The rapid advancement of information technology has heightened interest in complementary devices and circuits.Conventional p-type semiconductors often lack sufficient electrical performance,thus prompting the search f...The rapid advancement of information technology has heightened interest in complementary devices and circuits.Conventional p-type semiconductors often lack sufficient electrical performance,thus prompting the search for new materials with high hole mobility and long-term stability.Elemental tellurium(Te),featuring a one-dimensional chiral atomic structure,has emerged as a promising candidate due to its narrow bandgap,high hole mobility,and versatility in industrial applications,particularly in electronics and renewable energy.This review highlights recent progress in Te nanostructures and related devices,focusing on synthesis methods,including vapor deposition and hydrothermal synthesis,which produce Te nanowires,nanorods,and other nanostructures.Critical applications in photodetectors,gas sensors,and energy harvesting devices are discussed,with a special emphasis on their role within the internet of things(IoT)framework,a rapidly growing field that is reshaping our technological landscape.The prospects and potential applications of Te-based technologies are also highlighted.展开更多
As lithium-ion batteries(LIBs)continue to evolve toward lower costs and higher energy densities,their potential safety risks have become increasingly apparent.Incidents such as explosions at energy storage facilities,...As lithium-ion batteries(LIBs)continue to evolve toward lower costs and higher energy densities,their potential safety risks have become increasingly apparent.Incidents such as explosions at energy storage facilities,fires in electric vehicles,and building fires ignited by charging two-wheeled vehicles have been occurring with alarming frequency,often resulting in significant casualties and injuries.Conducting indepth investigations into thermal runaway(TR)incidents in LIBs can significantly reduce the risk of future occurrences.However,current investigations into LIB fire and explosion incidents face challenges due to the difficulty of conducting in-depth analyses and the lack of a robust theoretical framework to guide these investigations.To enhance the effectiveness of in-depth investigations into battery fire and explosion incidents and to address the lack of theoretical guidance,this paper is the first to systematically examine the conservation and flow patterns of elements during the TR process of LIBs.The analysis reveals that during TR,the gas products generated include approximately 1.5 g of H_(2),23.6 g of CO,88.4 g of CO_(2),8.9 g of C_(2)H_(4),7.3 g of CH_(4),3.7 g of C_(2)H_(6),and 82 g of electrolyte vapor.After TR,the solid compounds formed consist of approximately 2.5 g of LiF,29–92.2 g of elemental Ni/Co/Mn,11.4 g of Li_(2)CO_(3),200.6 g of graphite,1.4 g of NiO,29.6 g of MnO,30.1 g of CoO,67 g of elemental Cu,0.03 g of LiNiO_(2),and 4.3 g of LiAlO_(2).Importantly,the energy released from reactions forming solid compounds during TR surpasses that from gas-forming reactions.This investigation represents the first application of Hess’s law to verify the conservation of elements during the TR process of lithium-ion batteries.The proposed methodology is also applicable to other types of energy storage batteries,effectively advancing techniques for comprehensively investigating lithium battery fire and explosion incidents.展开更多
We demonstrate that the sliding motion between two layers of the newly discovered ferroelectric and topologically trivial bismuth(Bi)monolayer[Nature 61767(2023)]can induce a sequence of topological phase transitions,...We demonstrate that the sliding motion between two layers of the newly discovered ferroelectric and topologically trivial bismuth(Bi)monolayer[Nature 61767(2023)]can induce a sequence of topological phase transitions,alternating between Z_(2)trivial and nontrivial states.The lateral shift,while preserving spatial symmetry,can switch the quantum spin Hall state on and of.The sliding-induced changes in out-of-plane atomic buckling,which are directly coupled to in-plane ferroelectricity,are shown to signifcantly modulate the band gap and drive the topological phase transitions.We map out the topological phase diagram and in-plane ferroelectricity with respect to sliding displacements.With appropriate sliding,the bismuth bilayer can transition into a nontrivial polar metal,exhibiting a pronounced shift current response arising from interband geometric quantities of electronic bands.Moreover,bilayer Bi supports a sliding-tunable nonlinear anomalous Hall response resulting from the geometric Berry curvature dipole.Confgurations that are Z_(2)nontrivial can generate drastically different transverse currents orthogonal to the external electric feld,as both the direction and magnitude of the Berry curvature dipole at the Fermi level are highly sensitive to the sliding displacement.Our results suggest that bilayer bismuth,with its ability to generate multiple types of geometric currents,ofers a versatile platform for power-efcient“Berry slidetronics”for multistate memory applications integrating both band topology and ferroelectricity.展开更多
Neutron-induced gamma-ray imaging is a spectroscopic technique that uses characteristic gamma rays to infer the elemental distribution of an object.Currently,this technique requires the use of large facilities to supp...Neutron-induced gamma-ray imaging is a spectroscopic technique that uses characteristic gamma rays to infer the elemental distribution of an object.Currently,this technique requires the use of large facilities to supply a high neutron flux and a time-consuming detection procedure involving direct collimating measurements.In this study,a new method based on low neutron flux was proposed.A single-pixel gamma-ray detector combined with random pattern gamma-ray masks was used to measure the characteristic gamma rays emitted from the sample.Images of the elemental distribution in the sample,comprising 30×30 pixels,were reconstructed using the maximum-likelihood expectation-maximization algorithm.The results demonstrate that the elemental imaging of the sample can be accurately determined using this method.The proposed approach,which eliminates the need for high neutron flux and scanning measurements,can be used for in-field imaging applications.展开更多
X-ray microanalysis was used to study the elemental composition of the shell of the freshwater testate amoeba Difflugia tuberspinifera Hu et al.,1997 collected from Mulan Lake,Hubei province,China in July 2003.The res...X-ray microanalysis was used to study the elemental composition of the shell of the freshwater testate amoeba Difflugia tuberspinifera Hu et al.,1997 collected from Mulan Lake,Hubei province,China in July 2003.The results show that the shell is composed of ten elements:Si in greater quantity;then Ca and Al;and traces of K,Na,Cl,Fe,Mg,S and P.The analysis of results suggests that D.tuberspinifera in elemental composition appears to occupy a middle position between marine and soil testate amoebae.展开更多
The separation and enrichment of mercury and the recovery of elemental sulfur from flotation sulfur concentrate in zinc pressure leaching process were carried out by sodium sulfide leaching and carbon dioxide precipit...The separation and enrichment of mercury and the recovery of elemental sulfur from flotation sulfur concentrate in zinc pressure leaching process were carried out by sodium sulfide leaching and carbon dioxide precipitating. The results show that the leaching rate of elemental sulfur is more than 98%, and 98.13% of mercury is enriched in the residue, under the optimized conditions of sodium sulfide concentration 1.5 mol/L, liquid/solid ratio 6：1 and leaching time 30 min at room temperature. In addition, the content of mercury is enriched 5.23 times that in the leaching residue. The elemental sulfur is precipitated from leaching solution under conditions of carbon dioxide flow rate 200 mL/min and blowing time 150 min, while solution is stirred adequately. The recovery efficiency of elemental sulfur reaches 97.67%, and the purity of elemental sulfur is 99.75%, meeting the requirements of industrial first-rate product standard according to the national standard of GB/T 2449-2006 （PRC）.展开更多
