Agglomeration supports the high-quality development of the manufacturing industry,and its associated resource and environmental effects play a crucial role in driving green economic development.Based on data from pref...Agglomeration supports the high-quality development of the manufacturing industry,and its associated resource and environmental effects play a crucial role in driving green economic development.Based on data from prefecture-level cities in China from 2005 to 2019,this study employs the inverse distance weighting method,the bivariate local indicator of spatial association model,the spatial Durbin model,and other techniques to explore the relationship between manufacturing agglomeration and PM_(2.5)concentrations,and to assess the impact of its manufacturing agglomeration.Four correlation patterns are observed:high-high,low-low,high-low,and low-high.Among these,high-high and low-low patterns dominate in terms of number of cities.These correlation patterns demonstrate strong temporal stability,with a clear“Matthew effect”.The effect of manufacturing agglomeration on PM_(2.5)levels is significantly negative and helps reduce concentrations regionally,indicating the need to further enhance agglomeration levels regionally.However,it can increase PM_(2.5)levels in neighboring areas due to a siphon effect,and the impact of varies across regions.Compared with levels in 2005-2013,the significance of the relationship between manufacturing agglomeration and PM_(2.5)weakened in the 2013-2019 period.Accordingly,this study proposes countermeasures and policy recommendations aimed at strengthening regional collaborative governance and inspiring differentiated agglomeration strategies to support sustainable economic development in China.展开更多
Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electro...Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electrocatalytic reaction kinetics at the cathode.The integration of light energy into Zn/Sn-air batteries is a promising strategy for enhancing their performance.However,the photothermal and photoelectric effects generate heat in the battery under prolonged solar irradiation,leading to air cathode instability.This paper presents the first design and synthesis of Ni_(2)-1,5-diamino-4,8-dihydroxyanthraquinone(Ni_(2)DDA),an electronically conductiveπ-d conjugated metal-organic framework(MOF).Ni_(2)DDA exhibits both photoelectric and photothermal effects,with an optical band gap of~1.14 eV.Under illumination,Ni_(2)DDA achieves excellent oxygen evolution reaction performance(with an overpotential of 245 mV vs.reversible hydrogen electrode at 10 mA cm^(−2))and photothermal stability.These properties result from the synergy between the photoelectric and photothermal effects of Ni_(2)DDA.Upon integration into Zn/Sn-air batteries,Ni_(2)DDA ensures excellent cycling stability under light and exhibits remarkable performance in high-temperature environments up to 80℃.This study experimentally confirms the stable operation of photo-assisted Zn/Sn-air batteries under high-temperature conditions for the first time and provides novel insights into the application of electronically conductive MOFs in photoelectrocatalysis and photothermal catalysis.展开更多
The efficient electrocatalytic oxidation of glycerol(GLY)is one of the most promising routes for the valorization of GLY.Doping has emerged as a powerful strategy to tailor the electrocatalytic performance of silver n...The efficient electrocatalytic oxidation of glycerol(GLY)is one of the most promising routes for the valorization of GLY.Doping has emerged as a powerful strategy to tailor the electrocatalytic performance of silver nanoclusters(Ag NCs),yet the effects of doping mode(surface vs.core)and the interface environment(e.g.,electrolyte concentration)on the electrocatalytic performance for Ag NCs toward GLY oxidation remain understood.In this work,surface-doped Ag_(4)M_(2)(SR)_(8) and core-doped Ag_(24)M(SR)_(18)(M=Ni,Pd,Pt;SR=SPhMe_(2))NCs were synthesized for electrocatalytic GLY oxidation.The results revealed a strong dependence of selectivity on doping mode and electrolyte concentration:under low KOH concentration,Pd-and Pt-doped Ag_(4)M_(2) NCs exhibited 100%selectivity toward oxalic acid(OA),whereas Pd-and Pt-doped Ag_(24)M NCs delivered>95%selectivity for formic acid(FA).In contrast,under high KOH concentration,Pd-and Pt-doped Ag_(4)M_(2) NCs gave rise to>80%FA,while Pd-and Pt-doped Ag_(24)M NCs produced>45%FA.Mechanism studies indicated that Ni doping predominantly enhanced catalytic activity via lowering the activation barrier of the initial reaction step(GLY→glyceraldehyde),whereas Pd and Pt doping modulated selectivity through reducing the energy barrier of the selective branch step(glyceric acid→OA,OA→FA).High KOH concentration promoted the oxidation by increasing the electrochemical active surface area and facilitating electron transfer of Ag NCs.This study provides clear guidance for designing high-performance Ag-based electrocatalysts for biomass valorization.展开更多
The magnetic properties and Kondo effect in Ce_(3)TiBi_(5) with a quasi-one-dimensional structure were investigated using in situ high-pressure resistivity measurements up to 48 GPa.At ambient pressure,Ce_(3)TiBi_(5) ...The magnetic properties and Kondo effect in Ce_(3)TiBi_(5) with a quasi-one-dimensional structure were investigated using in situ high-pressure resistivity measurements up to 48 GPa.At ambient pressure,Ce_(3)TiBi_(5) undergoes an antiferromagnetic(AFM)transition at T_(N)∼5 K.Under high pressures within 8.9 GPa,we find that Kondo scattering contributes differently to the high-temperature resistance,R(T),depending on the applied current direction,demonstrating a significantly anisotropic Kondo effect.The complete P–T phase diagram has been constructed,in which the pressure dependence of T_(N) exhibits a dome-like shape.The AFM order remains robust under pressure,even when the coherence temperature T^(*) far exceeds 300 K.We attribute the observed anisotropic Kondo effect and the robust AFM to the underlying anisotropy in electronic hybridization under high pressure.展开更多
In magnetic topological materials,the interplay between magnetism and nontrivial topology gives rise to exotic quantum transport phenomena,including the anomalous Hall effect and anomalous Nernst effect.Here,we report...In magnetic topological materials,the interplay between magnetism and nontrivial topology gives rise to exotic quantum transport phenomena,including the anomalous Hall effect and anomalous Nernst effect.Here,we report the observation of intrinsic topological Hall and topological Nernst effects below the Néel temperature(T_(N)=25 K)in the antiferromagnetic(AFM)topological insulator Mn Bi_(2)Te_(4).The maximum of topological Hall resistivity reaches approximately 9μΩ·cm at 2 K,while the topological Nernst signal attains a peak value of 0.1μV/K near 10 K.These anomalous transport behaviors originate from the net Berry curvature induced by the non-collinear spin structure in the canted AFM state.Our results suggest a close connection between the topological thermoelectric effect and non-collinear AFM order in AFM topological insulators.展开更多
Herein,3‑aminopropyltriethoxysilane(APTES)was used to modify F‑containing silica slag(SS)by simple grafting and served as a multifunctional barrier layer.The amino group(—NH2)in the amino‑modified SS(NH2‑SS)forms lig...Herein,3‑aminopropyltriethoxysilane(APTES)was used to modify F‑containing silica slag(SS)by simple grafting and served as a multifunctional barrier layer.The amino group(—NH2)in the amino‑modified SS(NH2‑SS)forms ligand bonds or hydrogen bonds with sulfur ions in lithium polysulfides(LiPSs),thus inhibiting the shuttle effect.Electrochemical analyses demonstrated that lithium‑sulfur(Li‑S)batteries employing the NH2‑SS interlayer exhibited discharge specific capacities of 1048 and 789 mAh·g^(-1) at 0.2C and 2C,respectively,and even at 4C,the initial discharge specific capacity remained at 590 mAh·g^(-1),outperforming the Li‑S battery with unmodified SS as the interlayer.展开更多
