Light alloys have irreplaceable advantages such as high specific strength and low density.They are indispensable structural materials in aerospace,military,and marine engineering.It is an enduring research hotspot to ...Light alloys have irreplaceable advantages such as high specific strength and low density.They are indispensable structural materials in aerospace,military,and marine engineering.It is an enduring research hotspot to prepare high-strength and high-toughness light alloys to play a more significant role in advanced engineering applications.As a new method to improve the mechanical properties of light alloys,the magnetic field-assisted process can produce magnetoplastic effects.Therefore,in this paper,research progress on the magnetoplastic effects of light alloys assisted by magnetic fields was reviewed,and the effects of magnetic fields on dislocations,grain refinement,precipitation kinetics,phase transformation,and mechanical properties of light alloys were elucidated.Magnetic field treatment transforms radical pairs from the ground state to the excited state,which reduces the resistance between dislocations and obstacles,facilitating dislocation depinning.Moreover,magnetic field can promote grain refinement and phase transformation,increase precipitation kinetics,and synergistically improve strength and elongation.Finally,the prospects of magnetic field-assisted processes of light alloys were discussed.展开更多
Light sub-GeV dark matter(DM)particles up-scattered by high-energy cosmic rays(CRs)(referred to as CRDM)can be energetic and become detectable by conventional DM direct detection experiments.Nevertheless,current CRDM ...Light sub-GeV dark matter(DM)particles up-scattered by high-energy cosmic rays(CRs)(referred to as CRDM)can be energetic and become detectable by conventional DM direct detection experiments.Nevertheless,current CRDM theoretical frameworks remain limited by model-dependent parameterizations,whereas the effective operators provides a modelindependent computing framework.In this work,we systematically investigate the general relativistic DM-nucleus spin-independent interactions.We first construct effective operators for dark matter with spin up to two,i.e.spin-1/2 fermionic DM(χ),the scalar DM(φ),the vector DM(V_(μ)),spin-3/2 fermionic DM(Ψ)and spin-2 DM(T~(μν)).We then derive the CRDM flux and the nuclear recoil event rate based on these operators,and employ nuclear recoil data from the LUX-ZEPLIN(LZ)experiment to constrain all effective operators.We set stringent constraints on the CRDM-nucleon scattering cross section for sub-GeV DM.Especially,our results show that the exclusion limits from the spin-2 T~(μν)operator differ by as much as ten orders of magnitude from those calculated using constant cross section.展开更多
Infertility,defined as the inability to achieve a clinical pregnancy after 1 year of unprotected and regular sexual intercourse,affects approximately 8%–12%of couples worldwide during their childbearing years.Assiste...Infertility,defined as the inability to achieve a clinical pregnancy after 1 year of unprotected and regular sexual intercourse,affects approximately 8%–12%of couples worldwide during their childbearing years.Assisted reproductive technology(ART)offers interventions to facilitate conception in couples with infertility.Since the inception of traditional in vitro fertilization(IVF)in 1978,ART has facilitated the birth of millions of infants.Intracytoplasmic sperm injection(ICSI)is an effective technique for couples ineligible for traditional IVF.Individual female factors,such as age and endometrial thickness,have been shown to affect embryo development during the IVF process,resulting in unfavorable pregnancy outcomes[1-3].However,the influence of environmental and male factors on early reproductive outcomes cannot be ignored.As a novel form of environmental pollution,light at night(LAN)has intensified with the rapid pace of urbanization,potentially leading to reproductive health problems in both women and men.However,to our knowledge,no study has explored the effects of LAN exposure on the early reproductive outcomes of IVF.Furthermore,the normal development of embryos relies on the contributions of both partners,and the influence of male factors on the early reproductive outcomes of IVF should not be overlooked.展开更多
This study developed a novel heterogeneous Vis-Photo+Fenton-like system by integrating visible-light-responsive Co_(3)O_(4)/TiO_(2) photocatalysis with peroxymonosulfate(PMS)activation for efficient atrazine(ATZ)degra...This study developed a novel heterogeneous Vis-Photo+Fenton-like system by integrating visible-light-responsive Co_(3)O_(4)/TiO_(2) photocatalysis with peroxymonosulfate(PMS)activation for efficient atrazine(ATZ)degradation.The synergistic process achieved complete ATZ removal within 60 min under near-neutral pH(6.9),outperform-ing individual Fenton-like(39%)and photocatalytic(24%)processes.Key factors influencing the degradation efficiency included light sources(UV>visible),pH(optimal at 6.9),catalyst dosage(0.01 g Co_(3)O_(4)/TiO_(2)),and PMS:ATZ molar ratio(1:2).The system exhibited a synergistic coefficient of 5.03(degradation)and 1.97(miner-alization),attributed to enhanced radical generation and accelerated Co^(3+)/Co^(2+)redox cycling through photoin-duced electron transfer.Intermediate analysis revealed dealkylation,dechlorination,and oxidation pathways,with reduced toxicity of by-products(e.g.,CEAT,CIAT)confirmed by ecotoxicity assessments.The mineralization efficiency(Vis-Photo+Fenton-like)reached 83.1%,significantly higher than that of standalone processes(Fenton-like:43.2%;photocatalysis:30.5%).The catalyst demonstrated excellent stability(nearly 90%recov-ery,<1μg/L Co leaching)and practical applicability.This study provides an efficient,sludge-free,and solar-compatible strategy for eliminating persistent herbicides in water treatment.展开更多
