Fused salt accelerated hot corrosion is quite common in gas turbines, fossil fuelled devices, waste inclinators, pyrochemical systems, etc. Presence of fused salt on metal surface dissolves their existing oxide layer....Fused salt accelerated hot corrosion is quite common in gas turbines, fossil fuelled devices, waste inclinators, pyrochemical systems, etc. Presence of fused salt on metal surface dissolves their existing oxide layer. This results in an increase in oxidation rate of the metal. Since, zirconia coating is well recognized for corrosion protection under high temperature oxidative environment, we have developed zirconia coating on 9Cr1Mo ferritic steel and their oxidation performance was evaluated in LiCl-NaCl and Na2SO4-K2SO4 salts deposit system in air atmosphere at 650?C and 850?C, respectively. Before coating development, zirconium based sol was synthesized using zirconium (IV) propoxide as a precursor. Oxidation test results indicated that the zirconia coated specimens shows more than two times higher corrosion resistance in LiCl-NaCl and three time higher corrosion resistance in Na2SO4-K2SO4 salt deposit, respectively.展开更多
Aeolian deposits across the Yarlung Zangbo River Basin on the southern Tibetan Plateau record the landscape and atmospheric evolution of Earth's Third Pole.The complex mountain-basin system exhibits nonlinear resp...Aeolian deposits across the Yarlung Zangbo River Basin on the southern Tibetan Plateau record the landscape and atmospheric evolution of Earth's Third Pole.The complex mountain-basin system exhibits nonlinear responses to climate forcing,complicating the interpretation of its high-altitude environmental dynamics.Investigating the magnetic enhancement mechanism of aeolian deposits offers an opportunity to decipher climate signals.Our analysis of three aeolian sections from the basin indicates that magnetic minerals are predominantly low-coercivity ferrimagnetic minerals,and grain sizes fine from upper to lower reaches due to climate shifts from arid to humid.Magnetic enhancement in the upper reaches primarily originates from dust input,while dust input and pedogenesis contribute variably over time in the middle and lower reaches.Similar complex patterns occur in the Ili basin,a mountain-basin system in northwestern China.They differ from the Chinese Loess Plateau,where long-distance-transported dust is well-mixed and the pedogenic enhancement model is applied,and desert peripheries where short-distance dust is transported and the dust input model is applied.We summarize the magnetic enhancement mechanisms in various settings and offer a new framework for applying magnetic techniques in paleoclimate reconstruction within global mountain-basin systems,which highlights the need for caution in interpreting their magnetic susceptibility records.展开更多
Pulsed laser deposition(PLD),as an advanced synthesis technology with unparalleled control over thin films,has evolved into a universal platform for optoelectronic materials engineering.Its unique advantages including...Pulsed laser deposition(PLD),as an advanced synthesis technology with unparalleled control over thin films,has evolved into a universal platform for optoelectronic materials engineering.Its unique advantages including precise stoichiometric transfer,heterogeneous structure preparation and in-situ monitoring enable the design of opto-electrocatalysts with controllable active sites.Traditional methods struggle to pinpoint active sites in hydrogen technologies such as fuel cells and water electrolysis,impeding catalyst customization and mechanistic understanding.Nevertheless,PLD remains underused here despite its outstanding performances in targeted photo-assisted electrocatalysts design.This review systematically explores the breakthrough achievements and provides detailed insights into photo-enhanced water electrolysis and fuel cells based on PLD.Beginning with the fundamentals of epitaxial film growth and film classification,particularly emphasis the related in situ optical analysis techniques.It subsequently highlights recent advances in electro-oxidation and reduction reactions of H_(2)and O_(2),demonstrating the control capabilities of PLD in precisely correlating the structure and activity at the atomic level.Finally,the review concludes by proposing scalable fabrication strategies and performance optimization frameworks to bridge fundamental insights with industrial-scale optoelectronic integration systems.展开更多
Difficulties in the geometric and performance control of wire laser additive manufacturing have hindered its widespread application.In this study,an in situ process monitoring system that combines a machine vision-bas...Difficulties in the geometric and performance control of wire laser additive manufacturing have hindered its widespread application.In this study,an in situ process monitoring system that combines a machine vision-based interlayer height controller(IHC)and P-controller-based melt pool temperature controller(MTC)was developed to improve the vertical dimensional accuracy and mechanical properties of off-axis fine-wire laser-directed energy deposition(OAFW-LDED)for 316 L thin-walled parts.The IHC effectively mitigates external defect inheritance,while its synergy with the MTC ensures process stability,improving the vertical dimensional accuracy to±0.2 mm.Grain refinement was achieved by controlling the thermal input to optimize the thermal history and heat accumulation.A heterogeneous microstructure with alternating coarse and fine grains was observed and intergranular thermal cracking was suppressed.The yield and tensile strengths increased from 262 to 416 MPa to 313 and 516 MPa,respectively,with improved consistency in the yield strength between the top and bottom sections.However,excessive laser heat input caused interlayer cracks.Conversely,increasing the heat input through substrate preheating did not induce additional cracks and improved the overall hardness consistency of the thin-walled samples.Therefore,this study proposes a new formability control strategy for OAFW-LDEDs of thin-walled parts.展开更多
TiB_(2)coatings can significantly enhance the high-temperature oxidation resistance of molybdenum,which would broaden the application range of molybdenum and alloys thereof.However,traditional methods for preparing Ti...TiB_(2)coatings can significantly enhance the high-temperature oxidation resistance of molybdenum,which would broaden the application range of molybdenum and alloys thereof.However,traditional methods for preparing TiB_(2)coatings have disadvantages such as high equipment costs,complicated processes,and highly toxic gas emissions.This paper proposes an environmentally friendly method,which requires inexpensive equipment and simple processing,for preparing TiB_(2)coating on molybdenum via electrophoretic deposition within Na3AlF6-based molten salts.The produced TiB_(2)layer had an approximate thickness of 60μm and exhibited high density,outstanding hardness(38.2 GPa)and robust adhesion strength(51 N).Additionally,high-temperature oxidation experiments revealed that,at900℃,the TiB_(2)coating provided effective protection to the molybdenum substrate against oxidation for 3 h.This result indicates that the TiB_(2)coating prepared on molybdenum using molten salt electrophoretic deposition possesses good high-temperature oxidation resistance.展开更多
