Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the...Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.展开更多
The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D i...The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D interconnected pore structure was prepared through the high pressure pyrolysis of mesophase coal tar pitch.It is found that the 3D interconnected cellular pores of MPCF facilitate multiple reflections of electromagnetic waves,which results in the minimum reflection loss(RLmin)value of MPCF reaches-37.84 dB with the effective absorption bandwidth(EAB)of 5.44 GHz at a thickness of 2.70 mm,and the total average electromagnetic shielding effectiveness(SE_(T))under 3.00 mm thickness achieves 26.52 dB in X-band.Subsequently,MPCF is activated by KOH to obtain activated carbon foam(A-MPCF).The average SE_(T)of A-MPCF achieves 103.00 dB for abundant nanopores on the pore cell walls,which leads to a transition from the multiple reflections of electromagnetic waves on the walls to diffuse reflection.Unfortunately,the reflection coefficient(R)of A-MPCF increases from 0.78 to 0.90.To reduce the R value,Fe_(3)O_(4)/A-MPCF was fabricated via the in situ growth of nano Fe_(3)O_(4)on A-MPCF.Consequently,the R value of Fe_(3)O_(4)/A-MPCF was reduced from 0.90 to 0.74,whereas the MWA performance was only slightly decreased.This work proposes a simple strategy for simultaneously adjusting MWA and EMI shielding performances of materials.展开更多
The escalating demand for electromagnetic protection against increasingly severe electromagnetic pollution is making the development of advanced electromagnetic wave absorbing material systems imperative.MXene-based e...The escalating demand for electromagnetic protection against increasingly severe electromagnetic pollution is making the development of advanced electromagnetic wave absorbing material systems imperative.MXene-based electromagnetic wave absorbing fillers demonstrate advantages of lightweight and high efficiency.However,their microscale dimensions hinder the formation of interconnected networks within matrices,resulting in limited electromagnetic(EM)loss mechanisms and narrow effective absorption bandwidths.Herein,we employ wet spinning combined with molten salt-assisted in-situ synthesis to fabricate MAX@rGO(rGMAX_(n))fibrous absorbers featuring a hierarchical structure of“columnar cactus covered with MAX spheres”.Precise regulation of MAX phase content enables controlled tuning of the electromagnetic properties of rGMAX_(n) fibers.Moreover,subsequent in-situ etching further enhances their EM performance,yielding MXene@rGO(rGMX_(n))fibers with a hierarchical structure of“columnar cactus decorated with MXene nanosheet clusters”.Freeze-drying is utilized to modulate fiber filling content,and fibrous felts with conductive networks are obtained,which exhibit excellent electromagnetic wave absorption performance.Among them,the as-prepared rGMX_(10) fibrous felt exhibits good electromagnetic wave absorption performance at a low filling content(10 wt.%)with the RL_(max) of 54.4 dB and an effective absorption bandwidth of 5.31 GHz.This enhancement originates from improved impedance matching characteristics through fiber-interconnected networks and multiple electromagnetic loss mechanisms enabled by the hierarchical structure.The strategy of in-situ growing hierarchical MXene@rGO fibers establishes a novel approach for developing MXene-based fibrous absorbing materials.展开更多
The electromagnetic wave absorption of silicon carbide nanowires is improved by their uniform and diverse cross-structures.This study introduces a sustainable and high value-added method for synthesizing silicon carbi...The electromagnetic wave absorption of silicon carbide nanowires is improved by their uniform and diverse cross-structures.This study introduces a sustainable and high value-added method for synthesizing silicon carbide nanowires using lignite and waste silicon powder as raw materials through carbothermal reduction.The staggered structure of nanowires promotes the creation of interfacial polarization,impedance matching,and multiple loss mechanisms,leading to enhanced electromagnetic absorption performance.The silicon carbide nanowires demonstrate outstanding electromagnetic absorption capabilities with the minimum reflection loss of-48.09 d B at10.08 GHz and an effective absorption bandwidth(the reflection loss less than-10 d B)ranging from 8.54 to 16.68 GHz with a thickness of 2.17 mm.This research presents an innovative approach for utilizing solid waste in an environmentally friendly manner to produce broadband silicon carbide composite absorbers.展开更多
Electromagnetic interference(EMI)shielding materials principally attain shielding by reflecting electromagnetic waves through impedance mismatch caused by high conductivity,which inevitably leads to secondary electrom...Electromagnetic interference(EMI)shielding materials principally attain shielding by reflecting electromagnetic waves through impedance mismatch caused by high conductivity,which inevitably leads to secondary electromagnetic wave pollution.Consequently,the development of multifunctional,low-reflection electromagnetic shielding materials remains a significant challenge.Materials that are lightweight,possess high mechanical strength,exhibit excellent electromagnetic shielding absorption,and demonstrate low reflectivity have historically been the focus of significant interest.Natural silk,lightweight and strong,is an ideal composite matrix.Regenerated silk fibroin(RSF)synthesized via a bottom-up approach and cross-linked with polyvinyl alcohol(PVA)forms an aerogel matrix with remarkable compressive strength.In accordance with the principle of integrating functional design with structural design,spherical NiFe_(2)O_(4)particles were grown on the MXene surface via electrostatic self-assembly and combined with RSF/PVA as the aerogel absorptive layer,while RSF/PVA/MXene served as the reflective layer.A vertically oriented structure of Janus aerogel was prepared through sequential directed freezing.The resulting aerogel with 0.058 g/cm^(3) reveals the high compression strength(3.52 MPa).Reasonable functional and structural design enables aerogel to effectively dissipate incident electromagnetic waves through absorption,reflection,and reabsorption processes,achieving an average SET value of 48.05±1.75 dB and reaching a minimum reflection coefficient of 0.19.Furthermore,the aerogel displays remarkable infrared stealth capabilities.This lightweight,rigid,multifunctional aerogel is poised to play a significant role in the field of next-generation electronic devices.展开更多
