This study addresses the challenges posed by dispersive soil in various engineering fields,including hydraulic and agricultural engineering,by exploring the effects of physical adsorption on soil modification.The prim...This study addresses the challenges posed by dispersive soil in various engineering fields,including hydraulic and agricultural engineering,by exploring the effects of physical adsorption on soil modification.The primary objective is to identify an environmentally friendly stabilizer that can alleviate cracking and erosion resulting from soil dispersivity.Activated carbon(AC),known for its porous nature,was examined for its potential to enhance soil strength and erosion resistance.The charge neutralization process was evaluated by monitoring pH and conductivity,in addition to a comprehensive analysis of microscopic and mineral properties.The results show that high sodium levels or low clay contents result in the dispersive nature of soil in water.However,the incorporation of AC can transform such soil into a non-dispersive state.Moreover,both soil strength and erosion resistance exhibited enhancements with increasing AC content and curing duration.The incorporation of AC resulted in a maximum 5.6-fold increase in unconfined compressive strength and a 1.8-fold increase in tensile strength for dispersive soil.Notably,a significant correlation was observed during the curing phase among soil dispersivity,mechanical properties,and pH values.Microscopic analyses revealed that the porous structure of AC facilitated a filling effect and enhanced adsorption capacity,which contributed to improved soil characteristics and reduced dispersivity.The release of hydrogen ions and the formation of aggregates promote water stability.Validation tests conducted on dispersive soil from northern Shaanxi demonstrated the efficacy of physical adsorption using AC as a viable method for modifying dispersive soil in the water conservancy hub.展开更多
For the (2 + 1)-dimensional nonlinear dispersive Boussinesq equation, by using the bifurcation theory of planar dynamical systems to study its corresponding traveling wave system, the bifurcations and phase portraits ...For the (2 + 1)-dimensional nonlinear dispersive Boussinesq equation, by using the bifurcation theory of planar dynamical systems to study its corresponding traveling wave system, the bifurcations and phase portraits of the regular system are obtained. Under different parametric conditions, various sufficient conditions to guarantee the existence of analytical and non-analytical solutions of the singular system are given by using singular traveling wave theory. For certain special cases, some explicit and exact parametric representations of traveling wave solutions are derived such as analytical periodic waves and non-analytical periodic cusp waves. Further, two-dimensional wave plots of analytical periodic solutions and non-analytical periodic cusp wave solutions are drawn to visualize the dynamics of the equation.展开更多
High-order models with a dissipative term for nonlinear and dispersive wave in water of varying depth with an arbitrary sloping bottom are presented in this article. First, the formal derivations to any high order of ...High-order models with a dissipative term for nonlinear and dispersive wave in water of varying depth with an arbitrary sloping bottom are presented in this article. First, the formal derivations to any high order of mu(= h/lambda, depth to deep-water wave length ratio) and epsilon(= a/h, wave amplitude to depth ratio) for velocity potential, particle velocity vector, pressure and the Boussinesq-type equations for surface elevation eta and horizontal velocity vector (U) over right arrow at any given level in water are given. Then, the exact explicit expressions to the fourth order of mu are derived. Finally, the linear solutions of eta, (U) over right arrow, C (phase-celerity) and C-g (group velocity) for a constant water depth are obtained. Compared with the Airy theory, excellent results can be found even for a water depth as large as the wave legnth. The present high-order models are applicable to nonlinear regular and irregular waves in water of any varying depth (from shallow to deep) and bottom slope (from mild to steep).展开更多
A novel method for the determination of five carbamate pesticides （metolcarb, carbofuran, carbaryl, isoprocard and diethofencard） in water samples was developed by dispersive liquid-liquid microextraction （DLLME） ...A novel method for the determination of five carbamate pesticides （metolcarb, carbofuran, carbaryl, isoprocard and diethofencard） in water samples was developed by dispersive liquid-liquid microextraction （DLLME） coupled with high performance liquid chromatography-diode array detector （HPLC-DAD）. Some experimental parameters that influence the extraction efficiency were studied and optimized to obtain the best extraction results. Under the optimum conditions for the method, the calibration curve was linear in the concentration range from 5 to 1000 ng mL^-1 for all the five carbamate pesticides, with the correlation coefficients （r^2） varying from 0.9984 to 0.9994. Good enrichment factors were achieved ranging from 80 to 177- fold, depending on the compound. The limits of detection （LODs） （S/N = 3） were ranged from 0.1 to 0.5 ng mL^-1. The method has been successfully applied to the analysis of the pesticide residues in environmental water samples.展开更多
