The slag composition corresponding to different coals varies significantly,which directly affects the operation of industrial entrained-flow gasifier and the service life of refractory bricks.In this study,the corrosi...The slag composition corresponding to different coals varies significantly,which directly affects the operation of industrial entrained-flow gasifier and the service life of refractory bricks.In this study,the corrosion resistance of several typical coal slags for gasification on high chromia refractory bricks was comparatively investigated by static laboratory crucible tests and thermodynamic simulations.The results demonstrated that the corrosion degree of high chromia refractory bricks by different coal slags was high-Ca/Na slag>high-Fe slag>high-Si/Al slag.The surface structure of the refractory was relatively flat after corrosion by high-Si/Al slag,and the primary corrosion reaction was the partial dissolution of the matrix by the slag.High-Fe slag was prone to the precipitation of iron phases as well as the formation of(Mg,Fe)(Al,Cr)_(2)O_(4)composite spinel layer at the slag/refractory interface.The high-Ca/Na slag was susceptible to react with the refractory to yield a low melting point phase,which led to the destruction of the matrix structure of the refractory and an isolated distribution of particles.In addition,the monoclinic ZrO_(2) in the refractory reacted with CaO in the slag to formed calcium zirconate,which loosened its phase toughening effect,was the primary factor that aggravated the refractory corrosion.展开更多
The syngas composition change during the measurement process was analyzed using a detailed gas phase reaction mechanism.Results showed that the measurement error induced by the temperature and pressure change in the m...The syngas composition change during the measurement process was analyzed using a detailed gas phase reaction mechanism.Results showed that the measurement error induced by the temperature and pressure change in the measurement process cannot be ignored.Based on the results,suggestions were proposed for syngas concentration measurement and temperature measurement.展开更多
A computational particle fluid dynamics simulation model for entrained-flow gasification was established in this study.The simulation results agree with the experimental data.The detailed particle information and resi...A computational particle fluid dynamics simulation model for entrained-flow gasification was established in this study.The simulation results agree with the experimental data.The detailed particle information and residence-time distribution were obtained by injecting particle tracers in the simulation.The results show that the particles in the gasifier can be classified into three flowing zones,i.e.a fast-flowing zone,a recirculation zone and a spreading zone.The criterion for this classification was also provided.The rapid gas expansion caused by the fast reactions plays a significant role in forming the particle stream into these three zones.It accelerates the particles in the centre of the gasifier while pushing the particles near the expansion edge into the gas recirculation.Also,the concentrated oxygen distribution in the gasifier results in the formation of high-and low-temperature regions.The particles in the fast-flowing zone flow directly through the high-temperature region and most of these particles in this zone were fully reacted with a short residence time.Since particles in the recirculation zone are in a relatively low-temperature region,most of these particles are not fully gasified,although with a long residence time.The rest of particles in the spreading zone show moderate properties between the above two zones.展开更多
A mild gasification process has been implemented to provide an alternative form of clean coal technology called the Integrated Mild Gasification Combined Cycle (IMGCC), which can be utilized to build a new, highly eff...A mild gasification process has been implemented to provide an alternative form of clean coal technology called the Integrated Mild Gasification Combined Cycle (IMGCC), which can be utilized to build a new, highly efficient, and compact power plant or to retrofit an existing coal-fired power plant in order to achieve lower emissions and significantly improved thermal efficiency. The core technology of the mild gasification power plant lies on the design of a compact and effective mild gasifier that can produce synthesis gases with high energy volatiles through a hybrid system: utilizing the features of both entrained-flow and fluidized bed gasifiers. To aid in the design of the mild gasifier, a computational model has been implemented to investigate the thermal-flow and gasification process inside this mild gasifier using the commercial CFD (Computational Fluid Dynamics) solver ANSYS/FLUENT. The Eulerian-Eulerian method is employed to model both the primary phase (air) and the secondary phase (coal particles). However, the Eulerian-Eulerian model used in the software does not facilitate any built-in devolatilization model. The objective of this study is therefore to implement a devolatilization model (along with demoisturization) and incorporate it into the existing code. The Navier-Stokes equations and seven species transport equations are solved with three heterogeneous (gas-solid) and two homogeneous (gas-gas) global gasification reactions. Implementation of the complete model starts from adding demoisturization first, then devolatilization, and then adding one chemical equation at a time until finally all reactions are included in the multiphase flow. The result shows that the demoisturization and devolatilization models are successfully incorporated and a large amount of volatiles are preserved as high-energy fuels in the syngas stream without being further cracked or reacted into lighter gases. The overall results are encouraging but require future experimental data for verification.展开更多
