Supersonic Tailless Aerial Vehicles(STAVs)will become an essential force in Penetrating Counter Air(PCA),but STAVs do not have the traditional horizontal and vertical tails,making pitch and yaw control difficult.The a...Supersonic Tailless Aerial Vehicles(STAVs)will become an essential force in Penetrating Counter Air(PCA),but STAVs do not have the traditional horizontal and vertical tails,making pitch and yaw control difficult.The attack angle and the sideslip angle need to be limited to ensure that the engine inlet and the aerodynamic rudder at the rear of the vehicle can work properly,which is the so-called security constraints.In addition,the tracking error of the aerodynamic angle needs to be limited to achieve effective attitude control or high-accuracy tracking of trajectories,which is the so-called performance constraints.To this end,an attitude control method that meets the needs of PCA has been devised,based on constraint definition,coupled constraints handling,and control law design.Firstly,mathematical descriptions of the security constraints,performance constraints,and control constraints are given.Secondly,two treatment methods,coupled command filter and coupled funnel control are proposed for the aerodynamic angle coupled constraint problem.Finally,based on Nonlinear Dynamic Inverse(NDI)design,the coupled funnel controller is designed and validated by simulation for two typical mission scenarios,high-altitude penetration and low-altitude surprise defence.The proposed control method not only satisfies the security and performance constraints of STAV attitude control but also is highly robust.展开更多
The characteristics and climatology of funnel clouds in Alaska were examined using operational radiosondes, surface meteorological observations, and reanalysis data. Funnel clouds occurred under weak synoptic forcing ...The characteristics and climatology of funnel clouds in Alaska were examined using operational radiosondes, surface meteorological observations, and reanalysis data. Funnel clouds occurred under weak synoptic forcing between May and September between 11 am and 6 pm Alaska Daylight Time with a maximum occurrence in July. They occurred under Convective Available Potential Energy >500 J·kg-1 and strong low-level wind shear. Characteristic atmospheric profiles during funnel cloud events served to develop a retrieval algorithm based on similarity testing. Out of more than 129,000 soundings between 1971 and 2014, 2724, 442, and 744 profiles were similar to the profiles of observed funnel cloud events in the Interior, Alaska West Coast, and Anchorage regions. While the number of reported funnel clouds has increased since 2000, the frequency of synoptic situations favorable for such events has decreased.展开更多
Due to long-term over-exploitation of groundwater in Beijing Municipality, regional groundwater funnels have formed and land subsidence has been induced. By combining a groundwater monitoring network, GPS monitor- ing...Due to long-term over-exploitation of groundwater in Beijing Municipality, regional groundwater funnels have formed and land subsidence has been induced. By combining a groundwater monitoring network, GPS monitor- ing network data, radar satellite SAR data, GIS and other new technologies, a coupled process model based on the dy- namic variation of groundwater and the deformation response of land subsidence has been established. The dynamic variation of groundwater fimnels and the land subsidence response process were analyzed systematically in Beijing. Study results indicate that current groundwater funnel areas are distributed mainly in the southwest of Shunyi District, the northeast of Chaoyang District and the northwest of Tongzhou District, with an average decline rate of groundwa- ter level of 2.66 rn/yr and a maximum of 3.82 m/yr in the center of the funnels. Seasonal and interannual differences exist in the response model of land subsidence to groundwater funnels with uneven spatial and temporal distribution, where the maximum land subsidence rate was about --41.08 mm/yr and the area with a subsidence rate greater than 30 mm/yr was about 1637.29 km2. Although a consistency was revealed to exist between a groundwater funnel and the spatial distribution characteristics of the corresponding land subsidence funnel, this consistency was not perfect. The results showed that the response model of land subsidence to the dynamic variation of groundwater was more revealing when combining conventional technologies with InSAR, GIS, GPS, providing a new strategy for environmental and hydrogeological research and a scientific basis for regional land subsidence control.展开更多