In this work, a new microextraction method termed ionic liquid based dispersive liquid-liquid microextraction （IL-DLLME） was demonstrated for the extraction of 2-methylaniline, 4-chloroaniline, 1-naphthylamine and 4...In this work, a new microextraction method termed ionic liquid based dispersive liquid-liquid microextraction （IL-DLLME） was demonstrated for the extraction of 2-methylaniline, 4-chloroaniline, 1-naphthylamine and 4-aminobiphenyl in aqueous matrices. After extraction the ionic liquid （IL） phase was injected directly into the high performance liquid chromatography （HPLC） system for determination. Some parameters that might affect the extraction efficiency were optimized. Under the optimum conditions, good linear relationship, sensitivity and reproducibility were obtained. The limits of detection （LOD, S/N = 3） for the four analytes were in the range of 0.45-2.6 μg L^-1. The relative standard deviations （R.S.D., n = 6） were in the range of 6.2-9.8%. This method was applied for the analysis of the real water samples. The recoveries ranged from 93.4 to 106.4%. The main advantages of the method are high speed, high recovery, good repeatability and volatile organic solvent-free.展开更多
This article is concerned with the extended homogeneous balance method for studying the abundant localized solution structures in the (2+1)-dimensional dispersive long-wave equations . Starting from the homogeneous ba...This article is concerned with the extended homogeneous balance method for studying the abundant localized solution structures in the (2+1)-dimensional dispersive long-wave equations . Starting from the homogeneous balance method, we find that the richness of the localized coherent structures of the model is caused by the entrance of two variable-separated arbitrary functions. For some special selections of the arbitrary functions, it is shown that the localized structures of the model may be dromions, lumps, breathers, instantons and ring solitons.展开更多
A complete discrimination system for the fourth order polynomial is given. As an application, we have reduced a （1＋1）-dimensional dispersive long wave equation with general coefficients to an elementary integral fo...A complete discrimination system for the fourth order polynomial is given. As an application, we have reduced a （1＋1）-dimensional dispersive long wave equation with general coefficients to an elementary integral form and obtained its all possible exact travelling wave solutions including rational function type solutions, solitary wave solutions, triangle function type periodic solutions and Jacobian elliptic functions double periodic solutions. This method can be also applied to many other similar problems.展开更多
By using a mapping approach and a linear variable separation approach, a new family of solitary wave solutions with arbitrary functions for the （2＋1）-dimensional modified dispersive water-wave system （MDWW） is de...By using a mapping approach and a linear variable separation approach, a new family of solitary wave solutions with arbitrary functions for the （2＋1）-dimensional modified dispersive water-wave system （MDWW） is derived. Based on the derived solutions and using some multi-valued functions, we obtain some novel folded localized excitations of the system.展开更多
In the present work,dispersive liquid-liquid microextraction(DLLME)was used to extract six synthetic cannabinoids(JWH-018,JWH-019,JWH-073,JWH-200,or WIN 55,225,JWH-250,and AM-694)from oral fluids.A rapid baseline sepa...In the present work,dispersive liquid-liquid microextraction(DLLME)was used to extract six synthetic cannabinoids(JWH-018,JWH-019,JWH-073,JWH-200,or WIN 55,225,JWH-250,and AM-694)from oral fluids.A rapid baseline separation of the analytes was achieved on a bidentate octadecyl silica hydride phase(Cogent Bidentate C18;4.6 mm×250 mm,4μm)maintained at 37℃,by eluting in isocratic conditions(water:acetonitrile(25:75,V/V)).Detection was performed using positive electrospray ionization-tandem mass spectrometry.The parameters affecting DLLME(pH and ionic strength of the aqueous phase,type and volume of the extractant and dispersive solvent,vortex and centrifugation time)were optimized for maximizing yields.In particular,using 0.5 mL of oral fluid,acetonitrile(1 mL),was identified as the best option,both as a solvent to precipitate proteins and as a dispersing solvent in the DLLME procedure.To select an extraction solvent,a low transition temperature mixture(LTTM;composed of sesamol and chlorine chloride with a molar ratio of 1:3)and dichloromethane were compared;the latter(100μL)was proved to be a better extractant,with recoveries ranging from 73%to 101%by vortexing for 2 min.The method was validated according to the guidelines of Food and Drug Administration bioanalytical methods:intra-day and inter-day precisions ranged between 4%and 18%depending on the spike level and analyte;limits of detection spanned from 2 to 18 ng/mL;matrixmatched calibration curves were characterized by determination coefficients greater than 0.9914.Finally,the extraction procedure was compared with previous methods and with innovative techniques,presenting superior reliability,rapidity,simplicity,inexpensiveness,and efficiency.展开更多
A novel,simple,rapid,efficient and environment-friendly method for the determination of trace copper in cereal samples was developed by using dispersive liquid-liquid microextraction based on solidification of floatin...A novel,simple,rapid,efficient and environment-friendly method for the determination of trace copper in cereal samples was developed by using dispersive liquid-liquid microextraction based on solidification of floating organic drop（DLLME-SFO） followed by flame atomic absorption spectrometry.In the DLLME-SFO,copper was complexed with 8-hydroxy quinoline and extracted into a small volume of 1-dodecanol,which is of low density,low toxicity and proper melting point near room temperature. The experimental parameters affecting the extraction efficiency were investigated and optimized.Under the optimum conditions, the calibration graph exhibited linearity over the range of 0.5—500 ng/mL with the correlation coefficient（r） of 0.9996.The enrichment factor was 122 and the limit of detection was 0.1 ng/mL.The method was applied to the determination of copper in the complex matrix samples such as rice and millet with the recoveries for the spiked samples at 5.0 and 10.0 u,g/g falling in the range of 92.0-98.0%and the relative standard deviation of 3.9-5.7%.展开更多
