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离子液体EMBF_4中对硝基甲苯电还原的研究 被引量:1
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作者 肖友军 周磊 +1 位作者 王灵峰 李芳芳 《江西师范大学学报(自然科学版)》 CAS 北大核心 2010年第2期160-164,共5页
采用循环伏安法研究了离子液体EMBF4(1-乙基-3-甲基咪唑四氟硼酸)中对硝基甲苯在微铂电极上的电还原特性.实验结果表明:在EMBF4中,对硝基甲苯能够进行电还原反应,随着对硝基甲苯浓度增加,循环伏安曲线峰1和峰2的峰电位负移,峰电流增加;... 采用循环伏安法研究了离子液体EMBF4(1-乙基-3-甲基咪唑四氟硼酸)中对硝基甲苯在微铂电极上的电还原特性.实验结果表明:在EMBF4中,对硝基甲苯能够进行电还原反应,随着对硝基甲苯浓度增加,循环伏安曲线峰1和峰2的峰电位负移,峰电流增加;随着电解液中水浓度的增加,循环伏安曲线峰1峰电位正向移动,峰2峰电位负向移动,峰1和峰2的峰电流都增大;对硝基甲苯在离子液体EMBF4的电还原过程中扩散是其主要的控制步骤. 展开更多
关键词 对硝基甲苯 embf4 离子液体 电还原
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The Effect of AC Electro-magnetic Body Force on the Solidified Microstructure of Zn-10%Bi Hyper-Monotectic Alloy
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作者 ZHENG Tian-xiang ZHONG Yun-bo +4 位作者 SUN Zong-qian WANG Jiang LEI Zuo-sheng REN Wei-li REN Zhong-ming 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2012年第S1期420-424,共5页
Monotetic alloy have been researched for hundred years.Recent years,researchers have prepared homogeneous monotectic alloy by electro-magnetic body force(EMBF).But the mechanism of separation and refinement of the sec... Monotetic alloy have been researched for hundred years.Recent years,researchers have prepared homogeneous monotectic alloy by electro-magnetic body force(EMBF).But the mechanism of separation and refinement of the second phase in liquid matrix by EMBF is not very clear.This paper investigated the effect of different AC EMBF on the microstructure and solidification process of Zn-10%Bi hyper-monotectic alloy by quenching the samples in water under high static magnetic field.It is shown that,the superimposing of AC EMBF can influence the moving speed of the second phase droplet and damp the gravity segregation in solidifying Zn-10%Bi alloy.When the AC EMBF reaches 5×10~5N/m^3 in different magnetic flux densities from 2 to 10 Tesla,the homogenuous distribution of bismuth particles could be achieved,A physical model is established to illustrate the mechanism of separation and refinement of the second Bi droplets at the stage of liquid-liquid separation by AC EMBF.The results show that the second droplets can be divided into two or three smaller droplets by Lorenz force caused by induced current at the former and later location of bismuth droplet.When the bismuth droplet moves at a proper speed which is adjusted by EMBF,it will be broken down by Lorenz forces. 展开更多
关键词 High magnetic field Hyper-monotectic alloy SEGREGATION embf
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Behavior of particles in front of metallic solid/liquid interface in electromagnetic field
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作者 钟云波 任忠鸣 +3 位作者 孙秋霞 江志文 邓康 徐匡迪 《中国有色金属学会会刊:英文版》 CSCD 2003年第4期755-763,共9页
The first part deals with the behavior of particles theoretically, and the critical electromagnetic force needed to alter the behavior of particles was deduced under different conditions. It was proposed that applying... The first part deals with the behavior of particles theoretically, and the critical electromagnetic force needed to alter the behavior of particles was deduced under different conditions. It was proposed that applying electromagnetic force would change the distribution coefficient of the particles. By using the data from literatures, the migrating rate of SiC particle by electromagnetic force was calculated, which is far more than the critical rate of solidifying interface which will result in the engulfment of the SiC particle in the Al SiC matrix metal. Therefore the possibility of controlling the behavior of the particles in front of the solidifying interface by electromagnetic field was confirmed. In the second part, by using simulative experiments, the man made alternation of the behavior of the particles in front of the solidifying interface under electromagnetic field was observed, and the idea of changing the distribution of the particles in solidified metal by electromagnetic force was verified experimentally. It is shown that, the particle, which would be engulfed by the solidifying interface, would escape from the interface under electromagnetic buoyant force (EMBF), and the particles adherent to the interface would migrate toward it and be engulfed finally under EMBF. Further more, the particles being pushed by the interface would stay at the interface, the repulsive force exerted on the particles would be counteracted by EMBF, and then the particle would turn to be engulfed. Adjusting the direction and magnitude of EMBF could alter the distribution of the particles in the solidifying metal. 展开更多
关键词 电磁连铸 电磁场 固液界面 embf 碳化硅 铝合金
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