TiO2 nanowire arrays were successfully fabricated by liquid-phase deposition method using porous alumina templates. The obtained TiO2 nanowires were characterized using Raman spectroscopy, X-ray diffraction （XRD）, s...TiO2 nanowire arrays were successfully fabricated by liquid-phase deposition method using porous alumina templates. The obtained TiO2 nanowires were characterized using Raman spectroscopy, X-ray diffraction （XRD）, scanning electron microscopy （SEM）, field emission scanning electron microscopy （FE- SEM）, transmission electron microscopy （TEM）, and selected area electron diffraction （SAED） analysis. Results of electron microscopic observations indicated that the nanowires were smooth and uniform with a diameter of about 50-80 nm and several micrometers in length. SAED, Raman, and XRD mea- surements showed that TiO2 nanowires were single-crystalline with a pure rutile structure after heating at 800 ~C for 10 h. In this situation, the nanowire constituents grew preferentially along the 〈001〉 direction. Furthermore, the formation process and mechanistic study of the Ti02 nanowire arrays were proposed and discussed in detail. The nanowires are clearly produced by the deposition of TiO2 particles on the inner wall of the template nanochannels.展开更多
A coupling model between the canopy layer(CL) and atmospheric boundary layer (ABL) for the study of dry deposition velocity is developed. The model consists of six parts: chemical species conservation equation includi...A coupling model between the canopy layer(CL) and atmospheric boundary layer (ABL) for the study of dry deposition velocity is developed. The model consists of six parts: chemical species conservation equation including absorptive factor; the species uptake action including detailed vertical variation of absorptive element in CL; momentum exchange in CL which is represented by a first-order closure momentum equation with an additional larger-scale diffusive term; momentum exchange in ABL which is described by a complete set of the ABL turbulent statistic parameters; absorptivity (or solubility or reflection) at the surface including effects of the physical and chemical characters of the species, land type, seasonal and diurnal variations of the meteorological variables; and deposition velocity derived by distributions of the species with height in CL. Variational rules of the concentration and deposition velocity with both height and time are simulated with the model for both corn and forest canopies. Results predicted with the bulk deposition velocity derived in the paper consist well with experimental data.展开更多
Laser direct deposition （LDD） of metallic components is an advanced technology of combining CAD/CAM （computer aided design/computer aided manufacturing）, high power laser, and rapid prototyping. This technology us...Laser direct deposition （LDD） of metallic components is an advanced technology of combining CAD/CAM （computer aided design/computer aided manufacturing）, high power laser, and rapid prototyping. This technology uses laser beam to melt the powders fed coaxiaUy into the molten pool by the laser beam to fabricate fuUy dense metallic components. The present article mainly studies the LDD of Ti-6Al-4V alloy, which can be used to fabricate aircraft components. The mechanical properties of the Ti-6Al-4V alloy, fabricated by LDD, are obtained using the tension test, and the oxygen content of used powders and deposited specimens are measured. In the present article, it can be seen that the mechanical properties obtained using this method are higher than the ones obtained by casting, and equal to those got by wrought anneal. One aircraft part has been made using the LDD process. Because of this aircraft part, with sophisticated shape, the effect of the laser scanning track on the internal soundness of the deposited part was discussed.展开更多
Sedimentary process research is of great significance for understanding the distribution and characteristics of sediments.Through the detailed observation and measurement of the Sangyuan outcrop in Luanping Basin,this...Sedimentary process research is of great significance for understanding the distribution and characteristics of sediments.Through the detailed observation and measurement of the Sangyuan outcrop in Luanping Basin,this paper studies the depositional process of the hyperpycnal flow deposits,and divides their depositional process into three phases,namely,acceleration,erosion and deceleration.In the acceleration phase,hyperpycnal flow begins to enter the basin nearby,and then speeds up gradually.Deposits developed in the acceleration phase are reverse.In addition,the original deposits become unstable and are taken away by hyperpycnal flows under the eroding force.As a result,there are a lot of mixture of red mud pebbles outside the basin and gray mud pebbles within the basin.In the erosion phase,the reverse deposits are eroded and become thinner or even disappear.Therefore,no reverse grading characteristic is found in the proximal major channel that is closer to the source,but it is still preserved in the middle branch channel that is far from the source.After entering the deceleration phase,normally grading deposits appear and cover previous deposits.The final deposits in the basin are special.Some are reverse,and others are normal.They are superimposed with each other under the action of hyperpycnal flow.The analysis of the Sangyuan outcrop demonstrates the sedimentary process and distribution of hyperpycnites,and reasonably explain the sedimentary characteristics of hyperpycnites.It is helpful to the prediction of oil and gas exploration targets in gravity flow deposits.展开更多
Anatase nanoparticles were successfully prepared via a facile microwave assisted liquid phase deposition （MW-LPD） process with hexafluorotitanate ammonium （NH4）2TiF6 as precursor. Compared with the conventional LP...Anatase nanoparticles were successfully prepared via a facile microwave assisted liquid phase deposition （MW-LPD） process with hexafluorotitanate ammonium （NH4）2TiF6 as precursor. Compared with the conventional LPD processes, the MW-LPD technique could provide high yield quickly and crystallinity in a diluted precursor solution at a low temperature. The products were characterized by XRD and TEM. Their photocatalytic activities were also investigated by the photodegradation of methylene blue （MB） as a model molecule.展开更多
