We experimentally investigate the double ionization pulses. The total kinetic energy release of the two of molecular hydrogen subjected to ultrashort intense laser coincident H＋ ions, which provides a diagnosis of di...We experimentally investigate the double ionization pulses. The total kinetic energy release of the two of molecular hydrogen subjected to ultrashort intense laser coincident H＋ ions, which provides a diagnosis of different processes to double ionization of H2, is measured for two different pulse durations, i.e., 25 and 5 fs, and various laser intensities. It is found that, for the long pulse duration （i.e., 25 fs）, the double ionization occurs mainly via two processes, i.e., the charge resonance enhanced ionization and recollision-induced double ionization. Moreover, the contributions from these two processes can be significantly modulated by changing the laser intensity. In contrast, for a few-cycle pulse of 5 fs, only the recollsion-induced double ionization survives, and in particular, this process could be solely induced by the first-return reeollision at appropriate laser intensities, providing an efficient way to probe the sub-laser-cycle molecular dynamics.展开更多
Combinatorial optimization problems and ground state problems of spin glasses are crucial in various fields of science and technology.However,they often belong to the computational class of NP-hard,presenting signific...Combinatorial optimization problems and ground state problems of spin glasses are crucial in various fields of science and technology.However,they often belong to the computational class of NP-hard,presenting significant computational challenges.Traditional algorithms inspired by statistical physics like simulated annealing have been widely adopted.Recently,advancements in Ising machines,such as quantum annealers and coherent Ising machines,offer new paradigms for solving these problems efficiently by embedding them into the analog evolution of nonlinear dynamical systems.However,existing dynamics-based algorithms often suffer from low convergence rates and local minima traps.In this work,we introduce the dual mean-field dynamics into Ising machines.The approach integrates the gradient force and the transverse force into the dynamics of Ising machines in solving combinatorial optimization problems,making it easier for the system to jump out of the local minimums and allowing the dynamics to explore wider in configuration space.We conduct extensive numerical experiments using the Sherrington–Kirkpatrick spin glass up to 10000 spins and the maximum cut problems with the standard G-set benchmarks.The numerical results demonstrate that our dual mean-field dynamics approach enhances the performance of base Ising machines,providing a more effective solution for large-scale combinatorial optimization problems.展开更多
We demonstrate an all-optical technique for in situ monitoring of strong-field ionization(SFI)dynamics.The method relies on coherent scattering of a probe pulse from a transient plasma grating(TPG)formed by two interf...We demonstrate an all-optical technique for in situ monitoring of strong-field ionization(SFI)dynamics.The method relies on coherent scattering of a probe pulse from a transient plasma grating(TPG)formed by two interfering femtosecond pulses in a gas target.The diffracted signal provides a real-time,relative measure of the ionization yield.We demonstrate the method’s sensitivity by resolving the attosecond-scale coherent control of the ionization rate.Unlike conventional diagnostics that directly measure charged particles,our ensemble-based optical method is non-invasive and particularly suited for non-vacuum environments.To demonstrate its utility,we apply the technique to investigate the relationship between ionization and terahertz(THz)generation in a two-color(ω+2ω)field.We measure a phase offset of(0.18±0.05)π between the maxima of the ionization yield and the THz emission.This result provides a quantitative benchmark for theoretical models and establishes the TPG technique as a practical tool for probing SFI dynamics in ensemble systems.展开更多
Using the digital telemetric seismic waveform data of Chengdu and Kunming, this article studies the focal mechanism solutions and the apparent stress values of a large number of small earthquakes, and then analyzes th...Using the digital telemetric seismic waveform data of Chengdu and Kunming, this article studies the focal mechanism solutions and the apparent stress values of a large number of small earthquakes, and then analyzes the dynamic variation of regional stress fields and the spatio- temporal distribution of apparent stress values. The annual variation values of the azimuth of average principal stress field before the May 12, 2008 Ms8.0 Wenchuan earthquake in the Sichuan-Yunnan region were 58° from 2003 to 2004, 85° from 2003 to 2005,61° from 2006 to 2007 and 90° from 2006 to April 2008 respectively. In recent years, deflection or disturbances occurred in the azimuth of the average principal stress field in the Sichuan-Yunnan region. Analysis shows that this may be related to the change of stress field states of crustal blocks before and after the December 26, 2004 Ms9.0 Sumatra earthquake and the 2008 Ms8.0 Wenchuan earthquake. The ratio of thrust-type earthquakes in the Sichnan-Qinghai block was on the higher side in the period from 2006 to 2007, and the source faulting type of the regional moderate and small earthquakes had changed before the Ms8.0 Wenchnan earthquake. The change of state of the stress field is consistent with the changes in block displacement fields revealed by GPS data and the crustal shortening velocity vertical to the Longmenshan fault zone. Based on the radiation energy calculated from all bands of the seismic waveform, the value of apparent stress σapp is obtained. The fluctuation shape of the fitting trend of the apparent stress is related to the intensity of regional seismicity. It reveals that the micro- dynamic fluctuation process of the regional stress value is similar to the azimuth transition of the regional principal compressive stress field, which can be used to probe for pregnant physical processes. Areas with a higher value of apparent stress σapp are possible areas of potential seismic risk. It can be seen from the spatial distribution of the medium and shortterm apparent stress σapp before the Ms8.0 Wenchuan earthquake, the Longmenshan fault zone is in a low stress distribution area, and the relatively high apparent stress is in the peripheral area. These images may show medium and short-term locking phenomena near the seismogenic tectonics of the Ms8.0 Wenchuan earthquake. For example, changes with time of the focal parameter consistency of the sub-blocks in Sichuan and Yunnan Provinces, continual increase of thrust-type earthquakes in the Sichuan-Qinghai block and the appearance of spatial distribution areas of high apparent σapp stress. The work on this aspect was continued after the Ms8.0 Wenchuan earthquake, and the results seem to be shown a clearer relationship between these phenomena and future great earthquakes.展开更多
Metal organic chenlical vapor deposition （AIOCVD） growth systems arc one of the. main types of equipment used for growing single crystal materials, such as GaN. To obtain fihn epitaxial materials with uniform perfor...Metal organic chenlical vapor deposition （AIOCVD） growth systems arc one of the. main types of equipment used for growing single crystal materials, such as GaN. To obtain fihn epitaxial materials with uniform performanee, the flow field and ternperature field in a GaN-MOCVD reactor are investigated by modeling and simulating. To make the simulation results more consistent with the actual situation, the gases in the reactor are considered to be compressible, making it possible to investigate the distributions of gas density and pressure in the reactor. The computational fluid dynamics method is used to stud,v the effects of inlet gas flow velocity, pressure in the reactor, rotational speed of graphite susceptor, and gases used in the growth, which has great guiding~ significance for the growth of GaN fihn materials.展开更多
