Adsorption desulfurization performance of Na Y,HY and Ce HY zeolites is evaluated in a miniature fixedbed flow by model gasoline containing with thiophene,tetrahydrothiophene,2-methylthiophene,benzothiophene or mixed ...Adsorption desulfurization performance of Na Y,HY and Ce HY zeolites is evaluated in a miniature fixedbed flow by model gasoline containing with thiophene,tetrahydrothiophene,2-methylthiophene,benzothiophene or mixed sulfur compounds.The structural properties of adsorbents are characterized by XRD,N2-adsorption and XPS techniques.Adsorption desulfurization mechanisms of these sulfur compounds over the specific active sites of adsorbents as a major focus of this work,have been systematically investigated by using in situ FT-IR spectroscopy with single and double probing molecules.Desulfurization experimental results show that the Ce HY adsorbent exhibits superior adsorption sulfur capacity at breakthrough point of zero sulfur for ultra-deep removal of each thiophenic sulfur compound,especially in the capture of aromatic 2-methylthiophene(about ca.28.6 mgS/gadsorbent).The results of in situ FT-IR with single probing molecule demonstrate an important finding that high oligomerization ability of thiophene or 2-methylthiophene on the CeHY can promote the breakthrough adsorption sulfur capacity,mainly resulting from the synergy between Br?nsted acid sites and Ce(III)hydroxylated species active sites located in the supercages of Ce HY.Meanwhile,the result of in situ FT-IR with double probing molecules further reveals the essence of oligomerization reactions of thiophene and 2-methylthiophene molecules on those specific active sites.By contrast,the oligomerization reaction of benzothiophene molecules on the active sites of Ce HY cannot occur due to the restriction of cavity size of supercages,but they can be adsorbed on the Br?nsted acid sites via protonation,and on Ce(III)hydroxylated species and extra-framework aluminum hydroxyls species via direct"S-M"bonding interaction.As to the tetrahydrothiophene,adsorption mechanism is similar to that of benzothiophene,except in the absence of protonation.The paper can provide a new design idea of specific adsorption active sites in excellent desulfurization adsorbents for elevating higher quality of FCC gasoline in the future.展开更多
Abstract Biosorption of Zn2＋ from aqueous solutions by biomass of Agaricus bisporus was investigated. The removal rates of Zn2＋ by A. parameters （e.g., solution pH, initial Zn2＋ concentration） were A. bisporus＇s...Abstract Biosorption of Zn2＋ from aqueous solutions by biomass of Agaricus bisporus was investigated. The removal rates of Zn2＋ by A. parameters （e.g., solution pH, initial Zn2＋ concentration） were A. bisporus＇s biosorption by bisporus under different bio-sorbent dosage and studied. The inhibition of anionic ligands EDTA （Ethylene Diamine Tetraacetic Acid）, acetate and citrate） implied that EDTA and citrate might be used as eluting reagents. Regular and simultaneous solution pH change and light metal ions release after biosorption indicated that an ion exchange mechanism was involved. From FT-IR （Fourier Transform Infrared） spectroscopy, the main functional groups participated in biosorption were found. Biosorption of Znz＋ byd. bisporus could be well described by the Freundlich and Langmuir models. In conclusion, the biomass of A. bisporus showed high potential for the treatment of wastewater containing Zn2＋.展开更多
基金financially supported by the National Natural Science Foundation of China (Nos. U1662135 and 21376114, 21076100)by the China National Petroleum Corporation (Grant No. 1001A-01-01-01)
文摘Adsorption desulfurization performance of Na Y,HY and Ce HY zeolites is evaluated in a miniature fixedbed flow by model gasoline containing with thiophene,tetrahydrothiophene,2-methylthiophene,benzothiophene or mixed sulfur compounds.The structural properties of adsorbents are characterized by XRD,N2-adsorption and XPS techniques.Adsorption desulfurization mechanisms of these sulfur compounds over the specific active sites of adsorbents as a major focus of this work,have been systematically investigated by using in situ FT-IR spectroscopy with single and double probing molecules.Desulfurization experimental results show that the Ce HY adsorbent exhibits superior adsorption sulfur capacity at breakthrough point of zero sulfur for ultra-deep removal of each thiophenic sulfur compound,especially in the capture of aromatic 2-methylthiophene(about ca.28.6 mgS/gadsorbent).The results of in situ FT-IR with single probing molecule demonstrate an important finding that high oligomerization ability of thiophene or 2-methylthiophene on the CeHY can promote the breakthrough adsorption sulfur capacity,mainly resulting from the synergy between Br?nsted acid sites and Ce(III)hydroxylated species active sites located in the supercages of Ce HY.Meanwhile,the result of in situ FT-IR with double probing molecules further reveals the essence of oligomerization reactions of thiophene and 2-methylthiophene molecules on those specific active sites.By contrast,the oligomerization reaction of benzothiophene molecules on the active sites of Ce HY cannot occur due to the restriction of cavity size of supercages,but they can be adsorbed on the Br?nsted acid sites via protonation,and on Ce(III)hydroxylated species and extra-framework aluminum hydroxyls species via direct"S-M"bonding interaction.As to the tetrahydrothiophene,adsorption mechanism is similar to that of benzothiophene,except in the absence of protonation.The paper can provide a new design idea of specific adsorption active sites in excellent desulfurization adsorbents for elevating higher quality of FCC gasoline in the future.
文摘Abstract Biosorption of Zn2＋ from aqueous solutions by biomass of Agaricus bisporus was investigated. The removal rates of Zn2＋ by A. parameters （e.g., solution pH, initial Zn2＋ concentration） were A. bisporus＇s biosorption by bisporus under different bio-sorbent dosage and studied. The inhibition of anionic ligands EDTA （Ethylene Diamine Tetraacetic Acid）, acetate and citrate） implied that EDTA and citrate might be used as eluting reagents. Regular and simultaneous solution pH change and light metal ions release after biosorption indicated that an ion exchange mechanism was involved. From FT-IR （Fourier Transform Infrared） spectroscopy, the main functional groups participated in biosorption were found. Biosorption of Znz＋ byd. bisporus could be well described by the Freundlich and Langmuir models. In conclusion, the biomass of A. bisporus showed high potential for the treatment of wastewater containing Zn2＋.
