Formate bioconversion plays a crucial role in achieving renewable resource utilization and green and sustainable development,as it helps convert formate to biofuels and biochemicals.However,to tap the full potential o...Formate bioconversion plays a crucial role in achieving renewable resource utilization and green and sustainable development,as it helps convert formate to biofuels and biochemicals.However,to tap the full potential of formate bioconversion,it is important to identify the most appropriate microbial hosts,design the most promising formate assimilation pathways,and develop the most efficient formate assimilation cell factories.Here,we summarize the formatotrophic microorganisms capable of assimilating formate into building blocks of cell growth and analyze the characteristics of formate assimilation pathways for transmitting formate into central carbon metabolism.Furthermore,we discuss microbial engineering strategies to improve the efficiency of formate utilization for producing high-value bioproducts.Finally,we highlight the key challenges of formate bioconversion and their possible solutions to advance the formate bioeconomy and biomanufacturing.展开更多
The accumulation and circulation of carbon and hydrogen contribute to the chemical evolution of ice giant planets.Species separation and diamond precipitation have been reported in carbon-hydrogen systems and have bee...The accumulation and circulation of carbon and hydrogen contribute to the chemical evolution of ice giant planets.Species separation and diamond precipitation have been reported in carbon-hydrogen systems and have been verified by static and shock compression experiments.Nevertheless,the dynamic formation processes underlying these phenomena remain insufficiently understood.In combination with a deep learning model,we demonstrate that diamonds form through a three-step process involving dissociation,species separation,and nucleation processes.Under shock conditions of 125 GPa and 4590 K,hydrocarbons decompose to give hydrogen and low-molecular-weight alkanes(CH_(4) and C_(2)H_(6)),which escape from the carbon chains,resulting in C/H species separation.The remaining carbon atoms without C-H bonds accumulate and nucleate to form diamond crystals.The process of diamond growth is associated with a critical nucleus size at which the dynamic energy barrier plays a key role.These dynamic processes of diamond formation provide insight into the establishment of a model for the evolution of ice giant planets.展开更多
1.Objective The Songliao Basin(SB)is situated on the eastern margin of Eurasia continent(Northeast Asia).During the Late Jurassic to Early Cretaceous,hundreds of rifting basins developed in this area,and the SB is a u...1.Objective The Songliao Basin(SB)is situated on the eastern margin of Eurasia continent(Northeast Asia).During the Late Jurassic to Early Cretaceous,hundreds of rifting basins developed in this area,and the SB is a unique case among them as it evolved into the largest rift basin.The rift basin filling of SB includes Huoshiling Formation,Shahezi Formation,and Yingcheng Formation in ascending order.The mega-rifting was controlled by the Mongol-Okhotsk Collisional Belt to the north and northwest and the Pacific Subduction Zone to the east(Wang PJ et al.,2016).As the first rifting succession,the Huoshiling Formation contains key information about the formation of the rifting basins and records the evolution of the Mongol-Okhotsk Collisional Belt and the Pacific Subduction Zone.However,the geological period of the Huoshiling Formation has not been well constrained for two main reasons.First,it is easily confused with the Yingcheng Formation,as both are dominated by volcanogenic-sedimentary successions.Second,there is lack of reliable dating samples from the uppermost part of the Huoshiling Formation due to its considerable burial depth.展开更多
Quantonenpollenites,a pollen taxon which was assumed to be angiosperm,is of great significance in confirming the geological age of its bearing strata.Aims to clarify the taxonomic affiliation of Quantonenpollenites,we...Quantonenpollenites,a pollen taxon which was assumed to be angiosperm,is of great significance in confirming the geological age of its bearing strata.Aims to clarify the taxonomic affiliation of Quantonenpollenites,we investigated the external morphology and internal structure using Light Microscopy(LM),Scanning Electron Microscopy(SEM),and Transmission Electron Microscopy(TEM).According to TEM observations,the exine of Quantonenpollenites pollen is unstratified with the absence of a columellar layer,and the exine is tightly connected with the intine.Based on comprehensive morphological evidence,especially the lack of columellar layer which is typical characteristics existing in almost all angiosperm pollen,the botanical affinity of Quantonenpollenites should be attributed to gymnosperms rather than angiosperms as previously thought.Through comparative analysis,it may have a close affinity with Ephedra,but further analytical data are still needed for verification.As a characteristic palynological type of the Quantou Formation in the Songliao Basin,the occurrence of Quantonenpollenites has indicative significance for determining the age of the hosting strata.By systematically clarifying the phylogenetic affiliation of Quantonenpollenites,together with the other associated palynomorphs,this study provides crucial reference materials for defining the stratigraphic age range of the Quantou Formation(Cenomanian to early Turonian),improves the resolution of stratigraphic age calibration of the Quantou Formation,and provides key paleontological evidence for the refined division of the terrestrial Cretaceous chronostratigraphic framework in the Songliao Basin.展开更多
Electrocatalytic glucose oxidation to high-value chemicals provides a sustainable route for biomass valorization.NiCo-based catalysts have emerged as promising candidates for glucose oxidation reaction owing to the in...Electrocatalytic glucose oxidation to high-value chemicals provides a sustainable route for biomass valorization.NiCo-based catalysts have emerged as promising candidates for glucose oxidation reaction owing to the intrinsic activity of Ni and Co catalytic centers.However,the dynamic evolution and atomic-scale synergy between these centers remain elusive.Herein,we fabricated NiCo_(2)O_(4)nanosheets supported on nickel foam,where Ni preferentially occupies tetrahedral sites to regulate the electronic configuration of octahedral Co.Experimental and theoretical results demonstrate that the incorporation of tetrahedral Ni induces low-to-intermediate spin transition in octahedral Co,thereby optimizing eg orbital occupancy and stabilizing active sites.This spin-state engineering establishes Ni-Co synergistic catalytic centers for the selective oxidation of glucose to formate(FA).At higher potential(≥1.4 V vs.RHE),octahedral Co undergoes reconstruction into excessive active CoOOH and CoO_(2)species,resulting in glucose overoxidation to CO_(2)and intensified competitive oxygen evolution.In contrast,at lower potentials(<1.4 V vs.RHE),tetrahedral Ni facilitates electron delocalization across the Ni–O–Co lattice,thereby stabilizing octahedral Co for glucose adsorption and oxidation.Subsequently,a coupled electrocatalytic system was constructed,achieving 80.7%FA yield with 91.3%Faradaic efficiency(FE)at NiCo_(2)O_(4)anode and H2 evolution rate of 696μmol h^(−1)with 99.9%FE at Pt cathode for 2 h under 1.35 V vs.RHE.This work provides a deep insight into spin-state regulation of the catalytic center,offering valuable guidance for rational catalyst design.展开更多