In order to effectively control the stress and distortion which produced in welding process, the dynamic change laws of displacement field is the most important factor. The characteristics of the welding dynamic displ...In order to effectively control the stress and distortion which produced in welding process, the dynamic change laws of displacement field is the most important factor. The characteristics of the welding dynamic displacement field is high temperature, high strain velocity, thus ordinary methods such as resistance strain gauge or Moiré method can not be used for the measurement of the zone of high temperature. Speckle interference method has the merits of non-contact, resistance to the disturbance of impure lights, high accuracy of measurement (half of wavelength).The paper represents the measurement of dynamic displacement field of argon-arcspot welding, by which it shows that the method of speckle interference is feasible for the measurement of welding dynamic displacement.展开更多
We have studied the dynamics and transfer of the entanglement of the two identical atoms simultaneously interacting with vacuum field by employing the dressed-state representation. The two atoms are driven by classica...We have studied the dynamics and transfer of the entanglement of the two identical atoms simultaneously interacting with vacuum field by employing the dressed-state representation. The two atoms are driven by classical fields. The influence of the initial entanglement degree of two atoms, the coupling strength between the atom and the classical field and the detuning between the atomic transition frequency and the frequency of classical field on the entanglement and atomic linear entropy is discussed. The initial entanglement of the two atoms can be transferred into the entanglement between the atom and cavity field when the dissipation is neglected. The maximally entangled state between the atoms and cavity field can be obtained under some certain conditions. The time of disentanglement of two atoms can be controlled and manipulated by adjusting the detuning and classical driving fields. Moreover, the larger the cavity decay rate is, the more quickly the entanglement of the two atoms decays.展开更多
Instantaneous flow field and temperature field of the two-phase fluid are measured by particle image velocimetry （PIV） and steady state method during the state of onflow. A turbulent two-phase fluid model of stirred...Instantaneous flow field and temperature field of the two-phase fluid are measured by particle image velocimetry （PIV） and steady state method during the state of onflow. A turbulent two-phase fluid model of stirred bioreactor with punched impeller is established by the computational fluid dynamics （CFD）, using a rotating coordinate system and sliding mesh to describe the relative motion between impeller and baffles. The simulation and experiment results of flow and temperature field prove their warps are less than 10% and the mathematic model can well simulate the fields, which will also provide the study on optimized-design and scale-up of bioreactors with reference value.展开更多
The generalized rheological tests on sandstone were conducted under both dynamic stress and seepage fields.The results demonstrate that the rheological strain of the specimen under increased stress conditions is great...The generalized rheological tests on sandstone were conducted under both dynamic stress and seepage fields.The results demonstrate that the rheological strain of the specimen under increased stress conditions is greater than that under creep conditions,indicating that the dynamic stress field significantly influences the rheological behaviours of sandstone.Following the rheological tests,the number of small pores in the sandstone decreased,while the number of medium-sized pores increased,forming new seepage channels.The high initial rheological stress accelerated fracture compression and the closure of seepage channels,resulting in reduction in the permeability of sandstone.Based on the principles of generalized rheology and the experimental findings,a novel rock rheological constitutive model incorporating both the dynamic stress field and seepage properties has been developed.Numerical simulations of surrounding rock deformation in geotechnical engineering were carried out using a secondary development version of this model,which confirmed the applicability of the generalized rheological numerical simulation method.These results provide theoretical support for the long-term stability evaluation of engineering rock masses and for predicting the deformation of surrounding rock.展开更多
We investigate the interplay between the pseudogap state and d-wave superconductivity in the two-dimensional doped Hubbard model by employing an eight-site cluster dynamical mean-field theory method.By tuning electron...We investigate the interplay between the pseudogap state and d-wave superconductivity in the two-dimensional doped Hubbard model by employing an eight-site cluster dynamical mean-field theory method.By tuning electron hopping parameters,the strong-coupling pseudogap in the two-dimensional Hubbard model can be either enhanced or suppressed in the doped Mott insulator regime.We find that in underdoped cases,the closing of pseudogap leads to a significant enhancement of superconductivity,indicating competition between the two in the underdoped regime.In contrast,at large dopings,suppressing the pseudogap is accompanied by a concurrent decrease in the superconducting transition temperature Tc,which can be attributed to a reduction in antiferromagnetic correlations behind both the pseudogap and superconductivity.We elucidate this evolving relationship between pseudogap and superconductivity across different doping regimes.展开更多
Batteries power numerous technolo-gies,yet higher energy density de-mands push lithium cobalt oxide(Li-CoO_(2)referred as LCO)cathodes to higher voltages,triggering unwanted chemical reactions.In this work,we in-vesti...Batteries power numerous technolo-gies,yet higher energy density de-mands push lithium cobalt oxide(Li-CoO_(2)referred as LCO)cathodes to higher voltages,triggering unwanted chemical reactions.In this work,we in-vestigate how carbonate-based elec-trolytes degrade on deeply delithiated LCO surfaces via extensive reactive molecular dynamics simulations.These simulations unveil the forma-tion of characteristic gas products and unstable surface species,which can undermine the cathode structure and reduce battery performance.By examining different solvent composi-tions,the simulations reveal that partial fluorination reduces oxidative degradation and gas evolution,thus offering a route to improve interface stability.Overall,this study provides an atomic-level perspective on preventing unwanted reactions and guiding the design of safer and more robust battery systems for high-voltage applications.展开更多
The discovery and large-scale exploration of unconventional oil/gas resources since 1980s have been considered as the most important advancement in the history of petroleum geology;that has not only changed the balanc...The discovery and large-scale exploration of unconventional oil/gas resources since 1980s have been considered as the most important advancement in the history of petroleum geology;that has not only changed the balance of supply and demand in the global energy market,but also improved our understanding of the formation mechanisms and distribution characteristics of oil/gas reservoirs.However,what is the difference of conventional and unconventional resources and why they always related to each other in petroliferous basins is not clear.As the differences and correlations between unconventional and conventional resources are complex challenging issues and very critical for resources assessment and hydrocarbon exploration,this paper focused on studying the relationship of formations and distributions among different oil/gas reservoirs.Drilling results of 12,237 exploratory wells in 6 representative petroliferous basins of China and distribution characteristics for 52,926 oil/gas accumulations over the world were applied to clarify the formation conditions and genetic relations of different oil/gas reservoirs in a petroliferous basin,and then to establish a unified model to address the differences and correlations of conventional and unconventional reservoirs.In