Photon pairs with large nondegeneracy have recently attracted increasing interest, which gives rise to an urgent demand for revealing their complete and accurate spectral distribution. By thoroughly analyzing parametr...Photon pairs with large nondegeneracy have recently attracted increasing interest, which gives rise to an urgent demand for revealing their complete and accurate spectral distribution. By thoroughly analyzing parametric down-conversion(PDC), we put forward a model to directly describe the spatial-spectral distribution of these photon pairs, which is experimentally demonstrated by a 532-nm pumped type-I PDC in a beta barium borate(BBO) crystal. The measured spectral curves show good agreement with the theoretical predictions over the entire spectral range. We further demonstrate that, as signal wavelength increases, the photon pairs are initially spectrally distinguishable, then partly indistinguishable, finally completely indistinguishable with a maximum bandwidth of approximately 500 nm. Utilizing photon-number-resolving single-photon detectors(SPD), we observe the average photon number decreases significantly more slowly than the spectral intensity as the wavelength deviates from the peak, and the photon numbers follow a quasi-Poisson distribution well for wavelengths around the peak, but a thermal distribution better describes the statistics near the spectral boundaries. Finally,we use the signal photons as the trigger to generate heralded Fock states up to 10 photons in near-infrared range, which are suitable for quantum simulation and quantum key distribution in optical fiber networks.展开更多
The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor ...The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor featuring a broad spectral absorption range,is successfully employed as the electron acceptor to combine with CdS for constructing a S-scheme heterojunction.The optimized photocatalyst(CdSCuO2∶1)delivers an exceptional hydrogen evolution rate of 18.89 mmol/(g·h),4.15-fold higher compared with bare CdS.X-ray photoelectron spectroscopy(XPS)and ultraviolet-visible diffuse reflection absorption spectroscopy(UV-vis DRS)confirmed the S-scheme band structure of the composites.Moreover,the surface photovoltage(SPV)and electron paramagnetic resonance(EPR)indicated that the photogenerated electrons and photogenerated holes of CdS-CuO2∶1 were respectively transferred to the conduction band(CB)of CdS with a higher reduction potential and the valence band(VB)of CuO with a higher oxidation potential under illumination,as expected for the S-scheme mechanism.Density-functional-theory calculations of the electron density difference(EDD)disclose an interfacial electric field oriented from CdS to CuO.This built-in field suppresses charge recombination and accelerates carrier migration,rationalizing the markedly enhanced PHE activity.This study offers a novel strategy for designing S-scheme heterojunctions with high light harvesting and charge utilization toward sustainable solar-tohydrogen conversion.展开更多
The fatigue crack growth rate of a novel Ti-6Al-4V-1Mo titanium alloy,which is developed for laser directed energy deposition technique,was investigated before and after cyclic heat treatment(CHT).Changes in microstru...The fatigue crack growth rate of a novel Ti-6Al-4V-1Mo titanium alloy,which is developed for laser directed energy deposition technique,was investigated before and after cyclic heat treatment(CHT).Changes in microstructure,fracture surfaces,and crack growth paths were analyzed before and after CHT.Results indicate that in the stable crack growth region,the growth rates for the as-deposited and cyclic heat-treated specimens follow the relationships da/dN=1.8651×10^(−8)(ΔK)^(3.2271)and da/dN=1.4112×10^(−8)(ΔK)^(3.1125),respectively.Compared with that at the as-deposited state,the microstructure after CHT is transformed from a uniform basket-weave microstructure to a dual-phase microstructure consisting of near-sphericalαandβ-transformed matrix phases.The cyclic process also disrupts the continuity of the grain boundaryα(αGB)at the primaryβ-phase grain boundary.The coarsening of primaryαand the disruption ofαGB continuity are the primary factors to release stress concentration and promote crack deflection,thereby decreasing the fatigue crack growth rate.Additionally,the increased occurrence of crack branching,secondary cracking,and crack bridging in cyclic heat-treated specimens further reduces the crack driving force and slows the fatigue crack growth rate.展开更多
Directional three-dimensional carbon-based foams are emerging as highly attractive candidates for promising electromagnetic wave absorbing materials(EWAMs)thanks to their unique architecture,but their construction usu...Directional three-dimensional carbon-based foams are emerging as highly attractive candidates for promising electromagnetic wave absorbing materials(EWAMs)thanks to their unique architecture,but their construction usually involves complex procedures and extremely depends on unidirectional freezing technique.Herein,we propose a groundbreaking approach that leverages the assemblies of salting-out protein induced by ammonium metatungstate(AM)as the precursor,and then acquire directional three-dimensional carbon-based foams through simple pyrolysis.The electrostatic interaction between AM and protein ensures well dispersion of WC_(1−x)nanoparticles on carbon frameworks.The content of WC_(1−x)nanoparticles can be rationally regulated by AM dosage,and it also affects the electromagnetic(EM)properties of final carbon-based foams.The optimized foam exhibits exceptional EM absorption performance,achieving a remarkable minimum reflection loss of−72.0 dB and an effective absorption bandwidth of 6.3 GHz when EM wave propagates parallel to the directional pores.Such performance benefits from the synergistic effects of macroporous architecture and compositional design.Although there is a directional dependence of EM absorption,radar stealth simulation demonstrates that these foams can still promise considerable reduction in radar cross section with the change of incident angle.Moreover,COMSOL simulation further identifies their good performance in preventing EM interference among different electronic components.展开更多
The Cooling-Storage-Ring External-target Experiment(CEE)at the Heavy Ion Research Facility in Lanzhou(HIRFL)is designed to study the properties of nuclear matter created in heavy-ion collisions at beam energies from a...The Cooling-Storage-Ring External-target Experiment(CEE)at the Heavy Ion Research Facility in Lanzhou(HIRFL)is designed to study the properties of nuclear matter created in heavy-ion collisions at beam energies from a few hundred MeV/u up to 1 GeV/u.It aims to facilitate research on the quantum chromodynamics(QCD)phase structure in the high-baryondensity region.Collective flow is a fundamental observable in heavy-ion collision experiments,providing information on the bulk properties of the produced matter.Although the standard event plane method has been widely used to measure collective flow,it is still important to validate and optimize this method for the CEE spectrometer.In this paper,we study the experimental procedures for measuring directed flow in^(238)U+^(238)U collisions at 500 MeV/u,using event planes reconstructed by Multi-Wire Drift Chamber and Zero Degree Calorimeter,respectively.Jet AA Microscopic(JAM)transport generator is used to generate events,and the detector response is simulated by the CEE Fast Simulation(CFS)package.Finally,the optimal kinematic region for proton directed flow measurements is discussed for the future CEE experiment.展开更多
