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Development of visible/near-infrared multiband laser filter film
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作者 XIN Ya-wu PENG Yong-chao +5 位作者 ZHANG Yu-xiang CAO Xing-yu HAN Yang GUO Hong-ling XIONG Shi-fu HU Zhang-gui 《中国光学(中英文)》 北大核心 2026年第1期239-249,共11页
Filters,as a key component in the photoelectric detection system,can simplify the optical system and improve detection efficiency.Based on the usage requirements,a visible/near-infrared filter film with up to 5 waveba... Filters,as a key component in the photoelectric detection system,can simplify the optical system and improve detection efficiency.Based on the usage requirements,a visible/near-infrared filter film with up to 5 wavebands needs to be designed and prepared,while simultaneously satisfying high reflection in 2 wave-bands and high transmittance in 3 wavebands.Therefore,we have conducted a systematic study on the film design,thin film preparation process,and control accuracy of film layer thickness.In this work,the short-wave pass film system is superimposed with the long-wave pass film system,and the number of cycles and matching coefficient of the film system are tuned to meet the requirements of cut-off band.Additionally,Smith method was used to match bandpass film system to optimize the transmission band and complete the visible/near infrared multiband laser filter film design.In the preparation process,combined with the sensitiv-ity of the film layer,inverse analysis is used to invert the film layer monitored by each optical monitoring chip.The optical control scheme with weak optical signal in the monitoring process is simulated and correc-ted,and the monitoring wavelength with stronger optical signal is matched,resulting in an improvement of the control accuracy for the film thickness and the transmittance in the specified wavelength range.Ulti-mately,the actual physical thickness is 9.66μm,and the error with the theoretical design thickness is less than 0.4%,and the transmittance of the specified 3 wavebands exceeds 99%.The average transmittance of the cut-off bands at the 455−500 nm and 910−1000 nm is 0.45% and 0.16%,respectively. 展开更多
关键词 optical film MULTIBAND film system design reverse analysis
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Big Screen Boom:The robust growth of China’s film market points to a strong postpandemic recovery and reflects its immense potential
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作者 LU JIAJUN 《ChinAfrica》 2026年第2期54-55,共2页
The year 2025 marks the 120th anniversary of the birth of Chinese filmmaking.From the first film Dingjun Mountain released in 1905,which captured scenes from Peking opera,to the present day where artificial intelligen... The year 2025 marks the 120th anniversary of the birth of Chinese filmmaking.From the first film Dingjun Mountain released in 1905,which captured scenes from Peking opera,to the present day where artificial intelligence(AI)is utilised in film production,the Chinese film industry has been developing for over a century.Data from the China Film Administration shows that China’s 2025 box o"ce revenue topped 51.8 billion yuan($7.4 billion),realising a year-on-year increase of nearly 22 percent. 展开更多
关键词 postpandemic recovery robust growth box office revenue chinese film industry artificial intelligence ai th anniversary film dingjun mountain immense potential
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Flexible Gd‑MOF@PMMA/BMA composite film fluorescent sensor for highly sensitive detection of tyramine in bananas
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作者 ZHANG Xin JIAO Xinyi +4 位作者 BAI Wanqiao SUN Xuehua CUI Huali REN Yixia CHAI Hongmei 《无机化学学报》 北大核心 2026年第2期217-226,共10页
In this study,using 3,5‑di(3′,5′‑dicarboxylphenyl)‑1H‑1,2,4‑triazole(H4L)as ligands,a gadolinia‑based organic framework complex{[GdNa(L)(H_(2)O)3]·2H_(2)O}_(n)(Gd‑Na‑MOF)was successfully designed and synthesize... In this study,using 3,5‑di(3′,5′‑dicarboxylphenyl)‑1H‑1,2,4‑triazole(H4L)as ligands,a gadolinia‑based organic framework complex{[GdNa(L)(H_(2)O)3]·2H_(2)O}_(n)(Gd‑Na‑MOF)was successfully designed and synthesized by hydrothermal method.The structure and properties were systematically characterized and tested by techniques such as single‑crystal X‑ray diffraction,powder X‑ray diffraction,thermogravimetric analysis,infrared spectroscopy,and fluorescence spectroscopy.The results indicate that this complex has a unique 3D structure,excellent thermal stability,and outstanding luminescent performance.Based on its luminescent properties,a polymer‑embedding method was employed to fabricate the Gd‑Na‑MOF into a flexible,washable composite fluorescent film,Gd‑Na‑MOF@PMMA/BMA(PMMA=polymethyl methacrylate,BMA=butyl methacrylate).This fluorescent film exhibited highly sensitive recognition capability for tyramine,with a low detection limit of 1.66μmol·L^(-1).It was used for the detection of tyramine in bananas,with a recovery rate of 96.92%‑100.26%.CCDC:2466949. 展开更多