The traditional practice of employing a two-stage coal-fed gasification process is to feed all of the oxygen to provide a vigorous amount of combustion in the first stage but only feed the coal without oxygen in the s...The traditional practice of employing a two-stage coal-fed gasification process is to feed all of the oxygen to provide a vigorous amount of combustion in the first stage but only feed the coal without oxygen in the second stage to allow the endothermic gasification process to occur downstream of the second stage. One of the merits of this 2-stage practice is to keep the gasifier temperature low downstream from the 2nd stage. This helps to extend the life of refractory bricks, decrease gasifier shut-down frequency for scheduled maintenance, and reduce the maintenance costs. In this traditional 2-stage practice, the temperature reduction in the second stage is achieved at the expense of a higher than normal temperature in the first stage. This study investigates a concept totally opposite to the traditional two-stage coal feeding practices in which the injected oxygen is split between the two stages, while all the coal is fed into the first stage. The hypothesis of this two-stage oxygen injection is that a distributed oxygen injection scheme can also distribute the release of heat to a larger gasifier volume and, thus, reduce the peak temperature distribution in the gasifier. The increased life expectancy and reduced maintenance of the refractory bricks can prevail in the entire gasifier and not just downstream from the second stage. In this study, both experiments and computational simulations have been performed to verify the hypothesis. A series of experiments conducted at 2.5 - 3.0 bars shows that the peak temperature and temperature range in the gasifier do decrease from 600?C - 1550?C with one stage oxygen injection to 950?C - 1230?C with a 60 - 40 oxygen split-injection. The CFD results conducted at 2.5 bars show that 1) the carbon conversion ratio for different oxygen injection schemes are all above 95%;2) H2 (about 70% vol.) dominates the syngas composition at the exit;3) the 80% - 20% case yields the lowest peak temperature and the most uniform temperature distribution along the gasifier;and 4) the 40% - 60% case produces the syngas with the highest HHV. Both experimental data and CFD predictions verify the hypothesis that it is feasible to reduce the peak temperature and achieve more uniform temperature in the gasifier by adequately controlling a two-stage oxygen injection with only minor changes of the composition and heating value of the syngas.展开更多
A three stage equilibrium model is developed for coal gasification in the Texaco type coal gasifiersbased on Aspen Plus to calculate the composition of product gas, carbon conversion, and gasification teml^erature. Th...A three stage equilibrium model is developed for coal gasification in the Texaco type coal gasifiersbased on Aspen Plus to calculate the composition of product gas, carbon conversion, and gasification teml^erature. The model is divided into three stages including pyrolysis and combustion stage, char gas reaction stage, and gas p.hase reaction stage. Part of the water produced in thepyrolysis and combust!on stag.e is assumed to be involved inthe second stage to react with the unburned carbon. Carbon conversion is then estimated in the second stage by steam participation ratio expressed as a function of temperature. And the gas product compositions are calculated from gas phase reactions in the third stage. The simulation results are consistent with published experimental data.展开更多
Gasification technology is suggested to utilize asphalt particles, which are produced in the heavy oil deep separation process of using coupled low temperature separation of solvent and post extraction residue. In thi...Gasification technology is suggested to utilize asphalt particles, which are produced in the heavy oil deep separation process of using coupled low temperature separation of solvent and post extraction residue. In this work, the asphalt particles were first slurried with water and then gasified to produce synthesis gas. The gasification process of asphalt water slurry in an entrained flow gasifier was simulated using a three-dimensional computational fluid dynamics （CFD） model based on an Eulerian- Lagrangian method. The trajectories and residence time of asphalt particles, and the reaction rates, gas species distribution, temperature field and carbon conversion in the entrained flow gasifier were obtained. The predicted results indicated that the asphalt water slurry was a good feedstock for gasification. Moreover, the effects of particle size, oxygen equivalence ratio, and mass content of asphalt particles on the gasification performance of asphalt water slurry were investigated. These results are helpful for industrial application of asphalt water slurry gasification technology.展开更多
Based on the principle of discrete element method （DEM）, a 2D slot model of a COREX melter gasifier was established to analyze the influence of cohesive zone shape on solid flow, including mass distribution, velocit...Based on the principle of discrete element method （DEM）, a 2D slot model of a COREX melter gasifier was established to analyze the influence of cohesive zone shape on solid flow, including mass distribution, velocity distribution, normal force distribution and porosity distribution at a microscopic level. The results show that the co- hesive zone shape almost does not affect the particle movement in the upper shaft and deadman shape. The particles in the lower central bottom experience large normal force to support the particles above them, while particles around the raceway and in the fast flow zone exhibit weak force network. The porosity distribution was also examined under three kinds of cohesive zones. Like the velocity distribution, the whole packed bed can be divided into four main re- gions. With the increase of cohesive zone position, the low porosity region located in the root of cohesive zone increa- ses. And the porosity distribution becomes asymmetric in the case of biased cohesive zone.展开更多
COREX process is one of the earliest industrialized smelting reduction ironmaking technology.A numerical simulation model based on discrete element method(DEM)has been developed to analyze the burden distribution in t...COREX process is one of the earliest industrialized smelting reduction ironmaking technology.A numerical simulation model based on discrete element method(DEM)has been developed to analyze the burden distribution in the melter gasifier of COREX process.The DEM considering the collisions between particles can directly reproduce the charging process.The burden trajectory,the location and the burden surface profile are analyzed in melter gasifier with a mixing charging of coal and direct reduction iron(DRI)at the same time.Considering the porosity of packed bed has an important effect on the gas flow distribution of melter gasifier,a method to calculate porosity has been proposed.The distribution of DRI and coal and the porosity in the radial direction are given under different charging patterns,which is necessary to judge the gas flow distribution and provide base data for further researching the melter gasifier for the next work in the future.The research results can be used to guide the operation of adjusting charging and provide important basis for optimizing the charging patterns in order to obtain the reasonable gas distribution.展开更多
