Energy-storage welding connection characteristics of rapidly solidified AZ91D Mg alloy ribbons with 40-70 μm thickness are investigated using a microtype energy-storage welding machine. The microstructure and perform...Energy-storage welding connection characteristics of rapidly solidified AZ91D Mg alloy ribbons with 40-70 μm thickness are investigated using a microtype energy-storage welding machine. The microstructure and performance of the connection joints are analyzed and studied. The research results indicate that energy-storage welding is able to realize the spot welding connection of AZ9ID Mg alloy ribbons. The welding nugget consists of developed α-Mg equiaxed grains with the sizes of 1.2-2.7 μm and intergranular distributed β-Mg17Al12 compounds. The thickness of bond zone is about 4 μm and the solidification microstructure is characterized by the fine equiaxed grains with the sizes of 0.8-1.2μm and grain boundary has become coarsening. The columnar crystal in HAZ also becomes slightly coarsening and the grain boundary has broadened, however, there is no obvious change in its primitive morphology and crystallographic direction. When welding energy is about 2.0 J, the welding joints with higher shear strength and smaller electrical resistivity are obtained.展开更多
Fast charging stations play an important role in the use of electric vehicles(EV)and significantly affect the distribution network owing to the fluctuation of their power.For exploiting the rapid adjustment feature of...Fast charging stations play an important role in the use of electric vehicles(EV)and significantly affect the distribution network owing to the fluctuation of their power.For exploiting the rapid adjustment feature of the energy-storage system(ESS),a configuration method of the ESS for EV fast charging stations is proposed in this paper,which considers the fluctuation of the wind power as well as the characteristics of the charging load.The configuration of the ESS can not only mitigate the effects of fast charging stations on the connected distribution network but also improve its economic efficiency.First,the scenario method is adopted to model the wind power in the distribution network,and according to the characteristics of the EV and the driving probability,the charging demand of each station is calculated.Then,considering factors such as the investment cost,maintenance cost,discharging benefit,and wind curtailment cost,the ESS configuration model of the distribution network is set up,which takes the optimal total costs of the ESS for EV fast charging stations within its lifecycle as an objective.Finally,General Algebraic Modelling System(GAMS)is used to linearize and solve the proposed model.A simulation on an improved IEEE-69 bus system verifies the feasibility and economic efficiency of the proposed model.展开更多
We re port the facile synthesis of Ni,Co-double hydroxide wire(NCHW)-based electrodes directly grown on a conductive substrate via a hydrothermal process.Various NCHW nanostructures were grown on Ni foam,and the growt...We re port the facile synthesis of Ni,Co-double hydroxide wire(NCHW)-based electrodes directly grown on a conductive substrate via a hydrothermal process.Various NCHW nanostructures were grown on Ni foam,and the growth was controlled using different compositions of solvents(ethanol and water).With increasing volume ratio of ethanol to water,the density of the wires decreased,and the spatial voids between the wires increased.The formation of large empty spaces improved the electrochemical performance because the exposure of a large surface area of the structure to the electrolyte resulted in a large number of active sites and facile electrolyte penetration into the structure.The different NCHW structures were ascribed to the pivotal role of the solvent in the urea hydrolysis;the solvent triggered the formation of hydroxides during the hydrothermal synthesis.The electrochemical performance of the NCHW electrodes was investigated via galvanostatic charge/discha rge tests,cyclic voltammetry,and electrochemical impedance spectroscopy.The highest specific capacitance was 1694.7 m F/cm^2 at 2 mA/cm^2,with excellent capacitance retention of 81.5% after 5000 cycles.The superior electrochemical performance of the NCHW electrodes is attributed to the large number of active sites and facile electrolyte diffusion into the structure,due to the well-organized structure with an optimized density of nanowires and large voids between the wires.展开更多
A series of tungsten bronze(Sr_(2-x)Bi_(x)Ag_(0.2)Na_(0.8))(Nb_(4.8-x)Zr_(x)Sb_(0.2))O15 compounds were fabricated by solidstate method to systematically study the impacts of co-doping Bi^(3+)/Zr^(4+)ions in A/B-sites...A series of tungsten bronze(Sr_(2-x)Bi_(x)Ag_(0.2)Na_(0.8))(Nb_(4.8-x)Zr_(x)Sb_(0.2))O15 compounds were fabricated by solidstate method to systematically study the impacts of co-doping Bi^(3+)/Zr^(4+)ions in A/B-sites on the structures,relaxor characteristics,and energy-storage performances.The relationship between structures and relaxor behaviors are summarized as three main points:(1)with increasing the amount of codoping Bi^(3+)/Zr^(4+)ions,the crystal structure evolved from an orthorhombic Bbm^(2) to a tetragonal paraelectric P4/mbm symmetry at room temperature;(2)enhancing relaxor characteristics at room temperature was achieved by tailoring the temperature region of T_(m)-T_(B)(T_(m) is the dielectric maximum temperature,T_(B) is the Burns temperature),which could be attributed to the incommensurate local structure modulations associated with the orthogonal distortion of P4bm symmetry and the appearance of microdomains;(3)The co-introduction of Bi^(3+)and Zr^(4+)could also played an important role in inhibiting the grain sizes,increasing resistivity and band-gap to enhance the breakdown strength.Finally,a superior recoverable energy-storage density(3.61 J/cm^(3))and an ultrahigh energy efficiency(90%)were obtained simultaneously at 389 kV/cm in BZ0.05 ceramics.Moreover,an outstanding power density(158.98 MW/cm^(3))together with a current density of 1422.29 A/cm^(2)was realized at 220 kV/cm from the charging-discharging performance measurements.The excellent energy-storage performance(ESPs)make the environmentally friendly BZ0.05 samples show enormous potential in high-power capacitor applications.展开更多
Energy-storage technologies based on lithium-ion batteries are advancing rapidly.However,the occurrence of thermal runaway in batteries under extreme operating conditions poses serious safety concerns and potentially ...Energy-storage technologies based on lithium-ion batteries are advancing rapidly.However,the occurrence of thermal runaway in batteries under extreme operating conditions poses serious safety concerns and potentially leads to severe accidents.To address the detection and early warning of battery thermal runaway faults,this study conducted a comprehensive review of recent advances in lithium battery fault monitoring and early warning in energy-storage systems from various physical perspectives.The focus was electrical,thermal,acoustic,and mechanical aspects,which provide effective insights for energy-storage system safety enhancement.展开更多