The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)at...The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)attenuation behavior remain poorly understood.To address this gap,a thermodynamically controlled periodic coordination strategy is proposed to achieve precise modulation of magnetic nanoparticle spacing.This approach unveils the evolution of magnetic domain configurations,progressing from individual to coupled and ultimately to crosslinked domain configurations.A unique magnetic coupling phenomenon surpasses the Snoek limit in low-frequency range,which is observed through micromagnetic simulation.The crosslinked magnetic configuration achieves effective low-frequency EM wave absorption at 3.68 GHz,encompassing nearly the entire C-band.This exceptional magnetic interaction significantly enhances radar camouflage and thermal insulation properties.Additionally,a robust gradient metamaterial design extends coverage across the full band(2–40 GHz),effectively mitigating the impact of EM pollution on human health and environment.This comprehensive study elucidates the evolution mechanisms of magnetic domain configurations,addresses gaps in dynamic magnetic modulation,and provides novel insights for the development of high-performance,low-frequency EM wave absorption materials.展开更多
Efficient thermal management and electromagnetic interference(EMI)shielding are critical challenges for the reliable operation of portable electronic devices.Herein,we report the design and fabrication of multifunctio...Efficient thermal management and electromagnetic interference(EMI)shielding are critical challenges for the reliable operation of portable electronic devices.Herein,we report the design and fabrication of multifunctional layered composite phase change materials(CPCMs)comprising alternating cellulose nanofiber/phase change capsule/sodium alginate(CNF/PCC/SA)layers and MXene/sodium alginate(MXene/SA)layers.The strong interfacial adhesion and controlled multilayer architecture enable the CPCM to achieve high electrical conductivity(up to 279.8 S/cm)and excellent EMI shielding effectiveness(up to 57.6 dB in the X-band).The layered structure enhances electromagnetic wave attenuation via multiple internal reflections and polarization losses,outperforming homogeneous composites.Moreover,the CPCMs exhibit superior light absorption(maximum nearly 100% for the optimized 5-layer structure)and efficient light-to-thermal conversion,achieving rapid temperature increases and uniform heat distribution under light irradiation.Additionally,the phase change capsules enable latent heat storage,ensuring thermal buffering and prolonged temperature regulation.This work provides novel insights into the rational design of multifunctional composites integrating wireless thermal management and EMI shielding,with promising applications in wearable electronics and smart thermal regulation.展开更多
The widespread proliferation of modern wireless devices coupled with overlapping power emissions has brought about electromagnetic(EM)pollution issues,posing many challenges to environment and human health.Therefore,t...The widespread proliferation of modern wireless devices coupled with overlapping power emissions has brought about electromagnetic(EM)pollution issues,posing many challenges to environment and human health.Therefore,the development of EM shielding devices with high green shielding index(gs)is essential,as they offer absorption-dominant protection that minimizes reflections and safeguards both health and electronics.MXene,with its intrinsic ultra-high electrical conductivity,liquid-phase tunable surface chemistry,low density,large specific surface area,thermal stability,and mechanical stability,has become the leading two-dimensional(2D)material driving the development of green EM shielding devices.In this review we emphasize device-level strategies with engineered architectures for MXene-based green EM shielding.We first examine MXene’s crystal and electronic structure and the fundamental attenuation mechanisms in MXene-based devices.Then we survey fabrication and assembly methods,analyzing three device-level strategies for MXene-based green EM shielded devices:3D architectures,metastructure/meta-surfaces,and external stimulus.Throughout,we highlight how MXene’s distinguished properties enable green EM interference(EMI)shielding devices that minimize secondary interference.Finally,we discuss the challenges faced in the effective utilization of MXene-based in green EM shielding devices,provide insights into these challenges,and offer guidelines for developing the solutions of next-generation green MXene-based EM shielding devices.展开更多
With the continuous upgrading of traditional manufacturing industries and the rapid rise of emerging technology fields,the performance requirements for the permanent magnet synchronous motors(PMSMs)have become higher ...With the continuous upgrading of traditional manufacturing industries and the rapid rise of emerging technology fields,the performance requirements for the permanent magnet synchronous motors(PMSMs)have become higher and higher.The importance of fast and accurate electromagnetic thermal coupling analysis of such motors becomes more and more prominent.In view of this,the surfacemounted PMSM(SPMSM)equipped with unequally thick magnetic poles is taken as the main object and its electromagnetic thermal coupling analytical model(ETc AM)is investigated.First,the electromagnetic analytical model(EAM)is studied based on the modified subdomain method.It realizes the fast calculation of key electromagnetic characteristics.Subsequently,the 3D thermal analytical model(TAM)is developed by combining the EAM,the lumped parameter thermal network method(LPTNM),and the partial differential equation of heat flux.It realizes the fast calculation of key thermal characteristics in 3D space.Further,the information transfer channel between EAM and TAM is built with reference to the intrinsic connection between electromagnetic field and temperature field.Thereby,the novel ETcAM is proposed to realize the fast and accurate prediction of electromagnetic and temperature fields.Besides,ETcAM has a lot to commend it.One is that it well accounts for the complex structure,saturation,and heat exchange behavior.Second,it saves a lot of computer resources.It offers boundless possibilities for initial design,scheme evaluation,and optimization of motors.Finally,the validity,accuracy,and practicality of this study are verified by simulation and experiment.展开更多
In this paper,we study the ρ-meson electromagnetic form factors(EMFFs)within the framework of the light-front quark model.The physical form factors G_(C,M,Q)(Q^(2))of the ρ-meson,as well as the charged square radius...In this paper,we study the ρ-meson electromagnetic form factors(EMFFs)within the framework of the light-front quark model.The physical form factors G_(C,M,Q)(Q^(2))of the ρ-meson,as well as the charged square radius<r^(2)>,the magnetic moment μ,and the quadrupole moment Q,are calculated,which describe the behaviors of EMFFs at zero momentum transfer.Using the type-Ⅱ replacement,we find that the zero-mode does contribute zero to the matrix element S_(00)^(+).It is found that the“M→M_(0)”replacement improves the angular condition remarkably,which permits different prescriptions of ρ-meson EMFFs to give the consistent results.The residual tiny violation of angular condition needs other explanations beyond the zero-mode contributions.Our results indicate that the relativistic effects or interaction internal structure are weaken in the zero-binding limit.This work is also applicable to other spin-1 particles.展开更多
