As a versatile and environmentally benign oxidant,hydrogen peroxide(H_(2)O_(2))is highly desired in sanitation,disinfection,environmental remediation,and the chemical industry.Compared with the conventional anthraquin...As a versatile and environmentally benign oxidant,hydrogen peroxide(H_(2)O_(2))is highly desired in sanitation,disinfection,environmental remediation,and the chemical industry.Compared with the conventional anthraquinone process,the electrosynthesis of H_(2)O_(2)through the two-electron oxygen reduction reaction(2e^(−)ORR)is an efficient,competitive,and promising avenue.Electrocatalysts and devices are two core factors in 2e^(−)ORR,but the design principles of catalysts for different pH conditions and the development trends of relevant synthesis devices remain unclear.To this end,this review adopts a multiscale perspective to summarize recent advancements in the design principles,catalytic mechanisms,and application prospects of 2e^(−)ORR catalysts,with a particular focus on the influence of pH conditions,aiming at providing guidance for the selective design of advanced 2e^(−)ORR catalysts for highly-efficient H_(2)O_(2)production.Moreover,in response to diverse on-site application demands,we elaborate on the evolution of H_(2)O_(2)electrosynthesis devices,from rotating ring-disk electrodes and H-type cells to diverse flow-type cells.We elaborate on their characteristics and shortcomings,which can be beneficial for their further upgrades and customized applications.These insights may inspire the rational design of innovative catalysts and devices with high performance and wide serviceability for large-scale implementations.展开更多
Quantum dots(QDs)have attracted wide attention from academia and industry because of their advantages such as high emitting efficiency,narrow half-peak width,and continuously adjustable emitting wavelength.QDs light e...Quantum dots(QDs)have attracted wide attention from academia and industry because of their advantages such as high emitting efficiency,narrow half-peak width,and continuously adjustable emitting wavelength.QDs light emitting diodes(QLEDs)are expected to become the next generation commercial display technology.This paper reviews the progress of QLED from physical mechanism,materials,to device engineering.The strategies to improve QLED performance from the perspectives of quantum dot materials and device structures are summarized.展开更多
Organic solar cells(OSCs)have been developed for few decades since the preparation of the first photovoltaic device,and the record power conversion efficiency(PCE)certified by national renewable energy laboratory(NREL...Organic solar cells(OSCs)have been developed for few decades since the preparation of the first photovoltaic device,and the record power conversion efficiency(PCE)certified by national renewable energy laboratory(NREL)has exceeded 17%.Looking back the whole history of OSCs,its rapid development is inseparable from multi-disciplinary efforts,including the new materials synthesizing,the device physics,and the device engineering,especially the breakthroughs in these disciplines.In this review,we are aiming at reviewing the history of the development of OSCs and summarizing the representative breakthroughs.展开更多
Among a promising photovoltaic technology for solar energy conversion,organic solar cells(OSCs)have been paid much attention,of which the power conversion efficiencies(PCEs)have rapidly surpassed over 20%,approaching t...Among a promising photovoltaic technology for solar energy conversion,organic solar cells(OSCs)have been paid much attention,of which the power conversion efficiencies(PCEs)have rapidly surpassed over 20%,approaching the threshold for potential applications.However,the device stability of OSCs including storage stability,photostability and thermal stability,remains to be an enormous challenge when faced with practical applications.The major causes of device instability are rooted in the poor inherent properties of light-harvesting materials,metastable mor-phology,interfacial reactions and highly sensitive to external stresses.To get rid of theseflaws,a comprehensive review is provided about recent strategies and meth-ods for improving the device stability from active layers,interfacial layers,device engineering and encapsulation techniques for high-performance OSC devices.In the end,prospectives for the next stage development of high-performance devices with satisfactory long-term stability are afforded for the solar community.展开更多