Compared with antiferroelectric(AFE)orthothombic R phases,AFE orthothombic P phases in Na NbO_(3)(NN)ceramics have been rarely investigated,particularly in the field of energy-storage capadtors.The main bottlenedk is ...Compared with antiferroelectric(AFE)orthothombic R phases,AFE orthothombic P phases in Na NbO_(3)(NN)ceramics have been rarely investigated,particularly in the field of energy-storage capadtors.The main bottlenedk is closely related to the contradiction between d fficultly achieved stable relaxor AFE P phase and easily induced P-R phase transition during modifying dhemical compositions.Herein,we reporta novel lead-free AFE ceramic of(1-x)NN-x(Bi_(0.5)K_(0.5))ZrO_(3)((1-x)NN-xBKZ)with a pure AFE P phase str ucture,which exhibits excellent energy-storage characteristics,such as an ultrahigh recoverable energy density(W_(rec))-4.4 J/cm^(3) at x=0.11,a large powder density P_(D)-104 MW/cm^(3) and a fast discharge rate t_(0.9)-45 ns.The analysis of polarization-field response,Raman spectrum and transmission elecron microscopy demonstrates that the giant amplification of W_(rec) by≥177% should be ma inly ascribed to the simultaneously and effectively enhanced AFE P phase stbility and its relaxor dharacteristics,resulting in a diffused reversible electric field-induced AFE P-ferroelectric phase transition with concurrently incre.ased driving electric fields.Different from mast(1-x)NN-xABO_(3) systems,it was found that the reduced polarizability of B-site cations dominates the enhanced AFE P-phase stability in(1-x)NN-xBKZ ceramics,but the almost unchanged tolerance factor tends to ause the AFE R phase to be induced at a relatively high x value.展开更多
The combination of batteries and ultracapacitors has become an effective solution to satisfy the requirements of high power density and high energy density for the energy-storage system of electric vehicles.Three aspe...The combination of batteries and ultracapacitors has become an effective solution to satisfy the requirements of high power density and high energy density for the energy-storage system of electric vehicles.Three aspects of such combination efforts were considered for evaluating the four types of hybrid energy-storage system(HESS)topologies.First,a novel optimization framework was proposed and implemented to optimize the voltage level of a battery pack and an ultracapacitor pack for the four types of HESS topologies.During the optimization process,the dynamic programming(DP)algorithm was iteratively applied to determine the optimal control actions.The simulation results with DP were used to evaluate the energy efficiency of different HESS topologies at different voltage levels.Second,the optimized voltage level of the battery and ultracapacitor in each topology indicates that a higher voltage level usually results in a better system performance.The simulation results also illustrate that the optimized rated voltage level of the battery pack is approximately 499.5 V,while for the ultracapacitor pack,the optimized voltage level is at its maximum allowed value.Note that the constraint of the battery voltage is initialized at200–600 V.Third,the control rules for different HESS topologies were obtained through the systematic analysis of the simulation results.In addition,advantages and disadvantages of the four topologies were summarized through evaluation of the efficiency and operating currents of the batteries and the ultracapacitor.展开更多
Switching mechanisms and energy-storage properties have been investigated in(Pb_(0.98)La_(0.02)T(Zr_(0.95)Ti_(0.05)T_(0.995O_(3)) antiferroelectric ceramics.The electric field dependence of polarization(P–E hysteresi...Switching mechanisms and energy-storage properties have been investigated in(Pb_(0.98)La_(0.02)T(Zr_(0.95)Ti_(0.05)T_(0.995O_(3)) antiferroelectric ceramics.The electric field dependence of polarization(P–E hysteresis loops)indicates that both the ferroelectric(FE)and antiferroelectric(AFE)phases coexist,being the AFE more stable above 100℃.It has been observed that the temperature has an important influence on the switching parameters.On the other hand,the energy-storage density,which has been calculated from the P–E hysteresis loops,shows values higher than 1 J/cm^(3) for temperatures above 100℃ with around 73%of efficiency as average.These properties indicate that the studied ceramic system reveals as a promising AFE material for energy-storage devices application.展开更多
In the last few decades,dielectric capacitors have gotten a lot of attention because they can store more power and charge and discharge very quickly.But it has a low energy-storage density(Wrec),efficiency(h),and temp...In the last few decades,dielectric capacitors have gotten a lot of attention because they can store more power and charge and discharge very quickly.But it has a low energy-storage density(Wrec),efficiency(h),and temperature stability.By adding Pb(Mg1/3Nb2/3)O3(PMN)and(Bi0$1Sr0.85)TiO3(BST)to a nonstoichiometric(Bi0$51Na0.5)TiO3(BNT)matrix,the goal is to change the phase transition properties and make the material more relaxor ferroelectric(RFE)by lowering the remnant polarization Pr and keeping the maximum polarization Pmax.A viscous polymer process(VPP)is used to improve the electric breakdown strength,which is also a key part of being able to store energy.By working together,ceramics with the formula 0.79[0.85BNT-0.15PMN]-0.21BST(BP-0.21BST)are made.The phase structure has been changed from a rhombohedral phase to a rhombohedral-tetragonal coexisted phase.This is beneficial for RFE properties and gives a Wrec of 6.45 J/cm^(3) and a h of 90%at 400 kV/cm.Also,the energy-storage property is very temperature stable between 30 and 150C.These results show that process optimization and composition design can be used to improve the energy storage properties,and that the dielectric ceramic materials made can be used in high-powder pulse dielectric capacitors.展开更多