1 Results Protein thin films gather increasing interests in various biomedical-related materials including surface treatment of implants and bio-tips.Processes via colloid chemical routes such as simple adsorption,dip...1 Results Protein thin films gather increasing interests in various biomedical-related materials including surface treatment of implants and bio-tips.Processes via colloid chemical routes such as simple adsorption,dip-or spin coating enable formation of protein thin films on various substrates.Related methods are facile andconvenient without sophisticated instrumentation but not without restriction.Typical drawbacks are limited solubility of the film-forming species and wettability determined by the com...展开更多
Single variable and deposition weight methods were adopted in the experiment. The hafnium crystal bar was fabricated by the iodide process. Influence of hafnium filament temperature（K value）, temperature controlling...Single variable and deposition weight methods were adopted in the experiment. The hafnium crystal bar was fabricated by the iodide process. Influence of hafnium filament temperature（K value）, temperature controlling method, types of feed, and the loading methods on the deposition rate were studied. The results show that the K value, temperature control method, types of feed, and the loading methods have obvious effects on the deposition rate of the hafnium crystal bar. The deposition rate increases with the K value rising in the range of certain temperature;the salt bath controlling temperature method could effectively obtain the better deposition rate; the greater the contact areas of the feeds are, the faster the deposition rate is.So, the optimal iodide deposition techniques of preparing hafnium crystal bar are as follows： hafnium turnings as feed,molybdenum feed retainer charging, salt bath temperature controlling under the higher K value.展开更多
Superhydrophilic surfaces were fabricated on copper substrates by an electrochemical deposition and sintering process. Superhydrophobic surfaces were prepared by constructing micro/nano-structure on copper substrates ...Superhydrophilic surfaces were fabricated on copper substrates by an electrochemical deposition and sintering process. Superhydrophobic surfaces were prepared by constructing micro/nano-structure on copper substrates through an electrochemical deposition method. Conversion from superhydrophobic to superhydrophilic was obtained via a suitable sintering process. After reduction sintering, the contact angle of the superhydrophilic surfaces changed from 155° to 0°. The scanning electron microscope （SEM） images show that the morphology of superhydrophobic and superhydrophilic surfaces looks like corals and cells respectively. The chemical composition and crystal structure of these surfaces were examined using energy dispersive spectrometry （EDS） and X-ray diffraction （XRD）. The results show that the main components on superhydrophobic surfaces are Cu, Cu2O and CuO, while the superhydrophilic surfaces are composed of Cu merely. The crystal structure is more inerratic and the grain size becomes bigger after the sintering. The interracial strength of the superhydrophilic surfaces was investigated, showing that the interfacial strength between superhydrophilic layer and copper substrate is considerably high.展开更多
To aim at prototype parts fabricated with fused deposition modeling （FDM） process, the problems how to improve and enhance their surface micro-precision are studied. The producing mechanism of surface roughness is e...To aim at prototype parts fabricated with fused deposition modeling （FDM） process, the problems how to improve and enhance their surface micro-precision are studied. The producing mechanism of surface roughness is explained with three aspects concretely including the principle error of rapid prototyping （RP） process, the inherent characteristics of FDM process, and some mi- cro-scratches on the surface of the extruded fiber. Based on the micro-characters of section shape of the FDM prototype, a physical model reflecting the outer shape characters is abstracted. With the physical simplified and deduced, the evaluating equations of surface roughness are acquired. According to the FDM sample parts with special design for experimental measurement, the real surface roughness values of different inclined planes are obtained. And the measuring values of surface roughness are compared with the calculation values. Furthermore, the causes of surface roughness deviation between measuring values and calculation values are respectively analyzed and studied. With the references of analytic conclusions, the measuring values of the experimental part surface are revised, and the revised values nearly accord with the calculation values. Based on the influencing principles of FDM process parameters and special post processing of FDM prototype parts, some concrete measures are proposed to reduce the surface roughness of FDM parts, and the applying effects are better.展开更多
Porosity is a common phenomenon and can significantly hinder the quality of the coating.Here,the pore formation mechanism and the characteristics of the single tracks of the W-C coating using directed energy depositio...Porosity is a common phenomenon and can significantly hinder the quality of the coating.Here,the pore formation mechanism and the characteristics of the single tracks of the W-C coating using directed energy deposition(DED)are systematically investigated.The forming quality of the tracks,the distribution of the pores,and the elemental distribution near the pores are analyzed by the observations of the cross-sections of the tracks.The temperature field of the melt pool is discussed comprehensively to reveal the pore formation mechanism.The results confirm that Ni and Co evaporated during the DED process due to the high temperature of the melt pool.Pores were continuously produced adjacent to the fusion line when the melt pool was about to solidify since the temperature at the solidification front was higher than the boiling point of Ni.The vaporization area at the fusion line was proposed,where Ni could also evaporate at the time the melt pool started to solidify.The relationship between the solidification rate,the size of the vaporization area and the DED parameters(laser power and scanning speed)was established to discuss the causes of severe pores above the fusion line.This work contains a practical guide to reduce or eliminate the porosity in the coating preparation process on the surface of the tungsten alloy.展开更多