With advances in material science and a more in-depth understanding of device engineering,the power conversion efficiency(PCE)of solution-processed organic photovoltaic(OPV)cells have significantly boosted in the past...With advances in material science and a more in-depth understanding of device engineering,the power conversion efficiency(PCE)of solution-processed organic photovoltaic(OPV)cells have significantly boosted in the past few years.In 2019,a high PCE of 15.7%was achieved in the OPV cells adopting a wide bandgap polymer PM6 and a new emerging non-fullerene acceptor Y6.Such outstanding performance has attracted lots of research attention,driving considerable efforts to improve or take advantage of the high-performance PM6:Y6-based system.In this review,we first concentrate on the structural characteristics of PM6 and Y6 with the focus on understanding why their combination for OPV application can obtain such high efficiency.We also update the recent progress in highly efficient PM6:Y6-based OPV cells via various optimizing strategies.Then we summarize the other applications of the PM6:Y6-based system in semi-transparent,flexible or lay e-by-layer devices.The prospects for future OPV studies will be suggested in the end.展开更多
Device level performance of aqueous halide supercapatteries fabricated with equal electrode mass of activated carbon or graphene nanoplatelets has been characterized.It was revealed that the surface oxygen groups in t...Device level performance of aqueous halide supercapatteries fabricated with equal electrode mass of activated carbon or graphene nanoplatelets has been characterized.It was revealed that the surface oxygen groups in the graphitic structures of the nanoplatelets contributed toward a more enhanced charge storage capacity in bromide containing redox electrolytes.Moreover,the rate performance of the devices could be linked to the effect of the pore size of the carbons on the dynamics of the inactive alkali metal counterion of the redox halide salt.Additionally,the charge storage performance of aqueous halide supercapatteries with graphene nanoplatelets as the electrode material may be attributed to the combined effect of the porous structure on the dynamics of the non-active cations and a possible interaction of the Br^(-)/(Br_(2)+Br^(-)_(3))redox triple with the surface oxygen groups within the graphitic layer of the nanoplatelets.Generally,it has been shown that the surface groups and microstructure of electrode materials must be critically correlated with the redox electrolytes in the ongoing efforts to commercialize these devices.展开更多
Perovskite lead zirconate(PbZrOz)was synthesized in an orthorhombic form at a temperature below the Curie temperature,Tc.The orthorhombic form is a noncentrosymmetric structure which is capable of spontaneous polariza...Perovskite lead zirconate(PbZrOz)was synthesized in an orthorhombic form at a temperature below the Curie temperature,Tc.The orthorhombic form is a noncentrosymmetric structure which is capable of spontaneous polarization.Fourier transform infrared(FTIR)spectra and X-ray diffraction(XRD)patterns confirm the siuccessful synthesis of the lead zirconate;and scanning electron microscopy(SEM)micrographs indicate that PbZrO_(3) particles are moderately dispersed in the natural rubber(NR)matrix.Without an electrical field,the particles merely act as a ferroelectric fller,which can absorb and store additional stress.Under an electrical field,particle induced dipole motents are generated,leading to interparticle interaction and a sub-stantial increase in the storage modulus.At a small amount of lead ziroonate part iculates present in the natural rubber matrix,at a volume fraction of 0.007306,the electrical conductivity increases dramatically by nearly two orders of magnitude at the electrical frequency of 500 kHz.展开更多
This paper presents CMOS circuit designs of a ternary adder and a ternary multiplier,formulated using transmission function theory.Binary carry signals appearing in these designs allow conventional look-ahead carry te...This paper presents CMOS circuit designs of a ternary adder and a ternary multiplier,formulated using transmission function theory.Binary carry signals appearing in these designs allow conventional look-ahead carry techniques to be used.Compared with previous similar designs,the circuits proposed in this paper have advantages such as low dissipation,low output impedance,and simplicity of construction.展开更多
Perovskite solar cells(PSCs)are undergoing rapid development and the power conversion efficiency reaches 25.7%which attracts increasing attention on their commercialization recently.In this review,we summarized the re...Perovskite solar cells(PSCs)are undergoing rapid development and the power conversion efficiency reaches 25.7%which attracts increasing attention on their commercialization recently.In this review,we summarized the recent progress of PSCs based on device structures,perovskite-based tandem cells,large-area modules,stability,applications and industrialization.Last,the challenges and perspectives are discussed,aiming at providing a thrust for the commercialization of PSCs in the near future.展开更多
Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)(PEDOT:PSS)has been the most prominent conducting polymer due to its outstanding electrical properties,chemical stability,biocompatibility,and commercial availab...Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)(PEDOT:PSS)has been the most prominent conducting polymer due to its outstanding electrical properties,chemical stability,biocompatibility,and commercial availability.In this mini review,we aimto comprehensively outline the chemical approaches employed in tailoring PEDOT:PSS for bioelectronic applications.We open our discussion by showcasing various synthetic techniques and commercially accessible forms of PEDOT:PSS,providing practical advice and approaches to greatly enhance its electrical properties,and presenting diverse chemical designs and processing methods that are essential for converting PEDOT:PSS into different form factors,such as fibers,gels,and films,for integration a range of device structures.Additionally,we explore several burgeoning applications of PEDOT:PSS in bioelectronics,ranging from wearable health monitoring to implantable neural interfaces,underscoring its essential impact on improving device efficiency and biological compatibility,as it opens avenues for innovative diagnostic and therapeutic techniques in the realm of precision medicine.Concluding with an outlook,the review presents insights into the ongoing challenges and future research paths for PEDOT:PSS in the ever-evolving landscape of bioelectronics.We emphasize the need for continued innovation in materials science and engineering to further harness the full potential of this dynamic domain.展开更多
Organic solar cells(OSCs)have experienced remarkable performance progress up to 20%benchmark power conversion efficiency(PCE)in past years.Considering the<1%initial PCE obtained by OSC decades ago,the milestone of ...Organic solar cells(OSCs)have experienced remarkable performance progress up to 20%benchmark power conversion efficiency(PCE)in past years.Considering the<1%initial PCE obtained by OSC decades ago,the milestone of surpassing 20%efficiency is of great significance.Meanwhile,further performance promotion is urgently required for OsCs as other solution-processable photovoltaic technologies are also competitive.This review article aims to demonstrate a comprehensive summary of recent reports on OSCs with over 20%PCE,delving into key strategies including material innovations,multi-component system construction,deposition protocol optimization,solid/solvent additive engineering,as well as hole/electron transport layer development.In addition,this study identifies the next-stage scientific and technological issues that warrant greater attention.These issues are proposed to drive more prosperous research development,particularly in the field of flexible and wearable power suppliers.展开更多
Topological magnons give rise to possibilities for engineering novel spintronics devices with critical applications in quantum information and computation,due to their symmetry-protected robustness and low dissipation...Topological magnons give rise to possibilities for engineering novel spintronics devices with critical applications in quantum information and computation,due to their symmetry-protected robustness and low dissipation.However,to make reliable and systematic predictions about the material realization of topological magnons has been a major challenge,due to the lack of neutron scattering data formost materials and the absence of reliable ab initio calculations for magnons.In this work,we significantly advance the symmetry-based approach for identifying topological magnons through developing a fully automated algorithm,utilizing the theory of symmetry indicators,that enables a highly efficient and large-scale search for candidate materials hosting perturbation-driven topological magnons.This progress not only streamlines the discovery process but also expands the scope of materials exploration beyond previous manual or traditional approaches,offering a powerful tool for uncovering novel topological phases in magnetic systems.Performing a large-scale search over all 1649 magnetic materials in the Bilbao Crystallographic Server(BCS)with a commensurate magnetic order,we discover 387 perturbation-induced topological magnon materials,significantly expanding the pool of topological magnon materials and showing that more than 23%of all commensurate magnetic compounds in the BCS database are topological.We further discuss examples and experimental accessibility of the candidate materials,shedding light on future experimental realizations of topological magnons in magnetic materials.We provide an open-source program that checks the symmetry-enforced magnon band topology of any commensurate magnetic structure upon perturbations and allows researchers to reproduce our results.展开更多
