To comprehensively utilize the valuable geological map,exploration profile,borehole,and geochemical logging data and the knowledge on the formation of the Jinshan Ag-Au deposit for forecasting the exploration targets ...To comprehensively utilize the valuable geological map,exploration profile,borehole,and geochemical logging data and the knowledge on the formation of the Jinshan Ag-Au deposit for forecasting the exploration targets of concealed ore bodies,three-dimensional Mineral Prospectivity Modeling(MPM)of the deposit has been conducted using the weights-of-evidence(WofE)method.Conditional independence between evidence layers was tested,and the outline results using the prediction-volume(P-V)and Student's t-statistic methods for delineating favorable mineralization areas from continuous posterior probability map were critically compared.Four exploration targets delineated ultimately by the Student's t-statistic method for the discovery of minable ore bodies in each of the target areas were discussed in detail.The main conclusions include:(1)three-dimensional modeling of a deposit using multi-source reconnaissance data is useful for MPM in interpreting their relationships with known ore bodies;(2)WofE modeling can be used as a straightforward tool for integrating deposit model and reconnaissance data in MPM;(3)the Student's t-statistic method is more applicable in binarizing the continuous prospectivity map for exploration targeting than the PV approach;and(4)two target areas within high potential to find undiscovered ore bodies were diagnosed to guide future near-mine exploration activities of the Jinshan deposit.展开更多
The lower member of Dalazi Formation is an important oil reservoir in the Songjiang Basin.Based on the research on its field-measured geological profiles,lithological combination characteristics and grain size distrib...The lower member of Dalazi Formation is an important oil reservoir in the Songjiang Basin.Based on the research on its field-measured geological profiles,lithological combination characteristics and grain size distribution characteristics,combined with the analysis of the spatial distribution characteristics,sedimentary structural characteristics and hydrodynamic conditions of the sediments in this member,nine sedimentary microfacies of the fan delta plain subfacies,fan delta front subfacies and littoral-shallow lacustrine subfacies have been identified.The study reveals that lower member of Dalazi Formation in the research area follows a fan delta–shallow lacustrine depositional model in the steep slope zone of a rift lake basin.The sediments primarily originate from the Pre-Mesozoic strata in the steep southeastern and eastern margins.The basin center migrated from the early Xiaoshahe area to the Yangmucun–Shenglicun area,and the sedimentary system gradually transitioned from fan delta to littoral-shallow lacustrine facies.展开更多
The black shales of Wufeng and Longmaxi Formation(Late Ordovician-Early Silurian period)in Sichuan Basin are the main strata for marine shale gas exploration,which have a yearly shale gas production of 228×10^(8)...The black shales of Wufeng and Longmaxi Formation(Late Ordovician-Early Silurian period)in Sichuan Basin are the main strata for marine shale gas exploration,which have a yearly shale gas production of 228×10^(8)m^(3)and cumulative shale gas production of 919×10^(8)m^(3).According to the lithological and biological features,filling sequences,sedimentary structures and lab analysis,the authors divided the Wufeng/Guanyinqiao and Longmaxi Formations into shore,tidal flat,shoal,shallow water shelf and deep water shelf facies,and confirmed that a shallow water deposition between the two sets of shales.Although both Formations contain similar shales,their formation mechanisms differ.During the deposition of Wufeng shale,influenced by the Caledonian Movement,the Central Sichuan and Guizhou Uplifts led to the transformation of the Sichuan Basin into a back-bulge basin.Coinstantaneous volcanic activity provided significant nutrients,contributing to the deposition of Wufeng Formation black shales.In contrast,during the deposition of Longmaxi shale,collisions caused basement subsidence,melting glaciers raised sea levels,and renewed volcanic activity provided additional nutrients,leading to Longmaxi Formation black shale accumulation.Considering the basic sedimentary geology and shale gas characteristics,areas such as Suijiang-Leibo-Daguan,Luzhou-Zigong,Weirong-Yongchuan,and Nanchuan-Dingshan are identified as key prospects for future shale gas exploration in the Wufeng-Longmaxi Formations.展开更多
Lunar dust is considered to be one of the top challenges for enabling humans to have extended stays on the moon.Human activities such as module landings and launches,walking,rover operation and construction activities...Lunar dust is considered to be one of the top challenges for enabling humans to have extended stays on the moon.Human activities such as module landings and launches,walking,rover operation and construction activities will inevitably produce a significant amount of dust.Therefore,it is important to estimate the potential range and intensity of dust deposition caused by these activities to minimize dust accumulation over time and for maintenance planning and execution.A modular model that correlates the dust deposition distribution with initial mean dust particle velocity,its mean ejected angle and the total amount of ejected mass is developed for an elementary mechanical movement.This modular model is further employed to form a modeling framework to estimate dust deposition of a trajectory based activity of similar repeated movements such as the landing process of a lander,walking and rover operation.The model forms a unified modeling framework for different trajectory-based activities and is shown to predict consistent and physically meaningful ranges and intensities of dust deposition provided reliable data to calibrate the model parameters.展开更多
Based on analyzing the influences of a slicing scheme on stair-stepping effect, supporting structure, efficiency and deformation, etc. , analytical hierarchical process （AHP） combining with fuzzy synthetic evaluatio...Based on analyzing the influences of a slicing scheme on stair-stepping effect, supporting structure, efficiency and deformation, etc. , analytical hierarchical process （AHP） combining with fuzzy synthetic evaluation is introduced to make decision in slicing schemes for a processing part. The application in determining the slicing scheme for a computer mouse during prototyping shows that the method increases the rationality during decision- making and improves quality and efficiency for the prototyping part.展开更多
Three-dimensional geochemical modeling of ore-forming elements is crucial for predicting deep mineralization.This approach provides key information for the quantitative prediction of deep mineral localization,three-di...Three-dimensional geochemical modeling of ore-forming elements is crucial for predicting deep mineralization.This approach provides key information for the quantitative prediction of deep mineral localization,three-dimensional fine interpolation,analysis of spatial distribution patterns,and extraction of quantitative mineral-seeking markers.The Yechangping molybdenum(Mo)deposit is a significant and extensive porphyry-skarn deposit in the East Qinling-Dabie Mo polymetallic metallogenic belt at the southern margin of the North China Block.Abundant borehole data on oreforming elements underpin deep geochemical predictions.The methodology includes the following steps:(1)Threedimensional geological modeling of the deposit was established.(2)Correlation,cluster,and factor analyses post delineation of mineralization stages and determination of mineral generation sequence to identify(Cu,Pb,Zn,Ag)and(Mo,W,mfe)assemblages.(3)A three-dimensional geochemical block model was constructed for Mo,W,mfe,Cu,Zn,Pb,and Ag using the ordinary kriging method,and the variational function was developed.(4)Spatial distribution and enrichment characteristics analysis of ore-forming elements are performed to extract geological information,employing the variogram and w(Cu+Pb+Zn+Ag)/w(Mo+W)as predictive indicators.(5)Identifying the western,northwestern,and southwestern areas of the mine with limited mineralization potential,contrasted by the northeastern and southeastern areas favorable for mineral exploration.展开更多