The in-flight heating process of cerium dioxide(CeO_(2))powders was investigated through experiments and numerical simulations.In the experiment,CeO_(2)powder(average size of 30μm)was injected into radio-frequency(RF...The in-flight heating process of cerium dioxide(CeO_(2))powders was investigated through experiments and numerical simulations.In the experiment,CeO_(2)powder(average size of 30μm)was injected into radio-frequency(RF)argon plasma,and the temperatures were measured using a DPV-2000 monitor.A model combining the electromagnetism,thermal flow,and heat transfer characteristics of powder during in-flight heating in argon plasma was proposed.The melting processes of CeO_(2)powders of different diameters,with and without thermal resistance effect,were investigated.Results show that the heating process of CeO_(2)powder particles consists of three main stages,one of which is relevant to a dimensionless parameter known as the Biot number.When the Biot value≥0.1,thermal resistance increases significantly,especially for the larger powders.The predicted temperature of the particles at the outlet(1800–2880 K)is in good agreement with the experimental result.展开更多
Chitosan(CTS)was grafted onto the surface of amino‑functionalized silver chloride silicon dioxide(AgCl@SiO_(2)‑NH_(2))cores to obtain AgCl@SiO_(2)/CTS hybrid nanoparticles.The as‑obtained AgCl@SiO_(2)/CTS nanoparticle...Chitosan(CTS)was grafted onto the surface of amino‑functionalized silver chloride silicon dioxide(AgCl@SiO_(2)‑NH_(2))cores to obtain AgCl@SiO_(2)/CTS hybrid nanoparticles.The as‑obtained AgCl@SiO_(2)/CTS nanoparticles were chlorinated by NaClO solution to get AgCl@SiO_(2)/CTS‑based chloramine nano‑hybrid materials,denoted as AgCl@SiO_(2)/CTS‑Cl.A transmission electron microscope was used to observe the morphology of the as‑prepared samples AgCl@SiO_(2)/CTS and AgCl@SiO_(2)/CTS‑Cl.At the same time,an X‑ray diffractometer and an infrared spectroscope were utilized to characterize their crystal and chemical structures.Besides,ζpotentials were measured to elucidate the surface modification of AgCl nanoparticles by—NH_(2),the antibacterial mechanism of AgCl@SiO_(2)/CTS‑Cl was investigated by scanning electron microscopy,and Escherichia coli(E.coli)and Staphylococcus aureus(S.aureus)were used as the to‑be‑tested strains to evaluate the antimicrobial activity of samples AgCl@SiO_(2)/CTS and AgCl@SiO_(2)/CTS‑Cl.Findings demonstrate that sample AgCl@SiO_(2)/CTS exhibits a chain‑like structure ascribed to the interaction between—NH_(2),and each AgCl@SiO_(2)/CTS hybrid nanoparticle contains several AgCl cores.In the meantime,sample AgCl@SiO_(2)/CTS‑Cl exhibits excellent antibacterial activity against E.coli and S.aureus,which is attributed to the synergistic antibacterial effect of Ag^(+)and Cl^(-).Sample AgCl@SiO_(2)/CTS‑Cl with a dosage of 640.00μg·mL^(-1) could completely kill the two kinds of tested bacteria in 12 h of incubation;it retains a high antibacterial efficiency even after 10 cycles of antibacterial tests.展开更多
The Zeeman effect,a fundamental quantum phenomenon,demonstrates the interaction between magnetic fields and atomic systems.While precise spectroscopic measurements of this effect have advanced significantly,there rema...The Zeeman effect,a fundamental quantum phenomenon,demonstrates the interaction between magnetic fields and atomic systems.While precise spectroscopic measurements of this effect have advanced significantly,there remains a lack of simple,visually accessible demonstration for educational purposes.Here,we present a low-cost experiment that allows for direct visual observation of the Zeeman effect.Our setup involves a flame containing sodium(from table salt)placed in front of a sodium vapor lamp.When a magnetic field is applied to the flame,the shadow cast by the flame noticeably lightens,providing a clear,naked-eye demonstration of the Zeeman effect.Furthermore,we conduct two quantitative experiments using this setup,examining the effects of varying magnetic field strength and sodium concentration.This innovative approach not only enriches the experimental demonstration for teaching atomic physics at undergraduate and high school levels but also provides an open platform for students to explore the Zeeman effect through hands-on experience.展开更多
Preferential magnesium(Mg)electrodeposition on separators is a ubiquitous yet poorly understood phenomenon in rechargeable Mg-metal batteries,posing a fundamental challenge to their development.In this work,the synerg...Preferential magnesium(Mg)electrodeposition on separators is a ubiquitous yet poorly understood phenomenon in rechargeable Mg-metal batteries,posing a fundamental challenge to their development.In this work,the synergy effects of interface-accelerating desolvation and spatial confinement have been demonstrated as the essential causation of this counterintuitive experimental phenomenon.At the molecular level,the imide ring(-CO-NR-CO-,in which R represents the phenyl)groups in an artificially introduced polyimide(PI)interlayer facilitate the strong electrostatic affinity towards Mg^(2+),which accelerates the desolvation process for Mg^(2+)solvation structures at the inner Helmholtz plane.At the nucleation scale,the wedge-like concave geometry formed at the PI/current collector interface provides energetically favorable sites for Mg nucleation.This unique architecture reduces the critical nucleus size,thereby significantly lowering nucleation energy barriers.As a result,the satisfactory Coulombic efficiency for Mg plating/stripping(98.22%)and cycle lifespan(1200 cycles,above 100 days)have been achieved,outperforming most of the previous results.This work pioneers a molecular-level understanding of separator-directed Mg deposition and resolves a long-standing confusion in Mg-metal batteries.展开更多
Understanding the underlying mechanism that enhances the separation of specific target ions from complex background aqueous solutions is crucial for achieving controllable chemical reactions and industrial purificatio...Understanding the underlying mechanism that enhances the separation of specific target ions from complex background aqueous solutions is crucial for achieving controllable chemical reactions and industrial purification processes in modern industries.This study investigated the enhanced kinetic separatio n of target metal ions from complex aqueous solutio ns at a liquid-liquid interface,focusing on the presence of coexisting salt cations.Employing a typical thin-layer organic oil film(TOOF)extraction as a model system,the research examines how background Al^(3+)ions influence the mass transfer and separation of ions.Notably,the co ncentration of Al^(3+)ions affects both the distribution of Er^(3+)ions at the oil-water interface and the arrangement and orientation of P507 extractant molecules through the formation of unique hydrogen-bonding interactions.These interactions influence the selectivity of mass transfer,facilitating the separation of Er^(3+)from Al^(3+)ions.Specifically,the hydration shell of Er^(3+)ions is disrupted due to the strong hydration capability of coexisting Al^(3+)ions,leading to a higher interfacial concentration of Er^(3+)ions and a more ordered interfacial orientation of P507 molecules.At lower concentrations of Al^(3+)ions,the diffusion rate of Er^(3+)ions near the interface is high,enhancing the sepa ration perfo rmance of these ions.In contrast,at higher concentrations of Al^(3+)ions,the competitive hydration by Al^(3+)ions increases,and the interfacial concentration of Er^(3+)ions decreases due to enhanced diffusion resistance,resulting in poorer separation performance.Furthermore,a thinner membrane is more effective than a thicker one in enriching target Er^(3+)ions at the interface and achieving an ordered interfacial orientation of P507 molecules,thereby enhancing the separation coefficient(β_(Er/Al)).This work provides novel insights into the behaviors of ions and extractants at oil-wate r interface and the kinetic separation selectivity under varying concentrations of coexisting salt cations.展开更多