this model,conventional reservoirs formed in free hydrocarbon dynamic field with high porosity and permeability located above the boundary of hydrocarbon buoyancy-driven accumulation depth limit.Unconventional tight reservoirs formed in confined hydrocarbon dynamic field with low porosity and permeability located between hydrocarbon buoyancy-driven accumulation depth limit and hydrocarbon accumulation depth limit.Shale oil/gas reservoirs formed in the bound hydrocarbon dynamic field with low porosity and ultra-low permeability within the source rock layers.More than 75%of proved reserves around the world are discovered in the free hydrocarbon dynamic field,which is estimated to contain only 10%of originally generated hydrocarbons.Most of undiscovered resources distributed in the confined hydrocarbon dynamic field and the bound hydrocarbon dynamic field,which contains 90%of original generated hydrocarbons,implying a reasonable and promising area for future hydrocarbon explorations.The buried depths of hydrocarbon dynamic fields become shallow with the increase of heat flow,and the remaining oil/gas resources mainly exist in the deep area of“cold basin”with low geothermal gradient.Lithology changing in the hydrocarbon dynamic field causes local anomalies in the oil/gas dynamic mechanism,leading to the local formation of unconventional hydrocarbon reservoirs in the free hydrocarbon dynamic field or the occurrence of oil/gas enrichment sweet points with high porosity and permeability in the confined hydrocarbon dynamic field.The tectonic movements destroy the medium conditions and oil/gas components,which leads to the transformation of conventional oil/gas reservoirs formed in free hydrocarbon dynamic field to unconventional ones or unconventional ones formed in confined and bound hydrocarbon dynamic fields to conventional ones.展开更多
Hydrocarbon distribution rules in the deep and shallow parts of sedimentary basins are considerably different, particularly in the following four aspects. First, the critical porosity for hydrocarbon migration is much...Hydrocarbon distribution rules in the deep and shallow parts of sedimentary basins are considerably different, particularly in the following four aspects. First, the critical porosity for hydrocarbon migration is much lower in the deep parts of basins： at a depth of 7000 m, hydrocarbons can accumulate only in rocks with porosity less than 5%. However, in the shallow parts of basins （i.e., depths of around 1000 m）, hydrocarbon can accumulate in rocks only when porosity is over 20%. Second, hydrocarbon reservoirs tend to exhibit negative pressures after hydrocarbon accumulation at depth, with a pressure coefficient less than 0.7. However, hydrocarbon reservoirs at shallow depths tend to exhibit high pressure after hydrocarbon accumulation. Third, deep reservoirs tend to exhibit characteristics of oil （-gas）-water inversion, indicating that the oil （gas） accumulated under the water. However, the oil （gas） tends to accumulate over water in shallow reservoirs. Fourth, continuous unconventional tight hydrocarbon reservoirs are distributed widely in deep reservoirs, where the buoyancy force is not the primary dynamic force and the caprock is not involved during the process of hydrocarbon accumulation. Conversely, the majority of hydrocarbons in shallow regions accumulate in traps with complex structures. The results of this study indicate that two dynamic boundary conditions are primarily responsible for the above phenomena： a lower limit to the buoyancy force and the lower limit of hydrocarbon accumulation overall, corresponding to about 10%-12% porosity and irreducible water saturation of 100%, respectively. These two dynamic boundary conditions were used to divide sedimentary basins into three different dynamic fields of hydrocarbon accumulation： the free fluid dynamic field, limit fluid dynamic field, and restrain fluid dynamic field. The free fluid dynamic field is located between the surface and the lower limit of the buoyancy force, such that hydrocarbons in this field migrate and accumulate under the influence of, for example, the buoyancy force, pressure, hydrodynamic force, and capillary force. The hydrocarbon reservoirs formed are characterized as ＂four high,＂ indicating that they accumulate in high structures, are sealed in high locations, migrate into areas of high porosity, and are stored in reservoirs at high pressure. The basic features of distribution and accumulation in this case include hydrocarbon migration as a result of the buoyancy force and formation of a reservoir by a caprock. The limit fluid dynamic field is located between the lower limit of the buoyancy force and the lower limit of hydrocarbon accumulation overall; the hydrocarbon migrates and accumulates as a result of, for example, the molecular expansion force and the capillary force. The hydrocarbon reservoirs formed are characterized as ＂four low,＂ indicating that hydrocarbons accumulate in low structures, migrate into areas of low porosity, and accumulate in reservoirs with low pressure, and that oil（-gas）-water inversion occurs at low locations. Continuous hydrocarbon accumulation over a large area is a basic feature of this field. The restrain fluid dynamic field is located under the bottom of hydrocarbon accumulation, such that the entire pore space is filled with water. Hydrocarbons migrate as a result of the molecular diffusion force only. This field lacks many of the basic conditions required for formation of hydrocarbon reservoirs： there is no effective porosity, movable fluid, or hydrocarbon accumulation, and potential for hydrocarbon exploration is low. Many conventional hydrocarbon resources have been discovered and exploited in the free fluid dynamic field of shallow reservoirs, where exploration potential was previously considered to be low. Continuous unconventional tight hydrocarbon resources have been discovered in the limit fluid dynamic field of deep reservoirs; the exploration potential of this setting is thought to be tremendous, indicating that future exploration should be focused primarily in this direction.展开更多
With the raise of voltage level in electric power grid,the phenomena of high voltage gas insulation has received extensive attention from all over the world.The research on the breakdown mechanism of vacuum which is t...With the raise of voltage level in electric power grid,the phenomena of high voltage gas insulation has received extensive attention from all over the world.The research on the breakdown mechanism of vacuum which is the main insulation gas in high voltage level is one of the most important issues.It is also important to the study of vacuum arc in vacuum switch.But for the limitations of available method used in analyzing the breakdown mechanism of vacuum,the main research on vacuum breakdown is macroscopic experiment.The experiments are greatly influenced by environmental factors and high vacuum degree is difficult to be ensured.So the data from the experiments are dispersive and the complex physical change in vacuum breakdown can not be revealed.The purpose of this work is to analyze the mechanism of vacuum breakdown quantitatively by microscopic numerical simulation.The particle in cell and Monte Carlo methods are used here to solve microscopic dynamic equation of gas.Based on the field emission theory in vacuum,electrons produced by the cathode and ions produced by the collision between electron and metal vapor molecule are the objects of this study.The motions of microscopic particles which are at the functions of the applied and self-consistent electric filed are traced in time and two space dimensions.Mont Carlo method is used here to cope with the collisions between electrons and metal vapor molecules.The cross sections of the collision which is related with the energy are all from the experiments.The secondary electron emission,exciting,elastic and ionizing collisions between electrons and metal vapor molecules have been considered in this paper.By the simulation,the number densities of electron and ion are acquired and the microscopic dynamic electric field produced by space charge is also calculated. The effect of vacuum degree on discharge voltage is also discussed here.According to the simulation data,we draw the conclusion that the main reason for vacuum arc formation is metal vapor ionization and large amount of metal gas is from high energy electrons' collision with the anode.展开更多
