Residue deep hydrotreating(RDHT)process was developed by the Research Institute of Petroleum Processing(RIPP)to provide high quality feedstock for deep catalytic cracking(DCC)process.In this research work,the effects ...Residue deep hydrotreating(RDHT)process was developed by the Research Institute of Petroleum Processing(RIPP)to provide high quality feedstock for deep catalytic cracking(DCC)process.In this research work,the effects of RDHT process and reaction severity on heteroatom removal,hydrogen content increase,hydrocarbon composition improvement,and DCC product yields were studied.It was showed that the RDHT process can effectively reduce heteroatoms,increase hydrogen content and improve the hydrocarbon compositions,which can contribute to an increase of light olefins yield in DCC unit.展开更多
To analyze and predict the mechanical behaviors of deep hard rocks,some key issues concerning rock fracturing mechanics for deep hard rock excavations are discussed.First,a series of apparatuses and methods have been ...To analyze and predict the mechanical behaviors of deep hard rocks,some key issues concerning rock fracturing mechanics for deep hard rock excavations are discussed.First,a series of apparatuses and methods have been developed to test the mechanical properties and fracturing behaviors of hard rocks under high true triaxial stress paths.Evolution mechanisms of stress-induced disasters in deep hard rock excavations,such as spalling,deep cracking,massive roof collapse,large deformation and rockbursts,have been recognized.The analytical theory for the fracturing process of hard rock masses,including the three-dimensional failure criterion,stress-induced mechanical model,fracturing degree index,energy release index and numerical method,has been established.The cracking-restraint method is developed for mitigating or controlling rock spalling,deep cracking and massive collapse of deep hard rocks.An energy-controlled method is also proposed for the prevention of rockbursts.Finally,two typical cases are used to illustrate the application of the proposed methodology in the Baihetan caverns and Bayu tunnels of China.展开更多
In this study, it was assumed that three-dimensional penny-shaped cracks existed in deep rock masses. A new non-Euclidean model was established, in which the effects of penny- shaped cracks and axial in-situ stress on...In this study, it was assumed that three-dimensional penny-shaped cracks existed in deep rock masses. A new non-Euclidean model was established, in which the effects of penny- shaped cracks and axial in-situ stress on zonal disintegration of deep rock masses were taken into account. Based on the non-Euclidean model, the stress intensity factors at tips of the penny- shaped cracks were determined. The strain energy density factor was applied to investigate the occurrence of fractured zones. It was observed from the numerical results that the magnitude and location of fractured zones were sensitive to micro- and macro-mechanical parameters, as well as the value of in-situ stress. The numerical results were in good agreement with the experimental data.展开更多
Deep Catalytic Cracking （DCC） developed by RIPP （Research Institute of Petroleum Processing）, SINOPEC is a catalytic conversion process derived from the FCC process using heavy feedstocks for producing raw materia...Deep Catalytic Cracking （DCC） developed by RIPP （Research Institute of Petroleum Processing）, SINOPEC is a catalytic conversion process derived from the FCC process using heavy feedstocks for producing raw materials used in the petrochemical industry, such as ethylene and propylene. It was firstly demonstrated in 1990 and has been commercialized since 1994. Up to now, seven units have been put into production inside and outside China, and many other DCC units are under construction and in the phase of design now. Products ofpropylene and ethylene from DCCU have been used as feedstock for manufacturing high quality polypropylene, polyethylene and acrylonitrile. Many innovations on technological process, and preparation of catalytic materials used in the DCC process will be presented in this paper.展开更多
RIPP has developed the third generation novel DCC catalysts aimed at increasing the propylene yield, named as the MMC series catalysts. This catalyst is of the MFI structure composed of the ZSP zeolite as the main act...RIPP has developed the third generation novel DCC catalysts aimed at increasing the propylene yield, named as the MMC series catalysts. This catalyst is of the MFI structure composed of the ZSP zeolite as the main active component, which has higher capability for producing low-carbon olefins, in particular the propylene. The commercial application of this catalyst at SINOPEC Anqing Petrochemical Company has revealed that the adoption of the MMC-2 catalyst has resulted in a 1.6-4.0 percentages increase in propylene yield under basically similar conditions in terms of the feedstock property and process operating regime coupled with reduction in gasoline olefin COntent and increase in aromatic content to improve the gasoline quality.展开更多
One of the main problems with roads and highways in China is the reflection cracking caused by the cement stabilized subbase layers passing through the overlying asphaltic layers. The cracks permit the ingress of mois...One of the main problems with roads and highways in China is the reflection cracking caused by the cement stabilized subbase layers passing through the overlying asphaltic layers. The cracks permit the ingress of moisture which softens the layers below the subbase resulting in loss of support and accelerated breakdown of the subbase layer and reduction in the tiding quality. The aim of this paper is to present the use of South African pavement design approach of deep structure and thin surfacing to overcome the existing problems. The deep pavement structure provides good long-term support and avoids the influence of moisture ingress, which means that only surfacing damage needs to be repaired. An unbound crushed stone base layer which is an integral component of the pavement structure limits reflection cracking. The paper first deals with the South African pavement design procedure and contrast this with the Chinese pavement design method. The inherent weaknesses of these methods are discussed and flowing from this discussion proposals for adapting the South African approach to China is presented. The resultant proposals have a high likelihood of success and will counteract the influences of extreme climate and rampant overloading that occurs on the Chinese roads.展开更多
基金This work was supported by the Science and Technology Project of Sinopec(118015-1).