Green buildings have become broadly adopted in commercial and residential sectors with the objective of minimizing environmental impacts through reductions in energy usage and water usage and,to a lesser extent,minimi...Green buildings have become broadly adopted in commercial and residential sectors with the objective of minimizing environmental impacts through reductions in energy usage and water usage and,to a lesser extent,minimizing environmental disturbances from the building site.In this paper,we develop and discuss a techno-economic model for a green commercial building that is 100%powered by a photovoltaic(PV)system in stand-alone configuration.A medium-sized office building in El Paso,TX was modelled to rely on a photovoltaic system to supply all of its electricity needs either directly from the PV system or through an energy-storage system(ESS)using Li-ion batteries(LIBs)or reversible fuel cells(RFCs).Cost results show that a 400-kW PV system can generate electricity at a cost of 2.21 cents/kWh in El Paso,TX and the average levelized cost of energy storage(LCOS)using 450-kW RFC is~31.3 cents/kWh,while this could reach as low as 25.5 cents/kWh using a small LIB ESS.While the RFC provides the flexibility required to meet building-energy demand,LIBs may not be able to meet building needs unless the storage size is increased substantially,which in turn incurs more energy-storage cost,making LIBs less favourable from an economic perspective.Sensitivity analysis revealed that capital cost,discount rate and expected system lifetime play key roles in shaping the LCOS in both systems.展开更多
This review presents a comprehensive overview of recent advances in supercapacitor electrode materials,with a particular emphasis on the synergistic interactions between electrode materials and electrolytes.Beyond the...This review presents a comprehensive overview of recent advances in supercapacitor electrode materials,with a particular emphasis on the synergistic interactions between electrode materials and electrolytes.Beyond the conventional categorization of materials such as carbon-based materials,conducting polymers,and metal oxides,we focus on emerging nanostructured systems including MXenes,transition metal dichalcogenides(TMDs),black phosphorus,and quantum dots.We highlight how engineering the electrode–electrolyte interface—through the use of ionic liquids,gelbased,and solid-state electrolytes—can enhance device performance by expanding voltage windows,improving cycling stability,and suppressing selfdischarge.展开更多
New energy-storage systems play a pivotal role in the development of the new power system for advancing the energy transition in China.In the“14th Five-Year Plan”for the New Energy-Storage Development,it is proposed...New energy-storage systems play a pivotal role in the development of the new power system for advancing the energy transition in China.In the“14th Five-Year Plan”for the New Energy-Storage Development,it is proposed to expand investment and construction models by promoting the deployment of energy-storage facilities through the ways of self-construction,leasing,and purchasing,and to encourage the development of the shared energy-storage.However,the current scarcity in the model of the shared energy-storage invest-ment and construction substantially restricts its development,particularly due to unclear mechanisms for cost and benefit allocation,which also discourages potential investors.To address the issue,this paper proposes investment and construction models for shared energy-storage that aligns with the present stage of energy storage development.In specific,three main models are introduced:(1)Cen-tralized Self-built Shared Energy-Storage model(CSSES),(2)Third-party Investment Shared Energy-Storage model(TISES),and(3)Distributed Self-built Shared Energy Storage(DSSES)model.The cost–benefit analysis is conducted for each model.The results indicate that the CSSES model achieves the highest internal rate of return(11.5%)and the shortest payback period,while the DSSES model per-forms acceptable with an IRR of 9.4%.In contrast,the TISES model shows the lowest IRR(6.7%)and requires higher electricity price for being feasible.Furthermore,the study employs the entropy weight method and the analytic hierarchy process(AHP)for indicator eval-uation,and integrates the technique for order preference by the similarity to an ideal solution(TOPSIS)for scheme optimization.The results show that both the CSSES model and the DSSES model achieve the highest proximity scores.Under environmental regulations,these models demonstrate superior economic benefits by optimizing energy storage utilization,reducing user costs,and enhancing overall profitability.展开更多
Extensive efforts have recently been devoted to the construction of aqueous rechargeable sodium-ion batteries(ARSIBs)for large-scale energy-storage applications due to their desired properties of abundant sodium resou...Extensive efforts have recently been devoted to the construction of aqueous rechargeable sodium-ion batteries(ARSIBs)for large-scale energy-storage applications due to their desired properties of abundant sodium resources and inherently safer aqueous electrolytes.However,it is still a significant challenge to develop highly flexible ARSIBs ascribing to the lack of flexible electrode materials.In this work,nanocube-like KNiFe(CN)6(KNHCF)and rugby balllike NaTi2(PO4)3(NTP)are grown on carbon nanotube fibers via simple and mild methods as the flexible binder-free cathode(KNHCF@CNTF)and anode(NTP@CNTF),respectively.Taking advantage of their high conductivity,fast charge transport paths,and large accessible surface area,the as-fabricated binder-free electrodes display admirable electrochemical performance.Inspired by the remarkable flexibility of the binder-free electrodes and the synergy of KNHCF@CNTF and NTP@CNTF,a high-performance quasi-solid-state fiber-shaped ARSIB(FARSIB)is successfully assembled for the first time.Significantly,the as-assembled FARSIB possesses a high capacity of 34.21 mAh cm?3 and impressive energy density of 39.32 mWh cm?3.More encouragingly,our FARSIB delivers superior mechanical flexibility with only 5.7%of initial capacity loss after bending at 90°for over 3000 cycles.Thus,this work opens up an avenue to design ultraflexible ARSIBs based on all binder-free electrodes for powering wearable and portable electronics.展开更多
Flow batteries with high energy density and long cycle life have been pursued to advance the progress of energy storage and grid application. Non-aqueous batteries with wide voltage windows represent a promising techn...Flow batteries with high energy density and long cycle life have been pursued to advance the progress of energy storage and grid application. Non-aqueous batteries with wide voltage windows represent a promising technology without the limitation of water electrolysis, but they suffer from low electrolyte concentration and unsatisfactory battery performance. Here, a non-aqueous lithium bromine rechargeable battery is proposed, which is based on Br;/Br;and Li;/Li as active redox pairs, with fast redox kinetics and good stability. The Li/Br battery combines the advantages of high output voltage（;.1 V）,electrolyte concentration（3.0 mol/L）, maximum power density（29.1 m W/cm;） and practical energy density（232.6 Wh/kg）. Additionally, the battery displays a columbic efficiency（CE） of 90.0%, a voltage efficiency（VE） of 88.0% and an energy efficiency（EE） of 80.0% at 1.0 m A/cm;after continuously running for more than 1000 cycles, which is by far the longest cycle life reported for non-aqueous flow batteries.展开更多