关键词 metal‑organic frameworks Gd‑Na‑MOF@PMMA/BMA composite fluorescent film fluorescent sensing TYRAMINE
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Evolution of diamond film growth modes under varied plasma conditions:insights from optical emission spectroscopy
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作者 Pengfei Qu Guangdi Zhou +2 位作者 Peng Jin Xu Han Zhanguo Wang 《Journal of Semiconductors》 2026年第1期91-97,共7页
The synthesis of high-quality heteroepitaxial diamond films on iridium composite substrates is a critical step toward advancing diamond for electronic and optical applications.Microwave plasma chemical vapor depositio... The synthesis of high-quality heteroepitaxial diamond films on iridium composite substrates is a critical step toward advancing diamond for electronic and optical applications.Microwave plasma chemical vapor deposition,combined with in situ optical emission spectroscopy,enables precise control over growth modes through plasma parameter tuning.In this study,we examine how methane concentration,microwave power,and gas pressure influence plasma species and,consequently,the growth modes of heteroepitaxial diamond by optical emission spectroscopy and scanning electron microscope.At low nucleation densities,increased methane concentrations promote the transition from faceted polyhedral to ballas structures,driven by elevated C_(2) radical concentrations in the plasma.Conversely,at higher nucleation densities,gas pressure,and substrate temperature dominate growth mode determination,leading to diverse morphologies,such as planar,polycrystalline,octahedral,and step-flow growth.These findings elucidate the interplay among plasma species,growth parameters,and growth mode,offering critical insights for optimizing growth conditions and preparing heteroepitaxial diamond films in a specific growth mode. 展开更多
关键词 HETEROEPITAXY diamond films growth modes MPCVD OES
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Enhanced hydrophobicity and photosensitivity of DATNBI/alginate films via ionic cross-linking for near-infrared laser ignition
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作者 Ping Ye Weimiao Wang +7 位作者 Xiaodong Li Zhiqiang Qiao Changping Guo Jinjin He Xu Zhou Rui Li Guangcheng Yang Guoqing Lv 《Defence Technology(防务技术)》 2026年第1期109-117,共9页
Based on the characteristics of laser-induced surface ignition,energetic photosensitive films show promising potential to meet the ignition requirements of various energetic materials(EMs).In this study,DATNBI/ferric ... Based on the characteristics of laser-induced surface ignition,energetic photosensitive films show promising potential to meet the ignition requirements of various energetic materials(EMs).In this study,DATNBI/ferric alginate(DI/FeA),DI/cobalt alginate(DI/CoA),and DI/nickel alginate(DI/Ni A)films are fabricated by employing sodium alginate(SA)with a three-dimensional network structure as the film matrix,via ionic cross-linking of SA with Fe^(3+),Co^(2+),and Ni^(2+)ions.The study demonstrates that the ionic cross-linking enhances the hydrophobic performance of the films,with the water contact angle increasing from 82.1° to 123.5°.Concurrently,the films'near-infrared(NIR)light absorption improved.Furthermore,transition metal ions facilitate accelerated electron transfer,thereby catalyzing the thermal decomposition of DATNBI.Under 1064 nm laser irradiation,the DI/Fe A film exhibits exceptional combustion performance,with an ignition delay time as low as 76 ms.It successfully acts as an NIR laser ignition medium to initiate the self-sustained combustion of CL-20.This study demonstrates the synergistic realization of enhanced hydrophobicity,improved photosensitivity,and promoted catalytic decomposition through microstructural design of the material,providing new insights for the design of additive-free EMs in laser ignition applications. 展开更多
关键词 DATNBI Sodium alginate Ionic cross-linking Photosensitive films Laser ignition
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Comparing the Indoor and Solar Performance of Light-Concentrating Waveguide-Encoded Lattice Slim Films
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作者 Takashi Lawson Kathryn A.Benincasa +7 位作者 Anjilee Manhas Fariha Mahmood Helen Tunstall-García Zhihang Wang Zhongjin Shen Marina Freitag Kalaichelvi Saravanamuttu Rachel C.Evans 《Carbon Energy》 2026年第1期187-196,共10页