Mud pumping in subgrade beds under ballastless tracks will deteriorate the dynamic performance of infrastructure under railway lines,reduce the smoothness of the railway lines,and seriously affect the comfort and safe...Mud pumping in subgrade beds under ballastless tracks will deteriorate the dynamic performance of infrastructure under railway lines,reduce the smoothness of the railway lines,and seriously affect the comfort and safety of the trains.Due to their good mechanical properties,twocomponent polyurethane materials can be used for grouting to treat the fouling problems caused by ballastless track mud pumping.To develop a polyurethane formula suitable for the treatment of ballastless track mud pumping,we first performed indoor experiments to investigate the mechanical properties and gelation time of polyurethane elastomers synthesized with different raw material composition ratios,to determine an optimal composition ratio of the raw materials.Then,we conducted a dynamic field test to verify the remediation effect of the polyurethane material fabricated according to the design ratio.The results showed that polyurethane grouting material with the selected design ratios improved the contact characteristics between the surface layer of the subgrade bed and the base plate in the area,coordinating the dynamic response between the track structure and the subgrade bed.Thus,the obtained polyurethane grouting material could be used to renovate mud pumping areas of ballastless tracks with a good treatment effect.展开更多
A combination of the iterative perturbation theory （ITP） of the dynamical mean field theory （DMFT） and coherentpotential approximation （CPA） is generalized to the double exchange model with orbital degeneracy. T...A combination of the iterative perturbation theory （ITP） of the dynamical mean field theory （DMFT） and coherentpotential approximation （CPA） is generalized to the double exchange model with orbital degeneracy. The Hubbard interaction and the off-diagonal components for the hopping matrix tij^mn（m ≠ n） are considered in our calculation of spectrum and optical conductivity. The numerical results show that the effects of the non-diagonal hopping matrix elements are important.展开更多
We investigate the effect of interaction, temperature, and anisotropic parameter on the quantum phase transitions in an anisotropic square-octagon lattice with fermions under the framework of the single band Hubbard m...We investigate the effect of interaction, temperature, and anisotropic parameter on the quantum phase transitions in an anisotropic square-octagon lattice with fermions under the framework of the single band Hubbard model through using the combination of cellular dynamical mean field theory and a continuous time Monte Carlo algorithm. The competition between interaction and temperature shows that with the increase of the anisotropic parameter, the critical on-site repulsive interaction for the metal-insulator transition increases for fixed temperature. The interaction-anisotropic parameter phase diagram reveals that with the decrease of temperature, the critical anisotropic parameter for the Mott transition will increase for fixed interaction cases.展开更多
The hydrodynamic performance of a three-dimensional finite-length rotating cylinder is studied by means of a physical tank and numerical simulation.First,according to the identified influencing factors,a hydrodynamic ...The hydrodynamic performance of a three-dimensional finite-length rotating cylinder is studied by means of a physical tank and numerical simulation.First,according to the identified influencing factors,a hydrodynamic performance test of the rotating cylinder was carried out in a circulating water tank.In order to explore the changing law of hydrodynamic performance with these factors,a particle image velocimetry device was used to monitor the flow field.Subsequently,a computational field dynamics numerical simulation method was used to simulate the flow field,followed by an analysis of the effects of speed ratio,Reynolds number,and aspect ratio on the flow field.The results show that the lift coefficient and drag coefficient of the cylinder increase first and then decrease with the increase of the rotational speed ratio.The trend of numerical simulation and experimental results is similar.展开更多
Biomass chemical looping gasification technology is one of the essential ways to utilize abundant biomass resources.At the same time,dimethyl carbonate can replace phosgene as an environmentfriendly organic material f...Biomass chemical looping gasification technology is one of the essential ways to utilize abundant biomass resources.At the same time,dimethyl carbonate can replace phosgene as an environmentfriendly organic material for the synthesis of polycarbonate.In this paper,a novel system coupling biomass chemical looping gasification with dimethyl carbonate synthesis with methanol as an intermediate is designed through microscopic mechanism analysis and process optimization.Firstly,reactive force field molecular dynamics simulation is performed to explore the reaction mechanism of biomass chemical looping gasification to determine the optimal gasification temperature range.Secondly,steady-state simulations of the process based on molecular dynamics simulation results are carried out to investigate the effects of temperature,steam to biomass ratio,and oxygen carrier to biomass ratio on the syngas yield and compositions.In addition,the main energy indicators of biomass chemical looping gasification process including lower heating value and cold gas efficiency are analyzed based on the above optimum parameters.Then,two synthesis stages are simulated and optimized with the following results obtained:the optimal temperature and pressure of methanol synthesis stage are 150℃ and 4 MPa;the optimal temperature and pressure of dimethyl carbonate synthesis stage are 140℃ and 0.3 MPa.Finally,the pre-separation-extraction-decantation process separates the mixture of dimethyl carbonate and methanol generated in the synthesis stage with 99.11%purity of dimethyl carbonate.Above results verify the feasibility of producing dimethyl carbonate from the perspective of multi-scale simulation and realize the multi-level utilization of biomass resources.展开更多
We discuss quantum fluctuation in excited states （named thermo number states） of mesoscopic LC circuits at a finite temperature. By introducing the coherent thermo state into the thermo field dynamics pioneered by U...We discuss quantum fluctuation in excited states （named thermo number states） of mesoscopic LC circuits at a finite temperature. By introducing the coherent thermo state into the thermo field dynamics pioneered by Umezawa and using the natural representation of thermo squeezing operator we can concisely derive the fluctuation. The result shows that the noise becomes larger when either temperature or the excitation number increases.展开更多
基金Supported by the National Basic Research Program of China under Grant No 2013CB922201the National Natural Science Foundation of China under Grant Nos 11304365,11374329 and 11334009
文摘We experimentally investigate the double ionization pulses. The total kinetic energy release of the two of molecular hydrogen subjected to ultrashort intense laser coincident H＋ ions, which provides a diagnosis of different processes to double ionization of H2, is measured for two different pulse durations, i.e., 25 and 5 fs, and various laser intensities. It is found that, for the long pulse duration （i.e., 25 fs）, the double ionization occurs mainly via two processes, i.e., the charge resonance enhanced ionization and recollision-induced double ionization. Moreover, the contributions from these two processes can be significantly modulated by changing the laser intensity. In contrast, for a few-cycle pulse of 5 fs, only the recollsion-induced double ionization survives, and in particular, this process could be solely induced by the first-return reeollision at appropriate laser intensities, providing an efficient way to probe the sub-laser-cycle molecular dynamics.