The giant Upper Yangtze Pb-Zn metallogenic province,also known as the Sichuan-Yunnan-Guizhou(SYG)Pb-Zn province hosting>500 carbonate-hosted epigenetic Pb-Zn deposits that contain>20 Mt Pb+Zn base metal reserves...The giant Upper Yangtze Pb-Zn metallogenic province,also known as the Sichuan-Yunnan-Guizhou(SYG)Pb-Zn province hosting>500 carbonate-hosted epigenetic Pb-Zn deposits that contain>20 Mt Pb+Zn base metal reserves.The giant Maoping Pb-Zn deposit is the second largest deposit in this province and owns>5 Mt Pb+Zn metal reserves with ore grades of 12 wt.%-30 wt.%Pb+Zn.Such large tonnages and high grades make it among the top 100 similar mineral deposits in the world.The ore bodies are predominantly located within the strata of the Upper Devonian(Zaige Formation)and Lower(Baizuo Formation)-Upper(Weining Formation)Carboniferous.The principal ore minerals consist of galena(Gn),sphalerite(Sp),and pyrite(Py),while the primary gangue minerals include dolomite(Dol),calcite(Cal),and quartz(Qtz).Three mineralization stages of carbonate minerals have been identified:(1)pre-sulfide stage 1,(2)syn-sulfide stage 2,and(3)post-sulfide stage 3.Trace elements and C-O-Sr isotopes of three stages’carbonate minerals,together with S-Pb isotopes of sulfides,revealing that the metamorphic basement rocks played the role of the metal source during the early stage of Pb-Zn mineralization,whereas the metal contribution of the sedimentary wall rocks found to be more prominent during the late stage of Pb-Zn mineralization.In addition,the dissolution of marine carbonate rocks and CO_(2)degassing may have also played an important role in the formation of the Maoping deposit.Furthermore,syn-sulfide stage 2 calcite has a U-Pb age of 214±20 Ma obtained by LA-ICPMS in-situ analyses,suggesting that the hydrothermal mineralization occurred during the Triassic.Our study proposes a new coupled metallogenic model of fluid-structure-lithology assemblage and provides new insights about the formation and evolution of the Maoping deposit with significant implication for understanding and exploration of similar Pb-Zn deposits worldwide.展开更多
The use of additive manufacturing techniques in the development of unconventional materials can help reduce the environmental impact of traditional construction materials.In this paper,the properties of a 3D-printed b...The use of additive manufacturing techniques in the development of unconventional materials can help reduce the environmental impact of traditional construction materials.In this paper,the properties of a 3D-printed biocomposite were evaluated.Biofilaments obtained by mixing pulverized bamboo fibers with polylactic acid(PLA)resin were extruded during the manufacturing process.To assess the effect of incorporating plant fibers,an analysis was conducted on the morphology,elemental chemical composition,crystallinity index,principal functional groups,thermal stability,surface roughness,microhardness,density,tensile strength,elastic modulus,and strain percentage of reinforced samples.The results were comparedwith those obtained from the characterization of standard PLAfilaments(unreinforced).The fused deposition modeling(FDM)technique was employed to print biocomposite specimens.Additionally,the influence of the printing parameters(infill density,build orientation,and layer thickness)on the physical,tribological,andmechanical properties of the biocomposites was analyzed.These results were compared with those obtained for specimens printed with pure PLA.The findings indicate that incorporating 10%vegetable filler into PLA filaments enhanced the strength and stiffness of the biocomposite under axial loads.Finally,the strength of the biocomposite subjected to axial loads was compared with the standardized values for wood-plastic composites,demonstrating the feasibility of its use for non-structural purposes in civil construction.展开更多
Controversy is ongoing regarding the relationship between ore formation and the structural evolution of the Hadamengou gold deposit.To address this issue,we conducted a comprehensive investigation of mineralization-re...Controversy is ongoing regarding the relationship between ore formation and the structural evolution of the Hadamengou gold deposit.To address this issue,we conducted a comprehensive investigation of mineralization-related structures,geochronology and Fe isotopes.From the perspective of spatial evolution,hydrothermal fluids originating from the Shadegai and Xishadegai plutons have extracted accumulated ore-forming elements from the Wulashan Group(Ar2WL)and then evolved,initiating at Exploration Line 11 and migrating eastwards and westwards along the EW-trending thrust fault system to form orebodies.From the temporal evolution standpoint,the Wulashan Group(Ar_(2)WL)experienced diagenesis(2591.00 Ma to 2204.00 Ma)and metamorphism(2074.00 Ma to 1625.00 Ma)from late Neoarchean to early Paleoproterozoic,when ore-forming materials were initially accumulated;in the early Paleozoic(440.71 Ma to 425.00 Ma),the collision led to the formation of early-stage EW-trending imbricated thrust faults,which established a fundamental structural framework for the orefield and further accumulated ore-forming materials;from the late Paleozoic to the Mesozoic,multiple subsequent episodes of regional tectonic-magmatic-hydrothermal events have superimposed,modified and reactivated the thrust fault system.Notably,the Triassic period,particularly between 245.00 Ma and 217.90 Ma,is considered to be a primary ore-forming stage.In summary,the intricate relationship between ore-formation and structural evolution has been fundamentally elucidated.展开更多
The heteroepitaxy of diamond films has received widespread attention;however,its application remains limited owing to the mismatch in properties and structure between diamond and heterogeneous substrates.In this study...The heteroepitaxy of diamond films has received widespread attention;however,its application remains limited owing to the mismatch in properties and structure between diamond and heterogeneous substrates.In this study,diamond films were successfully synthesized on high-entropy alloys(HEAs)substrates using microwave plasma chemical vapor deposition.The resulting diamond films were continuous,uniform,and adhered to the HEAs substrates.The mixed carbides were identified using X-ray diffraction,and the quality of the diamond films was examined using Raman spectroscopy.Moreover,the corrosion test revealed that the diamond/TiZrHfMo samples had excellent electrochemical stability and corrosion resistance with a corrosion potential value of-0.169 V in a 3.5wt%NaCl solution.A multiple regression model was established to evaluate the effects of the structure and growth parameters,which confirmed that the mixing entropy significantly affected the grain size and corrosion properties.展开更多
Additive manufacturing(AM),particularly fused deposition modeling(FDM),has emerged as a transformative technology in modern manufacturing processes.The dimensional accuracy of FDM-printed parts is crucial for ensuring...Additive manufacturing(AM),particularly fused deposition modeling(FDM),has emerged as a transformative technology in modern manufacturing processes.The dimensional accuracy of FDM-printed parts is crucial for ensuring their functional integrity and performance.To achieve sustainable manufacturing in FDM,it is necessary to optimize the print quality and time efficiency concurrently.However,owing to the complex interactions of printing parameters,achieving a balanced optimization of both remains challenging.This study examines four key factors affecting dimensional accuracy and print time:printing speed,layer thickness,nozzle temperature,and bed temperature.Fifty parameter sets were generated using enhanced Latin hypercube sampling.A whale optimization algorithm(WOA)-enhanced support vector regression(SVR)model was developed to predict dimen-sional errors and print time effectively,with non-dominated sorting genetic algorithm Ⅲ(NSGA-Ⅲ)utilized for multi-objective optimization.The technique for Order Preference by Similarity to Ideal Solution(TOPSIS)was applied to select a balanced solution from the Pareto front.In experimental validation,the parts printed using the optimized parameters exhibited excellent dimensional accuracy and printing efficiency.This study comprehensively considered optimizing the printing time and size to meet quality requirements while achieving higher printing efficiency and aiding in the realization of sustainable manufacturing in the field of AM.In addition,the printing of a specific prosthetic component was used as a case study,highlighting the high demands on both dimensional precision and printing efficiency.The optimized process parameters required significantly less printing time,while satisfying the dimensional accuracy requirements.This study provides valuable insights for achieving sustainable AM using FDM.展开更多