Although multicrystalline Si photovoltaics have been extensively studied and applied in the collection of solar energy,the same systems suffer significant efficiency losses in indoor settings,where ambient light condi... Although multicrystalline Si photovoltaics have been extensively studied and applied in the collection of solar energy,the same systems suffer significant efficiency losses in indoor settings,where ambient light conditions are considerably smaller in intensity and possess greater components of non-normal incidence.Yet,indoor light-driven,stand-alone devices can offer sustainable advances in next-generation technologies such as the Internet of Things.Here,we present a non-invasive solution to aid in photovoltaic indoor light collection—radially distributed waveguide-encoded lattice(RDWEL)slim films(thickness 1.5 mm).Embedded with a monotonical radial array of cylindrical waveguides(±20°),the RDWEL demonstrates seamless light collection(FoV(fields of view)=74.5°)and imparts enhancements in JSC(short circuit current density)of 44%and 14%for indoor and outdoor lighting conditions,respectively,when coupled to a photovoltaic device and compared to an unstructured but otherwise identical slim film coating. 展开更多
关键词 indoor light light concentrators optical thin films PHOTOPATTERNING photovoltaics self-induced waveguides solar energy
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Demonstration of InSnO thin-film transistors with superior uniformity and reliability utilizing SiO_(2)passivation
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作者 Tingrui Huang Jie Cao +7 位作者 Zuoxu Yu Yuzhen Zhang Wenting Xu Xifeng Li Cong Peng Weifeng Sun Guangan Yang Wangran Wu 《Journal of Semiconductors》 2026年第2期15-21,共7页
In this work,we demonstrated the InSnO(ITO)TFTs passivated with SiO_(2)via the PECVD process compatible with large-area production for the first time.The passivated ITO TFTs with various channel thicknesses(t_(ch)=4,5... In this work,we demonstrated the InSnO(ITO)TFTs passivated with SiO_(2)via the PECVD process compatible with large-area production for the first time.The passivated ITO TFTs with various channel thicknesses(t_(ch)=4,5,6 nm)exhibit excellent electrical performance and superior uniformity.The reliability properties of ITO TFTs were evaluated in detail under positive bias stress(PBS)conditions before and after passivation.Compared to the devices without passivation,the passivated devices have only 50%threshold voltage degradation(ΔV_(th))and 50%newly generated traps due to excellent isolation of the ambient atmosphere.The negligible performance degradation of ITO TFTs with passivation during negative bias stress(NBS)and negative bias temperature stress(NBTS)verifies the outstanding immunity to the water vapor of the SiO_(2)passivation layer.Overall,the ITO TFT with the t_(ch)of 6 nm and with SiO_(2)passivation exhibits the best performance in terms of electrical properties,uniformity,and reliability,which is promising in large-area production. 展开更多
关键词 thin film transistor RELIABILITY INSNO SiO_(2)
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Comparison of tear film quantity parameters between keratoconus and normal eyes
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作者 Foroozan Narooie-Noori Masoud Khorrami-Nejad +1 位作者 Nabaa Ayad Hesam Hashemian 《International Journal of Ophthalmology(English edition)》 2026年第1期42-47,共6页
AIM:To compare the tear film quantity and stability parameters in keratoconus(KCN)and normal eyes using test breakup time(TBUT),noninvasive TBUT(NITBUT),and Schirmer test.METHODS:All participants(n=166),including pati... AIM:To compare the tear film quantity and stability parameters in keratoconus(KCN)and normal eyes using test breakup time(TBUT),noninvasive TBUT(NITBUT),and Schirmer test.METHODS:All participants(n=166),including patients with KCN and age-matched healthy individuals with normal corneas,were recruited from those referred to Farabi Eye Hospital,Iran,in 2023.To better account for genetic and environmental factors,the control group comprised healthy individuals who were relatives of KCN patients and had normal corneal topography.Tear quantity parameters were evaluated in the following order:NITBUT,TBUT,and Schirmer tests.RESULTS:The mean age of cases in KCN(61.7%males)and normal(63.5%males)participants was 27.54±5.44y(range 19 to 38)and 27.52±5.63y(range 20 to 38),respectively(P=0.976).NIBUT,TBUT,and Schirmer’s tests were significantly lower in KCN group compared to normal controls(all P<0.001).The mean difference for NIBUT was-7.81s(P<0.001),and for TBUT was-7.61s(P<0.001).Schirmer test values were also significantly lower in the KCN group,with a mean difference of-5.61 mm compared to normal people(P<0.001).CONCLUSION:Our findings demonstrate significant tear film impairment in KCN.The reductions in NIBUT,TBUT and Schirmer scores highlight an underlying tear film dysfunction in KCN that extends beyond the morphological changes of the cornea. 展开更多