The rapid expansion of lithium-ion batteries in electric vehicles and grid-scale energy storage intensify the demand for sustainable recycling strategies.Traditional metallurgical recycling methods face significant ch...The rapid expansion of lithium-ion batteries in electric vehicles and grid-scale energy storage intensify the demand for sustainable recycling strategies.Traditional metallurgical recycling methods face significant challenges,including high energy consumption,environmental pollution,and inefficient critical metals recovery.In contrast,advanced direct recycling can selectively extract valuable metals while preserving cathode structure,achieving over 99%lithium recovery from lithium iron phosphate.Moreover,by directly repairing defects and crystal structures of spent materials,their electrochemical performance can be effectively restored.Due to significantly reduced energy and reagent inputs,direct recycling cuts processing costs by over 20% and reduces waste emissions by at least 40% compared to conventional methods,making it a promising low-carbon alternative.This review systematically integrates the recent advances in direct recycling of spent batteries as well as the limitations and challenges of existing technologies,and proposes future research pathways to promote resource recycling and sustainable development.展开更多
For a multi-frequency non-reciprocal optical device,we first realize multi-frequency optical non-reciprocal transmission using a non-Hermitian multi-mode resonator array.Practically,multi-frequency operation can add c...For a multi-frequency non-reciprocal optical device,we first realize multi-frequency optical non-reciprocal transmission using a non-Hermitian multi-mode resonator array.Practically,multi-frequency operation can add channels to the non-reciprocal optical device and the non-reciprocity can route optical signals and prevent the reverse flow of noise.Using the Scully–Lamb model and gain saturation effect,we accomplish dual-frequency non-reciprocal transmission by introducing nonlinearity into a linear array of four-mode resonators.The accomplishment is directly demonstrated by the non-reciprocal transmission phenomena present in the non-divergent peaks.For example,a directional cyclic amplifier is constructed with non-reciprocal units.Regarding potential applications,non-reciprocal optical systems can be employed in dual-frequency control,parallel information processing,photonic integrated circuits,optical devices and so on.展开更多
Objective:To explore the interventional room nursing and its application effects in patients with ischemic stroke treated with tirofiban combined with direct thrombectomy.Methods:A total of 61 patients with ischemic s...Objective:To explore the interventional room nursing and its application effects in patients with ischemic stroke treated with tirofiban combined with direct thrombectomy.Methods:A total of 61 patients with ischemic stroke admitted to our hospital from June 2024 to June 2025 were selected and divided into two groups using the red and blue ball method:the control group(n=30,receiving routine interventional room nursing)and the observation group(n=31,receiving additional tirofiban medication-specific nursing+individualized interventional nursing on the basis of routine nursing).The cerebral hemodynamic indicators,adverse reactions,effectiveness of complication nursing,and nursing satisfaction were compared between the two groups.Results:After 7 days of treatment,the observation group had lower cerebrovascular peripheral resistance and higher mean blood flow velocity and mean blood flow volume compared to the control group(all p<0.05).The observation group had a higher effectiveness rate of complication nursing than the control group,with a statistically significant difference(p<0.05).The nursing satisfaction in the observation group(96.77%)was higher than that in the control group(80.00%),with a statistically significant difference(χ^(2)=4.223,p=0.040<0.05).Conclusion:Tirofiban combined with direct thrombectomy can significantly improve cerebral hemodynamics,enhance the effectiveness of complication nursing,and increase patient satisfaction in patients with ischemic stroke.展开更多
BACKGROUND Drug utilization research has an important role in assisting the healthcare administration to know,compute,and refine the prescription whose principal objective is to enable the rational use of drugs.Resear...BACKGROUND Drug utilization research has an important role in assisting the healthcare administration to know,compute,and refine the prescription whose principal objective is to enable the rational use of drugs.Research in developing nations relating to the cost of treatment is scarce when compared with developed countries.Thus,the drug utilization research studies from developing nations are most needed,and their number has been growing.AIM To evaluate patterns of utilization of antipsychotic drugs and direct medical cost analysis in patients newly diagnosed with schizophrenia.METHODS The present study was observational in type and based on a retrospective cohort to evaluate patterns of utilization of antipsychotic drugs using World Health Organization(WHO)core prescribing indicators and anatomical therapeutic chemical/defined daily dose indicators.We also calculated direct medical costs for a period of 6 months.RESULTS This study has found that atypical antipsychotics are the mainstay of treatment for schizophrenia in every age group and subcategories of schizophrenia.The evaluation based on WHO prescribing indicators showed a low average number of drugs per prescription and low prescribing frequency of antipsychotics from the National List of Essential Medicines 2015 and the WHO Essential Medicines List 2019.The total mean drug cost of our study was 1396 Indian rupees.The total mean cost due to the investigation in our study was 1017.34 Indian rupees.Therefore,the total mean direct medical cost incurred on patients in our study was 4337.28 Indian rupees.CONCLUSION The information from the present study can be used for reviewing and updating treatment policy at the institutional level.展开更多
Efficient energy utilization in covert communication sustains covertness while assuring communication quality and efficiency.This paper investigates covert communication energy efficiency(EE)in direct uplink satellite...Efficient energy utilization in covert communication sustains covertness while assuring communication quality and efficiency.This paper investigates covert communication energy efficiency(EE)in direct uplink satellite-ground communications,focusing on enhancing system EE via optimized transmit beamforming and satellite orbit altitude selection.This paper first establishes an optimization problem to maximize system EE in a direct uplink satelliteground covert communication scenario.To solve this non-convex optimization problem,it is decomposed into two subproblems and solved using the successive convex approximation(SCA)method.Based on the above methods,this paper proposes an overall iterative optimization algorithm.Simulation results demonstrate that the proposed algorithm surpasses the conventional baseline algorithms in terms of system EE.Furthermore,they elucidate the correlation between the amount of information received by the receiver and the variations in the satellite’s orbital altitude.展开更多