Polymer thin film with uniform thickness and flat surface profile is the key point for polymer light emitting diodes(PLEDs) by inkjet printing. However, the coffee ring effect is usually observed due to the mismatch b...Polymer thin film with uniform thickness and flat surface profile is the key point for polymer light emitting diodes(PLEDs) by inkjet printing. However, the coffee ring effect is usually observed due to the mismatch between the evaporation of the solvent and the decrease of solution volume, which promotes the formation of radial flow from the interior of the drop to the edge. In this paper, coffee ring effects of inkjet printed poly(spirobifluorene) films were proposed to be restrained by decreasing capillary force by adding co-solvent with high boiling point and high viscosity to the main solvent. The low evaporation rate of the co-solvent can reduce the driving force of the radial flow; meanwhile the high viscosity of the co-solvent can increase the resistance of the radial flow. Thus, polymer films with improve uniformity can be obtained due to the suppression of the radial flow. The device performance was greatly improved under the condition of proper film thickness and film uniformity and the maximum luminous efficiency of devices with inkjet printed poly(spirobifluorene) can reach 80% of the spin-coated devices.展开更多
Digital structured light （SL） profilometry is increasingly used in three-dimensional （3D） measurement technology. However, the nonlinearity of the off-the-shelf projectors and cameras seriously reduces the measure...Digital structured light （SL） profilometry is increasingly used in three-dimensional （3D） measurement technology. However, the nonlinearity of the off-the-shelf projectors and cameras seriously reduces the measurement accuracy. In this paper, first, we review the nonlinear effects of the projector-camera system in the phase-shifting structured light depth measurement method. We show that high order harmonic wave components lead to phase error in the phase-shifting method. Then a practical method based on frequency domain filtering is proposed for nonlinear error reduction. By using this method, the nonlinear calibration of the SL system is not required. Moreover, both the nonlinear effects of the projector and the camera can be effectively reduced. The simulations and experiments have verified our nonlinear correction method.展开更多
Light is an important parameter in algal culturing.In this work,the effects of different light qualities on growth of the marine diatom Chaetoceros gracilis are evaluated.The cells were cultured under light quantum fl...Light is an important parameter in algal culturing.In this work,the effects of different light qualities on growth of the marine diatom Chaetoceros gracilis are evaluated.The cells were cultured under light quantum flux density of 60μmol photons/(m2·s)with nine light qualities:LED red light(LR),LED blue light(LB),LED red plus LED blue light(LR+LB),LED white light(LW),fluorescent white light(FW),and combinations of LW and FW lights with increased proportions of red or blue light(FW+LR,FW+LB,LW+LR,and LW+LB).Blue light promoted the growth of C.gracilis largely.Three light qualities,FW+LR,LW+LR,and LR,resulted in the lowest growth rate.Both chlorophyll and carotenoids reached the highest level under LB and the lowest level under LR among monochromatic light sources;however,increasing of the proportion of blue or red light in the white light induced an increase of the chlorophyll and carotenoid concentrations.Light absorption ability of microalgae was critical for the growth of these organisms,as we observed a positive correlation between the extinction coefficient at different wavelengths and the specific growth rate.These findings are of importance to improve the culturing of this alga in bioreactors.展开更多
We investigate the effects of dynamical Casimir effect in superradiant light scattering by Bose-Einstein condensate in an optomechanical cavity. The system is studied using both classical and quantized mirror motions....We investigate the effects of dynamical Casimir effect in superradiant light scattering by Bose-Einstein condensate in an optomechanical cavity. The system is studied using both classical and quantized mirror motions. The cavity frequency is harmonically modulated in time for both the cases. The main quantity of interest is the number of intracavity scattered photons. The system has been investigated under the weak and strong modulations. It has been observed that the amplitude of the scattered photons is more for the classical mirror motion than the quantized mirror motion. Also, initially, the amplitude of scattered photons is high for lower modulation amplitude than higher modulation amplitude. We also found that the behavior of the plots are similar under strong and weak modulations for the quantized mirror motion.展开更多
Hall effect of light is a result of symmetry breaking in spin and/or orbital angular momentum(OAM)possessing optical system and is caused by e.g.refractive index gradient/interface between media or focusing of a spati...Hall effect of light is a result of symmetry breaking in spin and/or orbital angular momentum(OAM)possessing optical system and is caused by e.g.refractive index gradient/interface between media or focusing of a spatially asymmetrical beam,similar to the electric field breaking the symmetry in spin Hall effect for electrons.The angular momentum(AM)conservation law in the ensuing asymmetric system dictates redistribution of spin and orbital angular momentum,and is manifested in spin-orbit,orbit-orbit,and orbit-spin conversions and reorganization,i.e.spin-orbit and orbit-orbit interaction.This AM restructuring in turn requires shifts of the barycenter of the electric field of light.In the present study we show,both analytically and by numerical simulation,how different electric field components are displaced upon tight focusing of an asymmetric light beam having OAM and spin.The relation between field components shifts and the AM components shifts/redistribution is presented too.Moreover,we experimentally demonstrate,for the first time,to the best of our knowledge,the spin-orbit Hall effect of light upon tight focusing in free space.This is achieved using azopolymers as a media detecting longitudinal or z component of the electrical field of light.These findings elucidate the Hall effect of light and may broaden the spectrum of its applications.展开更多