Baise basin is a semi-graben type , pan-shaped faulted basin of Early Tertiary , in which carbonate lacustrine deposits and elastic lacustrine deposits developed . The assemblages of Gilbert-type delta-lakes ,littoral...Baise basin is a semi-graben type , pan-shaped faulted basin of Early Tertiary , in which carbonate lacustrine deposits and elastic lacustrine deposits developed . The assemblages of Gilbert-type delta-lakes ,littoral ,shallow and deep water fades are recognized . Based on grain size , the clastic lacustrine deposit systems can be grouped in three kinds of depositional sequences of progressive deposition : (1)from coarse to fine , (2)from fine to coarse and (3) from fine to coarse and then to fine agan . This was controlled mainly by hydrodynamic factor of lake bottom type .Lake shore was an important place for coal accumulation and peatmoor development . It had long time for coal accumulation and there was a very little amount of minerals into the basin ,and the thick coal layer and high quality coal developed m the zone where initial lake bottom was plan-like and the surface stream flow was weak .Peat accumulation advanced from the margin to the center of basin .Carbonate lakes contained much water ,very high preponderant contenis of coagel ,low inert contents and no fusinite in the coal .展开更多
The Silurian in the Tarim Basin was deposited on the basement deformed by the Caledonian tectonic movements at the end of the Late Ordovician. The development and distribution of sedimentary sequences of the Early Sil...The Silurian in the Tarim Basin was deposited on the basement deformed by the Caledonian tectonic movements at the end of the Late Ordovician. The development and distribution of sedimentary sequences of the Early Silurian have been clearly controlled by the palaeogeomorphology of the Late Ordovician. Based on unconformity characteristics and distribution of erosion, several zones can be differentiated including a high uplifted erosion zone, a transitional slope zone and a depression zone. The central and west Tabei Uplift zones show high angular unconformity and intense erosion. The Tarim Basin in the late Ordovician shows characteristics of higher in the west, lower in the east while higher in the south, lower in the north. The Early Silurian mainly developed transgressive and highstand systems tracts on the whole, while the lowstand systems tract only developed partly below the slope break. The palaeogeomorphology controlled the elastic source supply and deposit distribution. Braided delta system and tidal flat-estuary system were deposited. The duration of uplifting of the Tazhong paleo- uplift was longer than that of the Tabei paleo-uplift, and deposition was later. This led to the lower and middle members of the Kepingtage Formation missing in that area. As a large-scale transgression occurred during the deposition period of the upper member of the Kepingtage Formation, sediment from the west of the basin was transported and deposited by tides and waves, forming tidal-marine debris systems above the uplift. Proximal alluvial fan and fan delta coarse elastic deposits developed in proximal uplift zone in the east and southeast of the basin, and braided delta put forward to the transitional zone between the edge of uplift and the sea. Large-scale tidal channel, sub-distributary channel and mouth bar of the delta front can form favorable reservoirs, and they are primary targets for oil and gas exploration. This research on sequence-depositional systems development and distribution controlled by palaeogeomorphology is significant in guiding the prediction of reservoir sandstones.展开更多
In the light of field investigation, microscopic study, X\|ray phase analysis and mineral infrared spectral analysis, it is considered that laumontitization is of extensive occurrence in the Axi gold orefield. The dev...In the light of field investigation, microscopic study, X\|ray phase analysis and mineral infrared spectral analysis, it is considered that laumontitization is of extensive occurrence in the Axi gold orefield. The development of laumontitization and its relationship to mineralization show that the laumontitization appeared mainly at the top of and in the periphery of orebodies, and occurred at the edge of the epithermal system or at the late stage of epithermal system evolution. Therefore, laumontitization can be used as an exploration indicator of epithermal gold deposits. The fluids responsible for laumontitization in the Axi gold orefield are similar to those producing hot spring\|type gold deposits or those from modern geothermal fields. Epithermal mineralization of the Axi gold deposit was dated at Carboniferous, indicating that the West Tianshan of China is a region favorable to epithermal\|type gold mineralization and preservation. Hence the West Tianshan of China is a target area for exploring epithermal gold deposits.展开更多
The Tieluping silver deposit, which is sited along NE-trending faults within the high-grade metamorphic basement of the Xiong'er terrane, is part of an important Mesozoic orogenic-type Ag-Pb and Au belt recently d...The Tieluping silver deposit, which is sited along NE-trending faults within the high-grade metamorphic basement of the Xiong'er terrane, is part of an important Mesozoic orogenic-type Ag-Pb and Au belt recently discovered. Ore formation includes three stages: Early (E), Middle (M) and Late (L), which include quartz-pyrite (E), polymetallic sulfides (M) and carbonates (L), respectively. The E-stage fluids are characterized by δD=-90‰, and δ 18 O=9‰ at 373°C, and are deeply sourced; the L-stage fluids, with δD=-70‰, and δ 18 O=-2‰, are shallow-sourced meteoric water; whereas the M-stage fluids, with δD=-109‰, and δ 18 O=2‰, are a mix of deep-sourced and shallow-sourced fluids. Comparisons of the D-O-C isotopic systematics of the E- stage ore-forming fluids with the fluids derived from Mesozoic granites, Archean-Paleoproterozoic metamorphic basement and Paleo-Mesoproterozoic Xiong'er Group, show that these units cannot generate fluids with the measured isotopic composition (highδ 18 O and δ 13 C ratios and lowδD ratios) characteristic of the ore-forming fluids. This suggests that the E-stage ore-forming fluids originated from metamorphic devolatilization of a carbonate-shale-chert lithological association, locally rich in organic matter, which could correspond to the Meso-Neoproterozoic Guandaokou and Luanchuan Groups, rather than to geologic units in the Xiong'er terrane, the lower crust and the mantle. This supports the view that the rocks of the Guandaokou and Luanchuan Groups south of the Machaoying fault might be the favorable sources. A tectonic model that combines collisional orogeny, metallogeny and hydrothermal fluid flow is proposed to explain the formation of the Tieluping silver deposit. During the Mesozoic collision between the South and North China paleocontinents, a crustal slab containing a lithological association consisting of carbonate-shale-chert, locally rich in organic matter (carbonaceous shale) was thrust northwards beneath the Xiong'er terrane along the Machaoying fault. Metamorphic devolatilization of this underthrust slab provided the ore-forming fluids to develop the Au-Ag-(Pb-Zn) ore belt, which includes the Tieluping silver deposit.展开更多