Core-shell Bi-Bi2 O3/CNT(carbon nanotube) with 3-dimensional neural network structure where Bi-Bi2O3 nanospheres act as cell bodies supported by a 3-dimensional network of CNTs acting as synapses is designed and prepa...Core-shell Bi-Bi2 O3/CNT(carbon nanotube) with 3-dimensional neural network structure where Bi-Bi2O3 nanospheres act as cell bodies supported by a 3-dimensional network of CNTs acting as synapses is designed and prepared by simple solvothermal method and subsequent annealing autoreduction treatment,and this structure facilitates the efficient transport of electrons.It can provide two electron transfer paths due to the double contact of Bi2O3 shell with CNT and metal Bi core which enhances the efficiency of the electrochemical reaction.The Bi-Bi2 O3/CNT electrode shows a high gravimetric capacitance of 850 F g-1(1 A g-1),and the specific capacitance of Bi-Bi2O3/CNT can be still 714 F g-1 at 30 A g-1 indicating excellent rate performance.The asymmetric supercapacitor is assembled with Bi-Bi2 O3/CNT as the negative electrode and Ni(OH)2/CNT as the positive electrode,delivering a high energy density of 36.7 Wh kg-1 and a maximum power density of 8000 W kg-1.Therefore,the core-shell Bi-Bi2O3/CNT with 3-dimensional neural network structure as the negative electrode of supercapacitor shows great potential in the field of energy storage in the future.展开更多
Metal-ion capacitors(including Li^(+),Na^(+),and K^(+))effectively combine a battery negative electrode capable of reversibly intercalating metal cations,together with an electrical double-layer positive electrode.How...Metal-ion capacitors(including Li^(+),Na^(+),and K^(+))effectively combine a battery negative electrode capable of reversibly intercalating metal cations,together with an electrical double-layer positive electrode.However,such novel cell design has a birth defect,namely kinetics mismatch between sluggish negative electrode and fast positive electrode,thus limiting the energy-power performance.Herein,we design a MoS_(2)-carbon composite anode with the ordered macroporous architecture and interlayer-expanded feature,exhibiting the fast and reversible Na^(+)redox processes.This kinetically favored anode is coupled with a homemade activated carbon cathode that allows for the excellent electrochemical performance of sodiumion capacitor with respect to large specific capacity,high-rate capability,and robust cycling.Through quantification of the potential swings of anode and cathode via a three-electrode Swagelok cell,we for the first time observe the abnormal variation law of potential swings and thus directly providing the evidence that the kinetics gap has been filled up by this kinetically favored anode.Our results represent a crucial step toward understanding the key issues of kinetics mismatch for hybrid cell,thus propelling the development of design of kinetically favored anode materials for high-performance metalion capacitors.展开更多
Degradation of 2,6-dibromophenol (2,6-DBP) in the aqueous solution was studied using dielectric barrier discharge in micro-bubbles. Experimental comparison of working gas Ar, N<sub>2</sub>, O<sub>2&l...Degradation of 2,6-dibromophenol (2,6-DBP) in the aqueous solution was studied using dielectric barrier discharge in micro-bubbles. Experimental comparison of working gas Ar, N<sub>2</sub>, O<sub>2</sub>, and air showed that oxygen and air plasma efficiently decomposed 2,6-DBP to bromide ion, and inorganic carbon. The molecular orbital model was applied in the analysis of the degradation in electrophilic, nucleophilic, and radical reactions.展开更多
A novel three-phase active power filter （APF） circuit with photovoltaic （PV） system to improve the quality of service and to reduce the capacity of energy storage capacitor is presented. The energy balance concept...A novel three-phase active power filter （APF） circuit with photovoltaic （PV） system to improve the quality of service and to reduce the capacity of energy storage capacitor is presented. The energy balance concept and sampling technique were used to simplify the calculation algorithm for the required utility source current and to control the voltage of the energy storage capacitor. The feasibility was verified by using the Pspice simulations and experiments. When the APF mode was used during non-operational period, not only the utilization rate, power factor and power quality could be improved, but also the capacity of energy storage capacitor could sparing. As the results, the advantages of the APF circuit are simplicity of control circuits, low cost, and good transient response.展开更多
A microgrid is defined as a local electric power distribution system with diverse DG （distributed generation） units, energy storage systems, and loads, which can operate as a part of the distribution system or when ...A microgrid is defined as a local electric power distribution system with diverse DG （distributed generation） units, energy storage systems, and loads, which can operate as a part of the distribution system or when needed can operate in an islanded mode. Energy storage systems play a key role in improving security, stability, and power quality of the microgrid. During grid-connected mode, these storage units are charged from various DG sources as well as the main grid. During islanded mode, DG sources along with the storage units need to supply the load. Power electronic interfaces between the microgrid buses and the storage units should be able to detect the mode of operation, allow seamless transition between the modes, and allow power flow in both directions, while maintaining stability and power quality. An overview of bidirectional converter topologies relevant to microgrid energy storage application and their control strategies will be presented in this paper.展开更多
文摘Energy-storage welding connection characteristics of rapidly solidified AZ91D Mg alloy ribbons with 40-70 μm thickness are investigated using a microtype energy-storage welding machine. The microstructure and performance of the connection joints are analyzed and studied. The research results indicate that energy-storage welding is able to realize the spot welding connection of AZ9ID Mg alloy ribbons. The welding nugget consists of developed α-Mg equiaxed grains with the sizes of 1.2-2.7 μm and intergranular distributed β-Mg17Al12 compounds. The thickness of bond zone is about 4 μm and the solidification microstructure is characterized by the fine equiaxed grains with the sizes of 0.8-1.2μm and grain boundary has become coarsening. The columnar crystal in HAZ also becomes slightly coarsening and the grain boundary has broadened, however, there is no obvious change in its primitive morphology and crystallographic direction. When welding energy is about 2.0 J, the welding joints with higher shear strength and smaller electrical resistivity are obtained.