A fast analytical method for the simultaneous determination of 9 mycotoxins, including alfatoxins （B1, B2, G1, and G2）, fumonisins （B1, B2 and B3）, zearalenone, and deoxynivalenol in corn using dispersive solid-ph...A fast analytical method for the simultaneous determination of 9 mycotoxins, including alfatoxins （B1, B2, G1, and G2）, fumonisins （B1, B2 and B3）, zearalenone, and deoxynivalenol in corn using dispersive solid-phase extraction method and ultra-performance liquid chromatography coupled to tandem quadrupole time-of-lfight mass spectrometry （UPLC-Q-TOF-MS） was developed and validated. Samples were extracted with acetonitrile-water （84：16, v：v, containing 1% acetic acid） using ultrasonic extraction. The extracts were puriifed with a dispersive SPE method using C18 as a cleaning agent. The ifnal clear extracts were dried by nitrogen blowing and subsequently redissolved in methanol-water （5：5, v：v）. The samples were then analyzed by UPLC-Q-TOF-MS with 0.1% formic acid in ammonium acetate-methanol as mobile phase. The mean recoveries were ranged from 68.0 to 120.0%, and the relative standard deviation （RSD） ranged from 0.18 to 6.29%. Limits of detections ranged from 0.05 to 50 μg kg？1, and limits of quantiifcation ranged from 0.1 to 200 μg kg？1, which were below the legal limits set by the European Union for the legislated mycotoxins. The developed method was applied to 130 corn samples. Among the mycotoxins studied, alfatoxins B1 and fumonisins B1, B2 and B3 were the most predominant mycotoxins, and their concentrations were 0–593.12, 0–2.01×104, 0–6.94×103 and 0–3.05×103 μg kg–1, respectively.展开更多
On the basis of classical linear theory on longitudinal, torsional and flexural waves in thin elastic rods, and taking finite deformation and dispersive effects into consideration, three kinds of nonlinear evolution e...On the basis of classical linear theory on longitudinal, torsional and flexural waves in thin elastic rods, and taking finite deformation and dispersive effects into consideration, three kinds of nonlinear evolution equations are derived. Qualitative analysis of three kinds of nonlinear equations are presented. It is shown that these equations have homoclinic or heteroclinic orbits on the phase plane, corresponding to solitary wave or shock wave solutions, respectively. Based on the principle of homogeneous balance, these equations are solved with the Jacobi elliptic function expansion method. Results show that existence of solitary wave solution and shock wave solution is possible under certain conditions. These conclusions are consistent with qualitative analysis.展开更多
A simple method has been proposed for the determination of clozapine （CLZ） and chlorpromazine （CPZ） in human urine by dispersive liquid-liquid microextraction （DLLME） in combination with high-performance liquid ...A simple method has been proposed for the determination of clozapine （CLZ） and chlorpromazine （CPZ） in human urine by dispersive liquid-liquid microextraction （DLLME） in combination with high-performance liquid chromatography-ultraviolet detector （HPLC-UV）. All important variables influencing the extraction efficiency, such as pH, types of the extraction solvent and the disperser solvent and their volume, ionic strength and centrifugation time were investigated and optimized. Under the optimal conditions, the limit of detection （LODs） and quantification （LOQs） of the method were 13 and 39 ng/mL for CLZ, and 2 and 6 ng/mL for CPZ, respectively. The relative standard deviations （RSDs） of the targets were less than 5.1% （C=0.100 μg/mL, n=9）. Good linear behaviors over the tested concentration ranges were obtained with the values of R20.999 for the targets. The absolute extraction efficiencies of CLZ and CPZ from the spiked blank urine samples were 98.3% and 97.8%, respectively. The applicability of the technique was validated by analyzing urine samples and the mean recoveries for spiked urine samples ranged from 93.3% to 105.0%. The method was successfully applied for the determination of CLZ and CPZ in real human urine.展开更多
We investigate (2+1)-dimensional generalized modified dispersive water wave (GMDWW) equation by utilizing the bifurcation theory of dynamical systems. We give the phase portraits and bifurcation analysis of the plane ...We investigate (2+1)-dimensional generalized modified dispersive water wave (GMDWW) equation by utilizing the bifurcation theory of dynamical systems. We give the phase portraits and bifurcation analysis of the plane system corresponding to the GMDWW equation. By using the special orbits in the phase portraits, we analyze the existence of the traveling wave solutions. When some parameter takes special values, we obtain abundant exact kink wave solutions, singular wave solutions, periodic wave solutions, periodic singular wave solutions, and solitary wave solutions for the GMDWW equation.展开更多