关键词 KERATOCONUS tear breakup time noninvasive tear breakup time Schirmer test tear film
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Post-buckling analysis of square film under in-plane torsion:experiment and simulation comparisons
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作者 Yiming Shan Liang Wang Wenwang Wu 《Acta Mechanica Sinica》 2026年第1期220-232,共13页
Thin-film structures are widely used in industry due to their advantages in lightweight,flexibility and deployability.This paper investigates the wrinkling deformation pattern of square film subjected to in-plane tors... Thin-film structures are widely used in industry due to their advantages in lightweight,flexibility and deployability.This paper investigates the wrinkling deformation pattern of square film subjected to in-plane torsion through the post-buckling theory of shell,with the geometric nonlinear behavior derived by energy principle and analyzed with finite element method.An equal-sized experimental verification platform is designed and fabricated,and the wrinkling surface of polyimide film driven by rotary motor is reconstructed by 3D-digital image correlation measurement and verified with finite element simulation comparisons.Wrinkling region within the film expands continuously as the torsion proceeds,accompanied by multiple wrinkling configuration transitions throughout the complete evolutionary process.Due to the non-axial symmetry between structure and loading,significant discrepancies arise in amplitude,span and wavelength between different stripes,effects of thickness,torsion radius and pre-stretch on wrinkling pattern configuration are further discussed.This study can provide valuable references for understanding the wrinkling mechanism of hard film under complex torsion loading. 展开更多
关键词 film structure Post-buckling theory Wrinkling configuration 3D-DIC measurement Finite element analysis
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Correction: Optimizing Exciton and Charge-Carrier Behavior in Thick-Film Organic Photovoltaics: A Comprehensive Review
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作者 Lu Wei Yaxin Yang +2 位作者 Lingling Zhan Shouchun Yin Hongzheng Chen 《Nano-Micro Letters》 2026年第1期608-608,共1页
Correction to:Nano-Micro Letters(2026)18:10.https://doi.org/10.1007/s40820-025-01852-8 Following publication of the original article[1],the authors reported that the last author’s name was inadvertently misspelled.Th... Correction to:Nano-Micro Letters(2026)18:10.https://doi.org/10.1007/s40820-025-01852-8 Following publication of the original article[1],the authors reported that the last author’s name was inadvertently misspelled.The published version showed“Hongzhen Chen”,whereas the correct spelling should be“Hongzheng Chen”.The correct author name has been provided in this Correction,and the original article[1]has been corrected. 展开更多
关键词 charge carrier behavior exciton behavior comprehensive review thick film organic photovoltaics nano micro letters
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Ultrahigh Dielectric Permittivity of a Micron-Sized Hf_(0.5)Zr_(0.5)O_(2) Thin-Film Capacitor After Missing of a Mixed Tetragonal Phase
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作者 Wen Di Zhang Bing Li +3 位作者 Wei Wei Wang Xing Ya Wang Yan Cheng An Quan Jiang 《Nano-Micro Letters》 2026年第1期144-153,共10页
Innovative use of HfO_(2)-based high-dielectric-permittivity materials could enable their integration into few-nanometre-scale devices for storing substantial quantities of electrical charges,which have received wides... Innovative use of HfO_(2)-based high-dielectric-permittivity materials could enable their integration into few-nanometre-scale devices for storing substantial quantities of electrical charges,which have received widespread applications in high-storage-density dynamic random access memory and energy-efficient complementary metal-oxide-semiconductor devices.During bipolar high electric-field cycling in numbers close to dielectric breakdown,the dielectric permittivity suddenly increases by 30 times after oxygen-vacancy ordering and ferroelectric-to-nonferroelectric phase transition of near-edge plasma-treated Hf_(0.5)Zr_(0.5)O_(2) thin-film capacitors.Here we report a much higher dielectric permittivity of 1466 during downscaling of the capacitor into the diameter of 3.85μm when the ferroelectricity suddenly disappears without high-field cycling.The stored charge density is as high as 183μC cm^(−2) at an operating voltage/time of 1.2 V/50 ns at cycle numbers of more than 10^(12) without inducing dielectric breakdown.The study of synchrotron X-ray micro-diffraction patterns show missing of a mixed tetragonal phase.The image of electron energy loss spectroscopy shows the preferred oxygen-vacancy accumulation at the regions near top/bottom electrodes as well as grain boundaries.The ultrahigh dielectric-permittivity material enables high-density integration of extremely scaled logic and memory devices in the future. 展开更多