Biopolymeric nanocomposites have attracted considerable attention because of their biocompatibility,biodegradability,and unique physicochemical properties.It is essential to manufacture three-dimensional(3D)biocompati...Biopolymeric nanocomposites have attracted considerable attention because of their biocompatibility,biodegradability,and unique physicochemical properties.It is essential to manufacture three-dimensional(3D)biocompatible micro/nanostructures using biopolymeric nanocomposites.Herein,we demonstrate the high-fidelity fabrication of biocompatible 3D features with sub-50 nm resolution using femtosecond laser direct writing(FsLDW)of a biopolymeric nanocomposite composed of egg white and sulfonated graphene(S-graphene).The biopolymer nanocomposite acts as a negative photoresist suitable for water-based lithography.The introduction of S-graphene not only dramatically lowered the laser power threshold but also significantly modulated the morphology of the 3D features constructed by FsLDW.Microstructures with porous,rough,or smooth morphologies were obtained by optimizing the S-graphene concentration and laser scanning speed.The fabricated egg-white/S-graphene microstructures exhibited biocompatibility and environmental degradability.Egg white/S-graphene was also employed to fabricate diffractive gratings with superior optical quality.This study provides a promising method to manufacture biocompatible 3D features with controllable morphology,which has potential applications in biological and photonic fields.展开更多
The rapid accumulation of spent LiFePO_(4)(LFP)cathodes from retired lithium-ion batteries necessitates the development of effective and environmental-friendly recycling strategies.In this context,direct regeneration ...The rapid accumulation of spent LiFePO_(4)(LFP)cathodes from retired lithium-ion batteries necessitates the development of effective and environmental-friendly recycling strategies.In this context,direct regeneration has emerged as a promising approach for reclaiming LFP cathode materials,offering a streamlined pathway to restore their electrochemical functionality.We report an integrated regeneration protocol that simultaneously repairs the degraded crystal structure and reconstructs the damaged carbon coating in spent LFP.The regenerated cathode material had superfast lithium-ion diffusion kinetics and a stable cathode-electrolyte interface,giving a remarkable rate capability with specific capacities of 122 m Ah g^(-1)at 5C and 106 m Ah g^(-1)at 10C(1C=170 m A g^(-1)).It also maintained capacities of 110.7 m Ah g^(-1)(5C)and 84.1 m Ah g^(-1)(10C)after 400 cycles.It could be used in harsh environments and could be stably cycled at subzero temperatures(-10 and-20°C)and in solid-state electrolyte batteries.Life cycle assessment combined with economic evaluation using the Ever Batt model reveals that this direct regeneration approach has high economic and environmental benefits.展开更多
When stacking two-dimensional(2D)materials with a lattice mismatch and/or a small twist,moirésuperlattice emerges with fascinating electronic and optical properties.The fabrication of such stacked 2D materials us...When stacking two-dimensional(2D)materials with a lattice mismatch and/or a small twist,moirésuperlattice emerges with fascinating electronic and optical properties.The fabrication of such stacked 2D materials usually requires multiple transfer and stack processes,assisted by a certain transfer medium which needs to be removed afterwards,and it is very challenging to maintain pristine and clean surfaces/interfaces for these stacked structures.In this work,we report a facile direct bonding method for fabrication of twisted MoS_(2) bilayers with ultra-clean surfaces/interfaces.Novel interlayer interactions are revealed in the as-fabricated high-quality samples,leading to twist-angle related dispersion behavior of various Raman modes,such as layer breathing modes,shear modes and E_(2g)modes,as well as indirect bandgap excitons.Field-effect transistors(FETs)of twisted MoS_(2) bilayers also exhibit angle-dependent performance,which could be attributed to the band structure evolution.This facile method holds significance for the future integration of pre-designed multilayer 2D materials and paves a way to explore underlying physical mechanisms and potential applications.展开更多
Exercise produces a decrease in pain sensitivity via an effect called exercise-induced hypoalgesia(EIH).Transcranial direct current stimulation(tDCS),acting on similar analgesic mechanisms as EIH,represents a potentia...Exercise produces a decrease in pain sensitivity via an effect called exercise-induced hypoalgesia(EIH).Transcranial direct current stimulation(tDCS),acting on similar analgesic mechanisms as EIH,represents a potential complementary intervention that may amplify the effects of exercise on pain.This study aimed to explore if anodal tDCS could enhance the effect of exercise on pain compared to exercise alone.A total of 35 healthy participants aged 19–37 years completed a familiarisation session followed by two separate sessions where active and sham tDCS was applied in a randomised cross-over design.The familiarisation session involved familiarisation to the pain assessment and exercise tasks,while the subsequent tDCS sessions involved pain sensitivity assessment,exercise and either anodal tDCS or sham tDCS.tDCS doses were applied at 2 mA over the primary motor cortex for 10 min,with the reference electrode placed over the contralateral supraorbital area.The exercise task involved a sustained isometric grip strength contraction at 35%of maximal voluntary contraction(MVC)until volitional exhaustion.Pain sensitivity was evaluated as pressure pain threshold before tDCS,after tDCS,and after exercise.Across both tDCS conditions,pain threshold was higher after exercise when compared to pre-and post-tDCS measurement.This increase in pain threshold did not differ between active and sham tDCS conditions.Our findings suggest that the hypoalgesic effects of active anodal tDCS over the motor cortex prior to exercise are no greater than the effects of sham tDCS prior to exercise.展开更多
The 193 nm deep-ultraviolet(DUV)laser plays a critical role in advanced semiconductor chip manufacturing[1,2],micro-nano material characterization[3,4]and biomedical analysis[5,6],due to its high spatial resolution an...The 193 nm deep-ultraviolet(DUV)laser plays a critical role in advanced semiconductor chip manufacturing[1,2],micro-nano material characterization[3,4]and biomedical analysis[5,6],due to its high spatial resolution and short wavelength.Efficient and compact 193 nm DUV laser source thus becomes a hot research area.Currently,193 nm Ar F excimer gas laser is widely employed in DUV lithography systems and serves as the enabling technology for 7 and 5 nm semiconductor fabrication.展开更多