Remarkable progress in high-performance polymer solar cells demonstrates their great potential for practical applications in the near future. Indeed, the power conversion efficiencies over 10% have been reported by ma...Remarkable progress in high-performance polymer solar cells demonstrates their great potential for practical applications in the near future. Indeed, the power conversion efficiencies over 10% have been reported by many research groups, which are achieved through rational optimization of light-harvesting materials, interfaces and device processing technologies. In this mini review, we summarized the recent progress of highly efficient polymer solar cells, with specifically concern on successful strategies of rational molecular design of electron-donating and electron-accepting materials, elaborative interfacial engineering, and reasonable device architectures.展开更多
All-polymer solar cells(all-PSCs)have attracted considerable attention due to their inherent advantages over other types of organic solar cells,including superior optical and thermal stability,as well as exceptional m...All-polymer solar cells(all-PSCs)have attracted considerable attention due to their inherent advantages over other types of organic solar cells,including superior optical and thermal stability,as well as exceptional mechanical durability.Recently,all-PSCs have experienced remarkable advancements in device performance thanks to the invention of polymerized small-molecule acceptors(PSMAs)since 2017.Among these PSMAs,PY-IT has garnered immense interest from the scientific community due to its exceptional performance in all-PSCs.In this review,we presented the design principles of PY-IT and discussed the various strategies employed in device engineering for PY-IT-based all-PSCs.These strategies include additive and interface engineering,layer-by-layer processing methods,meniscus-assisted coating methods,and ternary strategy.Furthermore,this review highlighted several novel polymeric donor materials that are paired with PY-IT to achieve efficient all-PSCs.Lastly,we summarized the inspiring strategies for further advancing all-PSCs based on PY-IT.These strategies aim to enhance the overall performance and stability of all-PSCs by exploring new materials,optimizing device architectures,and improving fabrication techniques.By leveraging these approaches,we anticipate significant progress in the development of all-PSCs and their potential as a viable renewable energy source.展开更多
基金supported by the National Natural Science Foundation of China(Nos.22102073,22075147).
文摘As a versatile and environmentally benign oxidant,hydrogen peroxide(H_(2)O_(2))is highly desired in sanitation,disinfection,environmental remediation,and the chemical industry.Compared with the conventional anthraquinone process,the electrosynthesis of H_(2)O_(2)through the two-electron oxygen reduction reaction(2e^(−)ORR)is an efficient,competitive,and promising avenue.Electrocatalysts and devices are two core factors in 2e^(−)ORR,but the design principles of catalysts for different pH conditions and the development trends of relevant synthesis devices remain unclear.To this end,this review adopts a multiscale perspective to summarize recent advancements in the design principles,catalytic mechanisms,and application prospects of 2e^(−)ORR catalysts,with a particular focus on the influence of pH conditions,aiming at providing guidance for the selective design of advanced 2e^(−)ORR catalysts for highly-efficient H_(2)O_(2)production.Moreover,in response to diverse on-site application demands,we elaborate on the evolution of H_(2)O_(2)electrosynthesis devices,from rotating ring-disk electrodes and H-type cells to diverse flow-type cells.We elaborate on their characteristics and shortcomings,which can be beneficial for their further upgrades and customized applications.These insights may inspire the rational design of innovative catalysts and devices with high performance and wide serviceability for large-scale implementations.
基金Project supported by Leading innovation and entrepreneurship team of Zhejiang Province of China (Grant No.2021R01003)Science and Technology Innovation 2025 Major Project of Ningbo (Grant No.2022Z085)+2 种基金Ningbo 3315 Programme (Grant No.2020A-01-B)YONGJIANG Talent Introduction Programme (Grant No.2021A-038-B)Zhujiang Talent Programme (Grant No.2016LJ06C621)。
文摘Quantum dots(QDs)have attracted wide attention from academia and industry because of their advantages such as high emitting efficiency,narrow half-peak width,and continuously adjustable emitting wavelength.QDs light emitting diodes(QLEDs)are expected to become the next generation commercial display technology.This paper reviews the progress of QLED from physical mechanism,materials,to device engineering.The strategies to improve QLED performance from the perspectives of quantum dot materials and device structures are summarized.