This study investigates the facies development and sedimentology of the Late Permian Chhidru Formation,a mixed carbonate-siliciclastic unit exposed in the Western Salt Range,Potwar Basin,Pakistan.The formation is subd...This study investigates the facies development and sedimentology of the Late Permian Chhidru Formation,a mixed carbonate-siliciclastic unit exposed in the Western Salt Range,Potwar Basin,Pakistan.The formation is subdivided into four lithological units reflecting lateral variability,with thicknesses and lithologies ranging from fossiliferous sandy limestone to interbedded limestone and sandstone.These successions record a depositional shift from a carbonate platform to mixed carbonate-clastic,and ultimately,clastic-dominated environments.Lithostratigraphy suggests deposition on the underlying Wargal Limestone carbonates during a Late Permian sea-level fall on the northwest Indian margin of Gondwana.Similar Permian successions with identical lithological characteristics are documented in the Persian Gulf(Dalan Formation),Arabian Platform(Khuff Formation),and Iran(Nesen and Hambust formations).Petrographic analysis reveals deposition in the distal middle to proximal inner shelf settings of a carbonate-siliciclastic mixed,unrimmed platform.Based on identified foraminiferal assemblages,the Chhidru Formation's age is estimated to range from the late Wuchiapingian to Changhsingian stages of the Lopingian epoch.展开更多
Cholelithiasis has a complex pathogenesis,necessitating better therapeutic and preventive strategies.We recently read with interest Wang et al’s study on lysine acetyltransferase 2A(KAT2A)-mediated adenosine monophos...Cholelithiasis has a complex pathogenesis,necessitating better therapeutic and preventive strategies.We recently read with interest Wang et al’s study on lysine acetyltransferase 2A(KAT2A)-mediated adenosine monophosphate-activated protein kinase(AMPK)succinylation in cholelithiasis.Using mouse models and gallbladder mucosal epithelial cells,they found that KAT2A inhibits gallstones through AMPK K170 succinylation,thereby activating the AMPK/silent information regulator 1 pathway to reduce inflammation and pyroptosis.This study is the first to connect lysine succinylation with cholelithiasis,offering new insights and identifying succinylation as a potential therapeutic target.Future research should confirm these findings using patient samples,investigate other posttranslational modifications,and use structural biology to clarify succinylationinduced conformational changes,thereby bridging basic research to clinical applications.展开更多
Conventional error cancellation approaches separate molecules into smaller fragments and sum the errors of all fragments to counteract the overall computational error of the parent molecules.However,these approaches m...Conventional error cancellation approaches separate molecules into smaller fragments and sum the errors of all fragments to counteract the overall computational error of the parent molecules.However,these approaches may be ineffective for systems with strong localized chemical effects,as fragmenting specific substructures into simpler chemical bonds can introduce additional errors instead of mitigating them.To address this issue,we propose the Substructure-Preserved Connection-Based Hierarchy(SCBH),a method that automatically identifies and freezes substructures with significant local chemical effects prior to molecular fragmentation.The SCBH is validated by the gas-phase enthalpy of formation calculation of CHNO molecules.Therein,based on the atomization scheme,the reference and test values are derived at the levels of Gaussian-4(G4)and M062X/6-31+G(2df,p),respectively.Compared to commonly used approaches,SCBH reduces the average computational error by half and requires only15%of the computational cost of G4 to achieve comparable accuracy.Since different types of local effect structures have differentiated influences on gas-phase enthalpy of formation,substituents with strong electronic effects should be retained preferentially.SCBH can be readily extended to diverse classes of organic compounds.Its workflow and source code allow flexible customization of molecular moieties,including azide,carboxyl,trinitromethyl,phenyl,and others.This strategy facilitates accurate,rapid,and automated computations and corrections,making it well-suited for high-throughput molecular screening and dataset construction for gas-phase enthalpy of formation.展开更多
The Ordos Basin is a large superimposed hydrocarbon-bearing basin in China,and further research on the sedimentary characteristics and sedimentary evolution of the sequence framework of target layers is of great theor...The Ordos Basin is a large superimposed hydrocarbon-bearing basin in China,and further research on the sedimentary characteristics and sedimentary evolution of the sequence framework of target layers is of great theoretical and practical significance for guiding oil and gas exploration.The sedimentary facies and sedimentary evolution of the high-resolution sequence framework of the Carboniferous Taiyuan Formation in the Hangjinqi area have been systematically analyzed for the first time by drilling,logging and seismic data.The results show that four types of sequence interfaces can be identified in the Taiyuan Formation:regional unconformity surfaces,scour surfaces,lithologic-lithofacies transformation surfaces and flooding surfaces.According to the sedimentary response caused by the upward and downward movements of the base level at different levels,the Taiyuan Formation can be divided into 2 long-term cycles(LSC_(1)-LSC_(2)),4 mid-term cycles(MSC_(1)-MSC4)and 7 short-term cycles(SSC_(1)-SSC7).The long-and mid-term cycles correspond to members T_(1)and T_(2)and layers T_(1)-1,T_(1-2),T_(2-1),and T_(2)-2,respectively.Long-term cycles are dominated by C_(1);mid-term cycles are dominated by C_(1)and C_(2),followed by A2;and short-term cycles are dominated by C_(1),C_(2),A1 and A2.Under the high-resolution sequence stratigraphic framework,the Hangjinqi area underwent a transformation of fan delta and tidal flat depositional systems during the Taiyuan Formation sedimentary period.In the MSC_(1)-MSC_(2)stage,owing to a large-scale paleocontinent,the fan delta sedimentary body,which was limited in scale and scope,developed only in the southeastern corner and gradually transitioned basinward to tidal flat facies.In the MSC3-MSC4 stage,as the paleocontinent continuously decreased and the sedimentary range expanded,fan-delta plain sedimentation began in the study area.Several braided distributary channels with poor connectivity developed on the fan-delta plain,and between them were floodplains and peat swamps.展开更多
Pre-chamber ignition technology can address the issue of uneven in-cylinder mixture combustion in large-bore marine engines.The impact of various pre-chamber structures on the formation of the mixture and jet flames w...Pre-chamber ignition technology can address the issue of uneven in-cylinder mixture combustion in large-bore marine engines.The impact of various pre-chamber structures on the formation of the mixture and jet flames within the pre-chamber is explored.This study performed numerical simulations on a large-bore marine ammonia/hydrogen pre-chamber engine prototype,considering pre-chamber volume,throat diameter,the distance between the hydrogen injector and the spark plug,and the hydrogen injector angle.Compared with the original engine,when the pre-chamber volume is 73.4 ml,the throat diameter is 14 mm,the distance ratio is 0.92,and the hydrogen injector angle is 80°.Moreover,the peak pressure in the pre-chamber increased by 23.1%,and that in the main chamber increased by 46.3%.The results indicate that the performance of the original engine is greatly enhanced by altering its fuel and pre-chamber structure.展开更多