LaCrO 3 thin films were successfully prepared at lower temperatures by the sol gel process based on organic chelating precursors. The formation and transition of the gel derived from the chelate solution were analyz...LaCrO 3 thin films were successfully prepared at lower temperatures by the sol gel process based on organic chelating precursors. The formation and transition of the gel derived from the chelate solution were analyzed by means of IR, DTA TG, XRD and TEM. In addition, the formation and microstructure of thin films were investigated by SEM and XRD. The results show that the gel formed by the condensation reaction is decomposed at about 195 ℃, transformed into a great quantity of LaCrO 3 by heat treating at 200 ℃ for 1 h, and the complexing ways in the gel have an important influence upon the formation of LaCrO 3. The formation process of thin film includes the nucleation and growth on the substrate, the formation of polycrystalline islands and the continuous film by repeating the dip coating process. Higher heat treatment temperature gives rise to larger granules in the thin film.展开更多
The electrochemical deposition technique was applied to achieve porous silicon （PS） surface passivated with Ag deposition for improving the properties of PS photoluminescence. The relation of Ag depositing forms to ...The electrochemical deposition technique was applied to achieve porous silicon （PS） surface passivated with Ag deposition for improving the properties of PS photoluminescence. The relation of Ag depositing forms to current density and the effect of PS hydrophilic surface on deposition uniformity were investigated. The experimental results indicated that there were two critical current densities （maximum and minimum） in which Ag was absent and electroplated on PS surface correspondingly, and the range of current density for deposition of Ag on porous silicon was from 50 μA/cm^2 to 400 μA/cm^2. The process of changing PS surface from hydrophobic into hydrophilic had positive effect on Ag deposition uniformity. Under the same experimental conditions, PS hydrophobic surface presented uneven Ag deposition.However, hydrophilic surface treated with SC-1 solution was even. Finally, the effect of PS surface passivation with Ag even deposition on photoluminescence intensity and stabilization of PS was studied. It was discovered that Ag passivation inhibited the degradation of PL intensity effectively. In addition, excessive Ag deposition had a quenching effect on room-temperature visible photoluminescence of PS.展开更多
Sandy braided river deposits are widely preserved in ancient stratigraphic records and act as a significant type of hydrocarbon reservoir.Due to the frequent and rapid migration of channels within the riverbed,the sed...Sandy braided river deposits are widely preserved in ancient stratigraphic records and act as a significant type of hydrocarbon reservoir.Due to the frequent and rapid migration of channels within the riverbed,the sedimentary architecture is highly complex.In this paper,a flume experiment was conducted to reveal the detailed depositional process and establish a fine sedimentary architecture model for sandy braided rivers.The result showed that(1)Three types of braid channels,including the lateral migration channel,the confluence channel,and the deep incised channel,were recognized based on geometry,scale,distribution,and spatial patterns;they are interconnected,forming a complex channel network.(2)Braid channels were characterized by lateral migration,abandonment,filling,and chute cutoff.Lateral migration of channels shaped the braid bars and dominated the formation,growth,and reworking of braid bars.(3)Controlled by the fast and frequent variations of the braid channel network,braid bars were continuously formed,reworked,reshaped,and composited of multiple accretions with different types,orientations,scales,and preservation degrees.Symmetrical and asymmetrical braid bars pre-sented significantly different composition patterns.(4)Dominated by the continuous reworking of braid channels,temporary deposits were limited preserved,braid channel deposits account for 54.3 percent of the eventually preserved braided river deposits,and four types of amalgamate patterns were recognized.Braid bars were cut and limited preserved,only accounting for 45.7 percent of the eventually preserved braided river deposits.(5)During the experiment,only 28 percent of near-surface temporary deposits were eventually preserved in fragmented forms with the final experimental braided river;the shape,spatial patterns,and most of the deposits observed during the depositional process were largely reworked and poorly preserved.(6)The scale of eventually preserved braid bars and braid channels is significantly smaller than the temporary deposits from geomorphic observations.The aspect ratio of the eventually preserved braid bars and the width-to-depth ratio of the eventually preserved braid channel are also significantly different from that of the temporary ones measured from topography data.展开更多
Autogenic processes are widely found in various sedimentary systems and they play an important role in the depositional evolution and corresponding sedimentary architecture.However,autogenic processes are often affect...Autogenic processes are widely found in various sedimentary systems and they play an important role in the depositional evolution and corresponding sedimentary architecture.However,autogenic processes are often affected by changing allogenic factors and are difficult to be identified and analyzed from modern and ancient records.Through the flume tank experiment under constant boundary conditions,the depositional process,evolution principles,and the sedimentary architecture of a river-dominated delta was presented,and a corresponding sedimentary architecture model was constructed.The evolution of river-dominated delta controlled only by autogenic process is obviously periodic,and each autogenic cycle can be divided into an initial progradational stage,a middle retrogratational stage,and a late aggradational–progradational stage.In the initial progradational stage,one feeder channel incised into the delta plain,mouth bar(s)was formed in front of the channel mouth,and small-scale crevasse splays were formed on the delta plain.In the middle retrogradational stage,the feeder channel was blocked by the mouth bar(s)which grew out of water at the end of the initial stage,and a set of large-scale distributary splay complexes were formed on the delta plain.These distributary splay complexes were retrogradationally overlapped due to the continuous migration of the bifurcation point of the feeder channel.In the late aggradational–progradational stage,the feeder channel branched into several radial distributary channels,overlapped distributary channels were formed on the delta plain,and terminal lobe complexes were formed at the end of distributary channels.The three sedimentary layers formed in the three stages constituted an autogenic succession.The experimental delta consisted of six autogenic depositional successions.Dynamic allocation of accommodation space and the following adaptive sediments filling were the two main driving factors of the autogenic evolution of deltas.展开更多
