Understanding the temperature dependent deformation behavior of Mg alloys is crucial for their expanding use in the aerospace sector.This study investigates the deformation mechanisms of hot-rolled AZ61 Mg alloy under...Understanding the temperature dependent deformation behavior of Mg alloys is crucial for their expanding use in the aerospace sector.This study investigates the deformation mechanisms of hot-rolled AZ61 Mg alloy under uniaxial tension along rolling direction(RD)and transverse direction(TD)at-50,25,50,and 150℃.Results reveal a transition from high strength with limited elongation at-50℃ to significant softening and maximum ductility at 150℃.TD samples consistently showed 2%-6%higher strength than RD;however,this yield anisotropy diminished at 150℃ due to the shift from twinning to thermally activated slip and recovery.Fractography indicated a change from semi-brittle to fully ductile fracture with increasing temperature.Electron backscattered diffraction(EBSD)analysis confirmed twinning-driven grain refinement at low temperatures,while deformation at high temperatures involved grain elongation along shear zones,enabling greater strain accommodation before material failure.展开更多
Tellurene,a chiral chain semiconductor with a narrow bandgap and exceptional strain sensitivity,emerges as a pivotal material for tailoring electronic and optoelectronic properties via strain engineering.This study el...Tellurene,a chiral chain semiconductor with a narrow bandgap and exceptional strain sensitivity,emerges as a pivotal material for tailoring electronic and optoelectronic properties via strain engineering.This study elucidates the fundamental mechanisms of ultrafast laser shock imprinting(LSI)in two-dimensional tellurium(Te),establishing a direct relationship between strain field orientation,mold topology,and anisotropic structural evolution.This is the first demonstration of ultrafast LSI on chiral chain Te unveiling orientation-sensitive dislocation networks.By applying controlled strain fields parallel or transverse to Te’s helical chains,we uncover two distinct deformation regimes.Strain aligned parallel to the chain’s direction induces gliding and rotation governed by weak interchain interactions,preserving covalent intrachain bonds and vibrational modes.In contrast,transverse strain drives shear-mediated multimodal deformations—tensile stretching,compression,and bending—resulting in significant lattice distortions and electronic property modulation.We discovered the critical role of mold topology on deformation:sharp-edged gratings generate localized shear forces surpassing those from homogeneous strain fields via smooth CD molds,triggering dislocation tangle formation,lattice reorientation,and inhomogeneous plastic deformation.Asymmetrical strain configurations enable localized structural transformations while retaining single-crystal integrity in adjacent regions—a balance essential for functional device integration.These insights position LSI as a precision tool for nanoscale strain engineering,capable of sculpting 2D material morphologies without compromising crystallinity.By bridging ultrafast mechanics with chiral chain material science,this work advances the design of strain-tunable devices for next-generation electronics and optoelectronics,while establishing a universal framework for manipulating anisotropic 2D systems under extreme strain rates.This work discovered crystallographic orientation-dependent deformation mechanisms in 2D Te,linking parallel strain to chain gliding and transverse strain to shear-driven multimodal distortion.It demonstrates mold geometry as a critical lever for strain localization and dislocation dynamics,with sharp-edged gratings enabling unprecedented control over lattice reorientation.Crucially,the identification of strain field conditions that reconcile severe plastic deformation with single-crystal retention offers a pathway to functional nanostructure fabrication,redefining LSI’s potential in ultrafast strain engineering of chiral chain materials.展开更多
Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The t...Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The traditional thermal elastic-plastic finite element method(TEP-FEM)can accurately predict welding deformation.However,its efficiency is low because of the complex nonlinear transient computation,making it difficult to meet the needs of rapid engineering evaluation.To address this challenge,this study proposes an efficient prediction method for welding deformation in marine thin plate butt welds.This method is based on the coupled temperature gradient-thermal strain method(TG-TSM)that integrates inherent strain theory with a shell element finite element model.The proposed method first extracts the distribution pattern and characteristic value of welding-induced inherent strain through TEP-FEM analysis.This strain is then converted into the equivalent thermal load applied to the shell element model for rapid computation.The proposed method-particularly,the gradual temperature gradient-thermal strain method(GTG-TSM)-achieved improved computational efficiency and consistent precision.Furthermore,the proposed method required much less computation time than the traditional TEP-FEM.Thus,this study lays the foundation for future prediction of welding deformation in more complex marine thin plates.展开更多
The recently established theory has built clear connections between hardness and toughness and electron structure involving both valence electron concentration(VEC)and core electron count(CEC)in transition metal nitri...The recently established theory has built clear connections between hardness and toughness and electron structure involving both valence electron concentration(VEC)and core electron count(CEC)in transition metal nitride(TMN)ceramics.However,the underlying deformation mechanisms remain unclear.Herein,we conduct in-depth analysis on microstructure evolution during deformation of the high VEC-CEC solution TiMoN coatings having desired combination of high hardness and toughness.The effects of solid solution,preferred orientation linked with symbiotic compressive stress,grain size and dislocations are systematically discussed.We discover that numerous dislocations have been implanted into the nanocrystals of the TiMoN coating during the high-ionization arc deposition.Using two-beam bright-field imaging,we count the dislocation density and confirm occurrence of dislocation multiplication to form effective plastic deformation,which contributes to significant strain hardening,comparable to solid solution hardening,fine-grain hardening and compressive stress hardening.The improved dislocation activities also play a crucial role in enhancing the toughness by providing extra energy dissipation paths.This work gains new insights into the origins of mechanical properties of ceramic coatings and possibility to tune them via defects.展开更多