文摘Fast charging stations play an important role in the use of electric vehicles(EV)and significantly affect the distribution network owing to the fluctuation of their power.For exploiting the rapid adjustment feature of the energy-storage system(ESS),a configuration method of the ESS for EV fast charging stations is proposed in this paper,which considers the fluctuation of the wind power as well as the characteristics of the charging load.The configuration of the ESS can not only mitigate the effects of fast charging stations on the connected distribution network but also improve its economic efficiency.First,the scenario method is adopted to model the wind power in the distribution network,and according to the characteristics of the EV and the driving probability,the charging demand of each station is calculated.Then,considering factors such as the investment cost,maintenance cost,discharging benefit,and wind curtailment cost,the ESS configuration model of the distribution network is set up,which takes the optimal total costs of the ESS for EV fast charging stations within its lifecycle as an objective.Finally,General Algebraic Modelling System(GAMS)is used to linearize and solve the proposed model.A simulation on an improved IEEE-69 bus system verifies the feasibility and economic efficiency of the proposed model.
基金This work was supported by the National Research Foundation(NRF)of South Korea funded by the Ministry of Science and ICT,Republic of Korea(Nos.NRF-2017R1A4A1014569 and NRF2018M3A7B4071535)。
文摘We re port the facile synthesis of Ni,Co-double hydroxide wire(NCHW)-based electrodes directly grown on a conductive substrate via a hydrothermal process.Various NCHW nanostructures were grown on Ni foam,and the growth was controlled using different compositions of solvents(ethanol and water).With increasing volume ratio of ethanol to water,the density of the wires decreased,and the spatial voids between the wires increased.The formation of large empty spaces improved the electrochemical performance because the exposure of a large surface area of the structure to the electrolyte resulted in a large number of active sites and facile electrolyte penetration into the structure.The different NCHW structures were ascribed to the pivotal role of the solvent in the urea hydrolysis;the solvent triggered the formation of hydroxides during the hydrothermal synthesis.The electrochemical performance of the NCHW electrodes was investigated via galvanostatic charge/discha rge tests,cyclic voltammetry,and electrochemical impedance spectroscopy.The highest specific capacitance was 1694.7 m F/cm^2 at 2 mA/cm^2,with excellent capacitance retention of 81.5% after 5000 cycles.The superior electrochemical performance of the NCHW electrodes is attributed to the large number of active sites and facile electrolyte diffusion into the structure,due to the well-organized structure with an optimized density of nanowires and large voids between the wires.
基金supported by the National Natural Science Foundation of China(Grant Nos.52272119,51872177,52202143,52173263 and 22308283)the Young Talent Support Plan of Shaanxi Province and the Shaanxi Sanqin Scholars Innovation Team,National Key R&D Program of China(No.2022YFB3603703)the Qinchuangyuan High-level Talent Project of Shaanxi(No.QCYRCXM-2022-219)and the Youth Innovation Team of Shaanxi Universities and the Scientific research fund for high-level talents of Xijing University(No.XJ23B10).
文摘A series of tungsten bronze(Sr_(2-x)Bi_(x)Ag_(0.2)Na_(0.8))(Nb_(4.8-x)Zr_(x)Sb_(0.2))O15 compounds were fabricated by solidstate method to systematically study the impacts of co-doping Bi^(3+)/Zr^(4+)ions in A/B-sites on the structures,relaxor characteristics,and energy-storage performances.The relationship between structures and relaxor behaviors are summarized as three main points:(1)with increasing the amount of codoping Bi^(3+)/Zr^(4+)ions,the crystal structure evolved from an orthorhombic Bbm^(2) to a tetragonal paraelectric P4/mbm symmetry at room temperature;(2)enhancing relaxor characteristics at room temperature was achieved by tailoring the temperature region of T_(m)-T_(B)(T_(m) is the dielectric maximum temperature,T_(B) is the Burns temperature),which could be attributed to the incommensurate local structure modulations associated with the orthogonal distortion of P4bm symmetry and the appearance of microdomains;(3)The co-introduction of Bi^(3+)and Zr^(4+)could also played an important role in inhibiting the grain sizes,increasing resistivity and band-gap to enhance the breakdown strength.Finally,a superior recoverable energy-storage density(3.61 J/cm^(3))and an ultrahigh energy efficiency(90%)were obtained simultaneously at 389 kV/cm in BZ0.05 ceramics.Moreover,an outstanding power density(158.98 MW/cm^(3))together with a current density of 1422.29 A/cm^(2)was realized at 220 kV/cm from the charging-discharging performance measurements.The excellent energy-storage performance(ESPs)make the environmentally friendly BZ0.05 samples show enormous potential in high-power capacitor applications.