关键词 Hf_(0.5)Zr_(0.5)O_(2)thin film Ultrahigh dielectric permittivity Near-edge plasma treatment Oxygen vacancy Charge storage
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Robust ferroelectricity in ultrathin BaTiO_(3)films deposited at room temperature
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作者 Cong-Meng Li Hui Li +2 位作者 Jian Chen Ming-Kai Li Hong-Wei Gu 《Rare Metals》 2025年第7期5106-5111,共6页
Ferroelectric materials are widely applied in the ferroelectronic devices,photovoltaics,and so on.Ultrathin ferroelectric thin films are highly desired for their applications,which still remain a challenge.In this wor... Ferroelectric materials are widely applied in the ferroelectronic devices,photovoltaics,and so on.Ultrathin ferroelectric thin films are highly desired for their applications,which still remain a challenge.In this work,the ultrathin barium titanate(BaTiO_(3),BTO)films are deposited directly on the fluorine-doped tin oxide glass(SnO_(2):F,FTO)substrates by radio frequency magnetron sputtering method at different temperatures.All BTO ultrathin films exhibit strong ferroelectric properties.Interestingly,BTO thin films deposited at room temperature(RT)also exhibit robust ferroelectricity.The polar domains are switched reversibly with a phase degree of~180°by piezoelectric force microscopy for the BTO thin films deposited at room temperature,attributing to the strain and ion migration. 展开更多
关键词 radio frequency magnetron sputtering method barium titanate batio bto films ferroelectronic devicesphotovoltaicsand ferroelectric propertiesinterestinglybto ferroelectric materials ultrathin films ferroelectric thin films barium titanate
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Arrangement guideline of film holes along conjugate temperature difference in turbine guide vanes
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作者 Yuhao JIA Yongbao LIU +2 位作者 Xing HE Zewei MENG Shuai ZHAO 《Chinese Journal of Aeronautics》 2025年第6期242-259,共18页
A film hole arrangement guideline along the temperature difference is proposed.The performance of different film holes arrangement and the impact of parameters are investigated though cascade wind tunnel test and nume... A film hole arrangement guideline along the temperature difference is proposed.The performance of different film holes arrangement and the impact of parameters are investigated though cascade wind tunnel test and numerical simulations.Finally,the optimized flow field structure and the mechanism of its effects are explored.Under the same operating conditions,Hole pattern#2(arrangement along the 50 K temperature difference line)can reduce coolant consumption by half while achieves the same cooling effect as original film hole arrangement.Additionally,Hole pattern#2 reduces the temperature difference between the suction and pressure sides of the vane,effectively protecting the structural strength.At mass flow ratio is 6.23%,Hole pattern#2 achieves both good cooling effectiveness and relatively saves coolant consumption,offering the highest costeffectiveness.The modulation in the position of film holes results in different local pressures affecting the flow inside the cooling chamber.The coupling of internal and external flows leads to different vortex structures near the outlet of the film holes,thereby influencing the film effectiveness.Hole pattern#2 does not exhibit significant high-cooling regions,but it shows a more uniform distribution of overall cooling effectiveness.Therefore,optimizing the arrangement of film holes and spacing them along the temperature difference is considered a crucial technical means to enhance the efficiency of gas turbines. 展开更多
关键词 film cooling Turbineguidevane film hole layout Temperaturedifference CASCADE Wind tunnel experiment
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Solution for Environmentally Friendly Silver Surface Magnetron Sputtering Color Titanium Film Layer Technology
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作者 Huan Zhu Krisada Daoruang Chalisa Apiwathnasorn 《Journal of Environmental & Earth Sciences》 2025年第1期562-572,共11页
