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Density of Liquid Ni-Mo Alloys Measured by a Modified Sessile Drop Method 被引量:4
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作者 LiangFANG ZushuLI +1 位作者 ZaiNanTAO FengXIAO 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2004年第3期287-292,共6页
The density of liquid binary Ni-Mo alloys with molybdenum concentration from 0 to 20% (mass fraction) wasmeasured by a modified sessile drop method. It has been found that the density of the liquid Ni-Mo alloys decrea... The density of liquid binary Ni-Mo alloys with molybdenum concentration from 0 to 20% (mass fraction) wasmeasured by a modified sessile drop method. It has been found that the density of the liquid Ni-Mo alloys decreaseswith increasing temperature, but increases with the increase of molybdenum concentration in the alloys. The molarvolume of liquid Ni-Mo binary alloys increases with the increase of temperature and molybdenum concentration. Thepartial molar volume of molybdenum in Ni-Mo binary alloy has been approximately calculated as [13.18-2.65×10^(-3)T+(-47.94+3.10×10^(-2)T)×10^(-2)X_(Mo)]×10^(-6)m^3·mol^(-1). The molar volume of Ni-Mo alloy determined inthe present work shows a negative deviation from the ideal linear mixing molar volume. 展开更多
关键词 Ni-Mo alloy Densityv Modified sessile drop method Molar volume MOLYBDENUM
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Density Measurement of Liquid Ni-Ta Alloys by a Modified Sessile Drop Method 被引量:1
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作者 方亮 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2005年第2期67-70,共4页
The density of liquid Ni-Ta alloys was measured by using a modified sessile drop method. It is found that the density of the liquid Ni-Ta alloys decreases with the increasing temperature, but increases with the increa... The density of liquid Ni-Ta alloys was measured by using a modified sessile drop method. It is found that the density of the liquid Ni-Ta alloys decreases with the increasing temperature, but increases with the increase of tantalum concentration in the alloys. The molar volume of liquid Ni-Ta binary alloys increases with the increase of temperature and tantalum concentration. 展开更多
关键词 Ni-Ta alloy DENSITY modified sessile drop method molar volume tantalum concentration
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Surface tension of molten tin investigated with sessile drop method 被引量:1
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作者 李晶 袁章福 +1 位作者 范建峰 柯家骏 《中国有色金属学会会刊:英文版》 EI CSCD 2005年第5期1166-1171,共6页
The surface tension of molten tin was determined by a set of self-developed digital equipment with sessile drop method at oxygen partial pressure of 1.0×10 -6MPa under different temperatures, and the dependence... The surface tension of molten tin was determined by a set of self-developed digital equipment with sessile drop method at oxygen partial pressure of 1.0×10 -6MPa under different temperatures, and the dependence of surface tension of molten tin on temperature was also discussed. The emphasis was placed on the comparison of surface tension of the same molten tin sample measured by using different equipments with sessile drop method. Results of the comparison indicate that the measurement results with sessile drop method under the approximate experimental conditions are coincident, and the self-developed digital equipment for surface tension measurement has higher stability and accuracy. The relationships of surface tension of molten tin and its temperature coefficient with temperature and oxygen partial pressure were also elucidated from the thermodynamic equilibrium analysis. 展开更多
关键词 熔化工艺 界面结构 金属结构 金属物理学
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Density of liquid NiCoAlCr quartemary alloys measured by modified sessile drop method
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作者 方亮 张淑芳 +5 位作者 肖锋 杨凌川 董建新 曹春兰 陶再南 K.MUKAI 《中国有色金属学会会刊:英文版》 CSCD 2006年第A03期1962-1966,共5页