Fine structure and elemental composition of envelopes of 10 taxa of Trachelomonas and Strombomonas from natural freshwater bodies in China were studied and phylogeny of both genera were discussed. The results indicate...Fine structure and elemental composition of envelopes of 10 taxa of Trachelomonas and Strombomonas from natural freshwater bodies in China were studied and phylogeny of both genera were discussed. The results indicate that iron (Fe) and silicon (Si) are the primary mineral elements of the envelopes. Composition of mineral elements was uncorrelated with envelope color, however, it was highly correlated with the microarchitecture of the envelopes. Content of Si was higher than that of Fe in all species of Strombomonas and some species of Trachelomonas with rough surface. In most species of Trachelomonas, especially those with dense and smoothy surface, content of Fe was higher than that of Si. Based on the above results, we propose to assign those species of Strombomonas into Trachelomonas and consider them as a group of the latter. These species were the most primitive among the group with envelopes in Euglenaceae.展开更多
To explore air contamination resulting from special biomass combustion and suspended dust in Lhasa,the present study focused on the size distribution and chemical characteristics of particulate matter(PM)emission resu...To explore air contamination resulting from special biomass combustion and suspended dust in Lhasa,the present study focused on the size distribution and chemical characteristics of particulate matter(PM)emission resulting from 7 types of non-fossil pollution sources.We investigated the concentration and size distribution of trace elements from 7 pollution sources collected in Lhasa.Combining Lhasa’s atmospheric particulate matter data,enrichment factors(EFs)have been calculated to examine the potential impact of those pollution sources on the atmosphere quality of Lhasa.The highest mass concentration of total elements of biomass combustion appeared at PM_(0.4),and the second highest concentration existed in the size fraction 0.4-1μm;the higher proportion(12%)of toxicmetals was produced by biomass combustion.The elemental composition of suspended dust and atmospheric particulate matter was close(except for As and Cd);the highest concentration of elements was all noted in PM_(2.5-10)(PM_(3-10)).Potassium was found to be one of the main biomass markers.The proportion of Cu in suspended dust is significantly lower than that of atmospheric particulate matter(0.53%and 3.75%),which indicates that there are other anthropogenic sources.The EFs analysis showed that the Cr,Cu,Zn,and Pb produced by biomass combustion were highly enriched(EFs>100)in all particle sizes.The EFs of most trace elements increased with decreasing particle size,indicating the greater influence of humanfactors on smaller particles.展开更多
The Shichuanhe River,a major tributary of the lower Weihe River,is situated in Xi’an,Shaanxi Province,China.It holds signifi cant information regarding the evolution of the Northern Weihe River,making its study cruci...The Shichuanhe River,a major tributary of the lower Weihe River,is situated in Xi’an,Shaanxi Province,China.It holds signifi cant information regarding the evolution of the Northern Weihe River,making its study crucial for understanding environmental changes in the region.Despite its importance,research on the Shichuanhe River basin has thus far been primarily focused on riverbank construction,with limited exploration of its sediment characteristics.Although river sediments hold potential for guiding agricultural practices in the area,comprehensive studies on their composition and provenance remain scarce.To address this gap,a systematic sediment sampling campaign was conducted in the lower reaches of the Shichuanhe River,and detailed mineralogical analyses were performed.The results show that the sediment is predominantly composed of detrital quartz and feldspar(albite and orthoclase),with heavy minerals constituting approximately 10%–12%of the total sediment volume.The analysis of the heavy mineral assemblage reveals an absence of signifi cant contributions from igneous rocks in the sedimentary profi le.Furthermore,the distribution patterns of major,trace,and rare-earth elements in the Shichuanhe River’s argillaceous sediments exhibit similarities to those found in the Weihe River’s sediments.Elemental fractionation patterns suggest that the Shichuanhe River sediments are primarily derived from Loess Plateau sediments,aligning with fi ndings from both the Weihe River and the middle reaches of the Yellow River.展开更多
The Guanfang large-scale W deposit is located in the W polymetallic ore concentration area of Bozhushan in southeastern Yunnan,China.Despite extensive research,the fluid evolution process of the deposit remains ambigu...The Guanfang large-scale W deposit is located in the W polymetallic ore concentration area of Bozhushan in southeastern Yunnan,China.Despite extensive research,the fluid evolution process of the deposit remains ambiguous,leading to controversy regarding its genesis.This study conducted a detailed field geological survey,with systematic sampling of the KT6 orebody,to delineate mineralization stages.Fine mineralogy work,including the use of CL images of scheelite,in-situ LA-ICP-MS trace elements,and Sr isotopes,was carried out on diff erent generations of scheelite formed in various stages.The findings identified the evolution of fluids in the mineralization process,shedding light on the genesis of the deposit.The study revealed four mineralization stages at the Guanfang W deposit:prograde skarn stage,retrograde skarn stage,quartz-sulfide stage,and carbonate-fluorite stage.Diff erent generations of scheelite(Sch I,Sch II,Sch III)were observed in the first three stages,displaying distinct chondrite-normalized REE patterns.The REE of Sch I mainly substituted into the Ca site by REE^(3+)+□_(Ca),and there may be a similar substitution of Nb for REE,whereas it is not the main substitution method.The REE of Sch II mainly enter the scheelite lattice in the form of REE 3++Na+,and there may be a substitution of Nb for REE isomorphism.In the early stage,The REE of Sch III was mainly replaced by Nb for REE isomorphism,while in the later stage,the replacement mode of REE^(3+)+□_(Ca)coexisted with it.The Mo content in scheelite,along with the corresponding Eu anomalies in both scheelite and garnet,collectively imply that the ore-forming fluids during various mineralization stages were predominantly oxidizing,with only slight reducibility observed in Sch II.The in-situ Sr isotope ratios of scheelite concentrates ranged from 0.7093 to 0.7153,resembling those of the Bozhushan granite,indicating a relationship between W mineralization and granite.In addition,the Y/Ho ratios of scheelite from various mineralization stages exhibit a narrow range(19-31),with a pronounced correlation between the contents of Y and Ho and a similar trend in their variation.This consistency suggests that the Guanfang deposit has undergone a uniform or comparable evolutionary process,implying a stable ore-forming fluid across diff erent mineralization stages.展开更多