Understanding Cd contamination in the soil-rice ecosystem and the underlying its threshold and interaction effects is crucial for controlling Cd pollution and ensuring food safety.Although the quantitative relationshi...Understanding Cd contamination in the soil-rice ecosystem and the underlying its threshold and interaction effects is crucial for controlling Cd pollution and ensuring food safety.Although the quantitative relationships between Cd and environmental variables have been extensively studied,the threshold and interaction effects of multi-source environmental variables remain largely unexplored.This study employs a combination of random forest analysis and a human health risk model to investigate the effects of variables on Cd levels in rice grains,with the goal of quantifying their contributions and elucidating their relationships.The results indicated that the 15 selected variables collectively explained 47.36%of the variation in Cd content,with the top three variables being soil pH,distance from industrial park,and soil Zn.The majority of variables exhibited threshold effects on Cd levels in rice grains.By visualizing the interaction between Soil pH,distance from industrial park,and soil Zn with Cd levels in rice,we demonstrate the threshold effects of them on Cd level in rice grains,thereby providing further insight into the variation observed.Furthermore,oral intake of rice has been identified as the primary route of human exposure,significantly contributing to overall exposure pathways.Understanding these interactions is crucial for gaining insights into the underlying processes driving Cd pollution and fostering sustainable development within the industry.Our findings underscore the crucial need to consider multiple environmental variables and their interactions when managing heavy metals(HMs)contamination and mitigating health risks.展开更多
The effect of adding hydroxycinnamic acids(caffeic acid,sinapic acid,p-coumaric acid and chlorogenic acid)in Cabernet Sauvignon dry red wine before and after fermentation was investigated,taking into account the color...The effect of adding hydroxycinnamic acids(caffeic acid,sinapic acid,p-coumaric acid and chlorogenic acid)in Cabernet Sauvignon dry red wine before and after fermentation was investigated,taking into account the color parameters,anthocyanin content,and overall polyphenol levels in the wine samples.The copigmentation effect of malvidin-3-Oglucoside and sinapic acid was further explored in model solution and through theoretical calculations.The results indicated that the addition of hydroxycinnamic acids significantly enhanced the wine's color with sinapic acid(before the fermentation)showing the most pronounced color protection effect.Compared to control samples,the addition of hydroxycinnamic acids resulted in a 36%increase in total phenolic content and a 28% increase in total anthocyanin content.Thermodynamic analysis revealed that the interaction between sinapic acid and malvidin-3-O-glucoside was spontaneous and exothermic.Theoretical studies identified hydrogen bonding(HB)and dispersion forces as the main primary stabilizing forces,with the carboxyl group of sinapic acid playing a critical role while the anthocyanin backbone also influenced the interaction.展开更多
Objective:To explore the intervention effect of comprehensive perioperative blood glucose management on patients with diabetes complicated with cataract surgery.Method:A total of 68 patients in our hospital from July ...Objective:To explore the intervention effect of comprehensive perioperative blood glucose management on patients with diabetes complicated with cataract surgery.Method:A total of 68 patients in our hospital from July 2024 to July 2025 were selected and randomly divided into the experimental group and the control group,with 34 cases in each group.The control group received routine blood glucose management,while the experimental group,on this basis,implemented individualized intervention 3 days before the operation,real-time regulation during the operation,dynamic management 7 days after the operation,and self-management training.Result:The blood glucose control in the experimental group was more stable 7 days after the operation.The total incidence of complications(2.9%)was significantly lower than that in the control group(38.2%),and the average hospital stay(5.1±1.0 days)was shorter than that in the control group(7.3±1.4 days).One week after the operation,the proportions of uncorrected visual acuity and visual acuity≥0.6(67.6%)were both better than those of the control group(p<0.001).Conclusion:The whole-course management of perioperative blood glucose can enhance the stability of blood glucose control,reduce the risk of complications,shorten the length of hospital stay,promote visual recovery,and has high clinical promotion value.展开更多
Benzalkonium chloride(BAC)is widely employed as a broad-spectrum biocide and has emerged as a significant environmental pollutant.Polymyxin B(PB)serves as the last-line defense for the treatment of Gram-negative patho...Benzalkonium chloride(BAC)is widely employed as a broad-spectrum biocide and has emerged as a significant environmental pollutant.Polymyxin B(PB)serves as the last-line defense for the treatment of Gram-negative pathogens.Previous studies reported that BAC-adapted Pseudomonas aeruginosa increased the tolerance to PB.Herein,we present the novel finding that the combination of BAC and PB exhibited synergistic antibacterial effects against P.aeruginosa.Time-killing assay demonstrated a significant reduction in bacterial cell viability.Scanning electron microscopy,zeta potential analysis,hydrophobicity measurements,and fluorescence probe analyses collectively revealed severe disruption of the cell envelope and membrane potential induced by the combination of BAC and PB.Transcriptomic analysis revealed that the BAC-PB combination notably downreg-ulated the expression of genes involved in lipid A modification and cell envelope production,including phoPQ,pmrAB,bamABCDE,lptABCDEG,lolB,yidC,and murJ.Additionally,the combination group exhibited augmented production of reactive oxygen species and diminished ATP synthesis.The expression of the genes associated with substance metabolism and energy generation was significantly impeded.This study provides significant implica-tions for the interactions of biocides and antibiotics on Gram-negative pathogens,while also addressing antibiotic resistance and developing the external treatment strategy for Pseudomonas-infected wounds and burns.展开更多