Direct regeneration is considered a sustainable solution to the issue of resource recycling and the environmental pollution caused by discarded lithium-ion batteries(LIBs).However,the direct regeneration of spent LiFe...Direct regeneration is considered a sustainable solution to the issue of resource recycling and the environmental pollution caused by discarded lithium-ion batteries(LIBs).However,the direct regeneration of spent LiFePO_(4)cathode materials still faces a formidable challenge that the irregular strains induced by the irreversible FePO_(4)phase after several charge and discharge cycles hinder the regenerative replenishment of Li^(+).This work proposes a lattice stress modulation strategy that reduces FePO_(4)phase into Fe_(2)P_(2)O_(7)phase(reduction of unit cell volume from 271.7 to 122.6Å^(3)),which releases the residual stress,paving continuous transport channels for Li^(+).In addition,the phase transformation reconstructs the FeO6 octahedra,significantly decreasing the migration energy barrier of ions within the lattice.Ultimately,the steric effect is synergistically weakened,facilitating the replenishment of Li^(+)and the elimination of Li-Fe anti-site defects.The regenerated LiFePO_(4)cathodes outperform commercial cathodes(80.2%capacity retention after 1000 cycles at 2 C).This work establishes fundamental principles for the pretreatment stage of the direct regeneration process and provides a paradigm shifting solution for sustainable LIBs recycling technology.展开更多
In this study,α-TeO2：Ho3＋/Yb3＋,α-TeO2：Eu3＋ andα-TeO2：Ho3＋/Yb3＋/Eu3＋ nanoparticles were prepared via a simple hydrothermal process. The up- and down-conversion properties of the as-prepared nanoparticles we...In this study,α-TeO2：Ho3＋/Yb3＋,α-TeO2：Eu3＋ andα-TeO2：Ho3＋/Yb3＋/Eu3＋ nanoparticles were prepared via a simple hydrothermal process. The up- and down-conversion properties of the as-prepared nanoparticles were tested at room temperature un-der a near-infrared photo source （980 nm） and UV-vis photo source, respectively.The results indicated thatα-TeO2 NPs were a kind of outstanding host material for both up- and down-conversion luminescence. Theα-TeO2：Ho3＋/Yb3＋nanoparticles showed sharp up-conversion emission at 545 and 660 nm under 980 nm excitation, ascribed to the5S2→5I8 and5F5→5I8（Ho3＋） transitions, and weaker down-conversion emission at 545 nm under 455 nm excitation, ascribed to the5S2→5I8（Ho3＋） transitions. Theα-TeO2：Eu3＋nanoparticles showed strong down-conversion emission at 592 and 615 nm under 395 nm excitation, attributed to the5D0→7F1 and 5D0→7F2 （Eu3＋） transitions. Possessing the advantages of these two luminescent materials, the as-prepared tri-doped samples ofα-TeO2：0.5Ho3＋/10Yb3＋/3Eu3＋ （mol.%）nanoparticles could successfully emit visible light via both up- and down-conversion modes.展开更多
Near-infrared single photon sources in telecommunication bands, especially at 1550 nm, are required for long-distance quantum communication. Here a down-conversion quantum interface is implemented, where the single ph...Near-infrared single photon sources in telecommunication bands, especially at 1550 nm, are required for long-distance quantum communication. Here a down-conversion quantum interface is implemented, where the single photons emitted from single In As quantum dot at 864 nm is down converted to 1552 nm by using a fiber-coupled periodically poled lithium niobate（PPLN） waveguide and a 1.95 μmm pump laser, and the frequency conversion efficiency is ~40%. The singlephoton purity of quantum dot emission is preserved during the down-conversion process, i.e., g^（（2））（0）, only 0.22 at 1552 nm.This present technique advances the Ⅲ-Ⅴ semiconductor quantum dots as a promising platform for long-distance quantum communication.展开更多
We study the effect of waveguide thickness variations on the frequency spectrum of spontaneous parametric downconversion in the periodically-poled lithium niobate on insulator(LNOI)waveguide.We analyze several variati...We study the effect of waveguide thickness variations on the frequency spectrum of spontaneous parametric downconversion in the periodically-poled lithium niobate on insulator(LNOI)waveguide.We analyze several variation models and our simulation results show that thickness variations in several nanometers can induce distinct effects on the central peak of the spectrum,such as narrowing,broadening,and splitting.We also prove that the effects of positive and negative variations can be canceled and thus lead to a variation-robust feature and an ultra-broad bandwidth.Our study may promote the development of on-chip photon sources in the LNOI platform,as well as opens up a way to engineer photon frequency state.展开更多
In recent years, much attention has been paid to software-defined radio （SDR） technologies for multimode wireless systems SDR can be defined as a radio communication system that uses software to modulate and demodul...In recent years, much attention has been paid to software-defined radio （SDR） technologies for multimode wireless systems SDR can be defined as a radio communication system that uses software to modulate and demodulate radio signals. This article describes concepts, theory, and design principles for SDR down-conversion and up-conversion. Design issues in SDR down-conversion are discussed, and two different architectures, super-heterodyne and direct-conversion, are proposed. Design issues in SDR up-conversion are also discussed, and trade-offs in the design of filters, mixers, NCO, DAC, and signal processing are highlighted.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No. 62075010)。
文摘Photon pairs with large nondegeneracy have recently attracted increasing interest, which gives rise to an urgent demand for revealing their complete and accurate spectral distribution. By thoroughly analyzing parametric down-conversion(PDC), we put forward a model to directly describe the spatial-spectral distribution of these photon pairs, which is experimentally demonstrated by a 532-nm pumped type-I PDC in a beta barium borate(BBO) crystal. The measured spectral curves show good agreement with the theoretical predictions over the entire spectral range. We further demonstrate that, as signal wavelength increases, the photon pairs are initially spectrally distinguishable, then partly indistinguishable, finally completely indistinguishable with a maximum bandwidth of approximately 500 nm. Utilizing photon-number-resolving single-photon detectors(SPD), we observe the average photon number decreases significantly more slowly than the spectral intensity as the wavelength deviates from the peak, and the photon numbers follow a quasi-Poisson distribution well for wavelengths around the peak, but a thermal distribution better describes the statistics near the spectral boundaries. Finally,we use the signal photons as the trigger to generate heralded Fock states up to 10 photons in near-infrared range, which are suitable for quantum simulation and quantum key distribution in optical fiber networks.