Through our newly-developed ＂chemical vapor deposition integrated process （ISVD-IP）＇＂ using carbon OlOXlae （t..u2） as me raw matenal and only carbon source introduced, CO2 could be catalytically activated and c...Through our newly-developed ＂chemical vapor deposition integrated process （ISVD-IP）＇＂ using carbon OlOXlae （t..u2） as me raw matenal and only carbon source introduced, CO2 could be catalytically activated and converted to a new solid-form product, i.e., carbon nanotubes （CO2-derived） at a quite high yield （the single-pass carbon yield in the solid-form carbon-product produced from CO2 catalytic capture and conversion was more than 30% at a single-pass carbon-base）. For comparison, when only pure carbon dioxide was introduced using the conventional CVD method without integrated process, no solid-form carbon-material product could be formed. In the addition of saturated steam at room temperature in the feed for CVD, there were much more end-opening carbon nano-tubes produced, at a slightly higher carbon yield. These inspiring works opened a remarkable and alternative new approach for carbon dioxide catalytic capture to solid-form product, comparing with that of CO2 sequestration （CCS） or CO2 mineralization （solidification）, etc. As a result, there was much less body volume and almost no greenhouse effect for this solid-form carbon-material than those of primitive carbon dioxide.展开更多
Ge2Sb2Te5 gap filling is one of the key processes for phase-change random access memory manufacture. Physical vapor deposition is the mainstream method of Ge2Sb2Te5 film deposition due to its advantages of film qualit...Ge2Sb2Te5 gap filling is one of the key processes for phase-change random access memory manufacture. Physical vapor deposition is the mainstream method of Ge2Sb2Te5 film deposition due to its advantages of film quality, purity, and accurate composition control. However,the conventional physical vapor deposition process cannot meet the gap- filling requirement with the critical device dimension scaling down to 90 nm or below. In this study, we find that the deposit-etch-deposit process shows better gap-filling capability and scalability than the single-step deposition process, especially at the nano-scale critical dimension. The gap-filling mechanism of the deposit-etch-deposit process was briefly discussed. We also find that re-deposition of phase-change material from via the sidewall to via the bottom by argon ion bombardment during the etch step was a key ingredient for the final good gap filling. We achieve void-free gap filling of phase-change material on the 45-nm via the two-cycle deposit-etch-deposit process. We gain a rather comprehensive insight into the mechanism of deposit-etch-deposit process and propose a potential gap-filling solution for over 45-nm technology nodes for phase-change random access memory.展开更多
Carbon nanotube （CNT） arrays were fabricated on Ct-Me-N-（O） alloys with content of Ct in the range of 6-40 at.% by chemical vapour deposition. The Ct was a catalytic metal from the group of the following elements...Carbon nanotube （CNT） arrays were fabricated on Ct-Me-N-（O） alloys with content of Ct in the range of 6-40 at.% by chemical vapour deposition. The Ct was a catalytic metal from the group of the following elements： Ni, Co, Fe, Pd, while Me was a transition metal from the group of IV-VII of the periodic table （where Me=Ti, V, Cr, Zr, Nb, Mo, Ta, W, Re）. Carbon nanotubes were found to grow efficiently on the alloy surface with its composition containing Ti, V, Cr, Zr, Hf, Nb or Ta. The growth of CNTs was not observed when the alloy contained W or Re. Additions of oxygen and nitrogen in the alloy facilitated the formation of oxynitrides and catalyst extrusion on the alloy surface. Replacement of the metals in alloy composition affected the diameter of the resulting CNTs. The obtained results showed that the alloy films of varying thickness （10-500 nm） may be used for the CNTs growth. The resulting CNT material was highly homogenous and its synthesis reproducible.展开更多
A new deposition method is described using micro electrical discharge machining （EDM） to deposit tool electrode material on workpiece in air. The basic principles of micro electrical discharge deposition （EDD） are...A new deposition method is described using micro electrical discharge machining （EDM） to deposit tool electrode material on workpiece in air. The basic principles of micro electrical discharge deposition （EDD） are analyzed and the realized conditions are predicted. With an ordinary EDM shaping machine, brass as the electrode, high-speed steel as the workpiece, a lot of experiments are carried out on micro EDD systematically and thoroughly. The effects of major processing parameters, such as the discharge current, discharge duration, pulse interval and working medium, are obtained, As a result, a micro cylinder with 0.19 mm in diameter and 7.35 mm in height is deposited. By exchanging the polarities of the electrode and workpiece the micro cylinder can be removed selectively. So the reversible machining of deposition and removal is achieved, which breaks through the constraint of traditional EDM. Measurements show that the deposited material is compact and close to workpiece base, whose components depend on the tool electrode, material.展开更多
Acidic species, such as Nitrate, in polar snow and firn layers are “reversibly” deposited, and are sufficiently volatile to undergo significant post depositional exchange between snow/firn and the atmosphere. Throug...Acidic species, such as Nitrate, in polar snow and firn layers are “reversibly” deposited, and are sufficiently volatile to undergo significant post depositional exchange between snow/firn and the atmosphere. Through comparison of the snowpit and snowpack nitrate concentrations from central East Antarctica and the headwater of rumqi River, we conclude that the nitrate peaks in the uppermost surface snow layers in central Antarctica are not related to an atmospheric signal and must account for post depositional effects. Such effects, however, are not found in the surface snowpack nitrate profiles from the headwater of rumqi River. Two reasons may account for the post depositional difference. At first, nitrate in the polar snow and firn layers appears to be hydrated ion, which can be taken up by the atmosphere, while at the headwater of rumqi River it seems mainly as mineral ion, which assembles the behavior of aerosol derived species that are “irreversibly” deposited and do not undergo significant post depositional exchange with the atmosphere. Secondly, the chemical features of the snow and ice on the Antarctica are mainly determined by wet deposition, to the contrary, dry deposition is more significant at the headwater of rumqi River than that on the East Antarctic Plateau.展开更多