Fe_(3)Sn_(2),a ferromagnetic metal with a kagome lattice,serves as an ideal platform for exploring topological electronic states and Berry curvature due to its unique band structure.However,systematic reports on the t...Fe_(3)Sn_(2),a ferromagnetic metal with a kagome lattice,serves as an ideal platform for exploring topological electronic states and Berry curvature due to its unique band structure.However,systematic reports on the transport properties of Fe_(3)Sn_(2)nanosheets remain scarce.We present temperature-dependent transport property measurements of Fe_(3)Sn_(2)nanosheets synthesized via chemical vapor deposition on Si/SiO_(2)substrates.The samples exhibit a robust anomalous Hall effect from 40 K to 300 K,along with a magnetoresistance sign reversal at 40 K at high magnetic fields,indicating a spin reorientation from in-plane to out-of-plane.Notably,a sharp crossover in the dominant transport contribution from electrons to holes near 200 K is observed,accompanied by distinct anomalous Hall behaviors in the two regimes,indicating a temperature-induced Lifshitz transition within the multi-band system.This divergence is potentially linked to a topological reconstruction of the Fermi surface across the transition.Our findings highlight the tunability of topological transport in two-dimensional kagome magnets and provide new insights into the interplay between band topology,dimensionality and magnetic order.展开更多
High-entropy magnetocaloric alloys offer exceptional compositional flexibility and stability for magnetic refrigeration.However,enhancing their magnetic entropy change,working temperature range,and refrigeration capac...High-entropy magnetocaloric alloys offer exceptional compositional flexibility and stability for magnetic refrigeration.However,enhancing their magnetic entropy change,working temperature range,and refrigeration capacity remains challenging.In this study,we demonstrate that microalloying GdTbDyHo with only 0.4at%nonmagnetic Y effectively addresses this limitation.Our analysis indicates that Y uniformly dissolves into the hexagonal matrix lattice,disrupting the 4f–4f exchange interactions and inducing a local short-range order.This weakens the antiferromagnetic coupling,accelerates the antiferromagnetic–ferromagnetic transition,and broadensits range.Consequently,the peak magnetic entropy change increases from 8.2 to 8.7 J·kg^(−1)·K^(−1),the working temperature range expands from 77 to 89 K,and the refrigeration capacity improves by 23%,reaching 774 J·kg^(−1)(5 T)relative to the Y-free alloy,while the Néel temperature remains constant(~195 K).This study establishes nonmagnetic microalloying as a cost-effective and scalable strategy for designing high-performance magnetocaloric materials.展开更多
Significant progress has been recently made in studying artemisinin and its derivatives for treating cardiovascular diseases,making this area a prominent research focus.Artemisinin,discovered with great acclaim,was in...Significant progress has been recently made in studying artemisinin and its derivatives for treating cardiovascular diseases,making this area a prominent research focus.Artemisinin,discovered with great acclaim,was initially and widely adopted in antimalarial treatments.As scientific research steadily progressed,its latent potential role in the cardiovascular system gradually captured the attention of the global scientific community.Artemisinin and its derivatives can reportedly play a protective role in the cardiovascular system through various mechanisms,including anti-inflammatory,anti-angiogenic,antioxidant,and anti-fibrotic effects,as well as the regulation of blood lipids and blood pressure.In particular,they have shown promising therapeutic effects in models of cardiovascular diseases such as atherosclerosis,myocardial ischaemia,and cardiac hypertrophy.In addition,artemisinin and its derivatives can improve cardiovascular function and prevent cardiovascular injury by regulating signalling pathways closely related to cardiovascular disease,such as AMPK and NF-kB.Although numerous ex vivo and in vivo experiments have verified the potential role of artemisinin in treating cardiovascular diseases,systematic studies to comprehensively elucidate its specific mechanism of action remain scarce.Further exploration of the precise roles of artemisinin and its derivatives in cardiovascular disease therapy,along with their potential clinical applications,could offer valuable insights for future research and treatment strategies.展开更多
Cobalt is undoubtedly the most promising alternative metal to rhodium for a highly active and stable hydroformylation process under mild conditions.In this study,two cobalt-based heterogeneous catalysts were synthesiz...Cobalt is undoubtedly the most promising alternative metal to rhodium for a highly active and stable hydroformylation process under mild conditions.In this study,two cobalt-based heterogeneous catalysts were synthesized via impregnating a cobalt precursor into polymers(POPs-NVP).Comprehensive characterization revealed that the cobalt species on the catalysts exist as CoO with two distinct sizes:nanoparticles and single sites.The CoO nanoparticles on POPs-NVP exhibited outstanding hydroformylation activity(81.7%yield of aldehyde and alcohol,13.5%yield of alkane),while CoO single sites displayed robust olefin hydrogenation performance(62.6%yield of alkane,27.3% yield of aldehyde and alcohol).These divergent catalytic behaviors were attributed to distinct electron density distributions around surface-exposed cobalt species,which were critically governed by CoO sizes on catalysts.By elucidating the size-dependent effects of CoO/POPs-NVP catalysts,this work provided insights into the complex active species states in heterogeneous cobalt-based catalysts,and established valuable experimental and theoretical foundations for designing highly efficient cobalt-based heterogeneous catalysts for hydroformylation.展开更多
The effective density(ρ_(eff))is a key parameter of black carbon-containing(BCc)particles and is related to their morphologies,deposition processes,and optical properties.In this study,a tandem system was established...The effective density(ρ_(eff))is a key parameter of black carbon-containing(BCc)particles and is related to their morphologies,deposition processes,and optical properties.In this study,a tandem system was established and used to determine theρ_(eff)of ambient BCc particles.The results showed that theρ_(eff)distribution of ambient BCc particles exhibited a bimodal pattern with a left peak located at 0.69 g cm^(-3)and a right peak at 1.45 g cm^(-3).The averageρ_(eff)of BCc particles over the entire observation period was 1.38 g cm^(-3).Theρ_(eff)of BCc particles showed a clear diurnal pattern with a relatively stable distribution at night and large variations during the daytime.Theρ_(eff)value was demonstrated to be a good indicator of BCc particle morphology.BCc particles became more regular with increasingρ_(eff)related to the increasing coating thickness.More coating led to morphological restructuring of BCc particles.The restructuring could be more efficient under high relative humidity conditions.The observed data were further used in a dry deposition scheme,and it was found that the dry deposition velocity of fresh emitted BCc could be largely influenced by its irregular shape.This study reveals the presence of a significant amount of low-density/irregularly shaped black carbon in the environment with rapid morphological changes occurring during the daytime and highlights the need to consider morphological influences in future research on the physicochemical properties of BCc.展开更多
基金supported by the National Natural Science Foundation of China“Research on the Multi-scale Regional Industrial Spatial Evolution Mechanism,Resource and Environmental Effects,and Green Transformation in the Yellow River Basin”[Grant No.42371194]Taishan Scholar Foundation of Shandong Province[Grant Nos.tsqn202408148 and tstp20240821].