文摘Energy-storage technologies based on lithium-ion batteries are advancing rapidly.However,the occurrence of thermal runaway in batteries under extreme operating conditions poses serious safety concerns and potentially leads to severe accidents.To address the detection and early warning of battery thermal runaway faults,this study conducted a comprehensive review of recent advances in lithium battery fault monitoring and early warning in energy-storage systems from various physical perspectives.The focus was electrical,thermal,acoustic,and mechanical aspects,which provide effective insights for energy-storage system safety enhancement.
基金Financial support from the National Natural Science Foundation of China(Grant No.52072103 and U19A2087)the AHPU innovation team project(S022021058)is gratefully acknowledged.
文摘Compared with antiferroelectric(AFE)orthothombic R phases,AFE orthothombic P phases in Na NbO_(3)(NN)ceramics have been rarely investigated,particularly in the field of energy-storage capadtors.The main bottlenedk is closely related to the contradiction between d fficultly achieved stable relaxor AFE P phase and easily induced P-R phase transition during modifying dhemical compositions.Herein,we reporta novel lead-free AFE ceramic of(1-x)NN-x(Bi_(0.5)K_(0.5))ZrO_(3)((1-x)NN-xBKZ)with a pure AFE P phase str ucture,which exhibits excellent energy-storage characteristics,such as an ultrahigh recoverable energy density(W_(rec))-4.4 J/cm^(3) at x=0.11,a large powder density P_(D)-104 MW/cm^(3) and a fast discharge rate t_(0.9)-45 ns.The analysis of polarization-field response,Raman spectrum and transmission elecron microscopy demonstrates that the giant amplification of W_(rec) by≥177% should be ma inly ascribed to the simultaneously and effectively enhanced AFE P phase stbility and its relaxor dharacteristics,resulting in a diffused reversible electric field-induced AFE P-ferroelectric phase transition with concurrently incre.ased driving electric fields.Different from mast(1-x)NN-xABO_(3) systems,it was found that the reduced polarizability of B-site cations dominates the enhanced AFE P-phase stability in(1-x)NN-xBKZ ceramics,but the almost unchanged tolerance factor tends to ause the AFE R phase to be induced at a relatively high x value.
基金supported by the Beijing Institute of Technology Research Fund Program for Young Scholarsthe Excellent Young Scholars Research Fund of Beijing Institute of Technologythe National Science & Technology Pillar Program(Grant No.2013BAG05B00)
文摘The combination of batteries and ultracapacitors has become an effective solution to satisfy the requirements of high power density and high energy density for the energy-storage system of electric vehicles.Three aspects of such combination efforts were considered for evaluating the four types of hybrid energy-storage system(HESS)topologies.First,a novel optimization framework was proposed and implemented to optimize the voltage level of a battery pack and an ultracapacitor pack for the four types of HESS topologies.During the optimization process,the dynamic programming(DP)algorithm was iteratively applied to determine the optimal control actions.The simulation results with DP were used to evaluate the energy efficiency of different HESS topologies at different voltage levels.Second,the optimized voltage level of the battery and ultracapacitor in each topology indicates that a higher voltage level usually results in a better system performance.The simulation results also illustrate that the optimized rated voltage level of the battery pack is approximately 499.5 V,while for the ultracapacitor pack,the optimized voltage level is at its maximum allowed value.Note that the constraint of the battery voltage is initialized at200–600 V.Third,the control rules for different HESS topologies were obtained through the systematic analysis of the simulation results.In addition,advantages and disadvantages of the four topologies were summarized through evaluation of the efficiency and operating currents of the batteries and the ultracapacitor.
基金the Third World Academy of Sciences(RG/PHYS/LA Nos.99-050,02-225 and 05-043)the ICTP,Trieste-Italy,for financial support of Latin-American Network of Ferroelectric Materials(NET-43).
文摘Switching mechanisms and energy-storage properties have been investigated in(Pb_(0.98)La_(0.02)T(Zr_(0.95)Ti_(0.05)T_(0.995O_(3)) antiferroelectric ceramics.The electric field dependence of polarization(P–E hysteresis loops)indicates that both the ferroelectric(FE)and antiferroelectric(AFE)phases coexist,being the AFE more stable above 100℃.It has been observed that the temperature has an important influence on the switching parameters.On the other hand,the energy-storage density,which has been calculated from the P–E hysteresis loops,shows values higher than 1 J/cm^(3) for temperatures above 100℃ with around 73%of efficiency as average.These properties indicate that the studied ceramic system reveals as a promising AFE material for energy-storage devices application.
文摘In the last few decades,dielectric capacitors have gotten a lot of attention because they can store more power and charge and discharge very quickly.But it has a low energy-storage density(Wrec),efficiency(h),and temperature stability.By adding Pb(Mg1/3Nb2/3)O3(PMN)and(Bi0$1Sr0.85)TiO3(BST)to a nonstoichiometric(Bi0$51Na0.5)TiO3(BNT)matrix,the goal is to change the phase transition properties and make the material more relaxor ferroelectric(RFE)by lowering the remnant polarization Pr and keeping the maximum polarization Pmax.A viscous polymer process(VPP)is used to improve the electric breakdown strength,which is also a key part of being able to store energy.By working together,ceramics with the formula 0.79[0.85BNT-0.15PMN]-0.21BST(BP-0.21BST)are made.The phase structure has been changed from a rhombohedral phase to a rhombohedral-tetragonal coexisted phase.This is beneficial for RFE properties and gives a Wrec of 6.45 J/cm^(3) and a h of 90%at 400 kV/cm.Also,the energy-storage property is very temperature stable between 30 and 150C.These results show that process optimization and composition design can be used to improve the energy storage properties,and that the dielectric ceramic materials made can be used in high-powder pulse dielectric capacitors.