Xiamen, located on the southeastern coastal line of China, is undergoing rapid urbanization and industrialization, so its air quality has a trend of degradation. However, studies on level, temporal and spatial changes...Xiamen, located on the southeastern coastal line of China, is undergoing rapid urbanization and industrialization, so its air quality has a trend of degradation. However, studies on level, temporal and spatial changes of fine particles （PM2.5） and their carbonaceous fractions are scarce. In this article, abundance, sources, seasonal and spatial variations, distribution of organic carbon （OC） and elemental carbon （EC） in PM2.5, were studied at suburban, urban and industrial sites in Xiamen during four season-representative months in 2009-2010. PM2.5 samples were collected with middle volume sampler and were analyzed for OC and EC with thermal optical transmittance （TOT） method. Results showed that the annual average PM2.5 concentrations were 63.88-74.80 Ixg/m3 at three sites. While OC and EC concentrations were in the range of 15.81-19.73 [xg/m3 and 2.74-3.49 ~tg/m3, respectively, and clearly presented the summer minima and winter maxima in this study. The carbonaceous aerosol accounted for 42.8%-47.3% of the mass of PMzs. The annual average of secondary organic carbon （SOC） concentrations in Xiamen were 9.23-11.36 ~g/m3, accounting for approximately 56% of OC. Strong correlations between OC and EC was found in spring （R2 = 0.50） and autumn （R2 = 0.73）, suggesting that there were similar emission and transport processes for carbonaceous aerosols in these two seasons, while weak correlations were found in summer （R2 = 0.33） and winter （R2 = 0.41）. The OCI＇EC ratios in PM2.5 varied from 2.1 to 8.7 with an annual average of 5.7, indicating that vehicle exhaust, coal smoke and biomass burning were main source apportionments of carbonaceous fractions in Xiamen.展开更多
An investigation of gaseous elemental mercury concentration in atmosphere was conducted at Beijing and Guangzhou urban, Yangtze Delta regional sites and China Global Atmosphere Watch Baseline Observatory （CGAWBO） in...An investigation of gaseous elemental mercury concentration in atmosphere was conducted at Beijing and Guangzhou urban, Yangtze Delta regional sites and China Global Atmosphere Watch Baseline Observatory （CGAWBO） in Mt. Waliguan of remote continental area of China. High temporal resolved data were obtained using automated mercury analyzer RA-915^＋. Results showed that the overall hourly mean Hg^0 concentrations in Mt. Waliguan were 1.7±1.1 ng/m3 in summer and 0.6±0.08 ng/m^3 in winter. The concentration in Yangtze Delta regional site was 5.4±4.1 ng/m^3, which was much higher than those in Waliguan continental background area and also higher than that found in North America and Europe rural areas. In Beijing urban area the overall hourly mean Hg^0 concentrations were 8.3±3.6 ng/m^3 in winter, 6.5±5.2 ng/m^3 in spring, 4.9±3.3 ng/m^3 in summer, and 6.7±3.5 ng/m^3 in autumn, respectively, and the concentration was 13.5±7.1 ng/m^3 in Guangzhou site. The mean concentration reached the lowest value at 14：00 and the highest at 02：00 or 20：00 in all monitoring campaigns in Beijing and Guangzhou urban areas, which contrasted with the results measured in Yangtze Delta regional site and Mr. Waliguan. The features of concentration and diurnal variation of Hg^0 in Beijing and Guangzhou implied the importance of local anthropogenic sources in contributing to the high Hg^0 concentration in urban areas of China. Contrary seasonal variation patterns of Hg^0 concentration were found between urban and remote sites. In Beijing the highest Hg^0 concentration was in winter and the lowest in summer, while in Mt. Waliguan the Hg^0 concentration in summer was higher than that in winter. These indicated that different processes and factors controlled Hg^0 concentration in urban, regional and remote areas.展开更多
Heterogeneous oxidation of gas-phase Hg 0 by nano-Fe 2 O 3 was investigated on a fixed bed reactor, and the effects of oxygen concentration, bed temperature, water vapour concentration and particle size have been disc...Heterogeneous oxidation of gas-phase Hg 0 by nano-Fe 2 O 3 was investigated on a fixed bed reactor, and the effects of oxygen concentration, bed temperature, water vapour concentration and particle size have been discussed. The results showed that Hg 0 could be oxidized by active oxygen atom on the surface of nano-Fe 2 O 3 as well as lattice oxygen in nano-Fe 2 O 3 . Among the factors that affect Hg 0 oxidation by nano-Fe 2 O 3 , bed temperature plays an important role. More than 40% of total mercury was oxidized at 300°C, however, the test temperature at 400°C could cause sintering of nano-catalyst, which led to a lower efficiency of Hg 0 oxidation. The increase of oxygen concentration could promote mercury oxidation and led to higher Hg 0 oxidation efficiency. No obvious mercury oxidation was detected in the pure N 2 atmosphere, which indicates that oxygen is required in the gas stream for mercury oxidation. The presence of water vapour showed different effects on mercury oxidation depending on its concentration. The lower content of water vapour could promote mercury oxidation, while the higher content of water vapour inhibits mercury oxidation.展开更多
Hierarchical Ag-SiO_2@Fe_3O_4 magnetic composites were selected for elemental mercury(Hg^0) removal from non-ferrous metal smelting flue gas in this study. Results showed that the hierarchical Ag-SiO_2@Fe_3O_4 magneti...Hierarchical Ag-SiO_2@Fe_3O_4 magnetic composites were selected for elemental mercury(Hg^0) removal from non-ferrous metal smelting flue gas in this study. Results showed that the hierarchical Ag-SiO_2@Fe_3O_4 magnetic composites had favorable Hg^0 removal ability at low temperature. Moreover, the adsorption capacity of hierarchical magnetic composite is much larger than that of pure Fe_3O_4 and SiO_2@Fe_3O_4. The Hg^0 removal efficiency reached the highest value as approximately 92% under the reaction temperature of 150°C, while the removal efficiency sharply reduced in the absence of O_2. The characterization results indicated that Ag nanoparticles grew on the surface of SiO_2@Fe_3O_4 support. The large surface area of SiO_2 supplied efficient reaction room for Hg and Ag atoms. Ag–Hg amalgam is generated on the surface of the composites. In addition, this magnetic material could be easily separated from fly ashes when adopted for treating real flue gas, and the spent materials could be regenerated using a simple thermal-desorption method.展开更多
A continuous measurement of number size distributions and chemical composition of aerosol particles was conducted in Beijing in a dust storm event during 21-26 March 2001. The number concentration of coarse particles ...A continuous measurement of number size distributions and chemical composition of aerosol particles was conducted in Beijing in a dust storm event during 21-26 March 2001. The number concentration of coarse particles （ 〉2μm） increased more significantly than fine particles （ 〈2μm） during the dust storm due to dust weather, while the anthropogenic aerosols collected during the non-dust-storm period tended to be associated with fine particles. Elemental compositions were analyzed by using proton-induced X-ray emission （PIXE）. The results show that 20 elements in the dust storm were much higher than in the non-dust-storm period. The calculated soil dust concentration during the dust storm was, on average, 251.8μg m^-3, while it was only 52.1μg m^-3 on non-dust-storm days. The enrichment factors for Mg, A1, P, K, Ca, Ti, Mn, Fe, C1, Cu, Pb, and Zn show small variations between the dust storm and the non-dust-storm period, while those for Ca, Ni and Cr in the dust storm were much lower than those in the non-dust-storm period due to significant local emission sources. A high concentration and enrichment factor for S were observed during the dust storm, which implies that the dust particles were contaminated by aerosol particles from anthropogenic emissions during the long-range transport. A statistical analysis shows that the elemental composition of particles collected during the dust storm in Beijing were better correlated with those of desert soil colleted from desert regions in Inner Mongolia. Air mass back-trajectory analysis further confirmed that this dust storm event could be identified as streaks of dust plumes originating from Inner Mongolia.展开更多