文摘Agglomeration supports the high-quality development of the manufacturing industry,and its associated resource and environmental effects play a crucial role in driving green economic development.Based on data from prefecture-level cities in China from 2005 to 2019,this study employs the inverse distance weighting method,the bivariate local indicator of spatial association model,the spatial Durbin model,and other techniques to explore the relationship between manufacturing agglomeration and PM_(2.5)concentrations,and to assess the impact of its manufacturing agglomeration.Four correlation patterns are observed:high-high,low-low,high-low,and low-high.Among these,high-high and low-low patterns dominate in terms of number of cities.These correlation patterns demonstrate strong temporal stability,with a clear“Matthew effect”.The effect of manufacturing agglomeration on PM_(2.5)levels is significantly negative and helps reduce concentrations regionally,indicating the need to further enhance agglomeration levels regionally.However,it can increase PM_(2.5)levels in neighboring areas due to a siphon effect,and the impact of varies across regions.Compared with levels in 2005-2013,the significance of the relationship between manufacturing agglomeration and PM_(2.5)weakened in the 2013-2019 period.Accordingly,this study proposes countermeasures and policy recommendations aimed at strengthening regional collaborative governance and inspiring differentiated agglomeration strategies to support sustainable economic development in China.
基金supported by the National Natural Science Foundation of China(No.62464010)Spring City Plan-Special Program for Young Talents(K202005007)+2 种基金Yunnan Talents Support Plan for Young Talents(XDYC-QNRC-2022-0482)Yunnan Local Colleges Applied Basic Research Projects(202101BA070001-138)Frontier Research Team of Kunming University 2023.
文摘Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electrocatalytic reaction kinetics at the cathode.The integration of light energy into Zn/Sn-air batteries is a promising strategy for enhancing their performance.However,the photothermal and photoelectric effects generate heat in the battery under prolonged solar irradiation,leading to air cathode instability.This paper presents the first design and synthesis of Ni_(2)-1,5-diamino-4,8-dihydroxyanthraquinone(Ni_(2)DDA),an electronically conductiveπ-d conjugated metal-organic framework(MOF).Ni_(2)DDA exhibits both photoelectric and photothermal effects,with an optical band gap of~1.14 eV.Under illumination,Ni_(2)DDA achieves excellent oxygen evolution reaction performance(with an overpotential of 245 mV vs.reversible hydrogen electrode at 10 mA cm^(−2))and photothermal stability.These properties result from the synergy between the photoelectric and photothermal effects of Ni_(2)DDA.Upon integration into Zn/Sn-air batteries,Ni_(2)DDA ensures excellent cycling stability under light and exhibits remarkable performance in high-temperature environments up to 80℃.This study experimentally confirms the stable operation of photo-assisted Zn/Sn-air batteries under high-temperature conditions for the first time and provides novel insights into the application of electronically conductive MOFs in photoelectrocatalysis and photothermal catalysis.
基金support from the Jiangsu Natural Science Foundation of China(BK20230329)the National Natural Science Foundation of China(22401147,22361132540,and 22178161)the Russian Science Foundation(23-73-30007).
文摘The efficient electrocatalytic oxidation of glycerol(GLY)is one of the most promising routes for the valorization of GLY.Doping has emerged as a powerful strategy to tailor the electrocatalytic performance of silver nanoclusters(Ag NCs),yet the effects of doping mode(surface vs.core)and the interface environment(e.g.,electrolyte concentration)on the electrocatalytic performance for Ag NCs toward GLY oxidation remain understood.In this work,surface-doped Ag_(4)M_(2)(SR)_(8) and core-doped Ag_(24)M(SR)_(18)(M=Ni,Pd,Pt;SR=SPhMe_(2))NCs were synthesized for electrocatalytic GLY oxidation.The results revealed a strong dependence of selectivity on doping mode and electrolyte concentration:under low KOH concentration,Pd-and Pt-doped Ag_(4)M_(2) NCs exhibited 100%selectivity toward oxalic acid(OA),whereas Pd-and Pt-doped Ag_(24)M NCs delivered>95%selectivity for formic acid(FA).In contrast,under high KOH concentration,Pd-and Pt-doped Ag_(4)M_(2) NCs gave rise to>80%FA,while Pd-and Pt-doped Ag_(24)M NCs produced>45%FA.Mechanism studies indicated that Ni doping predominantly enhanced catalytic activity via lowering the activation barrier of the initial reaction step(GLY→glyceraldehyde),whereas Pd and Pt doping modulated selectivity through reducing the energy barrier of the selective branch step(glyceric acid→OA,OA→FA).High KOH concentration promoted the oxidation by increasing the electrochemical active surface area and facilitating electron transfer of Ag NCs.This study provides clear guidance for designing high-performance Ag-based electrocatalysts for biomass valorization.
基金supported by the National Key Research and Development Program of Chinathe National Natural Science Foundation of China (Grant Nos.2024YFA1408000,12474097,and2023YFA1406001)+2 种基金the Guangdong Provincial Quantum Science Strategic Initiative (Grant No.GDZX2201001)the Center for Computational Science and Engineering at Southern University of Science and Technology,the Major Science and Technology Infrastructure Project of Material Genome Big-science Facilities Platform supported by Municipal Development and Reform Commission of Shenzhen(for J.L.Z.and Y.L.)the Chinese funding sources applied via HPSTAR。
文摘The magnetic properties and Kondo effect in Ce_(3)TiBi_(5) with a quasi-one-dimensional structure were investigated using in situ high-pressure resistivity measurements up to 48 GPa.At ambient pressure,Ce_(3)TiBi_(5) undergoes an antiferromagnetic(AFM)transition at T_(N)∼5 K.Under high pressures within 8.9 GPa,we find that Kondo scattering contributes differently to the high-temperature resistance,R(T),depending on the applied current direction,demonstrating a significantly anisotropic Kondo effect.The complete P–T phase diagram has been constructed,in which the pressure dependence of T_(N) exhibits a dome-like shape.The AFM order remains robust under pressure,even when the coherence temperature T^(*) far exceeds 300 K.We attribute the observed anisotropic Kondo effect and the robust AFM to the underlying anisotropy in electronic hybridization under high pressure.
基金supported in part by the Natural Science Foundation of China(Grant No.U1932155)the Hangzhou Joint Fund of the Zhejiang Provincial Natural Science Foundation of China(Grant No.LHZSZ24A040001)+4 种基金the National Key R&D Program of China(Grant No.2022YFA1602602)the National Key R&D Program of China(Grant Nos.2022YFA1403800 and 20-23YFA1406500)the China Postdoctoral Science Foundation(Grant No.2023-M730011)the National Natural Science Foundation of China(Grant No.12274459)supported by the HZNU Scientific Research and Innovation Team Project(No.TD2025013)。
文摘In magnetic topological materials,the interplay between magnetism and nontrivial topology gives rise to exotic quantum transport phenomena,including the anomalous Hall effect and anomalous Nernst effect.Here,we report the observation of intrinsic topological Hall and topological Nernst effects below the Néel temperature(T_(N)=25 K)in the antiferromagnetic(AFM)topological insulator Mn Bi_(2)Te_(4).The maximum of topological Hall resistivity reaches approximately 9μΩ·cm at 2 K,while the topological Nernst signal attains a peak value of 0.1μV/K near 10 K.These anomalous transport behaviors originate from the net Berry curvature induced by the non-collinear spin structure in the canted AFM state.Our results suggest a close connection between the topological thermoelectric effect and non-collinear AFM order in AFM topological insulators.