基金supported by the financial support from the National Natural Science Foundation of China(Nos.21835006,21704004 and 21734008)the Fundamental Research Funds for the Central Universities,China(No.FRF-TP-19-047A2)China Postdoctoral Science Foundation(No.2019M660799).
文摘Organic solar cells(OSCs)have been developed for few decades since the preparation of the first photovoltaic device,and the record power conversion efficiency(PCE)certified by national renewable energy laboratory(NREL)has exceeded 17%.Looking back the whole history of OSCs,its rapid development is inseparable from multi-disciplinary efforts,including the new materials synthesizing,the device physics,and the device engineering,especially the breakthroughs in these disciplines.In this review,we are aiming at reviewing the history of the development of OSCs and summarizing the representative breakthroughs.
基金Shenzhen Fundamental Research Program,Grant/Award Number:JCYJ20210324120010028National Natural Science Foundation of China,Grant/Award Number:22225504Guangdong Provincial Key Laboratory of Catalysis,Grant/Award Number:2020B121201002。
文摘Among a promising photovoltaic technology for solar energy conversion,organic solar cells(OSCs)have been paid much attention,of which the power conversion efficiencies(PCEs)have rapidly surpassed over 20%,approaching the threshold for potential applications.However,the device stability of OSCs including storage stability,photostability and thermal stability,remains to be an enormous challenge when faced with practical applications.The major causes of device instability are rooted in the poor inherent properties of light-harvesting materials,metastable mor-phology,interfacial reactions and highly sensitive to external stresses.To get rid of theseflaws,a comprehensive review is provided about recent strategies and meth-ods for improving the device stability from active layers,interfacial layers,device engineering and encapsulation techniques for high-performance OSC devices.In the end,prospectives for the next stage development of high-performance devices with satisfactory long-term stability are afforded for the solar community.
基金supported by the National Natural Science Foundation of China(22005024,51873007,51961165102 and 21835006)。
文摘With advances in material science and a more in-depth understanding of device engineering,the power conversion efficiency(PCE)of solution-processed organic photovoltaic(OPV)cells have significantly boosted in the past few years.In 2019,a high PCE of 15.7%was achieved in the OPV cells adopting a wide bandgap polymer PM6 and a new emerging non-fullerene acceptor Y6.Such outstanding performance has attracted lots of research attention,driving considerable efforts to improve or take advantage of the high-performance PM6:Y6-based system.In this review,we first concentrate on the structural characteristics of PM6 and Y6 with the focus on understanding why their combination for OPV application can obtain such high efficiency.We also update the recent progress in highly efficient PM6:Y6-based OPV cells via various optimizing strategies.Then we summarize the other applications of the PM6:Y6-based system in semi-transparent,flexible or lay e-by-layer devices.The prospects for future OPV studies will be suggested in the end.
基金funding from the International Doctoral Innovation CentreNingbo Education Bureau+2 种基金Ningbo Science and Technology Bureauthe University of NottinghamNingbo Municipal Government(3315 Plan and 2014A35001-1)
文摘Device level performance of aqueous halide supercapatteries fabricated with equal electrode mass of activated carbon or graphene nanoplatelets has been characterized.It was revealed that the surface oxygen groups in the graphitic structures of the nanoplatelets contributed toward a more enhanced charge storage capacity in bromide containing redox electrolytes.Moreover,the rate performance of the devices could be linked to the effect of the pore size of the carbons on the dynamics of the inactive alkali metal counterion of the redox halide salt.Additionally,the charge storage performance of aqueous halide supercapatteries with graphene nanoplatelets as the electrode material may be attributed to the combined effect of the porous structure on the dynamics of the non-active cations and a possible interaction of the Br^(-)/(Br_(2)+Br^(-)_(3))redox triple with the surface oxygen groups within the graphitic layer of the nanoplatelets.Generally,it has been shown that the surface groups and microstructure of electrode materials must be critically correlated with the redox electrolytes in the ongoing efforts to commercialize these devices.