Magnetic absorbers with high permeability have significant advantages in lowfrequency and broadband electromagnetic wave(EMW)absorption.However,the insufficient magnetic loss and inherent high conductivity of existing...Magnetic absorbers with high permeability have significant advantages in lowfrequency and broadband electromagnetic wave(EMW)absorption.However,the insufficient magnetic loss and inherent high conductivity of existing magnetic absorbers limit the further expansion of EMW absorption bandwidth.Herein,the spinel(FeCoNiCrCu)_(3)O_(4) high-entropy oxides(HEO)are successfully constructed on the surface of FeCoNiCr_(0.4)Cu_(0.2) high-entropy alloys(HEA)through low-temperature oxygen bath treatment.On the one hand,HEO and HEA have different magnetocrystalline anisotropies,which is conducive to achieving continuous natural resonance to improve magnetic loss.On the other hand,HEO with low conductivity can serve as an impedance matching layer,achieving magneto-electric co-modulation.When the thickness is 5 mm,the minimum reflection loss(RL)value and absorption bandwidth(RL<−5 dB)of bi-phase high-entropy composites(BPHEC)can reach−12.8 dB and 633 MHz,respectively.The RCS reduction value of multilayer sample with impedance gradient characteristic can reach 18.34 dB m^(2).In addition,the BPHEC also exhibits temperaturestable EMW absorption performance,high Curie temperature,and oxidation resistance.The absorption bandwidth maintains between 593 and 691 MHz from−50 to 150℃.This work offers a new and tunable strategy toward modulating the electromagnetic genes for temperature-stable ultra-broadband megahertz EMW absorption.展开更多
Controlling molten steel flow in the mold and stabilizing the meniscus are critical challenges during the continuous casting,directly impacting the surface quality and internal quality of the final steel slab product....Controlling molten steel flow in the mold and stabilizing the meniscus are critical challenges during the continuous casting,directly impacting the surface quality and internal quality of the final steel slab product.The effects of electromagnetic swirling flow in nozzle(EMSFN)technology on molten steel flow in the mold during slab continuous casting under various casting speeds were investigated.A real-time adjustable EMSFN was developed,and a three-dimensional unsteady Reynolds-averaged Navier–Stokes turbulence mathematical model was established to simulate the flow field within the mold.The results demonstrate that the EMSFN effectively stabilizes the outflow from nozzle,reduces the impact depth and surface velocity of the molten steel,mitigates meniscus fluctuations,and promotes stable flow within the mold.However,a certain matching relationship exists between the casting speed and the current intensity.For the experimental medium-thick slab specifications,the optimal current intensities were found to be 100,130,and 200 A at casting speeds of 1.0,1.5,and 2.0 m/min,respectively.EMSFN can optimize the mold flow field under different casting speeds,providing theoretical support for improving the quality of continuously cast slab products.展开更多
Sine-wave drive and square-wave drive are two common motor control strategies.This study constructs a mathematical model capable of predicting the distribution of electromagnetic force waves in synchronous reluctance ...Sine-wave drive and square-wave drive are two common motor control strategies.This study constructs a mathematical model capable of predicting the distribution of electromagnetic force waves in synchronous reluctance motors(SynRMs)under these two drive methods,and comparatively analyzes the vibration phenomena induced by electromagnetic forces under different drive methods.It aims to provide an effective tool for predicting the distribution of electromagnetic force waves in SynRMs,while exploring the influence of drive modes on their vibration characteristics.The study focuses on a 4-pole,36-slot 5.5 kW SynRM.Based on the magnetomotive force(MMF)-permeance method,incorporating the special rotor structure and the characteristics of current harmonics under square-wave drive,an air-gap flux distribution function is established.Meanwhile,Maxwell’s stress tensor method is adopted to analyze how the air-gap flux density relates to electromagnetic excitation force waves.Subsequently,this analysis is applied to forecast the spatiotemporal distribution features of radial electromagnetic force waves.Finite element simulations are conducted to compute the modal and vibration responses of the SynRM,followed by a comparative analysis of the vibration characteristics under the two drive methods.Additionally,a 6-pole,36-slot SynRM is used for additional comparative verification.Ultimately,the effectiveness of the simulation results is verified through experiments.展开更多
An opposite combined vertical linear electromagnetic stirring(CV-LEMS)was proposed,which is applied in the final solidification zone of bloom continuous casting.The melt flow,heat transfer,and solidification under CV-...An opposite combined vertical linear electromagnetic stirring(CV-LEMS)was proposed,which is applied in the final solidification zone of bloom continuous casting.The melt flow,heat transfer,and solidification under CV-LEMS were investigated by establishing a three-dimensional numerical simulation model and a pilot continuous casting simulation experiment and compared with the conventional rotary electromagnetic stirring(REMS).The results show that a longitudinally symmetric linear magnetic field is formed in the liquid core of the bloom by applying CV-LEMS,which induces a strong longitudinal circulation flow both on the inner arc side and the outer arc side in the liquid core of the bloom.The height of the melt longitudinal effective mixing range under CV-LEMS reaches 0.9 m,which is greater than that of the REMS and makes up for the deficiency of REMS sensitivity to the position of the final solidification zone.CV-LEMS strongly promotes the mixing of upper melt with high temperature and the lower part melt with low temperature in the liquid core,improves the uniformity of melt temperature distribution and significantly increases the melt temperature near the solidification front,and the width of the liquid core increases by 4.2 mm at maximum.This shows that the appliction of CV-LEMS is more helpful to strengthen the feeding effect of the upper melt to the solidification shrinkage of the lower melt than the conventional REMS and inhibits the formation of porosity,shrinkage cavity and crack defects in the center of the bloom.展开更多