基金supported by Projects 12325501,12047503,12247104,and 12322501 of the National Natural Science Foundation of ChinaProject ZDRW-XX-2022-302 of the Chinese Academy of Sciencespartially supported by the Innovation Program for Quantum Science and Technology project 2021ZD0301900。
文摘Combinatorial optimization problems and ground state problems of spin glasses are crucial in various fields of science and technology.However,they often belong to the computational class of NP-hard,presenting significant computational challenges.Traditional algorithms inspired by statistical physics like simulated annealing have been widely adopted.Recently,advancements in Ising machines,such as quantum annealers and coherent Ising machines,offer new paradigms for solving these problems efficiently by embedding them into the analog evolution of nonlinear dynamical systems.However,existing dynamics-based algorithms often suffer from low convergence rates and local minima traps.In this work,we introduce the dual mean-field dynamics into Ising machines.The approach integrates the gradient force and the transverse force into the dynamics of Ising machines in solving combinatorial optimization problems,making it easier for the system to jump out of the local minimums and allowing the dynamics to explore wider in configuration space.We conduct extensive numerical experiments using the Sherrington–Kirkpatrick spin glass up to 10000 spins and the maximum cut problems with the standard G-set benchmarks.The numerical results demonstrate that our dual mean-field dynamics approach enhances the performance of base Ising machines,providing a more effective solution for large-scale combinatorial optimization problems.
基金supported by the NUDT Science Foundation for Indigenous Innovation(Grant No.24-ZZCX-ZXGC-15)the National Natural Science Foundation of China(Grant Nos.12234020,12450403,and 12374263)。
文摘We demonstrate an all-optical technique for in situ monitoring of strong-field ionization(SFI)dynamics.The method relies on coherent scattering of a probe pulse from a transient plasma grating(TPG)formed by two interfering femtosecond pulses in a gas target.The diffracted signal provides a real-time,relative measure of the ionization yield.We demonstrate the method’s sensitivity by resolving the attosecond-scale coherent control of the ionization rate.Unlike conventional diagnostics that directly measure charged particles,our ensemble-based optical method is non-invasive and particularly suited for non-vacuum environments.To demonstrate its utility,we apply the technique to investigate the relationship between ionization and terahertz(THz)generation in a two-color(ω+2ω)field.We measure a phase offset of(0.18±0.05)π between the maxima of the ionization yield and the THz emission.This result provides a quantitative benchmark for theoretical models and establishes the TPG technique as a practical tool for probing SFI dynamics in ensemble systems.
基金Scientific and Technology project(200808053)National Key Basic Research 973b project support
文摘Using the digital telemetric seismic waveform data of Chengdu and Kunming, this article studies the focal mechanism solutions and the apparent stress values of a large number of small earthquakes, and then analyzes the dynamic variation of regional stress fields and the spatio- temporal distribution of apparent stress values. The annual variation values of the azimuth of average principal stress field before the May 12, 2008 Ms8.0 Wenchuan earthquake in the Sichuan-Yunnan region were 58° from 2003 to 2004, 85° from 2003 to 2005,61° from 2006 to 2007 and 90° from 2006 to April 2008 respectively. In recent years, deflection or disturbances occurred in the azimuth of the average principal stress field in the Sichuan-Yunnan region. Analysis shows that this may be related to the change of stress field states of crustal blocks before and after the December 26, 2004 Ms9.0 Sumatra earthquake and the 2008 Ms8.0 Wenchuan earthquake. The ratio of thrust-type earthquakes in the Sichnan-Qinghai block was on the higher side in the period from 2006 to 2007, and the source faulting type of the regional moderate and small earthquakes had changed before the Ms8.0 Wenchnan earthquake. The change of state of the stress field is consistent with the changes in block displacement fields revealed by GPS data and the crustal shortening velocity vertical to the Longmenshan fault zone. Based on the radiation energy calculated from all bands of the seismic waveform, the value of apparent stress σapp is obtained. The fluctuation shape of the fitting trend of the apparent stress is related to the intensity of regional seismicity. It reveals that the micro- dynamic fluctuation process of the regional stress value is similar to the azimuth transition of the regional principal compressive stress field, which can be used to probe for pregnant physical processes. Areas with a higher value of apparent stress σapp are possible areas of potential seismic risk. It can be seen from the spatial distribution of the medium and shortterm apparent stress σapp before the Ms8.0 Wenchuan earthquake, the Longmenshan fault zone is in a low stress distribution area, and the relatively high apparent stress is in the peripheral area. These images may show medium and short-term locking phenomena near the seismogenic tectonics of the Ms8.0 Wenchuan earthquake. For example, changes with time of the focal parameter consistency of the sub-blocks in Sichuan and Yunnan Provinces, continual increase of thrust-type earthquakes in the Sichuan-Qinghai block and the appearance of spatial distribution areas of high apparent σapp stress. The work on this aspect was continued after the Ms8.0 Wenchuan earthquake, and the results seem to be shown a clearer relationship between these phenomena and future great earthquakes.
基金Supported by the National Key R&D Program of China under Grant No 2016YFB0400104
文摘Metal organic chenlical vapor deposition （AIOCVD） growth systems arc one of the. main types of equipment used for growing single crystal materials, such as GaN. To obtain fihn epitaxial materials with uniform performanee, the flow field and ternperature field in a GaN-MOCVD reactor are investigated by modeling and simulating. To make the simulation results more consistent with the actual situation, the gases in the reactor are considered to be compressible, making it possible to investigate the distributions of gas density and pressure in the reactor. The computational fluid dynamics method is used to stud,v the effects of inlet gas flow velocity, pressure in the reactor, rotational speed of graphite susceptor, and gases used in the growth, which has great guiding~ significance for the growth of GaN fihn materials.
文摘In order to effectively control the stress and distortion which produced in welding process, the dynamic change laws of displacement field is the most important factor. The characteristics of the welding dynamic displacement field is high temperature, high strain velocity, thus ordinary methods such as resistance strain gauge or Moiré method can not be used for the measurement of the zone of high temperature. Speckle interference method has the merits of non-contact, resistance to the disturbance of impure lights, high accuracy of measurement (half of wavelength).The paper represents the measurement of dynamic displacement field of argon-arcspot welding, by which it shows that the method of speckle interference is feasible for the measurement of welding dynamic displacement.