Located in Western Hubei Province,this deposit is a large-scale Ag-V ore deposit,listed among the fifth type of silver deposit in China.1 Geological Characteristics It lies in the NE sector of the Yangtze flat of the ...Located in Western Hubei Province,this deposit is a large-scale Ag-V ore deposit,listed among the fifth type of silver deposit in China.1 Geological Characteristics It lies in the NE sector of the Yangtze flat of the Yangtze paraplatform.There are sporadically magmatic rocks and fold basement made up of upper Archaeozoicmiddle and lower Proterozoic strata.The sedimentary cover consists of Sinian-lower Paleozoic marine sediments,Mesozoic-Cenozoic intercalated marine and nonmarine sediments or nonmarine sediments.展开更多
基金supported by the Institute of Science and High Technology and Environmental Sciences(No.1/1859)
文摘TiO2 nanowire arrays were successfully fabricated by liquid-phase deposition method using porous alumina templates. The obtained TiO2 nanowires were characterized using Raman spectroscopy, X-ray diffraction （XRD）, scanning electron microscopy （SEM）, field emission scanning electron microscopy （FE- SEM）, transmission electron microscopy （TEM）, and selected area electron diffraction （SAED） analysis. Results of electron microscopic observations indicated that the nanowires were smooth and uniform with a diameter of about 50-80 nm and several micrometers in length. SAED, Raman, and XRD mea- surements showed that TiO2 nanowires were single-crystalline with a pure rutile structure after heating at 800 ~C for 10 h. In this situation, the nanowire constituents grew preferentially along the 〈001〉 direction. Furthermore, the formation process and mechanistic study of the Ti02 nanowire arrays were proposed and discussed in detail. The nanowires are clearly produced by the deposition of TiO2 particles on the inner wall of the template nanochannels.
文摘A coupling model between the canopy layer(CL) and atmospheric boundary layer (ABL) for the study of dry deposition velocity is developed. The model consists of six parts: chemical species conservation equation including absorptive factor; the species uptake action including detailed vertical variation of absorptive element in CL; momentum exchange in CL which is represented by a first-order closure momentum equation with an additional larger-scale diffusive term; momentum exchange in ABL which is described by a complete set of the ABL turbulent statistic parameters; absorptivity (or solubility or reflection) at the surface including effects of the physical and chemical characters of the species, land type, seasonal and diurnal variations of the meteorological variables; and deposition velocity derived by distributions of the species with height in CL. Variational rules of the concentration and deposition velocity with both height and time are simulated with the model for both corn and forest canopies. Results predicted with the bulk deposition velocity derived in the paper consist well with experimental data.
基金This work was supported by the National Natural Science Foundation of China （No. 50331010）
文摘Laser direct deposition （LDD） of metallic components is an advanced technology of combining CAD/CAM （computer aided design/computer aided manufacturing）, high power laser, and rapid prototyping. This technology uses laser beam to melt the powders fed coaxiaUy into the molten pool by the laser beam to fabricate fuUy dense metallic components. The present article mainly studies the LDD of Ti-6Al-4V alloy, which can be used to fabricate aircraft components. The mechanical properties of the Ti-6Al-4V alloy, fabricated by LDD, are obtained using the tension test, and the oxygen content of used powders and deposited specimens are measured. In the present article, it can be seen that the mechanical properties obtained using this method are higher than the ones obtained by casting, and equal to those got by wrought anneal. One aircraft part has been made using the LDD process. Because of this aircraft part, with sophisticated shape, the effect of the laser scanning track on the internal soundness of the deposited part was discussed.
基金the Scientific research and technology development project of Petro China(2021DJ5303)。
文摘Sedimentary process research is of great significance for understanding the distribution and characteristics of sediments.Through the detailed observation and measurement of the Sangyuan outcrop in Luanping Basin,this paper studies the depositional process of the hyperpycnal flow deposits,and divides their depositional process into three phases,namely,acceleration,erosion and deceleration.In the acceleration phase,hyperpycnal flow begins to enter the basin nearby,and then speeds up gradually.Deposits developed in the acceleration phase are reverse.In addition,the original deposits become unstable and are taken away by hyperpycnal flows under the eroding force.As a result,there are a lot of mixture of red mud pebbles outside the basin and gray mud pebbles within the basin.In the erosion phase,the reverse deposits are eroded and become thinner or even disappear.Therefore,no reverse grading characteristic is found in the proximal major channel that is closer to the source,but it is still preserved in the middle branch channel that is far from the source.After entering the deceleration phase,normally grading deposits appear and cover previous deposits.The final deposits in the basin are special.Some are reverse,and others are normal.They are superimposed with each other under the action of hyperpycnal flow.The analysis of the Sangyuan outcrop demonstrates the sedimentary process and distribution of hyperpycnites,and reasonably explain the sedimentary characteristics of hyperpycnites.It is helpful to the prediction of oil and gas exploration targets in gravity flow deposits.
文摘Anatase nanoparticles were successfully prepared via a facile microwave assisted liquid phase deposition （MW-LPD） process with hexafluorotitanate ammonium （NH4）2TiF6 as precursor. Compared with the conventional LPD processes, the MW-LPD technique could provide high yield quickly and crystallinity in a diluted precursor solution at a low temperature. The products were characterized by XRD and TEM. Their photocatalytic activities were also investigated by the photodegradation of methylene blue （MB） as a model molecule.
