In this work, we propose a model of oscillation of Davydov solitons in three wells. It can be used as a mathematical and physical frame in simulation of circle of some nonlinear oscillation of excitations via acupunct...In this work, we propose a model of oscillation of Davydov solitons in three wells. It can be used as a mathematical and physical frame in simulation of circle of some nonlinear oscillation of excitations via acupuncture system. The calculation shows that this sort of oscillation is possible if the initial rate of average occupational number of the quasi-particles in the wells is not equal to zero. One of oscillations arising relies on the initial rate of average occupational number of quasi-particles to be equal with each other within three wells. Then, the oscillation is not a kind of Josephson oscillation and has complicated frequency distributions. However, the total behavior of oscillation played is similar to three big solitons concentrated in three wells. In this sense, this model generally reveals a sort of oscillation mechanism of the acupuncture system how to work in the body, which allows us to understand the oscillation that may be one of fundamental natures in the acupuncture system.展开更多
Introduction. -The laparoscopic Davydov is described. The data concerning the surgery and the postoperative course are reported at the same time as the data concerning the anatomical and sexological results. Patients ...Introduction. -The laparoscopic Davydov is described. The data concerning the surgery and the postoperative course are reported at the same time as the data concerning the anatomical and sexological results. Patients and methods. -The s urgery includes three steps: (i) cleavage under laparoscopic guidance, (ii) peri toneovestibular stitch by perineal approach, (iii) making the vaginal vault with the laparoscope. The cleavage can be performed in front of the fascia interpose d between the bladder and the rectum or behind it. A nymphoplasty can be added t o the colpopoeisis. Results. -Between February 1996 and March 2003 we operated on 28 patients affected by congenital vaginal agenesis using the laparoscopic Da vydov technique. Two peroperative complications occurred (urinary tract injuries during the first step: laparoscopic management) and two postoperative complicat ions (intraperitoneal migration of the mould and vesicovaginal fistula managed s uccessfully with the laparoscope for the first one and trough laparotomy for the second one). Four reoperations (incision and dilation) were necesssary. The len gth of the neovagina was, at the last assessment, 7.2 ±1.3cm. The Female Sexual Function Index was 26,5±5.6 vs. 27.9 ±4.5 in a control cohort. In the patient s whose cleavage was performed behind the fascia (13 cases vs. 15) no complicati on occurred, no re-operation was necessary, the length of the neovagina was 7,0 ±0,7cm and the FSFI was 26,3 ±5,9. Discussion and conclusion. -The laparoscop ic Davydov is, if the dorsal approach is used for the cleavage, an easy to make operation (operating time: 90 ±.29 minutes) with a short hospital stay. The pos toperative care is simple (vaginal mould useless). Heterosexual activity with pe nile penetration can start early (6 to 8 weeks). The level of satisfaction is hi gh. Laparoscopic Davydov procedure may be considered a good alternative to the m ore complex ones (as Vecchietti’s technique) or to the more dangerous ones (sig moid colpoplasty).展开更多
Carcinogenesis fits in a frequency pattern of electromagnetic field (EMF) waves, in which a gradual loss of cellular organization occurs. Such generation of cancer features can be inhibited by adequate exposure to coh...Carcinogenesis fits in a frequency pattern of electromagnetic field (EMF) waves, in which a gradual loss of cellular organization occurs. Such generation of cancer features can be inhibited by adequate exposure to coherent electromagnetic frequencies. However, cancer can also be initiated and promoted at other distinct frequencies of electromagnetic waves. Both observations were revealed by analyzing 100 different EMF frequency data reported in a meta-analyses of 123 different, earlier published, biomedical studies. The studied EM frequencies showed a fractal pattern of 12 beneficial (anti-cancer) frequencies, and 12 detrimental (cancer promoting) frequencies, that form the central pattern of a much wider self-similar EMF spectrum of cancer inhibiting or promoting activities. Inhibiting of the cancer process, and even curing of the disease, can thus be considered through exposure to the coherent type of EM fields. Stabilization of the disease can be understood by constructive resonance of macromolecules in the cancer cell with the externally appied coherent EMF field frequencies, called solitons/polarons. The latter, for instance, have been shown earlier to induce repair in DNA/RNA conformation and/or epigenetic changes. The field of EMF treatment of cancer disorders is rapidly expanding and our studies may invite further experimental and clinical studies in which systematically various potential EMF treatment protocols could be applied, with combined and modulated frequencies, to obtain even more efficient EMF anti-cancer therapies.展开更多
The exciton dispersion is examined in the case of four selected prototypical molecular solids: pentacene, tetracene, picene, and chrysene. The model parameters are determined by fitting to experimental data obtained b...The exciton dispersion is examined in the case of four selected prototypical molecular solids: pentacene, tetracene, picene, and chrysene. The model parameters are determined by fitting to experimental data obtained by inelastic electron scattering. Within the picture that relies on Frenkel-type excitons we obtain that theoretical dispersion curves along different directions in the Brillouin zone are in good agreement with the experimental data, suggesting that the influence of charge-transfer excitons on exciton dispersion of the analyzed organic solids is not as large as proposed. In reciprocal space directions where Davydov splitting is observed we employ the upgraded version of Hamiltonian used in Materials 11, 2219 (2018).展开更多
