Foaming issues are encountered at the stages in crude oil production, transportation, processing, especially in chemical flooding enhanced oil recovery(EOR) oilfields. These accumulated foams would cause a lot of trou...Foaming issues are encountered at the stages in crude oil production, transportation, processing, especially in chemical flooding enhanced oil recovery(EOR) oilfields. These accumulated foams would cause a lot of trouble for downstream operation. The destruction of foams under ultrasonic has been increasingly paying attention in the background of green oilfield development. This study focuses on the decay kinetic characteristics of alkaline-surfactant-polymer-strengthened foams under the ultrasonic standing wave.The performance of the diverse foams was characterized. A decay kinetic model incorporating the energy correlation was developed and validated. The factors that affect the decay kinetic characteristics were discussed. The results indicated that the collapse rate and the collapse volume fraction decreased when the foam size decreased, the gas-liquid ratio decreased and the surface tension increased. Ultrasonic standing wave parameters have a significant impact on the decay behavior of the foam. Both the ultrasonic frequency and ultrasonic amplitude were increased by 50%, the collapse volume fraction of foams increased by about 1.25 times in the identical irradiation time. The relative deviation between the measured results and the model prediction was less than 10%. The potential collapse mechanism was also explained using the principle of energy correlation of foam surface. This study is not only beneficial to provide a robust and rigorous way to defoam of produced liquid in the alkaline/surfactant/polymer(ASP)flooding EOR process but also meaningful to well understand the decay process of oil-based foams.展开更多
Diagnostic analysis of the balance of kinetic energy (KE) is made for a decaying onland typoon, its external torrential rain area and environment. Results show that, besides low-level frictional dissipation as an ener...Diagnostic analysis of the balance of kinetic energy (KE) is made for a decaying onland typoon, its external torrential rain area and environment. Results show that, besides low-level frictional dissipation as an energy sink, upper-level horizontal export of KE is another important one for the typhoon. In its decaying KE grows in the external torrential rain area, and the KE production term Gk represents the chief energy source for the torrential rain. The growth of Gk is attributed to the development of the heavy rain and to the heating effect of released latent heat, and the external torrential rain owes its evolution to the exported KE from the strong windbelt in the east of the typhoon and the conversion of synoptic KE into mesoscale perturbation KE. The development of the torrential rain results in the KE feedback to its environment. The KE transfer from the typhoon to the external torrential rain area and then to the environmental region as a mechanism constitutes one of the causes for the rapid disintegration of the tempest.展开更多
Ensemble and single particle studies of the excitation power density (P)-dependent upconversion luminescence (UCL) of core and core-shell β-NaYF_(4):Yb,Er upconversion nanoparticles (UCNPs) doped with 20% Yb^(3+) and...Ensemble and single particle studies of the excitation power density (P)-dependent upconversion luminescence (UCL) of core and core-shell β-NaYF_(4):Yb,Er upconversion nanoparticles (UCNPs) doped with 20% Yb^(3+) and 1% or 3% Er^(^(3+)) performed over a P regime of 6 orders of magnitude reveal an increasing contribution of the emission from high energy Er^(3+) levels at P > 1 kW/cm^(2). This changes the overall emission color from initially green over yellow to white. While initially the green and with increasing P the red emission dominate in ensemble measurements at P < 1 kW/cm^(2), the increasing population of higher Er^(^(3+)) energy levels by multiphotonic processes at higher P in single particle studies results in a multitude of emission bands in the ultraviolet/visible/near infrared (UV/vis/NIR) accompanied by a decreased contribution of the red luminescence. Based upon a thorough analysis of the P-dependence of UCL, the emission bands activated at high P were grouped and assigned to 2–3, 3–4, and 4 photonic processes involving energy transfer (ET), excited-state absorption (ESA), cross-relaxation (CR), back energy transfer (BET), and non-radiative relaxation processes (nRP). This underlines the P-tunability of UCNP brightness and color and highlights the potential of P-dependent measurements for mechanistic studies required to manifest the population pathways of the different Er^(3+) levels.展开更多