Recent advances in hydrocarbon exploration have been made in the Member Deng-2 marginal microbial mound-bank complex reservoirs of the Dengying Formation in the western Sichuan Basin, SW China,where the depositional p...Recent advances in hydrocarbon exploration have been made in the Member Deng-2 marginal microbial mound-bank complex reservoirs of the Dengying Formation in the western Sichuan Basin, SW China,where the depositional process is regarded confusing. The microfacies, construction types, and depositional model of the Member Deng-2 marginal microbial mound-bank complex have been investigated using unmanned aerial vehicle photography, outcrop section investigation, thin section identification,and seismic reflections in the southwestern Sichuan Basin. The microbialite lithologic textures in this region include thrombolite, dendrolite, stromatolite, fenestral stromatolite, spongiostromata stone,oncolite, aggregated grainstone, and botryoidal grapestone. Based on the comprehensive analysis of“depositional fabrics-lithology-microfacies”, an association between a fore mound, mound framework,and back mound subfacies has been proposed based on water depth, current direction, energy level and lithologic assemblages. The microfacies of the mound base, mound core, mound flank, mound cap, and mound flat could be recognized among the mound framework subfacies. Two construction types of marginal microbial mound-bank complex have been determined based on deposition location, mound scale, migration direction, and sedimentary facies association. Type Jinkouhe microbial mound constructions(TJMMCs) develop along the windward margin owing to their proximity to the seaward subfacies fore mound, with a northeastwardly migrated microbial mound on top of the mud mound,exhibiting the characteristics of large-sized mounds and small-sized banks in the surrounding area. Type E'bian microbial mound constructions(TEMMCs) primarily occur on the leeward margin, resulting from the presence of onshore back mound subfacies, with the smaller southwestward migrated microbial mounds existing on a thicker microbial flat. The platform margin microbial mound depositional model can be correlated with certain lateral comparison profile and seismic reflection structures in the 2D seismic section, which can provide references for future worldwide exploration. Microbial mounds with larger buildups and thicker vertical reservoirs are typically targeted on the windward margin, while small-sized microbial mounds and flats with better lateral connections are typically focused on the leeward margin.展开更多
The deltas serve as the primary interactive zone where terrestrial and marine environments converge,playing a pivotal role in the coastal deposition.In the Holocene,climate changes and sea level fluctuation are the pr...The deltas serve as the primary interactive zone where terrestrial and marine environments converge,playing a pivotal role in the coastal deposition.In the Holocene,climate changes and sea level fluctuation are the principal driving factors in the evolution of deltas.However,human activities such as the construction of dams and reservoirs in the Anthropocene have significantly altered sediment transport in rivers,leading to depositional pattern variation during deltaic evolution.In this study,we have conducted a comparative analysis of the morphological variations(1986-2021)in the barrier system of the Hanjiang River Delta(HRD)using satellite remote sensing(SRS)method.Additionally,we have examined the lithological changes and facies alterations observed in eight boreholes on the present barrier spit.Our findings indicate that the intensification of anthropogenic activities led to a significant reduction in the sediment flux of the Hanjiang River(HR),resulting in depocenter landward migration at the estuary.SRS analysis reveals their periodical morphological characteristics and spatial variations of estuarine sandbars(1986-1992),barrier islands-lagoons(1993-2009),and barrier spits(2010-2021)during 1986 to 2021.The stratigraphy of boreholes demonstrates a south-to-north facies transition from lagoon to lagoon-barrier spit and barrier spit in vertical lithology.Therefore,the depositional evolution of the HRD barrier system is categorized into three phases:estuarine sandbar-barrier island phase(1986-1998);barrier island-lagoon phase(1999-2009);and barrier spit phase(2010-2021).During the estuarine sandbar-barrier island phase,fluvial processes played a predominate role in the deposition.Consequently,with a significant decrease in river sediment load,the dominant factors driving depositional processes shifted towards wave action and alongshore current.Based on the conceptual model in the Holocene,we propose a modified depositional model of wave-dominated deltas during Anthropocene that encompasses three evolutionary phases:estuarine sandbars and delta front platforms,barrier island-lagoon formation and landward migration of barrier spits.This pattern highlights that human-induced reduction in river sediment flux has led to a seaward deltaic progradation driven by barrier landward migration.展开更多
Three-dimensional porous poly-lactic acid(PLA) scaffold was fabricated using fused deposition modeling(FDM) method including 30%, 50% and 70% nominal porosity. Study of phases in initial polymeric material and printed...Three-dimensional porous poly-lactic acid(PLA) scaffold was fabricated using fused deposition modeling(FDM) method including 30%, 50% and 70% nominal porosity. Study of phases in initial polymeric material and printed scaffolds was done by X-ray diffraction(XRD), and no significant phase difference was observed due to the manufacturing process, and the poly-lactic acid retains its crystalline properties. The results of the mechanical properties evaluation by the compression test show that the mechanical properties of the scaffold have decreased significantly with increasing the porosity of scaffold. The microstructure of scaffolds were studied by scanning electron microscope(SEM), showing that the pores had a regular arrangement and their morphology changed with porosity change. The mechanical properties of the poly-lactic acid scaffolds printed using fused deposition modeling, can be adapted to the surrounding tissue, by porosity change.展开更多
The current acid deposition critical loads in Guangdong, China were calculated using the PROFILE model with a 3 km × 3 km resolution. Calculations were carded out for critical loads of potential acidity, actual a...The current acid deposition critical loads in Guangdong, China were calculated using the PROFILE model with a 3 km × 3 km resolution. Calculations were carded out for critical loads of potential acidity, actual acidity, sulfur and nitrogen, with values in extents of 0-3.5, 0-14.0, 0-26.0 and 0-3.5 kmol/（hrnE.year）, respectively. These values were comparable to previously reported results and reflected the influences of vegetation and soil characteristics on the soil acid buffering capacity. Simulations of SO2 emission and sulfur deposition in this study showed that sulfur deposition core areas mirrored SO2 emission centers. The prediction of sulfur deposition after 20% and 40% reduction of SO2 emission suggested that the reduction of area sources contributed greatly to the decrease of sulfur deposition. Thus, abatement of area source emissions could be the primary way to mitigate sulfur deposition in Guangdong to meet both the provincial and national regulations of air pollution control.展开更多