The densities of liquid NiCoAlCr quaternary alloys with a fixed molar ratio of Ni to Co to Al (x(Ni):x(Co):x(Al)≈73:12.15) which is close to the average value of the commercial Ni-based superalloys TMS75, INCO713, CM... The densities of liquid NiCoAlCr quaternary alloys with a fixed molar ratio of Ni to Co to Al (x(Ni):x(Co):x(Al)≈73:12.15) which is close to the average value of the commercial Ni-based superalloys TMS75, INCO713, CM247LC and CMSX-4, and the mass fraction of chromium changes from 0 to 9% were measured by a modified sessile drop method. It is found that with increasing temperature and chromium concentration in the alloys, the densities of the liquid NiCoAlCr quaternary alloys decrease, whereas the molar volume of the liquid NiCoAlCr quaternary alloys increases. And the liquid densities of NiCoAlCr quaternary alloys calculated from the partial molar volumes of nickel, cobalt, aluminum and chromium in the corresponding Ni-bases binary alloys are in good agreement with the experimental ones, i.e. within the error tolerance range the densities of the liquid Ni-based multi-component alloys can be predicted from the partial volumes of elements in Ni-based binary alloys in liquid state. The molar volume of liquid NiCoAlCr binary alloy shows a negative deviation from the ideal linear mixing and the deviation changes small with the increase of chromium concentration at the same temperature. 展开更多
关键词 钴合金 有色金属 液相 抗热性
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Spherical silicon solar cell with reflector cup fabricated by decompression dropping method
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作者 MINEMOTO Takashi OKAMOTO Chikao +2 位作者 MUROZONO Mikio TAKAKURA Hideyuki HAMAKAWA Yoshihiro 《Rare Metals》 SCIE EI CAS CSCD 2006年第z1期121-126,共6页
A spherical Si solar cell with a reflector cup was successfully fabricated by a dropping method at decompression state. In the dropping method, melted Si droplets were instilled at decompression state (0.5×105 Pa... A spherical Si solar cell with a reflector cup was successfully fabricated by a dropping method at decompression state. In the dropping method, melted Si droplets were instilled at decompression state (0.5×105 Pa) to reduce crystal growth rate, dominating crystal quality such as dislocation density in crystal grains. Spherical Si solar cells were fabricated using the spherical Si crystals with a diameter of 1 mm and then mounted on a reflector cup. The current-voltage measurement of the solar cell shows an energy conversion efficiency of 11.1% (short-circuit current density (Jsc): 24.7 mA·cm-2, open-circuit voltage: 601 mV, fill factor: 74.6%). Minority carrier diffusion length determined by surface photovoltage method was 98 μm. This value can be enhanced by the improvement of crystal quality of spherical Si crystals. These results demonstrate that spherical Si crystals fabricated by the dropping method has a great potential for substrate material of high-efficiency and low-cost solar cells. 展开更多
关键词 spherical Si solar cell dropping method decompression state
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Measurement of contact angle between stainless steel surface and carbon dioxide by pendant drop method
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作者 PEI NianQiang GUO KaiHua +1 位作者 LIU Jie LI TingXun 《Chinese Science Bulletin》 SCIE EI CAS 2008年第16期2560-2564,共5页
To measure contact angle between CO2 and solid surface, in this study a visual high-pressure vessel has been developed, with a corresponding well-controlled constant temperature system. Pendant drop method is applied ... To measure contact angle between CO2 and solid surface, in this study a visual high-pressure vessel has been developed, with a corresponding well-controlled constant temperature system. Pendant drop method is applied to the investigation of the contact angles of CO2 on a stainless steel surface in its own vapor. The image of the pendant drop is recorded by a camera, and a B-Snake method is used to analyze the contour and the contact angle of the droplet. The experimental results have provided a set of well tested data, which show that CO2 has good infiltration into stainless steel surface and the de- veloped method can be used as a standard testing one for measuring the contact angle between high-pressure liquid and solid surface. 展开更多
关键词 二氧化碳 固体表面 温度系统 悬膜下垂
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Morphology observation of dipalmitoyl phosphatidyl choline (DPPC) monolayer on water surface by dropping method
