摘A highly enantioselective intramolecular Michael addition-Lactonization domino reaction of a range of enon acids catalyzed by nuleophilic organocatalyst(Fc-PIP)was developed,furnishing cis-2,3-dihydrobenzofuran derivatives with excellent enantioselecitivities(94%-98%ee)and good diastereoselectivities(up to 99/1).