文摘1 Results Protein thin films gather increasing interests in various biomedical-related materials including surface treatment of implants and bio-tips.Processes via colloid chemical routes such as simple adsorption,dip-or spin coating enable formation of protein thin films on various substrates.Related methods are facile andconvenient without sophisticated instrumentation but not without restriction.Typical drawbacks are limited solubility of the film-forming species and wettability determined by the com...
基金financially supported by the National Technology Support Project of China (No. 2012BAB10B10)China–Russia Corporation Program, Ministry of Science (No.2010DFR50800)
文摘Single variable and deposition weight methods were adopted in the experiment. The hafnium crystal bar was fabricated by the iodide process. Influence of hafnium filament temperature（K value）, temperature controlling method, types of feed, and the loading methods on the deposition rate were studied. The results show that the K value, temperature control method, types of feed, and the loading methods have obvious effects on the deposition rate of the hafnium crystal bar. The deposition rate increases with the K value rising in the range of certain temperature;the salt bath controlling temperature method could effectively obtain the better deposition rate; the greater the contact areas of the feeds are, the faster the deposition rate is.So, the optimal iodide deposition techniques of preparing hafnium crystal bar are as follows： hafnium turnings as feed,molybdenum feed retainer charging, salt bath temperature controlling under the higher K value.
基金Supported by the National Natural Science Foundation of China(51275180)the Fundamental Research Funds for the Central Universities(2013ZM0003)the Doctorate Dissertation Funds of Guangdong Province(sybzzxm 201213)
文摘Superhydrophilic surfaces were fabricated on copper substrates by an electrochemical deposition and sintering process. Superhydrophobic surfaces were prepared by constructing micro/nano-structure on copper substrates through an electrochemical deposition method. Conversion from superhydrophobic to superhydrophilic was obtained via a suitable sintering process. After reduction sintering, the contact angle of the superhydrophilic surfaces changed from 155° to 0°. The scanning electron microscope （SEM） images show that the morphology of superhydrophobic and superhydrophilic surfaces looks like corals and cells respectively. The chemical composition and crystal structure of these surfaces were examined using energy dispersive spectrometry （EDS） and X-ray diffraction （XRD）. The results show that the main components on superhydrophobic surfaces are Cu, Cu2O and CuO, while the superhydrophilic surfaces are composed of Cu merely. The crystal structure is more inerratic and the grain size becomes bigger after the sintering. The interracial strength of the superhydrophilic surfaces was investigated, showing that the interfacial strength between superhydrophilic layer and copper substrate is considerably high.
基金This project is supported by National Natural Science Foundation of China (No. 50575139)
文摘To aim at prototype parts fabricated with fused deposition modeling （FDM） process, the problems how to improve and enhance their surface micro-precision are studied. The producing mechanism of surface roughness is explained with three aspects concretely including the principle error of rapid prototyping （RP） process, the inherent characteristics of FDM process, and some mi- cro-scratches on the surface of the extruded fiber. Based on the micro-characters of section shape of the FDM prototype, a physical model reflecting the outer shape characters is abstracted. With the physical simplified and deduced, the evaluating equations of surface roughness are acquired. According to the FDM sample parts with special design for experimental measurement, the real surface roughness values of different inclined planes are obtained. And the measuring values of surface roughness are compared with the calculation values. Furthermore, the causes of surface roughness deviation between measuring values and calculation values are respectively analyzed and studied. With the references of analytic conclusions, the measuring values of the experimental part surface are revised, and the revised values nearly accord with the calculation values. Based on the influencing principles of FDM process parameters and special post processing of FDM prototype parts, some concrete measures are proposed to reduce the surface roughness of FDM parts, and the applying effects are better.
文摘Porosity is a common phenomenon and can significantly hinder the quality of the coating.Here,the pore formation mechanism and the characteristics of the single tracks of the W-C coating using directed energy deposition(DED)are systematically investigated.The forming quality of the tracks,the distribution of the pores,and the elemental distribution near the pores are analyzed by the observations of the cross-sections of the tracks.The temperature field of the melt pool is discussed comprehensively to reveal the pore formation mechanism.The results confirm that Ni and Co evaporated during the DED process due to the high temperature of the melt pool.Pores were continuously produced adjacent to the fusion line when the melt pool was about to solidify since the temperature at the solidification front was higher than the boiling point of Ni.The vaporization area at the fusion line was proposed,where Ni could also evaporate at the time the melt pool started to solidify.The relationship between the solidification rate,the size of the vaporization area and the DED parameters(laser power and scanning speed)was established to discuss the causes of severe pores above the fusion line.This work contains a practical guide to reduce or eliminate the porosity in the coating preparation process on the surface of the tungsten alloy.
文摘LaCrO 3 thin films were successfully prepared at lower temperatures by the sol gel process based on organic chelating precursors. The formation and transition of the gel derived from the chelate solution were analyzed by means of IR, DTA TG, XRD and TEM. In addition, the formation and microstructure of thin films were investigated by SEM and XRD. The results show that the gel formed by the condensation reaction is decomposed at about 195 ℃, transformed into a great quantity of LaCrO 3 by heat treating at 200 ℃ for 1 h, and the complexing ways in the gel have an important influence upon the formation of LaCrO 3. The formation process of thin film includes the nucleation and growth on the substrate, the formation of polycrystalline islands and the continuous film by repeating the dip coating process. Higher heat treatment temperature gives rise to larger granules in the thin film.