文摘Perovskite lead zirconate(PbZrOz)was synthesized in an orthorhombic form at a temperature below the Curie temperature,Tc.The orthorhombic form is a noncentrosymmetric structure which is capable of spontaneous polarization.Fourier transform infrared(FTIR)spectra and X-ray diffraction(XRD)patterns confirm the siuccessful synthesis of the lead zirconate;and scanning electron microscopy(SEM)micrographs indicate that PbZrO_(3) particles are moderately dispersed in the natural rubber(NR)matrix.Without an electrical field,the particles merely act as a ferroelectric fller,which can absorb and store additional stress.Under an electrical field,particle induced dipole motents are generated,leading to interparticle interaction and a sub-stantial increase in the storage modulus.At a small amount of lead ziroonate part iculates present in the natural rubber matrix,at a volume fraction of 0.007306,the electrical conductivity increases dramatically by nearly two orders of magnitude at the electrical frequency of 500 kHz.
基金Project supported by the National Natural Science Foundation of China.
文摘This paper presents CMOS circuit designs of a ternary adder and a ternary multiplier,formulated using transmission function theory.Binary carry signals appearing in these designs allow conventional look-ahead carry techniques to be used.Compared with previous similar designs,the circuits proposed in this paper have advantages such as low dissipation,low output impedance,and simplicity of construction.
文摘Perovskite solar cells(PSCs)are undergoing rapid development and the power conversion efficiency reaches 25.7%which attracts increasing attention on their commercialization recently.In this review,we summarized the recent progress of PSCs based on device structures,perovskite-based tandem cells,large-area modules,stability,applications and industrialization.Last,the challenges and perspectives are discussed,aiming at providing a thrust for the commercialization of PSCs in the near future.
基金supported by the start-up funding from the University of Pennsylvania.
文摘Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)(PEDOT:PSS)has been the most prominent conducting polymer due to its outstanding electrical properties,chemical stability,biocompatibility,and commercial availability.In this mini review,we aimto comprehensively outline the chemical approaches employed in tailoring PEDOT:PSS for bioelectronic applications.We open our discussion by showcasing various synthetic techniques and commercially accessible forms of PEDOT:PSS,providing practical advice and approaches to greatly enhance its electrical properties,and presenting diverse chemical designs and processing methods that are essential for converting PEDOT:PSS into different form factors,such as fibers,gels,and films,for integration a range of device structures.Additionally,we explore several burgeoning applications of PEDOT:PSS in bioelectronics,ranging from wearable health monitoring to implantable neural interfaces,underscoring its essential impact on improving device efficiency and biological compatibility,as it opens avenues for innovative diagnostic and therapeutic techniques in the realm of precision medicine.Concluding with an outlook,the review presents insights into the ongoing challenges and future research paths for PEDOT:PSS in the ever-evolving landscape of bioelectronics.We emphasize the need for continued innovation in materials science and engineering to further harness the full potential of this dynamic domain.
基金the National Natural Science Foundation of China(52422313 and 52173172)the PolyU Distinguished Postdoctoral Fellowship(1-YW4C)+4 种基金the National Natural Science Foundation of China(22475133,22309119,and 52303226)financially supported by the National Natural Science Foundation of China(52403239)the Sichuan Science and Technology Program(2023YFH0085 and 2023YFH0087)the National Key Laboratory of Advanced Polymer Materials(sklpme 2024-2-15)the Technology Development Program of Jilin Province(YDZJ202201ZYTS640)。
文摘Organic solar cells(OSCs)have experienced remarkable performance progress up to 20%benchmark power conversion efficiency(PCE)in past years.Considering the<1%initial PCE obtained by OSC decades ago,the milestone of surpassing 20%efficiency is of great significance.Meanwhile,further performance promotion is urgently required for OsCs as other solution-processable photovoltaic technologies are also competitive.This review article aims to demonstrate a comprehensive summary of recent reports on OSCs with over 20%PCE,delving into key strategies including material innovations,multi-component system construction,deposition protocol optimization,solid/solvent additive engineering,as well as hole/electron transport layer development.In addition,this study identifies the next-stage scientific and technological issues that warrant greater attention.These issues are proposed to drive more prosperous research development,particularly in the field of flexible and wearable power suppliers.