The spherical Ti particle(Ti_(p))reinforced Mg-5Zn-0.5Ca(Ti_(p)/ZX50)composite was prepared via the semisolid stirring casting process and the effects of Ti_(p)on the hot deformation and hot processing behavior of mat...The spherical Ti particle(Ti_(p))reinforced Mg-5Zn-0.5Ca(Ti_(p)/ZX50)composite was prepared via the semisolid stirring casting process and the effects of Ti_(p)on the hot deformation and hot processing behavior of matrix alloy were investigated through uniaxial hot compression testing.The results indicate that a particle deformation zone(PDZ)forms around the Ti_(p)with the deformation of the Ti_(p)/ZX50 composite,which is propitious to the dynamic recrystallization(DRX)of the matrix alloy.The range of the PDZ and the promoting effect of the Ti_(p)on DRXed nucleation are inversely related to the deformation degree of the Ti_(p).Moreover,the deformation of Ti_(p)alleviates the high stress in the matrix alloy during deformation,expanding the processing range and reducing the average deformation activation energy of the matrix alloy.Notably,the minimum processing temperature(493 K)of the Ti_(p)/ZX50 composite is significantly lower than that of hardened particle reinforced magnesium matrix composites.The hot deformation mechanism of the Ti_(p)/ZX50 composite is dislocation climb controlled by both lattice diffusion and pipe diffusion.展开更多
How to achieve high-entropy alloys(HEAs)with ultrahigh strength and ductility is a challenging issue.Precipitation strengthening is one of the methods to significantly enhance strength,but unfortunately,ductility will...How to achieve high-entropy alloys(HEAs)with ultrahigh strength and ductility is a challenging issue.Precipitation strengthening is one of the methods to significantly enhance strength,but unfortunately,ductility will be lost.To overcome the strength-ductility trade-off,the strategy of this study is to induce the formation of high-density nanoprecipitates through dual aging(DA),triggering multiple deformation mechanisms,to obtain HEAs with ultrahigh strength and ductility.First,the effect of precold deformation on precipitation behavior was studied using Ni_(35)(CoFe)_(55)V_(5)Nb_(5)(at.%)HEAas the object.The results reveal that the activation energy of recrystallization is 112.2 kJ/mol.As the precold-deformation amount increases from 15%to 65%,the activation energy of precipitation gradually decreases from 178.8 to 159.7 kJ/mol.The precipitation time shortens,the size of the nanoprecipitate decreases,and the density increases.Subsequently,the thermal treatment parameters were optimized,and the DA process was customized based on the effect of precold deformation on precipitation behavior.High-density L1_(2) nanoprecipitates(~3.21×10^(25) m^(-3))were induced in the 65% precold-deformed HEA,which led to the simultaneous formation of twins and stacking fault(SF)networks during deformation.The yield strength(YS),ultimate tensile strength,and ductility of the DA-HEA are~2.0 GPa,~2.2 GPa,and~12.3%,respectively.Compared with the solid solution HEA,the YS of the DA-HEA increased by 1,657 MPa,possessing an astonishing increase of~440%.The high YS stems from the precipitation strengthening contributed by the L1_(2) nanoprecipitates and the dislocation strengthening contributed by precold deformation.The synergistically enhanced ductility stems from the high strain-hardening ability under the dual support of twinning-induced plasticity and SF-induced plasticity.展开更多
Deep excavations in silt strata can lead to large deformation problems,posing risks to both the excavation and adjacent structures.This study combines field monitoring with numerical simulation to investigate the unde...Deep excavations in silt strata can lead to large deformation problems,posing risks to both the excavation and adjacent structures.This study combines field monitoring with numerical simulation to investigate the underlying mechanisms and key aspects associated with large deformation problems induced by deep excavation in silt strata in Shenzhen,China.The monitoring results reveal that,due to the weak property and creep effect of the silt strata,the maximum wall deflection in the first excavated section(Section 1)exceeds its controlled value at more than 93%of measurement points,reaching a peak value of 137.46 mm.Notably,the deformation exhibits prolonged development characteristics,with the diaphragm wall deflections contributing to 39%of the overall deformation magnitude during the construction of the base slab.Subsequently,numerical simulations are carried out to analyze and assess the primary factors influencing excavation-induced deformations,following the observation of large deformations.The simulations indicate that the low strength of the silt soil is a pivotal factor that results in significant deformations.Furthermore,the flexural stiffness of the diaphragm walls exerts a notable influence on the development of deformations.To address these concerns,an optimization study of potential treatment measures was performed during the subsequent excavation of Section 2.The combined treatment approach,which comprises the reinforcement of the silt layer within the excavation and the increase in the thickness of the diaphragm walls,has been demonstrated to offer an economically superior solution for the handling of thick silt strata.This approach has the effect of reducing the lateral wall displacement by 83.1%and the ground settlement by 70.8%,thereby ensuring the safe construction of the deep excavation.展开更多