Bamboo was carbonized at different temperatures ranging from 200℃to 600℃.The dependence of the change of hemicellulose,cellulose,and lignin on the temperature was investigated by means of elemental analysis and Four...Bamboo was carbonized at different temperatures ranging from 200℃to 600℃.The dependence of the change of hemicellulose,cellulose,and lignin on the temperature was investigated by means of elemental analysis and Fourier Transform Infrared(FTIR)spectra of the residual solid products.The results showed:(1)Below 200℃,hemicellulose in bamboo was de-composed and a large amount of hydroxyl groups are dislocated from hemicellulose and cellulose,accompanied by the evolu-tion of water to escape.(2)200℃-250℃,cellulose in bamboo was drastically decomposed whereas the net structure of lignin keep stable,with the except of the dislocation of methoxyl groups from lignin.(3)250℃~400℃,the net structure of lignin col-lapse,up to 400’℃,followed by that the more position in aryl groups are substituted.(4)For bamboo carbonization,the aroma-tization of residual carbon has approximately completed at the temperature as high as 600℃.But the fusion of aromatic rings possibly does not occur.展开更多
Elemental composition and geochemical characteristics of iron-manganese nodules from nine main soils in China were studied by chemical and multivariate statistical analyses to better understand the reactions and funct...Elemental composition and geochemical characteristics of iron-manganese nodules from nine main soils in China were studied by chemical and multivariate statistical analyses to better understand the reactions and functions of iron-manganese nodules in soils and sediment. Compared to the corresponding soils, Mn, Ba, Cd, Co and Pb had strong accumulation, Ni had moderate accumulation, while Ca, Cu, Fe, Na, P, Sr and Zn accumulated to a minor degree in the iron-manganese nodules. In contrast, Si, Al, K, Mg and Ti were reduced in the iron-manganese nodules. The contents of Ba, Cd, Co, Cu, Ni, Pb and Zn were positively and significantly correlated with that of MnO2 in the iron-manganese nodules, while the contents of Cr, Cu, Ni, Pb and Zn were positively and significantly correlated with that of Fe2O3 in soils. Based on a principle component analysis, the elements of iron-manganese nodules were divided into four groups: 1) Mn, Ba, Cd, Co, Cu, Li, Ni, Pb and Zn that were associated with Mn oxides, 2) Fe, Cr and P that were associated with Fe oxides, 3) Si, K, and Mg that were included in the elemental composition of phyllosilicate, and 4) Ca, Na, Al and Ti that existed in todorokite, birnessite, lithiophorite and phyllosilicate. It was suggested that accumulation, mineralization and specific adsorption were involved in the formation processes of soil iron-manganese nodules.展开更多
Elemental mercury（Hg^0）re-emissions from slurries and solutions were evaluated in a lab-scale simulated scrubber.Oxidized mercury（Hg^2 ＋）standard solution was injected into the simulated scrubber at a desired rat...Elemental mercury（Hg^0）re-emissions from slurries and solutions were evaluated in a lab-scale simulated scrubber.Oxidized mercury（Hg^2 ＋）standard solution was injected into the simulated scrubber at a desired rate to simulate absorbing and dissolving of Hg^2 ＋in the flue gas across wet flue gas desulfurization（WFGD）systems. PS analytical mercury analyzer was used to continuously determine Hg0re-emission concentrations in the carrier gas from the scrubber.Sulfite ion in the slurry of CaSO3 was validated to reduce Hg ^2＋to Hg^ 0,while no Hg ^0 re-emission occurred from slurries of CaSO4 and CaO.Transitional metal ions with low chemical valence such as Fe^2 ＋,Pb ^2＋,Ni ^2＋, AsO2^-and Cu ^＋were used to prepare solutions with concentration levels of mmol·L^-1.Reduction reaction of Hg^2 ＋to Hg 0was observed from these solutions.Reduction capabilities for the different transitional metal ions in the solutions were：Pb^2 ＋〉Cu ^＋〉Fe^ 2＋〉 AsO2^-〉Ni ^2＋.展开更多
Quantitative information on mass concentrations and other characteristics, such as spatial distribution, seasonal variation, indoor/outdoor （I/O） ratio, correlations and sources, of indoor and outdoor PM2.5 and elem...Quantitative information on mass concentrations and other characteristics, such as spatial distribution, seasonal variation, indoor/outdoor （I/O） ratio, correlations and sources, of indoor and outdoor PM2.5 and elemental components in Guangzhou City were provided. Mass concentration of PM2.5 and elemental components were determined by standard weight method and proton-induced X-ray emission （PIXE） method. 18 elements were detected, the results showed positive results. Average indoor and outdoor PM2.5 concentrations in nine sites were in the range of 67.7-74.5μg/m^3 for summer period, and 109.9-123.7 μg/m^3 for winter period, respectively. The sum of 18 elements average concentrations were 5362.6-5533.4 ng/m^3 for summer period, and 8416.8-8900.6 ng/m^3 for winter period, respectively. Average concentrations of PM2.5 and element components showed obvious spatial characteristic, that the concentrations in roadside area and in industrial plant area were higher than those in generic urban area. An obvious seasonal variation characteristic was found for PM2.5 and elemental components, that the concentrations in winter were higher than that in summer. The I/O ratio of PM2.5 and some elemental components presented larger than 1 sometimes. According to indoor/outdoor correlation of PM2.5 and element concentrations, it was found that there were often good relationships between indoor and outdoor concentrations. Enrichment factors were calculated to evaluate anthropogenic versus natural elements sources.展开更多
Continuous observations of mass concentration and elemental composition of aerosol particles （PM2.5） were conducted at Tongyu, a semi-arid site in Northeast China in the spring of 2006. The average mass concentratio...Continuous observations of mass concentration and elemental composition of aerosol particles （PM2.5） were conducted at Tongyu, a semi-arid site in Northeast China in the spring of 2006. The average mass concentration of PM2.5 at Tongyu station was 260.9±274.4 μg m^-3 during the observation period. Nine dust events were monitored with a mean concentration of 528.0±302.7 μgm^-3. The PM2.5 level during non- dust storm （NDS） period was 111.65±63.37 μg m^-3. High mass concentration shows that fine-size particles pollution was very serious in the semi-arid area in Northeast China. The enrichment factor values for crust elements during the dust storm （DS） period are close to those in the NDS period, while the enrichment factor values for pollution elements during the NDS period are much higher than those in the DS period, showing these elements were from anthropogenic sources. The ratios of dust elements to Fe were relative constant during the DS period. The Ca/Fe ratio in dust aerosols at Tongyu is remarkably different from that observed in other source regions and downwind regions. Meteorological analysis shows that dust events at Tongyu are usually associated with dry, low pressure and high wind speed weather conditions. Air mass back-trajectory analysis identified three kinds of general pathways were associated with the aerosol particle transport to Tongyu, and the northwest direction pathway was the main transport route.展开更多
基金supported by a fellowship award from the Research Grants Council of the Hong Kong Special Administrative Region,China(CityU RFS2021−1S04)the Innovation and Technology Fund(MHP/044/23)from the Innovation and Technology Commission of the Hong Kong Government Special Administrative Region,China.