Effects of La, N, and P doping on the structural, electronic and optical properties of TiO_2 synthesized from TiCl_4 hydrolysis via a microwave-hydrothermal process were investigated by X-ray diffraction, transmission...Effects of La, N, and P doping on the structural, electronic and optical properties of TiO_2 synthesized from TiCl_4 hydrolysis via a microwave-hydrothermal process were investigated by X-ray diffraction, transmission electron microscopy, N_2 adsorption-desorption isotherm, X-ray photoelectron spectroscopy, electron paramagnetic resonance, UV-vis absorbance spectroscopy, photoelectrochemical measurements, and photoluminescence spectroscopy. The results showed that the presence of La in the tri-doped TiO_2 played a predominant role in inhibiting the recombination of the photogenerated electrons and holes. The existence of the substitutional N, interstitial N, and oxygen vacancies in TiO_2 lattices led to the band gap narrowing. It was P-doping rather than La or N doping that played a key role in inhibiting both anatase-to-rutile phase transformation and crystal growth, in stabilizing the mesoporous textural properties, and in increasing the content of surface bridging hydroxyl. Moreover, the tri-doping significantly enhanced the surface Ti^（4＋）-O^（2-）-Ti^（4＋）-O^（-·） species. All above-mentioned factors cooperated to result in the enhanced photoactivity of the tri-doped TiO_2. As a result, it exhibited the highest photoactivity towards the degradation of 4-chlorophenol（4-CP） under visible-light irradiation among all samples, which was much superior to commercial P25 TiO_2.展开更多
Scattered light imaging through complex turbid media has significant applications in biomedical and optical research.For the past decade,various approaches have been proposed for rapidly reconstructing fullcolor,depth...Scattered light imaging through complex turbid media has significant applications in biomedical and optical research.For the past decade,various approaches have been proposed for rapidly reconstructing fullcolor,depth-extended images by introducing point spread functions(PSFs).However,because most of these methods consider memory effects(MEs),the PSFs have angular shift invariance over certain ranges of angles.This assumption is valid for only thin turbid media and hinders broader applications of these technologies in thick media.Furthermore,the time-variant characteristics of scattering media determine that the PSF acquisition and image reconstruction times must be less than the speckle decorrelation time,which is usually difficult to achieve.We demonstrate that image reconstruction methods can be applied to timevariant thick turbid media.Using the time-variant characteristics,the PSFs in dynamic turbid media within certain time intervals are recorded,and ergodic scattering regimes are achieved and combined as ensemble point spread functions(ePSFs).The ePSF traverses shift-invariant regions in the turbid media and retrieves objects beyond the ME.Furthermore,our theory and experimental results verify that our approach is applicable to thick turbid media with thickness of 1 cm at visible incident wavelengths.展开更多
Information concerns endocytosis and autophagic effects of magnetite particles is crucial for understanding the particle-cell interactions. In this work, we investigated the effects of bovine serum proteins on the end...Information concerns endocytosis and autophagic effects of magnetite particles is crucial for understanding the particle-cell interactions. In this work, we investigated the effects of bovine serum proteins on the endocytosis of magnetite spherical particles（MSPs）. Autophagic effects of MSPs in breast cancer cells were studied. Light scattering based flow cytometry and microscopy were used for evaluating the uptake potential of MSPs by cells and the cellular autophagosome accumulation. Results showed bovine serum proteins significantly reduced the endocytosis of MSPs by decreasing their adsorption to cell membranes. Additionally, serum proteins had influences on the endocytic mechanisms of MSPs.Autophagosome accumulation could be caused by the internalized MSPs rather than the particles associated with cell membrane. Above fundamental findings promote our understandings upon the interactions of MSPs with cells. Light scattering based methods were proved to be simple and effective.The present work may promote their application in studies upon endocytosis of metallic particles in the future.展开更多
We theoretically and experimentally investigate a switchable spin Hall effect（SHE） of light in reflection near the Brewster angle at an air-uniaxial crystal interface.We find a large transverse spin splitting near t...We theoretically and experimentally investigate a switchable spin Hall effect（SHE） of light in reflection near the Brewster angle at an air-uniaxial crystal interface.We find a large transverse spin splitting near the Brewster angle,whose sign can be altered by rotating the optical axis.As an analogy of the SHE in an electronic system,a switchable spin accumulation in the SHE of light is detected.We are able to switch the direction of the spin accumulation by adjusting the optical axis angle of the uniaxial crystal.These findings may give opportunities for photon spin manipulating and developing a new generation of nano-photonic devices.展开更多
We theoretically investigate a switchable spin Hall effect of light （SHEL） in reflection for three specific dispersion relations at an air-anisotropic metamaterial interface. The displacements of horizontal and vert...We theoretically investigate a switchable spin Hall effect of light （SHEL） in reflection for three specific dispersion relations at an air-anisotropic metamaterial interface. The displacements of horizontal and vertical polarization compo- nents vary with the incident angle at different dispersion relations. The transverse displacements can be obtained with the relevant metamaterial whose refractive index can be arbitrarily tailed. The results of the SHEL in the metamaterial provide a new way for manipulating the transverse displacements of a specific polarization component.展开更多