The recycled cathode ray tube(CRT)funnel glass was used as replacement of magnetite sand in the concrete,and its mass replacement rates were 0,20%,40%and 60%,respectively.The flowability,apparent density and mechanica...The recycled cathode ray tube(CRT)funnel glass was used as replacement of magnetite sand in the concrete,and its mass replacement rates were 0,20%,40%and 60%,respectively.The flowability,apparent density and mechanical properties of the radiation shielding concrete were investigated,while itsγ-ray radiation shielding parameters such as linear and mass attenuation coefficients(μandμm,respectively),thickness values of half-value layer(hHVL)and tenth-value layer(hTVL)were obtained by theoretical calculation,experiment and Monte.Carlo N-Particle(MCNP)simulation code.The experimental results show that the flowability of the concrete increases significantly,whilst its apparent density,compressive strength and static elastic modulus decrease slightly.The calculated,simulated and experimentalμm,μ,hHVL and hTVL values of all concrete samples are very consistent at the sameγ-ray photon energy,and it is feasible to use MCNP code to simulateγ-ray radiation shielding parameters of materials.The calculated results show that in a wide range ofγ-ray photon energy,theμm value of the concrete with CRT funnel glass replacing magnetite sand is improved effectively,and its radiation shielding performances are the same as those of the control concrete(M.1).By comprehensively comparing the flowability,mechanical properties andγ-ray radiation shielding properties,the concrete samples with 20%.40%funnel glass as fine aggregate have good performances.展开更多
An efficient approach for lead extraction from waste funnel glass through the lead smelting process has been proposed. To clarify the effect of funnel glass addition on the degradation of magnesia-chromite refractorie...An efficient approach for lead extraction from waste funnel glass through the lead smelting process has been proposed. To clarify the effect of funnel glass addition on the degradation of magnesia-chromite refractories by ZnO-containing fayalite slag, the corrosion behavior of magnesia-chromite refractories in lead smelting slags with different funnel glass additions from 0wt% to 40wt% was tested. Scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) was used to acquire the microstructural information of the worn refractory samples. Experimental results showed that the corrosion of magnesia-chromite refractory consisted predominantly of the dissolution of MgO into slag. ZnO and FeO reacted with periclase and chromite to form (Zn,Fe,Mg)O solid solution and (Zn,Fe,Mg)(Fe,Al,Cr)2O4 spinel, respectively. With the addition of funnel glass, the solubility of MgO increased whereas ZnO levels remained stable, thereby resulting in a reduced Mg content and an elevated Zn and Fe content in the (Zn,Fe,Mg)O solid solution and the (Zn,Fe,Mg)(Fe,Al,Cr)2O4 spinel. Considering the stability of the (Zn,Fe,Mg)O solid solution layer and the penetration depth of the slag, the optimal funnel glass addition for lead smelting was found to be 20wt%.展开更多
In recent years, thin slab continuous casting technology has been widely used to improve the quality of the product and to reduce the cost. One of the challenges faced by this technology is to design reasonable flow p...In recent years, thin slab continuous casting technology has been widely used to improve the quality of the product and to reduce the cost. One of the challenges faced by this technology is to design reasonable flow patterns, which strongly affect the surface and inner properties of the final slab in the mold. With the fixed scales and complex geometrical structures of nozzle and funnel type mold, a series of numerical simulations are made to analyze the flow patterns in melt steel using finite volume method based on structured body fitted coordinate grids. The CFD （computational fluid dynamics） package is validated first using one typical case described in previously published studies, and then it is developed to study the effect of operational parameters on fluid flow in thin slab caster. Two operational parameters, casting speed and SEN （submerged entry nozzle） depth, are mainly considered for numerical analysis. On the basis of present simulations, the reasonable SEN submergence depths corresponding to different casting speeds are suggested according to fluid flow characteristics like, flow jet impingement on the narrow side of the mold, flow speed of the melt steel beneath the meniscus and the recirculation region. This is the first stage of study on the numerical analysis of the whole thin slab casting process with electromagnetic brake.展开更多