Osmanthus fragrans is most famous for its strong aroma,and different varieties have different degrees of fragrance and color.Fragrance and color are important factors affecting the ornamental quality of O.fragrans.Ter...Osmanthus fragrans is most famous for its strong aroma,and different varieties have different degrees of fragrance and color.Fragrance and color are important factors affecting the ornamental quality of O.fragrans.Terpenoids are important secondary metabolites in plants,with β-carotene(C40)being the major pigment substance and linalool(C10)being the key aromatic component in O.fragrans.The geranylgeranyl pyrophosphate synthase genes(GGPPSs)play important roles in secondary metabolism in plants.However,the functions of the GGPPS family in floral color and fragrance formation has rarely been reported in O.fragrans.In this study,24 Of GGPPS genes were identified and classified into two subfamilies.The Of GGPPSs showed tissue-specific expression and Of GGPPS13 had highest expression in flowers.The Of GGPPS13 protein was localized to chloroplasts.The transcriptome data of Of GGPPS13 was verified by q RT-PCR and the expression level in‘Wanyingui'with strong aroma was higher than that in‘Zhuangyuanhong'with deep color at different flower development stages.Transient overexpression of Of GGPPS13 in O.fragrans petals showed that Of GGPPS13 increased the β-carotene content,the main color substance of O.fragrans,but decreased the linalool content,the main volatile organic compound(VOC)in the floral aroma of O.fragrans.Of GGPPS13 was indicated as the critical gene related to terpenoid synthesis in the floral aroma and color formation in O.fragrans.Our findings provide gene resources on the GGPPS gene family for further revealing the molecular regulation mechanism of the floral color and aroma formation in O.fragrans.展开更多
The Neogene Shawan Formation in the Chepaizi Uplift of the Junggar Basin(NW China)has obtained high oil flow,demonstrating a good potential for oil and gas exploration.The multi-source hydrocarbon generation backgroun...The Neogene Shawan Formation in the Chepaizi Uplift of the Junggar Basin(NW China)has obtained high oil flow,demonstrating a good potential for oil and gas exploration.The multi-source hydrocarbon generation background and strong tectonic activity have led to the simultaneous production of heavy oil and light oil from multi-layer in the area,which makes it very difficult to identify oil origins,presently,the hot debate on the oil origins needs to be clarified.In this paper,due to the selective consumption of different types of compounds in crude oils by severe and intense biodegradation,the commonly used oilsource correlation tools are ineffective or may produce misleading results,this study adopted a biomarker recovery method based on the principle of mass conservation that uses the sum of the mass of the residual biomarkers and their corresponding biodegradation products to obtain the mass of the original biomarkers,improving the reliability of oil origins determination.Based on the nature and occurrence of crude oils,the investigated oils are subdivided into three types,Group A,Group B and Group C.Group A,light oils occurred mainly in lower structure Neogene Shawan Formation in the western Chepaizi Uplift,while Group B,heavy oils occurred mainly in higher structure Neogene Shawan Formation in the western Chepaizi Uplift.The two types of crude oils may come from the mixed source of Jurassic Badaowan Formation source rocks(J_(1)b)and Paleogene Anjihaihe Formation source rocks(E_(2-3)a)in the Sikeshu Sag,and Jurassic Badaowan Formation source rocks(J_(1)b)are the main source of crude oils.Group C,heavy oils occurred mainly in Neogene Shawan Formation in the eastern Chepaizi Uplift,showing good correlation with the Permian(P_(1)f and P_(2)w)source rocks in the Shawan Sag.At the same time,by combining stable carbon isotope and parameters related to triaromatic steroids,the accuracy of the oilsource correlation results by biomarker recovery method was further verified.展开更多
Formation control in multi-agent systems has become a critical area of interest due to its wide-ranging applications in robotics,autonomous transportation,and surveillance.While various studies have explored distribut...Formation control in multi-agent systems has become a critical area of interest due to its wide-ranging applications in robotics,autonomous transportation,and surveillance.While various studies have explored distributed cooperative control,this review focuses on the theoretical foundations and recent developments in formation control strategies.The paper categorizes and analyzes key formation types,including formation maintenance,group or cluster formation,bipartite formations,event-triggered formations,finite-time convergence,and constrained formations.A significant portion of the review addresses formation control under constrained dynamics,presenting both modelbased and model-free approaches that consider practical limitations such as actuator bounds,communication delays,and nonholonomic constraints.Additionally,the paper discusses emerging trends,including the integration of eventdriven mechanisms and AI-enhanced coordination strategies.Comparative evaluations highlight the trade-offs among various methodologies regarding scalability,robustness,and real-world feasibility.Practical implementations are reviewed across diverse platforms,and the review identifies the current achievements and unresolved challenges in the field.The paper concludes by outlining promising research directions,such as adaptive control for dynamic environments,energy-efficient coordination,and using learning-based control under uncertainty.This review synthesizes the current state of the art and provides a road map for future investigation,making it a valuable reference for researchers and practitioners aiming to advance formation control in multi-agent systems.展开更多
Dear Editor,This letter addresses the formation control problem for constrained underactuated autonomous underwater vehicles (AUVs). The feasibility condition of the virtual control law is eliminated by introducing a ...Dear Editor,This letter addresses the formation control problem for constrained underactuated autonomous underwater vehicles (AUVs). The feasibility condition of the virtual control law is eliminated by introducing a nonlinear state dependence function (NSDF) that transforms the state of each AUV in the formation.展开更多
This study aims to determine the variation and controlling factors of shale gas adsorption capacity in reservoirs in the Upper Ordovician Wufeng Formation and the Lower Silurian Longmaxi Formation(also referred to as ...This study aims to determine the variation and controlling factors of shale gas adsorption capacity in reservoirs in the Upper Ordovician Wufeng Formation and the Lower Silurian Longmaxi Formation(also referred to as the WF-LMX formations),South China.Based on data obtained using scanning helium ion microscopy(HIM)and nitrogen(N_(2))and methane(CH_(4))adsorption experiments,this study analyzed the organic pore heterogeneity of shales in the WF-LMX formations in well A and its effect on shale gas adsorption.Using the Frenkel-Halsey-Hill(FHH)model,data from N_(2) adsorption experiments were converted into fractal dimensions,which can reflect the complexity and heterogeneity of organic pores while also serving as a novel indicator for quantitatively assessing the pore structure complexity.The results indicate that shales in the WF-LMX formations in well A can be divided into two sections:(Ⅰ)the Wufeng Formation and the lower Longmaxi Formation(depths:ca.2871.0-2898.6 m),and(Ⅱ)the upper Longmaxi Formation(depths:<2871.0 m).Organic pores in Section Ⅰ typically exhibit complex internal structures,coarse surfaces,and interconnectivity,whereas those in Section Ⅱ are simple,smooth,and isolated.Moreover,the former possesses larger specific surface areas(SSAs)than the latter.A fractal analysis reveals that organic pores in the shale sequence can be classified into micropores(<2 nm),mesopores(2-10 nm),and macropores(>10 nm).The calculated fractal dimensions show greater heterogeneity of organic pores,especially macropores,in Section Ⅰ compared to Section Ⅱ.The results also reveal that organic macropores are the primary pores controlling the SSAs of organic pores in shale reservoirs in the WF-LMX formations.Organic pores in Section Ⅰ manifest a superior shale gas adsorption capacity compared to Section Ⅱ.The heterogeneity of organic pores might affect the adsorption capacity of shales in the formations.Generally,organic macropores in Section Ⅰ of the shale sequence exhibit more complex structures and larger SSAs,leading to a stronger absorption capacity of shale reservoirs in Section Ⅰ compared to Section Ⅱ.展开更多
