The optimization of working fluids in single-well coaxial geothermal systems presents a critical pathway for advancing the use of enhanced geothermal systems(EGS)in renewable energy applications.This study evaluates t...The optimization of working fluids in single-well coaxial geothermal systems presents a critical pathway for advancing the use of enhanced geothermal systems(EGS)in renewable energy applications.This study evaluates the thermo-hydraulic performance of three working fluids(H_(2)O,CO_(2),and H_(2))in a single-well coaxial geothermal system,focusing on the effects of their injection temperatures.Using a 3D finite element model in COMSOL Multiphysics,simulations were conducted at three injection temperatures(17℃,27℃,40℃)under constant mass flow rates.The results reveal that hydrogen significantly outperforms water and carbon dioxide,achieving a 297.77% and 5453.76% higher thermal output,respectively.Notably,the heat transfer efficiency is significantly improved when the injected working fluids are at 40℃,compared to 27℃;this demonstrates a positive correlation between injection temperature and thermal recovery.Though water systems exhibit better geological compatibility,the superior thermal properties of hydrogen position it as a promising alternative-despite potential subsurface challenges.This study provides critical insights for advancing the application of high-efficiency geothermal systems as well as the development of non-aqueous working fluids,thus contributing to the sustainable utilization of geothermal energy.展开更多
Geothermal energy,a kind of clean and environmentally friendly energy source,is an important object of future natural resource development and utilization,among which,hot dry rock is one of the important deep geotherm...Geothermal energy,a kind of clean and environmentally friendly energy source,is an important object of future natural resource development and utilization,among which,hot dry rock is one of the important deep geothermal resources.In the current multi-objective optimization of heat extraction performance,reservoir production models are less considered and the effects of different optimization ideas are not compared comprehensively.To improve the heat extraction efficiency and prolong the exploitation life of geothermal reservoirs,this paper determines the appropriate operating parameters of geothermal system(injection temperature,injection rate,production pressure and injection-production well spacing)based on the coupled thermal-hydraulic-mechanical model of hot dry rock exploitation in the Gonghe area of Qinghai and three heat extraction optimization methods.In addition,the heat extraction performances of different schemes are comparatively evaluated.And the following research results are obtained.First,the sensitivity analysis of injection and production parameters shows that power generation and recovery factor are in a reverse relation with injection-production pressure difference,which is the direct reason for the adoption of multiobjective optimization.Second,the optimization scheme prepared on the basis of parametric study indicates that the shortest life of a geothermal reservoir is 10 years,the injection-production pressure difference is up to 67 MPa,there is a significant thermal breakthrough phenomenon and the reservoir safety faces challenges.Third,by virtue of multi-objective optimization and decision making integration,the optimal operation parameter combination of hot dry rock system is determined,the life of geothermal reservoirs can exceed 20 years and balanced optimization is achieved.In conclusion,the idea of multi-objective optimization is feasible and applicable to geothermal energy exploitation and this method provides a reference for the efficient geothermal energy development and utilization and is helpful to the realization of“double carbon”goal in China.展开更多
Oilfield geothermal energy is one important part of geothermal resources,and it can be developed and used for power generation and heating.The geothermal reserves and production ofmulti-layer sandstone oil reservoirs ...Oilfield geothermal energy is one important part of geothermal resources,and it can be developed and used for power generation and heating.The geothermal reserves and production ofmulti-layer sandstone oil reservoirs account for 50%of the total geothermal reserves and production in China,respectively,but due to the influence of interlayer heterogeneity,interlayer interference is common in the process of geothermal development by water injection.Therefore,it is in an urgent need to evaluate the heat extraction performance of oil-bearing geothermal reservoirs in multi-layer commingled production.Taking a depleted oil reservoir(and even a high-or an extra-high water-saturation oil reservoir)as the research object,this paper establishes a numerical model of coupled oilewater two-phase heat flow in a multi-layer commingled production oil reservoir.Then,interlayer interference characteristics and temperature and pressure distribution situations under different porosity,permeability and initial oil saturation are compared.Finally,the influence of interlayer interference on heat extraction performance is analyzed.And the following research results are obtained.First,under the research conditions and model settings of this paper,the injectioneproduction pressure difference and production temperature difference between low-permeability layers and high-permeability layers of the reservoir with different permeability after 20 years'production are up to 3.27MPa and 24.5 K,respectively,which are much higher than the corresponding differences of oil-bearing homogeneous reservoirs.Second,the lower the initial oil saturation,the smaller the reservoir production temperature and injectioneproduction pressure difference.And after 20 years,the maximum difference is 1.32MPa.Third,interlayer interference is sensitive to permeability.The fluid in the high-permeability layers comes from the injection well of the same layer and low-permeability layers.The production temperature of the reservoirs with different permeability can rise by 5.33 K at most.In conclusion,permeability is the key parameter influencing production temperature and injectioneproduction pressure difference of oil-bearing reservoirs while porosity has less influence on production behaviors.In addition,injectioneproduction pressure difference is more sensitive to the change of initial oil saturation and the existence of oil phase can increase the injection pressure significantly.Furthermore,if there is a boundary geothermal source,the reservoirs with strong interlayer interference can obtain high heat extraction more easily,so this type of reservoirs can be given priority in the heat extraction of abandoned wells.展开更多