Carbon-based materials exhibit excellent dielectric absorption properties,among which graphene has received particular attention in research of electromagnetic wave absorbing materials because of its high electrical c...Carbon-based materials exhibit excellent dielectric absorption properties,among which graphene has received particular attention in research of electromagnetic wave absorbing materials because of its high electrical conductivity and unique large-area,thin-layer two-dimensional structural features.However,the electromagnetic absorption performance of the material is hindered from further improvement due to its single component composition.It is influenced by the conductive network of graphene,making it challenging to achieve a balance in impedance matching and electromagnetic loss,thereby restricting its broader application.To address these challenges,we developed a series of nickel hydroxide-modified graphene composites.Through a structural composite design,we optimized overall impedance matching,introduced diverse loss mechanisms to enhance electromagnetic loss performance,and utilized a secondary reaction control method to precisely regulate the deposition of nickel hydroxide on the graphene surface,thereby achieving regulate of the composite material's electromagnetic parameters within a defined range.Under low sample filling ratios and a thin sample thickness of 1.8 mm,the effective absorption bandwidth reaches 6.5 GHz,demonstrating excellent electromagnetic absorption performance.This study provides a controllable design approach for modulating material electromagnetic parameters by influencing the reaction process.It also offers a design method for composites with an outstanding electromagnetic loss mechanism.展开更多
Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,how...Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.展开更多
Developing effective strategies to regulate graphene’s conduction loss and polarization has become a key to expanding its application in the electromagnetic wave absorption(EMWA)field.Based on the unique energy band ...Developing effective strategies to regulate graphene’s conduction loss and polarization has become a key to expanding its application in the electromagnetic wave absorption(EMWA)field.Based on the unique energy band structure of graphene,regulating its bandgap and electrical properties by introducing heteroatoms is considered a feasible solution.Herein,metal-nitrogen doping reduced graphene oxide(M–N-RGO)was prepared by embedding a series of single metal atoms M–N_(4) sites(M=Mn,Fe,Co,Ni,Cu,Zn,Nb,Cd,and Sn)in RGO using an N-coordination atom-assisted strategy.These composites had adjustable conductivity and polarization to optimize dielectric loss and impedance matching for efficient EMWA performance.The results showed that the minimum reflection loss(RL_(min))of Fe–N-RGO reaches−74.05 dB(2.0 mm)and the maximum effective absorption bandwidth(EAB_(max))is 7.05 GHz(1.89 mm)even with a low filler loading of only 1 wt%.Combined with X-ray absorption spectra(XAFS),atomic force microscopy,and density functional theory calculation analysis,the Fe–N_(4) can be used as the polarization center to increase dipole polarization,interface polarization and defect-induced polarization due to d-p orbital hybridization and structural distortion.Moreover,electron migration within the Fe further leads to conduction loss,thereby synergistically promoting energy attenuation.This study demonstrates the effectiveness of metal-nitrogen doping in regulating the graphene′s dielectric properties,which provides an important basis for further investigation of the loss mechanism.展开更多
Currently,the demand for electromagnetic wave(EMW)absorbing materials with specific functions and capable of withstanding harsh environments is becoming increasingly urgent.Multi-component interface engineering is con...Currently,the demand for electromagnetic wave(EMW)absorbing materials with specific functions and capable of withstanding harsh environments is becoming increasingly urgent.Multi-component interface engineering is considered an effective means to achieve high-efficiency EMW absorption.However,interface modulation engineering has not been fully discussed and has great potential in the field of EMW absorption.In this study,multi-component tin compound fiber composites based on carbon fiber(CF)substrate were prepared by electrospinning,hydrothermal synthesis,and high-temperature thermal reduction.By utilizing the different properties of different substances,rich heterogeneous interfaces are constructed.This effectively promotes charge transfer and enhances interfacial polarization and conduction loss.The prepared SnS/SnS_(2)/SnO_(2)/CF composites with abundant heterogeneous interfaces have and exhibit excellent EMW absorption properties at a loading of 50 wt%in epoxy resin.The minimum reflection loss(RL)is−46.74 dB and the maximum effective absorption bandwidth is 5.28 GHz.Moreover,SnS/SnS_(2)/SnO_(2)/CF epoxy composite coatings exhibited long-term corrosion resistance on Q235 steel surfaces.Therefore,this study provides an effective strategy for the design of high-efficiency EMW absorbing materials in complex and harsh environments.展开更多
Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significan...Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significant challenging in regulating local phase evolution.Herein,accordion-shaped Co/Co_(3)O_(4)@N-doped carbon nanosheets(Co/Co_(3)O_(4)@NC)with gradient magnetic heterointerfaces have been fabricated via the cooperative high-temperature carbonization and lowtemperature oxidation process.The results indicate that the surface epitaxial growth of crystal Co_(3)O_(4) domains on local Co nanoparticles realizes the adjustment of magnetic-heteroatomic components,which are beneficial for optimizing impedance matching and interfacial polarization.Moreover,gradient magnetic heterointerfaces simultaneously realize magnetic coupling,and long-range magnetic diffraction.Specifically,the synthesized Co/Co_(3)O_(4)@NC absorbents display the strong electromagnetic wave attenuation capability of−53.5 dB at a thickness of 3.0 mm with an effective absorption bandwidth of 5.36 GHz,both are superior to those of single magnetic domains embedded in carbon matrix.This design concept provides us an inspiration in optimizing interfacial polarization,regulating magnetic coupling and promoting electromagnetic wave absorption.展开更多
With vigorous developments in nanotechnology,the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers.Herein,a hierarchical porous structure and composite h...With vigorous developments in nanotechnology,the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers.Herein,a hierarchical porous structure and composite heterogeneous interface are constructed successfully to optimize the electromagnetic loss capacity.The macro–micro-synergistic graphene aerogel formed by the ice template‑assisted 3D printing strategy is cut by silicon carbide nanowires(SiC_(nws))grown in situ,while boron nitride(BN)interfacial structure is introduced on graphene nanoplates.The unique composite structure forces multiple scattering of incident EMWs,ensuring the combined effects of interfacial polarization,conduction networks,and magnetic-dielectric synergy.Therefore,the as-prepared composites present a minimum reflection loss value of−37.8 dB and a wide effective absorption bandwidth(EAB)of 9.2 GHz(from 8.8 to 18.0 GHz)at 2.5 mm.Besides,relying on the intrinsic high-temperature resistance of SiC_(nws) and BN,the EAB also remains above 5.0 GHz after annealing in air environment at 600℃ for 10 h.展开更多
基金support provided by the Center for Fabrication and Application of Electronic Materials at Dokuz Eylül University,Türkiye。
文摘Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.
基金Supported by the National Natural Science Foundation of China(22378181).