Waste cathode ray tube(CRT)funnel glass(FG)is an important part in the disposal of electrical and electronic waste(e-waste).A novel approach for efficient lead extraction and glass-ceramics synthesized from waste FG t...Waste cathode ray tube(CRT)funnel glass(FG)is an important part in the disposal of electrical and electronic waste(e-waste).A novel approach for efficient lead extraction and glass-ceramics synthesized from waste FG through collaboratively smelting FG with coal fly ash(CFA)is proposed.Glass-ceramics materials with 40 wt%-80 wt%FG additions were produced under sintering temperatures of 900-1000℃.The microstructure and phase composition of the produced glass-ceramics were studied using X-ray diffraction(XRD)and scanning electron microscopy(SEM).The density,water absorption,Vicker hardness,chemical resistance and heavy metal leaching characteristics of the glassceramics were measured.The experimental results indicate that the samples can be crystallized at sintering temperatures of 900-1000℃.An elevated sintering temperature is favorable for enhancing the degree of crystallization,while the crystallization process is inhibited at excessively high temperatures.Increasing FG addition can lead to the transformation of the main crystalline phase from diopside to gehlenite.Well-crystallized crystals were generated in the specimens with 50 wt%-70 wt%FG additions.The samples with 40 wt%,50 wt%,60 wt%,70 wt%,80 wt%FG addition exhibit the optimal chemical and physical properties at 975,925,950,925 and 900℃,respectively.Overall results demonstrate that this study provides a feasible strategy for reliably detoxifying and reusing waste FG and CFA.展开更多
In this paper we develop a variational theory to study the dynamic properties of ultracold Bose gas ina funnel external potential.We obtain one-dimensional nonlinear equation which describes the dynamics of transverse...In this paper we develop a variational theory to study the dynamic properties of ultracold Bose gas ina funnel external potential.We obtain one-dimensional nonlinear equation which describes the dynamics of transversetight confined bosonic gas from three-dimension to one-dimension,and find one-dimensional s-wave scattering lengthwhich depends on the shape of transverse confining potential.If the funnel trapping potential is strong enough at zerotemperature,all transverse excitations are frozen.We find the dynamic equation which describes the Tonks-Girardeaugas and present a qualitative analysis of the experimental accessibility of the Tonks-Girardeau gas with funnel-trappedalkalic atoms.展开更多
Anchoring molecular cocatalysts on semiconductors has been recognized as a general strategy to boost the charge separation efficiency required for efficient photocatalysis.However,the effect of molecular cocatalysts o...Anchoring molecular cocatalysts on semiconductors has been recognized as a general strategy to boost the charge separation efficiency required for efficient photocatalysis.However,the effect of molecular cocatalysts on energy funneling(i.e.,directional energy transfer)inside semiconductor photocatalysts has not been demonstrated yet.Here we prepared CdS nanorods with both thin and thick rods and anchored the conjugated molecules 2‐mercaptobenzimidazole(MBI)and cobalt molecular catalysts(MCoA)sequentially onto the surface of nanorods.Transient absorption measurements revealed that MBI molecules facilitated energy funneling from thin to thick rods by the electronic coupling between thin and thick nanorods,which is essentially a light‐harvesting antenna approach to enhance the charge generation efficiency in the reaction center(here the thick rods).Moreover,MBI and MCoA molecules selectively extracted photogenerated holes and electrons of CdS nanorods rapidly,leading to efficient charge separation.Consequently,CdS/MBI/MCoA displayed 15 times enhanced photocatalytic H_(2) evolution(1.65 mL)than pure CdS(0.11 mL)over 3 h of illumination.The amount of H_(2) evolution reached 60 mL over 48 h of illumination with a high turnover number of 26294 and an apparent quantum efficiency of 71%at 420 nm.This study demonstrates a novel design principle for next‐generation photocatalysts.展开更多