Many theoretical results on sandstone-type uranium mineralization in northern China obtained by the uranium research team of the Tianjin Center of Geological Survey in recent years are presented.From the source sink s...Many theoretical results on sandstone-type uranium mineralization in northern China obtained by the uranium research team of the Tianjin Center of Geological Survey in recent years are presented.From the source sink system of uranium-producing basins,sedimentary environment of uranium-bearing rock series,ore-forming fluid information,evolution of tectonic events,basin formation and development,we redefine and classify uranium orebodies,redox zoning,and ore-controlling structural styles.We then systematically propose a theoretical system of sandstone-type uranium deposits in northern China.We conclude that sandstone-type uranium deposits in northern China are mainly found in sedimentary environments such as rivers,deltas,and alluvial fans in the Mesozoic and Cenozoic lowstand systems tract and in gray sandstone layers in the vertical redox zoning.The orebodies are controlled by the tectonic slope belt,which is in the shape of a strip on the plane,and spreads in a layer or plate on the section.Vertical(ups and downs)tectonic movement triggers large-scale phreatic flow in the basin,which is the real driving force for controlling the ore-forming fluid.The theoretical system of sandstone-type uranium deposits in northern China should be based on global tectonic movement and environmental changes and take into account factors such as basins as a unit to study mineralization background,ore concentration areas as objects to study mineralization,and the correlation between regional tectonic movement and metallogenic process as a breakthrough point to study tectonic events and metallogenic events.It should also be based on different basin types to establish metallogenic models.The innovative research results and ideas are summarized with the aim of promoting the continuous improvement of sandstone-type uranium mineralization theory in northern China.展开更多
The reef-shoal depositional system of the Ordovician carbonate platform margin is well exposed in the Yijianfang （一间房） outcrop of the Bachn （巴楚） uplift region, which offers an advantageous condition to study ...The reef-shoal depositional system of the Ordovician carbonate platform margin is well exposed in the Yijianfang （一间房） outcrop of the Bachn （巴楚） uplift region, which offers an advantageous condition to study their paleoecology. Using a detailed field geologic survey and illustrated profiles of typical depositional systems, three types of genetic facies associations can be recognized in the reef-shoal depositional system： an organic reef, an organic shoal, and an upper slope. The organic reef is composed of three types of genetic facies （a reef base, a reef core, and fore-reef breccias）; the organic shoal is formed from five types of genetic facies （tide channels, fore-reef inner shoals, fore-reef outer shoals, back-reef inner shoals, and back-reef outer shoals）. The studies of the paleontological assemblage in each genetic facies of the depositional system indicate that the fauna preserved in each genetic facies are varied. The calathium, archaeoscyphia, bryozoan, and calcareous alga are well preserved in the organic reefs. The organisms preserved in the organic shoals are generally fragmented, while weil-preserved girvanella and nuia siberica with a content of about 15% in the back-reef outer shoals are the most characteristic and different from others. The sinoceras, trilobites, and gastropods are well preserved in the upper slope deposits. The studies will demonstrate that the reef-shoal complexes developed above the base of the fair-weather wave base and that the original hydrodynamic conditions for the reef core forming is the stronger and become more and more low-energy from the inner part to outer part of the organic shoals.展开更多
He-Ar isotopic compositions of fluid inclusions trapped in pyrites from some representative PGE-polymetallic deposits in Lower Cambrian black rock series in South China were analyzed by using an inert gas isotopic mas...He-Ar isotopic compositions of fluid inclusions trapped in pyrites from some representative PGE-polymetallic deposits in Lower Cambrian black rock series in South China were analyzed by using an inert gas isotopic mass spectrometer. The results show that the ore-forming fluids possess a low 3He/4He ratio, varying from 0.43×10-8 to 26.39×10-8, with corresponding R/Ra value of 0.003-0.189. The 40Ar/36Ar ratios are 258-287, close to those of air saturated water (ASW). He-Ar isotopic indicator studies show that the ore-forming fluids were mainly derived from the formation water or basinal hot brine and sea water, while the content of mantle-derived fluid or deep-derived magmatic water might be negligible. The PGE-polymetallic mineralization might be related to the evolution of the Caledonian miogeosynclines distributed along the southern margin of the Yangtze Craton. During the Early Cambrian, the formation water or basinal hot brine trapped in Caledonian basins which accumulated giant thick sediments was expelled and migrated laterally along strata because of the pressure generated by overlying sediments. The basinal hot brine ascended along faults, mixed with sea water and finally deposited ore minerals.展开更多
The Muruntau gold deposit in the Central Kyzylkum,Uzbekistan is one of the largest single gold deposits worldwide.Data available from the literature are reviewed with the aim to（1） integrate the present knowledge on...The Muruntau gold deposit in the Central Kyzylkum,Uzbekistan is one of the largest single gold deposits worldwide.Data available from the literature are reviewed with the aim to（1） integrate the present knowledge on this unique deposit from Russian and English literature;（2） show the considerable progress made in the understanding of the genesis of the Muruntau deposit during the last decades;and（3） point to problems still open for future research.Deposit formation occurred through a multi-stage process involving sedimentation,regional metamorphism including thrusting,magmatism with formation of hornfels aureoles and several stages of hydrothermal activity.According to recent knowledge,synsedimentary or pure metamorphic formation of gold mineralization seems unlikely.The role of granite magmatism occurring roughly within the same time interval as the main hydrothermal gold precipitation remains uncertain.There are no signs of interaction of matter between the magma（s） and the hydrothermal system（s）.On the other hand,there was an intense,high-temperature（above 400 ℃）fluid- wall rock interaction resulting in the formation of gold-bearing,cone-like stockworks with veins,veinlets and gold-bearing metasomatites.Several chemical and isotope indicators hint at an involvement of lower-crustal or mantle-related sources as well as of surface waters in ore formation.Deposit formation through brecciation involving explosion,hydrothermal or tectonic breccias might explain these data.Further investigations on breccia formation as well as on the exact timing of relevant sedimentary,metamorphic,magmatic and hydrothermal events are recommended.展开更多
As an example of atmospheric nitrogen(N) deposition,the paper summarizes the definition,form and amount of nutrient from the environment(NFE) and the relationship between NFE and anthro-pogenic reactive N emission.Bas...As an example of atmospheric nitrogen(N) deposition,the paper summarizes the definition,form and amount of nutrient from the environment(NFE) and the relationship between NFE and anthro-pogenic reactive N emission.Based on our own study and published articles,we find that N wet and dry deposition has been an important nutrient resource in agricultural and natural ecosystems in China.The total amount of N deposition and other environment-derived N in China was up to 18 Tg N/a,equal to ap-proximately 60% of the national N fertilizer consumption.Nitrogen deposition is expected to contribute substantially to nutrient cycling and net primary productivity in various ecosystems.Therefore,it is crucial to utilize this environment-derived nutrient resource by integrated nutrient resource management in order to realize the sustainable development of both agricultural and non-agricultural ecosystems.展开更多