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作者 Daisuke Yoshida Takashi Yokoyama +9 位作者 Takatsugu Shimoaki Takashi Tomita Tadayoshi Yoshida Yasushi Yamamoto Keijiro Taga Ayumi Sumino Takehisa Dewa Mamoru Nango Masato Yamamoto Zameer Sheravani 《Journal of Biophysical Chemistry》 2013年第4期115-121,共7页
Preparation of DPPC lipid monolayer in water trough has been done by dropping method and compared with compression method. Monolayer was studied by surface pressure isotherm, fluorescence microscopy, Brewster angle mi... Preparation of DPPC lipid monolayer in water trough has been done by dropping method and compared with compression method. Monolayer was studied by surface pressure isotherm, fluorescence microscopy, Brewster angle microscopy, and infrared external reflection spectroscopy. Results of these measurements showed that dropping method gave better results compared to compression method. In dropping method, transition from liquid expanded state to liquid condensed is gradual compared to sharp one in compressed method. During monolayer formation, adjustment and interaction between hydrophilic part of lipid and water and among hydrophobic part of lipid molecule are slow, stable, and more natural as worked out from surface area versus pressure isotherm. At a given molecular area, surface pressure is less compared to compression method thus monolayer is in more fluidic state in dropping method than compression method. The observation was supported by all techniques described above. 展开更多
关键词 DPPC MONOLAYER dropPING method Surface Tension Fluorescence MICROSCOPY BREWSTER Angle MICROSCOPY
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MorphologicaObservation of Specific Condensation Effect of Cholesterol on Dipalmitoyl Phosphatidyl Choline (DPPC) Monolayer by Dropping Method
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作者 Takashi Yokoyama Daisuke Yoshida +8 位作者 Hiroya Mori Masaya Okabe Zameer Shervani Keijiro Taga Yasushi Yamamoto Ayumi Sumino Takehisa Dewa Mamoru Nango Masato Yamamoto 《Journal of Biophysical Chemistry》 2016年第4期98-109,共12页
Morphology of dipalmitoyl phosphatidyl choline (DPPC)-cholesterol (Chol) mixed monolayer formed on water surface by dropping method was investigated using surface tension measurement (STm), Brewster angle microscopy (... Morphology of dipalmitoyl phosphatidyl choline (DPPC)-cholesterol (Chol) mixed monolayer formed on water surface by dropping method was investigated using surface tension measurement (STm), Brewster angle microscopy (BAM), and fluorescence microscopy (FM). STm showed strong condensation effect of Chol in fluidic DPPC monolayer. Excess area (S<sub>ex</sub>) from mean mixing state of DPPC and Chol was about twice larger than that by general compression method in the range from xC = 0.2 to 0.4 (xC: mole fraction of Chol). BAM and FM images showed clearly that the fluidic DPPC monolayer changed to condensed rigid monolayer due to the condensation effect of Chol. At more than xC = 0.3 DPPC-Chol mixed monolayer changed to condensed state similar to the Chol monolayer. These results support previous reports by compression method that Chol molecule demonstrates the strong condensation effect to the fluidic monolayer and also indicate that dropping method enables to form unique monolayer on the water surface. 展开更多
关键词 DPPC-Chol Mixed Monolayer dropping method Surface Tension Measurement Brewster Angle Microscopy Fluorescence Microscopy Condensation Effect
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Validation for Microbial Limit Test Method of Compound Yu E Nose Drops
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作者 Renhui YANG Peixue CAO +1 位作者 Zhen ZENG Xiangling QU 《Agricultural Biotechnology》 CAS 2019年第5期125-128,共4页
[Objectives] This study was conducted to establish a method for microbial limit test of Compound Yu E Nose Drops.[Methods] According to the Chinese Pharmacopoei (General Rules in the fourth part of the 2015 edition),t... [Objectives] This study was conducted to establish a method for microbial limit test of Compound Yu E Nose Drops.[Methods] According to the Chinese Pharmacopoei (General Rules in the fourth part of the 2015 edition),the microbial limit test method for Compound Yu E Nose Drops was verified.