The revolution in information sharing is fundamentally supported by the highly efficient processing,storage,and transmission of data[1].For the latter,energy consumption continuously increases with the rapid developme...The revolution in information sharing is fundamentally supported by the highly efficient processing,storage,and transmission of data[1].For the latter,energy consumption continuously increases with the rapid development of information and communication technology[2].展开更多
The supramolecular F?rster resonance energy transfer(FRET)is seen as a promising approach for organic photocatalysis using dyes as catalysts,because it combines the high efficiency of energy transfer with the dynamic ...The supramolecular F?rster resonance energy transfer(FRET)is seen as a promising approach for organic photocatalysis using dyes as catalysts,because it combines the high efficiency of energy transfer with the dynamic responsiveness based on non-covalent interactions.Here we propose a supramolecular FRET photocatalysis strategy forα-oxyamination reaction based on supramolecular confinement effect.The well-designed benzothiadiazole-based cationic monomer as energy donor and the dyes of Nile Red as acceptor are doped into the amphiphilic surfactants of sodium dodecyl sulfate(SDS).Benefitting from the supramolecular confinement space provided by SDS in aqueous environment,the FRET process between the monomer and Nile Red is effectively achieved(exciton migration rate:3.99×10^(14)L mol^(-1)s^(-1)).On this basis,the supramolecular FRET system is used as an efficient energy source to catalyzeα-oxyamination reactions between a series of 1,3-dicarbonyl compounds and 2,2,6,6-tetramethylpiperidine-1-oxyl under white LED light,showing a yield as high as 94%and a turnover frequency value of 3.92 h^(-1).This photocatalytic result shows a great enhancement compared to that of Nile Red alone.展开更多
Periodic photonic structures can provide rich modulation in propagation of light due to well-defined band structures.Especially near band edges,light localization and the effect of near-zero refractive index have attr...Periodic photonic structures can provide rich modulation in propagation of light due to well-defined band structures.Especially near band edges,light localization and the effect of near-zero refractive index have attracted wide attention.However,the practically fabricated structures can only have finite size,i.e.,limited numbers of periods,leading to changes of the light propagation modulation compared with infinite structures.Here,we study the size effect on light localization and near-zero refractive-index propagation near band edges in one-dimensional periodic structures.Near edges of the band gap,as the structure's size shrinks,the broadening of the band gap and the weakening of the light localization are discovered.When the size is small,an added layer on the surface will perform large modulation in the group velocity.Near the degenerate point with Dirac-like dispersion,the zero-refractive-index effects like the zero-phase difference and near-unity transmittance retain as the size changes,while absolute group velocity fluctuates when the size shrinks.展开更多
The angle compensation method is adopted to detect sloshing waves by laser diffraction, in the case that the wavelength of the sloshing waves is much greater than that of the incident light. The clear diffraction patt...The angle compensation method is adopted to detect sloshing waves by laser diffraction, in the case that the wavelength of the sloshing waves is much greater than that of the incident light. The clear diffraction pattern is observed to be of asymmetry, involving orders, position and interval of the diffraction spots that are discovered during the light grazing incidence. It is found that the larger the angle of incidence is, the more obvious the asymmetry is. The higher the negative diffraction orders are, the smaller the intervals between spots are. On the contrary~ in the positive region, the higher the diffraction orders are, the larger the spot intervals are. The positive interval is larger than that of the same negative diffraction order. If the incident angle reaches 1.558 rad in the experiment, all positive diffraction orders completely vanish. Based on the mechanism of phase modulation and with the Fourier transform method, the relations between the incident angle and position, interval spaces, and orders of diffraction spots are derived theoretically. The theoretical calculations are compared with the experimental data, and the comparison shows that the theoretical calculations are in good agreement with the experimental measurement.展开更多
With the increasing attention on circadian effects driven by light,lighting industry has inspired a revolution of photobiological lighting design.Due to diverse evaluation criteria for visual and non⁃visual systems,mo...With the increasing attention on circadian effects driven by light,lighting industry has inspired a revolution of photobiological lighting design.Due to diverse evaluation criteria for visual and non⁃visual systems,models that combine these evaluation parameters are indeed urgent.Thus,an integrated model for mesopic lighting evaluation of circadian effects was proposed.The circadian efficiency function adopted in this study was synthesized by CIE 1931 XYZ 2 deg color matching functions and standard scotopic sensitivity function.Then,the integrated model composed of International Commission on Illumination 1931 xy chromaticity coordinates,scotopic/photopic ratio,and illuminance could be obtained with synthesized circadian efficiency function.The model showed that for light sources with fixed chromaticity coordinates and fixed illuminance,enhancing the circadian effects is equivalent to increasing the scotopic/photopic ratio,which suggests a useful method for practitioners to explore the photobiologically reasonable spectrum for mesopic lighting.Light⁃emitting diodes spectra optimized by four⁃component color⁃mixing method were employed to figure out the property of the integrated model.展开更多
基金supported by the National Natural Science Foundation of China(No.52274382)the National Key Research and Development Program of China(No.2023YFB3407000).