文摘The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor featuring a broad spectral absorption range,is successfully employed as the electron acceptor to combine with CdS for constructing a S-scheme heterojunction.The optimized photocatalyst(CdSCuO2∶1)delivers an exceptional hydrogen evolution rate of 18.89 mmol/(g·h),4.15-fold higher compared with bare CdS.X-ray photoelectron spectroscopy(XPS)and ultraviolet-visible diffuse reflection absorption spectroscopy(UV-vis DRS)confirmed the S-scheme band structure of the composites.Moreover,the surface photovoltage(SPV)and electron paramagnetic resonance(EPR)indicated that the photogenerated electrons and photogenerated holes of CdS-CuO2∶1 were respectively transferred to the conduction band(CB)of CdS with a higher reduction potential and the valence band(VB)of CuO with a higher oxidation potential under illumination,as expected for the S-scheme mechanism.Density-functional-theory calculations of the electron density difference(EDD)disclose an interfacial electric field oriented from CdS to CuO.This built-in field suppresses charge recombination and accelerates carrier migration,rationalizing the markedly enhanced PHE activity.This study offers a novel strategy for designing S-scheme heterojunctions with high light harvesting and charge utilization toward sustainable solar-tohydrogen conversion.
基金National Key Research and Development Program of China(2024YFB4610803)。
文摘The fatigue crack growth rate of a novel Ti-6Al-4V-1Mo titanium alloy,which is developed for laser directed energy deposition technique,was investigated before and after cyclic heat treatment(CHT).Changes in microstructure,fracture surfaces,and crack growth paths were analyzed before and after CHT.Results indicate that in the stable crack growth region,the growth rates for the as-deposited and cyclic heat-treated specimens follow the relationships da/dN=1.8651×10^(−8)(ΔK)^(3.2271)and da/dN=1.4112×10^(−8)(ΔK)^(3.1125),respectively.Compared with that at the as-deposited state,the microstructure after CHT is transformed from a uniform basket-weave microstructure to a dual-phase microstructure consisting of near-sphericalαandβ-transformed matrix phases.The cyclic process also disrupts the continuity of the grain boundaryα(αGB)at the primaryβ-phase grain boundary.The coarsening of primaryαand the disruption ofαGB continuity are the primary factors to release stress concentration and promote crack deflection,thereby decreasing the fatigue crack growth rate.Additionally,the increased occurrence of crack branching,secondary cracking,and crack bridging in cyclic heat-treated specimens further reduces the crack driving force and slows the fatigue crack growth rate.
基金financially supported by the National Natural Science Foundation of China(Nos.22475057 and No.52373262).
文摘Directional three-dimensional carbon-based foams are emerging as highly attractive candidates for promising electromagnetic wave absorbing materials(EWAMs)thanks to their unique architecture,but their construction usually involves complex procedures and extremely depends on unidirectional freezing technique.Herein,we propose a groundbreaking approach that leverages the assemblies of salting-out protein induced by ammonium metatungstate(AM)as the precursor,and then acquire directional three-dimensional carbon-based foams through simple pyrolysis.The electrostatic interaction between AM and protein ensures well dispersion of WC_(1−x)nanoparticles on carbon frameworks.The content of WC_(1−x)nanoparticles can be rationally regulated by AM dosage,and it also affects the electromagnetic(EM)properties of final carbon-based foams.The optimized foam exhibits exceptional EM absorption performance,achieving a remarkable minimum reflection loss of−72.0 dB and an effective absorption bandwidth of 6.3 GHz when EM wave propagates parallel to the directional pores.Such performance benefits from the synergistic effects of macroporous architecture and compositional design.Although there is a directional dependence of EM absorption,radar stealth simulation demonstrates that these foams can still promise considerable reduction in radar cross section with the change of incident angle.Moreover,COMSOL simulation further identifies their good performance in preventing EM interference among different electronic components.
基金supported in part by the National Key R&D Program of China(No.2024YFA1610700)the National Natural Science Foundation of China(No.12475147)。
文摘The Cooling-Storage-Ring External-target Experiment(CEE)at the Heavy Ion Research Facility in Lanzhou(HIRFL)is designed to study the properties of nuclear matter created in heavy-ion collisions at beam energies from a few hundred MeV/u up to 1 GeV/u.It aims to facilitate research on the quantum chromodynamics(QCD)phase structure in the high-baryondensity region.Collective flow is a fundamental observable in heavy-ion collision experiments,providing information on the bulk properties of the produced matter.Although the standard event plane method has been widely used to measure collective flow,it is still important to validate and optimize this method for the CEE spectrometer.In this paper,we study the experimental procedures for measuring directed flow in^(238)U+^(238)U collisions at 500 MeV/u,using event planes reconstructed by Multi-Wire Drift Chamber and Zero Degree Calorimeter,respectively.Jet AA Microscopic(JAM)transport generator is used to generate events,and the detector response is simulated by the CEE Fast Simulation(CFS)package.Finally,the optimal kinematic region for proton directed flow measurements is discussed for the future CEE experiment.