[Results] Compound Yu E Nose Drops has a strong inhibitory effect on Staphylococcus aureus and Bacillus subtilis,and the inhibitory activity was significantly eliminated after increasing the diluent (1∶ 20).The recoveries were all in the range of 0.5-2.0 when the total quantities of aerobic microbes were determined by the dilution method (1∶ 20).When the total quantities of mould and yeast were determined by the conventional method,the recoveries were both in the range of 0.5-2.0.When examining control bacteria,Escherichia coli,S.aureus and Pseudomonas aeruginosa can all be detected in the test groups by the test liquid dilution method.[Conclusions] For Compound Yu E Nose Drops,the total quantities of aerobic microbe can be counted by the dilution method;the quantities of mould and yeast can be examined by the conventional plate method;and the conventional method can be used for control microbe examination. 展开更多
关键词 COMPOUND Yu E NOSE dropS MICROBIAL LIMIT test DILUTION method
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Comparative Study of Structural, Optical and Electrical Properties of SnO<sub>2</sub>Thin Film Growth via CBD, Drop-Cast and Dip-Coating Methods
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作者 Md. Tareq Rahman Zubair Ahmed +6 位作者 Md. Johurul Islam Kamaruzzaman Mst. Toma Khatun Md. Abdul Gafur Md. Shahriar Bashar Md. Monjarul Alam 《Materials Sciences and Applications》 2021年第12期578-594,共17页
Tin oxide (SnO<sub>2</sub>) thin films were deposited on glass substrate by Chemical Bath Deposition (CBD), Drop-Cast and Dip-Coating method. The thin films were post-annealed at 500&deg;C for 2 hours.... Tin oxide (SnO<sub>2</sub>) thin films were deposited on glass substrate by Chemical Bath Deposition (CBD), Drop-Cast and Dip-Coating method. The thin films were post-annealed at 500&deg;C for 2 hours. The structural, optical, and electrical properties of the SnO<sub>2</sub> thin films were investigated by using XRD, FTIR, SEM, EDX, UV-Vis spectroscopy, and Electrometer experiment. The XRD patterns of SnO<sub>2</sub> thin films deposited on glass substrate by CBD method, Drop-Cast method and Dip-Coating method showed cubic, tetragonal and amorphous structures respectively. The FTIR spectrum exhibited the strong presence of SnO<sub>2</sub> with the characteristic vibrational mode of Sn-O-Sn. The SEM analysis was observed that the surface morphology of the thin films toughly depends on the deposition methods of the SnO<sub>2</sub> thin films. EDX measurement confirmed that the thin films are the composition of Tin (Sn) and Oxygen (O<sub>2</sub>). The optical band gap of SnO<sub>2 </sub>thin films deposited by CBD method, Drop-Cast method and Dip-Coating method is found to be 3.12 eV, 3.14 eV and 3.16 eV respectively. Thin films deposited by Dip-Coating method showed the highest band gap. The electrical results confirmed that the SnO<sub>2</sub> thin films are good conductors and pursued Ohm’s Law. These properties of the SnO<sub>2</sub> thin films brand are appropriate for application in solar cell assembly, gas sensor devices and transparent electrodes of panel displays. 展开更多
关键词 SnO2 Thin Film CBD drop-Cast and Dip-Coating method Electrical
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Direct Numerical Simulation of Secondary Breakup of Liquid Drops 被引量:9
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作者 刘静 徐旭 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2010年第2期153-161,共9页
This article studies numerically a familiar important phenomenon in spray combustion which is deformation and breakup of liquid drops in gas flow. The SIMPLER method is used to solve the two-dimensional (2D) unstead... This article studies numerically a familiar important phenomenon in spray combustion which is deformation and breakup of liquid drops in gas flow. The SIMPLER method is used to solve the two-dimensional (2D) unsteady axisymmetric Navier-Stokes equations for both the drop and the ambient gas flow. The level set method is applied to capturing the liquid/gas interface. Through calculation are obtained four typical breakup modes--oscillation, bag breakup, sheet stripping breakup and shear breakup governed by four non-dimensional numbers which are gas Weber number (Weg), liquid Reynolds number (Rel), gas Reynolds number (Reg) and density ratio (γ). Their effects upon each mode are analyzed. The results indicate that among the four numbers, Weg is of the highest importance with Rel, Reg and γfollowing up. By widening the range of the density ratio up to 1 000, the breakup mode is discovered to be so complicated that a new one called multimode breakup mode turns up. This mode contains the shearing breakup and piercing breakup, which successively happen. The calculation results agree well with what is observed from the experiments. 展开更多