基金Supported by National Natural Science Foundation of China under Grant Nos.11247213,61368002,11304010,11264030,61168001China Postdoctoral Science Foundation under Grant No.2013M531558+4 种基金Jiangxi Postdoctoral Research Project under Grant No.2013KY33the Natural Science Foundation of Jiangxi Province under Grant No.20142BAB217001the Foundation for Young Scientists of Jiangxi Province(Jinggang Star)under Grant No.20122BCB23002the Research Foundation of the Education Department of Jiangxi Province under Grant Nos.GJJ13051,GJJ13057the Graduate Innovation Special Fund of Nanchang University under Grant No.cx2015137
文摘We have studied the dynamics and transfer of the entanglement of the two identical atoms simultaneously interacting with vacuum field by employing the dressed-state representation. The two atoms are driven by classical fields. The influence of the initial entanglement degree of two atoms, the coupling strength between the atom and the classical field and the detuning between the atomic transition frequency and the frequency of classical field on the entanglement and atomic linear entropy is discussed. The initial entanglement of the two atoms can be transferred into the entanglement between the atom and cavity field when the dissipation is neglected. The maximally entangled state between the atoms and cavity field can be obtained under some certain conditions. The time of disentanglement of two atoms can be controlled and manipulated by adjusting the detuning and classical driving fields. Moreover, the larger the cavity decay rate is, the more quickly the entanglement of the two atoms decays.
基金This project is supported by Provincial Science Technology Committee of Jiangsu China(No.BJ99025).
文摘Instantaneous flow field and temperature field of the two-phase fluid are measured by particle image velocimetry （PIV） and steady state method during the state of onflow. A turbulent two-phase fluid model of stirred bioreactor with punched impeller is established by the computational fluid dynamics （CFD）, using a rotating coordinate system and sliding mesh to describe the relative motion between impeller and baffles. The simulation and experiment results of flow and temperature field prove their warps are less than 10% and the mathematic model can well simulate the fields, which will also provide the study on optimized-design and scale-up of bioreactors with reference value.
基金supported and financed by Scientific Research Foundation for High-level Talents of Anhui University of Science and Technology (No.2024yjrc96)Anhui Provincial University Excellent Research and Innovation Team Support Project (No.2022AH010053)+2 种基金National Key Research and Development Program of China (Nos.2023YFC2907602 and 2022YFF1303302)Anhui Provincial Major Science and Technology Project (No.202203a07020011)Open Foundation of Joint National-Local Engineering Research Centre for Safe and Precise Coal Mining (No.EC2023020)。
文摘The generalized rheological tests on sandstone were conducted under both dynamic stress and seepage fields.The results demonstrate that the rheological strain of the specimen under increased stress conditions is greater than that under creep conditions,indicating that the dynamic stress field significantly influences the rheological behaviours of sandstone.Following the rheological tests,the number of small pores in the sandstone decreased,while the number of medium-sized pores increased,forming new seepage channels.The high initial rheological stress accelerated fracture compression and the closure of seepage channels,resulting in reduction in the permeability of sandstone.Based on the principles of generalized rheology and the experimental findings,a novel rock rheological constitutive model incorporating both the dynamic stress field and seepage properties has been developed.Numerical simulations of surrounding rock deformation in geotechnical engineering were carried out using a secondary development version of this model,which confirmed the applicability of the generalized rheological numerical simulation method.These results provide theoretical support for the long-term stability evaluation of engineering rock masses and for predicting the deformation of surrounding rock.
基金supported by the National Natural Science Foundation of China(Grant Nos.12274472,12494594,12494591,and 92165204)National Key Research and Development Program of China(Grant No.2022YFA1402802)+2 种基金Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices(Grant No.2022B1212010008)Guangdong Fundamental Research Center for Magnetoelectric Physics(Grant No.2024B0303390001)Guangdong Provincial Quantum Science Strategic Initiative(Grant No.GDZX2401010)。
文摘We investigate the interplay between the pseudogap state and d-wave superconductivity in the two-dimensional doped Hubbard model by employing an eight-site cluster dynamical mean-field theory method.By tuning electron hopping parameters,the strong-coupling pseudogap in the two-dimensional Hubbard model can be either enhanced or suppressed in the doped Mott insulator regime.We find that in underdoped cases,the closing of pseudogap leads to a significant enhancement of superconductivity,indicating competition between the two in the underdoped regime.In contrast,at large dopings,suppressing the pseudogap is accompanied by a concurrent decrease in the superconducting transition temperature Tc,which can be attributed to a reduction in antiferromagnetic correlations behind both the pseudogap and superconductivity.We elucidate this evolving relationship between pseudogap and superconductivity across different doping regimes.
基金support from the National Key Research and Development Program of China(No.2022YFB2502200)the Natural Science Foun-dation of Jiangsu Province(BK20230065)+2 种基金the Key Laboratory of Functional Nano&Soft Materials,the Collaborative Innovation Center of Suzhou Nano Sci-ence&Technology,the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the 111 Project,Joint International Research Laboratory of Carbon-Based Functional Materials and Devices,Yue Liu acknowledges support from the National Natural Science Foundation of China(22303058)the Natural Science Foundation of Jiangsu Province(BK20230475).
文摘Batteries power numerous technolo-gies,yet higher energy density de-mands push lithium cobalt oxide(Li-CoO_(2)referred as LCO)cathodes to higher voltages,triggering unwanted chemical reactions.In this work,we in-vestigate how carbonate-based elec-trolytes degrade on deeply delithiated LCO surfaces via extensive reactive molecular dynamics simulations.These simulations unveil the forma-tion of characteristic gas products and unstable surface species,which can undermine the cathode structure and reduce battery performance.By examining different solvent composi-tions,the simulations reveal that partial fluorination reduces oxidative degradation and gas evolution,thus offering a route to improve interface stability.Overall,this study provides an atomic-level perspective on preventing unwanted reactions and guiding the design of safer and more robust battery systems for high-voltage applications.
基金the Joint Fund of the National Natural Science Foundation of China under funding number of U19B6003-02-04the fund of A Theoretical Study of Marine Petroliferous System,Sichuan Basin,and the Science Foundation of China University of Petroleum,Beijing under funding number of 2462020BJRC005.