Based on the element geochemistry and biomarkers of the oil shale from the Chang 7 sub-unit in the southern Ordos Basin,the depositional conditions and organic source of the oil shale are discussed.Biomarkers analyses...Based on the element geochemistry and biomarkers of the oil shale from the Chang 7 sub-unit in the southern Ordos Basin,the depositional conditions and organic source of the oil shale are discussed.Biomarkers analyses show that the oil shale has a homologous organic matter source,with a mix of plankton and advanced plants.U/Th and V/Ni ratios suggest that the redox condition is dominated by a reducing condition,and the degree of anoxia in the Tongchuan area is higher than that of the Xunyi area.Sr/Ba ratios illustrate that the oil shale is deposited in fresh water and the paleosalinity in the Tongchuan area is slightly higher.Fe/Ti ratios imply that the Tongchuan area underwent obvious hydrothermal fluid activities.Sr/Cu ratios show warm and humid paleoclimate in both areas.As assessed by(La/Yb)NASC,the deposition rate in the Tongchuan area is relatively lower.Fe/Co and Th/U ratios suggest that the paleo-water-depth in the Tongchuan area is deeper.The source rock could have the advance plants source,which must have close relationship with the Qinling orogeny.Comparing the paleoenvironment,the Tongchuan area has better depositional conditions,and is the key oil shale exploration area in the southern Ordos Basin.展开更多
Ideal tissue engineering scaffolds need interconnected pores and high porosity to enable cell survival,migration,proliferation,and differentiation.However,obtaining a high-resolution structure is difficult with tradit...Ideal tissue engineering scaffolds need interconnected pores and high porosity to enable cell survival,migration,proliferation,and differentiation.However,obtaining a high-resolution structure is difficult with traditional one-temperature control fused deposition modeling(FDM).In this study,we propose a dual-temperature control method to improve printability.A numerical model is developed in which the viscosity is a function of temperature and shear rate to study the influence of two different temperature control modes.Quantitative tests are used to assess filament formation and shape fidelity,including one-dimensional filament printing,deposition at corners,fusion,and collapse.By using dual-temperature control,the width of the deposited poly(ε-caprolactone)filament is reduced to 50μm.The comparative results of both the experimental method and numerical simulation suggest that the dual-temperature control FDM can manufacture spatially arranged constructs and presents a promising application in tissue engineering。展开更多
Biodegradable polymers are highly attractive as potential alternatives to petroleum-based polymers in an attempt to achieve carbon neutrality whilst maintaining the mechanical properties of the structures.Among these ...Biodegradable polymers are highly attractive as potential alternatives to petroleum-based polymers in an attempt to achieve carbon neutrality whilst maintaining the mechanical properties of the structures.Among these polymers,polylactic acid(PLA)is particularly promising due to its good mechanical properties,biocompatibility and thermoplasticity.In this work,we aim to enhance the mechanical properties of PLA using mechanically-defibrated cellulose nanofibers(CNFs)that exhibit remarkable mechanical properties and biodegradability.We also employ fused deposition modeling(FDM),one of the three-dimensional printing methods for thermoplastic polymers,for the low-cost fabrication of the products.Mechanically-defibrated CNF-reinforced PLA matrix composites are fabricated by FDM.Their tensile properties are investigated in two printing directions(0°/90°and+45°/-45°).The discussion about the relationship between printing direction and tensile behavoir of mechanically-defibrated CNF-reinforced PLA matrix composite is the unique point of this study.We further discuss the microstructure and fracture surface of mechanically-defibrated CNF-reinforced PLA matrix composite by scanning electron microscope.展开更多
The development of functional relationships between the observed deposition rate and the experimental conditions is an important step toward understanding and optimizing low-pressure chemical vapor deposition(LPCVD)or...The development of functional relationships between the observed deposition rate and the experimental conditions is an important step toward understanding and optimizing low-pressure chemical vapor deposition(LPCVD)or low-pressure chemical vapor infiltration(LPCVI).In the field of ceramic matrix composites(CMCs),methyltrichlorosilane(CH3 SiCl3,MTS)is the most widely used source gas system for SiC,because stoichiometric SiC deposit can be facilitated at 900°C–1300°C.However,the reliability and accuracy of existing numerical models for these processing conditions are rarely reported.In this study,a comprehensive transport model was coupled with gas-phase and surface kinetics.The resulting gas-phase kinetics was confirmed via the measured concentration of gaseous species.The relationship between deposition rate and 24 gaseous species has been effectively evaluated by combining the special superiority of the novel extreme machine learning method and the conventional sticking coefficient method.Surface kinetics were then proposed and shown to reproduce the experimental results.The proposed simulation strategy can be used for different material systems.展开更多
The paper discusses the mechanical and thermal performance manifested in natural nanorods attapulgite(ATP)reinforced Acrylonitrile butadiene styrene(ABS)nanocomposites in the process of fused deposition modeling(FDM)....The paper discusses the mechanical and thermal performance manifested in natural nanorods attapulgite(ATP)reinforced Acrylonitrile butadiene styrene(ABS)nanocomposites in the process of fused deposition modeling(FDM).Molten extrusion technique was taken to manufacture the filaments of ABS/organic-attapulgite(OAT)nanocomposites with different mass fraction and the printing operation was made by one commercial FDM three-dimensional(3D)printer.Results indicate that the mechanical performance of these FDM 3D printed specimens are improved obviously via the introduction of OAT,and tensile strength of the ABS/OAT nanocomposites parts with only 2 wt%OAT addition is enhanced by 48.1%.At the same time,the addition OAT can reduce the linear expansion coefficient and creep flexibility,and improve the thermal stability and dimensional accuracy of these FDM 3D printed parts.展开更多
基金financially supported by the Ministry of Science and Technology of China(Nos.2022YFF0801201,2021YFC2900300)the National Natural Science Foundation of China(Nos.41872245,U1911202)the Guangdong Basic and Applied Basic Research Foundation(No.2020A1515010666)。
文摘To comprehensively utilize the valuable geological map,exploration profile,borehole,and geochemical logging data and the knowledge on the formation of the Jinshan Ag-Au deposit for forecasting the exploration targets of concealed ore bodies,three-dimensional Mineral Prospectivity Modeling(MPM)of the deposit has been conducted using the weights-of-evidence(WofE)method.Conditional independence between evidence layers was tested,and the outline results using the prediction-volume(P-V)and Student's t-statistic methods for delineating favorable mineralization areas from continuous posterior probability map were critically compared.Four exploration targets delineated ultimately by the Student's t-statistic method for the discovery of minable ore bodies in each of the target areas were discussed in detail.The main conclusions include:(1)three-dimensional modeling of a deposit using multi-source reconnaissance data is useful for MPM in interpreting their relationships with known ore bodies;(2)WofE modeling can be used as a straightforward tool for integrating deposit model and reconnaissance data in MPM;(3)the Student's t-statistic method is more applicable in binarizing the continuous prospectivity map for exploration targeting than the PV approach;and(4)two target areas within high potential to find undiscovered ore bodies were diagnosed to guide future near-mine exploration activities of the Jinshan deposit.