A thermodynamics-based unsaturated hydro-mechanical-chemical(HMC)coupling model is developed to analyze the coupled response and stability of boreholes in chemically active gas formations.The newly coupled constitutiv...A thermodynamics-based unsaturated hydro-mechanical-chemical(HMC)coupling model is developed to analyze the coupled response and stability of boreholes in chemically active gas formations.The newly coupled constitutive relations are formulated by incorporating the chemical effect into the solid-gasliquid unsaturated framework to account for the interactions between rock deformation,gas-liquid two-phase flow,and chemical potential difference.Compared with previous models,the present model shows significant prediction differences in field variables and wellbore stability evolution.The maximum absolute difference of pore pressure,effective radial stress,effective tangential stress,and collapse pressure can reach 8.98 MPa,7.64 MPa,7.29 MPa,7.65 MPa,respectively.It is more conservative to select a long-term wellbore collapse pressure rather than a short-term one to guide drilling operations.The two-phase flow behavior,jointly controlled by wellbore pressure,capillary pressure,and chemical osmosis effect,provides a more realistic observation of the mud intrusion process.Compared with low salinity muds,high salinity muds can effectively impede the mud intrusion into the formation,which is more conducive to preventing wellbore collapse,but at the same time increases the risk of wellbore fracture.Sensitivity analysis shows that solute diffusion and reflection coefficients affect early wellbore stability through pore pressure and solute transport,while the chemical swelling coefficient has a long-term effect through chemically induced deformation.The results can provide theoretical guidance for quantitative optimization of mud parameters and prevention of wellbore instability when drilling in chemically active gas formations.展开更多
0 INTRODUCTION Shale oil has become a significant component of unconventional oil and gas exploration worldwide,dramatically transforming the global energy landscape over the past two decades(Xu et al.,2024;Guo et al....0 INTRODUCTION Shale oil has become a significant component of unconventional oil and gas exploration worldwide,dramatically transforming the global energy landscape over the past two decades(Xu et al.,2024;Guo et al.,2023;Wan et al.,2023;Zou et al.,2020).The successful commercial development of shale oil resources in North America has triggered a global surge in unconventional petroleum exploration,with many countries now actively pursuing their own shale resource development programs(Yang and Jin,2019).展开更多
Formation control remains a critical challenge in cooperative multi-agent systems,particularly for Unmanned Underwater Vehicles(UUVs).Conventional approaches often suffer from several limitations,including reliance on...Formation control remains a critical challenge in cooperative multi-agent systems,particularly for Unmanned Underwater Vehicles(UUVs).Conventional approaches often suffer from several limitations,including reliance on global information,limited adaptability,high computational complexity,and poor scalability.To address these issues,we propose a novel bio-inspired formation control method for UUV swarms,drawing inspiration from the self-organizing behavior of fish schools.Our method integrates three key components:(1)a coordinated motion strategy without predefined targets that enables individual UUVs to align their movements via simple left or right rotations based solely on local neighbor interactions;(2)a target-directed movement strategy that guides UUVs toward specified regions;and(3)a dispersion control strategy that prevents overcrowding by regulating local spatial distributions.Simulation results confirm that the method achieves robust formation control and efficient area coverage using only local perception.Validation in a 9-UUV simulation environment demonstrates the approach’s flexibility,decentralization,and computational efficiency,making it particularly suitable for large-scale swarms with limited sensing and processing capabilities.展开更多
In recent years,drilling data from wells Pengshen 10,Heshen 9,Tongshen 17 and Zhengyang 1 in the Sichuan Basin have confirmed the presence of a set of porous reef-beach limestone reservoirs in the Upper Permian Changx...In recent years,drilling data from wells Pengshen 10,Heshen 9,Tongshen 17 and Zhengyang 1 in the Sichuan Basin have confirmed the presence of a set of porous reef-beach limestone reservoirs in the Upper Permian Changxing Formation,which breaks the traditional view that deep carbonate oil and gas are only distributed in porous dolomite reservoirs and karst fracture-cavity limestone reservoirs.Through core and thin section observations,geochemical analysis,and well-seismic based reservoir identification and tracking,the study on formation mechanism of pores in deep reef-beach limestone reservoirs is carried out,this study provides insights in four aspects.(1)Porous reef-beach limestone reservoirs are developed in the Changxing Formation in deep-buried layers.The reservoir space is composed of intergranular pores,framework pores,intra-fossil pores,moldic pores and dissolution pores,which are formed in depositional and epigenetic environments.(2)The intermittently distributed porous reef-beach complexes are surrounded by relatively dense micrite limestone,which leads to the formation of local abnormal high-pressure inside the reef-beach complexes with the temperature increased.(3)The floor of the Changxing Formation reservoir is composed with interbedded tight mudstone and limestone of the Upper Permian Wujiaping Formation,and the roof is the tight micrite limestone interbedded with mudstone of the first member of Lower Triassic Feixianguan Formation.Under the clamping of dense roof and floor,the abnormal high-pressure in the Changxing Formation is formed.Abnormal high-pressure(overpressured compartment)is the key to maintain the pores formed in the depositional and epigenetic environments in deep-buried layers.(4)Based on the identification of roof,floor and reef-beach complexes,the favorable reef-beach limestone reservoir distribution area of 10.3×10^(4) km^(2) is predicted by well-seismic integration.These insights lay the theoretical foundation for the development of deep porous limestone reservoirs,expand the new field of exploration of deep-buried limestone reservoirs in the Sichuan Basin.展开更多
In response to the need for a supportive on-orbit platform for future Mars exploration missions,this paper proposes the design and implementation of an autonomous spacecraft formation flying system near the Martian sy...In response to the need for a supportive on-orbit platform for future Mars exploration missions,this paper proposes the design and implementation of an autonomous spacecraft formation flying system near the Martian synchronous orbit using fuzzy learning-based intelligent control.A detailed analysis of spacecraft relative motion in the Mars environment is conducted,deducing the necessary conditions to reach the Martian synchronous orbit constraints.The modified Clohessy-Wiltshire(C-W)equation with Martian J_(2)(Oblateness index)perturbation is used as a reference to design a fuzzy learning-based intelligent and robust nonlinear control approach,which helps to autonomously track the desired formation configuration and stabilizes it.An introduction to spacecraft propulsion mechanisms is provided to analyze the feasibility of using electrical thrusters for spacecraft formation configuration tracking and stabilization in Martian synchronous orbits.The simulations show the effectiveness of the proposed control system for long-term on-orbit operations and reveal its reliability for designing intelligent deep-space formation flying configurations,such as an autonomous Mars observatory,a Martian telescope,or an interferometer.展开更多
基金supported by the National Natural Science Foundation of China(22378166)the Basic Research Program of Jiangsu and Jiangsu Basic Research Center for Synthetic Biology(BK20233003)+1 种基金the Fundamental Research Funds for the Central Universities(JUSRP622001)the Open Funding Project of Key Laboratory of Industrial Biotechnology Ministry of Education(KLIB-KF202403).