The Upper Eocene–Lower Oligocene Qianjiang Formation of the Jianghan Basin in central China consists of a 4700-m-thick lacustrine succession, containing 1800 m of halite deposits. The maximum thickness of the formati...The Upper Eocene–Lower Oligocene Qianjiang Formation of the Jianghan Basin in central China consists of a 4700-m-thick lacustrine succession, containing 1800 m of halite deposits. The maximum thickness of the formation is 4700 m, and includes 1800 m of halite. We have identified eight third-order depositional sequences based on pinch-out and onlap stratigraphic patterns in 2-D and 3-D seismic data and well logs. The basin evolved from a deep to shallow under-filled lake during the Eocene–Oligocene interval. The main rock types are dark mudstones, halite, and siltstone/sandstone in the depocenter, and alternating mudstone and gypsum in shallower areas. The vertical succession indicates a strong sedimentary cyclicity. Depositional facies indicate the presence of two lake system types. Halite developed in a saline lake system, whereas clastic sediments were deposited in freshwater lake systems. The alternating sediment types indicate that the basin cycled repeatedly between saline and freshwater lake systems. This cyclicity was caused by availability of accommodation space that was controlled by a combination of climate change, tectonic subsidence and sediment supply; notably, the highest frequency cycles occurred at Milankovitch timescales controlled by the Earth＇s orbital variations. The cyclic halite plays an important role in generating and preserving oil in the Qianjiang Formation of the Qianjiang depression.展开更多
In this study,commercial copper(Cu)foil and Cu foam are used as the working electrodes to systematically investigate the electrochemical deposition and dissolution processes of metallic lithium(Li)on these electrodes;...In this study,commercial copper(Cu)foil and Cu foam are used as the working electrodes to systematically investigate the electrochemical deposition and dissolution processes of metallic lithium(Li)on these electrodes;Li metal deposited on the Cu foil electrode is porous and loose.The surface solid electrolyte interface(SEI)film after dissolution from Li dendrites maintains a dendritic porous structure,resulting in a large volume effect of the electrode during the cycle.The Cu foam electrode provides preferential nucleation and deposition sites near the side surface of the separator;the difference in Li affinity results in a heterogeneous deposition and dendrite growth of metallic Li.展开更多
In the early Proterozoic the Li'eryu Formation and Dashiqiao Formation of eastern Liaoning province, China, there are distributed Mg-rich carbonate rock formations, in which large to superlarge deposits of boron, ...In the early Proterozoic the Li'eryu Formation and Dashiqiao Formation of eastern Liaoning province, China, there are distributed Mg-rich carbonate rock formations, in which large to superlarge deposits of boron, magnesite, talc, Xiuyan jade etc. occur. The formation of these magnesian nonmetallic deposits was related to early Proterozoic evaporates; then these deposits underwent reworking of regional metamorphism and hydrothermal metasomatism during the Lüliang orogeny and tectono-magmatism during the Indosinian-Yanshanian. Among other things, the Mg-rich carbonates formations, minerogenetic structures and ore-forming fluids played a controlling role in the formation of the mineral deposits. Therefore, it can be concluded that the mineral deposits are products of combined processes of the coupling of ore source field, fluid field, thermal field (energy field) and stress field under certain time-space conditions in the early Proterozoic and the late-stage superimposed reworking of tectono-magmatism.展开更多
A continuous three-year observation(from May 2008 to April 2011)was conducted to characterize the spatial variation of dissolved inorganic nitrogen(DIN)deposition at eight main forest ecosystems along the north-south ...A continuous three-year observation(from May 2008 to April 2011)was conducted to characterize the spatial variation of dissolved inorganic nitrogen(DIN)deposition at eight main forest ecosystems along the north-south transect of eastern China(NSTEC).The results show that both throughfall DIN deposition and bulk DIN deposition increase from north to south along the NSTEC.Throughfall DIN deposition varies greatly from 2.7 kg N/(ha·yr)to 33.0 kg N/(ha·yr),with an average of 10.6 kg N/(ha·yr),and bulk DIN deposition ranges from 4.1 kg N/(ha·yr)to 25.4 kg N/(ha·yr),with an average of 9.8 kg N/(ha·yr).NH4+-N is the dominant form of DIN deposition at most sampling sites.Additionally,the spatial variation of DIN deposition is controlled mainly by precipitation.Moreover,in the northern part of the NSTEC,bulk DIN deposition is 17%higher than throughfall DIN deposition,whereas the trend is opposite in the southern part of the NSTEC.The results demonstrate that DIN deposition would likely threaten the forest ecosystems along the NSTEC,compared with the critical loads(CL)of N deposition,and DIN deposition in this region is mostly controlled by agricultural activities rather than industrial activities or transportation.展开更多
Using analyses of the lithology,sequences,paleoenvironment,and tectonic setting,the depositional system of the Carboniferous Huanglong Formation in the eastern Sichuan Basin was identified.The lithological characteris...Using analyses of the lithology,sequences,paleoenvironment,and tectonic setting,the depositional system of the Carboniferous Huanglong Formation in the eastern Sichuan Basin was identified.The lithological characteristics of the Lower Member,Middle Member,and Upper Member were analyzed and classified.Before the use of carbon,oxygen,and strontium isotopes in the analysis,all of the geochemical data were tested for validity.On the basis of the Z values obtained from carbon and oxygen isotopes,the paleoenvironments of the three members were elucidated.Lower Member was dominantly an enclosed marine environment with intense evaporation and little freshwater input into the sea.Middle Member developed in a semi-enclosed to normal marine environment with many rivers.Upper Member was formed in a normal marine environment.The east Sichuan Basin was enclosed by paleouplifts before the deposition of the Huanglong Formation,forming a relatively enclosed depositional setting.Paleogullies developed in the Silurian strata that underlie the Carboniferous rocks;these paleogullies can be identified.On the basis of a comprehensive analysis,we propose that the Huanglong Formation developed in a platform system.Four microfacies were identified：supratidal flat,dolostone flat,grain shoal,and shelf microfacies.The high-permeability and high-porosity characteristics of the grain shoal microfacies are favorable for hydrocarbon accumulation,while the supratidal flat and shelf microfacies developed very few high-quality reservoirs.The paleogullies,in which increased amounts of grain shoal microfacies developed,controlled the distribution of high-quality reservoirs.展开更多
文摘Fused salt accelerated hot corrosion is quite common in gas turbines, fossil fuelled devices, waste inclinators, pyrochemical systems, etc. Presence of fused salt on metal surface dissolves their existing oxide layer. This results in an increase in oxidation rate of the metal. Since, zirconia coating is well recognized for corrosion protection under high temperature oxidative environment, we have developed zirconia coating on 9Cr1Mo ferritic steel and their oxidation performance was evaluated in LiCl-NaCl and Na2SO4-K2SO4 salts deposit system in air atmosphere at 650?C and 850?C, respectively. Before coating development, zirconium based sol was synthesized using zirconium (IV) propoxide as a precursor. Oxidation test results indicated that the zirconia coated specimens shows more than two times higher corrosion resistance in LiCl-NaCl and three time higher corrosion resistance in Na2SO4-K2SO4 salt deposit, respectively.