文摘The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D interconnected pore structure was prepared through the high pressure pyrolysis of mesophase coal tar pitch.It is found that the 3D interconnected cellular pores of MPCF facilitate multiple reflections of electromagnetic waves,which results in the minimum reflection loss(RLmin)value of MPCF reaches-37.84 dB with the effective absorption bandwidth(EAB)of 5.44 GHz at a thickness of 2.70 mm,and the total average electromagnetic shielding effectiveness(SE_(T))under 3.00 mm thickness achieves 26.52 dB in X-band.Subsequently,MPCF is activated by KOH to obtain activated carbon foam(A-MPCF).The average SE_(T)of A-MPCF achieves 103.00 dB for abundant nanopores on the pore cell walls,which leads to a transition from the multiple reflections of electromagnetic waves on the walls to diffuse reflection.Unfortunately,the reflection coefficient(R)of A-MPCF increases from 0.78 to 0.90.To reduce the R value,Fe_(3)O_(4)/A-MPCF was fabricated via the in situ growth of nano Fe_(3)O_(4)on A-MPCF.Consequently,the R value of Fe_(3)O_(4)/A-MPCF was reduced from 0.90 to 0.74,whereas the MWA performance was only slightly decreased.This work proposes a simple strategy for simultaneously adjusting MWA and EMI shielding performances of materials.
基金granted by the National Key R&D Program of China(No.2024YFB3409900).
文摘The escalating demand for electromagnetic protection against increasingly severe electromagnetic pollution is making the development of advanced electromagnetic wave absorbing material systems imperative.MXene-based electromagnetic wave absorbing fillers demonstrate advantages of lightweight and high efficiency.However,their microscale dimensions hinder the formation of interconnected networks within matrices,resulting in limited electromagnetic(EM)loss mechanisms and narrow effective absorption bandwidths.Herein,we employ wet spinning combined with molten salt-assisted in-situ synthesis to fabricate MAX@rGO(rGMAX_(n))fibrous absorbers featuring a hierarchical structure of“columnar cactus covered with MAX spheres”.Precise regulation of MAX phase content enables controlled tuning of the electromagnetic properties of rGMAX_(n) fibers.Moreover,subsequent in-situ etching further enhances their EM performance,yielding MXene@rGO(rGMX_(n))fibers with a hierarchical structure of“columnar cactus decorated with MXene nanosheet clusters”.Freeze-drying is utilized to modulate fiber filling content,and fibrous felts with conductive networks are obtained,which exhibit excellent electromagnetic wave absorption performance.Among them,the as-prepared rGMX_(10) fibrous felt exhibits good electromagnetic wave absorption performance at a low filling content(10 wt.%)with the RL_(max) of 54.4 dB and an effective absorption bandwidth of 5.31 GHz.This enhancement originates from improved impedance matching characteristics through fiber-interconnected networks and multiple electromagnetic loss mechanisms enabled by the hierarchical structure.The strategy of in-situ growing hierarchical MXene@rGO fibers establishes a novel approach for developing MXene-based fibrous absorbing materials.
基金supported by the National Natural Science Foundation of China(No.52436008)the Inner Mongolia Science and Technology Projects,China(Nos.JMRHZX20210003 and 2023YFCY0009)+3 种基金the Huaneng Group Co Ltd.,China(No.HNKJ23-H50)the National Natural Science Foundation of China(No.22408044)the China Postdoctoral Science Foundation(No.2024M761877)the National Key R&D Program of China(No.SQ2024YFD2200039)。
文摘The electromagnetic wave absorption of silicon carbide nanowires is improved by their uniform and diverse cross-structures.This study introduces a sustainable and high value-added method for synthesizing silicon carbide nanowires using lignite and waste silicon powder as raw materials through carbothermal reduction.The staggered structure of nanowires promotes the creation of interfacial polarization,impedance matching,and multiple loss mechanisms,leading to enhanced electromagnetic absorption performance.The silicon carbide nanowires demonstrate outstanding electromagnetic absorption capabilities with the minimum reflection loss of-48.09 d B at10.08 GHz and an effective absorption bandwidth(the reflection loss less than-10 d B)ranging from 8.54 to 16.68 GHz with a thickness of 2.17 mm.This research presents an innovative approach for utilizing solid waste in an environmentally friendly manner to produce broadband silicon carbide composite absorbers.
基金supported by Key R&D Program of Shandong Province,China(No.2025CXGC010407).
文摘Electromagnetic interference(EMI)shielding materials principally attain shielding by reflecting electromagnetic waves through impedance mismatch caused by high conductivity,which inevitably leads to secondary electromagnetic wave pollution.Consequently,the development of multifunctional,low-reflection electromagnetic shielding materials remains a significant challenge.Materials that are lightweight,possess high mechanical strength,exhibit excellent electromagnetic shielding absorption,and demonstrate low reflectivity have historically been the focus of significant interest.Natural silk,lightweight and strong,is an ideal composite matrix.Regenerated silk fibroin(RSF)synthesized via a bottom-up approach and cross-linked with polyvinyl alcohol(PVA)forms an aerogel matrix with remarkable compressive strength.In accordance with the principle of integrating functional design with structural design,spherical NiFe_(2)O_(4)particles were grown on the MXene surface via electrostatic self-assembly and combined with RSF/PVA as the aerogel absorptive layer,while RSF/PVA/MXene served as the reflective layer.A vertically oriented structure of Janus aerogel was prepared through sequential directed freezing.The resulting aerogel with 0.058 g/cm^(3) reveals the high compression strength(3.52 MPa).Reasonable functional and structural design enables aerogel to effectively dissipate incident electromagnetic waves through absorption,reflection,and reabsorption processes,achieving an average SET value of 48.05±1.75 dB and reaching a minimum reflection coefficient of 0.19.Furthermore,the aerogel displays remarkable infrared stealth capabilities.This lightweight,rigid,multifunctional aerogel is poised to play a significant role in the field of next-generation electronic devices.
基金supported by the National Natural Science Foundation of China(22265021,52231007,and 12327804)the Aeronautical Science Foundation of China(2020Z056056003)Jiangxi Provincial Natural Science Foundation(20232BAB212004).
文摘The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)attenuation behavior remain poorly understood.To address this gap,a thermodynamically controlled periodic coordination strategy is proposed to achieve precise modulation of magnetic nanoparticle spacing.This approach unveils the evolution of magnetic domain configurations,progressing from individual to coupled and ultimately to crosslinked domain configurations.A unique magnetic coupling phenomenon surpasses the Snoek limit in low-frequency range,which is observed through micromagnetic simulation.The crosslinked magnetic configuration achieves effective low-frequency EM wave absorption at 3.68 GHz,encompassing nearly the entire C-band.This exceptional magnetic interaction significantly enhances radar camouflage and thermal insulation properties.Additionally,a robust gradient metamaterial design extends coverage across the full band(2–40 GHz),effectively mitigating the impact of EM pollution on human health and environment.This comprehensive study elucidates the evolution mechanisms of magnetic domain configurations,addresses gaps in dynamic magnetic modulation,and provides novel insights for the development of high-performance,low-frequency EM wave absorption materials.