文摘Residue deep hydrotreating(RDHT)process was developed by the Research Institute of Petroleum Processing(RIPP)to provide high quality feedstock for deep catalytic cracking(DCC)process.In this research work,the effects of RDHT process and reaction severity on heteroatom removal,hydrogen content increase,hydrocarbon composition improvement,and DCC product yields were studied.It was showed that the RDHT process can effectively reduce heteroatoms,increase hydrogen content and improve the hydrocarbon compositions,which can contribute to an increase of light olefins yield in DCC unit.
基金financial support from the National Natural Science Foundation of China(Grant Nos.51839003 and 41827806)Liaoning Revitalization Talents Program of China(Grant No.XLYCYSZX1902)。
文摘To analyze and predict the mechanical behaviors of deep hard rocks,some key issues concerning rock fracturing mechanics for deep hard rock excavations are discussed.First,a series of apparatuses and methods have been developed to test the mechanical properties and fracturing behaviors of hard rocks under high true triaxial stress paths.Evolution mechanisms of stress-induced disasters in deep hard rock excavations,such as spalling,deep cracking,massive roof collapse,large deformation and rockbursts,have been recognized.The analytical theory for the fracturing process of hard rock masses,including the three-dimensional failure criterion,stress-induced mechanical model,fracturing degree index,energy release index and numerical method,has been established.The cracking-restraint method is developed for mitigating or controlling rock spalling,deep cracking and massive collapse of deep hard rocks.An energy-controlled method is also proposed for the prevention of rockbursts.Finally,two typical cases are used to illustrate the application of the proposed methodology in the Baihetan caverns and Bayu tunnels of China.
基金supported by the 973 Project(No.2014CB046903)the National Natural Science Foundation of China(Nos.51325903 and 51279218)the Natural Science Foundation Project of CQ CSTC(Nos.CSTC2013KJRC-1JRCCJ30001 and CSTC2013JCYJYS0005)
文摘In this study, it was assumed that three-dimensional penny-shaped cracks existed in deep rock masses. A new non-Euclidean model was established, in which the effects of penny- shaped cracks and axial in-situ stress on zonal disintegration of deep rock masses were taken into account. Based on the non-Euclidean model, the stress intensity factors at tips of the penny- shaped cracks were determined. The strain energy density factor was applied to investigate the occurrence of fractured zones. It was observed from the numerical results that the magnitude and location of fractured zones were sensitive to micro- and macro-mechanical parameters, as well as the value of in-situ stress. The numerical results were in good agreement with the experimental data.
文摘Deep Catalytic Cracking （DCC） developed by RIPP （Research Institute of Petroleum Processing）, SINOPEC is a catalytic conversion process derived from the FCC process using heavy feedstocks for producing raw materials used in the petrochemical industry, such as ethylene and propylene. It was firstly demonstrated in 1990 and has been commercialized since 1994. Up to now, seven units have been put into production inside and outside China, and many other DCC units are under construction and in the phase of design now. Products ofpropylene and ethylene from DCCU have been used as feedstock for manufacturing high quality polypropylene, polyethylene and acrylonitrile. Many innovations on technological process, and preparation of catalytic materials used in the DCC process will be presented in this paper.
文摘RIPP has developed the third generation novel DCC catalysts aimed at increasing the propylene yield, named as the MMC series catalysts. This catalyst is of the MFI structure composed of the ZSP zeolite as the main active component, which has higher capability for producing low-carbon olefins, in particular the propylene. The commercial application of this catalyst at SINOPEC Anqing Petrochemical Company has revealed that the adoption of the MMC-2 catalyst has resulted in a 1.6-4.0 percentages increase in propylene yield under basically similar conditions in terms of the feedstock property and process operating regime coupled with reduction in gasoline olefin COntent and increase in aromatic content to improve the gasoline quality.
文摘One of the main problems with roads and highways in China is the reflection cracking caused by the cement stabilized subbase layers passing through the overlying asphaltic layers. The cracks permit the ingress of moisture which softens the layers below the subbase resulting in loss of support and accelerated breakdown of the subbase layer and reduction in the tiding quality. The aim of this paper is to present the use of South African pavement design approach of deep structure and thin surfacing to overcome the existing problems. The deep pavement structure provides good long-term support and avoids the influence of moisture ingress, which means that only surfacing damage needs to be repaired. An unbound crushed stone base layer which is an integral component of the pavement structure limits reflection cracking. The paper first deals with the South African pavement design procedure and contrast this with the Chinese pavement design method. The inherent weaknesses of these methods are discussed and flowing from this discussion proposals for adapting the South African approach to China is presented. The resultant proposals have a high likelihood of success and will counteract the influences of extreme climate and rampant overloading that occurs on the Chinese roads.
