基于美国NCEP(National Centers for Environmental Prediction)的CFSR(Climate Forecast System Reanalysis)近20a(1991-2010)10m风场再分析数据(0.3°×0.3°,1h/次,简称CFSR风场),对我国近海风能资源分布特征进行了统计...基于美国NCEP(National Centers for Environmental Prediction)的CFSR(Climate Forecast System Reanalysis)近20a(1991-2010)10m风场再分析数据(0.3°×0.3°,1h/次,简称CFSR风场),对我国近海风能资源分布特征进行了统计分析与评估。利用天津渤海A平台观测站(118°25′E,38°27′N)逐时观测风速数据对CFSR风速数据进行了检验,发现均方根误差和平均偏差仅为均较小(分别为2.28m/s与0.16m/s)。基于此CFSR风场,本文章进一步统计并给出了我国陆地年平均风功率密度分布,结果与第三次风能普查(1971-2000年)及相关文献结果 (1991-2010年)相当一致。依据国家风电场风能资源评估方法,由CFSR风场推算了我国近海20a平均的70m高度风能资源分布。结果显示,年平均风功率密度均达到了200 W/m2以上,大于6m/s的风速累积小时数为4 000h以上;其中台湾海峡和东海南部海区风能最为丰富,黄海中部、渤海中部和辽东湾海区风能次之。参照海上风场选址要求,28°N以北的近岸海域由于水深较浅,30m/s以上风速发生频次极低,比较适合建立海上风电场。展开更多
Resonance enhancement has been increasingly employed in the emergent felntosecond stimu- lated Raman spectroscopy （FSRS） to selectively monitor molecular structure and dynamics with improved spectral and temporal re...Resonance enhancement has been increasingly employed in the emergent felntosecond stimu- lated Raman spectroscopy （FSRS） to selectively monitor molecular structure and dynamics with improved spectral and temporal resolutions and signal-to-noise ratios. Such joint eflforts by the technique- and application-oriented scientists and engineers have laid the foundation for exploiting the tunable FSRS methodology to investigate a great variety of photosensitive systems and elucidate the underlying functional mechanisms on molecular time scales. Dur- ing spectral analysis, peak line shapes remain a major concern with an intricate dependence on resonance conditions. Here, we present a comprehensive study of line shapes by tuning the Rarnan pump wavelength from red to blue side of the ground-state absorption band of the fluorescent dye rhodarnine 6G in solution. Distinct line shape patterns in Stokes and anti-Stokes FSRS as well as from the low to high-frequency modes highlight the competition between multiple third-order and higher-order nonlinear pathways, governed by difl^rent res- onance conditions achieved by Raman pump and probe pulses. In particular, the resonance condition of probe wavelength is revealed to play an important role in generating circular line shape changes through oppositely phased dispersion via hot luminescence （HL） pathways. Meanwhile, on-resonance conditions of the Rarnan pump could promote excited-state vibrational modes which are broadened and red-shifted from the coincident ground-state vibrational modes, posing challenges for spectral analysis. Certain strategies in tuning the Raman pump and probe to characteristic regions across an electronic transition band are discussed to improve the FSRS usability and versatility as a powerful structural dynamics toolset to advance chemical, physical, materials, and biological sciences.展开更多
基金supported by the U.S.National Science Foundation CAREER grant(CHE-1455353)the Oregon State University(OSU) Research Equipment Reserve Fund(Spring 2014)to C.Fang(USTC9603)the Wei Family Private Foundation in supporting C.Chen(USTC 0903) during his graduate studies at OSU Chemistry
文摘Resonance enhancement has been increasingly employed in the emergent felntosecond stimu- lated Raman spectroscopy （FSRS） to selectively monitor molecular structure and dynamics with improved spectral and temporal resolutions and signal-to-noise ratios. Such joint eflforts by the technique- and application-oriented scientists and engineers have laid the foundation for exploiting the tunable FSRS methodology to investigate a great variety of photosensitive systems and elucidate the underlying functional mechanisms on molecular time scales. Dur- ing spectral analysis, peak line shapes remain a major concern with an intricate dependence on resonance conditions. Here, we present a comprehensive study of line shapes by tuning the Rarnan pump wavelength from red to blue side of the ground-state absorption band of the fluorescent dye rhodarnine 6G in solution. Distinct line shape patterns in Stokes and anti-Stokes FSRS as well as from the low to high-frequency modes highlight the competition between multiple third-order and higher-order nonlinear pathways, governed by difl^rent res- onance conditions achieved by Raman pump and probe pulses. In particular, the resonance condition of probe wavelength is revealed to play an important role in generating circular line shape changes through oppositely phased dispersion via hot luminescence （HL） pathways. Meanwhile, on-resonance conditions of the Rarnan pump could promote excited-state vibrational modes which are broadened and red-shifted from the coincident ground-state vibrational modes, posing challenges for spectral analysis. Certain strategies in tuning the Raman pump and probe to characteristic regions across an electronic transition band are discussed to improve the FSRS usability and versatility as a powerful structural dynamics toolset to advance chemical, physical, materials, and biological sciences.