基金financially supported by the National Natural Science Foundation of China (Grant No.52174060)the PetroChina Innovation Foundation (Grant No.2019D-5007-0501)The Postdoctoral Scientific Foundation of Heilongjiang Province in China (Grant No. LBH-Q20012)。
文摘Foaming issues are encountered at the stages in crude oil production, transportation, processing, especially in chemical flooding enhanced oil recovery(EOR) oilfields. These accumulated foams would cause a lot of trouble for downstream operation. The destruction of foams under ultrasonic has been increasingly paying attention in the background of green oilfield development. This study focuses on the decay kinetic characteristics of alkaline-surfactant-polymer-strengthened foams under the ultrasonic standing wave.The performance of the diverse foams was characterized. A decay kinetic model incorporating the energy correlation was developed and validated. The factors that affect the decay kinetic characteristics were discussed. The results indicated that the collapse rate and the collapse volume fraction decreased when the foam size decreased, the gas-liquid ratio decreased and the surface tension increased. Ultrasonic standing wave parameters have a significant impact on the decay behavior of the foam. Both the ultrasonic frequency and ultrasonic amplitude were increased by 50%, the collapse volume fraction of foams increased by about 1.25 times in the identical irradiation time. The relative deviation between the measured results and the model prediction was less than 10%. The potential collapse mechanism was also explained using the principle of energy correlation of foam surface. This study is not only beneficial to provide a robust and rigorous way to defoam of produced liquid in the alkaline/surfactant/polymer(ASP)flooding EOR process but also meaningful to well understand the decay process of oil-based foams.
文摘Diagnostic analysis of the balance of kinetic energy (KE) is made for a decaying onland typoon, its external torrential rain area and environment. Results show that, besides low-level frictional dissipation as an energy sink, upper-level horizontal export of KE is another important one for the typhoon. In its decaying KE grows in the external torrential rain area, and the KE production term Gk represents the chief energy source for the torrential rain. The growth of Gk is attributed to the development of the heavy rain and to the heating effect of released latent heat, and the external torrential rain owes its evolution to the exported KE from the strong windbelt in the east of the typhoon and the conversion of synoptic KE into mesoscale perturbation KE. The development of the torrential rain results in the KE feedback to its environment. The KE transfer from the typhoon to the external torrential rain area and then to the environmental region as a mechanism constitutes one of the causes for the rapid disintegration of the tempest.
基金The authors thank the European Upconversion Network(EUN)for financial support of a research exchange program(COST-CM1403)U.R.-G.,F.F.and C.W.acknowledge financial support by research grants RE 1203/20-1(project NANOHYPE,DFG and M-Eranet).Y.M.is grateful to the Institut Universitaire de France(IUF)for support and providing additional time to be dedicated to research.
文摘Ensemble and single particle studies of the excitation power density (P)-dependent upconversion luminescence (UCL) of core and core-shell β-NaYF_(4):Yb,Er upconversion nanoparticles (UCNPs) doped with 20% Yb^(3+) and 1% or 3% Er^(^(3+)) performed over a P regime of 6 orders of magnitude reveal an increasing contribution of the emission from high energy Er^(3+) levels at P > 1 kW/cm^(2). This changes the overall emission color from initially green over yellow to white. While initially the green and with increasing P the red emission dominate in ensemble measurements at P < 1 kW/cm^(2), the increasing population of higher Er^(^(3+)) energy levels by multiphotonic processes at higher P in single particle studies results in a multitude of emission bands in the ultraviolet/visible/near infrared (UV/vis/NIR) accompanied by a decreased contribution of the red luminescence. Based upon a thorough analysis of the P-dependence of UCL, the emission bands activated at high P were grouped and assigned to 2–3, 3–4, and 4 photonic processes involving energy transfer (ET), excited-state absorption (ESA), cross-relaxation (CR), back energy transfer (BET), and non-radiative relaxation processes (nRP). This underlines the P-tunability of UCNP brightness and color and highlights the potential of P-dependent measurements for mechanistic studies required to manifest the population pathways of the different Er^(3+) levels.