基金supported by the National Science Fund for Distinguished Young Scholars(52425706)。
文摘The rapid expansion of lithium-ion batteries in electric vehicles and grid-scale energy storage intensify the demand for sustainable recycling strategies.Traditional metallurgical recycling methods face significant challenges,including high energy consumption,environmental pollution,and inefficient critical metals recovery.In contrast,advanced direct recycling can selectively extract valuable metals while preserving cathode structure,achieving over 99%lithium recovery from lithium iron phosphate.Moreover,by directly repairing defects and crystal structures of spent materials,their electrochemical performance can be effectively restored.Due to significantly reduced energy and reagent inputs,direct recycling cuts processing costs by over 20% and reduces waste emissions by at least 40% compared to conventional methods,making it a promising low-carbon alternative.This review systematically integrates the recent advances in direct recycling of spent batteries as well as the limitations and challenges of existing technologies,and proposes future research pathways to promote resource recycling and sustainable development.
基金supported by the National Nature Science Foundation of China(Grant Nos.12475019 and 12073056)the Major National Science and Technology Project of China(Grant No.BX2024B054)+1 种基金National Lab of Solid State Microstructure of Nanjing University(Grant Nos.M35040,M35053,and M37014)the Natural Science Foundation of Shandong Province(Grant No.ZR2024MA038)。
文摘For a multi-frequency non-reciprocal optical device,we first realize multi-frequency optical non-reciprocal transmission using a non-Hermitian multi-mode resonator array.Practically,multi-frequency operation can add channels to the non-reciprocal optical device and the non-reciprocity can route optical signals and prevent the reverse flow of noise.Using the Scully–Lamb model and gain saturation effect,we accomplish dual-frequency non-reciprocal transmission by introducing nonlinearity into a linear array of four-mode resonators.The accomplishment is directly demonstrated by the non-reciprocal transmission phenomena present in the non-divergent peaks.For example,a directional cyclic amplifier is constructed with non-reciprocal units.Regarding potential applications,non-reciprocal optical systems can be employed in dual-frequency control,parallel information processing,photonic integrated circuits,optical devices and so on.
文摘Objective:To explore the interventional room nursing and its application effects in patients with ischemic stroke treated with tirofiban combined with direct thrombectomy.Methods:A total of 61 patients with ischemic stroke admitted to our hospital from June 2024 to June 2025 were selected and divided into two groups using the red and blue ball method:the control group(n=30,receiving routine interventional room nursing)and the observation group(n=31,receiving additional tirofiban medication-specific nursing+individualized interventional nursing on the basis of routine nursing).The cerebral hemodynamic indicators,adverse reactions,effectiveness of complication nursing,and nursing satisfaction were compared between the two groups.Results:After 7 days of treatment,the observation group had lower cerebrovascular peripheral resistance and higher mean blood flow velocity and mean blood flow volume compared to the control group(all p<0.05).The observation group had a higher effectiveness rate of complication nursing than the control group,with a statistically significant difference(p<0.05).The nursing satisfaction in the observation group(96.77%)was higher than that in the control group(80.00%),with a statistically significant difference(χ^(2)=4.223,p=0.040<0.05).Conclusion:Tirofiban combined with direct thrombectomy can significantly improve cerebral hemodynamics,enhance the effectiveness of complication nursing,and increase patient satisfaction in patients with ischemic stroke.
文摘BACKGROUND Drug utilization research has an important role in assisting the healthcare administration to know,compute,and refine the prescription whose principal objective is to enable the rational use of drugs.Research in developing nations relating to the cost of treatment is scarce when compared with developed countries.Thus,the drug utilization research studies from developing nations are most needed,and their number has been growing.AIM To evaluate patterns of utilization of antipsychotic drugs and direct medical cost analysis in patients newly diagnosed with schizophrenia.METHODS The present study was observational in type and based on a retrospective cohort to evaluate patterns of utilization of antipsychotic drugs using World Health Organization(WHO)core prescribing indicators and anatomical therapeutic chemical/defined daily dose indicators.We also calculated direct medical costs for a period of 6 months.RESULTS This study has found that atypical antipsychotics are the mainstay of treatment for schizophrenia in every age group and subcategories of schizophrenia.The evaluation based on WHO prescribing indicators showed a low average number of drugs per prescription and low prescribing frequency of antipsychotics from the National List of Essential Medicines 2015 and the WHO Essential Medicines List 2019.The total mean drug cost of our study was 1396 Indian rupees.The total mean cost due to the investigation in our study was 1017.34 Indian rupees.Therefore,the total mean direct medical cost incurred on patients in our study was 4337.28 Indian rupees.CONCLUSION The information from the present study can be used for reviewing and updating treatment policy at the institutional level.
基金supported in part by the National Natural Science Foundation of China under Grants 62025110,62271093sponsored by Natural Science Foundation of Chongqing,China,under Grant CSTB2023NSCQ-LZX0108.
文摘Efficient energy utilization in covert communication sustains covertness while assuring communication quality and efficiency.This paper investigates covert communication energy efficiency(EE)in direct uplink satellite-ground communications,focusing on enhancing system EE via optimized transmit beamforming and satellite orbit altitude selection.This paper first establishes an optimization problem to maximize system EE in a direct uplink satelliteground covert communication scenario.To solve this non-convex optimization problem,it is decomposed into two subproblems and solved using the successive convex approximation(SCA)method.Based on the above methods,this paper proposes an overall iterative optimization algorithm.Simulation results demonstrate that the proposed algorithm surpasses the conventional baseline algorithms in terms of system EE.Furthermore,they elucidate the correlation between the amount of information received by the receiver and the variations in the satellite’s orbital altitude.