文摘Topological magnons give rise to possibilities for engineering novel spintronics devices with critical applications in quantum information and computation,due to their symmetry-protected robustness and low dissipation.However,to make reliable and systematic predictions about the material realization of topological magnons has been a major challenge,due to the lack of neutron scattering data formost materials and the absence of reliable ab initio calculations for magnons.In this work,we significantly advance the symmetry-based approach for identifying topological magnons through developing a fully automated algorithm,utilizing the theory of symmetry indicators,that enables a highly efficient and large-scale search for candidate materials hosting perturbation-driven topological magnons.This progress not only streamlines the discovery process but also expands the scope of materials exploration beyond previous manual or traditional approaches,offering a powerful tool for uncovering novel topological phases in magnetic systems.Performing a large-scale search over all 1649 magnetic materials in the Bilbao Crystallographic Server(BCS)with a commensurate magnetic order,we discover 387 perturbation-induced topological magnon materials,significantly expanding the pool of topological magnon materials and showing that more than 23%of all commensurate magnetic compounds in the BCS database are topological.We further discuss examples and experimental accessibility of the candidate materials,shedding light on future experimental realizations of topological magnons in magnetic materials.We provide an open-source program that checks the symmetry-enforced magnon band topology of any commensurate magnetic structure upon perturbations and allows researchers to reproduce our results.
基金supported by the Ministry of Science and Technology(2014CB643501)the National Natural Science Foundation of China(21520102006,21634004,51673069,21490573)the Guangdong Natural Science Foundation(S2012030006232)
文摘Remarkable progress in high-performance polymer solar cells demonstrates their great potential for practical applications in the near future. Indeed, the power conversion efficiencies over 10% have been reported by many research groups, which are achieved through rational optimization of light-harvesting materials, interfaces and device processing technologies. In this mini review, we summarized the recent progress of highly efficient polymer solar cells, with specifically concern on successful strategies of rational molecular design of electron-donating and electron-accepting materials, elaborative interfacial engineering, and reasonable device architectures.
基金support from the National Natural Science Foundation of China(52173172)the Natural Science Foundation for Distinguished Young Scholars of Guangdong Province(2021B1515020027)+7 种基金the Shenzhen Science and Technology Innovation Commission(JCYJ202103243104813035)the Open Fund of the State Key Laboratory of Luminescent Materials andDevices(South China University of Technology,2022-skllmd-17)the Research&Development Projects in Key Areas of Guangdong Province,China(2019B010933001)Science and Technology Projects in Guangzhou(202201000002)Department of Science&Technology of Guangdong Province(2022A156)University Students'Innovation Training Program(No.XJ202311078037)supported by the Shenzhen Science and Technology Program(KCXST20221021111413031)Key Discipline of Materials Science and Engineering,Bureau of Education of Guangzhou(No.202255464).
文摘All-polymer solar cells(all-PSCs)have attracted considerable attention due to their inherent advantages over other types of organic solar cells,including superior optical and thermal stability,as well as exceptional mechanical durability.Recently,all-PSCs have experienced remarkable advancements in device performance thanks to the invention of polymerized small-molecule acceptors(PSMAs)since 2017.Among these PSMAs,PY-IT has garnered immense interest from the scientific community due to its exceptional performance in all-PSCs.In this review,we presented the design principles of PY-IT and discussed the various strategies employed in device engineering for PY-IT-based all-PSCs.These strategies include additive and interface engineering,layer-by-layer processing methods,meniscus-assisted coating methods,and ternary strategy.Furthermore,this review highlighted several novel polymeric donor materials that are paired with PY-IT to achieve efficient all-PSCs.Lastly,we summarized the inspiring strategies for further advancing all-PSCs based on PY-IT.These strategies aim to enhance the overall performance and stability of all-PSCs by exploring new materials,optimizing device architectures,and improving fabrication techniques.By leveraging these approaches,we anticipate significant progress in the development of all-PSCs and their potential as a viable renewable energy source.