基金funding from Khalifa University-Grant number 8474000238/FSU-2020-14 to conduct this research.
文摘Green buildings have become broadly adopted in commercial and residential sectors with the objective of minimizing environmental impacts through reductions in energy usage and water usage and,to a lesser extent,minimizing environmental disturbances from the building site.In this paper,we develop and discuss a techno-economic model for a green commercial building that is 100%powered by a photovoltaic(PV)system in stand-alone configuration.A medium-sized office building in El Paso,TX was modelled to rely on a photovoltaic system to supply all of its electricity needs either directly from the PV system or through an energy-storage system(ESS)using Li-ion batteries(LIBs)or reversible fuel cells(RFCs).Cost results show that a 400-kW PV system can generate electricity at a cost of 2.21 cents/kWh in El Paso,TX and the average levelized cost of energy storage(LCOS)using 450-kW RFC is~31.3 cents/kWh,while this could reach as low as 25.5 cents/kWh using a small LIB ESS.While the RFC provides the flexibility required to meet building-energy demand,LIBs may not be able to meet building needs unless the storage size is increased substantially,which in turn incurs more energy-storage cost,making LIBs less favourable from an economic perspective.Sensitivity analysis revealed that capital cost,discount rate and expected system lifetime play key roles in shaping the LCOS in both systems.
基金supported by the Technology Innovation Program of the Ministry of Trade,Industry and Energy(MOTIE)(project No.RS-2023-00266568)。
文摘This review presents a comprehensive overview of recent advances in supercapacitor electrode materials,with a particular emphasis on the synergistic interactions between electrode materials and electrolytes.Beyond the conventional categorization of materials such as carbon-based materials,conducting polymers,and metal oxides,we focus on emerging nanostructured systems including MXenes,transition metal dichalcogenides(TMDs),black phosphorus,and quantum dots.We highlight how engineering the electrode–electrolyte interface—through the use of ionic liquids,gelbased,and solid-state electrolytes—can enhance device performance by expanding voltage windows,improving cycling stability,and suppressing selfdischarge.
基金supported by the Humanities and Social Sciences of Ministry of Education Planning Fund of China(Grant No.21YJA790009)the National Natural Science Foundation of China(Grant No.72140001).
文摘New energy-storage systems play a pivotal role in the development of the new power system for advancing the energy transition in China.In the“14th Five-Year Plan”for the New Energy-Storage Development,it is proposed to expand investment and construction models by promoting the deployment of energy-storage facilities through the ways of self-construction,leasing,and purchasing,and to encourage the development of the shared energy-storage.However,the current scarcity in the model of the shared energy-storage invest-ment and construction substantially restricts its development,particularly due to unclear mechanisms for cost and benefit allocation,which also discourages potential investors.To address the issue,this paper proposes investment and construction models for shared energy-storage that aligns with the present stage of energy storage development.In specific,three main models are introduced:(1)Cen-tralized Self-built Shared Energy-Storage model(CSSES),(2)Third-party Investment Shared Energy-Storage model(TISES),and(3)Distributed Self-built Shared Energy Storage(DSSES)model.The cost–benefit analysis is conducted for each model.The results indicate that the CSSES model achieves the highest internal rate of return(11.5%)and the shortest payback period,while the DSSES model per-forms acceptable with an IRR of 9.4%.In contrast,the TISES model shows the lowest IRR(6.7%)and requires higher electricity price for being feasible.Furthermore,the study employs the entropy weight method and the analytic hierarchy process(AHP)for indicator eval-uation,and integrates the technique for order preference by the similarity to an ideal solution(TOPSIS)for scheme optimization.The results show that both the CSSES model and the DSSES model achieve the highest proximity scores.Under environmental regulations,these models demonstrate superior economic benefits by optimizing energy storage utilization,reducing user costs,and enhancing overall profitability.
基金supported by the Fundamental Research Funds for the Central Universities(No.020514380183)the National Natural Science Foundation of China(No.51703241)+1 种基金the Key Research Program of Frontier Science of Chinese Academy of Sciences(No.QYZDB-SSW-SLH031)the Thousand Youth Talents Plan,and the Science and Technology Project of Nanchang(2017-SJSYS-008).
文摘Extensive efforts have recently been devoted to the construction of aqueous rechargeable sodium-ion batteries(ARSIBs)for large-scale energy-storage applications due to their desired properties of abundant sodium resources and inherently safer aqueous electrolytes.However,it is still a significant challenge to develop highly flexible ARSIBs ascribing to the lack of flexible electrode materials.In this work,nanocube-like KNiFe(CN)6(KNHCF)and rugby balllike NaTi2(PO4)3(NTP)are grown on carbon nanotube fibers via simple and mild methods as the flexible binder-free cathode(KNHCF@CNTF)and anode(NTP@CNTF),respectively.Taking advantage of their high conductivity,fast charge transport paths,and large accessible surface area,the as-fabricated binder-free electrodes display admirable electrochemical performance.Inspired by the remarkable flexibility of the binder-free electrodes and the synergy of KNHCF@CNTF and NTP@CNTF,a high-performance quasi-solid-state fiber-shaped ARSIB(FARSIB)is successfully assembled for the first time.Significantly,the as-assembled FARSIB possesses a high capacity of 34.21 mAh cm?3 and impressive energy density of 39.32 mWh cm?3.More encouragingly,our FARSIB delivers superior mechanical flexibility with only 5.7%of initial capacity loss after bending at 90°for over 3000 cycles.Thus,this work opens up an avenue to design ultraflexible ARSIBs based on all binder-free electrodes for powering wearable and portable electronics.