基金financially supported by the National Key Research and Development Program of China(Nos.2024YFB4607402 and 2016YFC1100502)the National Natural Science Foundation of China(Nos.51673208 and 61975213)。
文摘Biopolymeric nanocomposites have attracted considerable attention because of their biocompatibility,biodegradability,and unique physicochemical properties.It is essential to manufacture three-dimensional(3D)biocompatible micro/nanostructures using biopolymeric nanocomposites.Herein,we demonstrate the high-fidelity fabrication of biocompatible 3D features with sub-50 nm resolution using femtosecond laser direct writing(FsLDW)of a biopolymeric nanocomposite composed of egg white and sulfonated graphene(S-graphene).The biopolymer nanocomposite acts as a negative photoresist suitable for water-based lithography.The introduction of S-graphene not only dramatically lowered the laser power threshold but also significantly modulated the morphology of the 3D features constructed by FsLDW.Microstructures with porous,rough,or smooth morphologies were obtained by optimizing the S-graphene concentration and laser scanning speed.The fabricated egg-white/S-graphene microstructures exhibited biocompatibility and environmental degradability.Egg white/S-graphene was also employed to fabricate diffractive gratings with superior optical quality.This study provides a promising method to manufacture biocompatible 3D features with controllable morphology,which has potential applications in biological and photonic fields.
基金financial support from the National Key R&D Program of China(2022YFB2402600)the National Natural Science Foundation of China(52372250,52125105,52173242)+1 种基金Shenzhen Science and Technology Planning Project(RCYX20221008092850072,JSGG20220831104004008,KJZD20230923113859006,JCYJ20220531100405012,KJZD20241122161900001)Science and Technology Planning Project of Guangdong Province(2024A1515030076)。
文摘The rapid accumulation of spent LiFePO_(4)(LFP)cathodes from retired lithium-ion batteries necessitates the development of effective and environmental-friendly recycling strategies.In this context,direct regeneration has emerged as a promising approach for reclaiming LFP cathode materials,offering a streamlined pathway to restore their electrochemical functionality.We report an integrated regeneration protocol that simultaneously repairs the degraded crystal structure and reconstructs the damaged carbon coating in spent LFP.The regenerated cathode material had superfast lithium-ion diffusion kinetics and a stable cathode-electrolyte interface,giving a remarkable rate capability with specific capacities of 122 m Ah g^(-1)at 5C and 106 m Ah g^(-1)at 10C(1C=170 m A g^(-1)).It also maintained capacities of 110.7 m Ah g^(-1)(5C)and 84.1 m Ah g^(-1)(10C)after 400 cycles.It could be used in harsh environments and could be stably cycled at subzero temperatures(-10 and-20°C)and in solid-state electrolyte batteries.Life cycle assessment combined with economic evaluation using the Ever Batt model reveals that this direct regeneration approach has high economic and environmental benefits.
基金supported by Guangdong Major Project of Basic and Applied Basic Research(Grant No.2021B0301030002)the National Key Research and Development Program(Grant No.2021YFA1202900)the National Natural Science Foundation of China(Grant Nos.62204166 and 62404145)。
文摘When stacking two-dimensional(2D)materials with a lattice mismatch and/or a small twist,moirésuperlattice emerges with fascinating electronic and optical properties.The fabrication of such stacked 2D materials usually requires multiple transfer and stack processes,assisted by a certain transfer medium which needs to be removed afterwards,and it is very challenging to maintain pristine and clean surfaces/interfaces for these stacked structures.In this work,we report a facile direct bonding method for fabrication of twisted MoS_(2) bilayers with ultra-clean surfaces/interfaces.Novel interlayer interactions are revealed in the as-fabricated high-quality samples,leading to twist-angle related dispersion behavior of various Raman modes,such as layer breathing modes,shear modes and E_(2g)modes,as well as indirect bandgap excitons.Field-effect transistors(FETs)of twisted MoS_(2) bilayers also exhibit angle-dependent performance,which could be attributed to the band structure evolution.This facile method holds significance for the future integration of pre-designed multilayer 2D materials and paves a way to explore underlying physical mechanisms and potential applications.
文摘Exercise produces a decrease in pain sensitivity via an effect called exercise-induced hypoalgesia(EIH).Transcranial direct current stimulation(tDCS),acting on similar analgesic mechanisms as EIH,represents a potential complementary intervention that may amplify the effects of exercise on pain.This study aimed to explore if anodal tDCS could enhance the effect of exercise on pain compared to exercise alone.A total of 35 healthy participants aged 19–37 years completed a familiarisation session followed by two separate sessions where active and sham tDCS was applied in a randomised cross-over design.The familiarisation session involved familiarisation to the pain assessment and exercise tasks,while the subsequent tDCS sessions involved pain sensitivity assessment,exercise and either anodal tDCS or sham tDCS.tDCS doses were applied at 2 mA over the primary motor cortex for 10 min,with the reference electrode placed over the contralateral supraorbital area.The exercise task involved a sustained isometric grip strength contraction at 35%of maximal voluntary contraction(MVC)until volitional exhaustion.Pain sensitivity was evaluated as pressure pain threshold before tDCS,after tDCS,and after exercise.Across both tDCS conditions,pain threshold was higher after exercise when compared to pre-and post-tDCS measurement.This increase in pain threshold did not differ between active and sham tDCS conditions.Our findings suggest that the hypoalgesic effects of active anodal tDCS over the motor cortex prior to exercise are no greater than the effects of sham tDCS prior to exercise.