In order to simulate the recovery of groundwater funnels under the condition of reducing groundwater abstraction, hydrogeological conditions of recoverability construction of Shijiazhuang groundwater funnel were analy...In order to simulate the recovery of groundwater funnels under the condition of reducing groundwater abstraction, hydrogeological conditions of recoverability construction of Shijiazhuang groundwater funnel were analyzed, and a numerical simulation method was used based on the change of various parameters. The results show that the groundwater flow model can accurately reflect groundwater hydrogeological characteristics, and can guarantee the reliability of groundwater restoration prediction. The research has set up four schemes for rural water-saving, planting structure adjustment, urban reducing abstraction and integrated method. The effect of four restoration schemes on the restoration of groundwater funnels was compared with water table variations of two observation well. Comparison results show that the level changes of plan Three and Four are different from the other two kinds of exploitation and the drop trend of water table in the funnel area is flat. So we can conclude that Plan Three and Four have significant effect on the groundwater funnel restoration of Shijiazhuang.展开更多
Devices operating with excitons exhibit promising prospects for overcoming the dilemma of response time and integration in electron or/and photon based system.Strain engineering has emerged as an effective approach to...Devices operating with excitons exhibit promising prospects for overcoming the dilemma of response time and integration in electron or/and photon based system.Strain engineering has emerged as an effective approach to modulate exciton transport and dynamics,with bubbles induced biaxial strain attracting particular attention for nanoscopic manipulation of exciton flux.However,the unintentionally produced bubbles are completely stochastic in dimensions and morphology,thereby the active and controllable bubbles formation still remain challenge,which is imperative for modulating excitonic and opt-electric performance on demand.Here,we propose the annealing-driven reassembly of micro-bubbles to create the controllable artificial potential landscapes in atomically thin semiconductor,facilitating the active manipulation of exciton flux at room temperature.Correlating micro PL mappings with strain maps calculated from AFM topography and strain modeling,demonstrates the efficient localized exciton emission and exciton funneling in spectral.The imaging of exciton transport and emission provide more intuitive evidence in spatial that excitons flow towards bubble center from excitation location driven by the conventional diffusion and strain gradient induced drift effect,supported by drift-diffusion model.These findings demonstrate the great potential to control exciton dynamics on-demand through annealing driven reassembled micro-bubbles,and lay the foundation for promising applications in high-performance sensing,energy harvesting,and quantum information processing.展开更多
Owing to their effectiveness in regulating charge separation and migration,heterostructures have been widely employed in gaining advanced photocatalysts.However,once the anisotropic crystal and electronic characterist...Owing to their effectiveness in regulating charge separation and migration,heterostructures have been widely employed in gaining advanced photocatalysts.However,once the anisotropic crystal and electronic characteristics of catalysts are considered,those general nondirectional heterostructures fabricated by casually assembling different components seem to be unable to maximize their effectiveness.Herein we highlight that spatial orientation should be taken into account in designing heterostructurebased photocatalysts.By taking bismuth oxyhalide as a model,we fabricated an in-plane heterostructure with(001)-facet exposure,where BiOCl and BiOCl_(x)Br_(1-x) compose the interior and edge components,respectively.With the combination of spatially resolved analyses and theoretical simulations,we demonstrate that such heterostructure orientation facilitates the accumulation of photoinduced charge carriers in the reactive edge region,attributable to the directional migration of interior charge carrier driven by the in-plane energy-level gradient.Benefiting from these features,this in-plane heterostructure shows excellent photocatalytic performance in triggering C-H fluorination under visible light illumination.展开更多
基金supported by the National Natural Science Foundation of China(No.62103439)the China Postdoctoral Science Foundation(No.2020M683716)+1 种基金the National Key Laboratory of Unmanned Aerial Vehicle Technology,Chinathe Youth Innovation Team of Shaanxi University,China.
