The structural changes in the CaO-SiO_(2)-Al_(2)O_(3)-MgO slag system with varying CaO contents were investigated through molecular dynamics(MD)simulations,and its effect on the dissolution behavior of alumina inclusi...The structural changes in the CaO-SiO_(2)-Al_(2)O_(3)-MgO slag system with varying CaO contents were investigated through molecular dynamics(MD)simulations,and its effect on the dissolution behavior of alumina inclusions was characterized by the Kullback-Leibler(KL)divergence.The slag structure analysis revealed that the[AlO]tetrahedral structure was the primary network structure in the slag.With increasing the CaO content,the non-bridge oxygen(NBO)content in the slag structure increases,and the bridge oxygen(BO)content decreases,thereby reducing the complexity of the slag network structure.Raman spectroscopy detection verifies the results of the MD simulations.The results indicated that the dissolution rate of alumina inclusions accelerates with increasing the CaO content in the slag,owing to the reduced complexity of the slag network structure and the enhanced interatomic interactions.The simulation results for the dissolution of alumina inclusions were consistent with theoretical calculations based on the slag inclusion capacity and the dimensionless dissolution rate of inclusions.Radial distribution function analysis demonstrated that the interaction between atoms in the slag system and alumina inclusions strengthens,increasing the dissolution rate of alumina inclusions.The[AlO_(6)]octahedral structure of the alumina inclusions is disrupted,forming BO structures,which in turn enhances the complexity of the slag network structure,slowing the dissolution rate of alumina inclusions.In contrast,the slag system with a higher CaO content has a relatively simpler network structure,promoting faster alumina inclusion dissolution.展开更多
Visual observations on dissolution of La in LaCl_3-KCl and Nd in NdCl_3-KCl as well as La,Nd in KCl-NaCl melt respectively is first made by means of a see-through cell.It is found that black metal fog is formed as the...Visual observations on dissolution of La in LaCl_3-KCl and Nd in NdCl_3-KCl as well as La,Nd in KCl-NaCl melt respectively is first made by means of a see-through cell.It is found that black metal fog is formed as the dissolution of La,Nd in their melts.There is a little resistance to the dissolution and diffusion of La and Nd into their halide melts under electrolysis.The dissolution and diffusion rate of Nd in its halide melt is mt(?)h faster than that of La.The metal fog of La and Nd consists mainly of their lower valence ions and partially of metal particles.展开更多
Counter-rotating electrochemical machining(CRECM)is a novel shaping method with advantages in processing revolving parts,especially engine casings.However,few researchers have studied the anodic behaviour of the count...Counter-rotating electrochemical machining(CRECM)is a novel shaping method with advantages in processing revolving parts,especially engine casings.However,few researchers have studied the anodic behaviour of the counter-rotating state.This paper aims to analyse the anode dissolution behaviour of TA15 and obtain desired surface qualities in CRECM.The anodic characteristics were measured by polarization and cyclic voltammetry curves,and the passive-trans passive behaviour of TA15 was revealed.The electrode surface structures at different stages were analysed using electrochemical impedance spectroscopy(EIS),and a quantitative dissolution model was established to illustrate the electrochemical dissolution and structural evolution of the revolving surfaces.A series of CRECM experiments were conducted,and three stages(pitting corrosion,pitting expansion,and smoothing)were detected according to the current signals.In the first stage,an oxide film with small pores was formed initially on the metal surface when exposed to air.This air-formed oxide film was broken down locally during the electrochemical reaction process,resulting in the occurrence of pitting.With the increase of electricity,the oxide layer became thinner,and the pitting areas expanded and began to connect with each other.In this stage,the surface quality was poor owing to the uneven material dissolution.When the amount of electricity approximately reached a constant,the oxide layer was completely removed,and a very thin salt film was generated at the metal-electrolyte interface.In this stage,the material was dissolved uniformly,and the surface was smooth without pitting corrosion.Based on the obtained results,anode workpieces with grid-like convex structures were fabricated using CRECM.Both the revolving surface and the sidewalls of the convex structures can be controlled from pitting to smoothness.展开更多
基金supported by Special Funding Projects for Local Science and Technology Development guided by the Central Committee(No.YDZJSX2022C028)the Fundamental Research Program of Shanxi Province(Nos.20210302123218 and 202203021211187)+4 种基金Innovation and Entrepreneurship Training Program for College Students in Shanxi Province(202210109006)the National Natural Science Foundation(52474367)the Key Research and Development for University-Local Government Collaboration of Lvliang City(2024XDHZ01)the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(2025Q022)the Foundation of State Key Laboratory of Advanced Metallurgy,USTB(K22-10).