基金supported by the National Natural Science Foundation of China(Grant Nos.62450006,62304217,62274157,62127807,62234011,62034008,62074142,62074140)Tianshan Innovation Team Program(Grant No.2022TSYCTD0005)+1 种基金Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB0880000)Youth Innovation Promotion Association of the Chinese Academy of Sciences(Grant Nos.2023124,Y2023032)。
文摘The 193 nm deep-ultraviolet(DUV)laser plays a critical role in advanced semiconductor chip manufacturing[1,2],micro-nano material characterization[3,4]and biomedical analysis[5,6],due to its high spatial resolution and short wavelength.Efficient and compact 193 nm DUV laser source thus becomes a hot research area.Currently,193 nm Ar F excimer gas laser is widely employed in DUV lithography systems and serves as the enabling technology for 7 and 5 nm semiconductor fabrication.
基金supported by the National Natural Science Foundation of China(52433002)Key projects of Shaanxi Province(2023GXLH-001)+2 种基金Key R&D Program of Shandong Province(2022TSGC2569)New Energy Material Innovation Consortium Projects of Yunnan Province(202302AB080018)Natural Science Basic Research Program of Shaanxi(2022TD-27)。
文摘Direct regeneration is considered a sustainable solution to the issue of resource recycling and the environmental pollution caused by discarded lithium-ion batteries(LIBs).However,the direct regeneration of spent LiFePO_(4)cathode materials still faces a formidable challenge that the irregular strains induced by the irreversible FePO_(4)phase after several charge and discharge cycles hinder the regenerative replenishment of Li^(+).This work proposes a lattice stress modulation strategy that reduces FePO_(4)phase into Fe_(2)P_(2)O_(7)phase(reduction of unit cell volume from 271.7 to 122.6Å^(3)),which releases the residual stress,paving continuous transport channels for Li^(+).In addition,the phase transformation reconstructs the FeO6 octahedra,significantly decreasing the migration energy barrier of ions within the lattice.Ultimately,the steric effect is synergistically weakened,facilitating the replenishment of Li^(+)and the elimination of Li-Fe anti-site defects.The regenerated LiFePO_(4)cathodes outperform commercial cathodes(80.2%capacity retention after 1000 cycles at 2 C).This work establishes fundamental principles for the pretreatment stage of the direct regeneration process and provides a paradigm shifting solution for sustainable LIBs recycling technology.
基金supported by the National Natural Science Foundation of China(21075053)the"Challenge Cup"Undergraduate Extra-curriculum Academics,Science and Technology Works Competition and Student's Platform for Innovation and Entrepreneurship Training Program(201410559056)in Jinan University
文摘In this study,α-TeO2：Ho3＋/Yb3＋,α-TeO2：Eu3＋ andα-TeO2：Ho3＋/Yb3＋/Eu3＋ nanoparticles were prepared via a simple hydrothermal process. The up- and down-conversion properties of the as-prepared nanoparticles were tested at room temperature un-der a near-infrared photo source （980 nm） and UV-vis photo source, respectively.The results indicated thatα-TeO2 NPs were a kind of outstanding host material for both up- and down-conversion luminescence. Theα-TeO2：Ho3＋/Yb3＋nanoparticles showed sharp up-conversion emission at 545 and 660 nm under 980 nm excitation, ascribed to the5S2→5I8 and5F5→5I8（Ho3＋） transitions, and weaker down-conversion emission at 545 nm under 455 nm excitation, ascribed to the5S2→5I8（Ho3＋） transitions. Theα-TeO2：Eu3＋nanoparticles showed strong down-conversion emission at 592 and 615 nm under 395 nm excitation, attributed to the5D0→7F1 and 5D0→7F2 （Eu3＋） transitions. Possessing the advantages of these two luminescent materials, the as-prepared tri-doped samples ofα-TeO2：0.5Ho3＋/10Yb3＋/3Eu3＋ （mol.%）nanoparticles could successfully emit visible light via both up- and down-conversion modes.
基金Project supported by the National Key Technologies R&D Program of China(Grant No.2018YFA0306101)the Scientific Instrument Developing Project of Chinese Academy of Sciences(Grant No.YJKYYQ20170032)the National Natural Science Foundation of China(Grant No.61505196)
文摘Near-infrared single photon sources in telecommunication bands, especially at 1550 nm, are required for long-distance quantum communication. Here a down-conversion quantum interface is implemented, where the single photons emitted from single In As quantum dot at 864 nm is down converted to 1552 nm by using a fiber-coupled periodically poled lithium niobate（PPLN） waveguide and a 1.95 μmm pump laser, and the frequency conversion efficiency is ~40%. The singlephoton purity of quantum dot emission is preserved during the down-conversion process, i.e., g^（（2））（0）, only 0.22 at 1552 nm.This present technique advances the Ⅲ-Ⅴ semiconductor quantum dots as a promising platform for long-distance quantum communication.
基金Project supported by the National Key R&D Program of China(Grant No.2019YFA0705000)Leading-edge Technology Program of Jiangsu Natural Science Foundation,China(Grant No.BK20192001)the National Natural Science Foundation of China(Grant Nos.51890861,11690031,11974178,and 11627810).
文摘We study the effect of waveguide thickness variations on the frequency spectrum of spontaneous parametric downconversion in the periodically-poled lithium niobate on insulator(LNOI)waveguide.We analyze several variation models and our simulation results show that thickness variations in several nanometers can induce distinct effects on the central peak of the spectrum,such as narrowing,broadening,and splitting.We also prove that the effects of positive and negative variations can be canceled and thus lead to a variation-robust feature and an ultra-broad bandwidth.Our study may promote the development of on-chip photon sources in the LNOI platform,as well as opens up a way to engineer photon frequency state.
文摘In recent years, much attention has been paid to software-defined radio （SDR） technologies for multimode wireless systems SDR can be defined as a radio communication system that uses software to modulate and demodulate radio signals. This article describes concepts, theory, and design principles for SDR down-conversion and up-conversion. Design issues in SDR down-conversion are discussed, and two different architectures, super-heterodyne and direct-conversion, are proposed. Design issues in SDR up-conversion are also discussed, and trade-offs in the design of filters, mixers, NCO, DAC, and signal processing are highlighted.