关键词 two phase flow drop breakup level set method SIMPLER method numerical simulation
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Drop test and crash simulation of a civil airplane fuselage section 被引量:18
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作者 Liu Xiaochuan Guo Jun +2 位作者 Bai Chunyu Sun Xiasheng Mou Rangke 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2015年第2期447-456,共10页
Crashworthiness of a civil airplane fuselage section was studied in this paper. Firstly, the failure criterion of a rivet was studied by test, showing that the ultimate tension and shear failure loads were obviously a... Crashworthiness of a civil airplane fuselage section was studied in this paper. Firstly, the failure criterion of a rivet was studied by test, showing that the ultimate tension and shear failure loads were obviously affected by the loading speed. The relations between the loading speed and the average ultimate shear, tension loads were expressed by two logarithmic functions, Then, a vertical drop test of a civil airplane fuselage section was conducted with an actual impact velocity of 6.85 m/s, meanwhile the deformation of cabin frame and the accelerations at typical locations were measured. The finite element model of a main fuselage structure was developed and validated by modal test, and the error between the calculated frequencies and the test ones of the first four modes were less than 5%. Numerical simulation of the drop test was performed by using the LS-DYNA code and the simulation results show a good agreement with that of drop test. Deforming mode of the analysis was the same as the drop test; the maximum average rigid acceleration in test was 8.8 l g while the calculated one was 9.17g, with an error of 4.1%; average maximum test deformation at four points on the front cabin floor was 420 mm, while the calculated one was 406 mm, with an error of 3.2%; the peak value of the calculated acceleration at a typical location was 14.72g, which is lower than the test result by 5.46%; the calculated rebound velocity result was greater than the test result 17.8% and energy absorption duration was longer than the test result by 5.73%. 展开更多
关键词 Civil airplane drop test Finite element method Fuselage section Rivet failure
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Numerical investigation of the deformation mechanism of a bubble or a drop rising or falling in another fluid 被引量:4
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作者 王含 张振宇 +2 位作者 杨永明 胡越 张慧生 《Chinese Physics B》 SCIE EI CAS CSCD 2008年第10期3847-3855,共9页
A numerical method for simulating the motion and deformation of an axisymmetric bubble or drop rising or falling in another infinite and initially stationary fluid is developed based on the volume of fluid (VOF) met... A numerical method for simulating the motion and deformation of an axisymmetric bubble or drop rising or falling in another infinite and initially stationary fluid is developed based on the volume of fluid (VOF) method in the frame of two incompressible and immiscible viscous fluids under the action of gravity, taking into consideration of surface tension effects. A comparison of the numerical results by this method with those by other works indicates the validity of the method. In the frame of inviseid and incompressible fluids without taking into consideration of surface tension effects, the mechanisms of the generation of the liquid jet and the transition from spherical shape to toroidal shape during the bubble or drop deformation, the increase of the ring diameter of the toroidal bubble or drop and the decrease of its cross-section area during its motion, and the effects of the density ratio of the two fluids on the deformation of the bubble or drop are analysed both theoretically and numerically. 展开更多
关键词 BUBBLE drop BUOYANCY deformation mechanism VOF method
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Thermocapillary migration and interaction of two nondeformable drops 被引量:1