This work presents a theoretical simulation of the infrared spectra of strong hydrogen bond in alpha-phase 2-pyridone dimers, as well as in their deuterium derivatives at room temperature. The theory takes into accoun...This work presents a theoretical simulation of the infrared spectra of strong hydrogen bond in alpha-phase 2-pyridone dimers, as well as in their deuterium derivatives at room temperature. The theory takes into account an adiabatic anharmonic coupling between the high-frequency N-H(D) stretching and the low-frequency intermolecular N...O stretching modes by considering that the effective angular frequency of the fast mode N-H(D) is assumed to be strongly dependent on the slow mode stretching coordinate N...O, the intrinsic anharmonicity of the low-frequency N...O mode through a Morse potential, Davydov coupling triggered by resonance exchange between the excited states of the fast modes of the two hydrogen bonds involved in the cyclic dimer, multiple Fermi resonances between the N-H(D) stretching and the overtone of the N-H(D) bending vibrations and the direct and indirect damping of the fast stretching modes of the hydrogen bonds and of the bending modes. The IR spectral density is computed within the linear response theory by Fourier transform of the autocorrelation function of the transition dipole moment operator of the N-H(D) bond. The theoretical line shapes of the υN-H(D) band of alpha-phase 2-pyridone dimers are compared to the experimental ones. The effect of deuteration is successfully reproduced.展开更多
Orthorhombic copper polysilicate, CuSiO3, is isotypic to the spin-Peierls compound CuGeO3 and represents a further example of a quasi-one-dimensional spin = 1/2 antiferromagnetic Heisenberg chain system. This is a rep...Orthorhombic copper polysilicate, CuSiO3, is isotypic to the spin-Peierls compound CuGeO3 and represents a further example of a quasi-one-dimensional spin = 1/2 antiferromagnetic Heisenberg chain system. This is a representation of the first Raman and IR/FIR spectra for CuSiO3, measured at room temperature on polycrystalline samples. A comparison of the optical phonons, predicted by a factor group analysis, with those observed for the CuGeO3 prototype, is presented. A mode assignment for the silicate is given. Surface effects due to a very small crystallite size may cause additional broad bands observed in the Raman spectrum of CuSiO3. From the analysis of the Davydov doublet an intralayer-to-interlayer bond strength of about 40 is derived for the silicate, which is about 20% lower than for the isotypic germanate, allowing for different magnetic responses at low temperature.展开更多
文摘In this work, we propose a model of oscillation of Davydov solitons in three wells. It can be used as a mathematical and physical frame in simulation of circle of some nonlinear oscillation of excitations via acupuncture system. The calculation shows that this sort of oscillation is possible if the initial rate of average occupational number of the quasi-particles in the wells is not equal to zero. One of oscillations arising relies on the initial rate of average occupational number of quasi-particles to be equal with each other within three wells. Then, the oscillation is not a kind of Josephson oscillation and has complicated frequency distributions. However, the total behavior of oscillation played is similar to three big solitons concentrated in three wells. In this sense, this model generally reveals a sort of oscillation mechanism of the acupuncture system how to work in the body, which allows us to understand the oscillation that may be one of fundamental natures in the acupuncture system.
文摘Introduction. -The laparoscopic Davydov is described. The data concerning the surgery and the postoperative course are reported at the same time as the data concerning the anatomical and sexological results. Patients and methods. -The s urgery includes three steps: (i) cleavage under laparoscopic guidance, (ii) peri toneovestibular stitch by perineal approach, (iii) making the vaginal vault with the laparoscope. The cleavage can be performed in front of the fascia interpose d between the bladder and the rectum or behind it. A nymphoplasty can be added t o the colpopoeisis. Results. -Between February 1996 and March 2003 we operated on 28 patients affected by congenital vaginal agenesis using the laparoscopic Da vydov technique. Two peroperative complications occurred (urinary tract injuries during the first step: laparoscopic management) and two postoperative complicat ions (intraperitoneal migration of the mould and vesicovaginal fistula managed s uccessfully with the laparoscope for the first one and trough laparotomy for the second one). Four reoperations (incision and dilation) were necesssary. The len gth of the neovagina was, at the last assessment, 7.2 ±1.3cm. The Female Sexual Function Index was 26,5±5.6 vs. 27.9 ±4.5 in a control cohort. In the patient s whose cleavage was performed behind the fascia (13 cases vs. 15) no complicati on occurred, no re-operation was necessary, the length of the neovagina was 7,0 ±0,7cm and the FSFI was 26,3 ±5,9. Discussion and conclusion. -The laparoscop ic Davydov is, if the dorsal approach is used for the cleavage, an easy to make operation (operating time: 90 ±.29 minutes) with a short hospital stay. The pos toperative care is simple (vaginal mould useless). Heterosexual activity with pe nile penetration can start early (6 to 8 weeks). The level of satisfaction is hi gh. Laparoscopic Davydov procedure may be considered a good alternative to the m ore complex ones (as Vecchietti’s technique) or to the more dangerous ones (sig moid colpoplasty).