文摘The rapid advancement of information technology has heightened interest in complementary devices and circuits.Conventional p-type semiconductors often lack sufficient electrical performance,thus prompting the search for new materials with high hole mobility and long-term stability.Elemental tellurium(Te),featuring a one-dimensional chiral atomic structure,has emerged as a promising candidate due to its narrow bandgap,high hole mobility,and versatility in industrial applications,particularly in electronics and renewable energy.This review highlights recent progress in Te nanostructures and related devices,focusing on synthesis methods,including vapor deposition and hydrothermal synthesis,which produce Te nanowires,nanorods,and other nanostructures.Critical applications in photodetectors,gas sensors,and energy harvesting devices are discussed,with a special emphasis on their role within the internet of things(IoT)framework,a rapidly growing field that is reshaping our technological landscape.The prospects and potential applications of Te-based technologies are also highlighted.
基金supported by the National Natural Science Foundation of China(52106284,52422609)the Natural Science Foundation of Hebei Province(B2021507001)Key Research Special Project of CPPU(ZDZX202501)。
文摘As lithium-ion batteries(LIBs)continue to evolve toward lower costs and higher energy densities,their potential safety risks have become increasingly apparent.Incidents such as explosions at energy storage facilities,fires in electric vehicles,and building fires ignited by charging two-wheeled vehicles have been occurring with alarming frequency,often resulting in significant casualties and injuries.Conducting indepth investigations into thermal runaway(TR)incidents in LIBs can significantly reduce the risk of future occurrences.However,current investigations into LIB fire and explosion incidents face challenges due to the difficulty of conducting in-depth analyses and the lack of a robust theoretical framework to guide these investigations.To enhance the effectiveness of in-depth investigations into battery fire and explosion incidents and to address the lack of theoretical guidance,this paper is the first to systematically examine the conservation and flow patterns of elements during the TR process of LIBs.The analysis reveals that during TR,the gas products generated include approximately 1.5 g of H_(2),23.6 g of CO,88.4 g of CO_(2),8.9 g of C_(2)H_(4),7.3 g of CH_(4),3.7 g of C_(2)H_(6),and 82 g of electrolyte vapor.After TR,the solid compounds formed consist of approximately 2.5 g of LiF,29–92.2 g of elemental Ni/Co/Mn,11.4 g of Li_(2)CO_(3),200.6 g of graphite,1.4 g of NiO,29.6 g of MnO,30.1 g of CoO,67 g of elemental Cu,0.03 g of LiNiO_(2),and 4.3 g of LiAlO_(2).Importantly,the energy released from reactions forming solid compounds during TR surpasses that from gas-forming reactions.This investigation represents the first application of Hess’s law to verify the conservation of elements during the TR process of lithium-ion batteries.The proposed methodology is also applicable to other types of energy storage batteries,effectively advancing techniques for comprehensively investigating lithium battery fire and explosion incidents.
基金the supports from Westlake Education Foundationthe support provided by the National Natural Science Foundation of China(Grant No.12304049)。
文摘We demonstrate that the sliding motion between two layers of the newly discovered ferroelectric and topologically trivial bismuth(Bi)monolayer[Nature 61767(2023)]can induce a sequence of topological phase transitions,alternating between Z_(2)trivial and nontrivial states.The lateral shift,while preserving spatial symmetry,can switch the quantum spin Hall state on and of.The sliding-induced changes in out-of-plane atomic buckling,which are directly coupled to in-plane ferroelectricity,are shown to signifcantly modulate the band gap and drive the topological phase transitions.We map out the topological phase diagram and in-plane ferroelectricity with respect to sliding displacements.With appropriate sliding,the bismuth bilayer can transition into a nontrivial polar metal,exhibiting a pronounced shift current response arising from interband geometric quantities of electronic bands.Moreover,bilayer Bi supports a sliding-tunable nonlinear anomalous Hall response resulting from the geometric Berry curvature dipole.Confgurations that are Z_(2)nontrivial can generate drastically different transverse currents orthogonal to the external electric feld,as both the direction and magnitude of the Berry curvature dipole at the Fermi level are highly sensitive to the sliding displacement.Our results suggest that bilayer bismuth,with its ability to generate multiple types of geometric currents,ofers a versatile platform for power-efcient“Berry slidetronics”for multistate memory applications integrating both band topology and ferroelectricity.
基金supported by the National Natural Science Foundation of China(Nos.12105143 and 11975121)the China Postdoctoral Science Foundation(No.2023M741453)+1 种基金the Engineering Research Center of Nuclear Technology Application(No.HJSJYB2020-1)the Key Laboratory of Ionizing Radiation Metering and Safety Evaluation for Jiangsu Province Market Regulation,and the Jiangsu Province Excellent Postdoctoral Program(No.JB23057).
文摘Neutron-induced gamma-ray imaging is a spectroscopic technique that uses characteristic gamma rays to infer the elemental distribution of an object.Currently,this technique requires the use of large facilities to supply a high neutron flux and a time-consuming detection procedure involving direct collimating measurements.In this study,a new method based on low neutron flux was proposed.A single-pixel gamma-ray detector combined with random pattern gamma-ray masks was used to measure the characteristic gamma rays emitted from the sample.Images of the elemental distribution in the sample,comprising 30×30 pixels,were reconstructed using the maximum-likelihood expectation-maximization algorithm.The results demonstrate that the elemental imaging of the sample can be accurately determined using this method.The proposed approach,which eliminates the need for high neutron flux and scanning measurements,can be used for in-field imaging applications.
文摘X-ray microanalysis was used to study the elemental composition of the shell of the freshwater testate amoeba Difflugia tuberspinifera Hu et al.,1997 collected from Mulan Lake,Hubei province,China in July 2003.The results show that the shell is composed of ten elements:Si in greater quantity;then Ca and Al;and traces of K,Na,Cl,Fe,Mg,S and P.The analysis of results suggests that D.tuberspinifera in elemental composition appears to occupy a middle position between marine and soil testate amoebae.