基金Supported by Jinchang City Level Science and Technology Plan Project(No.2023RC012).
文摘The lower member of Dalazi Formation is an important oil reservoir in the Songjiang Basin.Based on the research on its field-measured geological profiles,lithological combination characteristics and grain size distribution characteristics,combined with the analysis of the spatial distribution characteristics,sedimentary structural characteristics and hydrodynamic conditions of the sediments in this member,nine sedimentary microfacies of the fan delta plain subfacies,fan delta front subfacies and littoral-shallow lacustrine subfacies have been identified.The study reveals that lower member of Dalazi Formation in the research area follows a fan delta–shallow lacustrine depositional model in the steep slope zone of a rift lake basin.The sediments primarily originate from the Pre-Mesozoic strata in the steep southeastern and eastern margins.The basin center migrated from the early Xiaoshahe area to the Yangmucun–Shenglicun area,and the sedimentary system gradually transitioned from fan delta to littoral-shallow lacustrine facies.
基金supported by the project of the China Geological Survey(DD20221661).
文摘The black shales of Wufeng and Longmaxi Formation(Late Ordovician-Early Silurian period)in Sichuan Basin are the main strata for marine shale gas exploration,which have a yearly shale gas production of 228×10^(8)m^(3)and cumulative shale gas production of 919×10^(8)m^(3).According to the lithological and biological features,filling sequences,sedimentary structures and lab analysis,the authors divided the Wufeng/Guanyinqiao and Longmaxi Formations into shore,tidal flat,shoal,shallow water shelf and deep water shelf facies,and confirmed that a shallow water deposition between the two sets of shales.Although both Formations contain similar shales,their formation mechanisms differ.During the deposition of Wufeng shale,influenced by the Caledonian Movement,the Central Sichuan and Guizhou Uplifts led to the transformation of the Sichuan Basin into a back-bulge basin.Coinstantaneous volcanic activity provided significant nutrients,contributing to the deposition of Wufeng Formation black shales.In contrast,during the deposition of Longmaxi shale,collisions caused basement subsidence,melting glaciers raised sea levels,and renewed volcanic activity provided additional nutrients,leading to Longmaxi Formation black shale accumulation.Considering the basic sedimentary geology and shale gas characteristics,areas such as Suijiang-Leibo-Daguan,Luzhou-Zigong,Weirong-Yongchuan,and Nanchuan-Dingshan are identified as key prospects for future shale gas exploration in the Wufeng-Longmaxi Formations.
文摘Lunar dust is considered to be one of the top challenges for enabling humans to have extended stays on the moon.Human activities such as module landings and launches,walking,rover operation and construction activities will inevitably produce a significant amount of dust.Therefore,it is important to estimate the potential range and intensity of dust deposition caused by these activities to minimize dust accumulation over time and for maintenance planning and execution.A modular model that correlates the dust deposition distribution with initial mean dust particle velocity,its mean ejected angle and the total amount of ejected mass is developed for an elementary mechanical movement.This modular model is further employed to form a modeling framework to estimate dust deposition of a trajectory based activity of similar repeated movements such as the landing process of a lander,walking and rover operation.The model forms a unified modeling framework for different trajectory-based activities and is shown to predict consistent and physically meaningful ranges and intensities of dust deposition provided reliable data to calibrate the model parameters.
基金Supported by the Science and Technology Support Key Project of Jiangsu Province (DE2008365)~~
文摘Based on analyzing the influences of a slicing scheme on stair-stepping effect, supporting structure, efficiency and deformation, etc. , analytical hierarchical process （AHP） combining with fuzzy synthetic evaluation is introduced to make decision in slicing schemes for a processing part. The application in determining the slicing scheme for a computer mouse during prototyping shows that the method increases the rationality during decision- making and improves quality and efficiency for the prototyping part.
基金supported by the Key Research Project of China Geological Survey(Grant No.DD20230564)the Research Project of Natural Resources Department of Gansu Province(Grant No.202219)。
文摘Three-dimensional geochemical modeling of ore-forming elements is crucial for predicting deep mineralization.This approach provides key information for the quantitative prediction of deep mineral localization,three-dimensional fine interpolation,analysis of spatial distribution patterns,and extraction of quantitative mineral-seeking markers.The Yechangping molybdenum(Mo)deposit is a significant and extensive porphyry-skarn deposit in the East Qinling-Dabie Mo polymetallic metallogenic belt at the southern margin of the North China Block.Abundant borehole data on oreforming elements underpin deep geochemical predictions.The methodology includes the following steps:(1)Threedimensional geological modeling of the deposit was established.(2)Correlation,cluster,and factor analyses post delineation of mineralization stages and determination of mineral generation sequence to identify(Cu,Pb,Zn,Ag)and(Mo,W,mfe)assemblages.(3)A three-dimensional geochemical block model was constructed for Mo,W,mfe,Cu,Zn,Pb,and Ag using the ordinary kriging method,and the variational function was developed.(4)Spatial distribution and enrichment characteristics analysis of ore-forming elements are performed to extract geological information,employing the variogram and w(Cu+Pb+Zn+Ag)/w(Mo+W)as predictive indicators.(5)Identifying the western,northwestern,and southwestern areas of the mine with limited mineralization potential,contrasted by the northeastern and southeastern areas favorable for mineral exploration.
基金supported by the National Natural Science Foundation of China(41872095,U1812402 and 42172082)the Research Startup Project(YJRC4201804)of Yunnan University to J.-X.Zhou.