Birds have developed near-perfect structures and functionality over millions of years of natural evolution.To improve the efficiency of fixed-wing vehicles in different environments,researchers have developed deformab...Birds have developed near-perfect structures and functionality over millions of years of natural evolution.To improve the efficiency of fixed-wing vehicles in different environments,researchers have developed deformable wings inspired by the wing structures of birds.Shape Memory Alloy(SMA)is applied as a smart material to the deformable wing.Compared with other drive methods,SMA actuators have the advantages of high drive capacity and a simple structure for driving wing deformation.According to the shape memory effect,SMA actuators are classified as single-range and dual-range actuators.The wing structure designed for each SMA drive is unique.By comparing and analyzing the structures of airfoils,airfoils with similar drive forms and deformation structures are put together for review and discussion.The deformable wings are categorized into out-of-face deformation,in-face deformation,airfoil curvature deformation,and combined deformation with multiple degrees of freedom based on the structure and location of the wing that produces the deformation.An overview of the deformed wing is introduced by telling the bionic theory of seagulls.The principles of deformation of the wing,the mechanics of the SMA actuator mechanism,and the aerodynamic characteristics of the deformable wing are presented.The structure and working principle of SMA actuators for each type of deformable wing are explained in detail.Methods and approaches to study the deformability of deformable wings are analyzed and summarized.This work provides comprehensive insights and perspectives for future studies of SMA-driven deformable airfoils.展开更多
Current hyperelastic constitutive models of hydrogels face difficulties in capturing the stress-strain behaviors of hydrogels under extremely large deformation because the effect of non-affine deformation of the polym...Current hyperelastic constitutive models of hydrogels face difficulties in capturing the stress-strain behaviors of hydrogels under extremely large deformation because the effect of non-affine deformation of the polymer network inside is ambiguous.In this work,we construct periodic random network(PRN)models for the effective polymer network in hydrogels and investigate the non-affine deformation of polymer chains intrinsically originates from the structural randomness from bottom up.The non-affine deformation in PRN models is manifested as the actual stretch of polymer chains randomly deviated from the chain stretch predicted by affine assumption,and quantified by a non-affine ratio of each polymer chain.It is found that the non-affine ratios of polymer chains are closely related to bulk deformation state,chain orientation,and initial chain elongation.By fitting the non-affine ratio of polymer chains in all PRN models,we propose a non-affine constitutive model for the hydrogel polymer network based on micro-sphere model.The stress-strain curves of the proposed constitutive models under uniaxial tension condition agree with the simulation results of different PRN models of hydrogels very well.展开更多
Almost all solid surfaces are rough.The randomness and complexity of roughness make the behavior of contact deformation,electrical conductivity,and heat transfer between solids elusive.If the solids are subjected to f...Almost all solid surfaces are rough.The randomness and complexity of roughness make the behavior of contact deformation,electrical conductivity,and heat transfer between solids elusive.If the solids are subjected to further tensile,bending,or torsional deformation,will more complex or new contact phenomena occur?Clarifying this issue is of great significance to developing and designing some major equipment serving in extreme environments.展开更多
Multi-pass hot processing methods are commonly used in magnesium(Mg)alloys to overcome the poor workability due to limited slip systems,which generally involve complicated post-deformation softening and hardening beha...Multi-pass hot processing methods are commonly used in magnesium(Mg)alloys to overcome the poor workability due to limited slip systems,which generally involve complicated post-deformation softening and hardening behaviors.In this work,to reveal post-deformation softening and hardening mechanisms of a Mg-2Y-1Zn alloy,double-stage hot compression tests and microstructural observations were conducted.The results showed that the softening fraction of Mg-2Y-1Zn alloy showed a non-linear dependence on deformation conditions and could be general coupled by Z parameter.Due to the formation and cross-overlapping of twins and kinks,only static recovery(SRV)occurred during holding process at 300℃/0.001 s^(-1) which led to the least static softening:5.52% after 10 s of holding.For samples at 400℃/0.001s^(-1),the enhanced post-deformation softening,which is 11.93% after 10 s of holding,was attributed to static recrystallization(SRX)followed continuous dynamic recrystallization(CDRX)happened during first deformation stage as well as SRV influenced by the LPSO phases.Under deformation condition of 400℃/0.1 s^(-1),the coupled meta-dynamic recrystallization(MDRX)and SRX resulted in serious stress relaxation,which is 42.83% after 10 s of holding,and caused hardening phenomenon at reloading stage.The 18R-LPSO and 14H-LPSO phases synchronously worked on deformation behaviors and limited the growth of recrystallized grains.Further,a simplified static softening kinetics model was established based on Johnson-Mehl-Avrami-Kolmogorov equation and employed to rationalize experimental data.展开更多