文摘Herein,3‑aminopropyltriethoxysilane(APTES)was used to modify F‑containing silica slag(SS)by simple grafting and served as a multifunctional barrier layer.The amino group(—NH2)in the amino‑modified SS(NH2‑SS)forms ligand bonds or hydrogen bonds with sulfur ions in lithium polysulfides(LiPSs),thus inhibiting the shuttle effect.Electrochemical analyses demonstrated that lithium‑sulfur(Li‑S)batteries employing the NH2‑SS interlayer exhibited discharge specific capacities of 1048 and 789 mAh·g^(-1) at 0.2C and 2C,respectively,and even at 4C,the initial discharge specific capacity remained at 590 mAh·g^(-1),outperforming the Li‑S battery with unmodified SS as the interlayer.
基金National Natural Science Foundation of China(11875039)Shanxi Scholarship Council of China(2023-033)+2 种基金Fundamental Research Program of Shanxi Province(202303021221071)China Baowu Low Carbon Metallurgical Innovation Foundation(2022)2023 Anhui Major Industrial Innovation Plan Project。
文摘The in-flight heating process of cerium dioxide(CeO_(2))powders was investigated through experiments and numerical simulations.In the experiment,CeO_(2)powder(average size of 30μm)was injected into radio-frequency(RF)argon plasma,and the temperatures were measured using a DPV-2000 monitor.A model combining the electromagnetism,thermal flow,and heat transfer characteristics of powder during in-flight heating in argon plasma was proposed.The melting processes of CeO_(2)powders of different diameters,with and without thermal resistance effect,were investigated.Results show that the heating process of CeO_(2)powder particles consists of three main stages,one of which is relevant to a dimensionless parameter known as the Biot number.When the Biot value≥0.1,thermal resistance increases significantly,especially for the larger powders.The predicted temperature of the particles at the outlet(1800–2880 K)is in good agreement with the experimental result.
文摘Chitosan(CTS)was grafted onto the surface of amino‑functionalized silver chloride silicon dioxide(AgCl@SiO_(2)‑NH_(2))cores to obtain AgCl@SiO_(2)/CTS hybrid nanoparticles.The as‑obtained AgCl@SiO_(2)/CTS nanoparticles were chlorinated by NaClO solution to get AgCl@SiO_(2)/CTS‑based chloramine nano‑hybrid materials,denoted as AgCl@SiO_(2)/CTS‑Cl.A transmission electron microscope was used to observe the morphology of the as‑prepared samples AgCl@SiO_(2)/CTS and AgCl@SiO_(2)/CTS‑Cl.At the same time,an X‑ray diffractometer and an infrared spectroscope were utilized to characterize their crystal and chemical structures.Besides,ζpotentials were measured to elucidate the surface modification of AgCl nanoparticles by—NH_(2),the antibacterial mechanism of AgCl@SiO_(2)/CTS‑Cl was investigated by scanning electron microscopy,and Escherichia coli(E.coli)and Staphylococcus aureus(S.aureus)were used as the to‑be‑tested strains to evaluate the antimicrobial activity of samples AgCl@SiO_(2)/CTS and AgCl@SiO_(2)/CTS‑Cl.Findings demonstrate that sample AgCl@SiO_(2)/CTS exhibits a chain‑like structure ascribed to the interaction between—NH_(2),and each AgCl@SiO_(2)/CTS hybrid nanoparticle contains several AgCl cores.In the meantime,sample AgCl@SiO_(2)/CTS‑Cl exhibits excellent antibacterial activity against E.coli and S.aureus,which is attributed to the synergistic antibacterial effect of Ag^(+)and Cl^(-).Sample AgCl@SiO_(2)/CTS‑Cl with a dosage of 640.00μg·mL^(-1) could completely kill the two kinds of tested bacteria in 12 h of incubation;it retains a high antibacterial efficiency even after 10 cycles of antibacterial tests.
基金the National Natural Science Foundation of China for support under grant No.12305037the Fundamental Research Funds for the Central Universities under grant No.2023NTST017。
文摘The Zeeman effect,a fundamental quantum phenomenon,demonstrates the interaction between magnetic fields and atomic systems.While precise spectroscopic measurements of this effect have advanced significantly,there remains a lack of simple,visually accessible demonstration for educational purposes.Here,we present a low-cost experiment that allows for direct visual observation of the Zeeman effect.Our setup involves a flame containing sodium(from table salt)placed in front of a sodium vapor lamp.When a magnetic field is applied to the flame,the shadow cast by the flame noticeably lightens,providing a clear,naked-eye demonstration of the Zeeman effect.Furthermore,we conduct two quantitative experiments using this setup,examining the effects of varying magnetic field strength and sodium concentration.This innovative approach not only enriches the experimental demonstration for teaching atomic physics at undergraduate and high school levels but also provides an open platform for students to explore the Zeeman effect through hands-on experience.
基金supported by the National Natural Science Foundation of China(22279068,52374306)the Taishan Scholars of Shandong Province(tsqn202408202)the Qingdao New Energy Shandong Laboratory Open Project(QNESL OP202312)。
文摘Preferential magnesium(Mg)electrodeposition on separators is a ubiquitous yet poorly understood phenomenon in rechargeable Mg-metal batteries,posing a fundamental challenge to their development.In this work,the synergy effects of interface-accelerating desolvation and spatial confinement have been demonstrated as the essential causation of this counterintuitive experimental phenomenon.At the molecular level,the imide ring(-CO-NR-CO-,in which R represents the phenyl)groups in an artificially introduced polyimide(PI)interlayer facilitate the strong electrostatic affinity towards Mg^(2+),which accelerates the desolvation process for Mg^(2+)solvation structures at the inner Helmholtz plane.At the nucleation scale,the wedge-like concave geometry formed at the PI/current collector interface provides energetically favorable sites for Mg nucleation.This unique architecture reduces the critical nucleus size,thereby significantly lowering nucleation energy barriers.As a result,the satisfactory Coulombic efficiency for Mg plating/stripping(98.22%)and cycle lifespan(1200 cycles,above 100 days)have been achieved,outperforming most of the previous results.This work pioneers a molecular-level understanding of separator-directed Mg deposition and resolves a long-standing confusion in Mg-metal batteries.