文摘Light alloys have irreplaceable advantages such as high specific strength and low density.They are indispensable structural materials in aerospace,military,and marine engineering.It is an enduring research hotspot to prepare high-strength and high-toughness light alloys to play a more significant role in advanced engineering applications.As a new method to improve the mechanical properties of light alloys,the magnetic field-assisted process can produce magnetoplastic effects.Therefore,in this paper,research progress on the magnetoplastic effects of light alloys assisted by magnetic fields was reviewed,and the effects of magnetic fields on dislocations,grain refinement,precipitation kinetics,phase transformation,and mechanical properties of light alloys were elucidated.Magnetic field treatment transforms radical pairs from the ground state to the excited state,which reduces the resistance between dislocations and obstacles,facilitating dislocation depinning.Moreover,magnetic field can promote grain refinement and phase transformation,increase precipitation kinetics,and synergistically improve strength and elongation.Finally,the prospects of magnetic field-assisted processes of light alloys were discussed.
基金supported in part by the National Key R&D Program of China under Grant No.2017YFA0402204the National Natural Science Foundation of China(NSFC)under Grant Nos.11825506,11821505,12047503。
文摘Light sub-GeV dark matter(DM)particles up-scattered by high-energy cosmic rays(CRs)(referred to as CRDM)can be energetic and become detectable by conventional DM direct detection experiments.Nevertheless,current CRDM theoretical frameworks remain limited by model-dependent parameterizations,whereas the effective operators provides a modelindependent computing framework.In this work,we systematically investigate the general relativistic DM-nucleus spin-independent interactions.We first construct effective operators for dark matter with spin up to two,i.e.spin-1/2 fermionic DM(χ),the scalar DM(φ),the vector DM(V_(μ)),spin-3/2 fermionic DM(Ψ)and spin-2 DM(T~(μν)).We then derive the CRDM flux and the nuclear recoil event rate based on these operators,and employ nuclear recoil data from the LUX-ZEPLIN(LZ)experiment to constrain all effective operators.We set stringent constraints on the CRDM-nucleon scattering cross section for sub-GeV DM.Especially,our results show that the exclusion limits from the spin-2 T~(μν)operator differ by as much as ten orders of magnitude from those calculated using constant cross section.
基金supported by grants from the National Key Research and Development Program of China(No.2018YFC1004201)National Natural Science Foundation of China(No.82473642)+3 种基金Research Funds of the Center for Big Data and Population Health of IHM(No.JKS2023017)Natural Science Foundation of Anhui Province(No.2408085QH278)Research Fund of the Anhui Institute of Translational Medicine(No.2022zhyx-C05)Anhui Medical University National Undergraduate Innovation and Entrepreneurship Training Program(No.S202410366070).
文摘Infertility,defined as the inability to achieve a clinical pregnancy after 1 year of unprotected and regular sexual intercourse,affects approximately 8%–12%of couples worldwide during their childbearing years.Assisted reproductive technology(ART)offers interventions to facilitate conception in couples with infertility.Since the inception of traditional in vitro fertilization(IVF)in 1978,ART has facilitated the birth of millions of infants.Intracytoplasmic sperm injection(ICSI)is an effective technique for couples ineligible for traditional IVF.Individual female factors,such as age and endometrial thickness,have been shown to affect embryo development during the IVF process,resulting in unfavorable pregnancy outcomes[1-3].However,the influence of environmental and male factors on early reproductive outcomes cannot be ignored.As a novel form of environmental pollution,light at night(LAN)has intensified with the rapid pace of urbanization,potentially leading to reproductive health problems in both women and men.However,to our knowledge,no study has explored the effects of LAN exposure on the early reproductive outcomes of IVF.Furthermore,the normal development of embryos relies on the contributions of both partners,and the influence of male factors on the early reproductive outcomes of IVF should not be overlooked.
基金supported by the Financial Supports of the National Natural Science Foundation of China(Nos.51508056,52370030 and 42007352)the Chongqing Postgraduate Joint Training Base Project(No.JDLHPYJD2022005)the special fund of Henan Key Labora-tory of Water Pollution Control and Rehabilitation Technology(No.CJSZ2024001).
文摘This study developed a novel heterogeneous Vis-Photo+Fenton-like system by integrating visible-light-responsive Co_(3)O_(4)/TiO_(2) photocatalysis with peroxymonosulfate(PMS)activation for efficient atrazine(ATZ)degradation.The synergistic process achieved complete ATZ removal within 60 min under near-neutral pH(6.9),outperform-ing individual Fenton-like(39%)and photocatalytic(24%)processes.Key factors influencing the degradation efficiency included light sources(UV>visible),pH(optimal at 6.9),catalyst dosage(0.01 g Co_(3)O_(4)/TiO_(2)),and PMS:ATZ molar ratio(1:2).The system exhibited a synergistic coefficient of 5.03(degradation)and 1.97(miner-alization),attributed to enhanced radical generation and accelerated Co^(3+)/Co^(2+)redox cycling through photoin-duced electron transfer.Intermediate analysis revealed dealkylation,dechlorination,and oxidation pathways,with reduced toxicity of by-products(e.g.,CEAT,CIAT)confirmed by ecotoxicity assessments.The mineralization efficiency(Vis-Photo+Fenton-like)reached 83.1%,significantly higher than that of standalone processes(Fenton-like:43.2%;photocatalysis:30.5%).The catalyst demonstrated excellent stability(nearly 90%recov-ery,<1μg/L Co leaching)and practical applicability.This study provides an efficient,sludge-free,and solar-compatible strategy for eliminating persistent herbicides in water treatment.