304H austenitic stainless steel wire was investigated,emphasizing microstructural deformation,martensite phase transformation,and residual magnetic properties during drawing.Utilizing several microstructural observati...304H austenitic stainless steel wire was investigated,emphasizing microstructural deformation,martensite phase transformation,and residual magnetic properties during drawing.Utilizing several microstructural observation techniques,the volume fraction of martensite,modes of grain deformation in distinct regions,and the phase relationship between austenite and martensite were comprehensively characterized.In addition,a finite element simulation with representative volume elements specific to different zones also offers insights into strain responses during the drawing process.Results from the first-pass drawing reveal that there exists a higher volume fraction of martensite in the central region of 304H austenitic stainless steel wire compared to edge areas.This discrepancy is attributed to a concentrated presence of shear slip system{111}<110>γcrystallographic orientation,primarily accumulating in the central region obeying the Kurdjumov-Sachs path.Subsequent to the second drawing pass,the cumulative shear deformation within distinct regions of the steel wire became more pronounced.This resulted in a progressive augmentation of the volume fraction of martensite in both the central and peripheral regions of the steel wire.Concurrently,this led to a discernible elevation in the overall residual magnetism of the steel wire.展开更多
Heterogeneous structure exhibits superiority in improving mechanical properties,whereas their effects on fatigue damage properties have rarely been studied.In this work,we employed a high-throughput gradient heat trea...Heterogeneous structure exhibits superiority in improving mechanical properties,whereas their effects on fatigue damage properties have rarely been studied.In this work,we employed a high-throughput gradient heat treatment method(757−857℃)to rapidly acquire the solution microstructure of the Ti-6554 alloy with different recrystallization degrees(0%,40%and 100%),followed by the same aging treatment.The results showed that theβ-hetero structure exhibited a yield strength(σ_(YS))of 1403 MPa,an increase of 6.7%,and a remarkable improvement in uniform elongation(UE)of 109.7%,reaching 6.5%,compared to the homogeneous structure.Interestingly,introducing a heterogeneous structure not only overcame the traditional trade-off between strength and ductility but also enhanced fatigue crack propagation(FCP)performance.During FCP process,β-hetero structure,through hetero-deformation induced(HDI)strengthening effects,promoted the accumulation of geometric necessary dislocations(GNDs)within coarseα_(S) phase,enabling faster attainment of the critical shear stress of twinning and increasing twinning density.This facilitated stress relief,improved plastic deformation in the crack tip zone,and increased the critical fast fracture threshold from 30.4 to 36.0 MPa·m^(1/2)showing an enlarged steady state propagation region.This study provides valuable insights on tailoring fatigue damage tolerance through heterogeneous structure for titanium alloys.展开更多
Theβsolidifiedγ-TiAl alloy holds important application value in the aerospace industry,while its com-plex phase compositions and geometric structures pose challenges to its microstructure control during the thermal-...Theβsolidifiedγ-TiAl alloy holds important application value in the aerospace industry,while its com-plex phase compositions and geometric structures pose challenges to its microstructure control during the thermal-mechanical process.The microstructure evolution of Ti-43Al-4Nb-1Mo-0.2B alloy at 1200℃/0.01 s−1 was investigated to clarify the coupling role of dynamic recrystallization(DRX)and phase transformation.The results revealed that the rate of DRX inα2+γlamellar colonies was comparatively slower than that inβo+γmixed structure,instead being accompanied by intense lamellar kinking and rotation.The initiation and development rates of DRX inα2,βo,andγphases decreased sequentially.The asynchronous DRX of the various geometric structures and phase compositions resulted in the un-even deformed microstructure,and the dynamic softening induced by lamellar kinking and rotation was replaced by strengthened DRX as strain increased.Additionally,the blockyα2 phase and the terminals ofα2 lamellae were the preferential DRX sites owing to the abundant activated slip systems.Theα2→βo transformation within lamellar colonies facilitated DRX and fragment ofα2 lamellae,while theα2→γtransformation promoted the decomposition ofα2 lamellae and DRX ofγlamellae.Moreover,the var-iedβo+γmixed structures underwent complicated evolution:(1)Theγ→βo transformation occurred at boundaries of lamellar colonies,followed by simultaneous DRX ofγlamellar terminals and neighboringβo phase;(2)DRX occurred earlier within the band-likeβo phase,with the delayed DRX in enclosedγphase;(3)DRX within theβo synapses and neighboringγphase was accelerated owing to generation of elastic stress field;(4)Dispersedβo particles triggered particle stimulated nucleation(PSN)ofγphase.Eventually,atomic diffusion along crystal defects inβo andγphases caused fracture of band-likeβo phase and formation of massiveβo particles,impeding grain boundary migration and hindering DRXed grain growth ofγphase.展开更多
基金supported by the Korea Institute of Energy Technology Evaluation and Planning(KETEP)the Ministry of Trade,Industry&Energy(MOTIE)of the Republic of Korea Program(No.RS-2025-02603127,Innovation Research Center for Zero-carbon Fuel Gas Turbine Design,Manufacture,and Safety)。
文摘Understanding the temperature dependent deformation behavior of Mg alloys is crucial for their expanding use in the aerospace sector.This study investigates the deformation mechanisms of hot-rolled AZ61 Mg alloy under uniaxial tension along rolling direction(RD)and transverse direction(TD)at-50,25,50,and 150℃.Results reveal a transition from high strength with limited elongation at-50℃ to significant softening and maximum ductility at 150℃.TD samples consistently showed 2%-6%higher strength than RD;however,this yield anisotropy diminished at 150℃ due to the shift from twinning to thermally activated slip and recovery.Fractography indicated a change from semi-brittle to fully ductile fracture with increasing temperature.Electron backscattered diffraction(EBSD)analysis confirmed twinning-driven grain refinement at low temperatures,while deformation at high temperatures involved grain elongation along shear zones,enabling greater strain accommodation before material failure.