文摘The separation and enrichment of mercury and the recovery of elemental sulfur from flotation sulfur concentrate in zinc pressure leaching process were carried out by sodium sulfide leaching and carbon dioxide precipitating. The results show that the leaching rate of elemental sulfur is more than 98%, and 98.13% of mercury is enriched in the residue, under the optimized conditions of sodium sulfide concentration 1.5 mol/L, liquid/solid ratio 6：1 and leaching time 30 min at room temperature. In addition, the content of mercury is enriched 5.23 times that in the leaching residue. The elemental sulfur is precipitated from leaching solution under conditions of carbon dioxide flow rate 200 mL/min and blowing time 150 min, while solution is stirred adequately. The recovery efficiency of elemental sulfur reaches 97.67%, and the purity of elemental sulfur is 99.75%, meeting the requirements of industrial first-rate product standard according to the national standard of GB/T 2449-2006 （PRC）.
文摘Fine structure and elemental composition of envelopes of 10 taxa of Trachelomonas and Strombomonas from natural freshwater bodies in China were studied and phylogeny of both genera were discussed. The results indicate that iron (Fe) and silicon (Si) are the primary mineral elements of the envelopes. Composition of mineral elements was uncorrelated with envelope color, however, it was highly correlated with the microarchitecture of the envelopes. Content of Si was higher than that of Fe in all species of Strombomonas and some species of Trachelomonas with rough surface. In most species of Trachelomonas, especially those with dense and smoothy surface, content of Fe was higher than that of Si. Based on the above results, we propose to assign those species of Strombomonas into Trachelomonas and consider them as a group of the latter. These species were the most primitive among the group with envelopes in Euglenaceae.
基金supported by the Natural Science Foundation of China (No.11775180).
文摘To explore air contamination resulting from special biomass combustion and suspended dust in Lhasa,the present study focused on the size distribution and chemical characteristics of particulate matter(PM)emission resulting from 7 types of non-fossil pollution sources.We investigated the concentration and size distribution of trace elements from 7 pollution sources collected in Lhasa.Combining Lhasa’s atmospheric particulate matter data,enrichment factors(EFs)have been calculated to examine the potential impact of those pollution sources on the atmosphere quality of Lhasa.The highest mass concentration of total elements of biomass combustion appeared at PM_(0.4),and the second highest concentration existed in the size fraction 0.4-1μm;the higher proportion(12%)of toxicmetals was produced by biomass combustion.The elemental composition of suspended dust and atmospheric particulate matter was close(except for As and Cd);the highest concentration of elements was all noted in PM_(2.5-10)(PM_(3-10)).Potassium was found to be one of the main biomass markers.The proportion of Cu in suspended dust is significantly lower than that of atmospheric particulate matter(0.53%and 3.75%),which indicates that there are other anthropogenic sources.The EFs analysis showed that the Cr,Cu,Zn,and Pb produced by biomass combustion were highly enriched(EFs>100)in all particle sizes.The EFs of most trace elements increased with decreasing particle size,indicating the greater influence of humanfactors on smaller particles.
基金supported by the Key Project of Natural Science Basic Research Program of Shaanxi Province(2023-JC-ZD-16).
文摘The Shichuanhe River,a major tributary of the lower Weihe River,is situated in Xi’an,Shaanxi Province,China.It holds signifi cant information regarding the evolution of the Northern Weihe River,making its study crucial for understanding environmental changes in the region.Despite its importance,research on the Shichuanhe River basin has thus far been primarily focused on riverbank construction,with limited exploration of its sediment characteristics.Although river sediments hold potential for guiding agricultural practices in the area,comprehensive studies on their composition and provenance remain scarce.To address this gap,a systematic sediment sampling campaign was conducted in the lower reaches of the Shichuanhe River,and detailed mineralogical analyses were performed.The results show that the sediment is predominantly composed of detrital quartz and feldspar(albite and orthoclase),with heavy minerals constituting approximately 10%–12%of the total sediment volume.The analysis of the heavy mineral assemblage reveals an absence of signifi cant contributions from igneous rocks in the sedimentary profi le.Furthermore,the distribution patterns of major,trace,and rare-earth elements in the Shichuanhe River’s argillaceous sediments exhibit similarities to those found in the Weihe River’s sediments.Elemental fractionation patterns suggest that the Shichuanhe River sediments are primarily derived from Loess Plateau sediments,aligning with fi ndings from both the Weihe River and the middle reaches of the Yellow River.
基金suppor ted by Yunnan Major Scientific and Technological Projects(Grant No.202202AG050006)the Personnel Training Project of Kunming University of Science and Technology(Grant No.KKZ3202221022)。
文摘The Guanfang large-scale W deposit is located in the W polymetallic ore concentration area of Bozhushan in southeastern Yunnan,China.Despite extensive research,the fluid evolution process of the deposit remains ambiguous,leading to controversy regarding its genesis.This study conducted a detailed field geological survey,with systematic sampling of the KT6 orebody,to delineate mineralization stages.Fine mineralogy work,including the use of CL images of scheelite,in-situ LA-ICP-MS trace elements,and Sr isotopes,was carried out on diff erent generations of scheelite formed in various stages.The findings identified the evolution of fluids in the mineralization process,shedding light on the genesis of the deposit.The study revealed four mineralization stages at the Guanfang W deposit:prograde skarn stage,retrograde skarn stage,quartz-sulfide stage,and carbonate-fluorite stage.Diff erent generations of scheelite(Sch I,Sch II,Sch III)were observed in the first three stages,displaying distinct chondrite-normalized REE patterns.The REE of Sch I mainly substituted into the Ca site by REE^(3+)+□_(Ca),and there may be a similar substitution of Nb for REE,whereas it is not the main substitution method.The REE of Sch II mainly enter the scheelite lattice in the form of REE 3++Na+,and there may be a substitution of Nb for REE isomorphism.In the early stage,The REE of Sch III was mainly replaced by Nb for REE isomorphism,while in the later stage,the replacement mode of REE^(3+)+□_(Ca)coexisted with it.The Mo content in scheelite,along with the corresponding Eu anomalies in both scheelite and garnet,collectively imply that the ore-forming fluids during various mineralization stages were predominantly oxidizing,with only slight reducibility observed in Sch II.The in-situ Sr isotope ratios of scheelite concentrates ranged from 0.7093 to 0.7153,resembling those of the Bozhushan granite,indicating a relationship between W mineralization and granite.In addition,the Y/Ho ratios of scheelite from various mineralization stages exhibit a narrow range(19-31),with a pronounced correlation between the contents of Y and Ho and a similar trend in their variation.This consistency suggests that the Guanfang deposit has undergone a uniform or comparable evolutionary process,implying a stable ore-forming fluid across diff erent mineralization stages.