基金financially supported by the National Natural Science Foundation of China (Nos. 21574130, 51473161, 51873212)the Ministry of Science and Technology of China (No. 2015CB655001)National Key R&D Program of "Strategic Advanced Electronic Materials" (Nos. 2016YFB0401301, 2016YFB04011001)
文摘Polymer thin film with uniform thickness and flat surface profile is the key point for polymer light emitting diodes(PLEDs) by inkjet printing. However, the coffee ring effect is usually observed due to the mismatch between the evaporation of the solvent and the decrease of solution volume, which promotes the formation of radial flow from the interior of the drop to the edge. In this paper, coffee ring effects of inkjet printed poly(spirobifluorene) films were proposed to be restrained by decreasing capillary force by adding co-solvent with high boiling point and high viscosity to the main solvent. The low evaporation rate of the co-solvent can reduce the driving force of the radial flow; meanwhile the high viscosity of the co-solvent can increase the resistance of the radial flow. Thus, polymer films with improve uniformity can be obtained due to the suppression of the radial flow. The device performance was greatly improved under the condition of proper film thickness and film uniformity and the maximum luminous efficiency of devices with inkjet printed poly(spirobifluorene) can reach 80% of the spin-coated devices.
基金Project supported by the Science and Technology Major Projects of Zhejiang Province,China(Grant No.2013C03043-5)
文摘Digital structured light （SL） profilometry is increasingly used in three-dimensional （3D） measurement technology. However, the nonlinearity of the off-the-shelf projectors and cameras seriously reduces the measurement accuracy. In this paper, first, we review the nonlinear effects of the projector-camera system in the phase-shifting structured light depth measurement method. We show that high order harmonic wave components lead to phase error in the phase-shifting method. Then a practical method based on frequency domain filtering is proposed for nonlinear error reduction. By using this method, the nonlinear calibration of the SL system is not required. Moreover, both the nonlinear effects of the projector and the camera can be effectively reduced. The simulations and experiments have verified our nonlinear correction method.
基金Supported by the Shandong Provincial Natural Science Foundation,China(No.ZR2017QC008)the National Natural Science Foundation of China(No.U1706209)。
文摘Light is an important parameter in algal culturing.In this work,the effects of different light qualities on growth of the marine diatom Chaetoceros gracilis are evaluated.The cells were cultured under light quantum flux density of 60μmol photons/(m2·s)with nine light qualities:LED red light(LR),LED blue light(LB),LED red plus LED blue light(LR+LB),LED white light(LW),fluorescent white light(FW),and combinations of LW and FW lights with increased proportions of red or blue light(FW+LR,FW+LB,LW+LR,and LW+LB).Blue light promoted the growth of C.gracilis largely.Three light qualities,FW+LR,LW+LR,and LR,resulted in the lowest growth rate.Both chlorophyll and carotenoids reached the highest level under LB and the lowest level under LR among monochromatic light sources;however,increasing of the proportion of blue or red light in the white light induced an increase of the chlorophyll and carotenoid concentrations.Light absorption ability of microalgae was critical for the growth of these organisms,as we observed a positive correlation between the extinction coefficient at different wavelengths and the specific growth rate.These findings are of importance to improve the culturing of this alga in bioreactors.
文摘We investigate the effects of dynamical Casimir effect in superradiant light scattering by Bose-Einstein condensate in an optomechanical cavity. The system is studied using both classical and quantized mirror motions. The cavity frequency is harmonically modulated in time for both the cases. The main quantity of interest is the number of intracavity scattered photons. The system has been investigated under the weak and strong modulations. It has been observed that the amplitude of the scattered photons is more for the classical mirror motion than the quantized mirror motion. Also, initially, the amplitude of scattered photons is high for lower modulation amplitude than higher modulation amplitude. We also found that the behavior of the plots are similar under strong and weak modulations for the quantized mirror motion.
基金supported by the Russian Science Foundation grant No.22-79-10007.
文摘Hall effect of light is a result of symmetry breaking in spin and/or orbital angular momentum(OAM)possessing optical system and is caused by e.g.refractive index gradient/interface between media or focusing of a spatially asymmetrical beam,similar to the electric field breaking the symmetry in spin Hall effect for electrons.The angular momentum(AM)conservation law in the ensuing asymmetric system dictates redistribution of spin and orbital angular momentum,and is manifested in spin-orbit,orbit-orbit,and orbit-spin conversions and reorganization,i.e.spin-orbit and orbit-orbit interaction.This AM restructuring in turn requires shifts of the barycenter of the electric field of light.In the present study we show,both analytically and by numerical simulation,how different electric field components are displaced upon tight focusing of an asymmetric light beam having OAM and spin.The relation between field components shifts and the AM components shifts/redistribution is presented too.Moreover,we experimentally demonstrate,for the first time,to the best of our knowledge,the spin-orbit Hall effect of light upon tight focusing in free space.This is achieved using azopolymers as a media detecting longitudinal or z component of the electrical field of light.These findings elucidate the Hall effect of light and may broaden the spectrum of its applications.