基金the National Natural Science Foundation of China(No.52436003)Guangdong Basic and Applied Basic Research Foundation(No.2023A1515011985).
文摘Efficient thermal management and electromagnetic interference(EMI)shielding are critical challenges for the reliable operation of portable electronic devices.Herein,we report the design and fabrication of multifunctional layered composite phase change materials(CPCMs)comprising alternating cellulose nanofiber/phase change capsule/sodium alginate(CNF/PCC/SA)layers and MXene/sodium alginate(MXene/SA)layers.The strong interfacial adhesion and controlled multilayer architecture enable the CPCM to achieve high electrical conductivity(up to 279.8 S/cm)and excellent EMI shielding effectiveness(up to 57.6 dB in the X-band).The layered structure enhances electromagnetic wave attenuation via multiple internal reflections and polarization losses,outperforming homogeneous composites.Moreover,the CPCMs exhibit superior light absorption(maximum nearly 100% for the optimized 5-layer structure)and efficient light-to-thermal conversion,achieving rapid temperature increases and uniform heat distribution under light irradiation.Additionally,the phase change capsules enable latent heat storage,ensuring thermal buffering and prolonged temperature regulation.This work provides novel insights into the rational design of multifunctional composites integrating wireless thermal management and EMI shielding,with promising applications in wearable electronics and smart thermal regulation.
基金the National Natural Science Foundation of China(No.62304020)supported by the National Key R&D Program of China(No.2023YFB3811300)the National Natural Science Foundation of China(No.52202370).
文摘The widespread proliferation of modern wireless devices coupled with overlapping power emissions has brought about electromagnetic(EM)pollution issues,posing many challenges to environment and human health.Therefore,the development of EM shielding devices with high green shielding index(gs)is essential,as they offer absorption-dominant protection that minimizes reflections and safeguards both health and electronics.MXene,with its intrinsic ultra-high electrical conductivity,liquid-phase tunable surface chemistry,low density,large specific surface area,thermal stability,and mechanical stability,has become the leading two-dimensional(2D)material driving the development of green EM shielding devices.In this review we emphasize device-level strategies with engineered architectures for MXene-based green EM shielding.We first examine MXene’s crystal and electronic structure and the fundamental attenuation mechanisms in MXene-based devices.Then we survey fabrication and assembly methods,analyzing three device-level strategies for MXene-based green EM shielded devices:3D architectures,metastructure/meta-surfaces,and external stimulus.Throughout,we highlight how MXene’s distinguished properties enable green EM interference(EMI)shielding devices that minimize secondary interference.Finally,we discuss the challenges faced in the effective utilization of MXene-based in green EM shielding devices,provide insights into these challenges,and offer guidelines for developing the solutions of next-generation green MXene-based EM shielding devices.
基金supported by the Project of National Natural Science Foundation of China under Grant 52077122。
文摘With the continuous upgrading of traditional manufacturing industries and the rapid rise of emerging technology fields,the performance requirements for the permanent magnet synchronous motors(PMSMs)have become higher and higher.The importance of fast and accurate electromagnetic thermal coupling analysis of such motors becomes more and more prominent.In view of this,the surfacemounted PMSM(SPMSM)equipped with unequally thick magnetic poles is taken as the main object and its electromagnetic thermal coupling analytical model(ETc AM)is investigated.First,the electromagnetic analytical model(EAM)is studied based on the modified subdomain method.It realizes the fast calculation of key electromagnetic characteristics.Subsequently,the 3D thermal analytical model(TAM)is developed by combining the EAM,the lumped parameter thermal network method(LPTNM),and the partial differential equation of heat flux.It realizes the fast calculation of key thermal characteristics in 3D space.Further,the information transfer channel between EAM and TAM is built with reference to the intrinsic connection between electromagnetic field and temperature field.Thereby,the novel ETcAM is proposed to realize the fast and accurate prediction of electromagnetic and temperature fields.Besides,ETcAM has a lot to commend it.One is that it well accounts for the complex structure,saturation,and heat exchange behavior.Second,it saves a lot of computer resources.It offers boundless possibilities for initial design,scheme evaluation,and optimization of motors.Finally,the validity,accuracy,and practicality of this study are verified by simulation and experiment.
基金supported by the National Natural Science Foundation of China(Grant Nos.11875122,12175025,and 12147102)Tongling University Talent Program(Grant No.R23100)。
文摘In this paper,we study the ρ-meson electromagnetic form factors(EMFFs)within the framework of the light-front quark model.The physical form factors G_(C,M,Q)(Q^(2))of the ρ-meson,as well as the charged square radius<r^(2)>,the magnetic moment μ,and the quadrupole moment Q,are calculated,which describe the behaviors of EMFFs at zero momentum transfer.Using the type-Ⅱ replacement,we find that the zero-mode does contribute zero to the matrix element S_(00)^(+).It is found that the“M→M_(0)”replacement improves the angular condition remarkably,which permits different prescriptions of ρ-meson EMFFs to give the consistent results.The residual tiny violation of angular condition needs other explanations beyond the zero-mode contributions.Our results indicate that the relativistic effects or interaction internal structure are weaken in the zero-binding limit.This work is also applicable to other spin-1 particles.
基金Supported by Program for the National Natural Science Foundation of China(No.52071053,U1704253,52103334)the Fundamental Research Funds for the Central Universities(DUT24GF102)the Shandong Province Natural Science Youth Fund(ZR2024QA134)。
文摘Magnetic absorbers with high permeability have significant advantages in lowfrequency and broadband electromagnetic wave(EMW)absorption.However,the insufficient magnetic loss and inherent high conductivity of existing magnetic absorbers limit the further expansion of EMW absorption bandwidth.Herein,the spinel(FeCoNiCrCu)_(3)O_(4) high-entropy oxides(HEO)are successfully constructed on the surface of FeCoNiCr_(0.4)Cu_(0.2) high-entropy alloys(HEA)through low-temperature oxygen bath treatment.On the one hand,HEO and HEA have different magnetocrystalline anisotropies,which is conducive to achieving continuous natural resonance to improve magnetic loss.On the other hand,HEO with low conductivity can serve as an impedance matching layer,achieving magneto-electric co-modulation.When the thickness is 5 mm,the minimum reflection loss(RL)value and absorption bandwidth(RL<−5 dB)of bi-phase high-entropy composites(BPHEC)can reach−12.8 dB and 633 MHz,respectively.The RCS reduction value of multilayer sample with impedance gradient characteristic can reach 18.34 dB m^(2).In addition,the BPHEC also exhibits temperaturestable EMW absorption performance,high Curie temperature,and oxidation resistance.The absorption bandwidth maintains between 593 and 691 MHz from−50 to 150℃.This work offers a new and tunable strategy toward modulating the electromagnetic genes for temperature-stable ultra-broadband megahertz EMW absorption.