The efficient exploitation of geothermal energy through enhanced geothermal systems(EGS)has been a relevant topic for hot dry rock(HDR)geothermal resources.When cryogenic fluid is injected into a thermal reservoir,imp...The efficient exploitation of geothermal energy through enhanced geothermal systems(EGS)has been a relevant topic for hot dry rock(HDR)geothermal resources.When cryogenic fluid is injected into a thermal reservoir,improving heat exchange efficiency is key to achieving the optimal exploitation of HDR.In this paper,granite outcrops from Gonghe Basin were used as the testing sample.The natural fractures in the granite samples were relatively well developed.To simulate long-term injection and production from multi-wells in situ,physical ex-periments were performed in a newly-developed,in-house large-scale true triaxial experimental system.Geothermal extraction performance of an HDR was simulated for long-term injection and production operations.Simultaneously,the mode of one-injection and multiple-production wells was represented.In the paper,the ef-fects of the production-injection well spacing,the number of production wells and the injection rate on the production temperature and flow rate are discussed.The results show that,during long-term injection and pro-duction,there are two stages of production temperature variation,namely stabilization and attenuation.When the number of the production wells is increased,the heat extraction efficiency is accelerated.Moreover,competitive diversion of fluid among fractures occurred due to different conductivities.Furthermore,under different pro-duction modes,the production flow rate contributed differently to the heat extraction.Finally,the effect of the production-injection wells spacing on the heat exchange performance was analyzed;this is mainly reflected in the change of the effective heat exchange area between the rock and the injected fluid.The results emphasize the importance of designing an appropriate production mode and optimizing the injection-production parameters to ensure efficient HDR exploitation.展开更多
Geothermal energy,a form of renewable energy,has been extensively utilized for building heating.However,there is a lack of detailed comparative studies on the use of shallow and medium-deep geothermal energy in buildi...Geothermal energy,a form of renewable energy,has been extensively utilized for building heating.However,there is a lack of detailed comparative studies on the use of shallow and medium-deep geothermal energy in building energy systems,which are essential for decision-making.Therefore,this paper presents a comparative study of the performance and economic analysis of shallow and medium-deep borehole heat exchanger heating systems.Based on the geological parameters of Xi’an,China and commonly used borehole heat exchanger structures,numerical simulationmethods are employed to analyze performance and economic efficiency.The results indicate that increasing the spacing between shallow borehole heat exchangers can effectively reduce thermal interference between the pipes and improve heat extraction performance.As the flow rate increases,the outlet water temperature ranges from 279.3 to 279.7 K,with heat extraction power varying between 595 and 609 W.For medium-deep borehole heat exchangers,performance predictions show that a higher flow rate results in greater heat extraction power.However,when the flow rate exceeds 30 m^(3)/h,further increases in flow rate have only a minor effect on enhancing heat extraction power.Additionally,the economic analysis reveals that the payback period for shallow geothermal heating systems ranges from 10 to 11 years,while for medium-deep geothermal heating systems,it varies more widely from 3 to 25 years.Therefore,the payback period for medium-deep geothermal heating systems is more significantly influenced by operational and installation parameters,and optimizing these parameters can considerably shorten the payback period.The results of this study are expected to provide valuable insights into the efficient and cost-effective utilization of geothermal energy for building heating.展开更多
To establish an analytical method for determination of four bisphenols （BPA, BPB, BPF, and BPS） and two alkylphenols （4-n-OP, 4-n-NP） in water by ultra performance liquid chromatography- tandem mass spectrometry ...To establish an analytical method for determination of four bisphenols （BPA, BPB, BPF, and BPS） and two alkylphenols （4-n-OP, 4-n-NP） in water by ultra performance liquid chromatography- tandem mass spectrometry （UPLC/MS/MS）. The water samples were extracted and condensed with solid-phase extraction （SPE） using C18 cartridges and eluted by acetonitrile. Separation was carried out with Acquity BEH C8 column and detection were performed by UPLC/MS/MS. Quantification was calculated by using the internal standard BPA-d16 and 4-n-NP-d8. The linear correlation coefficients of these compounds in the range of 1.0-100.0μg/L were all over 0.999. The minimum detectable concentrations were 0.75-1.0 ng/L, and the recoveries ranged from 87.0% to 106.9%.展开更多
The procedures of ultrasonic extraction and clean-up were optimized for the determination of polycyclic aromatic hydrocarbons (PAHs) in marine sediments. Samples were ultrasonically extracted, and the extracts were pu...The procedures of ultrasonic extraction and clean-up were optimized for the determination of polycyclic aromatic hydrocarbons (PAHs) in marine sediments. Samples were ultrasonically extracted, and the extracts were purified with a miniaturized silica gel chromatographic column and analyzed with high performance liquid chromatography (HPLC) with a fluorescence detector. Ultrasonication with methanol-dichloromethane (2:1, v/v) mixture gave higher extraction efficiency than that with dichloromethane. Among the three elution solvents used in clean-up step, dichloromethane-hexane (2:3, v/v) mixture was the most satisfactory. Under the optimized conditions, the recoveries in the range of 54.82% to 94.70% with RSDs of 3.02% to 23.22% for a spiked blank, and in the range of 61.20% to 127.08% with RSDs of 7.61% to 26.93% for a spiked matrix, were obtained for the 15 PAHs studied, while the recoveries for a NIST standard reference SRM 1941b were in the range of 50.79% to 83.78% with RSDs of 5.24% to 21.38%. The detection limits were between 0.75 ng L-1 and 10.99 ng L-1for different PAHs. A sample from the Jiaozhou Bay area was examined to test the established methods.展开更多