A novel temperature controlled ionic liquid dispersive liquid phase microextracfion （TCIL-DLPME） coupled with rapid resolution liquid chromatography-electrospray tandem mass spectrometry （RRLC-ESI-MS-MS） has been ...A novel temperature controlled ionic liquid dispersive liquid phase microextracfion （TCIL-DLPME） coupled with rapid resolution liquid chromatography-electrospray tandem mass spectrometry （RRLC-ESI-MS-MS） has been developed for the enrichment and determination of three hexabromocyclododecane diastereomers （HBCDs） in water samples. Green solvent ionic liquid （IL） was used as extraction solvent instead of toxic organic solvents. This technique also avoided the usage of dispersive solvent. Some important parameters that might affect the extraction efficiency were optimized. Under the optimum conditions, good linear relationship, sensitivity and reproducibility were obtained. All the limits of detection for the three diastereomers were 0.1 ng/ mL. The linear range was obtained in the range of 1-100 ng/mL for the total amount of three HBCD diastereomers. It was satisfactory to analyze real environmental water samples with the recoveries ranging from 77.2% to 99.3%. The main advantage of the method is toxic organic solvent-free.展开更多
New exact solutions expressed by the Jacobi elliptic functions are obtained to the （2＋1）-dimensional dispersive long-wave equations by using the modified F-expansion method. In the limit case, new solitary wave sol...New exact solutions expressed by the Jacobi elliptic functions are obtained to the （2＋1）-dimensional dispersive long-wave equations by using the modified F-expansion method. In the limit case, new solitary wave solutions and triangular periodic wave solutions are obtained as well.展开更多
Using a simple homogeneous balance method,which is very concise and primary,we find the multiple soliton solutions of the dispersive long-wave equations.The method can be generalized to deal with the higher dimensiona...Using a simple homogeneous balance method,which is very concise and primary,we find the multiple soliton solutions of the dispersive long-wave equations.The method can be generalized to deal with the higher dimensional dispersive long-wave equations and other class of nonlinear equation.展开更多
Dispersive optics quantum key distribution(DO-QKD)based on energy-time entangled photon pairs is an important QKD scheme.In DO-QKD,the arrival time of photons is used in key generation and security analysis,which woul...Dispersive optics quantum key distribution(DO-QKD)based on energy-time entangled photon pairs is an important QKD scheme.In DO-QKD,the arrival time of photons is used in key generation and security analysis,which would be greatly affected by fiber dispersion.In this work,we establish a theoretical model of the entanglement-based DO-QKD system,considering the protocol,physical processes(such as fiber transmission and single-photon detection),and the analysis of security tests.Based on this theoretical model,we investigate the influence of chromatic dispersion introduced by transmission fibers on the performance of DO-QKD.By analyzing the benefits and costs of dispersion compensation,the system performance under G.652 and G.655 optical fibers are shown,respectively.The results show that dispersion compensation is unnecessary for DO-QKD systems in campus networks and even metro networks.Whereas,it is still required in DO-QKD systems with longer fiber transmission distances.展开更多
Alternating direction implicit finite difference time domain （ADI-FDTD） method is unconditionally stable and the maximum time step is not limited by the Courant stability condition, but rather by numerical error. Co...Alternating direction implicit finite difference time domain （ADI-FDTD） method is unconditionally stable and the maximum time step is not limited by the Courant stability condition, but rather by numerical error. Compared with the conventional FDTD method, the time step of ADI-FDTD can be enlarged arbitrarily and the CPU cost can be reduced. 2D perfectly matched layer （PML） absorbing boundary condition is proposed to truncate computation space for ADI-FDTD in dispersive media using recursive convolution（RC） method and the 2D PML formulations for dispersive media are derived. ADI-FDTD formulations for dispersive media can be obtained from the simplified PML formulations. The scattering of target in dispersive soil is simulated under sine wave and Gaussian pulse excitations and numerical results of ADI-FDTD with PML are compared with FDTD. Good agreement is observed. At the same time the CPU cost for ADI-FDTD is obviously reduced.展开更多
Enrichment of trace bioactive constituents and metabolites from complex biological samples is challenging.This study presented a one-pot synthesis of magnetic polydopamine nanoparticles(Fe3O4@-SiO2@PDA NPs)with multip...Enrichment of trace bioactive constituents and metabolites from complex biological samples is challenging.This study presented a one-pot synthesis of magnetic polydopamine nanoparticles(Fe3O4@-SiO2@PDA NPs)with multiple recognition sites for the magnetic dispersive solid-phase extraction(MDSPE)of ginsenosides from rat plasma treated with white ginseng.The extracted ginsenosides were characterized by combining an ultra-high-performance liquid chromatography coupled to a highresolution mass spectrometry with supplemental UNIFI libraries.Response surface methodology was statistically used to optimize the extraction procedure of the ginsenosides.The reusability of Fe3O4@-SiO2@PDA NPs was also examined and the results showed that the recovery rate exceeded 80%after recycling 6 times.Furthermore,the proposed method showed greater enrichment efficiency and could rapidly determine and characterize 23 ginsenoside prototypes and metabolites from plasma.In comparison,conventional methanol method can only detect 8 ginsenosides from the same plasma samples.The proposed approach can provide methodological reference for the trace determination and characterization of different bioactive ingredients and metabolites of traditional Chinese medicines and food.展开更多
基金financially supported by the National Postdoctoral Program for Innovative Talents(Grant No.BX20200287)the National Natural Science Foundation of China(Grant Nos.52079116 and 52378322).