基金Project supported by the National Natural Science Foundation of China(52074031,51574213,51904027)the Fundamental Research Funds for the Central Universities of China(06500104)。
文摘Understanding the underlying mechanism that enhances the separation of specific target ions from complex background aqueous solutions is crucial for achieving controllable chemical reactions and industrial purification processes in modern industries.This study investigated the enhanced kinetic separatio n of target metal ions from complex aqueous solutio ns at a liquid-liquid interface,focusing on the presence of coexisting salt cations.Employing a typical thin-layer organic oil film(TOOF)extraction as a model system,the research examines how background Al^(3+)ions influence the mass transfer and separation of ions.Notably,the co ncentration of Al^(3+)ions affects both the distribution of Er^(3+)ions at the oil-water interface and the arrangement and orientation of P507 extractant molecules through the formation of unique hydrogen-bonding interactions.These interactions influence the selectivity of mass transfer,facilitating the separation of Er^(3+)from Al^(3+)ions.Specifically,the hydration shell of Er^(3+)ions is disrupted due to the strong hydration capability of coexisting Al^(3+)ions,leading to a higher interfacial concentration of Er^(3+)ions and a more ordered interfacial orientation of P507 molecules.At lower concentrations of Al^(3+)ions,the diffusion rate of Er^(3+)ions near the interface is high,enhancing the sepa ration perfo rmance of these ions.In contrast,at higher concentrations of Al^(3+)ions,the competitive hydration by Al^(3+)ions increases,and the interfacial concentration of Er^(3+)ions decreases due to enhanced diffusion resistance,resulting in poorer separation performance.Furthermore,a thinner membrane is more effective than a thicker one in enriching target Er^(3+)ions at the interface and achieving an ordered interfacial orientation of P507 molecules,thereby enhancing the separation coefficient(β_(Er/Al)).This work provides novel insights into the behaviors of ions and extractants at oil-wate r interface and the kinetic separation selectivity under varying concentrations of coexisting salt cations.
基金supported by the GDAS’Project of Science and Technology Development(No.2022GDASZH-2022010104-2)Guangdong Major Project of Basic and Applied Basic Research(No.2023B0303000006).
文摘Understanding Cd contamination in the soil-rice ecosystem and the underlying its threshold and interaction effects is crucial for controlling Cd pollution and ensuring food safety.Although the quantitative relationships between Cd and environmental variables have been extensively studied,the threshold and interaction effects of multi-source environmental variables remain largely unexplored.This study employs a combination of random forest analysis and a human health risk model to investigate the effects of variables on Cd levels in rice grains,with the goal of quantifying their contributions and elucidating their relationships.The results indicated that the 15 selected variables collectively explained 47.36%of the variation in Cd content,with the top three variables being soil pH,distance from industrial park,and soil Zn.The majority of variables exhibited threshold effects on Cd levels in rice grains.By visualizing the interaction between Soil pH,distance from industrial park,and soil Zn with Cd levels in rice,we demonstrate the threshold effects of them on Cd level in rice grains,thereby providing further insight into the variation observed.Furthermore,oral intake of rice has been identified as the primary route of human exposure,significantly contributing to overall exposure pathways.Understanding these interactions is crucial for gaining insights into the underlying processes driving Cd pollution and fostering sustainable development within the industry.Our findings underscore the crucial need to consider multiple environmental variables and their interactions when managing heavy metals(HMs)contamination and mitigating health risks.
基金supported by the Key R&D Program of Shaanxi Province,China(2024NC-YBXM-146)the Xi’an Agricultural Technology Research and Development Project,China(24NYGG0048)+1 种基金the Key R&D Program of Xianyang,China(L2024-ZDYF-ZDYF-NY-0028)the National Foreign Expert Project of China(G2023172002L)。
文摘The effect of adding hydroxycinnamic acids(caffeic acid,sinapic acid,p-coumaric acid and chlorogenic acid)in Cabernet Sauvignon dry red wine before and after fermentation was investigated,taking into account the color parameters,anthocyanin content,and overall polyphenol levels in the wine samples.The copigmentation effect of malvidin-3-Oglucoside and sinapic acid was further explored in model solution and through theoretical calculations.The results indicated that the addition of hydroxycinnamic acids significantly enhanced the wine's color with sinapic acid(before the fermentation)showing the most pronounced color protection effect.Compared to control samples,the addition of hydroxycinnamic acids resulted in a 36%increase in total phenolic content and a 28% increase in total anthocyanin content.Thermodynamic analysis revealed that the interaction between sinapic acid and malvidin-3-O-glucoside was spontaneous and exothermic.Theoretical studies identified hydrogen bonding(HB)and dispersion forces as the main primary stabilizing forces,with the carboxyl group of sinapic acid playing a critical role while the anthocyanin backbone also influenced the interaction.
文摘Objective:To explore the intervention effect of comprehensive perioperative blood glucose management on patients with diabetes complicated with cataract surgery.Method:A total of 68 patients in our hospital from July 2024 to July 2025 were selected and randomly divided into the experimental group and the control group,with 34 cases in each group.The control group received routine blood glucose management,while the experimental group,on this basis,implemented individualized intervention 3 days before the operation,real-time regulation during the operation,dynamic management 7 days after the operation,and self-management training.Result:The blood glucose control in the experimental group was more stable 7 days after the operation.The total incidence of complications(2.9%)was significantly lower than that in the control group(38.2%),and the average hospital stay(5.1±1.0 days)was shorter than that in the control group(7.3±1.4 days).One week after the operation,the proportions of uncorrected visual acuity and visual acuity≥0.6(67.6%)were both better than those of the control group(p<0.001).Conclusion:The whole-course management of perioperative blood glucose can enhance the stability of blood glucose control,reduce the risk of complications,shorten the length of hospital stay,promote visual recovery,and has high clinical promotion value.
基金supported by the National Natural Science Foundation of China(No.32170121).
文摘Benzalkonium chloride(BAC)is widely employed as a broad-spectrum biocide and has emerged as a significant environmental pollutant.Polymyxin B(PB)serves as the last-line defense for the treatment of Gram-negative pathogens.Previous studies reported that BAC-adapted Pseudomonas aeruginosa increased the tolerance to PB.Herein,we present the novel finding that the combination of BAC and PB exhibited synergistic antibacterial effects against P.aeruginosa.Time-killing assay demonstrated a significant reduction in bacterial cell viability.Scanning electron microscopy,zeta potential analysis,hydrophobicity measurements,and fluorescence probe analyses collectively revealed severe disruption of the cell envelope and membrane potential induced by the combination of BAC and PB.Transcriptomic analysis revealed that the BAC-PB combination notably downreg-ulated the expression of genes involved in lipid A modification and cell envelope production,including phoPQ,pmrAB,bamABCDE,lptABCDEG,lolB,yidC,and murJ.Additionally,the combination group exhibited augmented production of reactive oxygen species and diminished ATP synthesis.The expression of the genes associated with substance metabolism and energy generation was significantly impeded.This study provides significant implica-tions for the interactions of biocides and antibiotics on Gram-negative pathogens,while also addressing antibiotic resistance and developing the external treatment strategy for Pseudomonas-infected wounds and burns.