文摘The discovery and large-scale exploration of unconventional oil/gas resources since 1980s have been considered as the most important advancement in the history of petroleum geology;that has not only changed the balance of supply and demand in the global energy market,but also improved our understanding of the formation mechanisms and distribution characteristics of oil/gas reservoirs.However,what is the difference of conventional and unconventional resources and why they always related to each other in petroliferous basins is not clear.As the differences and correlations between unconventional and conventional resources are complex challenging issues and very critical for resources assessment and hydrocarbon exploration,this paper focused on studying the relationship of formations and distributions among different oil/gas reservoirs.Drilling results of 12,237 exploratory wells in 6 representative petroliferous basins of China and distribution characteristics for 52,926 oil/gas accumulations over the world were applied to clarify the formation conditions and genetic relations of different oil/gas reservoirs in a petroliferous basin,and then to establish a unified model to address the differences and correlations of conventional and unconventional reservoirs.In this model,conventional reservoirs formed in free hydrocarbon dynamic field with high porosity and permeability located above the boundary of hydrocarbon buoyancy-driven accumulation depth limit.Unconventional tight reservoirs formed in confined hydrocarbon dynamic field with low porosity and permeability located between hydrocarbon buoyancy-driven accumulation depth limit and hydrocarbon accumulation depth limit.Shale oil/gas reservoirs formed in the bound hydrocarbon dynamic field with low porosity and ultra-low permeability within the source rock layers.More than 75%of proved reserves around the world are discovered in the free hydrocarbon dynamic field,which is estimated to contain only 10%of originally generated hydrocarbons.Most of undiscovered resources distributed in the confined hydrocarbon dynamic field and the bound hydrocarbon dynamic field,which contains 90%of original generated hydrocarbons,implying a reasonable and promising area for future hydrocarbon explorations.The buried depths of hydrocarbon dynamic fields become shallow with the increase of heat flow,and the remaining oil/gas resources mainly exist in the deep area of“cold basin”with low geothermal gradient.Lithology changing in the hydrocarbon dynamic field causes local anomalies in the oil/gas dynamic mechanism,leading to the local formation of unconventional hydrocarbon reservoirs in the free hydrocarbon dynamic field or the occurrence of oil/gas enrichment sweet points with high porosity and permeability in the confined hydrocarbon dynamic field.The tectonic movements destroy the medium conditions and oil/gas components,which leads to the transformation of conventional oil/gas reservoirs formed in free hydrocarbon dynamic field to unconventional ones or unconventional ones formed in confined and bound hydrocarbon dynamic fields to conventional ones.
基金supported by the National Basic Research Program of China (Grant No: 2011CB201100)
文摘Hydrocarbon distribution rules in the deep and shallow parts of sedimentary basins are considerably different, particularly in the following four aspects. First, the critical porosity for hydrocarbon migration is much lower in the deep parts of basins： at a depth of 7000 m, hydrocarbons can accumulate only in rocks with porosity less than 5%. However, in the shallow parts of basins （i.e., depths of around 1000 m）, hydrocarbon can accumulate in rocks only when porosity is over 20%. Second, hydrocarbon reservoirs tend to exhibit negative pressures after hydrocarbon accumulation at depth, with a pressure coefficient less than 0.7. However, hydrocarbon reservoirs at shallow depths tend to exhibit high pressure after hydrocarbon accumulation. Third, deep reservoirs tend to exhibit characteristics of oil （-gas）-water inversion, indicating that the oil （gas） accumulated under the water. However, the oil （gas） tends to accumulate over water in shallow reservoirs. Fourth, continuous unconventional tight hydrocarbon reservoirs are distributed widely in deep reservoirs, where the buoyancy force is not the primary dynamic force and the caprock is not involved during the process of hydrocarbon accumulation. Conversely, the majority of hydrocarbons in shallow regions accumulate in traps with complex structures. The results of this study indicate that two dynamic boundary conditions are primarily responsible for the above phenomena： a lower limit to the buoyancy force and the lower limit of hydrocarbon accumulation overall, corresponding to about 10%-12% porosity and irreducible water saturation of 100%, respectively. These two dynamic boundary conditions were used to divide sedimentary basins into three different dynamic fields of hydrocarbon accumulation： the free fluid dynamic field, limit fluid dynamic field, and restrain fluid dynamic field. The free fluid dynamic field is located between the surface and the lower limit of the buoyancy force, such that hydrocarbons in this field migrate and accumulate under the influence of, for example, the buoyancy force, pressure, hydrodynamic force, and capillary force. The hydrocarbon reservoirs formed are characterized as ＂four high,＂ indicating that they accumulate in high structures, are sealed in high locations, migrate into areas of high porosity, and are stored in reservoirs at high pressure. The basic features of distribution and accumulation in this case include hydrocarbon migration as a result of the buoyancy force and formation of a reservoir by a caprock. The limit fluid dynamic field is located between the lower limit of the buoyancy force and the lower limit of hydrocarbon accumulation overall; the hydrocarbon migrates and accumulates as a result of, for example, the molecular expansion force and the capillary force. The hydrocarbon reservoirs formed are characterized as ＂four low,＂ indicating that hydrocarbons accumulate in low structures, migrate into areas of low porosity, and accumulate in reservoirs with low pressure, and that oil（-gas）-water inversion occurs at low locations. Continuous hydrocarbon accumulation over a large area is a basic feature of this field. The restrain fluid dynamic field is located under the bottom of hydrocarbon accumulation, such that the entire pore space is filled with water. Hydrocarbons migrate as a result of the molecular diffusion force only. This field lacks many of the basic conditions required for formation of hydrocarbon reservoirs： there is no effective porosity, movable fluid, or hydrocarbon accumulation, and potential for hydrocarbon exploration is low. Many conventional hydrocarbon resources have been discovered and exploited in the free fluid dynamic field of shallow reservoirs, where exploration potential was previously considered to be low. Continuous unconventional tight hydrocarbon resources have been discovered in the limit fluid dynamic field of deep reservoirs; the exploration potential of this setting is thought to be tremendous, indicating that future exploration should be focused primarily in this direction.