文摘Formate bioconversion plays a crucial role in achieving renewable resource utilization and green and sustainable development,as it helps convert formate to biofuels and biochemicals.However,to tap the full potential of formate bioconversion,it is important to identify the most appropriate microbial hosts,design the most promising formate assimilation pathways,and develop the most efficient formate assimilation cell factories.Here,we summarize the formatotrophic microorganisms capable of assimilating formate into building blocks of cell growth and analyze the characteristics of formate assimilation pathways for transmitting formate into central carbon metabolism.Furthermore,we discuss microbial engineering strategies to improve the efficiency of formate utilization for producing high-value bioproducts.Finally,we highlight the key challenges of formate bioconversion and their possible solutions to advance the formate bioeconomy and biomanufacturing.
基金supported by the National Natural Science Foundation of China(Grant Nos.12534013,12047561,and 12104507)the Science and Technology Innovation Program of Hunan Province(Grant Nos.2025ZYJ001 and 2021RC4026)the National University of Defense Technology Research Fund Project.
文摘The accumulation and circulation of carbon and hydrogen contribute to the chemical evolution of ice giant planets.Species separation and diamond precipitation have been reported in carbon-hydrogen systems and have been verified by static and shock compression experiments.Nevertheless,the dynamic formation processes underlying these phenomena remain insufficiently understood.In combination with a deep learning model,we demonstrate that diamonds form through a three-step process involving dissociation,species separation,and nucleation processes.Under shock conditions of 125 GPa and 4590 K,hydrocarbons decompose to give hydrogen and low-molecular-weight alkanes(CH_(4) and C_(2)H_(6)),which escape from the carbon chains,resulting in C/H species separation.The remaining carbon atoms without C-H bonds accumulate and nucleate to form diamond crystals.The process of diamond growth is associated with a critical nucleus size at which the dynamic energy barrier plays a key role.These dynamic processes of diamond formation provide insight into the establishment of a model for the evolution of ice giant planets.
基金supported by the National Natural Science Foundation of China(42102135,42072140,42202122 and 41790453)Science and Technology Research Program of Chongqing Municipal Education Commission(KJZD-M202101502,KJQN202201549 and KJQN202101535)+1 种基金Natural Science Foundation of Chongqing(CSTB2022NSCQ-JQX0031 and CSTB2022NSCQMSX1586)China Scholarship Council(202208505055)。
文摘1.Objective The Songliao Basin(SB)is situated on the eastern margin of Eurasia continent(Northeast Asia).During the Late Jurassic to Early Cretaceous,hundreds of rifting basins developed in this area,and the SB is a unique case among them as it evolved into the largest rift basin.The rift basin filling of SB includes Huoshiling Formation,Shahezi Formation,and Yingcheng Formation in ascending order.The mega-rifting was controlled by the Mongol-Okhotsk Collisional Belt to the north and northwest and the Pacific Subduction Zone to the east(Wang PJ et al.,2016).As the first rifting succession,the Huoshiling Formation contains key information about the formation of the rifting basins and records the evolution of the Mongol-Okhotsk Collisional Belt and the Pacific Subduction Zone.However,the geological period of the Huoshiling Formation has not been well constrained for two main reasons.First,it is easily confused with the Yingcheng Formation,as both are dominated by volcanogenic-sedimentary successions.Second,there is lack of reliable dating samples from the uppermost part of the Huoshiling Formation due to its considerable burial depth.
基金supported by the National Key Research and Development Program of China (2023YFC2906701)National Natural Science Foundation of China (42372041, 42072027)China Geological Survey (DD20221646)
文摘Quantonenpollenites,a pollen taxon which was assumed to be angiosperm,is of great significance in confirming the geological age of its bearing strata.Aims to clarify the taxonomic affiliation of Quantonenpollenites,we investigated the external morphology and internal structure using Light Microscopy(LM),Scanning Electron Microscopy(SEM),and Transmission Electron Microscopy(TEM).According to TEM observations,the exine of Quantonenpollenites pollen is unstratified with the absence of a columellar layer,and the exine is tightly connected with the intine.Based on comprehensive morphological evidence,especially the lack of columellar layer which is typical characteristics existing in almost all angiosperm pollen,the botanical affinity of Quantonenpollenites should be attributed to gymnosperms rather than angiosperms as previously thought.Through comparative analysis,it may have a close affinity with Ephedra,but further analytical data are still needed for verification.As a characteristic palynological type of the Quantou Formation in the Songliao Basin,the occurrence of Quantonenpollenites has indicative significance for determining the age of the hosting strata.By systematically clarifying the phylogenetic affiliation of Quantonenpollenites,together with the other associated palynomorphs,this study provides crucial reference materials for defining the stratigraphic age range of the Quantou Formation(Cenomanian to early Turonian),improves the resolution of stratigraphic age calibration of the Quantou Formation,and provides key paleontological evidence for the refined division of the terrestrial Cretaceous chronostratigraphic framework in the Songliao Basin.
基金financially supported by the National Natural Science Foundation of China(22472199)Chinese Universities Scientific Fund(15055009)and Central University Guided Funds for Building World-Class Universities(Disciplines)and Advancing Characteristic Development.The authors extend their gratitude to Theoretical and Computational Chemistry Team(from Scientific Compass www.shiyanjia.com)for providing invaluable assistance.
文摘Electrocatalytic glucose oxidation to high-value chemicals provides a sustainable route for biomass valorization.NiCo-based catalysts have emerged as promising candidates for glucose oxidation reaction owing to the intrinsic activity of Ni and Co catalytic centers.However,the dynamic evolution and atomic-scale synergy between these centers remain elusive.Herein,we fabricated NiCo_(2)O_(4)nanosheets supported on nickel foam,where Ni preferentially occupies tetrahedral sites to regulate the electronic configuration of octahedral Co.Experimental and theoretical results demonstrate that the incorporation of tetrahedral Ni induces low-to-intermediate spin transition in octahedral Co,thereby optimizing eg orbital occupancy and stabilizing active sites.This spin-state engineering establishes Ni-Co synergistic catalytic centers for the selective oxidation of glucose to formate(FA).At higher potential(≥1.4 V vs.RHE),octahedral Co undergoes reconstruction into excessive active CoOOH and CoO_(2)species,resulting in glucose overoxidation to CO_(2)and intensified competitive oxygen evolution.In contrast,at lower potentials(<1.4 V vs.RHE),tetrahedral Ni facilitates electron delocalization across the Ni–O–Co lattice,thereby stabilizing octahedral Co for glucose adsorption and oxidation.Subsequently,a coupled electrocatalytic system was constructed,achieving 80.7%FA yield with 91.3%Faradaic efficiency(FE)at NiCo_(2)O_(4)anode and H2 evolution rate of 696μmol h^(−1)with 99.9%FE at Pt cathode for 2 h under 1.35 V vs.RHE.This work provides a deep insight into spin-state regulation of the catalytic center,offering valuable guidance for rational catalyst design.