A local thermal stress model of water-cooled-wall pulverized-coal gasifier was built, and ANSYS was used to simulate the stress field in the gasifier operation to research the damage of refractories and slag layer cau...A local thermal stress model of water-cooled-wall pulverized-coal gasifier was built, and ANSYS was used to simulate the stress field in the gasifier operation to research the damage of refractories and slag layer caused by the thermal stress. The results reveal that:（1） the maximum stress of water-cooled-wall gasifier appears at the interface between anchor nails and refractories as well as the interface between refractories and the slag layer, and the maximum stress of slag layer appears on the surface of the slag layer;（2） the increase of slag layer thickness can significantly reduce the thermal stress at the interface between anchor nails and refractories, but increase the thermal stress between slag layer and refractories;（3） when the therma I conductivity is 2-6 W · m-1 · K-1, the thermal stress increases rapidly with the increase of the thermal conductivity, but when the thermal conductivity is 6-10 W · m-1 · K-1, the thermal stress is basically stable;（4） the higher the cooling rate, the faster the decreasing speed of the temperature and thermal stress.展开更多
With the help of Aspen Plus,a two-dimensional unsteady CFD model is developed to simulate the coal gasification process in a fixed bed gasifier.A developed and validated two dimensional CFD model for coal gasification...With the help of Aspen Plus,a two-dimensional unsteady CFD model is developed to simulate the coal gasification process in a fixed bed gasifier.A developed and validated two dimensional CFD model for coal gasification has been used to predict and assess the viability of the syngas generation from coal gasification employing the updraft fixed bed gasifier.The process rate model and the sub-model of gas generation are determined.The particle size variation and char burning during gasification are also taken into account.In order to verify the model and increase the understanding of gasification characteristics,a set of experiments and numerical comparisons have been carried out.The simulated results in the bed are used to predict the composition of syngas and the conversion of carbon.The model proposed in this paper is a promising tool for simulating the coal gasification process in a fixed bed gasifier.展开更多
The temperature distribution of COREX melter gasifier was studied by using a two-dimensional 1/30 scale thermal dynamic model.A set of operating conditions,such as radial distribution of direct reduction iron（DRI） t...The temperature distribution of COREX melter gasifier was studied by using a two-dimensional 1/30 scale thermal dynamic model.A set of operating conditions,such as radial distribution of direct reduction iron（DRI） to lump coal and coke volume ratio,coke charging location,coke charging amount and coke size,were taken into account.The results show that the temperature near the wall region decreases with the decrease of the radial distribution of DRI to lump coal and coke volume ratio.The temperature with central coke charging is higher than that without central coke column.Furthermore,the temperature significantly increases with the increase of central coke charging amount.With the increase of intermediate coke charging amount,the temperature near the wall region decreases while the temperature in the intermediate region increases.The temperature increases with the increase of coke size whether charging central coke or intermediate coke.展开更多
The variation of toxic pollutants emission during a feeding cycle was examined by field monitoring from a batch feeding updraft fixed bed gasifier for disposing rural domestic solid waste. Results showed that the cont...The variation of toxic pollutants emission during a feeding cycle was examined by field monitoring from a batch feeding updraft fixed bed gasifier for disposing rural domestic solid waste. Results showed that the content of oxygen in flue gas gradually increased, while SO_2 and HCl in flue gas decreased with time after feeding in a whole feeding cycle. Although large amount of CO was produced during the gasifying, low CO content in flue gas could be obtained after the heat treatment with an electric heating device. The distribution characteristics of dioxin congeners in flue gas indicted the re-synthesis of dioxins after flue gas heating, and the increase of oxygen promoted the synthesis of dioxins. The emission content of dioxins could meet the standard(0.1 ng I-TEQ·m^(-3),GB18458-2014) of China when the oxygen content was controlled below 8.3%. Hence, for a batch feeding gasifier,low oxygen condition should be offered by reducing air intake at the later stage of feeding cycle in order to decrease the re-synthesis of dioxins after the flue gas heating.展开更多
To reveal the damage mechanism of high chrome bricks for opposed multi nozzle gasifier with expanded diameter,the chemical composition and the morphology of a used high chrome brick were researched using XRF,SEM and E...To reveal the damage mechanism of high chrome bricks for opposed multi nozzle gasifier with expanded diameter,the chemical composition and the morphology of a used high chrome brick were researched using XRF,SEM and EDS,and the properties of the high chrome bricks were improved by adding ultra fine alumina,alumina-chrome-iron oxide synthetic material with spinel structure,and chromium metal.The results show that(1)the high chrome brick is seriously damaged by the chemical dissolution of chrome as well as the chemical reactions at the slag/brick interface,the slag penetration and the structural spalling;(2)FeO in the slag reacts with Cr_(2)O_(3)in the brick to form a FeCr_(2)O_(4)layer on the particle surface thus leading to spalling;CaO reacts with SiO_(2)and Al2O3 in the brick forming a metamorphic layer of low melting point materials;due to the different thermal expansion coefficients of the metamorphic layer and the original brick,cracks appear and continue to expand and deepen under multiple temperature and pressure fluctuations thus leading to spalling of brick layer;(3)the improved brick has decreased apparent porosity,increased bulk density and compressive strength,and better thermal shock resistance compared with the original brick;after one cycle of on-site application,the furnace lining surface is smooth and flat with little damage,indicating that the improved high chrome bricks basically meet the working condition requirements of the opposed multi nozzle gasifier with expanded diameter,however,the final effects need to be evaluated in detail after the whole furnace service.展开更多