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作者 尹兆华 常磊 +1 位作者 胡文瑞 高鹏 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2011年第7期811-824,共14页
A numerical study on the interaction of two spherical drops in the thermocapillary migration is presented in the microgravity environment. Finite-difference methods are adopted. The interfaces of the drops are capture... A numerical study on the interaction of two spherical drops in the thermocapillary migration is presented in the microgravity environment. Finite-difference methods are adopted. The interfaces of the drops are captured by the front-tracking technique. It is found that the arrangement of the drops directly influences their migration and interaction, and the motion of one drop is mainly determined by the disturbed temperature field because of the existence of the other drop. 展开更多
关键词 interaction of two drops thermocapillary motion front tracking method
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低界面张力驱油表面活性剂的界面扩张流变研究
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作者 楚艳苹 高峰 +2 位作者 张伟华 张磊 张路 《日用化学工业(中英文)》 北大核心 2025年第8期961-968,共8页
采用旋转滴法研究了阴离子表面活性剂重烷基苯磺酸盐(HABS)和石油磺酸盐(PS)的界面扩张流变特性。考察了振荡频率、表面活性剂浓度、油相、界面张力对界面模量的影响,比较了HABS和PS的界面膜强度和界面活性的差异。结果表明,HABS的亲水... 采用旋转滴法研究了阴离子表面活性剂重烷基苯磺酸盐(HABS)和石油磺酸盐(PS)的界面扩张流变特性。考察了振荡频率、表面活性剂浓度、油相、界面张力对界面模量的影响,比较了HABS和PS的界面膜强度和界面活性的差异。结果表明,HABS的亲水亲油平衡能力比PS强,能将癸烷-水界面张力和原油-水界面张力降低至0.01 mN/m数量级。HABS和PS分子间均以静电斥力为主,扩散-交换过程主导,界面膜黏性较大。在癸烷-水界面,分子尺寸较小的HABS扩散-交换更快,界面膜的黏性比PS高,扩张模量在高浓度时降低得更明显;原油中活性组分在原油-水界面上混合吸附,造成HABS和PS界面膜的黏弹特性相似。HABS与原油组分间存在协同效应,在将界面张力降低至0.01 mN/m数量级的同时,还能维持一定的界面膜强度,在提高原油采收率方面有较大潜力。 展开更多
关键词 旋转滴法 界面张力 界面扩张模量 重烷基苯磺酸盐 石油磺酸盐
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The mechanism and clinical effectiveness of the six-step Chinese Daoyin technique on hemiplegic patients with drop-foot
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作者 Wen-Ru Zhao Hai-Hong Zhao +2 位作者 Xue-Min Zhang Xiao Cao Xin Li 《Journal of Biomedical Science and Engineering》 2012年第11期652-656,共5页
Objective: The aim of this study was to improve the Chinese Daoyin technique (physical and breathing exercises), which is an ancient rehabilitation method, to elevate its effect and to standardize its operational proc... Objective: The aim of this study was to improve the Chinese Daoyin technique (physical and breathing exercises), which is an ancient rehabilitation method, to elevate its effect and to standardize its operational procedure. Methods: Based on the ancient Chinese Daoyin technique, a six-step method was developed including: 1) motion imagination and imitation;2) mental and breathing regulation;3) target point determination;4) motion percussion;5) motion persistence;6) relaxation. Sixty drop-foot patients who suffered from hemiparesis after a stroke were randomly divided into the experimental group and the control group. Functional evaluation including Fugl-Meyer assessment score, Lovett manual muscle test (MMT), active range of motion of the ankle joint and electromyography were performed before and after the training course. The data were analyzed using the statistical software SPSS 12.0. Results: The differences between the two groups were significant. The effectiveness of the six-step group was significantly better than the effectiveness of the control group. Conclusion: The six-step method of the Chinese Daoyin technique is an effective rehabilitation training method for drop-foot in stroke patients with hemiparesis. 展开更多
关键词 Rehabilitation CHINESE DAOYIN Technique Six-Step method Hemiparesis drop-Foot
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NUMERICAL SIMULATION OF DROP MIGRATION IN CHANNEL FLOW UNDER ZERO-GRAVITY
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作者 柳涛 陆夕云 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2004年第3期199-205,共7页