文摘The structural changes in the CaO-SiO_(2)-Al_(2)O_(3)-MgO slag system with varying CaO contents were investigated through molecular dynamics(MD)simulations,and its effect on the dissolution behavior of alumina inclusions was characterized by the Kullback-Leibler(KL)divergence.The slag structure analysis revealed that the[AlO]tetrahedral structure was the primary network structure in the slag.With increasing the CaO content,the non-bridge oxygen(NBO)content in the slag structure increases,and the bridge oxygen(BO)content decreases,thereby reducing the complexity of the slag network structure.Raman spectroscopy detection verifies the results of the MD simulations.The results indicated that the dissolution rate of alumina inclusions accelerates with increasing the CaO content in the slag,owing to the reduced complexity of the slag network structure and the enhanced interatomic interactions.The simulation results for the dissolution of alumina inclusions were consistent with theoretical calculations based on the slag inclusion capacity and the dimensionless dissolution rate of inclusions.Radial distribution function analysis demonstrated that the interaction between atoms in the slag system and alumina inclusions strengthens,increasing the dissolution rate of alumina inclusions.The[AlO_(6)]octahedral structure of the alumina inclusions is disrupted,forming BO structures,which in turn enhances the complexity of the slag network structure,slowing the dissolution rate of alumina inclusions.In contrast,the slag system with a higher CaO content has a relatively simpler network structure,promoting faster alumina inclusion dissolution.
文摘Visual observations on dissolution of La in LaCl_3-KCl and Nd in NdCl_3-KCl as well as La,Nd in KCl-NaCl melt respectively is first made by means of a see-through cell.It is found that black metal fog is formed as the dissolution of La,Nd in their melts.There is a little resistance to the dissolution and diffusion of La and Nd into their halide melts under electrolysis.The dissolution and diffusion rate of Nd in its halide melt is mt(?)h faster than that of La.The metal fog of La and Nd consists mainly of their lower valence ions and partially of metal particles.
基金supported by the National Natural Science Foundation of China(Grant No.51805259)the National Natural Science Foundation of China for Creative Research Groups(Grant No.51921003)+1 种基金the China Postdoctoral Science Foundation(Grant No.2019M661833)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grant No.KYCX21_0192)。
文摘Counter-rotating electrochemical machining(CRECM)is a novel shaping method with advantages in processing revolving parts,especially engine casings.However,few researchers have studied the anodic behaviour of the counter-rotating state.This paper aims to analyse the anode dissolution behaviour of TA15 and obtain desired surface qualities in CRECM.The anodic characteristics were measured by polarization and cyclic voltammetry curves,and the passive-trans passive behaviour of TA15 was revealed.The electrode surface structures at different stages were analysed using electrochemical impedance spectroscopy(EIS),and a quantitative dissolution model was established to illustrate the electrochemical dissolution and structural evolution of the revolving surfaces.A series of CRECM experiments were conducted,and three stages(pitting corrosion,pitting expansion,and smoothing)were detected according to the current signals.In the first stage,an oxide film with small pores was formed initially on the metal surface when exposed to air.This air-formed oxide film was broken down locally during the electrochemical reaction process,resulting in the occurrence of pitting.With the increase of electricity,the oxide layer became thinner,and the pitting areas expanded and began to connect with each other.In this stage,the surface quality was poor owing to the uneven material dissolution.When the amount of electricity approximately reached a constant,the oxide layer was completely removed,and a very thin salt film was generated at the metal-electrolyte interface.In this stage,the material was dissolved uniformly,and the surface was smooth without pitting corrosion.Based on the obtained results,anode workpieces with grid-like convex structures were fabricated using CRECM.Both the revolving surface and the sidewalls of the convex structures can be controlled from pitting to smoothness.