基金Dr.Stergios D.Zarkogiannis would like to acknowledge UK Research and Innovation Grant(SODIOM)EP/Y004221/1 in supporting the research reported here.
文摘This study investigates the facies development and sedimentology of the Late Permian Chhidru Formation,a mixed carbonate-siliciclastic unit exposed in the Western Salt Range,Potwar Basin,Pakistan.The formation is subdivided into four lithological units reflecting lateral variability,with thicknesses and lithologies ranging from fossiliferous sandy limestone to interbedded limestone and sandstone.These successions record a depositional shift from a carbonate platform to mixed carbonate-clastic,and ultimately,clastic-dominated environments.Lithostratigraphy suggests deposition on the underlying Wargal Limestone carbonates during a Late Permian sea-level fall on the northwest Indian margin of Gondwana.Similar Permian successions with identical lithological characteristics are documented in the Persian Gulf(Dalan Formation),Arabian Platform(Khuff Formation),and Iran(Nesen and Hambust formations).Petrographic analysis reveals deposition in the distal middle to proximal inner shelf settings of a carbonate-siliciclastic mixed,unrimmed platform.Based on identified foraminiferal assemblages,the Chhidru Formation's age is estimated to range from the late Wuchiapingian to Changhsingian stages of the Lopingian epoch.
基金Supported by Wenzhou Science and Technology Bureau,No.Y20240207.
文摘Cholelithiasis has a complex pathogenesis,necessitating better therapeutic and preventive strategies.We recently read with interest Wang et al’s study on lysine acetyltransferase 2A(KAT2A)-mediated adenosine monophosphate-activated protein kinase(AMPK)succinylation in cholelithiasis.Using mouse models and gallbladder mucosal epithelial cells,they found that KAT2A inhibits gallstones through AMPK K170 succinylation,thereby activating the AMPK/silent information regulator 1 pathway to reduce inflammation and pyroptosis.This study is the first to connect lysine succinylation with cholelithiasis,offering new insights and identifying succinylation as a potential therapeutic target.Future research should confirm these findings using patient samples,investigate other posttranslational modifications,and use structural biology to clarify succinylationinduced conformational changes,thereby bridging basic research to clinical applications.
基金the support of the National Natural Science Foundation of China(22575230)。
文摘Conventional error cancellation approaches separate molecules into smaller fragments and sum the errors of all fragments to counteract the overall computational error of the parent molecules.However,these approaches may be ineffective for systems with strong localized chemical effects,as fragmenting specific substructures into simpler chemical bonds can introduce additional errors instead of mitigating them.To address this issue,we propose the Substructure-Preserved Connection-Based Hierarchy(SCBH),a method that automatically identifies and freezes substructures with significant local chemical effects prior to molecular fragmentation.The SCBH is validated by the gas-phase enthalpy of formation calculation of CHNO molecules.Therein,based on the atomization scheme,the reference and test values are derived at the levels of Gaussian-4(G4)and M062X/6-31+G(2df,p),respectively.Compared to commonly used approaches,SCBH reduces the average computational error by half and requires only15%of the computational cost of G4 to achieve comparable accuracy.Since different types of local effect structures have differentiated influences on gas-phase enthalpy of formation,substituents with strong electronic effects should be retained preferentially.SCBH can be readily extended to diverse classes of organic compounds.Its workflow and source code allow flexible customization of molecular moieties,including azide,carboxyl,trinitromethyl,phenyl,and others.This strategy facilitates accurate,rapid,and automated computations and corrections,making it well-suited for high-throughput molecular screening and dataset construction for gas-phase enthalpy of formation.
基金supported by the Fundamental Research Funds for the Liaoning Universities(Grant No.LJ202410166012).
文摘The Ordos Basin is a large superimposed hydrocarbon-bearing basin in China,and further research on the sedimentary characteristics and sedimentary evolution of the sequence framework of target layers is of great theoretical and practical significance for guiding oil and gas exploration.The sedimentary facies and sedimentary evolution of the high-resolution sequence framework of the Carboniferous Taiyuan Formation in the Hangjinqi area have been systematically analyzed for the first time by drilling,logging and seismic data.The results show that four types of sequence interfaces can be identified in the Taiyuan Formation:regional unconformity surfaces,scour surfaces,lithologic-lithofacies transformation surfaces and flooding surfaces.According to the sedimentary response caused by the upward and downward movements of the base level at different levels,the Taiyuan Formation can be divided into 2 long-term cycles(LSC_(1)-LSC_(2)),4 mid-term cycles(MSC_(1)-MSC4)and 7 short-term cycles(SSC_(1)-SSC7).The long-and mid-term cycles correspond to members T_(1)and T_(2)and layers T_(1)-1,T_(1-2),T_(2-1),and T_(2)-2,respectively.Long-term cycles are dominated by C_(1);mid-term cycles are dominated by C_(1)and C_(2),followed by A2;and short-term cycles are dominated by C_(1),C_(2),A1 and A2.Under the high-resolution sequence stratigraphic framework,the Hangjinqi area underwent a transformation of fan delta and tidal flat depositional systems during the Taiyuan Formation sedimentary period.In the MSC_(1)-MSC_(2)stage,owing to a large-scale paleocontinent,the fan delta sedimentary body,which was limited in scale and scope,developed only in the southeastern corner and gradually transitioned basinward to tidal flat facies.In the MSC3-MSC4 stage,as the paleocontinent continuously decreased and the sedimentary range expanded,fan-delta plain sedimentation began in the study area.Several braided distributary channels with poor connectivity developed on the fan-delta plain,and between them were floodplains and peat swamps.
基金Supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions under Grant No.014000319/2018-00391.
文摘Pre-chamber ignition technology can address the issue of uneven in-cylinder mixture combustion in large-bore marine engines.The impact of various pre-chamber structures on the formation of the mixture and jet flames within the pre-chamber is explored.This study performed numerical simulations on a large-bore marine ammonia/hydrogen pre-chamber engine prototype,considering pre-chamber volume,throat diameter,the distance between the hydrogen injector and the spark plug,and the hydrogen injector angle.Compared with the original engine,when the pre-chamber volume is 73.4 ml,the throat diameter is 14 mm,the distance ratio is 0.92,and the hydrogen injector angle is 80°.Moreover,the peak pressure in the pre-chamber increased by 23.1%,and that in the main chamber increased by 46.3%.The results indicate that the performance of the original engine is greatly enhanced by altering its fuel and pre-chamber structure.