文摘The electrochemical deposition technique was applied to achieve porous silicon （PS） surface passivated with Ag deposition for improving the properties of PS photoluminescence. The relation of Ag depositing forms to current density and the effect of PS hydrophilic surface on deposition uniformity were investigated. The experimental results indicated that there were two critical current densities （maximum and minimum） in which Ag was absent and electroplated on PS surface correspondingly, and the range of current density for deposition of Ag on porous silicon was from 50 μA/cm^2 to 400 μA/cm^2. The process of changing PS surface from hydrophobic into hydrophilic had positive effect on Ag deposition uniformity. Under the same experimental conditions, PS hydrophobic surface presented uneven Ag deposition.However, hydrophilic surface treated with SC-1 solution was even. Finally, the effect of PS surface passivation with Ag even deposition on photoluminescence intensity and stabilization of PS was studied. It was discovered that Ag passivation inhibited the degradation of PL intensity effectively. In addition, excessive Ag deposition had a quenching effect on room-temperature visible photoluminescence of PS.
基金funded by two projects of the National Natural Science Foundation of China(No.41802123,42130813).
文摘Sandy braided river deposits are widely preserved in ancient stratigraphic records and act as a significant type of hydrocarbon reservoir.Due to the frequent and rapid migration of channels within the riverbed,the sedimentary architecture is highly complex.In this paper,a flume experiment was conducted to reveal the detailed depositional process and establish a fine sedimentary architecture model for sandy braided rivers.The result showed that(1)Three types of braid channels,including the lateral migration channel,the confluence channel,and the deep incised channel,were recognized based on geometry,scale,distribution,and spatial patterns;they are interconnected,forming a complex channel network.(2)Braid channels were characterized by lateral migration,abandonment,filling,and chute cutoff.Lateral migration of channels shaped the braid bars and dominated the formation,growth,and reworking of braid bars.(3)Controlled by the fast and frequent variations of the braid channel network,braid bars were continuously formed,reworked,reshaped,and composited of multiple accretions with different types,orientations,scales,and preservation degrees.Symmetrical and asymmetrical braid bars pre-sented significantly different composition patterns.(4)Dominated by the continuous reworking of braid channels,temporary deposits were limited preserved,braid channel deposits account for 54.3 percent of the eventually preserved braided river deposits,and four types of amalgamate patterns were recognized.Braid bars were cut and limited preserved,only accounting for 45.7 percent of the eventually preserved braided river deposits.(5)During the experiment,only 28 percent of near-surface temporary deposits were eventually preserved in fragmented forms with the final experimental braided river;the shape,spatial patterns,and most of the deposits observed during the depositional process were largely reworked and poorly preserved.(6)The scale of eventually preserved braid bars and braid channels is significantly smaller than the temporary deposits from geomorphic observations.The aspect ratio of the eventually preserved braid bars and the width-to-depth ratio of the eventually preserved braid channel are also significantly different from that of the temporary ones measured from topography data.
基金supported by a National Natural Science Foundation of China(No.41802123)China Postdoctoral Science Foundation funded project(No.2018M630843)Open Fund of Key Laboratory of Exploration Technologies for Oil and Gas Resources(Yangtze University),Ministry of Education(No.K2017-31)
文摘Autogenic processes are widely found in various sedimentary systems and they play an important role in the depositional evolution and corresponding sedimentary architecture.However,autogenic processes are often affected by changing allogenic factors and are difficult to be identified and analyzed from modern and ancient records.Through the flume tank experiment under constant boundary conditions,the depositional process,evolution principles,and the sedimentary architecture of a river-dominated delta was presented,and a corresponding sedimentary architecture model was constructed.The evolution of river-dominated delta controlled only by autogenic process is obviously periodic,and each autogenic cycle can be divided into an initial progradational stage,a middle retrogratational stage,and a late aggradational–progradational stage.In the initial progradational stage,one feeder channel incised into the delta plain,mouth bar(s)was formed in front of the channel mouth,and small-scale crevasse splays were formed on the delta plain.In the middle retrogradational stage,the feeder channel was blocked by the mouth bar(s)which grew out of water at the end of the initial stage,and a set of large-scale distributary splay complexes were formed on the delta plain.These distributary splay complexes were retrogradationally overlapped due to the continuous migration of the bifurcation point of the feeder channel.In the late aggradational–progradational stage,the feeder channel branched into several radial distributary channels,overlapped distributary channels were formed on the delta plain,and terminal lobe complexes were formed at the end of distributary channels.The three sedimentary layers formed in the three stages constituted an autogenic succession.The experimental delta consisted of six autogenic depositional successions.Dynamic allocation of accommodation space and the following adaptive sediments filling were the two main driving factors of the autogenic evolution of deltas.
基金the National 973 Program of Ministry of Sciences and Technologies of China(2011CB201202)the National Natural Science Foundation of China(20776089)
文摘Through our newly-developed ＂chemical vapor deposition integrated process （ISVD-IP）＇＂ using carbon OlOXlae （t..u2） as me raw matenal and only carbon source introduced, CO2 could be catalytically activated and converted to a new solid-form product, i.e., carbon nanotubes （CO2-derived） at a quite high yield （the single-pass carbon yield in the solid-form carbon-product produced from CO2 catalytic capture and conversion was more than 30% at a single-pass carbon-base）. For comparison, when only pure carbon dioxide was introduced using the conventional CVD method without integrated process, no solid-form carbon-material product could be formed. In the addition of saturated steam at room temperature in the feed for CVD, there were much more end-opening carbon nano-tubes produced, at a slightly higher carbon yield. These inspiring works opened a remarkable and alternative new approach for carbon dioxide catalytic capture to solid-form product, comparing with that of CO2 sequestration （CCS） or CO2 mineralization （solidification）, etc. As a result, there was much less body volume and almost no greenhouse effect for this solid-form carbon-material than those of primitive carbon dioxide.