文摘Supersonic Tailless Aerial Vehicles(STAVs)will become an essential force in Penetrating Counter Air(PCA),but STAVs do not have the traditional horizontal and vertical tails,making pitch and yaw control difficult.The attack angle and the sideslip angle need to be limited to ensure that the engine inlet and the aerodynamic rudder at the rear of the vehicle can work properly,which is the so-called security constraints.In addition,the tracking error of the aerodynamic angle needs to be limited to achieve effective attitude control or high-accuracy tracking of trajectories,which is the so-called performance constraints.To this end,an attitude control method that meets the needs of PCA has been devised,based on constraint definition,coupled constraints handling,and control law design.Firstly,mathematical descriptions of the security constraints,performance constraints,and control constraints are given.Secondly,two treatment methods,coupled command filter and coupled funnel control are proposed for the aerodynamic angle coupled constraint problem.Finally,based on Nonlinear Dynamic Inverse(NDI)design,the coupled funnel controller is designed and validated by simulation for two typical mission scenarios,high-altitude penetration and low-altitude surprise defence.The proposed control method not only satisfies the security and performance constraints of STAV attitude control but also is highly robust.
基金Supported by National Natural Science Foundation of China(61403343)Scientific Research Foundation of the Education Department of Zhejiang Province,China(Y201329260)Natural Science Foundation of Zhejiang University of Technology(1301103053408)
基金the National Science Foundation(NSF),the SOARS program,the Gwichyaa Zhee Gwich’in Tribal Government,and SLOAN for financial support.
文摘The characteristics and climatology of funnel clouds in Alaska were examined using operational radiosondes, surface meteorological observations, and reanalysis data. Funnel clouds occurred under weak synoptic forcing between May and September between 11 am and 6 pm Alaska Daylight Time with a maximum occurrence in July. They occurred under Convective Available Potential Energy >500 J·kg-1 and strong low-level wind shear. Characteristic atmospheric profiles during funnel cloud events served to develop a retrieval algorithm based on similarity testing. Out of more than 129,000 soundings between 1971 and 2014, 2724, 442, and 744 profiles were similar to the profiles of observed funnel cloud events in the Interior, Alaska West Coast, and Anchorage regions. While the number of reported funnel clouds has increased since 2000, the frequency of synoptic situations favorable for such events has decreased.
基金Under the auspices of Program of International S&T Cooperation(No.2010DFA92400)Non-profit Industry Financial Program of the Ministry of Water Resources(No.200901091)+2 种基金Beijing Municipal Natural Science Foundation(No.8101002)Beijing Municipal Education Commission Plans to Focus Science and Technology Projects(No.KZ201010028030)National Natural Science Foundation of China(No.41130744,41171335)
文摘Due to long-term over-exploitation of groundwater in Beijing Municipality, regional groundwater funnels have formed and land subsidence has been induced. By combining a groundwater monitoring network, GPS monitor- ing network data, radar satellite SAR data, GIS and other new technologies, a coupled process model based on the dy- namic variation of groundwater and the deformation response of land subsidence has been established. The dynamic variation of groundwater fimnels and the land subsidence response process were analyzed systematically in Beijing. Study results indicate that current groundwater funnel areas are distributed mainly in the southwest of Shunyi District, the northeast of Chaoyang District and the northwest of Tongzhou District, with an average decline rate of groundwa- ter level of 2.66 rn/yr and a maximum of 3.82 m/yr in the center of the funnels. Seasonal and interannual differences exist in the response model of land subsidence to groundwater funnels with uneven spatial and temporal distribution, where the maximum land subsidence rate was about --41.08 mm/yr and the area with a subsidence rate greater than 30 mm/yr was about 1637.29 km2. Although a consistency was revealed to exist between a groundwater funnel and the spatial distribution characteristics of the corresponding land subsidence funnel, this consistency was not perfect. The results showed that the response model of land subsidence to the dynamic variation of groundwater was more revealing when combining conventional technologies with InSAR, GIS, GPS, providing a new strategy for environmental and hydrogeological research and a scientific basis for regional land subsidence control.