基金financial support from NSF ExpandQISE program.The synthesis of tellurene was supported by NSF under grant no.CMMI-2046936supports from Purdue Research Foundation.
文摘Tellurene,a chiral chain semiconductor with a narrow bandgap and exceptional strain sensitivity,emerges as a pivotal material for tailoring electronic and optoelectronic properties via strain engineering.This study elucidates the fundamental mechanisms of ultrafast laser shock imprinting(LSI)in two-dimensional tellurium(Te),establishing a direct relationship between strain field orientation,mold topology,and anisotropic structural evolution.This is the first demonstration of ultrafast LSI on chiral chain Te unveiling orientation-sensitive dislocation networks.By applying controlled strain fields parallel or transverse to Te’s helical chains,we uncover two distinct deformation regimes.Strain aligned parallel to the chain’s direction induces gliding and rotation governed by weak interchain interactions,preserving covalent intrachain bonds and vibrational modes.In contrast,transverse strain drives shear-mediated multimodal deformations—tensile stretching,compression,and bending—resulting in significant lattice distortions and electronic property modulation.We discovered the critical role of mold topology on deformation:sharp-edged gratings generate localized shear forces surpassing those from homogeneous strain fields via smooth CD molds,triggering dislocation tangle formation,lattice reorientation,and inhomogeneous plastic deformation.Asymmetrical strain configurations enable localized structural transformations while retaining single-crystal integrity in adjacent regions—a balance essential for functional device integration.These insights position LSI as a precision tool for nanoscale strain engineering,capable of sculpting 2D material morphologies without compromising crystallinity.By bridging ultrafast mechanics with chiral chain material science,this work advances the design of strain-tunable devices for next-generation electronics and optoelectronics,while establishing a universal framework for manipulating anisotropic 2D systems under extreme strain rates.This work discovered crystallographic orientation-dependent deformation mechanisms in 2D Te,linking parallel strain to chain gliding and transverse strain to shear-driven multimodal distortion.It demonstrates mold geometry as a critical lever for strain localization and dislocation dynamics,with sharp-edged gratings enabling unprecedented control over lattice reorientation.Crucially,the identification of strain field conditions that reconcile severe plastic deformation with single-crystal retention offers a pathway to functional nanostructure fabrication,redefining LSI’s potential in ultrafast strain engineering of chiral chain materials.
基金Supported by the National Natural Science Foundation of China under Grant No.51975138the High-Tech Ship Scientific Research Project from the Ministry of Industry and Information Technology under Grant No.CJ05N20the National Defense Basic Research Project under Grant No.JCKY2023604C006.
文摘Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The traditional thermal elastic-plastic finite element method(TEP-FEM)can accurately predict welding deformation.However,its efficiency is low because of the complex nonlinear transient computation,making it difficult to meet the needs of rapid engineering evaluation.To address this challenge,this study proposes an efficient prediction method for welding deformation in marine thin plate butt welds.This method is based on the coupled temperature gradient-thermal strain method(TG-TSM)that integrates inherent strain theory with a shell element finite element model.The proposed method first extracts the distribution pattern and characteristic value of welding-induced inherent strain through TEP-FEM analysis.This strain is then converted into the equivalent thermal load applied to the shell element model for rapid computation.The proposed method-particularly,the gradual temperature gradient-thermal strain method(GTG-TSM)-achieved improved computational efficiency and consistent precision.Furthermore,the proposed method required much less computation time than the traditional TEP-FEM.Thus,this study lays the foundation for future prediction of welding deformation in more complex marine thin plates.
基金supported by the Distinguished Young Scholars of China(No.52025014)Natural Science Foundation of Zhejiang Province(No.LQ23E010002)Innovation 2025 Major Project of Ningbo(Nos.2022Z011 and 2023Z022).
文摘The recently established theory has built clear connections between hardness and toughness and electron structure involving both valence electron concentration(VEC)and core electron count(CEC)in transition metal nitride(TMN)ceramics.However,the underlying deformation mechanisms remain unclear.Herein,we conduct in-depth analysis on microstructure evolution during deformation of the high VEC-CEC solution TiMoN coatings having desired combination of high hardness and toughness.The effects of solid solution,preferred orientation linked with symbiotic compressive stress,grain size and dislocations are systematically discussed.We discover that numerous dislocations have been implanted into the nanocrystals of the TiMoN coating during the high-ionization arc deposition.Using two-beam bright-field imaging,we count the dislocation density and confirm occurrence of dislocation multiplication to form effective plastic deformation,which contributes to significant strain hardening,comparable to solid solution hardening,fine-grain hardening and compressive stress hardening.The improved dislocation activities also play a crucial role in enhancing the toughness by providing extra energy dissipation paths.This work gains new insights into the origins of mechanical properties of ceramic coatings and possibility to tune them via defects.