India is having more than 500,000 villages of which about 85% have been electrified. But as per RGGVY （Rejiv Gandhi Grammen Vidyutikaran Yojana）, the rate of village electrification is much lower as household connec...India is having more than 500,000 villages of which about 85% have been electrified. But as per RGGVY （Rejiv Gandhi Grammen Vidyutikaran Yojana）, the rate of village electrification is much lower as household connectivity has been fairly low. The rest 15% villages and a larger proportion of households have to be electrified. Villages have been a major concern as cost of electrification is fairly high. The most favored alternative to any kind of users is generation of electricity from diesel generating sets and renewable sources of energy. But the capital cost of renewable energy equipments is fairly high. Gradually, there is a reduction in the prices of these systems due to availability of better technological options and they are becoming competitive to grid electricity. In this paper, an attempt has been made to calculate the cost of production of electricity from stand-alone, off-grid devices biomass gasifiers （both dual fuel and pure gas type） and compare with that of diesel generating sets by using the concept of LCC （life cycle costing） and Homer software. It is found that the cost of per unit electricity generation （kWh） has been always the lowest in comparison to diesel generating sets even if the price of biomass increases to some extent.展开更多
Optimizing operational parameters for syngas production of Texaco coal-water slurry gasifier studied in this paper is a complicated nonlinear constrained problem concerning 3 BP(Error Back Propagation) neural networks...Optimizing operational parameters for syngas production of Texaco coal-water slurry gasifier studied in this paper is a complicated nonlinear constrained problem concerning 3 BP(Error Back Propagation) neural networks. To solve this model, a new 3-layer cultural evolving algorithm framework which has a population space, a medium space and a belief space is firstly conceived. Standard differential evolution algorithm(DE), genetic algorithm(GA), and particle swarm optimization algorithm(PSO) are embedded in this framework to build 3-layer mixed cultural DE/GA/PSO(3LM-CDE, 3LM-CGA, and 3LM-CPSO) algorithms. The accuracy and efficiency of the proposed hybrid algorithms are firstly tested in 20 benchmark nonlinear constrained functions. Then, the operational optimization model for syngas production in a Texaco coal-water slurry gasifier of a real-world chemical plant is solved effectively. The simulation results are encouraging that the 3-layer cultural algorithm evolving framework suggests ways in which the performance of DE, GA, PSO and other population-based evolutionary algorithms(EAs) can be improved,and the optimal operational parameters based on 3LM-CDE algorithm of the syngas production in the Texaco coalwater slurry gasifier shows outstanding computing results than actual industry use and other algorithms.展开更多
A laboratory scale downdraft biomass gasifier was designed to deliver a mechanical power of 4 kW and thermal power of about 15 kW. The gasifier was manufactured as a single piece having a water seal and cover. The gas...A laboratory scale downdraft biomass gasifier was designed to deliver a mechanical power of 4 kW and thermal power of about 15 kW. The gasifier was manufactured as a single piece having a water seal and cover. The gasifier was tested in natural downdraft and forced downdraft mode. Ignition of the fuel beneath the grate, during natural downdraft mode, using wood shavings as fuel, produced gas which burned with a blue flame for 15 minutes. Ignition at the throat, using either palm kernel shells or wood shavings, during the natural downdraft mode, the gasifier did not produce syngas. During the forced downdraft mode, fuel was ignited at the throat. Gasification was successful with the palm kernel shells, during forced downdraft, which produced gas which burned steadily with luminous flame for 15 minutes per kilogram of biomass fed. However, wood shavings experienced some bridging problems during the forced downdraft mode of operation. The fuel conversion rate of the gasifier, when using palm kernel shells as fuel in forced downdraft mode, was 4 kg/h. Forced downdraft mode of operation yielded better results and is the preferred operation of the gasifier.展开更多
Sulphonated nano-structured micro-porous ion exchange polymers, known as sulphonated PolyHIPE Polymers （s-PHPs） were used in syngas cleaning to investigate their impact on tar composition, concentration and dew poin...Sulphonated nano-structured micro-porous ion exchange polymers, known as sulphonated PolyHIPE Polymers （s-PHPs） were used in syngas cleaning to investigate their impact on tar composition, concentration and dew point depression during the gasification of fuel cane bagasse as a model biomass. The results showed that the s-PHPs used as a secondary syngas treatment system, was highly effective at adsorbing and reducing the concentration of all class of tars in syngas by 95%-80% which resulted in tar dew point depression from 90 ~C to 73 ~C. It was shown that tars underwent chemical reactions within s-PHPs, indicating that tar diffusion from syngas was driven by chemical potential. It was also observed that s-PHPs also captured ash forming elements from syngas. The use of s-PHPs in gasification as well as in an integrated thermochemical biorefinery technology is discussed since the tar loaded s-PHPs can be used as natural herbicides in the form of soil additives to enhance the biomass growth and crop yield.展开更多
Slagging coal gasification process became a highlight of coal chemical industry in China during the last decade. Refractory lining＇ s life of slagging gasifiers is one of the most critical factors for a cost - effect...Slagging coal gasification process became a highlight of coal chemical industry in China during the last decade. Refractory lining＇ s life of slagging gasifiers is one of the most critical factors for a cost - effective operation. The paper introduces current status of coal gasification in China, lining structure of slagging gasifiers and performance of refractory lining. It also summarizes the major factors impacting on refractory wear in slagging coal gasifiers in four Chinese chemical plants, based on ten years of industrial experience. The utilizability is discussed in terms of cost -effectiveness of high chromia refractories and possibility of the alternatives.展开更多
Research was focused on slag corrosion mechanism of high chrome bricks used for different types of gasifier by comparing the structure of high chrome bricks for petroleum coke gasifier and water-coal slurry gasifier w...Research was focused on slag corrosion mechanism of high chrome bricks used for different types of gasifier by comparing the structure of high chrome bricks for petroleum coke gasifier and water-coal slurry gasifier with slag corroded testing brick and water coal slurry gasifier through Scanning Electron Microscope （SEM） examination and X-ray diffi＇action. Results show that for high chrome brick used for petroleum coke gasifier, corrosion is mainly caused by Cr2O3 in the brick and V2O5 in molten slag and liquid phase generation at low temperature; for high chrome brick used for water-coal slurry gasifier, corrosion is caused by dissolution of Cr2O3 in molten slag and corrosion of ZrO2. For LIRR-HK95 brick, it performs better petroleum coke corrosion resistance than the others due to the optimal composition and structure.展开更多
基金financial support from the Joint Funds of the National Natural Science Foundation of China(U21A20318).