基金Project(14JJ2083)supported by the Natural Science Foundation of Hunan Province,ChinaProject(2015JC3090)supported by the Science and Technology Department of Hunan Province,China
文摘The recycled cathode ray tube(CRT)funnel glass was used as replacement of magnetite sand in the concrete,and its mass replacement rates were 0,20%,40%and 60%,respectively.The flowability,apparent density and mechanical properties of the radiation shielding concrete were investigated,while itsγ-ray radiation shielding parameters such as linear and mass attenuation coefficients(μandμm,respectively),thickness values of half-value layer(hHVL)and tenth-value layer(hTVL)were obtained by theoretical calculation,experiment and Monte.Carlo N-Particle(MCNP)simulation code.The experimental results show that the flowability of the concrete increases significantly,whilst its apparent density,compressive strength and static elastic modulus decrease slightly.The calculated,simulated and experimentalμm,μ,hHVL and hTVL values of all concrete samples are very consistent at the sameγ-ray photon energy,and it is feasible to use MCNP code to simulateγ-ray radiation shielding parameters of materials.The calculated results show that in a wide range ofγ-ray photon energy,theμm value of the concrete with CRT funnel glass replacing magnetite sand is improved effectively,and its radiation shielding performances are the same as those of the control concrete(M.1).By comprehensively comparing the flowability,mechanical properties andγ-ray radiation shielding properties,the concrete samples with 20%.40%funnel glass as fine aggregate have good performances.
基金financially supported by the National Key R&D Program of China (No. 2018YFC1902004)the National Natural Science Foundation of China (No. U1608254)+1 种基金the Project for Guangdong Collaborative Innovation and Platform Environment Building (No. 2017B090904035)the Special Project for Key Laboratory of Guangdong Science and Technology Department, China (No. 2017B030314046)
文摘An efficient approach for lead extraction from waste funnel glass through the lead smelting process has been proposed. To clarify the effect of funnel glass addition on the degradation of magnesia-chromite refractories by ZnO-containing fayalite slag, the corrosion behavior of magnesia-chromite refractories in lead smelting slags with different funnel glass additions from 0wt% to 40wt% was tested. Scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) was used to acquire the microstructural information of the worn refractory samples. Experimental results showed that the corrosion of magnesia-chromite refractory consisted predominantly of the dissolution of MgO into slag. ZnO and FeO reacted with periclase and chromite to form (Zn,Fe,Mg)O solid solution and (Zn,Fe,Mg)(Fe,Al,Cr)2O4 spinel, respectively. With the addition of funnel glass, the solubility of MgO increased whereas ZnO levels remained stable, thereby resulting in a reduced Mg content and an elevated Zn and Fe content in the (Zn,Fe,Mg)O solid solution and the (Zn,Fe,Mg)(Fe,Al,Cr)2O4 spinel. Considering the stability of the (Zn,Fe,Mg)O solid solution layer and the penetration depth of the slag, the optimal funnel glass addition for lead smelting was found to be 20wt%.
文摘In recent years, thin slab continuous casting technology has been widely used to improve the quality of the product and to reduce the cost. One of the challenges faced by this technology is to design reasonable flow patterns, which strongly affect the surface and inner properties of the final slab in the mold. With the fixed scales and complex geometrical structures of nozzle and funnel type mold, a series of numerical simulations are made to analyze the flow patterns in melt steel using finite volume method based on structured body fitted coordinate grids. The CFD （computational fluid dynamics） package is validated first using one typical case described in previously published studies, and then it is developed to study the effect of operational parameters on fluid flow in thin slab caster. Two operational parameters, casting speed and SEN （submerged entry nozzle） depth, are mainly considered for numerical analysis. On the basis of present simulations, the reasonable SEN submergence depths corresponding to different casting speeds are suggested according to fluid flow characteristics like, flow jet impingement on the narrow side of the mold, flow speed of the melt steel beneath the meniscus and the recirculation region. This is the first stage of study on the numerical analysis of the whole thin slab casting process with electromagnetic brake.