基金supported by the Knowledge Innovation Program of the Chinese Academy of Sciences (No. KZCX2-YW-453,KZCX2-YW-JS404,KZCX2-EW-408)the Commonweal Program of Environment Protection Department of China (No. 201009004)the Program of Bureau of Science and Technology,Xiamen (No. 3502Z20081117,350205Z20095001)
文摘Xiamen, located on the southeastern coastal line of China, is undergoing rapid urbanization and industrialization, so its air quality has a trend of degradation. However, studies on level, temporal and spatial changes of fine particles （PM2.5） and their carbonaceous fractions are scarce. In this article, abundance, sources, seasonal and spatial variations, distribution of organic carbon （OC） and elemental carbon （EC） in PM2.5, were studied at suburban, urban and industrial sites in Xiamen during four season-representative months in 2009-2010. PM2.5 samples were collected with middle volume sampler and were analyzed for OC and EC with thermal optical transmittance （TOT） method. Results showed that the annual average PM2.5 concentrations were 63.88-74.80 Ixg/m3 at three sites. While OC and EC concentrations were in the range of 15.81-19.73 [xg/m3 and 2.74-3.49 ~tg/m3, respectively, and clearly presented the summer minima and winter maxima in this study. The carbonaceous aerosol accounted for 42.8%-47.3% of the mass of PMzs. The annual average of secondary organic carbon （SOC） concentrations in Xiamen were 9.23-11.36 ~g/m3, accounting for approximately 56% of OC. Strong correlations between OC and EC was found in spring （R2 = 0.50） and autumn （R2 = 0.73）, suggesting that there were similar emission and transport processes for carbonaceous aerosols in these two seasons, while weak correlations were found in summer （R2 = 0.33） and winter （R2 = 0.41）. The OCI＇EC ratios in PM2.5 varied from 2.1 to 8.7 with an annual average of 5.7, indicating that vehicle exhaust, coal smoke and biomass burning were main source apportionments of carbonaceous fractions in Xiamen.
基金Project supported by the National Basic Research Program (973) of China (No. 2003CB415003)the Pilot Project of Knowledge Innovation Program of the Chinese Academy of Sciences (No. KZCX3-SW-443)the National Natural Science Foundation of China (No. 40473055).
文摘An investigation of gaseous elemental mercury concentration in atmosphere was conducted at Beijing and Guangzhou urban, Yangtze Delta regional sites and China Global Atmosphere Watch Baseline Observatory （CGAWBO） in Mt. Waliguan of remote continental area of China. High temporal resolved data were obtained using automated mercury analyzer RA-915^＋. Results showed that the overall hourly mean Hg^0 concentrations in Mt. Waliguan were 1.7±1.1 ng/m3 in summer and 0.6±0.08 ng/m^3 in winter. The concentration in Yangtze Delta regional site was 5.4±4.1 ng/m^3, which was much higher than those in Waliguan continental background area and also higher than that found in North America and Europe rural areas. In Beijing urban area the overall hourly mean Hg^0 concentrations were 8.3±3.6 ng/m^3 in winter, 6.5±5.2 ng/m^3 in spring, 4.9±3.3 ng/m^3 in summer, and 6.7±3.5 ng/m^3 in autumn, respectively, and the concentration was 13.5±7.1 ng/m^3 in Guangzhou site. The mean concentration reached the lowest value at 14：00 and the highest at 02：00 or 20：00 in all monitoring campaigns in Beijing and Guangzhou urban areas, which contrasted with the results measured in Yangtze Delta regional site and Mr. Waliguan. The features of concentration and diurnal variation of Hg^0 in Beijing and Guangzhou implied the importance of local anthropogenic sources in contributing to the high Hg^0 concentration in urban areas of China. Contrary seasonal variation patterns of Hg^0 concentration were found between urban and remote sites. In Beijing the highest Hg^0 concentration was in winter and the lowest in summer, while in Mt. Waliguan the Hg^0 concentration in summer was higher than that in winter. These indicated that different processes and factors controlled Hg^0 concentration in urban, regional and remote areas.
基金supported by the Scientific Funds for Outstanding Young Scientists of China(No.50525619)the National Natural Science Foundation of China(No.51078163,50706014)the National High Technology Research and Development Program(863)of China(No.2006AA05Z304)
文摘Heterogeneous oxidation of gas-phase Hg 0 by nano-Fe 2 O 3 was investigated on a fixed bed reactor, and the effects of oxygen concentration, bed temperature, water vapour concentration and particle size have been discussed. The results showed that Hg 0 could be oxidized by active oxygen atom on the surface of nano-Fe 2 O 3 as well as lattice oxygen in nano-Fe 2 O 3 . Among the factors that affect Hg 0 oxidation by nano-Fe 2 O 3 , bed temperature plays an important role. More than 40% of total mercury was oxidized at 300°C, however, the test temperature at 400°C could cause sintering of nano-catalyst, which led to a lower efficiency of Hg 0 oxidation. The increase of oxygen concentration could promote mercury oxidation and led to higher Hg 0 oxidation efficiency. No obvious mercury oxidation was detected in the pure N 2 atmosphere, which indicates that oxygen is required in the gas stream for mercury oxidation. The presence of water vapour showed different effects on mercury oxidation depending on its concentration. The lower content of water vapour could promote mercury oxidation, while the higher content of water vapour inhibits mercury oxidation.
基金supported by the National Key R&D Program of China (No. 2017YFC0210500)the National Natural Science Foundation of China (No. 51508525)the Key Research and Development Program of Ningxia Hui Autonomous Region (No. 2016KJHM31)
文摘Hierarchical Ag-SiO_2@Fe_3O_4 magnetic composites were selected for elemental mercury(Hg^0) removal from non-ferrous metal smelting flue gas in this study. Results showed that the hierarchical Ag-SiO_2@Fe_3O_4 magnetic composites had favorable Hg^0 removal ability at low temperature. Moreover, the adsorption capacity of hierarchical magnetic composite is much larger than that of pure Fe_3O_4 and SiO_2@Fe_3O_4. The Hg^0 removal efficiency reached the highest value as approximately 92% under the reaction temperature of 150°C, while the removal efficiency sharply reduced in the absence of O_2. The characterization results indicated that Ag nanoparticles grew on the surface of SiO_2@Fe_3O_4 support. The large surface area of SiO_2 supplied efficient reaction room for Hg and Ag atoms. Ag–Hg amalgam is generated on the surface of the composites. In addition, this magnetic material could be easily separated from fly ashes when adopted for treating real flue gas, and the spent materials could be regenerated using a simple thermal-desorption method.
文摘A continuous measurement of number size distributions and chemical composition of aerosol particles was conducted in Beijing in a dust storm event during 21-26 March 2001. The number concentration of coarse particles （ 〉2μm） increased more significantly than fine particles （ 〈2μm） during the dust storm due to dust weather, while the anthropogenic aerosols collected during the non-dust-storm period tended to be associated with fine particles. Elemental compositions were analyzed by using proton-induced X-ray emission （PIXE）. The results show that 20 elements in the dust storm were much higher than in the non-dust-storm period. The calculated soil dust concentration during the dust storm was, on average, 251.8μg m^-3, while it was only 52.1μg m^-3 on non-dust-storm days. The enrichment factors for Mg, A1, P, K, Ca, Ti, Mn, Fe, C1, Cu, Pb, and Zn show small variations between the dust storm and the non-dust-storm period, while those for Ca, Ni and Cr in the dust storm were much lower than those in the non-dust-storm period due to significant local emission sources. A high concentration and enrichment factor for S were observed during the dust storm, which implies that the dust particles were contaminated by aerosol particles from anthropogenic emissions during the long-range transport. A statistical analysis shows that the elemental composition of particles collected during the dust storm in Beijing were better correlated with those of desert soil colleted from desert regions in Inner Mongolia. Air mass back-trajectory analysis further confirmed that this dust storm event could be identified as streaks of dust plumes originating from Inner Mongolia.