文摘The slag composition corresponding to different coals varies significantly,which directly affects the operation of industrial entrained-flow gasifier and the service life of refractory bricks.In this study,the corrosion resistance of several typical coal slags for gasification on high chromia refractory bricks was comparatively investigated by static laboratory crucible tests and thermodynamic simulations.The results demonstrated that the corrosion degree of high chromia refractory bricks by different coal slags was high-Ca/Na slag>high-Fe slag>high-Si/Al slag.The surface structure of the refractory was relatively flat after corrosion by high-Si/Al slag,and the primary corrosion reaction was the partial dissolution of the matrix by the slag.High-Fe slag was prone to the precipitation of iron phases as well as the formation of(Mg,Fe)(Al,Cr)_(2)O_(4)composite spinel layer at the slag/refractory interface.The high-Ca/Na slag was susceptible to react with the refractory to yield a low melting point phase,which led to the destruction of the matrix structure of the refractory and an isolated distribution of particles.In addition,the monoclinic ZrO_(2) in the refractory reacted with CaO in the slag to formed calcium zirconate,which loosened its phase toughening effect,was the primary factor that aggravated the refractory corrosion.
基金sponsored by the State Key Development Program for Basic Research of China(973)under contract 2005CB221207.
文摘The syngas composition change during the measurement process was analyzed using a detailed gas phase reaction mechanism.Results showed that the measurement error induced by the temperature and pressure change in the measurement process cannot be ignored.Based on the results,suggestions were proposed for syngas concentration measurement and temperature measurement.
文摘A computational particle fluid dynamics simulation model for entrained-flow gasification was established in this study.The simulation results agree with the experimental data.The detailed particle information and residence-time distribution were obtained by injecting particle tracers in the simulation.The results show that the particles in the gasifier can be classified into three flowing zones,i.e.a fast-flowing zone,a recirculation zone and a spreading zone.The criterion for this classification was also provided.The rapid gas expansion caused by the fast reactions plays a significant role in forming the particle stream into these three zones.It accelerates the particles in the centre of the gasifier while pushing the particles near the expansion edge into the gas recirculation.Also,the concentrated oxygen distribution in the gasifier results in the formation of high-and low-temperature regions.The particles in the fast-flowing zone flow directly through the high-temperature region and most of these particles in this zone were fully reacted with a short residence time.Since particles in the recirculation zone are in a relatively low-temperature region,most of these particles are not fully gasified,although with a long residence time.The rest of particles in the spreading zone show moderate properties between the above two zones.
文摘A mild gasification process has been implemented to provide an alternative form of clean coal technology called the Integrated Mild Gasification Combined Cycle (IMGCC), which can be utilized to build a new, highly efficient, and compact power plant or to retrofit an existing coal-fired power plant in order to achieve lower emissions and significantly improved thermal efficiency. The core technology of the mild gasification power plant lies on the design of a compact and effective mild gasifier that can produce synthesis gases with high energy volatiles through a hybrid system: utilizing the features of both entrained-flow and fluidized bed gasifiers. To aid in the design of the mild gasifier, a computational model has been implemented to investigate the thermal-flow and gasification process inside this mild gasifier using the commercial CFD (Computational Fluid Dynamics) solver ANSYS/FLUENT. The Eulerian-Eulerian method is employed to model both the primary phase (air) and the secondary phase (coal particles). However, the Eulerian-Eulerian model used in the software does not facilitate any built-in devolatilization model. The objective of this study is therefore to implement a devolatilization model (along with demoisturization) and incorporate it into the existing code. The Navier-Stokes equations and seven species transport equations are solved with three heterogeneous (gas-solid) and two homogeneous (gas-gas) global gasification reactions. Implementation of the complete model starts from adding demoisturization first, then devolatilization, and then adding one chemical equation at a time until finally all reactions are included in the multiphase flow. The result shows that the demoisturization and devolatilization models are successfully incorporated and a large amount of volatiles are preserved as high-energy fuels in the syngas stream without being further cracked or reacted into lighter gases. The overall results are encouraging but require future experimental data for verification.