文摘The giant Upper Yangtze Pb-Zn metallogenic province,also known as the Sichuan-Yunnan-Guizhou(SYG)Pb-Zn province hosting>500 carbonate-hosted epigenetic Pb-Zn deposits that contain>20 Mt Pb+Zn base metal reserves.The giant Maoping Pb-Zn deposit is the second largest deposit in this province and owns>5 Mt Pb+Zn metal reserves with ore grades of 12 wt.%-30 wt.%Pb+Zn.Such large tonnages and high grades make it among the top 100 similar mineral deposits in the world.The ore bodies are predominantly located within the strata of the Upper Devonian(Zaige Formation)and Lower(Baizuo Formation)-Upper(Weining Formation)Carboniferous.The principal ore minerals consist of galena(Gn),sphalerite(Sp),and pyrite(Py),while the primary gangue minerals include dolomite(Dol),calcite(Cal),and quartz(Qtz).Three mineralization stages of carbonate minerals have been identified:(1)pre-sulfide stage 1,(2)syn-sulfide stage 2,and(3)post-sulfide stage 3.Trace elements and C-O-Sr isotopes of three stages’carbonate minerals,together with S-Pb isotopes of sulfides,revealing that the metamorphic basement rocks played the role of the metal source during the early stage of Pb-Zn mineralization,whereas the metal contribution of the sedimentary wall rocks found to be more prominent during the late stage of Pb-Zn mineralization.In addition,the dissolution of marine carbonate rocks and CO_(2)degassing may have also played an important role in the formation of the Maoping deposit.Furthermore,syn-sulfide stage 2 calcite has a U-Pb age of 214±20 Ma obtained by LA-ICPMS in-situ analyses,suggesting that the hydrothermal mineralization occurred during the Triassic.Our study proposes a new coupled metallogenic model of fluid-structure-lithology assemblage and provides new insights about the formation and evolution of the Maoping deposit with significant implication for understanding and exploration of similar Pb-Zn deposits worldwide.
基金a derivative product of the project INV-ING-3788 financed by the Vicerectory of Research of the Universidad Militar Nueva Granada,validity 2023.
文摘The use of additive manufacturing techniques in the development of unconventional materials can help reduce the environmental impact of traditional construction materials.In this paper,the properties of a 3D-printed biocomposite were evaluated.Biofilaments obtained by mixing pulverized bamboo fibers with polylactic acid(PLA)resin were extruded during the manufacturing process.To assess the effect of incorporating plant fibers,an analysis was conducted on the morphology,elemental chemical composition,crystallinity index,principal functional groups,thermal stability,surface roughness,microhardness,density,tensile strength,elastic modulus,and strain percentage of reinforced samples.The results were comparedwith those obtained from the characterization of standard PLAfilaments(unreinforced).The fused deposition modeling(FDM)technique was employed to print biocomposite specimens.Additionally,the influence of the printing parameters(infill density,build orientation,and layer thickness)on the physical,tribological,andmechanical properties of the biocomposites was analyzed.These results were compared with those obtained for specimens printed with pure PLA.The findings indicate that incorporating 10%vegetable filler into PLA filaments enhanced the strength and stiffness of the biocomposite under axial loads.Finally,the strength of the biocomposite subjected to axial loads was compared with the standardized values for wood-plastic composites,demonstrating the feasibility of its use for non-structural purposes in civil construction.
基金the financial support by the Major Research Plan of National Natural Science Foundation of China(92062219)the Young Elite Scientists Sponsorship Program by BAST(No.BYESS2023411)+2 种基金the Open Research Project from the State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences(GPMR202407)the Geological Survey Project of the China Geological Survey„General survey of Hadamengou Rock Gold Deposit in Inner Mongolia'(DD20191017)the Geological Survey Project(H90063).
文摘Controversy is ongoing regarding the relationship between ore formation and the structural evolution of the Hadamengou gold deposit.To address this issue,we conducted a comprehensive investigation of mineralization-related structures,geochronology and Fe isotopes.From the perspective of spatial evolution,hydrothermal fluids originating from the Shadegai and Xishadegai plutons have extracted accumulated ore-forming elements from the Wulashan Group(Ar2WL)and then evolved,initiating at Exploration Line 11 and migrating eastwards and westwards along the EW-trending thrust fault system to form orebodies.From the temporal evolution standpoint,the Wulashan Group(Ar_(2)WL)experienced diagenesis(2591.00 Ma to 2204.00 Ma)and metamorphism(2074.00 Ma to 1625.00 Ma)from late Neoarchean to early Paleoproterozoic,when ore-forming materials were initially accumulated;in the early Paleozoic(440.71 Ma to 425.00 Ma),the collision led to the formation of early-stage EW-trending imbricated thrust faults,which established a fundamental structural framework for the orefield and further accumulated ore-forming materials;from the late Paleozoic to the Mesozoic,multiple subsequent episodes of regional tectonic-magmatic-hydrothermal events have superimposed,modified and reactivated the thrust fault system.Notably,the Triassic period,particularly between 245.00 Ma and 217.90 Ma,is considered to be a primary ore-forming stage.In summary,the intricate relationship between ore-formation and structural evolution has been fundamentally elucidated.
基金financial support from the Shanxi Scholarship Council of China(No.2024-057)the Water Conservancy Science and Technology Research and Promotion Project of Shanxi Province,China(No.2025GM13)the National Natural Science Foundation of China(No.52571048).
文摘The heteroepitaxy of diamond films has received widespread attention;however,its application remains limited owing to the mismatch in properties and structure between diamond and heterogeneous substrates.In this study,diamond films were successfully synthesized on high-entropy alloys(HEAs)substrates using microwave plasma chemical vapor deposition.The resulting diamond films were continuous,uniform,and adhered to the HEAs substrates.The mixed carbides were identified using X-ray diffraction,and the quality of the diamond films was examined using Raman spectroscopy.Moreover,the corrosion test revealed that the diamond/TiZrHfMo samples had excellent electrochemical stability and corrosion resistance with a corrosion potential value of-0.169 V in a 3.5wt%NaCl solution.A multiple regression model was established to evaluate the effects of the structure and growth parameters,which confirmed that the mixing entropy significantly affected the grain size and corrosion properties.
基金supporteded by Natural Science Foundation of Shanghai(Grant No.22ZR1463900)State Key Laboratory of Mechanical System and Vibration(Grant No.MSV202318)the Fundamental Research Funds for the Central Universities(Grant No.22120220649).
