通过1-乙基-3-甲基咪唑硫酸乙酯离子液体(EMIES)和对甲苯磺酸(p-TsOH)的混合物制备EMIES/p-TsOH型低共熔溶剂。其结构特征通过红外光谱、氢谱和热重技术进行了分析。并以EMIES/p-TsOH作为催化剂与萃取剂,H2O2作为氧化剂研究了其对模拟...通过1-乙基-3-甲基咪唑硫酸乙酯离子液体(EMIES)和对甲苯磺酸(p-TsOH)的混合物制备EMIES/p-TsOH型低共熔溶剂。其结构特征通过红外光谱、氢谱和热重技术进行了分析。并以EMIES/p-TsOH作为催化剂与萃取剂,H2O2作为氧化剂研究了其对模拟油中的硫化物的脱除性能。考察了反应温度、n(H2O2)/n(S)比、低共熔溶剂加入量及硫化物类型对脱硫效果的影响。在最佳的条件下,模拟油中二苯并噻吩(DBT)、4,6-二甲基二苯并噻吩(4,6-DMDBT)和苯并噻吩(BT)的脱除率分别为96.2%、92.2%和88.8%。经过五次循环使用后,DBT的脱除率仍达到93.6%。对该脱硫体系进行了动力学分析,其表观活化能为66.4 k J/mol。展开更多
Cross-band camouflage technology is a critical necessity,enabling personnel and equipment to evade detection across evolving surveillance systems,thereby enhancing survivability and mission success.Herein,this work de...Cross-band camouflage technology is a critical necessity,enabling personnel and equipment to evade detection across evolving surveillance systems,thereby enhancing survivability and mission success.Herein,this work develops a layer-structured composite system based on carbon nanotube(CNT)film comprising ionic liquid(IL)interlayer for infrared(IR)modulation and surface-engineered Cu_(2)O nanoparticles for visible camouflage.The CNT/IL/CNT architecture enables reversible IR emissivity switching(Δε≈0.55)through electrically driven ion intercalation/deintercalation within 2 s,while spray-coated Cu_(2)O nanoparticles(100~400 nm diameter)on the top CNT film layer generate rich structure colors with 90%IR transmittance.This spectral-decoupling design overcomes the traditional trade-off between color visibility and IR transmittance observed in pigment-based systems.Remarkably,due to physical interface coupling,the Cu_(2)O-coated layer-structured system maintains exceptional electrical conductivity,enabling simultaneous electromagnetic interference shielding and electrothermal energy conversion.The integrated system demonstrates long-term operational stability.By unifying visible-IR camouflage,electromagnetic protection,and energy management in a lightweight platform,this work provides an important paradigm for cross-band camouflage technologies.展开更多
文摘通过1-乙基-3-甲基咪唑硫酸乙酯离子液体(EMIES)和对甲苯磺酸(p-TsOH)的混合物制备EMIES/p-TsOH型低共熔溶剂。其结构特征通过红外光谱、氢谱和热重技术进行了分析。并以EMIES/p-TsOH作为催化剂与萃取剂,H2O2作为氧化剂研究了其对模拟油中的硫化物的脱除性能。考察了反应温度、n(H2O2)/n(S)比、低共熔溶剂加入量及硫化物类型对脱硫效果的影响。在最佳的条件下,模拟油中二苯并噻吩(DBT)、4,6-二甲基二苯并噻吩(4,6-DMDBT)和苯并噻吩(BT)的脱除率分别为96.2%、92.2%和88.8%。经过五次循环使用后,DBT的脱除率仍达到93.6%。对该脱硫体系进行了动力学分析,其表观活化能为66.4 k J/mol。
基金Financial support from the National Nature Science Foundation of China(No.:52373244)the Foundation of National Science and Technology Key Laboratory(No.:KZ571801)。
文摘Cross-band camouflage technology is a critical necessity,enabling personnel and equipment to evade detection across evolving surveillance systems,thereby enhancing survivability and mission success.Herein,this work develops a layer-structured composite system based on carbon nanotube(CNT)film comprising ionic liquid(IL)interlayer for infrared(IR)modulation and surface-engineered Cu_(2)O nanoparticles for visible camouflage.The CNT/IL/CNT architecture enables reversible IR emissivity switching(Δε≈0.55)through electrically driven ion intercalation/deintercalation within 2 s,while spray-coated Cu_(2)O nanoparticles(100~400 nm diameter)on the top CNT film layer generate rich structure colors with 90%IR transmittance.This spectral-decoupling design overcomes the traditional trade-off between color visibility and IR transmittance observed in pigment-based systems.Remarkably,due to physical interface coupling,the Cu_(2)O-coated layer-structured system maintains exceptional electrical conductivity,enabling simultaneous electromagnetic interference shielding and electrothermal energy conversion.The integrated system demonstrates long-term operational stability.By unifying visible-IR camouflage,electromagnetic protection,and energy management in a lightweight platform,this work provides an important paradigm for cross-band camouflage technologies.