The migration of deformable drops in the channel flow neglecting the gravity influence is investigated numerically by solving the incompressible Navier-Stokes equations using the finite- difference method coupled with... The migration of deformable drops in the channel flow neglecting the gravity influence is investigated numerically by solving the incompressible Navier-Stokes equations using the finite- difference method coupled with the front-tracking technique.The objectives of this study are to examine the effectiveness of the present approach for predicting the migration of drops in a shear flow and to investigate the behavior of the drop migration in the channel flow under zero-gravity.To validate the present calculation,some typical results are compared with available computational and theoretical data,which confirms that the present approach is reliable in predicting the drop migration. With respect to the drop migration in the channel flow at finite Reynolds numbers,the drops either move to an equilibrium lateral position or undergo an oscillatory motion under different conditions. The effects of some typical parameters,e.g.,the Reynolds number,the Weber number,the viscosity ratio and the density ratio of the drop fluid to the suspending medium,and the drop size,on the migration of drops are discussed and analyzed. 展开更多
关键词 drop migration zero-gravity front-tracking method finite-difference method
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Ti-Zr-Hf-Si合金熔体对C/C复合材料的润湿性能影响研究
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作者 吴靓 刘达 +1 位作者 王博 陈翀 《金属加工(热加工)》 2025年第9期107-112,119,共7页
高温下将合金熔体引入C/C复合材料孔隙中,并与预先沉积的基体材料发生原位反应,从而形成的超高温陶瓷具有高强度、高熔点和优异的导热性,对于高温及热防护材料的性能需求愈发严苛的今天具有重要意义。聚焦(Ti,Zr,Hf,Si)高温合金的润湿性... 高温下将合金熔体引入C/C复合材料孔隙中,并与预先沉积的基体材料发生原位反应,从而形成的超高温陶瓷具有高强度、高熔点和优异的导热性,对于高温及热防护材料的性能需求愈发严苛的今天具有重要意义。聚焦(Ti,Zr,Hf,Si)高温合金的润湿性,以座滴法为原理,采用YG0020-2300型超高温熔体表面张力润湿性测量仪测量多元合金熔体在热解碳材料上的润湿性,旨在深入剖析润湿性的影响因素与内在机制。结果表明:Ti∶Zr∶Hf∶Si的原子比为3∶12∶4∶2时,其润湿角仅为0.58585422°,此时Ti-Zr-Hf-Si合金熔体具有最好的润湿性能。 展开更多
关键词 Ti-Zr-Hf-Si合金 C/C复合材料 润湿性 座滴法
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电位落差法测定铀矿地质样品的氧化-还原电位
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作者 张建梅 邓长生 乔浩 《世界核地质科学》 2025年第3期647-658,667,共13页
为实现铀矿地质样品氧化-还原电位的准确测定,对比分析酸性重铬酸钾法和碱性高锰酸钾法在铀矿地质样品氧化-还原电位测定中的应用效果,探寻更优的测定方法与实验条件,本研究采用电位落差法,系统地对酸性重铬酸钾法和碱性高锰酸钾法进行... 为实现铀矿地质样品氧化-还原电位的准确测定,对比分析酸性重铬酸钾法和碱性高锰酸钾法在铀矿地质样品氧化-还原电位测定中的应用效果,探寻更优的测定方法与实验条件,本研究采用电位落差法,系统地对酸性重铬酸钾法和碱性高锰酸钾法进行多维度对比,包括溶液稳定性、最佳溶液浓度、样品浸泡时长、固液比和电极平衡时间。碱性高锰酸钾法的样品浸泡时间和电极平衡时间比酸性重铬酸钾法短,能更快达到稳定可靠的电位值。针对强还原性样品,酸性重铬酸钾法所得ΔEh值更大,但两种方法对样品还原能力大小的评价结论一致。碱性高锰酸钾法的精密度更优。碱性高锰酸钾法的最佳实验条件为:浓度0.03 mol·L^(-1),样品浸泡1.5 h,固液比1∶25,电极平衡时间5 min,反应介质为0.2%氢氧化钾溶液,温度(25±1)℃。采用该方法测定的ΔEh值与氧化系数法(Fe^(2+)/Fe^(3+))对氧化-还原环境的判定结果基本一致,且与样品颜色基本吻合。综合各项实验指标,碱性高锰酸钾法在铀矿地质样品氧化-还原电位测定中整体性能优于酸性重铬酸钾法。采用最佳实验条件,实现了对铀矿地质样品氧化-还原电位的准确测定,为铀矿地质研究提供了可靠的技术支撑。 展开更多
关键词 电位落差法 氧化-还原电位 碱性高锰酸钾 酸性重铬酸钾 铀矿地质样品
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Wetting behavior of Mo, Ta, and stainless steel substrates in contact with molten Mg
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作者 S.Terlicka N.Sobczak +1 位作者 K.Janus J.J.Sobczak 《Journal of Magnesium and Alloys》 2025年第3期1149-1159,共11页
The sessile drop method combined with a capillary purification procedure was used,for thefirst time,to analyze the high-temperature behavior of molten Mg on three dissimilar substrates:1)molybdenum,2)tantalum and 3)AISI... The sessile drop method combined with a capillary purification procedure was used,for thefirst time,to analyze the high-temperature behavior of molten Mg on three dissimilar substrates:1)molybdenum,2)tantalum and 3)AISI 316L stainless steel.All tests were performed under isothermal conditions at 720℃ in a protective atmosphere(Ar+5 wt.%H2).Images of Mg/substrate couples recorded during the experiments were used to calculate the contact angles(θ)formed between the liquid Mg drop and the selected substrates.After the sessile drop tests,the Mg/Mo,Mg/Ta,and Mg/AISI 316L couples were subjected to in-depth microstructural characterization using scanning electron microscopy(SEM)and energy-dispersive X-ray spectroscopy(EDS).Under the employed experimental conditions,oxide-free Mg drops on all tested couples presented non-wetting behavior(θ>90°).The average values of the calculated contact angles after 40 s of liquid Mg deposition wereθMg/Mo=124°,θMg/Ta=125°,andθMg/AISI 316L=126°,respectively.The SEM/EDS analysis showed no mass transfer and no bonding between solidified drops and the substrates.This non-reactive and non-wetting behavior of investigated couples can be associated with the immiscible nature of the Mg-Mo,Mg-Ta,and Mg-Fe systems,where the solubility of liquid Mg with all tested materials is negligible,and Mg does not form any compounds with them. 展开更多
关键词 Liquid Mg MOLYBDENUM TANTALUM Stainless steel Sessile drop method Contact angle
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