In this work, a metal-organic framework derived nanoporous carbon （MOF-5-C） was fabricated and modified with Fe3O4 magnetic nanoparticles. The resulting magnetic MOF-5-derived porous carbon （Fe304@MOF-5-C） was the...In this work, a metal-organic framework derived nanoporous carbon （MOF-5-C） was fabricated and modified with Fe3O4 magnetic nanoparticles. The resulting magnetic MOF-5-derived porous carbon （Fe304@MOF-5-C） was then used for the magnetic solid-phase extraction of chlorophenols （CPs） from mushroom samples prior to high performance liquid chromatography-ultraviolet detection. Scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and N2 adsorption were used to characterize the adsorbent. After experimental optimization, the amount of the adsorbent was chosen as 8.0 mg, extraction time as 10 min, sample volume as 50 mL, desorption solvent as 0.4 mL （0.2 mL × 2） of alkaline methanol, and sample pH as 6. Under the above optimized conditions, good linearity for the analytes was obtained in the range of 0.8-100.0 ng g 1 with the correlation coefficients between 0.9923 and 0.9963. The limits of detection （SIN= 3） were in the range of 0.25-0.30 ng g-1, and the relative standard deviations were below 6.8%. The result showed that the Fe304@MOF-5-C has an excellent adsorption capacity for the analytes.展开更多
An improved method for trace level quantification of dicyandiamide in stream water has been developed. This method includes sample pretreatment using solid phase extraction.The extraction procedure（including loading,...An improved method for trace level quantification of dicyandiamide in stream water has been developed. This method includes sample pretreatment using solid phase extraction.The extraction procedure（including loading, washing, and eluting） used a flow rate of1.0 m L/min, and dicyandiamide was eluted with 20 m L of a methanol/acetonitrile mixture（V/V = 2：3）, followed by pre-concentration using nitrogen evaporation and analysis with high performance liquid chromatography–ultraviolet spectroscopy（HPLC–UV）. Sample extraction was carried out using a Waters Sep-Pak AC-2 Cartridge（with activated carbon）.Separation was achieved on a ZIC-Hydrophilic Interaction Liquid Chromatography（ZIC-HILIC）（50 mm × 2.1 mm, 3.5 μm） chromatography column and quantification was accomplished based on UV absorbance. A reliable linear relationship was obtained for the calibration curve using standard solutions（R^2〉 0.999）. Recoveries for dicyandiamide ranged from 84.6% to 96.8%, and the relative standard deviations（RSDs, n = 3） were below 6.1% with a detection limit of 5.0 ng/m L for stream water samples.展开更多
The phenc, lic compounds found in mango fruit are antioxidants, and contribute to a reduction in the risk of cardiovascular diseases. Mango carotenoids are synthesized in mango fruit during ripening. A major by-produc...The phenc, lic compounds found in mango fruit are antioxidants, and contribute to a reduction in the risk of cardiovascular diseases. Mango carotenoids are synthesized in mango fruit during ripening. A major by-product of mango fruit is the skin, which is available after the fruits is consumed or used, particularly in the preparation of jams and fruit juices by the fruit canning industry. The objective of this study was to investigate the effects of dietary mango skin （MS） or mango skin combined with paprika extracts （PE） on production performance, egg quality, and egg yolk polyphenols. Total of 60 44-week-old Boris Brown hens was assigned, based on egg production rate and body weight, to 6 groups （10 birds in each group）. The laying hens were fed a basal diet （control group, 18 CP, 2,800 kcal/kg ME）, a basal diet supplemented with 0.1% PE, 1% or 5% MS, or with a mixture of 0.1% PE with 1% or 5% MS respectively. During the three-week experimental feeding period, the birds had free access to feed and water. Feed consumption was measured weekly and egg production was recorded daily. The results for initial body weight, feed consumption, hen-day production, egg mass, mortality, and final body weight did not indicate any effects of the different treatments （P 〉 0.05）. There were no significant differences （P 〉 0.05） in shell-breaking strength, shell thickness, shell ratio, yolk ratio or Haugh units, except in the case of egg yolk color. Roche yolk color fan scores were better in all experimental groups than in the control （P 〈 0.0001）. The yolk color, yellow index, and ratio of redness to yellowness were greater （P 〈 0.0001） in the 0.1% PE, the 0.1% PE ＋ 1% MS, and the 0.1% PE ＋ 5% MS group than in the 1%, 5% MS, and control groups. Compared with the control, lightness was decreased significantly in the 0.1% PE, the 0.1% PE ＋ 1% MS, and the 0.1% PE ＋ 5% MS groups （P 〈 0.05）, whereas redness was increased significantly in the 0.1% PE, 0.1% PE ＋ 1% MS, and 0.1% PE ＋ 5% MS groups （P 〈 0.0001）. No significant differences among the treatments were observed in either yellowness or egg yolk polyphenols. The results of the present experiment indicate that dietary mango skin or mango skin combined with paprika extracts did not show adverse effects on production performance, egg quality or egg yolk polyphenols. Moreover, supplementation with only mango skin did not enhance egg yolk color.展开更多