Silver is an elegant white precious metal,but it is easily oxidized by O3,SO2,and H2S in the air,turning yellow or dark,which affects its decorative effect.The existing silver coating,primarily prepared through the el... Silver is an elegant white precious metal,but it is easily oxidized by O3,SO2,and H2S in the air,turning yellow or dark,which affects its decorative effect.The existing silver coating,primarily prepared through the electroplating process,poses serious environmental pollution problems.It is necessary to seek new,green,and environmentally friendly coating processes while also enhancing the color palette of silver jewelry coatings.Titanium film layers were deposited on Ag925 and Ag999 surfaces using magnetron sputtering coating technology.The effects of sputtering time,substrate surface state,reaction gas type and time,and film thickness on the color of the film layers were studied,and the anti discoloration performance of the obtained film layers under the optimal process was tested.The experimental results show that when the sputtering time varies from 5 to 10 minutes,injecting argon,oxygen,and nitrogen into the coating chamber yields rich colors such as purple with a red tint,blue,yellow green,yellowish purple,and blue purple.The precise control of gas injection time has a significant impact on the color of the film layer.In terms of anti tarnish performance,the film showed good stability in the artificial sweat immersion test.From an environmental perspective,the magnetron sputtering titanium film process has no harmful gas or liquid emissions,which aligns with the sustainable development trend of the jewelry industry and holds great promise for application.This study has improved the visual effect and practical performance of the product,providing important theoretical basis and experimental data support for the application of environmentally friendly silver surface vacuum magnetron sputtering titanium thin film coating technology. 展开更多
关键词 Environmental Protection Magnetron Sputtering SILVER Colored film Titanium film Layer
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Enhancement of Ising Superconductivity in Pb_(1-x)Bi_(x) Ultrathin Films
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作者 Yitong Gu Kun Xie +9 位作者 Yingcai Qian Yuzhou Liu Siyu Huo Yumin Xia Desheng Cai Wenhui Pang Gan Yu Haoen Chi Chuanying Xi Shengyong Qin 《Chinese Physics Letters》 2025年第5期176-187,共12页
Ising superconductivity has garnered much attention in recent years due to its extremely high in-plane upper critical field (B_(c2)).Here,we fabricated 14 multilayer Pb_(1-x)Bi_(x) (0%≤x≤40%) thin films on Si (111)-... Ising superconductivity has garnered much attention in recent years due to its extremely high in-plane upper critical field (B_(c2)).Here,we fabricated 14 multilayer Pb_(1-x)Bi_(x) (0%≤x≤40%) thin films on Si (111)-7×7 reconstructed surface by molecular beam epitaxy.Large B_(c2) beyond the Pauli limit is observed in all the Pb_(1-x)Bi_(x) films,indicating that they may exhibit characteristics of Ising superconductivity.Moreover,the introduction of Bi doping can significantly enhance and effectively tune the in-plane B_(c2) of Pb_(1-x)Bi_(x) films,which will help us better understand Ising superconductivity and provide a new platform for the development of tunable Ising superconductors. 展开更多
关键词 plane upper critical field molecular beam epitaxylarge ising superconductivitymoreoverthe ising superconductivity ultrathin films Pb xBix bi doping thin films
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The Effect of Carrier Doping and Thickness on the Electronic Structures of La_(3)Ni_(2)O_(7)Thin Films
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作者 Haoliang Shi Zihao Huo +4 位作者 Guanlin Li Hao Ma Tian Cui Daoxin Yao Defang Duan 《Chinese Physics Letters》 2025年第8期201-229,共29页
The discovery of high-temperature superconductivity in bilayer nickelate La_(3)Ni_(2)O_(7)under high-pressure conditions has spurred extensive efforts to stabilize superconductivity at ambient pressure.Recently,the re... The discovery of high-temperature superconductivity in bilayer nickelate La_(3)Ni_(2)O_(7)under high-pressure conditions has spurred extensive efforts to stabilize superconductivity at ambient pressure.Recently,the realization of superconductivity in compressively strained La_(3)Ni_(2)O_(7)thin films grown on the SrLaAlO_(4)substrates,with a T_(c)exceeding 40 K,represents a significant step toward this goal.Here,we investigate the influence of film thickness and carrier doping on the electronic structure of La_(3)Ni_(2)O_(7)thin films,ranging from 0.5 to 3 unit cells,using first-principles calculations.For a 2 unit-cell film with an optimal doping concentration of 0.3 hole per formula unit(0.15 hole/Ni),the Ni-d_(z^(2))interlayer bonding state crosses the Fermi level,resulting in the formation ofγpockets at the Fermi surface.These findings align with angle-resolved photoemission spectroscopy experimental data.Our results provide theoretical validation for the recent experimental discovery of ambient-pressure superconductivity in La_(3)Ni_(2)O_(7)thin films and underscore the significant impact of film thickness and carrier doping on electronic property modulation. 展开更多