基金Project supported by the Natural Science Foundation of Heilongjiang Province(E201323)the Science and Technology Research Program of Education Bureau of Heilongjiang Province(12531213)
文摘Effects of La, N, and P doping on the structural, electronic and optical properties of TiO_2 synthesized from TiCl_4 hydrolysis via a microwave-hydrothermal process were investigated by X-ray diffraction, transmission electron microscopy, N_2 adsorption-desorption isotherm, X-ray photoelectron spectroscopy, electron paramagnetic resonance, UV-vis absorbance spectroscopy, photoelectrochemical measurements, and photoluminescence spectroscopy. The results showed that the presence of La in the tri-doped TiO_2 played a predominant role in inhibiting the recombination of the photogenerated electrons and holes. The existence of the substitutional N, interstitial N, and oxygen vacancies in TiO_2 lattices led to the band gap narrowing. It was P-doping rather than La or N doping that played a key role in inhibiting both anatase-to-rutile phase transformation and crystal growth, in stabilizing the mesoporous textural properties, and in increasing the content of surface bridging hydroxyl. Moreover, the tri-doping significantly enhanced the surface Ti^（4＋）-O^（2-）-Ti^（4＋）-O^（-·） species. All above-mentioned factors cooperated to result in the enhanced photoactivity of the tri-doped TiO_2. As a result, it exhibited the highest photoactivity towards the degradation of 4-chlorophenol（4-CP） under visible-light irradiation among all samples, which was much superior to commercial P25 TiO_2.
基金supported by the National Natural Science Foundation of China(Grant Nos.61991452 and 12074444)the Guangdong Major Project of Basic and Applied Basic Research(Grant No.2020B0301030009)+1 种基金the Guangdong Basic and Applied Basic Research Foundation(Grant No.2020A1515011184)the Guangzhou Basic and Applied Basic Research Foundation(Grant No.202102020987).
文摘Scattered light imaging through complex turbid media has significant applications in biomedical and optical research.For the past decade,various approaches have been proposed for rapidly reconstructing fullcolor,depth-extended images by introducing point spread functions(PSFs).However,because most of these methods consider memory effects(MEs),the PSFs have angular shift invariance over certain ranges of angles.This assumption is valid for only thin turbid media and hinders broader applications of these technologies in thick media.Furthermore,the time-variant characteristics of scattering media determine that the PSF acquisition and image reconstruction times must be less than the speckle decorrelation time,which is usually difficult to achieve.We demonstrate that image reconstruction methods can be applied to timevariant thick turbid media.Using the time-variant characteristics,the PSFs in dynamic turbid media within certain time intervals are recorded,and ergodic scattering regimes are achieved and combined as ensemble point spread functions(ePSFs).The ePSF traverses shift-invariant regions in the turbid media and retrieves objects beyond the ME.Furthermore,our theory and experimental results verify that our approach is applicable to thick turbid media with thickness of 1 cm at visible incident wavelengths.
基金the support from the University of MichiganThe National Natural Science Foundation of China (Nos. 61527806)+4 种基金National Key Research and Development Program of China (No. 2017YFA0205301)Natural Science Foundation of jiangsu Province(No. BK20141397)National Key Program for Developing Basic Research(No. 2014CB744501)Research Fund for the Doctoral Program of Higher Education of China(No.20120092120042)CMA-L'Oreal China Skin Grant 2015 (No. S2015121421) are also acknowledged for the financial support
文摘Information concerns endocytosis and autophagic effects of magnetite particles is crucial for understanding the particle-cell interactions. In this work, we investigated the effects of bovine serum proteins on the endocytosis of magnetite spherical particles（MSPs）. Autophagic effects of MSPs in breast cancer cells were studied. Light scattering based flow cytometry and microscopy were used for evaluating the uptake potential of MSPs by cells and the cellular autophagosome accumulation. Results showed bovine serum proteins significantly reduced the endocytosis of MSPs by decreasing their adsorption to cell membranes. Additionally, serum proteins had influences on the endocytic mechanisms of MSPs.Autophagosome accumulation could be caused by the internalized MSPs rather than the particles associated with cell membrane. Above fundamental findings promote our understandings upon the interactions of MSPs with cells. Light scattering based methods were proved to be simple and effective.The present work may promote their application in studies upon endocytosis of metallic particles in the future.
基金Project supported by the National Natural Science Foundation of China (Grants Nos. 61025024 and 11074068)the Hunan Provincial Natural Science Foundation of China (Grant No. 12JJ7005)
文摘We theoretically and experimentally investigate a switchable spin Hall effect（SHE） of light in reflection near the Brewster angle at an air-uniaxial crystal interface.We find a large transverse spin splitting near the Brewster angle,whose sign can be altered by rotating the optical axis.As an analogy of the SHE in an electronic system,a switchable spin accumulation in the SHE of light is detected.We are able to switch the direction of the spin accumulation by adjusting the optical axis angle of the uniaxial crystal.These findings may give opportunities for photon spin manipulating and developing a new generation of nano-photonic devices.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61025024 and 11074068)
文摘We theoretically investigate a switchable spin Hall effect of light （SHEL） in reflection for three specific dispersion relations at an air-anisotropic metamaterial interface. The displacements of horizontal and vertical polarization compo- nents vary with the incident angle at different dispersion relations. The transverse displacements can be obtained with the relevant metamaterial whose refractive index can be arbitrarily tailed. The results of the SHEL in the metamaterial provide a new way for manipulating the transverse displacements of a specific polarization component.