文摘Carcinogenesis fits in a frequency pattern of electromagnetic field (EMF) waves, in which a gradual loss of cellular organization occurs. Such generation of cancer features can be inhibited by adequate exposure to coherent electromagnetic frequencies. However, cancer can also be initiated and promoted at other distinct frequencies of electromagnetic waves. Both observations were revealed by analyzing 100 different EMF frequency data reported in a meta-analyses of 123 different, earlier published, biomedical studies. The studied EM frequencies showed a fractal pattern of 12 beneficial (anti-cancer) frequencies, and 12 detrimental (cancer promoting) frequencies, that form the central pattern of a much wider self-similar EMF spectrum of cancer inhibiting or promoting activities. Inhibiting of the cancer process, and even curing of the disease, can thus be considered through exposure to the coherent type of EM fields. Stabilization of the disease can be understood by constructive resonance of macromolecules in the cancer cell with the externally appied coherent EMF field frequencies, called solitons/polarons. The latter, for instance, have been shown earlier to induce repair in DNA/RNA conformation and/or epigenetic changes. The field of EMF treatment of cancer disorders is rapidly expanding and our studies may invite further experimental and clinical studies in which systematically various potential EMF treatment protocols could be applied, with combined and modulated frequencies, to obtain even more efficient EMF anti-cancer therapies.
基金Project supported by the Serbian Ministry of Education and Science(Grant No.OI-171009)the Provincial Secretariat for High Education and Scientific Research of Vojvodina(Grant No.APV 114-451-2201).
文摘The exciton dispersion is examined in the case of four selected prototypical molecular solids: pentacene, tetracene, picene, and chrysene. The model parameters are determined by fitting to experimental data obtained by inelastic electron scattering. Within the picture that relies on Frenkel-type excitons we obtain that theoretical dispersion curves along different directions in the Brillouin zone are in good agreement with the experimental data, suggesting that the influence of charge-transfer excitons on exciton dispersion of the analyzed organic solids is not as large as proposed. In reciprocal space directions where Davydov splitting is observed we employ the upgraded version of Hamiltonian used in Materials 11, 2219 (2018).
文摘This work presents a theoretical simulation of the infrared spectra of strong hydrogen bond in alpha-phase 2-pyridone dimers, as well as in their deuterium derivatives at room temperature. The theory takes into account an adiabatic anharmonic coupling between the high-frequency N-H(D) stretching and the low-frequency intermolecular N...O stretching modes by considering that the effective angular frequency of the fast mode N-H(D) is assumed to be strongly dependent on the slow mode stretching coordinate N...O, the intrinsic anharmonicity of the low-frequency N...O mode through a Morse potential, Davydov coupling triggered by resonance exchange between the excited states of the fast modes of the two hydrogen bonds involved in the cyclic dimer, multiple Fermi resonances between the N-H(D) stretching and the overtone of the N-H(D) bending vibrations and the direct and indirect damping of the fast stretching modes of the hydrogen bonds and of the bending modes. The IR spectral density is computed within the linear response theory by Fourier transform of the autocorrelation function of the transition dipole moment operator of the N-H(D) bond. The theoretical line shapes of the υN-H(D) band of alpha-phase 2-pyridone dimers are compared to the experimental ones. The effect of deuteration is successfully reproduced.
文摘Orthorhombic copper polysilicate, CuSiO3, is isotypic to the spin-Peierls compound CuGeO3 and represents a further example of a quasi-one-dimensional spin = 1/2 antiferromagnetic Heisenberg chain system. This is a representation of the first Raman and IR/FIR spectra for CuSiO3, measured at room temperature on polycrystalline samples. A comparison of the optical phonons, predicted by a factor group analysis, with those observed for the CuGeO3 prototype, is presented. A mode assignment for the silicate is given. Surface effects due to a very small crystallite size may cause additional broad bands observed in the Raman spectrum of CuSiO3. From the analysis of the Davydov doublet an intralayer-to-interlayer bond strength of about 40 is derived for the silicate, which is about 20% lower than for the isotypic germanate, allowing for different magnetic responses at low temperature.