基金National Natural Science Foundation of China(Nos.U21A20117,52104347 and 52272078)the Fundamental Research Funds for the Central Universities(No.N2409006)Natural Science Foundation of Liaoning Province(2023-MSBA-135)for the financial support.
文摘Controlling molten steel flow in the mold and stabilizing the meniscus are critical challenges during the continuous casting,directly impacting the surface quality and internal quality of the final steel slab product.The effects of electromagnetic swirling flow in nozzle(EMSFN)technology on molten steel flow in the mold during slab continuous casting under various casting speeds were investigated.A real-time adjustable EMSFN was developed,and a three-dimensional unsteady Reynolds-averaged Navier–Stokes turbulence mathematical model was established to simulate the flow field within the mold.The results demonstrate that the EMSFN effectively stabilizes the outflow from nozzle,reduces the impact depth and surface velocity of the molten steel,mitigates meniscus fluctuations,and promotes stable flow within the mold.However,a certain matching relationship exists between the casting speed and the current intensity.For the experimental medium-thick slab specifications,the optimal current intensities were found to be 100,130,and 200 A at casting speeds of 1.0,1.5,and 2.0 m/min,respectively.EMSFN can optimize the mold flow field under different casting speeds,providing theoretical support for improving the quality of continuously cast slab products.
基金supported by the Science and Technology Project of State Grid Corporation of China Headquarters under Grant 5500-202416156A-1-1-ZN.
文摘Sine-wave drive and square-wave drive are two common motor control strategies.This study constructs a mathematical model capable of predicting the distribution of electromagnetic force waves in synchronous reluctance motors(SynRMs)under these two drive methods,and comparatively analyzes the vibration phenomena induced by electromagnetic forces under different drive methods.It aims to provide an effective tool for predicting the distribution of electromagnetic force waves in SynRMs,while exploring the influence of drive modes on their vibration characteristics.The study focuses on a 4-pole,36-slot 5.5 kW SynRM.Based on the magnetomotive force(MMF)-permeance method,incorporating the special rotor structure and the characteristics of current harmonics under square-wave drive,an air-gap flux distribution function is established.Meanwhile,Maxwell’s stress tensor method is adopted to analyze how the air-gap flux density relates to electromagnetic excitation force waves.Subsequently,this analysis is applied to forecast the spatiotemporal distribution features of radial electromagnetic force waves.Finite element simulations are conducted to compute the modal and vibration responses of the SynRM,followed by a comparative analysis of the vibration characteristics under the two drive methods.Additionally,a 6-pole,36-slot SynRM is used for additional comparative verification.Ultimately,the effectiveness of the simulation results is verified through experiments.
基金the National Natural Science Foundation of China(Grant No.U1760206 and Grant No.51574083)the 111 Project(2.0)of China(No.BP0719037)for the financial support。
文摘An opposite combined vertical linear electromagnetic stirring(CV-LEMS)was proposed,which is applied in the final solidification zone of bloom continuous casting.The melt flow,heat transfer,and solidification under CV-LEMS were investigated by establishing a three-dimensional numerical simulation model and a pilot continuous casting simulation experiment and compared with the conventional rotary electromagnetic stirring(REMS).The results show that a longitudinally symmetric linear magnetic field is formed in the liquid core of the bloom by applying CV-LEMS,which induces a strong longitudinal circulation flow both on the inner arc side and the outer arc side in the liquid core of the bloom.The height of the melt longitudinal effective mixing range under CV-LEMS reaches 0.9 m,which is greater than that of the REMS and makes up for the deficiency of REMS sensitivity to the position of the final solidification zone.CV-LEMS strongly promotes the mixing of upper melt with high temperature and the lower part melt with low temperature in the liquid core,improves the uniformity of melt temperature distribution and significantly increases the melt temperature near the solidification front,and the width of the liquid core increases by 4.2 mm at maximum.This shows that the appliction of CV-LEMS is more helpful to strengthen the feeding effect of the upper melt to the solidification shrinkage of the lower melt than the conventional REMS and inhibits the formation of porosity,shrinkage cavity and crack defects in the center of the bloom.
基金supported by the Research Funds of the State Key Laboratory for Marine Corrosion and Protection(No.JS220903).
文摘Carbon-based materials exhibit excellent dielectric absorption properties,among which graphene has received particular attention in research of electromagnetic wave absorbing materials because of its high electrical conductivity and unique large-area,thin-layer two-dimensional structural features.However,the electromagnetic absorption performance of the material is hindered from further improvement due to its single component composition.It is influenced by the conductive network of graphene,making it challenging to achieve a balance in impedance matching and electromagnetic loss,thereby restricting its broader application.To address these challenges,we developed a series of nickel hydroxide-modified graphene composites.Through a structural composite design,we optimized overall impedance matching,introduced diverse loss mechanisms to enhance electromagnetic loss performance,and utilized a secondary reaction control method to precisely regulate the deposition of nickel hydroxide on the graphene surface,thereby achieving regulate of the composite material's electromagnetic parameters within a defined range.Under low sample filling ratios and a thin sample thickness of 1.8 mm,the effective absorption bandwidth reaches 6.5 GHz,demonstrating excellent electromagnetic absorption performance.This study provides a controllable design approach for modulating material electromagnetic parameters by influencing the reaction process.It also offers a design method for composites with an outstanding electromagnetic loss mechanism.
基金financially supported by the National Natural Science Foundation of China(Grants nos.62201411,62371378,22205168,52302150 and 62304171)the China Postdoctoral Science Foundation(2022M722500)+1 种基金the Fundamental Research Funds for the Central Universities(Grants nos.ZYTS2308 and 20103237929)Startup Foundation of Xidian University(10251220001).