Problems associated with organochlorine pesticide （OCP）-contaminated sites in China have received wide attention. To solve such problems, innovative ex-situ methods of site remediation are urgently needed. We invest...Problems associated with organochlorine pesticide （OCP）-contaminated sites in China have received wide attention. To solve such problems, innovative ex-situ methods of site remediation are urgently needed. We investigated the feasibility of the extraction method with different organic solvents, ethanol, 1-propanol, and three fractions of petroleum ether, using a soil collected from Wujiang （W J）, China, a region with long-term contamination of dichlorodiphenyltrichloroethanes （DDTs）. We evaluated different influential factors, including organic solvent concentration, washing time, mixing speed, solutiomto-soil ratio, and washing temperature, on the removal of DDTs from the WJ soil. A set of relatively better parameters were selected for extraction with 100 mL L-1 petroleum ether （60-90 ℃）： washing time of 180 min, mixing speed of 100 r min-I, solution-to-soil ratio of 10：1, and washing temperature of 50 ℃. These selected parameters were also applied on three other seriously OCP-polluted soils. Results demonstrated their broad-spectrum effectiveness and excellent OCP extraction performance on the contaminated soils with different characteristics.展开更多
Based on the independently developed true triaxial multi-physical field large-scale physical simulation system of in-situ injection and production,we conducted physical simulation of long-term multi-well injection and...Based on the independently developed true triaxial multi-physical field large-scale physical simulation system of in-situ injection and production,we conducted physical simulation of long-term multi-well injection and production in the hot dry rocks of the Gonghe Basin,Qinghai Province,NW China.Through multi-well connectivity experiments,the spatial distribution characteristics of the natural fracture system in the rock samples and the connectivity between fracture and wellbore were clarified.The injection and production wells were selected to conduct the experiments,namely one injection well and two production wells,one injection well and one production well.The variation of several physical parameters in the production well was analyzed,such as flow rate,temperature,heat recovery rate and fluid recovery.The results show that under the combination of thermal shock and injection pressure,the fracture conductivity was enhanced,and the production temperature showed a downward trend.The larger the flow rate,the faster the decrease.When the local closed area of the fracture was gradually activated,new heat transfer areas were generated,resulting in a lower rate of increase or decrease in the mining temperature.The heat recovery rate was mainly controlled by the extraction flow rate and the temperature difference between injection and production fluid.As the conductivity of the leak-off channel increased,the fluid recovery of the production well rapidly decreased.The influence mechanisms of dominant channels and fluid leak-off on thermal recovery performance are different.The former limits the heat exchange area,while the latter affects the flow rate of the produced fluid.Both of them are important factors affecting the long-term and efficient development of hot dry rock.展开更多
Phellodendron amurense has been used for many years as a medical plant in traditional Chinese medicine and has shown great prospect in recent clinical trials for future applications. Berberine is an essential active c...Phellodendron amurense has been used for many years as a medical plant in traditional Chinese medicine and has shown great prospect in recent clinical trials for future applications. Berberine is an essential active compound contained in P. amurense. Our objective in this study was to quantify the content of berberine in P.amurense from sites at different elevations on Changbai Mountain. We collected samples of P. amurense from five different elevations on Changbai Mountain. Berberine in samples was extracted by ultrahigh pressure extraction（UPE）. And the quantity was measured by high performance liquid chromatography（HPLC）. First, the optimal HPLC conditions for berberine were identified with satisfactory precision（relative standard deviation, R SD／5.6 %）, good accuracy（relative error, R E／ 3.6 %） and good linear relation（R2= 0.9998） in the range of 6.576–328.8 mg L-1. Second, the combination of UPE and HPLC methods in quantitative analysis of berberine showed high repeatability（R SD= 3.28 %）, reproducibility（R SD= 4.72 %）,stability（R SD／ 1.27 %） and good recovery（99.54 %） for real plant materials. Samples from Heilongjiang Province at the lowest elevation contained the highest amount of berberine.Similarly, the lowest amount of berberine was recorded in samples from Changbai Forest Bureau of Jilin Province collected at the highest elevation in this paper. The proposed UPE–HPLC method is simple, reliable and low-cost for quantitative analysis of berberine. Content of berberine in P.amurense varied significantly by site on Changbai Mountain.展开更多
基金funded by the China National Administration of Coal Geology Science and Technology Innovation Project"Research on Clean Energy Exploration and Development Technology"(ZMKJ-2021-ZX04)the China National Administration of Coal Geology Special Task Project"Research on Geothermal Resource Exploration and Development Technology"(ZMKJ-2023-JBGS06)。
文摘The optimization of working fluids in single-well coaxial geothermal systems presents a critical pathway for advancing the use of enhanced geothermal systems(EGS)in renewable energy applications.This study evaluates the thermo-hydraulic performance of three working fluids(H_(2)O,CO_(2),and H_(2))in a single-well coaxial geothermal system,focusing on the effects of their injection temperatures.Using a 3D finite element model in COMSOL Multiphysics,simulations were conducted at three injection temperatures(17℃,27℃,40℃)under constant mass flow rates.The results reveal that hydrogen significantly outperforms water and carbon dioxide,achieving a 297.77% and 5453.76% higher thermal output,respectively.Notably,the heat transfer efficiency is significantly improved when the injected working fluids are at 40℃,compared to 27℃;this demonstrates a positive correlation between injection temperature and thermal recovery.Though water systems exhibit better geological compatibility,the superior thermal properties of hydrogen position it as a promising alternative-despite potential subsurface challenges.This study provides critical insights for advancing the application of high-efficiency geothermal systems as well as the development of non-aqueous working fluids,thus contributing to the sustainable utilization of geothermal energy.