基金supported by the National Natural Science Foundation of China(Nos.52271109 and 52401162)Natural Science Foundation of Shanxi(Nos.202403021211064 and 202403011212003)the Major Special Plan for Science and Technology in Shanxi Province(No.202201050201012).
文摘The spherical Ti particle(Ti_(p))reinforced Mg-5Zn-0.5Ca(Ti_(p)/ZX50)composite was prepared via the semisolid stirring casting process and the effects of Ti_(p)on the hot deformation and hot processing behavior of matrix alloy were investigated through uniaxial hot compression testing.The results indicate that a particle deformation zone(PDZ)forms around the Ti_(p)with the deformation of the Ti_(p)/ZX50 composite,which is propitious to the dynamic recrystallization(DRX)of the matrix alloy.The range of the PDZ and the promoting effect of the Ti_(p)on DRXed nucleation are inversely related to the deformation degree of the Ti_(p).Moreover,the deformation of Ti_(p)alleviates the high stress in the matrix alloy during deformation,expanding the processing range and reducing the average deformation activation energy of the matrix alloy.Notably,the minimum processing temperature(493 K)of the Ti_(p)/ZX50 composite is significantly lower than that of hardened particle reinforced magnesium matrix composites.The hot deformation mechanism of the Ti_(p)/ZX50 composite is dislocation climb controlled by both lattice diffusion and pipe diffusion.
基金supported by the National Key Research and Development Project(No.2023YFA1600082)the National Natural Science Foundation of China(Nos.U2141207,52001083,52171111)+3 种基金Natural Science Foundation of Heilongjiang(No.YQ2023E026)the Fundamental Research Funds for the Central Universities(No.3072022JIP1002)Key Laboratory Found of the Ministry of Industry and Information Technology(No.GXB202201)Youth Talent Project of China National Nuclear Corporation(No.CNNC2021YTEP-HEU01).
文摘How to achieve high-entropy alloys(HEAs)with ultrahigh strength and ductility is a challenging issue.Precipitation strengthening is one of the methods to significantly enhance strength,but unfortunately,ductility will be lost.To overcome the strength-ductility trade-off,the strategy of this study is to induce the formation of high-density nanoprecipitates through dual aging(DA),triggering multiple deformation mechanisms,to obtain HEAs with ultrahigh strength and ductility.First,the effect of precold deformation on precipitation behavior was studied using Ni_(35)(CoFe)_(55)V_(5)Nb_(5)(at.%)HEAas the object.The results reveal that the activation energy of recrystallization is 112.2 kJ/mol.As the precold-deformation amount increases from 15%to 65%,the activation energy of precipitation gradually decreases from 178.8 to 159.7 kJ/mol.The precipitation time shortens,the size of the nanoprecipitate decreases,and the density increases.Subsequently,the thermal treatment parameters were optimized,and the DA process was customized based on the effect of precold deformation on precipitation behavior.High-density L1_(2) nanoprecipitates(~3.21×10^(25) m^(-3))were induced in the 65% precold-deformed HEA,which led to the simultaneous formation of twins and stacking fault(SF)networks during deformation.The yield strength(YS),ultimate tensile strength,and ductility of the DA-HEA are~2.0 GPa,~2.2 GPa,and~12.3%,respectively.Compared with the solid solution HEA,the YS of the DA-HEA increased by 1,657 MPa,possessing an astonishing increase of~440%.The high YS stems from the precipitation strengthening contributed by the L1_(2) nanoprecipitates and the dislocation strengthening contributed by precold deformation.The synergistically enhanced ductility stems from the high strain-hardening ability under the dual support of twinning-induced plasticity and SF-induced plasticity.
基金supported by the National Natural Science Foundation of China (Grant Nos.52008039 and 52308425)the Natural Science Foundation of Hunan Province (Grant No.2021JJ40592).
文摘Deep excavations in silt strata can lead to large deformation problems,posing risks to both the excavation and adjacent structures.This study combines field monitoring with numerical simulation to investigate the underlying mechanisms and key aspects associated with large deformation problems induced by deep excavation in silt strata in Shenzhen,China.The monitoring results reveal that,due to the weak property and creep effect of the silt strata,the maximum wall deflection in the first excavated section(Section 1)exceeds its controlled value at more than 93%of measurement points,reaching a peak value of 137.46 mm.Notably,the deformation exhibits prolonged development characteristics,with the diaphragm wall deflections contributing to 39%of the overall deformation magnitude during the construction of the base slab.Subsequently,numerical simulations are carried out to analyze and assess the primary factors influencing excavation-induced deformations,following the observation of large deformations.The simulations indicate that the low strength of the silt soil is a pivotal factor that results in significant deformations.Furthermore,the flexural stiffness of the diaphragm walls exerts a notable influence on the development of deformations.To address these concerns,an optimization study of potential treatment measures was performed during the subsequent excavation of Section 2.The combined treatment approach,which comprises the reinforcement of the silt layer within the excavation and the increase in the thickness of the diaphragm walls,has been demonstrated to offer an economically superior solution for the handling of thick silt strata.This approach has the effect of reducing the lateral wall displacement by 83.1%and the ground settlement by 70.8%,thereby ensuring the safe construction of the deep excavation.