基金This paper was supported by the Innovation Project of Nanjing Forestry University.
文摘Bamboo was carbonized at different temperatures ranging from 200℃to 600℃.The dependence of the change of hemicellulose,cellulose,and lignin on the temperature was investigated by means of elemental analysis and Fourier Transform Infrared(FTIR)spectra of the residual solid products.The results showed:(1)Below 200℃,hemicellulose in bamboo was de-composed and a large amount of hydroxyl groups are dislocated from hemicellulose and cellulose,accompanied by the evolu-tion of water to escape.(2)200℃-250℃,cellulose in bamboo was drastically decomposed whereas the net structure of lignin keep stable,with the except of the dislocation of methoxyl groups from lignin.(3)250℃~400℃,the net structure of lignin col-lapse,up to 400’℃,followed by that the more position in aryl groups are substituted.(4)For bamboo carbonization,the aroma-tization of residual carbon has approximately completed at the temperature as high as 600℃.But the fusion of aromatic rings possibly does not occur.
基金Project supported by the National Natural Science Foundation of China (No. 40101017)the Doctor Foundation of the Ministry of Education of China (No. 2002050411).
文摘Elemental composition and geochemical characteristics of iron-manganese nodules from nine main soils in China were studied by chemical and multivariate statistical analyses to better understand the reactions and functions of iron-manganese nodules in soils and sediment. Compared to the corresponding soils, Mn, Ba, Cd, Co and Pb had strong accumulation, Ni had moderate accumulation, while Ca, Cu, Fe, Na, P, Sr and Zn accumulated to a minor degree in the iron-manganese nodules. In contrast, Si, Al, K, Mg and Ti were reduced in the iron-manganese nodules. The contents of Ba, Cd, Co, Cu, Ni, Pb and Zn were positively and significantly correlated with that of MnO2 in the iron-manganese nodules, while the contents of Cr, Cu, Ni, Pb and Zn were positively and significantly correlated with that of Fe2O3 in soils. Based on a principle component analysis, the elements of iron-manganese nodules were divided into four groups: 1) Mn, Ba, Cd, Co, Cu, Li, Ni, Pb and Zn that were associated with Mn oxides, 2) Fe, Cr and P that were associated with Fe oxides, 3) Si, K, and Mg that were included in the elemental composition of phyllosilicate, and 4) Ca, Na, Al and Ti that existed in todorokite, birnessite, lithiophorite and phyllosilicate. It was suggested that accumulation, mineralization and specific adsorption were involved in the formation processes of soil iron-manganese nodules.
基金Supported by the US Agency for International Development(USAID)cooperation agreement(486-A-00-06-000140-00)
文摘Elemental mercury（Hg^0）re-emissions from slurries and solutions were evaluated in a lab-scale simulated scrubber.Oxidized mercury（Hg^2 ＋）standard solution was injected into the simulated scrubber at a desired rate to simulate absorbing and dissolving of Hg^2 ＋in the flue gas across wet flue gas desulfurization（WFGD）systems. PS analytical mercury analyzer was used to continuously determine Hg0re-emission concentrations in the carrier gas from the scrubber.Sulfite ion in the slurry of CaSO3 was validated to reduce Hg ^2＋to Hg^ 0,while no Hg ^0 re-emission occurred from slurries of CaSO4 and CaO.Transitional metal ions with low chemical valence such as Fe^2 ＋,Pb ^2＋,Ni ^2＋, AsO2^-and Cu ^＋were used to prepare solutions with concentration levels of mmol·L^-1.Reduction reaction of Hg^2 ＋to Hg 0was observed from these solutions.Reduction capabilities for the different transitional metal ions in the solutions were：Pb^2 ＋〉Cu ^＋〉Fe^ 2＋〉 AsO2^-〉Ni ^2＋.
基金Project supported by the Foundation of Research Grants Council of Hong Kong (No. PolyU 5145/03E) the National Natural Science Foundation of China (No. 40121303).
文摘Quantitative information on mass concentrations and other characteristics, such as spatial distribution, seasonal variation, indoor/outdoor （I/O） ratio, correlations and sources, of indoor and outdoor PM2.5 and elemental components in Guangzhou City were provided. Mass concentration of PM2.5 and elemental components were determined by standard weight method and proton-induced X-ray emission （PIXE） method. 18 elements were detected, the results showed positive results. Average indoor and outdoor PM2.5 concentrations in nine sites were in the range of 67.7-74.5μg/m^3 for summer period, and 109.9-123.7 μg/m^3 for winter period, respectively. The sum of 18 elements average concentrations were 5362.6-5533.4 ng/m^3 for summer period, and 8416.8-8900.6 ng/m^3 for winter period, respectively. Average concentrations of PM2.5 and element components showed obvious spatial characteristic, that the concentrations in roadside area and in industrial plant area were higher than those in generic urban area. An obvious seasonal variation characteristic was found for PM2.5 and elemental components, that the concentrations in winter were higher than that in summer. The I/O ratio of PM2.5 and some elemental components presented larger than 1 sometimes. According to indoor/outdoor correlation of PM2.5 and element concentrations, it was found that there were often good relationships between indoor and outdoor concentrations. Enrichment factors were calculated to evaluate anthropogenic versus natural elements sources.
基金National Basic Research Program of China (Grant No. 2006CB400501)the Hundred Talents Program (Aerosol Characteristics and its Climatic Impact) of the Chinese Academy of Sciences, and National Natural Science Foun- dation of China (Grant Nos. 40675074, 40645028)
文摘Continuous observations of mass concentration and elemental composition of aerosol particles （PM2.5） were conducted at Tongyu, a semi-arid site in Northeast China in the spring of 2006. The average mass concentration of PM2.5 at Tongyu station was 260.9±274.4 μg m^-3 during the observation period. Nine dust events were monitored with a mean concentration of 528.0±302.7 μgm^-3. The PM2.5 level during non- dust storm （NDS） period was 111.65±63.37 μg m^-3. High mass concentration shows that fine-size particles pollution was very serious in the semi-arid area in Northeast China. The enrichment factor values for crust elements during the dust storm （DS） period are close to those in the NDS period, while the enrichment factor values for pollution elements during the NDS period are much higher than those in the DS period, showing these elements were from anthropogenic sources. The ratios of dust elements to Fe were relative constant during the DS period. The Ca/Fe ratio in dust aerosols at Tongyu is remarkably different from that observed in other source regions and downwind regions. Meteorological analysis shows that dust events at Tongyu are usually associated with dry, low pressure and high wind speed weather conditions. Air mass back-trajectory analysis identified three kinds of general pathways were associated with the aerosol particle transport to Tongyu, and the northwest direction pathway was the main transport route.