基金National Natural Science Foundation of China(NSFC)“Theory and Technology of Complex Seam Network in High Temperature Rock for Storage”(No.52192621)National Key Research and Development Program(No.2018YFB1501804)+2 种基金Sichuan Science and Technology Program Project“Research on the Mechanism of Enhanced Heat Transfer between Geothermal Well Completion Structure and Downhole Heat Exchanger”(No.2021Ya1.389)National Key Research and Development Program(No.2021YJ0389)“Research on the Mechanism of Fracture Damage in Dry Hot Rock Extraction”(PRP/open-2110)of the State Key Laboratory of Oil and Gas Resources and Exploration,China University of Petroleum(Beijing).
文摘Geothermal energy,a kind of clean and environmentally friendly energy source,is an important object of future natural resource development and utilization,among which,hot dry rock is one of the important deep geothermal resources.In the current multi-objective optimization of heat extraction performance,reservoir production models are less considered and the effects of different optimization ideas are not compared comprehensively.To improve the heat extraction efficiency and prolong the exploitation life of geothermal reservoirs,this paper determines the appropriate operating parameters of geothermal system(injection temperature,injection rate,production pressure and injection-production well spacing)based on the coupled thermal-hydraulic-mechanical model of hot dry rock exploitation in the Gonghe area of Qinghai and three heat extraction optimization methods.In addition,the heat extraction performances of different schemes are comparatively evaluated.And the following research results are obtained.First,the sensitivity analysis of injection and production parameters shows that power generation and recovery factor are in a reverse relation with injection-production pressure difference,which is the direct reason for the adoption of multiobjective optimization.Second,the optimization scheme prepared on the basis of parametric study indicates that the shortest life of a geothermal reservoir is 10 years,the injection-production pressure difference is up to 67 MPa,there is a significant thermal breakthrough phenomenon and the reservoir safety faces challenges.Third,by virtue of multi-objective optimization and decision making integration,the optimal operation parameter combination of hot dry rock system is determined,the life of geothermal reservoirs can exceed 20 years and balanced optimization is achieved.In conclusion,the idea of multi-objective optimization is feasible and applicable to geothermal energy exploitation and this method provides a reference for the efficient geothermal energy development and utilization and is helpful to the realization of“double carbon”goal in China.
基金National Natural Science Foundation of China major project“High-temperature rock dynamic damage mechanism and high-efficiency crushing method”(No.52192624)National Natural Science Foundation of China key research and development plan project“Multi-field coupled flow heat transfer mechanism and heat extraction performance optimization in thermal storage”(No.:2018YFB1501804)China University of Petroleum(Beijing)State Key Laboratory of Oil and Gas Resources and Exploration Fund Project“Research on Fracture Damage Mechanism during Hot Dry Rock Exploitation”(No.PRP/open-2110).
文摘Oilfield geothermal energy is one important part of geothermal resources,and it can be developed and used for power generation and heating.The geothermal reserves and production ofmulti-layer sandstone oil reservoirs account for 50%of the total geothermal reserves and production in China,respectively,but due to the influence of interlayer heterogeneity,interlayer interference is common in the process of geothermal development by water injection.Therefore,it is in an urgent need to evaluate the heat extraction performance of oil-bearing geothermal reservoirs in multi-layer commingled production.Taking a depleted oil reservoir(and even a high-or an extra-high water-saturation oil reservoir)as the research object,this paper establishes a numerical model of coupled oilewater two-phase heat flow in a multi-layer commingled production oil reservoir.Then,interlayer interference characteristics and temperature and pressure distribution situations under different porosity,permeability and initial oil saturation are compared.Finally,the influence of interlayer interference on heat extraction performance is analyzed.And the following research results are obtained.First,under the research conditions and model settings of this paper,the injectioneproduction pressure difference and production temperature difference between low-permeability layers and high-permeability layers of the reservoir with different permeability after 20 years'production are up to 3.27MPa and 24.5 K,respectively,which are much higher than the corresponding differences of oil-bearing homogeneous reservoirs.Second,the lower the initial oil saturation,the smaller the reservoir production temperature and injectioneproduction pressure difference.And after 20 years,the maximum difference is 1.32MPa.Third,interlayer interference is sensitive to permeability.The fluid in the high-permeability layers comes from the injection well of the same layer and low-permeability layers.The production temperature of the reservoirs with different permeability can rise by 5.33 K at most.In conclusion,permeability is the key parameter influencing production temperature and injectioneproduction pressure difference of oil-bearing reservoirs while porosity has less influence on production behaviors.In addition,injectioneproduction pressure difference is more sensitive to the change of initial oil saturation and the existence of oil phase can increase the injection pressure significantly.Furthermore,if there is a boundary geothermal source,the reservoirs with strong interlayer interference can obtain high heat extraction more easily,so this type of reservoirs can be given priority in the heat extraction of abandoned wells.