文摘The traditional practice of employing a two-stage coal-fed gasification process is to feed all of the oxygen to provide a vigorous amount of combustion in the first stage but only feed the coal without oxygen in the second stage to allow the endothermic gasification process to occur downstream of the second stage. One of the merits of this 2-stage practice is to keep the gasifier temperature low downstream from the 2nd stage. This helps to extend the life of refractory bricks, decrease gasifier shut-down frequency for scheduled maintenance, and reduce the maintenance costs. In this traditional 2-stage practice, the temperature reduction in the second stage is achieved at the expense of a higher than normal temperature in the first stage. This study investigates a concept totally opposite to the traditional two-stage coal feeding practices in which the injected oxygen is split between the two stages, while all the coal is fed into the first stage. The hypothesis of this two-stage oxygen injection is that a distributed oxygen injection scheme can also distribute the release of heat to a larger gasifier volume and, thus, reduce the peak temperature distribution in the gasifier. The increased life expectancy and reduced maintenance of the refractory bricks can prevail in the entire gasifier and not just downstream from the second stage. In this study, both experiments and computational simulations have been performed to verify the hypothesis. A series of experiments conducted at 2.5 - 3.0 bars shows that the peak temperature and temperature range in the gasifier do decrease from 600?C - 1550?C with one stage oxygen injection to 950?C - 1230?C with a 60 - 40 oxygen split-injection. The CFD results conducted at 2.5 bars show that 1) the carbon conversion ratio for different oxygen injection schemes are all above 95%;2) H2 (about 70% vol.) dominates the syngas composition at the exit;3) the 80% - 20% case yields the lowest peak temperature and the most uniform temperature distribution along the gasifier;and 4) the 40% - 60% case produces the syngas with the highest HHV. Both experimental data and CFD predictions verify the hypothesis that it is feasible to reduce the peak temperature and achieve more uniform temperature in the gasifier by adequately controlling a two-stage oxygen injection with only minor changes of the composition and heating value of the syngas.
基金Supported by the Major State Basic Research Development Program of China(2012CB720500)the National Natural Science Foundation of China(U1162202,61174118)+1 种基金the National Science Fund for Outstanding Young Scholars(61222303)Shanghai Leading Academic Discipline Project(B504)
文摘A three stage equilibrium model is developed for coal gasification in the Texaco type coal gasifiersbased on Aspen Plus to calculate the composition of product gas, carbon conversion, and gasification teml^erature. The model is divided into three stages including pyrolysis and combustion stage, char gas reaction stage, and gas p.hase reaction stage. Part of the water produced in thepyrolysis and combust!on stag.e is assumed to be involved inthe second stage to react with the unburned carbon. Carbon conversion is then estimated in the second stage by steam participation ratio expressed as a function of temperature. And the gas product compositions are calculated from gas phase reactions in the third stage. The simulation results are consistent with published experimental data.
基金support by the National Basic Research Program (Grant No. 2010CB226906)the Science Foundation of China University of Petroleum, Beijing (No. KYJJ2012-03-01)
文摘Gasification technology is suggested to utilize asphalt particles, which are produced in the heavy oil deep separation process of using coupled low temperature separation of solvent and post extraction residue. In this work, the asphalt particles were first slurried with water and then gasified to produce synthesis gas. The gasification process of asphalt water slurry in an entrained flow gasifier was simulated using a three-dimensional computational fluid dynamics （CFD） model based on an Eulerian- Lagrangian method. The trajectories and residence time of asphalt particles, and the reaction rates, gas species distribution, temperature field and carbon conversion in the entrained flow gasifier were obtained. The predicted results indicated that the asphalt water slurry was a good feedstock for gasification. Moreover, the effects of particle size, oxygen equivalence ratio, and mass content of asphalt particles on the gasification performance of asphalt water slurry were investigated. These results are helpful for industrial application of asphalt water slurry gasification technology.
基金Item Sponsored by the Fundamental Research Funds for the Central Universities of China(N090402021)
文摘Based on the principle of discrete element method （DEM）, a 2D slot model of a COREX melter gasifier was established to analyze the influence of cohesive zone shape on solid flow, including mass distribution, velocity distribution, normal force distribution and porosity distribution at a microscopic level. The results show that the co- hesive zone shape almost does not affect the particle movement in the upper shaft and deadman shape. The particles in the lower central bottom experience large normal force to support the particles above them, while particles around the raceway and in the fast flow zone exhibit weak force network. The porosity distribution was also examined under three kinds of cohesive zones. Like the velocity distribution, the whole packed bed can be divided into four main re- gions. With the increase of cohesive zone position, the low porosity region located in the root of cohesive zone increa- ses. And the porosity distribution becomes asymmetric in the case of biased cohesive zone.
基金Item Sponsored by Fundamental Research Funds for Central Universities of China(N090402021)
文摘COREX process is one of the earliest industrialized smelting reduction ironmaking technology.A numerical simulation model based on discrete element method(DEM)has been developed to analyze the burden distribution in the melter gasifier of COREX process.The DEM considering the collisions between particles can directly reproduce the charging process.The burden trajectory,the location and the burden surface profile are analyzed in melter gasifier with a mixing charging of coal and direct reduction iron(DRI)at the same time.Considering the porosity of packed bed has an important effect on the gas flow distribution of melter gasifier,a method to calculate porosity has been proposed.The distribution of DRI and coal and the porosity in the radial direction are given under different charging patterns,which is necessary to judge the gas flow distribution and provide base data for further researching the melter gasifier for the next work in the future.The research results can be used to guide the operation of adjusting charging and provide important basis for optimizing the charging patterns in order to obtain the reasonable gas distribution.