文摘The revolution in information sharing is fundamentally supported by the highly efficient processing,storage,and transmission of data[1].For the latter,energy consumption continuously increases with the rapid development of information and communication technology[2].
基金financially supported by the National Natural Science Foundation of China (Nos.22371230,22022107,22001213,and 22071197)the Postdoctoral Science Foundation of China (Nos.2023M732855,2022TQ0258)the Shaanxi Fundamental Science Research Project for Chemistry & Biology (No.22JHQ020)。
文摘The supramolecular F?rster resonance energy transfer(FRET)is seen as a promising approach for organic photocatalysis using dyes as catalysts,because it combines the high efficiency of energy transfer with the dynamic responsiveness based on non-covalent interactions.Here we propose a supramolecular FRET photocatalysis strategy forα-oxyamination reaction based on supramolecular confinement effect.The well-designed benzothiadiazole-based cationic monomer as energy donor and the dyes of Nile Red as acceptor are doped into the amphiphilic surfactants of sodium dodecyl sulfate(SDS).Benefitting from the supramolecular confinement space provided by SDS in aqueous environment,the FRET process between the monomer and Nile Red is effectively achieved(exciton migration rate:3.99×10^(14)L mol^(-1)s^(-1)).On this basis,the supramolecular FRET system is used as an efficient energy source to catalyzeα-oxyamination reactions between a series of 1,3-dicarbonyl compounds and 2,2,6,6-tetramethylpiperidine-1-oxyl under white LED light,showing a yield as high as 94%and a turnover frequency value of 3.92 h^(-1).This photocatalytic result shows a great enhancement compared to that of Nile Red alone.
基金the National Key Basic Research Program of China(Grant No.2022YFA1404800)the National Natural Science Foundation of China(Grant Nos.12234007 and 12221004)supported by Science and Technology Commission of Shanghai Municipality,China(Grant Nos.19XD1434600,2019SHZDZX01,19DZ2253000,20501110500,and 21DZ1101500)。
文摘Periodic photonic structures can provide rich modulation in propagation of light due to well-defined band structures.Especially near band edges,light localization and the effect of near-zero refractive index have attracted wide attention.However,the practically fabricated structures can only have finite size,i.e.,limited numbers of periods,leading to changes of the light propagation modulation compared with infinite structures.Here,we study the size effect on light localization and near-zero refractive-index propagation near band edges in one-dimensional periodic structures.Near edges of the band gap,as the structure's size shrinks,the broadening of the band gap and the weakening of the light localization are discovered.When the size is small,an added layer on the surface will perform large modulation in the group velocity.Near the degenerate point with Dirac-like dispersion,the zero-refractive-index effects like the zero-phase difference and near-unity transmittance retain as the size changes,while absolute group velocity fluctuates when the size shrinks.
基金Supported by the Open Research Fund of State Key Laboratory of Transient Optics and Photonics of Chinese Academy of Sciences under Grant No SKLST201508the China Postdoctoral Science Foundation Funded Project under Grant No 2015M580945the Government of Chaoyang District Postdoctoral Research Foundation
文摘The angle compensation method is adopted to detect sloshing waves by laser diffraction, in the case that the wavelength of the sloshing waves is much greater than that of the incident light. The clear diffraction pattern is observed to be of asymmetry, involving orders, position and interval of the diffraction spots that are discovered during the light grazing incidence. It is found that the larger the angle of incidence is, the more obvious the asymmetry is. The higher the negative diffraction orders are, the smaller the intervals between spots are. On the contrary~ in the positive region, the higher the diffraction orders are, the larger the spot intervals are. The positive interval is larger than that of the same negative diffraction order. If the incident angle reaches 1.558 rad in the experiment, all positive diffraction orders completely vanish. Based on the mechanism of phase modulation and with the Fourier transform method, the relations between the incident angle and position, interval spaces, and orders of diffraction spots are derived theoretically. The theoretical calculations are compared with the experimental data, and the comparison shows that the theoretical calculations are in good agreement with the experimental measurement.
基金Sponsored by the Opening Funds of State Key Laboratory of Building Safety and Built Environment and National Engineering Research Center of Building Technology(Grant No.BSBE2018-01)the Fundamental Research Funds for the Central Universities(Grant No.2018ZD34)the Autonomous Research Project of State Key Laboratory of Subtropical Building Science(Grant No.2017KB11).
文摘With the increasing attention on circadian effects driven by light,lighting industry has inspired a revolution of photobiological lighting design.Due to diverse evaluation criteria for visual and non⁃visual systems,models that combine these evaluation parameters are indeed urgent.Thus,an integrated model for mesopic lighting evaluation of circadian effects was proposed.The circadian efficiency function adopted in this study was synthesized by CIE 1931 XYZ 2 deg color matching functions and standard scotopic sensitivity function.Then,the integrated model composed of International Commission on Illumination 1931 xy chromaticity coordinates,scotopic/photopic ratio,and illuminance could be obtained with synthesized circadian efficiency function.The model showed that for light sources with fixed chromaticity coordinates and fixed illuminance,enhancing the circadian effects is equivalent to increasing the scotopic/photopic ratio,which suggests a useful method for practitioners to explore the photobiologically reasonable spectrum for mesopic lighting.Light⁃emitting diodes spectra optimized by four⁃component color⁃mixing method were employed to figure out the property of the integrated model.