文摘The efficient exploitation of geothermal energy through enhanced geothermal systems(EGS)has been a relevant topic for hot dry rock(HDR)geothermal resources.When cryogenic fluid is injected into a thermal reservoir,improving heat exchange efficiency is key to achieving the optimal exploitation of HDR.In this paper,granite outcrops from Gonghe Basin were used as the testing sample.The natural fractures in the granite samples were relatively well developed.To simulate long-term injection and production from multi-wells in situ,physical ex-periments were performed in a newly-developed,in-house large-scale true triaxial experimental system.Geothermal extraction performance of an HDR was simulated for long-term injection and production operations.Simultaneously,the mode of one-injection and multiple-production wells was represented.In the paper,the ef-fects of the production-injection well spacing,the number of production wells and the injection rate on the production temperature and flow rate are discussed.The results show that,during long-term injection and pro-duction,there are two stages of production temperature variation,namely stabilization and attenuation.When the number of the production wells is increased,the heat extraction efficiency is accelerated.Moreover,competitive diversion of fluid among fractures occurred due to different conductivities.Furthermore,under different pro-duction modes,the production flow rate contributed differently to the heat extraction.Finally,the effect of the production-injection wells spacing on the heat exchange performance was analyzed;this is mainly reflected in the change of the effective heat exchange area between the rock and the injected fluid.The results emphasize the importance of designing an appropriate production mode and optimizing the injection-production parameters to ensure efficient HDR exploitation.
基金support by the Shanghai Engineering Research Center for Shallow Geothermal Energy(DRZX-202306)Shaanxi Coal Geology Group Co.,Ltd.(SMDZ-ZD2024-23)+4 种基金Key Laboratory of Coal Resources Exploration and Comprehensive Utilization,Ministry of Natural Resources,China(ZP2020-1)Shaanxi Investment Group Co.,Ltd.(SIGC2023-KY-05)Key Research and Development Projects of Shaanxi Province(2023-GHZD-54)Shaanxi Qinchuangyuan Scientist+Engineer Team Construction Project(2022KXJ-049)China Postdoctoral Science Foundation(2023M742802,2024T170721).
文摘Geothermal energy,a form of renewable energy,has been extensively utilized for building heating.However,there is a lack of detailed comparative studies on the use of shallow and medium-deep geothermal energy in building energy systems,which are essential for decision-making.Therefore,this paper presents a comparative study of the performance and economic analysis of shallow and medium-deep borehole heat exchanger heating systems.Based on the geological parameters of Xi’an,China and commonly used borehole heat exchanger structures,numerical simulationmethods are employed to analyze performance and economic efficiency.The results indicate that increasing the spacing between shallow borehole heat exchangers can effectively reduce thermal interference between the pipes and improve heat extraction performance.As the flow rate increases,the outlet water temperature ranges from 279.3 to 279.7 K,with heat extraction power varying between 595 and 609 W.For medium-deep borehole heat exchangers,performance predictions show that a higher flow rate results in greater heat extraction power.However,when the flow rate exceeds 30 m^(3)/h,further increases in flow rate have only a minor effect on enhancing heat extraction power.Additionally,the economic analysis reveals that the payback period for shallow geothermal heating systems ranges from 10 to 11 years,while for medium-deep geothermal heating systems,it varies more widely from 3 to 25 years.Therefore,the payback period for medium-deep geothermal heating systems is more significantly influenced by operational and installation parameters,and optimizing these parameters can considerably shorten the payback period.The results of this study are expected to provide valuable insights into the efficient and cost-effective utilization of geothermal energy for building heating.
基金supported by the Preventive medicine and public health research project of Anhui,China(No.2011Y0103)the Natural Science Foundation of Anhui,China(No.11040606M216)
文摘To establish an analytical method for determination of four bisphenols （BPA, BPB, BPF, and BPS） and two alkylphenols （4-n-OP, 4-n-NP） in water by ultra performance liquid chromatography- tandem mass spectrometry （UPLC/MS/MS）. The water samples were extracted and condensed with solid-phase extraction （SPE） using C18 cartridges and eluted by acetonitrile. Separation was carried out with Acquity BEH C8 column and detection were performed by UPLC/MS/MS. Quantification was calculated by using the internal standard BPA-d16 and 4-n-NP-d8. The linear correlation coefficients of these compounds in the range of 1.0-100.0μg/L were all over 0.999. The minimum detectable concentrations were 0.75-1.0 ng/L, and the recoveries ranged from 87.0% to 106.9%.