基金Supported by National Natural Science Foundation of China(50877048)Program for New Century Excellent Talents in University of China(NECT-08-0863)Key Scientific and Technological project of Liaoning Science and Technology Department (2010219016)
文摘With the raise of voltage level in electric power grid,the phenomena of high voltage gas insulation has received extensive attention from all over the world.The research on the breakdown mechanism of vacuum which is the main insulation gas in high voltage level is one of the most important issues.It is also important to the study of vacuum arc in vacuum switch.But for the limitations of available method used in analyzing the breakdown mechanism of vacuum,the main research on vacuum breakdown is macroscopic experiment.The experiments are greatly influenced by environmental factors and high vacuum degree is difficult to be ensured.So the data from the experiments are dispersive and the complex physical change in vacuum breakdown can not be revealed.The purpose of this work is to analyze the mechanism of vacuum breakdown quantitatively by microscopic numerical simulation.The particle in cell and Monte Carlo methods are used here to solve microscopic dynamic equation of gas.Based on the field emission theory in vacuum,electrons produced by the cathode and ions produced by the collision between electron and metal vapor molecule are the objects of this study.The motions of microscopic particles which are at the functions of the applied and self-consistent electric filed are traced in time and two space dimensions.Mont Carlo method is used here to cope with the collisions between electrons and metal vapor molecules.The cross sections of the collision which is related with the energy are all from the experiments.The secondary electron emission,exciting,elastic and ionizing collisions between electrons and metal vapor molecules have been considered in this paper.By the simulation,the number densities of electron and ion are acquired and the microscopic dynamic electric field produced by space charge is also calculated. The effect of vacuum degree on discharge voltage is also discussed here.According to the simulation data,we draw the conclusion that the main reason for vacuum arc formation is metal vapor ionization and large amount of metal gas is from high energy electrons' collision with the anode.
基金The authors gratefully acknowledge the financial support for this research by the National Natural Science Foundation of China(Grant Nos.51978588 and 52078434)。
文摘Mud pumping in subgrade beds under ballastless tracks will deteriorate the dynamic performance of infrastructure under railway lines,reduce the smoothness of the railway lines,and seriously affect the comfort and safety of the trains.Due to their good mechanical properties,twocomponent polyurethane materials can be used for grouting to treat the fouling problems caused by ballastless track mud pumping.To develop a polyurethane formula suitable for the treatment of ballastless track mud pumping,we first performed indoor experiments to investigate the mechanical properties and gelation time of polyurethane elastomers synthesized with different raw material composition ratios,to determine an optimal composition ratio of the raw materials.Then,we conducted a dynamic field test to verify the remediation effect of the polyurethane material fabricated according to the design ratio.The results showed that polyurethane grouting material with the selected design ratios improved the contact characteristics between the surface layer of the subgrade bed and the base plate in the area,coordinating the dynamic response between the track structure and the subgrade bed.Thus,the obtained polyurethane grouting material could be used to renovate mud pumping areas of ballastless tracks with a good treatment effect.
基金Project supported by the National Natural Science Foundation of China (Grant No 60476047)the Natural Science Foundation of Henan Province, China (Grant No 0411011700)
文摘A combination of the iterative perturbation theory （ITP） of the dynamical mean field theory （DMFT） and coherentpotential approximation （CPA） is generalized to the double exchange model with orbital degeneracy. The Hubbard interaction and the off-diagonal components for the hopping matrix tij^mn（m ≠ n） are considered in our calculation of spectrum and optical conductivity. The numerical results show that the effects of the non-diagonal hopping matrix elements are important.
基金supported by the National Natural Science Foundation of China(Grant Nos.11174169,11234007,and 51471093)
文摘We investigate the effect of interaction, temperature, and anisotropic parameter on the quantum phase transitions in an anisotropic square-octagon lattice with fermions under the framework of the single band Hubbard model through using the combination of cellular dynamical mean field theory and a continuous time Monte Carlo algorithm. The competition between interaction and temperature shows that with the increase of the anisotropic parameter, the critical on-site repulsive interaction for the metal-insulator transition increases for fixed temperature. The interaction-anisotropic parameter phase diagram reveals that with the decrease of temperature, the critical anisotropic parameter for the Mott transition will increase for fixed interaction cases.
基金Supported by the National Natural Science Foundation of China under Grant Nos. 51709060 and 51609030
文摘The hydrodynamic performance of a three-dimensional finite-length rotating cylinder is studied by means of a physical tank and numerical simulation.First,according to the identified influencing factors,a hydrodynamic performance test of the rotating cylinder was carried out in a circulating water tank.In order to explore the changing law of hydrodynamic performance with these factors,a particle image velocimetry device was used to monitor the flow field.Subsequently,a computational field dynamics numerical simulation method was used to simulate the flow field,followed by an analysis of the effects of speed ratio,Reynolds number,and aspect ratio on the flow field.The results show that the lift coefficient and drag coefficient of the cylinder increase first and then decrease with the increase of the rotational speed ratio.The trend of numerical simulation and experimental results is similar.
基金supported by the National Natural Science Foundation of China(22178189)the Natural Science Foundation of Shandong Province(ZR2021MB113)the Postdoctoral Science Foundation of China(2022M711746)。
文摘Biomass chemical looping gasification technology is one of the essential ways to utilize abundant biomass resources.At the same time,dimethyl carbonate can replace phosgene as an environmentfriendly organic material for the synthesis of polycarbonate.In this paper,a novel system coupling biomass chemical looping gasification with dimethyl carbonate synthesis with methanol as an intermediate is designed through microscopic mechanism analysis and process optimization.Firstly,reactive force field molecular dynamics simulation is performed to explore the reaction mechanism of biomass chemical looping gasification to determine the optimal gasification temperature range.Secondly,steady-state simulations of the process based on molecular dynamics simulation results are carried out to investigate the effects of temperature,steam to biomass ratio,and oxygen carrier to biomass ratio on the syngas yield and compositions.In addition,the main energy indicators of biomass chemical looping gasification process including lower heating value and cold gas efficiency are analyzed based on the above optimum parameters.Then,two synthesis stages are simulated and optimized with the following results obtained:the optimal temperature and pressure of methanol synthesis stage are 150℃ and 4 MPa;the optimal temperature and pressure of dimethyl carbonate synthesis stage are 140℃ and 0.3 MPa.Finally,the pre-separation-extraction-decantation process separates the mixture of dimethyl carbonate and methanol generated in the synthesis stage with 99.11%purity of dimethyl carbonate.Above results verify the feasibility of producing dimethyl carbonate from the perspective of multi-scale simulation and realize the multi-level utilization of biomass resources.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 10574060 and 10775097)the Natural Science Foundation of Shandong Province of China (Grant No. Y2008A23)the Shandong Province Higher Educational Science and Technology Program (Grant No. J09LA07)
文摘We discuss quantum fluctuation in excited states （named thermo number states） of mesoscopic LC circuits at a finite temperature. By introducing the coherent thermo state into the thermo field dynamics pioneered by Umezawa and using the natural representation of thermo squeezing operator we can concisely derive the fluctuation. The result shows that the noise becomes larger when either temperature or the excitation number increases.