文摘Additive manufacturing(AM),particularly fused deposition modeling(FDM),has emerged as a transformative technology in modern manufacturing processes.The dimensional accuracy of FDM-printed parts is crucial for ensuring their functional integrity and performance.To achieve sustainable manufacturing in FDM,it is necessary to optimize the print quality and time efficiency concurrently.However,owing to the complex interactions of printing parameters,achieving a balanced optimization of both remains challenging.This study examines four key factors affecting dimensional accuracy and print time:printing speed,layer thickness,nozzle temperature,and bed temperature.Fifty parameter sets were generated using enhanced Latin hypercube sampling.A whale optimization algorithm(WOA)-enhanced support vector regression(SVR)model was developed to predict dimen-sional errors and print time effectively,with non-dominated sorting genetic algorithm Ⅲ(NSGA-Ⅲ)utilized for multi-objective optimization.The technique for Order Preference by Similarity to Ideal Solution(TOPSIS)was applied to select a balanced solution from the Pareto front.In experimental validation,the parts printed using the optimized parameters exhibited excellent dimensional accuracy and printing efficiency.This study comprehensively considered optimizing the printing time and size to meet quality requirements while achieving higher printing efficiency and aiding in the realization of sustainable manufacturing in the field of AM.In addition,the printing of a specific prosthetic component was used as a case study,highlighting the high demands on both dimensional precision and printing efficiency.The optimized process parameters required significantly less printing time,while satisfying the dimensional accuracy requirements.This study provides valuable insights for achieving sustainable AM using FDM.
基金jointly funded by projects supported by the National Natural Science Foundation of China(Grant No.41872150)the Joint Funds of the National Natural Science Foundation of China(Grant No.U19B6003)Major Scientific and Technological Projects of CNPC during the 13th five-year plan(No.2019A-02-10)。
文摘Recent advances in hydrocarbon exploration have been made in the Member Deng-2 marginal microbial mound-bank complex reservoirs of the Dengying Formation in the western Sichuan Basin, SW China,where the depositional process is regarded confusing. The microfacies, construction types, and depositional model of the Member Deng-2 marginal microbial mound-bank complex have been investigated using unmanned aerial vehicle photography, outcrop section investigation, thin section identification,and seismic reflections in the southwestern Sichuan Basin. The microbialite lithologic textures in this region include thrombolite, dendrolite, stromatolite, fenestral stromatolite, spongiostromata stone,oncolite, aggregated grainstone, and botryoidal grapestone. Based on the comprehensive analysis of“depositional fabrics-lithology-microfacies”, an association between a fore mound, mound framework,and back mound subfacies has been proposed based on water depth, current direction, energy level and lithologic assemblages. The microfacies of the mound base, mound core, mound flank, mound cap, and mound flat could be recognized among the mound framework subfacies. Two construction types of marginal microbial mound-bank complex have been determined based on deposition location, mound scale, migration direction, and sedimentary facies association. Type Jinkouhe microbial mound constructions(TJMMCs) develop along the windward margin owing to their proximity to the seaward subfacies fore mound, with a northeastwardly migrated microbial mound on top of the mud mound,exhibiting the characteristics of large-sized mounds and small-sized banks in the surrounding area. Type E'bian microbial mound constructions(TEMMCs) primarily occur on the leeward margin, resulting from the presence of onshore back mound subfacies, with the smaller southwestward migrated microbial mounds existing on a thicker microbial flat. The platform margin microbial mound depositional model can be correlated with certain lateral comparison profile and seismic reflection structures in the 2D seismic section, which can provide references for future worldwide exploration. Microbial mounds with larger buildups and thicker vertical reservoirs are typically targeted on the windward margin, while small-sized microbial mounds and flats with better lateral connections are typically focused on the leeward margin.
基金The Guangdong Basic and Applied Basic Research Foundation under contract Nos 2024A1515012628the National Natural Science Foundation of China under contract Nos 41876059 and 42372213+4 种基金the Open Research Fund Program of Zhoushan Field Scientific Observation and Research Station for Marine Geo-hazards,China Geological Survey under contract No.ZSORS-22-5the Shantou University Scientific Research Foundation for Talents under contract No.NTF20028China-Association of Southeast Asian Nations(ASEAN)Maritime Cooperation Fund Project under contract No.12120100500017001China Geological Survey Projects under contract Nos DD20211553,DD20221710,and DD20230415the Science and Technology Innovation Fund of Command Center of Integrated Natural Resources Survey Center under contract No.KC20230017.
文摘The deltas serve as the primary interactive zone where terrestrial and marine environments converge,playing a pivotal role in the coastal deposition.In the Holocene,climate changes and sea level fluctuation are the principal driving factors in the evolution of deltas.However,human activities such as the construction of dams and reservoirs in the Anthropocene have significantly altered sediment transport in rivers,leading to depositional pattern variation during deltaic evolution.In this study,we have conducted a comparative analysis of the morphological variations(1986-2021)in the barrier system of the Hanjiang River Delta(HRD)using satellite remote sensing(SRS)method.Additionally,we have examined the lithological changes and facies alterations observed in eight boreholes on the present barrier spit.Our findings indicate that the intensification of anthropogenic activities led to a significant reduction in the sediment flux of the Hanjiang River(HR),resulting in depocenter landward migration at the estuary.SRS analysis reveals their periodical morphological characteristics and spatial variations of estuarine sandbars(1986-1992),barrier islands-lagoons(1993-2009),and barrier spits(2010-2021)during 1986 to 2021.The stratigraphy of boreholes demonstrates a south-to-north facies transition from lagoon to lagoon-barrier spit and barrier spit in vertical lithology.Therefore,the depositional evolution of the HRD barrier system is categorized into three phases:estuarine sandbar-barrier island phase(1986-1998);barrier island-lagoon phase(1999-2009);and barrier spit phase(2010-2021).During the estuarine sandbar-barrier island phase,fluvial processes played a predominate role in the deposition.Consequently,with a significant decrease in river sediment load,the dominant factors driving depositional processes shifted towards wave action and alongshore current.Based on the conceptual model in the Holocene,we propose a modified depositional model of wave-dominated deltas during Anthropocene that encompasses three evolutionary phases:estuarine sandbars and delta front platforms,barrier island-lagoon formation and landward migration of barrier spits.This pattern highlights that human-induced reduction in river sediment flux has led to a seaward deltaic progradation driven by barrier landward migration.
文摘Three-dimensional porous poly-lactic acid(PLA) scaffold was fabricated using fused deposition modeling(FDM) method including 30%, 50% and 70% nominal porosity. Study of phases in initial polymeric material and printed scaffolds was done by X-ray diffraction(XRD), and no significant phase difference was observed due to the manufacturing process, and the poly-lactic acid retains its crystalline properties. The results of the mechanical properties evaluation by the compression test show that the mechanical properties of the scaffold have decreased significantly with increasing the porosity of scaffold. The microstructure of scaffolds were studied by scanning electron microscope(SEM), showing that the pores had a regular arrangement and their morphology changed with porosity change. The mechanical properties of the poly-lactic acid scaffolds printed using fused deposition modeling, can be adapted to the surrounding tissue, by porosity change.