基金Project(2020GDASYL-20200103101)supported by the GDAS’Project of Science and Technology Development,ChinaProject(2020A1515010729)supported by the Natural Science Foundation of Guangdong Province,ChinaProject(2018YFC1902004)supported by the National Key R&D Program of China。
文摘Waste cathode ray tube(CRT)funnel glass(FG)is an important part in the disposal of electrical and electronic waste(e-waste).A novel approach for efficient lead extraction and glass-ceramics synthesized from waste FG through collaboratively smelting FG with coal fly ash(CFA)is proposed.Glass-ceramics materials with 40 wt%-80 wt%FG additions were produced under sintering temperatures of 900-1000℃.The microstructure and phase composition of the produced glass-ceramics were studied using X-ray diffraction(XRD)and scanning electron microscopy(SEM).The density,water absorption,Vicker hardness,chemical resistance and heavy metal leaching characteristics of the glassceramics were measured.The experimental results indicate that the samples can be crystallized at sintering temperatures of 900-1000℃.An elevated sintering temperature is favorable for enhancing the degree of crystallization,while the crystallization process is inhibited at excessively high temperatures.Increasing FG addition can lead to the transformation of the main crystalline phase from diopside to gehlenite.Well-crystallized crystals were generated in the specimens with 50 wt%-70 wt%FG additions.The samples with 40 wt%,50 wt%,60 wt%,70 wt%,80 wt%FG addition exhibit the optimal chemical and physical properties at 975,925,950,925 and 900℃,respectively.Overall results demonstrate that this study provides a feasible strategy for reliably detoxifying and reusing waste FG and CFA.
基金Supported by National Natural Science Foundation of China under Grant No.10647144Natural Science Foundation under Grant GK0513102Doctoral Special Fund of Yangzhou University
文摘In this paper we develop a variational theory to study the dynamic properties of ultracold Bose gas ina funnel external potential.We obtain one-dimensional nonlinear equation which describes the dynamics of transversetight confined bosonic gas from three-dimension to one-dimension,and find one-dimensional s-wave scattering lengthwhich depends on the shape of transverse confining potential.If the funnel trapping potential is strong enough at zerotemperature,all transverse excitations are frozen.We find the dynamic equation which describes the Tonks-Girardeaugas and present a qualitative analysis of the experimental accessibility of the Tonks-Girardeau gas with funnel-trappedalkalic atoms.
文摘Anchoring molecular cocatalysts on semiconductors has been recognized as a general strategy to boost the charge separation efficiency required for efficient photocatalysis.However,the effect of molecular cocatalysts on energy funneling(i.e.,directional energy transfer)inside semiconductor photocatalysts has not been demonstrated yet.Here we prepared CdS nanorods with both thin and thick rods and anchored the conjugated molecules 2‐mercaptobenzimidazole(MBI)and cobalt molecular catalysts(MCoA)sequentially onto the surface of nanorods.Transient absorption measurements revealed that MBI molecules facilitated energy funneling from thin to thick rods by the electronic coupling between thin and thick nanorods,which is essentially a light‐harvesting antenna approach to enhance the charge generation efficiency in the reaction center(here the thick rods).Moreover,MBI and MCoA molecules selectively extracted photogenerated holes and electrons of CdS nanorods rapidly,leading to efficient charge separation.Consequently,CdS/MBI/MCoA displayed 15 times enhanced photocatalytic H_(2) evolution(1.65 mL)than pure CdS(0.11 mL)over 3 h of illumination.The amount of H_(2) evolution reached 60 mL over 48 h of illumination with a high turnover number of 26294 and an apparent quantum efficiency of 71%at 420 nm.This study demonstrates a novel design principle for next‐generation photocatalysts.