文摘A local thermal stress model of water-cooled-wall pulverized-coal gasifier was built, and ANSYS was used to simulate the stress field in the gasifier operation to research the damage of refractories and slag layer caused by the thermal stress. The results reveal that:（1） the maximum stress of water-cooled-wall gasifier appears at the interface between anchor nails and refractories as well as the interface between refractories and the slag layer, and the maximum stress of slag layer appears on the surface of the slag layer;（2） the increase of slag layer thickness can significantly reduce the thermal stress at the interface between anchor nails and refractories, but increase the thermal stress between slag layer and refractories;（3） when the therma I conductivity is 2-6 W · m-1 · K-1, the thermal stress increases rapidly with the increase of the thermal conductivity, but when the thermal conductivity is 6-10 W · m-1 · K-1, the thermal stress is basically stable;（4） the higher the cooling rate, the faster the decreasing speed of the temperature and thermal stress.
基金The research was supported by the National Key Research and Development Project(2016YFB060040202).
文摘With the help of Aspen Plus,a two-dimensional unsteady CFD model is developed to simulate the coal gasification process in a fixed bed gasifier.A developed and validated two dimensional CFD model for coal gasification has been used to predict and assess the viability of the syngas generation from coal gasification employing the updraft fixed bed gasifier.The process rate model and the sub-model of gas generation are determined.The particle size variation and char burning during gasification are also taken into account.In order to verify the model and increase the understanding of gasification characteristics,a set of experiments and numerical comparisons have been carried out.The simulated results in the bed are used to predict the composition of syngas and the conversion of carbon.The model proposed in this paper is a promising tool for simulating the coal gasification process in a fixed bed gasifier.
基金Item Sponsored by Fundamental Research Funds for Central Universities of China(090402021)
文摘The temperature distribution of COREX melter gasifier was studied by using a two-dimensional 1/30 scale thermal dynamic model.A set of operating conditions,such as radial distribution of direct reduction iron（DRI） to lump coal and coke volume ratio,coke charging location,coke charging amount and coke size,were taken into account.The results show that the temperature near the wall region decreases with the decrease of the radial distribution of DRI to lump coal and coke volume ratio.The temperature with central coke charging is higher than that without central coke column.Furthermore,the temperature significantly increases with the increase of central coke charging amount.With the increase of intermediate coke charging amount,the temperature near the wall region decreases while the temperature in the intermediate region increases.The temperature increases with the increase of coke size whether charging central coke or intermediate coke.
基金Supported by the Science and Technology Planning Project of Guangdong Province,China(2013B090600134)the National Natural Science Foundation of China(51608223)the Fund for Basic Scientific Research Business of Central Institutes of Environmental Protection(PM-zx 703-201602-050)
文摘The variation of toxic pollutants emission during a feeding cycle was examined by field monitoring from a batch feeding updraft fixed bed gasifier for disposing rural domestic solid waste. Results showed that the content of oxygen in flue gas gradually increased, while SO_2 and HCl in flue gas decreased with time after feeding in a whole feeding cycle. Although large amount of CO was produced during the gasifying, low CO content in flue gas could be obtained after the heat treatment with an electric heating device. The distribution characteristics of dioxin congeners in flue gas indicted the re-synthesis of dioxins after flue gas heating, and the increase of oxygen promoted the synthesis of dioxins. The emission content of dioxins could meet the standard(0.1 ng I-TEQ·m^(-3),GB18458-2014) of China when the oxygen content was controlled below 8.3%. Hence, for a batch feeding gasifier,low oxygen condition should be offered by reducing air intake at the later stage of feeding cycle in order to decrease the re-synthesis of dioxins after the flue gas heating.
文摘To reveal the damage mechanism of high chrome bricks for opposed multi nozzle gasifier with expanded diameter,the chemical composition and the morphology of a used high chrome brick were researched using XRF,SEM and EDS,and the properties of the high chrome bricks were improved by adding ultra fine alumina,alumina-chrome-iron oxide synthetic material with spinel structure,and chromium metal.The results show that(1)the high chrome brick is seriously damaged by the chemical dissolution of chrome as well as the chemical reactions at the slag/brick interface,the slag penetration and the structural spalling;(2)FeO in the slag reacts with Cr_(2)O_(3)in the brick to form a FeCr_(2)O_(4)layer on the particle surface thus leading to spalling;CaO reacts with SiO_(2)and Al2O3 in the brick forming a metamorphic layer of low melting point materials;due to the different thermal expansion coefficients of the metamorphic layer and the original brick,cracks appear and continue to expand and deepen under multiple temperature and pressure fluctuations thus leading to spalling of brick layer;(3)the improved brick has decreased apparent porosity,increased bulk density and compressive strength,and better thermal shock resistance compared with the original brick;after one cycle of on-site application,the furnace lining surface is smooth and flat with little damage,indicating that the improved high chrome bricks basically meet the working condition requirements of the opposed multi nozzle gasifier with expanded diameter,however,the final effects need to be evaluated in detail after the whole furnace service.