基金supported by the National Natural Science Foundation of China (Grant No.20775074)
文摘The procedures of ultrasonic extraction and clean-up were optimized for the determination of polycyclic aromatic hydrocarbons (PAHs) in marine sediments. Samples were ultrasonically extracted, and the extracts were purified with a miniaturized silica gel chromatographic column and analyzed with high performance liquid chromatography (HPLC) with a fluorescence detector. Ultrasonication with methanol-dichloromethane (2:1, v/v) mixture gave higher extraction efficiency than that with dichloromethane. Among the three elution solvents used in clean-up step, dichloromethane-hexane (2:3, v/v) mixture was the most satisfactory. Under the optimized conditions, the recoveries in the range of 54.82% to 94.70% with RSDs of 3.02% to 23.22% for a spiked blank, and in the range of 61.20% to 127.08% with RSDs of 7.61% to 26.93% for a spiked matrix, were obtained for the 15 PAHs studied, while the recoveries for a NIST standard reference SRM 1941b were in the range of 50.79% to 83.78% with RSDs of 5.24% to 21.38%. The detection limits were between 0.75 ng L-1 and 10.99 ng L-1for different PAHs. A sample from the Jiaozhou Bay area was examined to test the established methods.
基金Financial support from the National Natural Science Foundation of China (Nos. 31471643, 31571925)the Innovation Research Program of the Department of Education of Hebei for Hebei Provincial Universities (No. LJRC009)
文摘In this work, a metal-organic framework derived nanoporous carbon （MOF-5-C） was fabricated and modified with Fe3O4 magnetic nanoparticles. The resulting magnetic MOF-5-derived porous carbon （Fe304@MOF-5-C） was then used for the magnetic solid-phase extraction of chlorophenols （CPs） from mushroom samples prior to high performance liquid chromatography-ultraviolet detection. Scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and N2 adsorption were used to characterize the adsorbent. After experimental optimization, the amount of the adsorbent was chosen as 8.0 mg, extraction time as 10 min, sample volume as 50 mL, desorption solvent as 0.4 mL （0.2 mL × 2） of alkaline methanol, and sample pH as 6. Under the above optimized conditions, good linearity for the analytes was obtained in the range of 0.8-100.0 ng g 1 with the correlation coefficients between 0.9923 and 0.9963. The limits of detection （SIN= 3） were in the range of 0.25-0.30 ng g-1, and the relative standard deviations were below 6.8%. The result showed that the Fe304@MOF-5-C has an excellent adsorption capacity for the analytes.
基金Department of Chemistry at Mississippi State University for financial support for this project
文摘An improved method for trace level quantification of dicyandiamide in stream water has been developed. This method includes sample pretreatment using solid phase extraction.The extraction procedure（including loading, washing, and eluting） used a flow rate of1.0 m L/min, and dicyandiamide was eluted with 20 m L of a methanol/acetonitrile mixture（V/V = 2：3）, followed by pre-concentration using nitrogen evaporation and analysis with high performance liquid chromatography–ultraviolet spectroscopy（HPLC–UV）. Sample extraction was carried out using a Waters Sep-Pak AC-2 Cartridge（with activated carbon）.Separation was achieved on a ZIC-Hydrophilic Interaction Liquid Chromatography（ZIC-HILIC）（50 mm × 2.1 mm, 3.5 μm） chromatography column and quantification was accomplished based on UV absorbance. A reliable linear relationship was obtained for the calibration curve using standard solutions（R^2〉 0.999）. Recoveries for dicyandiamide ranged from 84.6% to 96.8%, and the relative standard deviations（RSDs, n = 3） were below 6.1% with a detection limit of 5.0 ng/m L for stream water samples.
文摘The phenc, lic compounds found in mango fruit are antioxidants, and contribute to a reduction in the risk of cardiovascular diseases. Mango carotenoids are synthesized in mango fruit during ripening. A major by-product of mango fruit is the skin, which is available after the fruits is consumed or used, particularly in the preparation of jams and fruit juices by the fruit canning industry. The objective of this study was to investigate the effects of dietary mango skin （MS） or mango skin combined with paprika extracts （PE） on production performance, egg quality, and egg yolk polyphenols. Total of 60 44-week-old Boris Brown hens was assigned, based on egg production rate and body weight, to 6 groups （10 birds in each group）. The laying hens were fed a basal diet （control group, 18 CP, 2,800 kcal/kg ME）, a basal diet supplemented with 0.1% PE, 1% or 5% MS, or with a mixture of 0.1% PE with 1% or 5% MS respectively. During the three-week experimental feeding period, the birds had free access to feed and water. Feed consumption was measured weekly and egg production was recorded daily. The results for initial body weight, feed consumption, hen-day production, egg mass, mortality, and final body weight did not indicate any effects of the different treatments （P 〉 0.05）. There were no significant differences （P 〉 0.05） in shell-breaking strength, shell thickness, shell ratio, yolk ratio or Haugh units, except in the case of egg yolk color. Roche yolk color fan scores were better in all experimental groups than in the control （P 〈 0.0001）. The yolk color, yellow index, and ratio of redness to yellowness were greater （P 〈 0.0001） in the 0.1% PE, the 0.1% PE ＋ 1% MS, and the 0.1% PE ＋ 5% MS group than in the 1%, 5% MS, and control groups. Compared with the control, lightness was decreased significantly in the 0.1% PE, the 0.1% PE ＋ 1% MS, and the 0.1% PE ＋ 5% MS groups （P 〈 0.05）, whereas redness was increased significantly in the 0.1% PE, 0.1% PE ＋ 1% MS, and 0.1% PE ＋ 5% MS groups （P 〈 0.0001）. No significant differences among the treatments were observed in either yellowness or egg yolk polyphenols. The results of the present experiment indicate that dietary mango skin or mango skin combined with paprika extracts did not show adverse effects on production performance, egg quality or egg yolk polyphenols. Moreover, supplementation with only mango skin did not enhance egg yolk color.