基金National Natural Science Foundation of China,No.42501182The Open Foundation of Key Laboratory of Western China’s Environmental System,Ministry of Education,Lanzhou Universitythe Fundamental Research Funds for the Central Universities,No.lzujbky-2024-jdzx01。
文摘Aeolian deposits across the Yarlung Zangbo River Basin on the southern Tibetan Plateau record the landscape and atmospheric evolution of Earth's Third Pole.The complex mountain-basin system exhibits nonlinear responses to climate forcing,complicating the interpretation of its high-altitude environmental dynamics.Investigating the magnetic enhancement mechanism of aeolian deposits offers an opportunity to decipher climate signals.Our analysis of three aeolian sections from the basin indicates that magnetic minerals are predominantly low-coercivity ferrimagnetic minerals,and grain sizes fine from upper to lower reaches due to climate shifts from arid to humid.Magnetic enhancement in the upper reaches primarily originates from dust input,while dust input and pedogenesis contribute variably over time in the middle and lower reaches.Similar complex patterns occur in the Ili basin,a mountain-basin system in northwestern China.They differ from the Chinese Loess Plateau,where long-distance-transported dust is well-mixed and the pedogenic enhancement model is applied,and desert peripheries where short-distance dust is transported and the dust input model is applied.We summarize the magnetic enhancement mechanisms in various settings and offer a new framework for applying magnetic techniques in paleoclimate reconstruction within global mountain-basin systems,which highlights the need for caution in interpreting their magnetic susceptibility records.
基金supported by the Youth Project of the National Natural Science Foundation of China(Grant No.22402024)the Postdoctoral Innovation Talents Support Program of China(Grant No.BX20230061)the Natural Science Foundation of Sichuan(Grant No.25QNJJ3094).P.M.-B.acknowledges funding from Deutsche Forschungsgemeinschaft(DFG,German Research Foundation)under Germany's Excellence Strategy-EXC 2089/1-390776260(e conversion).
文摘Pulsed laser deposition(PLD),as an advanced synthesis technology with unparalleled control over thin films,has evolved into a universal platform for optoelectronic materials engineering.Its unique advantages including precise stoichiometric transfer,heterogeneous structure preparation and in-situ monitoring enable the design of opto-electrocatalysts with controllable active sites.Traditional methods struggle to pinpoint active sites in hydrogen technologies such as fuel cells and water electrolysis,impeding catalyst customization and mechanistic understanding.Nevertheless,PLD remains underused here despite its outstanding performances in targeted photo-assisted electrocatalysts design.This review systematically explores the breakthrough achievements and provides detailed insights into photo-enhanced water electrolysis and fuel cells based on PLD.Beginning with the fundamentals of epitaxial film growth and film classification,particularly emphasis the related in situ optical analysis techniques.It subsequently highlights recent advances in electro-oxidation and reduction reactions of H_(2)and O_(2),demonstrating the control capabilities of PLD in precisely correlating the structure and activity at the atomic level.Finally,the review concludes by proposing scalable fabrication strategies and performance optimization frameworks to bridge fundamental insights with industrial-scale optoelectronic integration systems.
基金supported by Open Research Fund of the Sichuan Institute of Xiamen University(Grant No.202401ZDB004)。
文摘Difficulties in the geometric and performance control of wire laser additive manufacturing have hindered its widespread application.In this study,an in situ process monitoring system that combines a machine vision-based interlayer height controller(IHC)and P-controller-based melt pool temperature controller(MTC)was developed to improve the vertical dimensional accuracy and mechanical properties of off-axis fine-wire laser-directed energy deposition(OAFW-LDED)for 316 L thin-walled parts.The IHC effectively mitigates external defect inheritance,while its synergy with the MTC ensures process stability,improving the vertical dimensional accuracy to±0.2 mm.Grain refinement was achieved by controlling the thermal input to optimize the thermal history and heat accumulation.A heterogeneous microstructure with alternating coarse and fine grains was observed and intergranular thermal cracking was suppressed.The yield and tensile strengths increased from 262 to 416 MPa to 313 and 516 MPa,respectively,with improved consistency in the yield strength between the top and bottom sections.However,excessive laser heat input caused interlayer cracks.Conversely,increasing the heat input through substrate preheating did not induce additional cracks and improved the overall hardness consistency of the thin-walled samples.Therefore,this study proposes a new formability control strategy for OAFW-LDEDs of thin-walled parts.
基金supported by the Original Exploratory Program of the National Natural Science Foundation of China(No.52450012)。
文摘TiB_(2)coatings can significantly enhance the high-temperature oxidation resistance of molybdenum,which would broaden the application range of molybdenum and alloys thereof.However,traditional methods for preparing TiB_(2)coatings have disadvantages such as high equipment costs,complicated processes,and highly toxic gas emissions.This paper proposes an environmentally friendly method,which requires inexpensive equipment and simple processing,for preparing TiB_(2)coating on molybdenum via electrophoretic deposition within Na3AlF6-based molten salts.The produced TiB_(2)layer had an approximate thickness of 60μm and exhibited high density,outstanding hardness(38.2 GPa)and robust adhesion strength(51 N).Additionally,high-temperature oxidation experiments revealed that,at900℃,the TiB_(2)coating provided effective protection to the molybdenum substrate against oxidation for 3 h.This result indicates that the TiB_(2)coating prepared on molybdenum using molten salt electrophoretic deposition possesses good high-temperature oxidation resistance.