文摘This study addresses the challenges posed by dispersive soil in various engineering fields,including hydraulic and agricultural engineering,by exploring the effects of physical adsorption on soil modification.The primary objective is to identify an environmentally friendly stabilizer that can alleviate cracking and erosion resulting from soil dispersivity.Activated carbon(AC),known for its porous nature,was examined for its potential to enhance soil strength and erosion resistance.The charge neutralization process was evaluated by monitoring pH and conductivity,in addition to a comprehensive analysis of microscopic and mineral properties.The results show that high sodium levels or low clay contents result in the dispersive nature of soil in water.However,the incorporation of AC can transform such soil into a non-dispersive state.Moreover,both soil strength and erosion resistance exhibited enhancements with increasing AC content and curing duration.The incorporation of AC resulted in a maximum 5.6-fold increase in unconfined compressive strength and a 1.8-fold increase in tensile strength for dispersive soil.Notably,a significant correlation was observed during the curing phase among soil dispersivity,mechanical properties,and pH values.Microscopic analyses revealed that the porous structure of AC facilitated a filling effect and enhanced adsorption capacity,which contributed to improved soil characteristics and reduced dispersivity.The release of hydrogen ions and the formation of aggregates promote water stability.Validation tests conducted on dispersive soil from northern Shaanxi demonstrated the efficacy of physical adsorption using AC as a viable method for modifying dispersive soil in the water conservancy hub.
文摘For the (2 + 1)-dimensional nonlinear dispersive Boussinesq equation, by using the bifurcation theory of planar dynamical systems to study its corresponding traveling wave system, the bifurcations and phase portraits of the regular system are obtained. Under different parametric conditions, various sufficient conditions to guarantee the existence of analytical and non-analytical solutions of the singular system are given by using singular traveling wave theory. For certain special cases, some explicit and exact parametric representations of traveling wave solutions are derived such as analytical periodic waves and non-analytical periodic cusp waves. Further, two-dimensional wave plots of analytical periodic solutions and non-analytical periodic cusp wave solutions are drawn to visualize the dynamics of the equation.
文摘High-order models with a dissipative term for nonlinear and dispersive wave in water of varying depth with an arbitrary sloping bottom are presented in this article. First, the formal derivations to any high order of mu(= h/lambda, depth to deep-water wave length ratio) and epsilon(= a/h, wave amplitude to depth ratio) for velocity potential, particle velocity vector, pressure and the Boussinesq-type equations for surface elevation eta and horizontal velocity vector (U) over right arrow at any given level in water are given. Then, the exact explicit expressions to the fourth order of mu are derived. Finally, the linear solutions of eta, (U) over right arrow, C (phase-celerity) and C-g (group velocity) for a constant water depth are obtained. Compared with the Airy theory, excellent results can be found even for a water depth as large as the wave legnth. The present high-order models are applicable to nonlinear regular and irregular waves in water of any varying depth (from shallow to deep) and bottom slope (from mild to steep).
基金supported both by the Natural Science Foundations of Hebei(No.B2008000210)the Scientific Research Foundation of Agricultural University of Hebei.
文摘A novel method for the determination of five carbamate pesticides （metolcarb, carbofuran, carbaryl, isoprocard and diethofencard） in water samples was developed by dispersive liquid-liquid microextraction （DLLME） coupled with high performance liquid chromatography-diode array detector （HPLC-DAD）. Some experimental parameters that influence the extraction efficiency were studied and optimized to obtain the best extraction results. Under the optimum conditions for the method, the calibration curve was linear in the concentration range from 5 to 1000 ng mL^-1 for all the five carbamate pesticides, with the correlation coefficients （r^2） varying from 0.9984 to 0.9994. Good enrichment factors were achieved ranging from 80 to 177- fold, depending on the compound. The limits of detection （LODs） （S/N = 3） were ranged from 0.1 to 0.5 ng mL^-1. The method has been successfully applied to the analysis of the pesticide residues in environmental water samples.