基金supported by Public Welfare Project of Ministry of Water Resources(201501008)Natural Science Foundation of Hebei Province(D2015504019)
文摘In order to simulate the recovery of groundwater funnels under the condition of reducing groundwater abstraction, hydrogeological conditions of recoverability construction of Shijiazhuang groundwater funnel were analyzed, and a numerical simulation method was used based on the change of various parameters. The results show that the groundwater flow model can accurately reflect groundwater hydrogeological characteristics, and can guarantee the reliability of groundwater restoration prediction. The research has set up four schemes for rural water-saving, planting structure adjustment, urban reducing abstraction and integrated method. The effect of four restoration schemes on the restoration of groundwater funnels was compared with water table variations of two observation well. Comparison results show that the level changes of plan Three and Four are different from the other two kinds of exploitation and the drop trend of water table in the funnel area is flat. So we can conclude that Plan Three and Four have significant effect on the groundwater funnel restoration of Shijiazhuang.
基金supported by the National Science Foundation of China(Grant Nos.12027807,12104241,62225501)Fundamental Research Funds for the Central Universities(Grant No.075-63253216).
文摘Devices operating with excitons exhibit promising prospects for overcoming the dilemma of response time and integration in electron or/and photon based system.Strain engineering has emerged as an effective approach to modulate exciton transport and dynamics,with bubbles induced biaxial strain attracting particular attention for nanoscopic manipulation of exciton flux.However,the unintentionally produced bubbles are completely stochastic in dimensions and morphology,thereby the active and controllable bubbles formation still remain challenge,which is imperative for modulating excitonic and opt-electric performance on demand.Here,we propose the annealing-driven reassembly of micro-bubbles to create the controllable artificial potential landscapes in atomically thin semiconductor,facilitating the active manipulation of exciton flux at room temperature.Correlating micro PL mappings with strain maps calculated from AFM topography and strain modeling,demonstrates the efficient localized exciton emission and exciton funneling in spectral.The imaging of exciton transport and emission provide more intuitive evidence in spatial that excitons flow towards bubble center from excitation location driven by the conventional diffusion and strain gradient induced drift effect,supported by drift-diffusion model.These findings demonstrate the great potential to control exciton dynamics on-demand through annealing driven reassembled micro-bubbles,and lay the foundation for promising applications in high-performance sensing,energy harvesting,and quantum information processing.
基金supported by the National Key R&D Program of China(grant nos.2022YFA1502903 and 2021YFA1501502)the Strategic Priority Research Program of Chinese Academy of Sciences(grant no.XDB0450102)+3 种基金the National Natural Science Foundation of China(grant nos.92163105,22275179,and T2122004)the Youth Innovation Promotion Association of CAS(grant no.Y2021123)the Fundamental Research Funds for the Central Universities(grant no.WK2060000039)the Anhui Provincial Natural Science Foundation(grant no.2108085J07).
文摘Owing to their effectiveness in regulating charge separation and migration,heterostructures have been widely employed in gaining advanced photocatalysts.However,once the anisotropic crystal and electronic characteristics of catalysts are considered,those general nondirectional heterostructures fabricated by casually assembling different components seem to be unable to maximize their effectiveness.Herein we highlight that spatial orientation should be taken into account in designing heterostructurebased photocatalysts.By taking bismuth oxyhalide as a model,we fabricated an in-plane heterostructure with(001)-facet exposure,where BiOCl and BiOCl_(x)Br_(1-x) compose the interior and edge components,respectively.With the combination of spatially resolved analyses and theoretical simulations,we demonstrate that such heterostructure orientation facilitates the accumulation of photoinduced charge carriers in the reactive edge region,attributable to the directional migration of interior charge carrier driven by the in-plane energy-level gradient.Benefiting from these features,this in-plane heterostructure shows excellent photocatalytic performance in triggering C-H fluorination under visible light illumination.