文摘Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.
基金supported by National Natural Science Foundation of China(NSFC 52432002,52372041,52302087)Heilongjiang Touyan Team Program,the Fundamental Research Funds for the Central Universities(Grant No.HIT.OCEF.2021003)the Shanghai Aerospace Science and Technology Innovation Fund(SAST2022-60).
文摘Developing effective strategies to regulate graphene’s conduction loss and polarization has become a key to expanding its application in the electromagnetic wave absorption(EMWA)field.Based on the unique energy band structure of graphene,regulating its bandgap and electrical properties by introducing heteroatoms is considered a feasible solution.Herein,metal-nitrogen doping reduced graphene oxide(M–N-RGO)was prepared by embedding a series of single metal atoms M–N_(4) sites(M=Mn,Fe,Co,Ni,Cu,Zn,Nb,Cd,and Sn)in RGO using an N-coordination atom-assisted strategy.These composites had adjustable conductivity and polarization to optimize dielectric loss and impedance matching for efficient EMWA performance.The results showed that the minimum reflection loss(RL_(min))of Fe–N-RGO reaches−74.05 dB(2.0 mm)and the maximum effective absorption bandwidth(EAB_(max))is 7.05 GHz(1.89 mm)even with a low filler loading of only 1 wt%.Combined with X-ray absorption spectra(XAFS),atomic force microscopy,and density functional theory calculation analysis,the Fe–N_(4) can be used as the polarization center to increase dipole polarization,interface polarization and defect-induced polarization due to d-p orbital hybridization and structural distortion.Moreover,electron migration within the Fe further leads to conduction loss,thereby synergistically promoting energy attenuation.This study demonstrates the effectiveness of metal-nitrogen doping in regulating the graphene′s dielectric properties,which provides an important basis for further investigation of the loss mechanism.
基金financially supported by the National Natural Science Foundation of China(No.52377026 and No.52301192)Taishan Scholars and Young Experts Program of Shandong Province(No.tsqn202103057)+4 种基金Postdoctoral Fellowship Program of CPSF under Grant Number(No.GZB20240327)Shandong Postdoctoral Science Foundation(No.SDCXZG-202400275)Qingdao Postdoctoral Application Research Project(No.QDBSH20240102023)China Postdoctoral Science Foundation(No.2024M751563)the Qingchuang Talents Induction Program of Shandong Higher Education Institution(Research and Innovation Team of Structural-Functional Polymer Composites).
文摘Currently,the demand for electromagnetic wave(EMW)absorbing materials with specific functions and capable of withstanding harsh environments is becoming increasingly urgent.Multi-component interface engineering is considered an effective means to achieve high-efficiency EMW absorption.However,interface modulation engineering has not been fully discussed and has great potential in the field of EMW absorption.In this study,multi-component tin compound fiber composites based on carbon fiber(CF)substrate were prepared by electrospinning,hydrothermal synthesis,and high-temperature thermal reduction.By utilizing the different properties of different substances,rich heterogeneous interfaces are constructed.This effectively promotes charge transfer and enhances interfacial polarization and conduction loss.The prepared SnS/SnS_(2)/SnO_(2)/CF composites with abundant heterogeneous interfaces have and exhibit excellent EMW absorption properties at a loading of 50 wt%in epoxy resin.The minimum reflection loss(RL)is−46.74 dB and the maximum effective absorption bandwidth is 5.28 GHz.Moreover,SnS/SnS_(2)/SnO_(2)/CF epoxy composite coatings exhibited long-term corrosion resistance on Q235 steel surfaces.Therefore,this study provides an effective strategy for the design of high-efficiency EMW absorbing materials in complex and harsh environments.
基金financially supported by the National Natural Science Foundation of China(52373271)Science,Technology and Innovation Commission of Shenzhen Municipality under Grant(KCXFZ20201221173004012)+1 种基金National Key Research and Development Program of Shaanxi Province(No.2023-YBNY-271)Open Testing Foundation of the Analytical&Testing Center of Northwestern Polytechnical University(2023T019).
文摘Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significant challenging in regulating local phase evolution.Herein,accordion-shaped Co/Co_(3)O_(4)@N-doped carbon nanosheets(Co/Co_(3)O_(4)@NC)with gradient magnetic heterointerfaces have been fabricated via the cooperative high-temperature carbonization and lowtemperature oxidation process.The results indicate that the surface epitaxial growth of crystal Co_(3)O_(4) domains on local Co nanoparticles realizes the adjustment of magnetic-heteroatomic components,which are beneficial for optimizing impedance matching and interfacial polarization.Moreover,gradient magnetic heterointerfaces simultaneously realize magnetic coupling,and long-range magnetic diffraction.Specifically,the synthesized Co/Co_(3)O_(4)@NC absorbents display the strong electromagnetic wave attenuation capability of−53.5 dB at a thickness of 3.0 mm with an effective absorption bandwidth of 5.36 GHz,both are superior to those of single magnetic domains embedded in carbon matrix.This design concept provides us an inspiration in optimizing interfacial polarization,regulating magnetic coupling and promoting electromagnetic wave absorption.
基金sponsored by National Natural Science Foundation of China(No.52302121,No.52203386)Shanghai Sailing Program(No.23YF1454700)+1 种基金Shanghai Natural Science Foundation(No.23ZR1472700)Shanghai Post-doctoral Excellent Program(No.2022664).
文摘With vigorous developments in nanotechnology,the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers.Herein,a hierarchical porous structure and composite heterogeneous interface are constructed successfully to optimize the electromagnetic loss capacity.The macro–micro-synergistic graphene aerogel formed by the ice template‑assisted 3D printing strategy is cut by silicon carbide nanowires(SiC_(nws))grown in situ,while boron nitride(BN)interfacial structure is introduced on graphene nanoplates.The unique composite structure forces multiple scattering of incident EMWs,ensuring the combined effects of interfacial polarization,conduction networks,and magnetic-dielectric synergy.Therefore,the as-prepared composites present a minimum reflection loss value of−37.8 dB and a wide effective absorption bandwidth(EAB)of 9.2 GHz(from 8.8 to 18.0 GHz)at 2.5 mm.Besides,relying on the intrinsic high-temperature resistance of SiC_(nws) and BN,the EAB also remains above 5.0 GHz after annealing in air environment at 600℃ for 10 h.