基金financial supported by the Natural Science Foundation of China(Grant No.21476224,21406219 and 51361135701)
文摘Flow batteries with high energy density and long cycle life have been pursued to advance the progress of energy storage and grid application. Non-aqueous batteries with wide voltage windows represent a promising technology without the limitation of water electrolysis, but they suffer from low electrolyte concentration and unsatisfactory battery performance. Here, a non-aqueous lithium bromine rechargeable battery is proposed, which is based on Br;/Br;and Li;/Li as active redox pairs, with fast redox kinetics and good stability. The Li/Br battery combines the advantages of high output voltage（;.1 V）,electrolyte concentration（3.0 mol/L）, maximum power density（29.1 m W/cm;） and practical energy density（232.6 Wh/kg）. Additionally, the battery displays a columbic efficiency（CE） of 90.0%, a voltage efficiency（VE） of 88.0% and an energy efficiency（EE） of 80.0% at 1.0 m A/cm;after continuously running for more than 1000 cycles, which is by far the longest cycle life reported for non-aqueous flow batteries.
文摘Core-shell Bi-Bi2 O3/CNT(carbon nanotube) with 3-dimensional neural network structure where Bi-Bi2O3 nanospheres act as cell bodies supported by a 3-dimensional network of CNTs acting as synapses is designed and prepared by simple solvothermal method and subsequent annealing autoreduction treatment,and this structure facilitates the efficient transport of electrons.It can provide two electron transfer paths due to the double contact of Bi2O3 shell with CNT and metal Bi core which enhances the efficiency of the electrochemical reaction.The Bi-Bi2 O3/CNT electrode shows a high gravimetric capacitance of 850 F g-1(1 A g-1),and the specific capacitance of Bi-Bi2O3/CNT can be still 714 F g-1 at 30 A g-1 indicating excellent rate performance.The asymmetric supercapacitor is assembled with Bi-Bi2 O3/CNT as the negative electrode and Ni(OH)2/CNT as the positive electrode,delivering a high energy density of 36.7 Wh kg-1 and a maximum power density of 8000 W kg-1.Therefore,the core-shell Bi-Bi2O3/CNT with 3-dimensional neural network structure as the negative electrode of supercapacitor shows great potential in the field of energy storage in the future.
基金supported by National Natural Science Foundation of China(No.51902188)Natural Science Foundation of Jiangsu Province(No.BK20190207)+1 种基金Natural Science Doctoral Foundation of Shandong Province(No.ZR2019BB057)the CAS Key Laboratory of Carbon Materials(No.KLCMKFJJ2006).
文摘Metal-ion capacitors(including Li^(+),Na^(+),and K^(+))effectively combine a battery negative electrode capable of reversibly intercalating metal cations,together with an electrical double-layer positive electrode.However,such novel cell design has a birth defect,namely kinetics mismatch between sluggish negative electrode and fast positive electrode,thus limiting the energy-power performance.Herein,we design a MoS_(2)-carbon composite anode with the ordered macroporous architecture and interlayer-expanded feature,exhibiting the fast and reversible Na^(+)redox processes.This kinetically favored anode is coupled with a homemade activated carbon cathode that allows for the excellent electrochemical performance of sodiumion capacitor with respect to large specific capacity,high-rate capability,and robust cycling.Through quantification of the potential swings of anode and cathode via a three-electrode Swagelok cell,we for the first time observe the abnormal variation law of potential swings and thus directly providing the evidence that the kinetics gap has been filled up by this kinetically favored anode.Our results represent a crucial step toward understanding the key issues of kinetics mismatch for hybrid cell,thus propelling the development of design of kinetically favored anode materials for high-performance metalion capacitors.
文摘Degradation of 2,6-dibromophenol (2,6-DBP) in the aqueous solution was studied using dielectric barrier discharge in micro-bubbles. Experimental comparison of working gas Ar, N<sub>2</sub>, O<sub>2</sub>, and air showed that oxygen and air plasma efficiently decomposed 2,6-DBP to bromide ion, and inorganic carbon. The molecular orbital model was applied in the analysis of the degradation in electrophilic, nucleophilic, and radical reactions.
文摘A novel three-phase active power filter （APF） circuit with photovoltaic （PV） system to improve the quality of service and to reduce the capacity of energy storage capacitor is presented. The energy balance concept and sampling technique were used to simplify the calculation algorithm for the required utility source current and to control the voltage of the energy storage capacitor. The feasibility was verified by using the Pspice simulations and experiments. When the APF mode was used during non-operational period, not only the utilization rate, power factor and power quality could be improved, but also the capacity of energy storage capacitor could sparing. As the results, the advantages of the APF circuit are simplicity of control circuits, low cost, and good transient response.
文摘A microgrid is defined as a local electric power distribution system with diverse DG （distributed generation） units, energy storage systems, and loads, which can operate as a part of the distribution system or when needed can operate in an islanded mode. Energy storage systems play a key role in improving security, stability, and power quality of the microgrid. During grid-connected mode, these storage units are charged from various DG sources as well as the main grid. During islanded mode, DG sources along with the storage units need to supply the load. Power electronic interfaces between the microgrid buses and the storage units should be able to detect the mode of operation, allow seamless transition between the modes, and allow power flow in both directions, while maintaining stability and power quality. An overview of bidirectional converter topologies relevant to microgrid energy storage application and their control strategies will be presented in this paper.