基金the National Natural Science Foundation of China(Nos.20375035,20527005,20775070)by Zhejiang Provincial Natural Science Foundation of China(Nos.Z404105,Y507252).
文摘In this work, a new microextraction method termed ionic liquid based dispersive liquid-liquid microextraction （IL-DLLME） was demonstrated for the extraction of 2-methylaniline, 4-chloroaniline, 1-naphthylamine and 4-aminobiphenyl in aqueous matrices. After extraction the ionic liquid （IL） phase was injected directly into the high performance liquid chromatography （HPLC） system for determination. Some parameters that might affect the extraction efficiency were optimized. Under the optimum conditions, good linear relationship, sensitivity and reproducibility were obtained. The limits of detection （LOD, S/N = 3） for the four analytes were in the range of 0.45-2.6 μg L^-1. The relative standard deviations （R.S.D., n = 6） were in the range of 6.2-9.8%. This method was applied for the analysis of the real water samples. The recoveries ranged from 93.4 to 106.4%. The main advantages of the method are high speed, high recovery, good repeatability and volatile organic solvent-free.
文摘This article is concerned with the extended homogeneous balance method for studying the abundant localized solution structures in the (2+1)-dimensional dispersive long-wave equations . Starting from the homogeneous balance method, we find that the richness of the localized coherent structures of the model is caused by the entrance of two variable-separated arbitrary functions. For some special selections of the arbitrary functions, it is shown that the localized structures of the model may be dromions, lumps, breathers, instantons and ring solitons.
文摘A complete discrimination system for the fourth order polynomial is given. As an application, we have reduced a （1＋1）-dimensional dispersive long wave equation with general coefficients to an elementary integral form and obtained its all possible exact travelling wave solutions including rational function type solutions, solitary wave solutions, triangle function type periodic solutions and Jacobian elliptic functions double periodic solutions. This method can be also applied to many other similar problems.
基金Project supported by the Natural Science Foundation of Zhejiang Province, China (Grant Nos. Y6100257 and Y6110140)
文摘By using a mapping approach and a linear variable separation approach, a new family of solitary wave solutions with arbitrary functions for the （2＋1）-dimensional modified dispersive water-wave system （MDWW） is derived. Based on the derived solutions and using some multi-valued functions, we obtain some novel folded localized excitations of the system.
基金supported by the Sapienza University of Rome through the project RICERCA 2019(protocol number:RG11916B6451D44A)。
文摘In the present work,dispersive liquid-liquid microextraction(DLLME)was used to extract six synthetic cannabinoids(JWH-018,JWH-019,JWH-073,JWH-200,or WIN 55,225,JWH-250,and AM-694)from oral fluids.A rapid baseline separation of the analytes was achieved on a bidentate octadecyl silica hydride phase(Cogent Bidentate C18;4.6 mm×250 mm,4μm)maintained at 37℃,by eluting in isocratic conditions(water:acetonitrile(25:75,V/V)).Detection was performed using positive electrospray ionization-tandem mass spectrometry.The parameters affecting DLLME(pH and ionic strength of the aqueous phase,type and volume of the extractant and dispersive solvent,vortex and centrifugation time)were optimized for maximizing yields.In particular,using 0.5 mL of oral fluid,acetonitrile(1 mL),was identified as the best option,both as a solvent to precipitate proteins and as a dispersing solvent in the DLLME procedure.To select an extraction solvent,a low transition temperature mixture(LTTM;composed of sesamol and chlorine chloride with a molar ratio of 1:3)and dichloromethane were compared;the latter(100μL)was proved to be a better extractant,with recoveries ranging from 73%to 101%by vortexing for 2 min.The method was validated according to the guidelines of Food and Drug Administration bioanalytical methods:intra-day and inter-day precisions ranged between 4%and 18%depending on the spike level and analyte;limits of detection spanned from 2 to 18 ng/mL;matrixmatched calibration curves were characterized by determination coefficients greater than 0.9914.Finally,the extraction procedure was compared with previous methods and with innovative techniques,presenting superior reliability,rapidity,simplicity,inexpensiveness,and efficiency.
基金supported by the Natural Science Foundation of Hebei(No.B2010000657)
文摘A novel,simple,rapid,efficient and environment-friendly method for the determination of trace copper in cereal samples was developed by using dispersive liquid-liquid microextraction based on solidification of floating organic drop（DLLME-SFO） followed by flame atomic absorption spectrometry.In the DLLME-SFO,copper was complexed with 8-hydroxy quinoline and extracted into a small volume of 1-dodecanol,which is of low density,low toxicity and proper melting point near room temperature. The experimental parameters affecting the extraction efficiency were investigated and optimized.Under the optimum conditions, the calibration graph exhibited linearity over the range of 0.5—500 ng/mL with the correlation coefficient（r） of 0.9996.The enrichment factor was 122 and the limit of detection was 0.1 ng/mL.The method was applied to the determination of copper in the complex matrix samples such as rice and millet with the recoveries for the spiked samples at 5.0 and 10.0 u,g/g falling in the range of 92.0-98.0%and the relative standard deviation of 3.9-5.7%.