基金funded by the National Natural Science Foundation of China(32071828 and 32471943)the Central Finance Forestry Science and Technology Promotion Demonstration Project,China(Su2024TG04)+1 种基金the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD),Chinapartly supported by the open funds of the National Key Laboratory for Germplasm Innovation&Utilization of Horticultural Crops,China。
文摘Osmanthus fragrans is most famous for its strong aroma,and different varieties have different degrees of fragrance and color.Fragrance and color are important factors affecting the ornamental quality of O.fragrans.Terpenoids are important secondary metabolites in plants,with β-carotene(C40)being the major pigment substance and linalool(C10)being the key aromatic component in O.fragrans.The geranylgeranyl pyrophosphate synthase genes(GGPPSs)play important roles in secondary metabolism in plants.However,the functions of the GGPPS family in floral color and fragrance formation has rarely been reported in O.fragrans.In this study,24 Of GGPPS genes were identified and classified into two subfamilies.The Of GGPPSs showed tissue-specific expression and Of GGPPS13 had highest expression in flowers.The Of GGPPS13 protein was localized to chloroplasts.The transcriptome data of Of GGPPS13 was verified by q RT-PCR and the expression level in‘Wanyingui'with strong aroma was higher than that in‘Zhuangyuanhong'with deep color at different flower development stages.Transient overexpression of Of GGPPS13 in O.fragrans petals showed that Of GGPPS13 increased the β-carotene content,the main color substance of O.fragrans,but decreased the linalool content,the main volatile organic compound(VOC)in the floral aroma of O.fragrans.Of GGPPS13 was indicated as the critical gene related to terpenoid synthesis in the floral aroma and color formation in O.fragrans.Our findings provide gene resources on the GGPPS gene family for further revealing the molecular regulation mechanism of the floral color and aroma formation in O.fragrans.
基金co-funded by the National Natural Science Foundation of China(42372160,42072172)。
文摘The Neogene Shawan Formation in the Chepaizi Uplift of the Junggar Basin(NW China)has obtained high oil flow,demonstrating a good potential for oil and gas exploration.The multi-source hydrocarbon generation background and strong tectonic activity have led to the simultaneous production of heavy oil and light oil from multi-layer in the area,which makes it very difficult to identify oil origins,presently,the hot debate on the oil origins needs to be clarified.In this paper,due to the selective consumption of different types of compounds in crude oils by severe and intense biodegradation,the commonly used oilsource correlation tools are ineffective or may produce misleading results,this study adopted a biomarker recovery method based on the principle of mass conservation that uses the sum of the mass of the residual biomarkers and their corresponding biodegradation products to obtain the mass of the original biomarkers,improving the reliability of oil origins determination.Based on the nature and occurrence of crude oils,the investigated oils are subdivided into three types,Group A,Group B and Group C.Group A,light oils occurred mainly in lower structure Neogene Shawan Formation in the western Chepaizi Uplift,while Group B,heavy oils occurred mainly in higher structure Neogene Shawan Formation in the western Chepaizi Uplift.The two types of crude oils may come from the mixed source of Jurassic Badaowan Formation source rocks(J_(1)b)and Paleogene Anjihaihe Formation source rocks(E_(2-3)a)in the Sikeshu Sag,and Jurassic Badaowan Formation source rocks(J_(1)b)are the main source of crude oils.Group C,heavy oils occurred mainly in Neogene Shawan Formation in the eastern Chepaizi Uplift,showing good correlation with the Permian(P_(1)f and P_(2)w)source rocks in the Shawan Sag.At the same time,by combining stable carbon isotope and parameters related to triaromatic steroids,the accuracy of the oilsource correlation results by biomarker recovery method was further verified.
基金supported in part by the National Natural Science Foundation of China under Grant 6237319in part by the Postgraduate Research and Practice Innovation Program of Jiangsu Province under Grant KYCX230479.
文摘Formation control in multi-agent systems has become a critical area of interest due to its wide-ranging applications in robotics,autonomous transportation,and surveillance.While various studies have explored distributed cooperative control,this review focuses on the theoretical foundations and recent developments in formation control strategies.The paper categorizes and analyzes key formation types,including formation maintenance,group or cluster formation,bipartite formations,event-triggered formations,finite-time convergence,and constrained formations.A significant portion of the review addresses formation control under constrained dynamics,presenting both modelbased and model-free approaches that consider practical limitations such as actuator bounds,communication delays,and nonholonomic constraints.Additionally,the paper discusses emerging trends,including the integration of eventdriven mechanisms and AI-enhanced coordination strategies.Comparative evaluations highlight the trade-offs among various methodologies regarding scalability,robustness,and real-world feasibility.Practical implementations are reviewed across diverse platforms,and the review identifies the current achievements and unresolved challenges in the field.The paper concludes by outlining promising research directions,such as adaptive control for dynamic environments,energy-efficient coordination,and using learning-based control under uncertainty.This review synthesizes the current state of the art and provides a road map for future investigation,making it a valuable reference for researchers and practitioners aiming to advance formation control in multi-agent systems.
基金supported by the National Natural Science Foundation of China(62073094)the Fundamental Research Funds for the Central Universities(3072024GH0404)
文摘Dear Editor,This letter addresses the formation control problem for constrained underactuated autonomous underwater vehicles (AUVs). The feasibility condition of the virtual control law is eliminated by introducing a nonlinear state dependence function (NSDF) that transforms the state of each AUV in the formation.
基金funded by the National Natural Science Foundation Research of China(No.41902127,41802157)the Shandong Provincial Natural Science Foundation,China(No.ZR2018BD015).
文摘This study aims to determine the variation and controlling factors of shale gas adsorption capacity in reservoirs in the Upper Ordovician Wufeng Formation and the Lower Silurian Longmaxi Formation(also referred to as the WF-LMX formations),South China.Based on data obtained using scanning helium ion microscopy(HIM)and nitrogen(N_(2))and methane(CH_(4))adsorption experiments,this study analyzed the organic pore heterogeneity of shales in the WF-LMX formations in well A and its effect on shale gas adsorption.Using the Frenkel-Halsey-Hill(FHH)model,data from N_(2) adsorption experiments were converted into fractal dimensions,which can reflect the complexity and heterogeneity of organic pores while also serving as a novel indicator for quantitatively assessing the pore structure complexity.The results indicate that shales in the WF-LMX formations in well A can be divided into two sections:(Ⅰ)the Wufeng Formation and the lower Longmaxi Formation(depths:ca.2871.0-2898.6 m),and(Ⅱ)the upper Longmaxi Formation(depths:<2871.0 m).Organic pores in Section Ⅰ typically exhibit complex internal structures,coarse surfaces,and interconnectivity,whereas those in Section Ⅱ are simple,smooth,and isolated.Moreover,the former possesses larger specific surface areas(SSAs)than the latter.A fractal analysis reveals that organic pores in the shale sequence can be classified into micropores(<2 nm),mesopores(2-10 nm),and macropores(>10 nm).The calculated fractal dimensions show greater heterogeneity of organic pores,especially macropores,in Section Ⅰ compared to Section Ⅱ.The results also reveal that organic macropores are the primary pores controlling the SSAs of organic pores in shale reservoirs in the WF-LMX formations.Organic pores in Section Ⅰ manifest a superior shale gas adsorption capacity compared to Section Ⅱ.The heterogeneity of organic pores might affect the adsorption capacity of shales in the formations.Generally,organic macropores in Section Ⅰ of the shale sequence exhibit more complex structures and larger SSAs,leading to a stronger absorption capacity of shale reservoirs in Section Ⅰ compared to Section Ⅱ.