基金supported by the National Science Fund for Distinguished Young Scholars(No.52025053)National Natural Science Foundation of China(No.52305302)+1 种基金the Natural Science Foundation of Jilin Province(No.20220101216JC)the asterisk indicates the corresponding authors.
文摘Birds have developed near-perfect structures and functionality over millions of years of natural evolution.To improve the efficiency of fixed-wing vehicles in different environments,researchers have developed deformable wings inspired by the wing structures of birds.Shape Memory Alloy(SMA)is applied as a smart material to the deformable wing.Compared with other drive methods,SMA actuators have the advantages of high drive capacity and a simple structure for driving wing deformation.According to the shape memory effect,SMA actuators are classified as single-range and dual-range actuators.The wing structure designed for each SMA drive is unique.By comparing and analyzing the structures of airfoils,airfoils with similar drive forms and deformation structures are put together for review and discussion.The deformable wings are categorized into out-of-face deformation,in-face deformation,airfoil curvature deformation,and combined deformation with multiple degrees of freedom based on the structure and location of the wing that produces the deformation.An overview of the deformed wing is introduced by telling the bionic theory of seagulls.The principles of deformation of the wing,the mechanics of the SMA actuator mechanism,and the aerodynamic characteristics of the deformable wing are presented.The structure and working principle of SMA actuators for each type of deformable wing are explained in detail.Methods and approaches to study the deformability of deformable wings are analyzed and summarized.This work provides comprehensive insights and perspectives for future studies of SMA-driven deformable airfoils.
基金supported by the National Natural Science Foundation of China(Grant Nos.12202339 and 12172273)Xi’an Jiaotong University Tang Scholar.
文摘Current hyperelastic constitutive models of hydrogels face difficulties in capturing the stress-strain behaviors of hydrogels under extremely large deformation because the effect of non-affine deformation of the polymer network inside is ambiguous.In this work,we construct periodic random network(PRN)models for the effective polymer network in hydrogels and investigate the non-affine deformation of polymer chains intrinsically originates from the structural randomness from bottom up.The non-affine deformation in PRN models is manifested as the actual stretch of polymer chains randomly deviated from the chain stretch predicted by affine assumption,and quantified by a non-affine ratio of each polymer chain.It is found that the non-affine ratios of polymer chains are closely related to bulk deformation state,chain orientation,and initial chain elongation.By fitting the non-affine ratio of polymer chains in all PRN models,we propose a non-affine constitutive model for the hydrogel polymer network based on micro-sphere model.The stress-strain curves of the proposed constitutive models under uniaxial tension condition agree with the simulation results of different PRN models of hydrogels very well.
文摘Almost all solid surfaces are rough.The randomness and complexity of roughness make the behavior of contact deformation,electrical conductivity,and heat transfer between solids elusive.If the solids are subjected to further tensile,bending,or torsional deformation,will more complex or new contact phenomena occur?Clarifying this issue is of great significance to developing and designing some major equipment serving in extreme environments.
基金supported by the National Natural Science Foundation of China(52174361,52074114)Science and Technology Innovation Program of Hunan Province(2023RC3106)+2 种基金Open Fund of the China Spallation Neutron Source Songshan Lake Science City(KFKT2023B13)Graduate Training and Innovation Practice Base of Hunan Province,China Scholarship Council(202106130051)Postgraduate Scientific Research Innovation Project of Hunan Province(QL20220100,QL20230094).
文摘Multi-pass hot processing methods are commonly used in magnesium(Mg)alloys to overcome the poor workability due to limited slip systems,which generally involve complicated post-deformation softening and hardening behaviors.In this work,to reveal post-deformation softening and hardening mechanisms of a Mg-2Y-1Zn alloy,double-stage hot compression tests and microstructural observations were conducted.The results showed that the softening fraction of Mg-2Y-1Zn alloy showed a non-linear dependence on deformation conditions and could be general coupled by Z parameter.Due to the formation and cross-overlapping of twins and kinks,only static recovery(SRV)occurred during holding process at 300℃/0.001 s^(-1) which led to the least static softening:5.52% after 10 s of holding.For samples at 400℃/0.001s^(-1),the enhanced post-deformation softening,which is 11.93% after 10 s of holding,was attributed to static recrystallization(SRX)followed continuous dynamic recrystallization(CDRX)happened during first deformation stage as well as SRV influenced by the LPSO phases.Under deformation condition of 400℃/0.1 s^(-1),the coupled meta-dynamic recrystallization(MDRX)and SRX resulted in serious stress relaxation,which is 42.83% after 10 s of holding,and caused hardening phenomenon at reloading stage.The 18R-LPSO and 14H-LPSO phases synchronously worked on deformation behaviors and limited the growth of recrystallized grains.Further,a simplified static softening kinetics model was established based on Johnson-Mehl-Avrami-Kolmogorov equation and employed to rationalize experimental data.