基金supported by the Key Project of Science and Technology Development Program of Shandong Province,China(2013KF03)
文摘A fast analytical method for the simultaneous determination of 9 mycotoxins, including alfatoxins （B1, B2, G1, and G2）, fumonisins （B1, B2 and B3）, zearalenone, and deoxynivalenol in corn using dispersive solid-phase extraction method and ultra-performance liquid chromatography coupled to tandem quadrupole time-of-lfight mass spectrometry （UPLC-Q-TOF-MS） was developed and validated. Samples were extracted with acetonitrile-water （84：16, v：v, containing 1% acetic acid） using ultrasonic extraction. The extracts were puriifed with a dispersive SPE method using C18 as a cleaning agent. The ifnal clear extracts were dried by nitrogen blowing and subsequently redissolved in methanol-water （5：5, v：v）. The samples were then analyzed by UPLC-Q-TOF-MS with 0.1% formic acid in ammonium acetate-methanol as mobile phase. The mean recoveries were ranged from 68.0 to 120.0%, and the relative standard deviation （RSD） ranged from 0.18 to 6.29%. Limits of detections ranged from 0.05 to 50 μg kg？1, and limits of quantiifcation ranged from 0.1 to 200 μg kg？1, which were below the legal limits set by the European Union for the legislated mycotoxins. The developed method was applied to 130 corn samples. Among the mycotoxins studied, alfatoxins B1 and fumonisins B1, B2 and B3 were the most predominant mycotoxins, and their concentrations were 0–593.12, 0–2.01×104, 0–6.94×103 and 0–3.05×103 μg kg–1, respectively.
基金Project supported by the National Natural Science Foundation of China (No.10772129)the Youth Science Foundation of Shanxi Province of China (No.2006021005)
文摘On the basis of classical linear theory on longitudinal, torsional and flexural waves in thin elastic rods, and taking finite deformation and dispersive effects into consideration, three kinds of nonlinear evolution equations are derived. Qualitative analysis of three kinds of nonlinear equations are presented. It is shown that these equations have homoclinic or heteroclinic orbits on the phase plane, corresponding to solitary wave or shock wave solutions, respectively. Based on the principle of homogeneous balance, these equations are solved with the Jacobi elliptic function expansion method. Results show that existence of solitary wave solution and shock wave solution is possible under certain conditions. These conclusions are consistent with qualitative analysis.
基金supported by Science Research Funds of Medical Course, HUST
文摘A simple method has been proposed for the determination of clozapine （CLZ） and chlorpromazine （CPZ） in human urine by dispersive liquid-liquid microextraction （DLLME） in combination with high-performance liquid chromatography-ultraviolet detector （HPLC-UV）. All important variables influencing the extraction efficiency, such as pH, types of the extraction solvent and the disperser solvent and their volume, ionic strength and centrifugation time were investigated and optimized. Under the optimal conditions, the limit of detection （LODs） and quantification （LOQs） of the method were 13 and 39 ng/mL for CLZ, and 2 and 6 ng/mL for CPZ, respectively. The relative standard deviations （RSDs） of the targets were less than 5.1% （C=0.100 μg/mL, n=9）. Good linear behaviors over the tested concentration ranges were obtained with the values of R20.999 for the targets. The absolute extraction efficiencies of CLZ and CPZ from the spiked blank urine samples were 98.3% and 97.8%, respectively. The applicability of the technique was validated by analyzing urine samples and the mean recoveries for spiked urine samples ranged from 93.3% to 105.0%. The method was successfully applied for the determination of CLZ and CPZ in real human urine.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11361069 and 11775146).
文摘We investigate (2+1)-dimensional generalized modified dispersive water wave (GMDWW) equation by utilizing the bifurcation theory of dynamical systems. We give the phase portraits and bifurcation analysis of the plane system corresponding to the GMDWW equation. By using the special orbits in the phase portraits, we analyze the existence of the traveling wave solutions. When some parameter takes special values, we obtain abundant exact kink wave solutions, singular wave solutions, periodic wave solutions, periodic singular wave solutions, and solitary wave solutions for the GMDWW equation.