基金Project supported by the National Basic Research Program of China (Grant Nos.2010CB934300,2011CBA00607,and 2011CB932800)the National Integrate Circuit Research Program of China (Grant No. 2009ZX02023-003)+1 种基金the National Natural Science Foundation of China (Grant Nos. 60906004,60906003,61006087,and 61076121)the Science and Technology Council of Shanghai,China (Grant No. 1052nm07000)
文摘Ge2Sb2Te5 gap filling is one of the key processes for phase-change random access memory manufacture. Physical vapor deposition is the mainstream method of Ge2Sb2Te5 film deposition due to its advantages of film quality, purity, and accurate composition control. However,the conventional physical vapor deposition process cannot meet the gap- filling requirement with the critical device dimension scaling down to 90 nm or below. In this study, we find that the deposit-etch-deposit process shows better gap-filling capability and scalability than the single-step deposition process, especially at the nano-scale critical dimension. The gap-filling mechanism of the deposit-etch-deposit process was briefly discussed. We also find that re-deposition of phase-change material from via the sidewall to via the bottom by argon ion bombardment during the etch step was a key ingredient for the final good gap filling. We achieve void-free gap filling of phase-change material on the 45-nm via the two-cycle deposit-etch-deposit process. We gain a rather comprehensive insight into the mechanism of deposit-etch-deposit process and propose a potential gap-filling solution for over 45-nm technology nodes for phase-change random access memory.
基金financially supported by the Russian Science Foundation(No.16-19-10625)
文摘Carbon nanotube （CNT） arrays were fabricated on Ct-Me-N-（O） alloys with content of Ct in the range of 6-40 at.% by chemical vapour deposition. The Ct was a catalytic metal from the group of the following elements： Ni, Co, Fe, Pd, while Me was a transition metal from the group of IV-VII of the periodic table （where Me=Ti, V, Cr, Zr, Nb, Mo, Ta, W, Re）. Carbon nanotubes were found to grow efficiently on the alloy surface with its composition containing Ti, V, Cr, Zr, Hf, Nb or Ta. The growth of CNTs was not observed when the alloy contained W or Re. Additions of oxygen and nitrogen in the alloy facilitated the formation of oxynitrides and catalyst extrusion on the alloy surface. Replacement of the metals in alloy composition affected the diameter of the resulting CNTs. The obtained results showed that the alloy films of varying thickness （10-500 nm） may be used for the CNTs growth. The resulting CNT material was highly homogenous and its synthesis reproducible.
基金This project is supported by National Natural Science Foundation of China (No.50275038).
文摘A new deposition method is described using micro electrical discharge machining （EDM） to deposit tool electrode material on workpiece in air. The basic principles of micro electrical discharge deposition （EDD） are analyzed and the realized conditions are predicted. With an ordinary EDM shaping machine, brass as the electrode, high-speed steel as the workpiece, a lot of experiments are carried out on micro EDD systematically and thoroughly. The effects of major processing parameters, such as the discharge current, discharge duration, pulse interval and working medium, are obtained, As a result, a micro cylinder with 0.19 mm in diameter and 7.35 mm in height is deposited. By exchanging the polarities of the electrode and workpiece the micro cylinder can be removed selectively. So the reversible machining of deposition and removal is achieved, which breaks through the constraint of traditional EDM. Measurements show that the deposited material is compact and close to workpiece base, whose components depend on the tool electrode, material.
文摘Acidic species, such as Nitrate, in polar snow and firn layers are “reversibly” deposited, and are sufficiently volatile to undergo significant post depositional exchange between snow/firn and the atmosphere. Through comparison of the snowpit and snowpack nitrate concentrations from central East Antarctica and the headwater of rumqi River, we conclude that the nitrate peaks in the uppermost surface snow layers in central Antarctica are not related to an atmospheric signal and must account for post depositional effects. Such effects, however, are not found in the surface snowpack nitrate profiles from the headwater of rumqi River. Two reasons may account for the post depositional difference. At first, nitrate in the polar snow and firn layers appears to be hydrated ion, which can be taken up by the atmosphere, while at the headwater of rumqi River it seems mainly as mineral ion, which assembles the behavior of aerosol derived species that are “irreversibly” deposited and do not undergo significant post depositional exchange with the atmosphere. Secondly, the chemical features of the snow and ice on the Antarctica are mainly determined by wet deposition, to the contrary, dry deposition is more significant at the headwater of rumqi River than that on the East Antarctic Plateau.
文摘Located in Western Hubei Province,this deposit is a large-scale Ag-V ore deposit,listed among the fifth type of silver deposit in China.1 Geological Characteristics It lies in the NE sector of the Yangtze flat of the Yangtze paraplatform.There are sporadically magmatic rocks and fold basement made up of upper Archaeozoicmiddle and lower Proterozoic strata.The sedimentary cover consists of Sinian-lower Paleozoic marine sediments,Mesozoic-Cenozoic intercalated marine and nonmarine sediments or nonmarine sediments.