基金funded by National Natural Science Foundation of China(52201084 and 52231003)Major Program(JD)of Hubei Province(2023BAA019)+2 种基金China Scholarship Council(CSC)Postdoctoral Station of metallurgical Engineering of Wuhan University of Science and Technology(WUST)Postdoctoral workstation of Zhejiang Jincheng New Material Co.,Ltd.
文摘304H austenitic stainless steel wire was investigated,emphasizing microstructural deformation,martensite phase transformation,and residual magnetic properties during drawing.Utilizing several microstructural observation techniques,the volume fraction of martensite,modes of grain deformation in distinct regions,and the phase relationship between austenite and martensite were comprehensively characterized.In addition,a finite element simulation with representative volume elements specific to different zones also offers insights into strain responses during the drawing process.Results from the first-pass drawing reveal that there exists a higher volume fraction of martensite in the central region of 304H austenitic stainless steel wire compared to edge areas.This discrepancy is attributed to a concentrated presence of shear slip system{111}<110>γcrystallographic orientation,primarily accumulating in the central region obeying the Kurdjumov-Sachs path.Subsequent to the second drawing pass,the cumulative shear deformation within distinct regions of the steel wire became more pronounced.This resulted in a progressive augmentation of the volume fraction of martensite in both the central and peripheral regions of the steel wire.Concurrently,this led to a discernible elevation in the overall residual magnetism of the steel wire.
基金Project(2021YFB3700801)supported by the National Key Research and Development Program of ChinaProject(2023JJ30683)supported by the Natural Science Foundation of Hunan Province,ChinaProject supported by the State Key Laboratory of Powder Metallurgy(Central South University),China。
文摘Heterogeneous structure exhibits superiority in improving mechanical properties,whereas their effects on fatigue damage properties have rarely been studied.In this work,we employed a high-throughput gradient heat treatment method(757−857℃)to rapidly acquire the solution microstructure of the Ti-6554 alloy with different recrystallization degrees(0%,40%and 100%),followed by the same aging treatment.The results showed that theβ-hetero structure exhibited a yield strength(σ_(YS))of 1403 MPa,an increase of 6.7%,and a remarkable improvement in uniform elongation(UE)of 109.7%,reaching 6.5%,compared to the homogeneous structure.Interestingly,introducing a heterogeneous structure not only overcame the traditional trade-off between strength and ductility but also enhanced fatigue crack propagation(FCP)performance.During FCP process,β-hetero structure,through hetero-deformation induced(HDI)strengthening effects,promoted the accumulation of geometric necessary dislocations(GNDs)within coarseα_(S) phase,enabling faster attainment of the critical shear stress of twinning and increasing twinning density.This facilitated stress relief,improved plastic deformation in the crack tip zone,and increased the critical fast fracture threshold from 30.4 to 36.0 MPa·m^(1/2)showing an enlarged steady state propagation region.This study provides valuable insights on tailoring fatigue damage tolerance through heterogeneous structure for titanium alloys.
基金financially supported by the National Key Re-search and Development Program of China(No.2021YFB3702604)the National Natural Science Foundation of China(No.52174377)+1 种基金the Chongqing Natural Science Foundation Project(No.CSTB2023NSCQ-MSX0824)This work was also supported by the Shaanxi Materials Analysis&Research Center and the Analytical&Testing Center of NPU.
文摘Theβsolidifiedγ-TiAl alloy holds important application value in the aerospace industry,while its com-plex phase compositions and geometric structures pose challenges to its microstructure control during the thermal-mechanical process.The microstructure evolution of Ti-43Al-4Nb-1Mo-0.2B alloy at 1200℃/0.01 s−1 was investigated to clarify the coupling role of dynamic recrystallization(DRX)and phase transformation.The results revealed that the rate of DRX inα2+γlamellar colonies was comparatively slower than that inβo+γmixed structure,instead being accompanied by intense lamellar kinking and rotation.The initiation and development rates of DRX inα2,βo,andγphases decreased sequentially.The asynchronous DRX of the various geometric structures and phase compositions resulted in the un-even deformed microstructure,and the dynamic softening induced by lamellar kinking and rotation was replaced by strengthened DRX as strain increased.Additionally,the blockyα2 phase and the terminals ofα2 lamellae were the preferential DRX sites owing to the abundant activated slip systems.Theα2→βo transformation within lamellar colonies facilitated DRX and fragment ofα2 lamellae,while theα2→γtransformation promoted the decomposition ofα2 lamellae and DRX ofγlamellae.Moreover,the var-iedβo+γmixed structures underwent complicated evolution:(1)Theγ→βo transformation occurred at boundaries of lamellar colonies,followed by simultaneous DRX ofγlamellar terminals and neighboringβo phase;(2)DRX occurred earlier within the band-likeβo phase,with the delayed DRX in enclosedγphase;(3)DRX within theβo synapses and neighboringγphase was accelerated owing to generation of elastic stress field;(4)Dispersedβo particles triggered particle stimulated nucleation(PSN)ofγphase.Eventually,atomic diffusion along crystal defects inβo andγphases caused fracture of band-likeβo phase and formation of massiveβo particles,impeding grain boundary migration and hindering DRXed grain growth ofγphase.