关键词 bilayer nickelate film thickness electronic structure l electronic structure la ni o thin films carrier doping stabilize superconductivity SUPERCONDUCTIVITY
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Poly(lactic acid)/Poly(butylene adipate-co-terephthalate)films with simultaneous high oxygen barrier and fast degradation properties 被引量:1
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作者 Mengjing Yang Yuxi Mao +4 位作者 Penghui Zhang Jie Li Zeming Tong Zhenguo Liu Yanhui Chen 《Green Energy & Environment》 SCIE EI CAS 2025年第1期1-10,共10页
Although poly(lactic acid)(PLA)is a good environmentally-friendly bio-degradable polymer which is used to substitute traditional petrochemical-based polymer packaging films,the barrier properties of PLA films are stil... Although poly(lactic acid)(PLA)is a good environmentally-friendly bio-degradable polymer which is used to substitute traditional petrochemical-based polymer packaging films,the barrier properties of PLA films are still insufficient for high-barrier packaging applications.In this study,oxygen scavenger hydroxyl-terminated polybutadiene(HTPB)and cobalt salt catalyst were incorporated into the PLA/poly(butylene adipate-co-terephthalate)(PLA/PBAT),followed by melting extrusion and three-layer co-extrusion blown film process to prepare the composite films.The oxygen permeability coefficient of the composite film combined with 6 wt%oxygen scavenger and 0.4 wt%catalyst was decreased significantly from 377.00 cc·mil·m^(-2)·day^(-1)·0.1 MPa^(-1) to 0.98 cc·mil·m^(-2)·day^(-1)·0.1 MPa^(-1),showing a remarkable enhancement of 384.69 times compared with the PLA/PBAT composite film.Meanwhile,the degradation behavior of the composite film was also accelerated,exhibiting a mass loss of nearly 60%of the original mass after seven days of degradation in an alkaline environment,whereas PLA/PBAT composite film only showed a mass loss of 32%.This work has successfully prepared PLA/PBAT composite films with simultaneously improved oxygen barrier property and degradation behavior,which has great potential for high-demanding green chemistry packaging industries,including food,agricultural,and military packaging. 展开更多
关键词 Barrier property Oxygen scavenging Blow molding Eco-packaging Degradable composite film
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Film thickness effect on 2D lead-free hybrid double perovskite properties: Band gap, photocurrent and stability 被引量:2
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作者 Mohamed Saber Lassoued Faizan Ahmad Yanzhen Zheng 《Chinese Chemical Letters》 2025年第4期449-454,共6页
Lead-free hybrid double perovskites(LFHDPs) have received a lot of attention due to their environmental friendliness and promising attributes. However, studying the effect of film thickness on LFHDPs optoelectronic pr... Lead-free hybrid double perovskites(LFHDPs) have received a lot of attention due to their environmental friendliness and promising attributes. However, studying the effect of film thickness on LFHDPs optoelectronic properties has not yet been investigated. Herein, we synthesized two new Ruddlesden–Popper LFHDPs, namely(C_(5)H_(12)N)_(4)AgBiI_(8)(CAB-1) and(C_(6)H_(14)N)_(4)Ag Bi I8(CAB-2) using cyclopentylamine and cyclohexylamine as monoamine ligands. Indeed, these two Ag(Ⅰ)-Bi(Ⅲ) LFHDPs form smooth and uniform films ranging in thickness from 250 nm to 1 μm, with preferred orientations. Notably, the studies on the optical properties showed that the direct band gap value decreased from 2.17 e V to 1.91 e V for CAB-1 and from 2.05 e V to 1.86 e V for CAB-2 with increasing thickness. Accordingly, photo-current response using a xenon lamp revealed a significant difference of over 1000 n A between light and dark conditions for1 μm-thickness films, suggesting potential for light harvesting. Other than that, thicker films of CAB-1and CAB-2 exhibit high stability for 90 days in a relatively humid environment(RH of 55%), paving the way for promising optoelectronic applications. 展开更多
关键词 LEAD-FREE Double perovskites film thickness Photocurrent response High stability
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Enhancing carbon sequestration and greenhouse gas mitigation in semiarid farmland:The promising role of biochar application with biodegradable film mulching 被引量:2