文摘Baise basin is a semi-graben type , pan-shaped faulted basin of Early Tertiary , in which carbonate lacustrine deposits and elastic lacustrine deposits developed . The assemblages of Gilbert-type delta-lakes ,littoral ,shallow and deep water fades are recognized . Based on grain size , the clastic lacustrine deposit systems can be grouped in three kinds of depositional sequences of progressive deposition : (1)from coarse to fine , (2)from fine to coarse and (3) from fine to coarse and then to fine agan . This was controlled mainly by hydrodynamic factor of lake bottom type .Lake shore was an important place for coal accumulation and peatmoor development . It had long time for coal accumulation and there was a very little amount of minerals into the basin ,and the thick coal layer and high quality coal developed m the zone where initial lake bottom was plan-like and the surface stream flow was weak .Peat accumulation advanced from the margin to the center of basin .Carbonate lakes contained much water ,very high preponderant contenis of coagel ,low inert contents and no fusinite in the coal .
基金funded by the National Key Basic Research Program (973) (No. 2006CB202302)National Natural Science Foundation Program (No. 40372056)+1 种基金Fundamental Research Funds for the Central Universities(2010ZD07)the Frontier Research Project of Marine Facies (Evolution of the Tarim Basin and Surrounding Areaand Petroleum Resource Prospecting)
文摘The Silurian in the Tarim Basin was deposited on the basement deformed by the Caledonian tectonic movements at the end of the Late Ordovician. The development and distribution of sedimentary sequences of the Early Silurian have been clearly controlled by the palaeogeomorphology of the Late Ordovician. Based on unconformity characteristics and distribution of erosion, several zones can be differentiated including a high uplifted erosion zone, a transitional slope zone and a depression zone. The central and west Tabei Uplift zones show high angular unconformity and intense erosion. The Tarim Basin in the late Ordovician shows characteristics of higher in the west, lower in the east while higher in the south, lower in the north. The Early Silurian mainly developed transgressive and highstand systems tracts on the whole, while the lowstand systems tract only developed partly below the slope break. The palaeogeomorphology controlled the elastic source supply and deposit distribution. Braided delta system and tidal flat-estuary system were deposited. The duration of uplifting of the Tazhong paleo- uplift was longer than that of the Tabei paleo-uplift, and deposition was later. This led to the lower and middle members of the Kepingtage Formation missing in that area. As a large-scale transgression occurred during the deposition period of the upper member of the Kepingtage Formation, sediment from the west of the basin was transported and deposited by tides and waves, forming tidal-marine debris systems above the uplift. Proximal alluvial fan and fan delta coarse elastic deposits developed in proximal uplift zone in the east and southeast of the basin, and braided delta put forward to the transitional zone between the edge of uplift and the sea. Large-scale tidal channel, sub-distributary channel and mouth bar of the delta front can form favorable reservoirs, and they are primary targets for oil and gas exploration. This research on sequence-depositional systems development and distribution controlled by palaeogeomorphology is significant in guiding the prediction of reservoir sandstones.
文摘In the light of field investigation, microscopic study, X\|ray phase analysis and mineral infrared spectral analysis, it is considered that laumontitization is of extensive occurrence in the Axi gold orefield. The development of laumontitization and its relationship to mineralization show that the laumontitization appeared mainly at the top of and in the periphery of orebodies, and occurred at the edge of the epithermal system or at the late stage of epithermal system evolution. Therefore, laumontitization can be used as an exploration indicator of epithermal gold deposits. The fluids responsible for laumontitization in the Axi gold orefield are similar to those producing hot spring\|type gold deposits or those from modern geothermal fields. Epithermal mineralization of the Axi gold deposit was dated at Carboniferous, indicating that the West Tianshan of China is a region favorable to epithermal\|type gold mineralization and preservation. Hence the West Tianshan of China is a target area for exploring epithermal gold deposits.
基金the Ministry ofScience and Technology of China(Grant No.95-Pre-39-04)National Natural Science Foundation of China(Grant Nos.40425006,49972035,40352003)+1 种基金the Hundred YoungScientists Program of the Chinese Academy of Sciences(CAS) the Trans-Century Teacher Program of theEducation Ministry of China.
文摘The Tieluping silver deposit, which is sited along NE-trending faults within the high-grade metamorphic basement of the Xiong'er terrane, is part of an important Mesozoic orogenic-type Ag-Pb and Au belt recently discovered. Ore formation includes three stages: Early (E), Middle (M) and Late (L), which include quartz-pyrite (E), polymetallic sulfides (M) and carbonates (L), respectively. The E-stage fluids are characterized by δD=-90‰, and δ 18 O=9‰ at 373°C, and are deeply sourced; the L-stage fluids, with δD=-70‰, and δ 18 O=-2‰, are shallow-sourced meteoric water; whereas the M-stage fluids, with δD=-109‰, and δ 18 O=2‰, are a mix of deep-sourced and shallow-sourced fluids. Comparisons of the D-O-C isotopic systematics of the E- stage ore-forming fluids with the fluids derived from Mesozoic granites, Archean-Paleoproterozoic metamorphic basement and Paleo-Mesoproterozoic Xiong'er Group, show that these units cannot generate fluids with the measured isotopic composition (highδ 18 O and δ 13 C ratios and lowδD ratios) characteristic of the ore-forming fluids. This suggests that the E-stage ore-forming fluids originated from metamorphic devolatilization of a carbonate-shale-chert lithological association, locally rich in organic matter, which could correspond to the Meso-Neoproterozoic Guandaokou and Luanchuan Groups, rather than to geologic units in the Xiong'er terrane, the lower crust and the mantle. This supports the view that the rocks of the Guandaokou and Luanchuan Groups south of the Machaoying fault might be the favorable sources. A tectonic model that combines collisional orogeny, metallogeny and hydrothermal fluid flow is proposed to explain the formation of the Tieluping silver deposit. During the Mesozoic collision between the South and North China paleocontinents, a crustal slab containing a lithological association consisting of carbonate-shale-chert, locally rich in organic matter (carbonaceous shale) was thrust northwards beneath the Xiong'er terrane along the Machaoying fault. Metamorphic devolatilization of this underthrust slab provided the ore-forming fluids to develop the Au-Ag-(Pb-Zn) ore belt, which includes the Tieluping silver deposit.