基金financially supported by National Water Pollution Control and Management Technology Major Projects(No.2009ZX07210-009)Scientific and Technological Developing Project of Shandong Province(No. 2009GG20001021-9)+1 种基金Open Research Fund Program of Shandong Provincial Key Laboratory of Eco-Environmental Science for Yellow River Delta(No.2009KFJJ01)Basic Foundation of Shandong Academy of Sciences and Analysis and Test center of Shandong province
文摘A novel temperature controlled ionic liquid dispersive liquid phase microextracfion （TCIL-DLPME） coupled with rapid resolution liquid chromatography-electrospray tandem mass spectrometry （RRLC-ESI-MS-MS） has been developed for the enrichment and determination of three hexabromocyclododecane diastereomers （HBCDs） in water samples. Green solvent ionic liquid （IL） was used as extraction solvent instead of toxic organic solvents. This technique also avoided the usage of dispersive solvent. Some important parameters that might affect the extraction efficiency were optimized. Under the optimum conditions, good linear relationship, sensitivity and reproducibility were obtained. All the limits of detection for the three diastereomers were 0.1 ng/ mL. The linear range was obtained in the range of 1-100 ng/mL for the total amount of three HBCD diastereomers. It was satisfactory to analyze real environmental water samples with the recoveries ranging from 77.2% to 99.3%. The main advantage of the method is toxic organic solvent-free.
基金The project supported by the Natural Science Foundation of Shandong Province of China under Grant No. 2004 zx16
文摘New exact solutions expressed by the Jacobi elliptic functions are obtained to the （2＋1）-dimensional dispersive long-wave equations by using the modified F-expansion method. In the limit case, new solitary wave solutions and triangular periodic wave solutions are obtained as well.
文摘Using a simple homogeneous balance method,which is very concise and primary,we find the multiple soliton solutions of the dispersive long-wave equations.The method can be generalized to deal with the higher dimensional dispersive long-wave equations and other class of nonlinear equation.
基金the National Key R&D Program of China under Grants No.2017YFA0303704 and No.2018YFB2200400Natural Science Foundation of Beijing under Grant No.Z180012National Natural Science Foundation of China under Grants No.61875101 and No.91750206.
文摘Dispersive optics quantum key distribution(DO-QKD)based on energy-time entangled photon pairs is an important QKD scheme.In DO-QKD,the arrival time of photons is used in key generation and security analysis,which would be greatly affected by fiber dispersion.In this work,we establish a theoretical model of the entanglement-based DO-QKD system,considering the protocol,physical processes(such as fiber transmission and single-photon detection),and the analysis of security tests.Based on this theoretical model,we investigate the influence of chromatic dispersion introduced by transmission fibers on the performance of DO-QKD.By analyzing the benefits and costs of dispersion compensation,the system performance under G.652 and G.655 optical fibers are shown,respectively.The results show that dispersion compensation is unnecessary for DO-QKD systems in campus networks and even metro networks.Whereas,it is still required in DO-QKD systems with longer fiber transmission distances.
文摘Alternating direction implicit finite difference time domain （ADI-FDTD） method is unconditionally stable and the maximum time step is not limited by the Courant stability condition, but rather by numerical error. Compared with the conventional FDTD method, the time step of ADI-FDTD can be enlarged arbitrarily and the CPU cost can be reduced. 2D perfectly matched layer （PML） absorbing boundary condition is proposed to truncate computation space for ADI-FDTD in dispersive media using recursive convolution（RC） method and the 2D PML formulations for dispersive media are derived. ADI-FDTD formulations for dispersive media can be obtained from the simplified PML formulations. The scattering of target in dispersive soil is simulated under sine wave and Gaussian pulse excitations and numerical results of ADI-FDTD with PML are compared with FDTD. Good agreement is observed. At the same time the CPU cost for ADI-FDTD is obviously reduced.
基金This work was supported by grants from the National Natural Science Foundation of China Key Program(NO.81530094)General Program(NO.81573574,81873193)the Science and Technology Development Project of Jilin Province(20190201283JC).
文摘Enrichment of trace bioactive constituents and metabolites from complex biological samples is challenging.This study presented a one-pot synthesis of magnetic polydopamine nanoparticles(Fe3O4@-SiO2@PDA NPs)with multiple recognition sites for the magnetic dispersive solid-phase extraction(MDSPE)of ginsenosides from rat plasma treated with white ginseng.The extracted ginsenosides were characterized by combining an ultra-high-performance liquid chromatography coupled to a highresolution mass spectrometry with supplemental UNIFI libraries.Response surface methodology was statistically used to optimize the extraction procedure of the ginsenosides.The reusability of Fe3O4@-SiO2@PDA NPs was also examined and the results showed that the recovery rate exceeded 80%after recycling 6 times.Furthermore,the proposed method showed greater enrichment efficiency and could rapidly determine and characterize 23 ginsenoside prototypes and metabolites from plasma.In comparison,conventional methanol method can only detect 8 ginsenosides from the same plasma samples.The proposed approach can provide methodological reference for the trace determination and characterization of different bioactive ingredients and metabolites of traditional Chinese medicines and food.