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作者 Jinwen Pang Zhonghong Tian +9 位作者 Mengjie Zhang Yuhao Wang Tianxiang Qi Qilin Zhang Enke Liu Weijun Zhang Xiaolong Ren Zhikuan Jia Kadambot H.M.Siddique Peng Zhang 《Journal of Integrative Agriculture》 2025年第2期517-535,共19页
Long-term mulching has improved crop yields and farmland productivity in semiarid areas,but it has also increased greenhouse gas(GHG)emissions and depleted soil fertility.Biochar application has emerged as a promising... Long-term mulching has improved crop yields and farmland productivity in semiarid areas,but it has also increased greenhouse gas(GHG)emissions and depleted soil fertility.Biochar application has emerged as a promising solution for addressing these issues.In this study,we investigated the effects of four biochar application rates(no biochar(N)=0 t ha^(-1),low(L)=3 t ha^(-1),medium(M)=6 t ha^(-1),and high(H)=9 t ha^(-1))under film mulching and no mulching conditions over three growing seasons.We assessed the impacts on GHG emissions,soil organic carbon sequestration(SOCS),and maize yield to evaluate the productivity and sustainability of farmland ecosystems.Our results demonstrated that mulching increased maize yield(18.68-41.80%),total fixed C in straw(23.64%),grain(28.87%),and root(46.31%)biomass,and GHG emissions(CO_(2),10.78%;N_(2)O,3.41%),while reducing SOCS(6.57%)and GHG intensity(GHGI;13.61%).Under mulching,biochar application significantly increased maize yield(10.20%),total fixed C in straw(17.97%),grain(17.69%)and root(16.75%)biomass,and SOCS(4.78%).Moreover,it reduced the GHG emissions(CO_(2),3.09%;N_(2)O,6.36%)and GHGI(12.28%).These effects correlated with the biochar addition rate,with the optimal rate being 9.0 t ha^(-1).In conclusion,biochar application reduces CO_(2) and N_(2)O emissions,enhances CH_(4) absorption,and improves maize yield under film mulching.It also improves the soil carbon fixation capacity while mitigating the warming potential,making it a promising sustainable management method for mulched farmland in semiarid areas. 展开更多
关键词 BIOCHAR film mulching greenhouse gas emissions carbon sequestration
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Combining slow-release fertilizer and plastic film mulching reduced the carbon footprint and enhanced maize yield on the Loess Plateau 被引量:2
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作者 Xiaoqing Han Pengfei Dang +12 位作者 Lechen Liao Fangqi Song Miaomiao Zhang Maoxue Zhang Guoqing Li Shuyue Wen Ning Yang Xiping Pan Xiaofan Wang WenWang Xiaoliang Qin Charles O.Joseph Kadambot H.M.Siddique 《Journal of Environmental Sciences》 2025年第1期359-369,共11页
Agricultural practices significantly contribute to greenhouse gas(GHG)emissions,necessitating cleaner production technologies to reduce environmental pressure and achieve sustainable maize production.Plastic film mulc... Agricultural practices significantly contribute to greenhouse gas(GHG)emissions,necessitating cleaner production technologies to reduce environmental pressure and achieve sustainable maize production.Plastic film mulching is commonly used in the Loess Plateau region.Incorporating slow-release fertilizers as a replacement for urea within this practice can reduce nitrogen losses and enhance crop productivity.Combining these techniques represents a novel agricultural approach in semi-arid areas.However,the impact of this integration on soil carbon storage(SOCS),carbon footprint(CF),and economic benefits has received limited research attention.Therefore,we conducted an eight-year study(2015-2022)in the semi-arid northwestern region to quantify the effects of four treatments[urea supplied without plastic film mulching(CK-U),slow-release fertilizer supplied without plastic film mulching(CK-S),urea supplied with plastic film mulching(PM-U),and slow-release fertilizer supplied with plastic film mulching(PM-S)]on soil fertility,economic and environmental benefits.The results revealed that nitrogen fertilizer was the primary contributor to total GHG emissions(≥71.97%).Compared to other treatments,PM-S increased average grain yield by 12.01%-37.89%,water use efficiency by 9.19%-23.33%,nitrogen accumulation by 27.07%-66.19%,and net return by 6.21%-29.57%.Furthermore,PM-S decreased CF by 12.87%-44.31%and CF per net return by 14.25%-41.16%.After eight years,PM-S increased SOCS(0-40 cm)by 2.46%,while PM-U decreased it by 7.09%.These findings highlight the positive effects of PM-S on surface soil fertility,economic gains,and environmental benefits in spring maize production on the Loess Plateau,underscoring its potential for widespread adoption and application. 展开更多
关键词 Plastic film mulching Slow-release fertilizer Maize grain yield Carbon footprint Economic benefits
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