基金supported by Guangdong Provincial Natural Science Foundation (No. 02-38100-4202003 and 06202438)New Century Excellent Talents Program of Ministry of Education of the People’s Republic of China(No. NCET-04-0790)
文摘The current acid deposition critical loads in Guangdong, China were calculated using the PROFILE model with a 3 km × 3 km resolution. Calculations were carded out for critical loads of potential acidity, actual acidity, sulfur and nitrogen, with values in extents of 0-3.5, 0-14.0, 0-26.0 and 0-3.5 kmol/（hrnE.year）, respectively. These values were comparable to previously reported results and reflected the influences of vegetation and soil characteristics on the soil acid buffering capacity. Simulations of SO2 emission and sulfur deposition in this study showed that sulfur deposition core areas mirrored SO2 emission centers. The prediction of sulfur deposition after 20% and 40% reduction of SO2 emission suggested that the reduction of area sources contributed greatly to the decrease of sulfur deposition. Thus, abatement of area source emissions could be the primary way to mitigate sulfur deposition in Guangdong to meet both the provincial and national regulations of air pollution control.
基金Projects(41173055,41772118)supported by the National Natural Science Foundation of China
文摘Based on the element geochemistry and biomarkers of the oil shale from the Chang 7 sub-unit in the southern Ordos Basin,the depositional conditions and organic source of the oil shale are discussed.Biomarkers analyses show that the oil shale has a homologous organic matter source,with a mix of plankton and advanced plants.U/Th and V/Ni ratios suggest that the redox condition is dominated by a reducing condition,and the degree of anoxia in the Tongchuan area is higher than that of the Xunyi area.Sr/Ba ratios illustrate that the oil shale is deposited in fresh water and the paleosalinity in the Tongchuan area is slightly higher.Fe/Ti ratios imply that the Tongchuan area underwent obvious hydrothermal fluid activities.Sr/Cu ratios show warm and humid paleoclimate in both areas.As assessed by(La/Yb)NASC,the deposition rate in the Tongchuan area is relatively lower.Fe/Co and Th/U ratios suggest that the paleo-water-depth in the Tongchuan area is deeper.The source rock could have the advance plants source,which must have close relationship with the Qinling orogeny.Comparing the paleoenvironment,the Tongchuan area has better depositional conditions,and is the key oil shale exploration area in the southern Ordos Basin.
基金The authors gratefully acknowledge the support provided by the National Natural Science Foundation of China(Nos.52250006 and 52075482)the Starry Night Science Fund of Zhejiang University Shanghai Institute for Advanced Study(No.SNZJU-SIAS-004).
文摘Ideal tissue engineering scaffolds need interconnected pores and high porosity to enable cell survival,migration,proliferation,and differentiation.However,obtaining a high-resolution structure is difficult with traditional one-temperature control fused deposition modeling(FDM).In this study,we propose a dual-temperature control method to improve printability.A numerical model is developed in which the viscosity is a function of temperature and shear rate to study the influence of two different temperature control modes.Quantitative tests are used to assess filament formation and shape fidelity,including one-dimensional filament printing,deposition at corners,fusion,and collapse.By using dual-temperature control,the width of the deposited poly(ε-caprolactone)filament is reduced to 50μm.The comparative results of both the experimental method and numerical simulation suggest that the dual-temperature control FDM can manufacture spatially arranged constructs and presents a promising application in tissue engineering。
基金supported by the Program for Creation of Interdisciplinary Research and Ensemble Program of Frontier Research Institute for Interdisciplinary Sciences,Tohoku University。
文摘Biodegradable polymers are highly attractive as potential alternatives to petroleum-based polymers in an attempt to achieve carbon neutrality whilst maintaining the mechanical properties of the structures.Among these polymers,polylactic acid(PLA)is particularly promising due to its good mechanical properties,biocompatibility and thermoplasticity.In this work,we aim to enhance the mechanical properties of PLA using mechanically-defibrated cellulose nanofibers(CNFs)that exhibit remarkable mechanical properties and biodegradability.We also employ fused deposition modeling(FDM),one of the three-dimensional printing methods for thermoplastic polymers,for the low-cost fabrication of the products.Mechanically-defibrated CNF-reinforced PLA matrix composites are fabricated by FDM.Their tensile properties are investigated in two printing directions(0°/90°and+45°/-45°).The discussion about the relationship between printing direction and tensile behavoir of mechanically-defibrated CNF-reinforced PLA matrix composite is the unique point of this study.We further discuss the microstructure and fracture surface of mechanically-defibrated CNF-reinforced PLA matrix composite by scanning electron microscope.
基金the National Key R&D Program of China(Grants No.2017YFB0703200)National Natural Science Foundation of China(Grants Nos.51702100,51972268)China Postdoctoral Science Foundation(Grants No.2018M643075)for financial support。
文摘The development of functional relationships between the observed deposition rate and the experimental conditions is an important step toward understanding and optimizing low-pressure chemical vapor deposition(LPCVD)or low-pressure chemical vapor infiltration(LPCVI).In the field of ceramic matrix composites(CMCs),methyltrichlorosilane(CH3 SiCl3,MTS)is the most widely used source gas system for SiC,because stoichiometric SiC deposit can be facilitated at 900°C–1300°C.However,the reliability and accuracy of existing numerical models for these processing conditions are rarely reported.In this study,a comprehensive transport model was coupled with gas-phase and surface kinetics.The resulting gas-phase kinetics was confirmed via the measured concentration of gaseous species.The relationship between deposition rate and 24 gaseous species has been effectively evaluated by combining the special superiority of the novel extreme machine learning method and the conventional sticking coefficient method.Surface kinetics were then proposed and shown to reproduce the experimental results.The proposed simulation strategy can be used for different material systems.
基金The authors gratefully acknowledge the financial support by the Jiangsu Key R&D program(BE2019072).
文摘The paper discusses the mechanical and thermal performance manifested in natural nanorods attapulgite(ATP)reinforced Acrylonitrile butadiene styrene(ABS)nanocomposites in the process of fused deposition modeling(FDM).Molten extrusion technique was taken to manufacture the filaments of ABS/organic-attapulgite(OAT)nanocomposites with different mass fraction and the printing operation was made by one commercial FDM three-dimensional(3D)printer.Results indicate that the mechanical performance of these FDM 3D printed specimens are improved obviously via the introduction of OAT,and tensile strength of the ABS/OAT nanocomposites parts with only 2 wt%OAT addition is enhanced by 48.1%.At the same time,the addition OAT can reduce the linear expansion coefficient and creep flexibility,and improve the thermal stability and dimensional accuracy of these FDM 3D printed parts.