文摘India is having more than 500,000 villages of which about 85% have been electrified. But as per RGGVY （Rejiv Gandhi Grammen Vidyutikaran Yojana）, the rate of village electrification is much lower as household connectivity has been fairly low. The rest 15% villages and a larger proportion of households have to be electrified. Villages have been a major concern as cost of electrification is fairly high. The most favored alternative to any kind of users is generation of electricity from diesel generating sets and renewable sources of energy. But the capital cost of renewable energy equipments is fairly high. Gradually, there is a reduction in the prices of these systems due to availability of better technological options and they are becoming competitive to grid electricity. In this paper, an attempt has been made to calculate the cost of production of electricity from stand-alone, off-grid devices biomass gasifiers （both dual fuel and pure gas type） and compare with that of diesel generating sets by using the concept of LCC （life cycle costing） and Homer software. It is found that the cost of per unit electricity generation （kWh） has been always the lowest in comparison to diesel generating sets even if the price of biomass increases to some extent.
基金Supported by the National Natural Science Foundation of China(61174040,U1162110,21206174)Shanghai Commission of Nature Science(12ZR1408100)
文摘Optimizing operational parameters for syngas production of Texaco coal-water slurry gasifier studied in this paper is a complicated nonlinear constrained problem concerning 3 BP(Error Back Propagation) neural networks. To solve this model, a new 3-layer cultural evolving algorithm framework which has a population space, a medium space and a belief space is firstly conceived. Standard differential evolution algorithm(DE), genetic algorithm(GA), and particle swarm optimization algorithm(PSO) are embedded in this framework to build 3-layer mixed cultural DE/GA/PSO(3LM-CDE, 3LM-CGA, and 3LM-CPSO) algorithms. The accuracy and efficiency of the proposed hybrid algorithms are firstly tested in 20 benchmark nonlinear constrained functions. Then, the operational optimization model for syngas production in a Texaco coal-water slurry gasifier of a real-world chemical plant is solved effectively. The simulation results are encouraging that the 3-layer cultural algorithm evolving framework suggests ways in which the performance of DE, GA, PSO and other population-based evolutionary algorithms(EAs) can be improved,and the optimal operational parameters based on 3LM-CDE algorithm of the syngas production in the Texaco coalwater slurry gasifier shows outstanding computing results than actual industry use and other algorithms.
文摘A laboratory scale downdraft biomass gasifier was designed to deliver a mechanical power of 4 kW and thermal power of about 15 kW. The gasifier was manufactured as a single piece having a water seal and cover. The gasifier was tested in natural downdraft and forced downdraft mode. Ignition of the fuel beneath the grate, during natural downdraft mode, using wood shavings as fuel, produced gas which burned with a blue flame for 15 minutes. Ignition at the throat, using either palm kernel shells or wood shavings, during the natural downdraft mode, the gasifier did not produce syngas. During the forced downdraft mode, fuel was ignited at the throat. Gasification was successful with the palm kernel shells, during forced downdraft, which produced gas which burned steadily with luminous flame for 15 minutes per kilogram of biomass fed. However, wood shavings experienced some bridging problems during the forced downdraft mode of operation. The fuel conversion rate of the gasifier, when using palm kernel shells as fuel in forced downdraft mode, was 4 kg/h. Forced downdraft mode of operation yielded better results and is the preferred operation of the gasifier.
基金supported by the EU FP7 Integrated Project(COPIRIDE)Andrea Jordan was supported for her PhD studies by a National Development Scholarship from the Government of Barbados+1 种基金a research grant from the Barbados Light and Power Company Limited which also supplied fuel cane bagasse for the experimentsAbdulaziz Mohamed was supported for his PhD studies by the Libyan Ministry of Higher Education and Scientific Research
文摘Sulphonated nano-structured micro-porous ion exchange polymers, known as sulphonated PolyHIPE Polymers （s-PHPs） were used in syngas cleaning to investigate their impact on tar composition, concentration and dew point depression during the gasification of fuel cane bagasse as a model biomass. The results showed that the s-PHPs used as a secondary syngas treatment system, was highly effective at adsorbing and reducing the concentration of all class of tars in syngas by 95%-80% which resulted in tar dew point depression from 90 ~C to 73 ~C. It was shown that tars underwent chemical reactions within s-PHPs, indicating that tar diffusion from syngas was driven by chemical potential. It was also observed that s-PHPs also captured ash forming elements from syngas. The use of s-PHPs in gasification as well as in an integrated thermochemical biorefinery technology is discussed since the tar loaded s-PHPs can be used as natural herbicides in the form of soil additives to enhance the biomass growth and crop yield.
文摘Slagging coal gasification process became a highlight of coal chemical industry in China during the last decade. Refractory lining＇ s life of slagging gasifiers is one of the most critical factors for a cost - effective operation. The paper introduces current status of coal gasification in China, lining structure of slagging gasifiers and performance of refractory lining. It also summarizes the major factors impacting on refractory wear in slagging coal gasifiers in four Chinese chemical plants, based on ten years of industrial experience. The utilizability is discussed in terms of cost -effectiveness of high chromia refractories and possibility of the alternatives.
文摘Research was focused on slag corrosion mechanism of high chrome bricks used for different types of gasifier by comparing the structure of high chrome bricks for petroleum coke gasifier and water-coal slurry gasifier with slag corroded testing brick and water coal slurry gasifier through Scanning Electron Microscope （SEM） examination and X-ray diffi＇action. Results show that for high chrome brick used for petroleum coke gasifier, corrosion is mainly caused by Cr2O3 in the brick and V2O5 in molten slag and liquid phase generation at low temperature; for high chrome brick used for water-coal slurry gasifier, corrosion is caused by dissolution of Cr2O3 in molten slag and corrosion of ZrO2. For LIRR-HK95 brick, it performs better petroleum coke corrosion resistance than the others due to the optimal composition and structure.