基金The“Northern Sandstone-type Uranium Deposits Investigation Project”(Project 0108)of the China Geological Survey has led to the discovery of many new sandstone-type uranium depositsThe National Basic Research Program(973 Program)(No.2015CB453000)+1 种基金the National Key R&D Program of China(No.2018YFC0604200)both from the Ministry of Science and Technology of the People’s Republic of China have led to innovations in many theoretical understandings of sandstone-type uranium depositsUnder the International Geoscience Programme(No.IGCP-675),a comparative study of sandstone-type uranium deposits between China and the rest of the world has been conducted。
文摘Many theoretical results on sandstone-type uranium mineralization in northern China obtained by the uranium research team of the Tianjin Center of Geological Survey in recent years are presented.From the source sink system of uranium-producing basins,sedimentary environment of uranium-bearing rock series,ore-forming fluid information,evolution of tectonic events,basin formation and development,we redefine and classify uranium orebodies,redox zoning,and ore-controlling structural styles.We then systematically propose a theoretical system of sandstone-type uranium deposits in northern China.We conclude that sandstone-type uranium deposits in northern China are mainly found in sedimentary environments such as rivers,deltas,and alluvial fans in the Mesozoic and Cenozoic lowstand systems tract and in gray sandstone layers in the vertical redox zoning.The orebodies are controlled by the tectonic slope belt,which is in the shape of a strip on the plane,and spreads in a layer or plate on the section.Vertical(ups and downs)tectonic movement triggers large-scale phreatic flow in the basin,which is the real driving force for controlling the ore-forming fluid.The theoretical system of sandstone-type uranium deposits in northern China should be based on global tectonic movement and environmental changes and take into account factors such as basins as a unit to study mineralization background,ore concentration areas as objects to study mineralization,and the correlation between regional tectonic movement and metallogenic process as a breakthrough point to study tectonic events and metallogenic events.It should also be based on different basin types to establish metallogenic models.The innovative research results and ideas are summarized with the aim of promoting the continuous improvement of sandstone-type uranium mineralization theory in northern China.
基金supported by the SINOPEC Forward Looking Project of China (No. YPH08114)
文摘The reef-shoal depositional system of the Ordovician carbonate platform margin is well exposed in the Yijianfang （一间房） outcrop of the Bachn （巴楚） uplift region, which offers an advantageous condition to study their paleoecology. Using a detailed field geologic survey and illustrated profiles of typical depositional systems, three types of genetic facies associations can be recognized in the reef-shoal depositional system： an organic reef, an organic shoal, and an upper slope. The organic reef is composed of three types of genetic facies （a reef base, a reef core, and fore-reef breccias）; the organic shoal is formed from five types of genetic facies （tide channels, fore-reef inner shoals, fore-reef outer shoals, back-reef inner shoals, and back-reef outer shoals）. The studies of the paleontological assemblage in each genetic facies of the depositional system indicate that the fauna preserved in each genetic facies are varied. The calathium, archaeoscyphia, bryozoan, and calcareous alga are well preserved in the organic reefs. The organisms preserved in the organic shoals are generally fragmented, while weil-preserved girvanella and nuia siberica with a content of about 15% in the back-reef outer shoals are the most characteristic and different from others. The sinoceras, trilobites, and gastropods are well preserved in the upper slope deposits. The studies will demonstrate that the reef-shoal complexes developed above the base of the fair-weather wave base and that the original hydrodynamic conditions for the reef core forming is the stronger and become more and more low-energy from the inner part to outer part of the organic shoals.
基金the National Natural Sciences Foundation of China(grants40173025,49928201)Trans-century Training Program Foundation for the Talents by the Ministry of Education the Visiting Scholar Foundation of Labs in Universities.
文摘He-Ar isotopic compositions of fluid inclusions trapped in pyrites from some representative PGE-polymetallic deposits in Lower Cambrian black rock series in South China were analyzed by using an inert gas isotopic mass spectrometer. The results show that the ore-forming fluids possess a low 3He/4He ratio, varying from 0.43×10-8 to 26.39×10-8, with corresponding R/Ra value of 0.003-0.189. The 40Ar/36Ar ratios are 258-287, close to those of air saturated water (ASW). He-Ar isotopic indicator studies show that the ore-forming fluids were mainly derived from the formation water or basinal hot brine and sea water, while the content of mantle-derived fluid or deep-derived magmatic water might be negligible. The PGE-polymetallic mineralization might be related to the evolution of the Caledonian miogeosynclines distributed along the southern margin of the Yangtze Craton. During the Early Cambrian, the formation water or basinal hot brine trapped in Caledonian basins which accumulated giant thick sediments was expelled and migrated laterally along strata because of the pressure generated by overlying sediments. The basinal hot brine ascended along faults, mixed with sea water and finally deposited ore minerals.
基金supported by several grantsfrom DAAD,DFG(Wo 489/15-1,15-2KL 692/11-1,11-2)+1 种基金NSERC,NHM CERCAMS,IGCP(IGCP-473)the IGCP project 592 sponsored by IUGS and UNESCO
文摘The Muruntau gold deposit in the Central Kyzylkum,Uzbekistan is one of the largest single gold deposits worldwide.Data available from the literature are reviewed with the aim to（1） integrate the present knowledge on this unique deposit from Russian and English literature;（2） show the considerable progress made in the understanding of the genesis of the Muruntau deposit during the last decades;and（3） point to problems still open for future research.Deposit formation occurred through a multi-stage process involving sedimentation,regional metamorphism including thrusting,magmatism with formation of hornfels aureoles and several stages of hydrothermal activity.According to recent knowledge,synsedimentary or pure metamorphic formation of gold mineralization seems unlikely.The role of granite magmatism occurring roughly within the same time interval as the main hydrothermal gold precipitation remains uncertain.There are no signs of interaction of matter between the magma（s） and the hydrothermal system（s）.On the other hand,there was an intense,high-temperature（above 400 ℃）fluid- wall rock interaction resulting in the formation of gold-bearing,cone-like stockworks with veins,veinlets and gold-bearing metasomatites.Several chemical and isotope indicators hint at an involvement of lower-crustal or mantle-related sources as well as of surface waters in ore formation.Deposit formation through brecciation involving explosion,hydrothermal or tectonic breccias might explain these data.Further investigations on breccia formation as well as on the exact timing of relevant sedimentary,metamorphic,magmatic and hydrothermal events are recommended.
基金funded by the One-hundred Talents Program of CAS,the Special Fund for Agricultural Profession (200803030)the Sino-German project (DFG Training Group,GK1070)
文摘As an example of atmospheric nitrogen(N) deposition,the paper summarizes the definition,form and amount of nutrient from the environment(NFE) and the relationship between NFE and anthro-pogenic reactive N emission.Based on our own study and published articles,we find that N wet and dry deposition has been an important nutrient resource in agricultural and natural ecosystems in China.The total amount of N deposition and other environment-derived N in China was up to 18 Tg N/a,equal to ap-proximately 60% of the national N fertilizer consumption.Nitrogen deposition is expected to contribute substantially to nutrient cycling and net primary productivity in various ecosystems.Therefore,it is crucial to utilize this environment-derived nutrient resource by integrated nutrient resource management in order to realize the sustainable development of both agricultural and non-agricultural ecosystems.