基金Project supported by the National Key Research and Development Program of China(Grant Nos.2022YFA1403503,2022YFA1602802,2023YFA1607400,and 2024YFA1613200)Beijing Natural Science Foundation(Grant No.JQ23022)supported by the Synergetic Extreme Condition User Facility and the Innovation Program for Quantum Science and Technology(Grant No.2021ZD0302600)。
文摘Fe_(3)Sn_(2),a ferromagnetic metal with a kagome lattice,serves as an ideal platform for exploring topological electronic states and Berry curvature due to its unique band structure.However,systematic reports on the transport properties of Fe_(3)Sn_(2)nanosheets remain scarce.We present temperature-dependent transport property measurements of Fe_(3)Sn_(2)nanosheets synthesized via chemical vapor deposition on Si/SiO_(2)substrates.The samples exhibit a robust anomalous Hall effect from 40 K to 300 K,along with a magnetoresistance sign reversal at 40 K at high magnetic fields,indicating a spin reorientation from in-plane to out-of-plane.Notably,a sharp crossover in the dominant transport contribution from electrons to holes near 200 K is observed,accompanied by distinct anomalous Hall behaviors in the two regimes,indicating a temperature-induced Lifshitz transition within the multi-band system.This divergence is potentially linked to a topological reconstruction of the Fermi surface across the transition.Our findings highlight the tunability of topological transport in two-dimensional kagome magnets and provide new insights into the interplay between band topology,dimensionality and magnetic order.
基金financially supported by the National Sci-ence Foundation for Young Scientists of China(Nos.52201172,52201171,52401219)the National Science Fund for Distinguished Young Scholars(No.52225103)+4 种基金the National Natural Science Foundation of China(No.52130108)the National Key R&D Program of China(No.2022YFB4602101)the Joint Funds of the National Natural Science Foundation of China(No.U2441262)the Funds for International Cooperation and Exchange of the National Nat-ural Science Foundation of China(No.W2412068)the Fundamental Research Fund for the Central Universities of China(No.FRF-TP-22-001C2).
文摘High-entropy magnetocaloric alloys offer exceptional compositional flexibility and stability for magnetic refrigeration.However,enhancing their magnetic entropy change,working temperature range,and refrigeration capacity remains challenging.In this study,we demonstrate that microalloying GdTbDyHo with only 0.4at%nonmagnetic Y effectively addresses this limitation.Our analysis indicates that Y uniformly dissolves into the hexagonal matrix lattice,disrupting the 4f–4f exchange interactions and inducing a local short-range order.This weakens the antiferromagnetic coupling,accelerates the antiferromagnetic–ferromagnetic transition,and broadensits range.Consequently,the peak magnetic entropy change increases from 8.2 to 8.7 J·kg^(−1)·K^(−1),the working temperature range expands from 77 to 89 K,and the refrigeration capacity improves by 23%,reaching 774 J·kg^(−1)(5 T)relative to the Y-free alloy,while the Néel temperature remains constant(~195 K).This study establishes nonmagnetic microalloying as a cost-effective and scalable strategy for designing high-performance magnetocaloric materials.
基金supported by the Youth Natural Science Foundation of Shandong Province(grant number:ZR2022QH340).
文摘Significant progress has been recently made in studying artemisinin and its derivatives for treating cardiovascular diseases,making this area a prominent research focus.Artemisinin,discovered with great acclaim,was initially and widely adopted in antimalarial treatments.As scientific research steadily progressed,its latent potential role in the cardiovascular system gradually captured the attention of the global scientific community.Artemisinin and its derivatives can reportedly play a protective role in the cardiovascular system through various mechanisms,including anti-inflammatory,anti-angiogenic,antioxidant,and anti-fibrotic effects,as well as the regulation of blood lipids and blood pressure.In particular,they have shown promising therapeutic effects in models of cardiovascular diseases such as atherosclerosis,myocardial ischaemia,and cardiac hypertrophy.In addition,artemisinin and its derivatives can improve cardiovascular function and prevent cardiovascular injury by regulating signalling pathways closely related to cardiovascular disease,such as AMPK and NF-kB.Although numerous ex vivo and in vivo experiments have verified the potential role of artemisinin in treating cardiovascular diseases,systematic studies to comprehensively elucidate its specific mechanism of action remain scarce.Further exploration of the precise roles of artemisinin and its derivatives in cardiovascular disease therapy,along with their potential clinical applications,could offer valuable insights for future research and treatment strategies.
基金supported by the National Key Research and Development Program of China(2023YFA1508003)the National Natural Science Foundation of China(22408363,22302192)+6 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA29050300)the Youth Innovation Promotion Association CAS(2021181)the Key Research and Development Program of Liaoning(2023JH2/101800051)the Dalian of Science and Technology Project(2023RY012)the Postdoctoral Fellowship Program of CPSF(GZC20241677,GZB20230724)the Postdoctoral Science Foundation(2024T170900)the Doctoral Research Start-up Fund of Liaoning(2024-BSBA-28)。
文摘Cobalt is undoubtedly the most promising alternative metal to rhodium for a highly active and stable hydroformylation process under mild conditions.In this study,two cobalt-based heterogeneous catalysts were synthesized via impregnating a cobalt precursor into polymers(POPs-NVP).Comprehensive characterization revealed that the cobalt species on the catalysts exist as CoO with two distinct sizes:nanoparticles and single sites.The CoO nanoparticles on POPs-NVP exhibited outstanding hydroformylation activity(81.7%yield of aldehyde and alcohol,13.5%yield of alkane),while CoO single sites displayed robust olefin hydrogenation performance(62.6%yield of alkane,27.3% yield of aldehyde and alcohol).These divergent catalytic behaviors were attributed to distinct electron density distributions around surface-exposed cobalt species,which were critically governed by CoO sizes on catalysts.By elucidating the size-dependent effects of CoO/POPs-NVP catalysts,this work provided insights into the complex active species states in heterogeneous cobalt-based catalysts,and established valuable experimental and theoretical foundations for designing highly efficient cobalt-based heterogeneous catalysts for hydroformylation.
基金supported by the National Key Research and Development Program of China(Grant No.2022YFC3701000,Task 4)the National Natural Science Foundation of China(Grant Nos.42207126 and 41877314)。
文摘The effective density(ρ_(eff))is a key parameter of black carbon-containing(BCc)particles and is related to their morphologies,deposition processes,and optical properties.In this study,a tandem system was established and used to determine theρ_(eff)of ambient BCc particles.The results showed that theρ_(eff)distribution of ambient BCc particles exhibited a bimodal pattern with a left peak located at 0.69 g cm^(-3)and a right peak at 1.45 g cm^(-3).The averageρ_(eff)of BCc particles over the entire observation period was 1.38 g cm^(-3).Theρ_(eff)of BCc particles showed a clear diurnal pattern with a relatively stable distribution at night and large variations during the daytime.Theρ_(eff)value was demonstrated to be a good indicator of BCc particle morphology.BCc particles became more regular with increasingρ_(eff)related to the increasing coating thickness.More coating led to morphological restructuring of BCc particles.The restructuring could be more efficient under high relative humidity conditions.The observed data were further used in a dry deposition scheme,and it was found that the dry deposition velocity of fresh emitted BCc could be largely influenced by its irregular shape.This study reveals the presence of a significant amount of low-density/irregularly shaped black carbon in the environment with rapid morphological changes occurring during the daytime and highlights the need to consider morphological influences in future research on the physicochemical properties of BCc.