基金Supported by the National High Technology Research and Development Program of China (No. 2009AA063103)the National Natural Science Foundation of China (No. 41030531)
文摘Problems associated with organochlorine pesticide （OCP）-contaminated sites in China have received wide attention. To solve such problems, innovative ex-situ methods of site remediation are urgently needed. We investigated the feasibility of the extraction method with different organic solvents, ethanol, 1-propanol, and three fractions of petroleum ether, using a soil collected from Wujiang （W J）, China, a region with long-term contamination of dichlorodiphenyltrichloroethanes （DDTs）. We evaluated different influential factors, including organic solvent concentration, washing time, mixing speed, solutiomto-soil ratio, and washing temperature, on the removal of DDTs from the WJ soil. A set of relatively better parameters were selected for extraction with 100 mL L-1 petroleum ether （60-90 ℃）： washing time of 180 min, mixing speed of 100 r min-I, solution-to-soil ratio of 10：1, and washing temperature of 50 ℃. These selected parameters were also applied on three other seriously OCP-polluted soils. Results demonstrated their broad-spectrum effectiveness and excellent OCP extraction performance on the contaminated soils with different characteristics.
基金Supported by the National Natural Science Foundation of China(52192622,52304003).
文摘Based on the independently developed true triaxial multi-physical field large-scale physical simulation system of in-situ injection and production,we conducted physical simulation of long-term multi-well injection and production in the hot dry rocks of the Gonghe Basin,Qinghai Province,NW China.Through multi-well connectivity experiments,the spatial distribution characteristics of the natural fracture system in the rock samples and the connectivity between fracture and wellbore were clarified.The injection and production wells were selected to conduct the experiments,namely one injection well and two production wells,one injection well and one production well.The variation of several physical parameters in the production well was analyzed,such as flow rate,temperature,heat recovery rate and fluid recovery.The results show that under the combination of thermal shock and injection pressure,the fracture conductivity was enhanced,and the production temperature showed a downward trend.The larger the flow rate,the faster the decrease.When the local closed area of the fracture was gradually activated,new heat transfer areas were generated,resulting in a lower rate of increase or decrease in the mining temperature.The heat recovery rate was mainly controlled by the extraction flow rate and the temperature difference between injection and production fluid.As the conductivity of the leak-off channel increased,the fluid recovery of the production well rapidly decreased.The influence mechanisms of dominant channels and fluid leak-off on thermal recovery performance are different.The former limits the heat exchange area,while the latter affects the flow rate of the produced fluid.Both of them are important factors affecting the long-term and efficient development of hot dry rock.
基金supported by the 12th five-year National Science and Technology plan of China(2012BAC01B03)the 111 Project of China(B13007)
文摘Phellodendron amurense has been used for many years as a medical plant in traditional Chinese medicine and has shown great prospect in recent clinical trials for future applications. Berberine is an essential active compound contained in P. amurense. Our objective in this study was to quantify the content of berberine in P.amurense from sites at different elevations on Changbai Mountain. We collected samples of P. amurense from five different elevations on Changbai Mountain. Berberine in samples was extracted by ultrahigh pressure extraction（UPE）. And the quantity was measured by high performance liquid chromatography（HPLC）. First, the optimal HPLC conditions for berberine were identified with satisfactory precision（relative standard deviation, R SD／5.6 %）, good accuracy（relative error, R E／ 3.6 %） and good linear relation（R2= 0.9998） in the range of 6.576–328.8 mg L-1. Second, the combination of UPE and HPLC methods in quantitative analysis of berberine showed high repeatability（R SD= 3.28 %）, reproducibility（R SD= 4.72 %）,stability（R SD／ 1.27 %） and good recovery（99.54 %） for real plant materials. Samples from Heilongjiang Province at the lowest elevation contained the highest amount of berberine.Similarly, the lowest amount of berberine was recorded in samples from Changbai Forest Bureau of Jilin Province collected at the highest elevation in this paper. The proposed UPE–HPLC method is simple, reliable and low-cost for quantitative analysis of berberine. Content of berberine in P.amurense varied significantly by site on Changbai Mountain.