基金supported by the National Natural Science Foundation of China (No. 41322013)the Program for New Century Excellent Talents in Universities (No. NCET-110723)+2 种基金the National Key Basic Research Development Program of China (No. 2012CB822003)the Programme of Introducing Talents of Discipline to Universities (No. B14031)the Fundamental Research Funds for the Central Universities, China University of Geosciences (Wuhan) (No. CUG110611)
文摘The Upper Eocene–Lower Oligocene Qianjiang Formation of the Jianghan Basin in central China consists of a 4700-m-thick lacustrine succession, containing 1800 m of halite deposits. The maximum thickness of the formation is 4700 m, and includes 1800 m of halite. We have identified eight third-order depositional sequences based on pinch-out and onlap stratigraphic patterns in 2-D and 3-D seismic data and well logs. The basin evolved from a deep to shallow under-filled lake during the Eocene–Oligocene interval. The main rock types are dark mudstones, halite, and siltstone/sandstone in the depocenter, and alternating mudstone and gypsum in shallower areas. The vertical succession indicates a strong sedimentary cyclicity. Depositional facies indicate the presence of two lake system types. Halite developed in a saline lake system, whereas clastic sediments were deposited in freshwater lake systems. The alternating sediment types indicate that the basin cycled repeatedly between saline and freshwater lake systems. This cyclicity was caused by availability of accommodation space that was controlled by a combination of climate change, tectonic subsidence and sediment supply; notably, the highest frequency cycles occurred at Milankovitch timescales controlled by the Earth＇s orbital variations. The cyclic halite plays an important role in generating and preserving oil in the Qianjiang Formation of the Qianjiang depression.
基金the National Natural Science Foundation of China(No.51874361)the National Natural Science Foundation of China Youth Fund(51904343)for supporting this work.
文摘In this study,commercial copper(Cu)foil and Cu foam are used as the working electrodes to systematically investigate the electrochemical deposition and dissolution processes of metallic lithium(Li)on these electrodes;Li metal deposited on the Cu foil electrode is porous and loose.The surface solid electrolyte interface(SEI)film after dissolution from Li dendrites maintains a dendritic porous structure,resulting in a large volume effect of the electrode during the cycle.The Cu foam electrode provides preferential nucleation and deposition sites near the side surface of the separator;the difference in Li affinity results in a heterogeneous deposition and dendrite growth of metallic Li.
基金supported by the Foundation for Development of Geological Science and Technology of the former Ministry of Geology and Mineral Resources of China grant HY979830
文摘In the early Proterozoic the Li'eryu Formation and Dashiqiao Formation of eastern Liaoning province, China, there are distributed Mg-rich carbonate rock formations, in which large to superlarge deposits of boron, magnesite, talc, Xiuyan jade etc. occur. The formation of these magnesian nonmetallic deposits was related to early Proterozoic evaporates; then these deposits underwent reworking of regional metamorphism and hydrothermal metasomatism during the Lüliang orogeny and tectono-magmatism during the Indosinian-Yanshanian. Among other things, the Mg-rich carbonates formations, minerogenetic structures and ore-forming fluids played a controlling role in the formation of the mineral deposits. Therefore, it can be concluded that the mineral deposits are products of combined processes of the coupling of ore source field, fluid field, thermal field (energy field) and stress field under certain time-space conditions in the early Proterozoic and the late-stage superimposed reworking of tectono-magmatism.
基金Under the auspices of Major State Basic Research Development Program of China(No.2010CB833504)Strategic Priority Research Program of Chinese Academy of Sciences(No.XDA05050601)
文摘A continuous three-year observation(from May 2008 to April 2011)was conducted to characterize the spatial variation of dissolved inorganic nitrogen(DIN)deposition at eight main forest ecosystems along the north-south transect of eastern China(NSTEC).The results show that both throughfall DIN deposition and bulk DIN deposition increase from north to south along the NSTEC.Throughfall DIN deposition varies greatly from 2.7 kg N/(ha·yr)to 33.0 kg N/(ha·yr),with an average of 10.6 kg N/(ha·yr),and bulk DIN deposition ranges from 4.1 kg N/(ha·yr)to 25.4 kg N/(ha·yr),with an average of 9.8 kg N/(ha·yr).NH4+-N is the dominant form of DIN deposition at most sampling sites.Additionally,the spatial variation of DIN deposition is controlled mainly by precipitation.Moreover,in the northern part of the NSTEC,bulk DIN deposition is 17%higher than throughfall DIN deposition,whereas the trend is opposite in the southern part of the NSTEC.The results demonstrate that DIN deposition would likely threaten the forest ecosystems along the NSTEC,compared with the critical loads(CL)of N deposition,and DIN deposition in this region is mostly controlled by agricultural activities rather than industrial activities or transportation.
基金granted by the National Science and Technology Major Project(2011ZX05004-001)
文摘Using analyses of the lithology,sequences,paleoenvironment,and tectonic setting,the depositional system of the Carboniferous Huanglong Formation in the eastern Sichuan Basin was identified.The lithological characteristics of the Lower Member,Middle Member,and Upper Member were analyzed and classified.Before the use of carbon,oxygen,and strontium isotopes in the analysis,all of the geochemical data were tested for validity.On the basis of the Z values obtained from carbon and oxygen isotopes,the paleoenvironments of the three members were elucidated.Lower Member was dominantly an enclosed marine environment with intense evaporation and little freshwater input into the sea.Middle Member developed in a semi-enclosed to normal marine environment with many rivers.Upper Member was formed in a normal marine environment.The east Sichuan Basin was enclosed by paleouplifts before the deposition of the Huanglong Formation,forming a relatively enclosed depositional setting.Paleogullies developed in the Silurian strata that underlie the Carboniferous rocks;these paleogullies can be identified.On the basis of a comprehensive analysis,we propose that the Huanglong Formation developed in a platform system.Four microfacies were identified：supratidal flat,dolostone flat,grain shoal,and shelf microfacies.The high-permeability and high-porosity characteristics of the grain shoal microfacies are favorable for hydrocarbon accumulation,while the supratidal flat and shelf microfacies developed very few high-quality reservoirs.The paleogullies,in which increased amounts of grain shoal microfacies developed,controlled the distribution of high-quality reservoirs.