基金supported by the National Natural Science Foundation of China(Grant No.52474010)the Natural Science Foundation of Sichuan Province(Grant No.2024NSFSC0023)the Sichuan Science and Technology Program(Grant No.2020JDJQ0055).
文摘A thermodynamics-based unsaturated hydro-mechanical-chemical(HMC)coupling model is developed to analyze the coupled response and stability of boreholes in chemically active gas formations.The newly coupled constitutive relations are formulated by incorporating the chemical effect into the solid-gasliquid unsaturated framework to account for the interactions between rock deformation,gas-liquid two-phase flow,and chemical potential difference.Compared with previous models,the present model shows significant prediction differences in field variables and wellbore stability evolution.The maximum absolute difference of pore pressure,effective radial stress,effective tangential stress,and collapse pressure can reach 8.98 MPa,7.64 MPa,7.29 MPa,7.65 MPa,respectively.It is more conservative to select a long-term wellbore collapse pressure rather than a short-term one to guide drilling operations.The two-phase flow behavior,jointly controlled by wellbore pressure,capillary pressure,and chemical osmosis effect,provides a more realistic observation of the mud intrusion process.Compared with low salinity muds,high salinity muds can effectively impede the mud intrusion into the formation,which is more conducive to preventing wellbore collapse,but at the same time increases the risk of wellbore fracture.Sensitivity analysis shows that solute diffusion and reflection coefficients affect early wellbore stability through pore pressure and solute transport,while the chemical swelling coefficient has a long-term effect through chemically induced deformation.The results can provide theoretical guidance for quantitative optimization of mud parameters and prevention of wellbore instability when drilling in chemically active gas formations.
基金supported by the State Key Laboratory of Petroleum Resources and Engineering,China University of Petroleum(Beijing)(No.PRE/open-2501)。
文摘0 INTRODUCTION Shale oil has become a significant component of unconventional oil and gas exploration worldwide,dramatically transforming the global energy landscape over the past two decades(Xu et al.,2024;Guo et al.,2023;Wan et al.,2023;Zou et al.,2020).The successful commercial development of shale oil resources in North America has triggered a global surge in unconventional petroleum exploration,with many countries now actively pursuing their own shale resource development programs(Yang and Jin,2019).
基金supported by The Special Fund for Basic Scientific Research for Liaoning Provincial Governed Universities(2024JBZDZ004)Fishery Central Financial Support Project of Liaoning Province(2023)+5 种基金Liaoning Province Key Research and Development Plan(2023JH26/10200015)Natural Science Foundation of Liaoning Province(2020-KF-12-09)The Liaoning Provincial Education Commission Fund(LJKZ0730,QL202016)Applied Basic Research Project of Science and Technology Commission of Liaoning Province(2022JH2/101300187)Open Fund of Key Laboratory of Environmental Control Aquaculture of Ministry of Education(Dalian Ocean University)(202219)Liaoning Province Science and Technology Plan Joint Program(2024JH2/102600083).
文摘Formation control remains a critical challenge in cooperative multi-agent systems,particularly for Unmanned Underwater Vehicles(UUVs).Conventional approaches often suffer from several limitations,including reliance on global information,limited adaptability,high computational complexity,and poor scalability.To address these issues,we propose a novel bio-inspired formation control method for UUV swarms,drawing inspiration from the self-organizing behavior of fish schools.Our method integrates three key components:(1)a coordinated motion strategy without predefined targets that enables individual UUVs to align their movements via simple left or right rotations based solely on local neighbor interactions;(2)a target-directed movement strategy that guides UUVs toward specified regions;and(3)a dispersion control strategy that prevents overcrowding by regulating local spatial distributions.Simulation results confirm that the method achieves robust formation control and efficient area coverage using only local perception.Validation in a 9-UUV simulation environment demonstrates the approach’s flexibility,decentralization,and computational efficiency,making it particularly suitable for large-scale swarms with limited sensing and processing capabilities.
基金Supported by the National Natural Science Foundation of China(U23B20154)General Program of the National Natural Science Foundation of China(42372169)。
文摘In recent years,drilling data from wells Pengshen 10,Heshen 9,Tongshen 17 and Zhengyang 1 in the Sichuan Basin have confirmed the presence of a set of porous reef-beach limestone reservoirs in the Upper Permian Changxing Formation,which breaks the traditional view that deep carbonate oil and gas are only distributed in porous dolomite reservoirs and karst fracture-cavity limestone reservoirs.Through core and thin section observations,geochemical analysis,and well-seismic based reservoir identification and tracking,the study on formation mechanism of pores in deep reef-beach limestone reservoirs is carried out,this study provides insights in four aspects.(1)Porous reef-beach limestone reservoirs are developed in the Changxing Formation in deep-buried layers.The reservoir space is composed of intergranular pores,framework pores,intra-fossil pores,moldic pores and dissolution pores,which are formed in depositional and epigenetic environments.(2)The intermittently distributed porous reef-beach complexes are surrounded by relatively dense micrite limestone,which leads to the formation of local abnormal high-pressure inside the reef-beach complexes with the temperature increased.(3)The floor of the Changxing Formation reservoir is composed with interbedded tight mudstone and limestone of the Upper Permian Wujiaping Formation,and the roof is the tight micrite limestone interbedded with mudstone of the first member of Lower Triassic Feixianguan Formation.Under the clamping of dense roof and floor,the abnormal high-pressure in the Changxing Formation is formed.Abnormal high-pressure(overpressured compartment)is the key to maintain the pores formed in the depositional and epigenetic environments in deep-buried layers.(4)Based on the identification of roof,floor and reef-beach complexes,the favorable reef-beach limestone reservoir distribution area of 10.3×10^(4) km^(2) is predicted by well-seismic integration.These insights lay the theoretical foundation for the development of deep porous limestone reservoirs,expand the new field of exploration of deep-buried limestone reservoirs in the Sichuan Basin.
基金supported by the National Laboratory of Space Intelligent Control(No.HTKJ2023KL502007)the Chinese Government Scholarship(CSC)。
文摘In response to the need for a supportive on-orbit platform for future Mars exploration missions,this paper proposes the design and implementation of an autonomous spacecraft formation flying system near the Martian synchronous orbit using fuzzy learning-based intelligent control.A detailed analysis of spacecraft relative motion in the Mars environment is conducted,deducing the necessary conditions to reach the Martian synchronous orbit constraints.The modified Clohessy-Wiltshire(C-W)equation with Martian J_(2)(Oblateness index)perturbation is used as a reference to design a fuzzy learning-based intelligent and robust nonlinear control approach,which helps to autonomously track the desired formation configuration and stabilizes it.An introduction to spacecraft propulsion mechanisms is provided to analyze the feasibility of using electrical thrusters for spacecraft formation configuration tracking and stabilization in Martian synchronous orbits.The simulations show the effectiveness of the proposed control system for long-term on-orbit operations and reveal its reliability for designing intelligent deep-space formation flying configurations,such as an autonomous Mars observatory,a Martian telescope,or an interferometer.
