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STRUCTURAL ANALYSIS AND ENVIRONMENTAL STABILITY OF POLYFLUORINATED GROUP SUBSTITUTED POLYTHIOPHENES
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作者 张旭庆 沈学明 +2 位作者 杨士勇 陆伟 张景云 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1996年第4期330-337,共8页
Electrochemical polymerization of 3-fluoroalkoxy and 3-fluoroether thiophenes gives polymers with relatively high molecular weights and good processibility. Investigation of these polymers by means of GPC indicates th... Electrochemical polymerization of 3-fluoroalkoxy and 3-fluoroether thiophenes gives polymers with relatively high molecular weights and good processibility. Investigation of these polymers by means of GPC indicates that an increase in the number of fluorine atoms in the fluorinated group results in a decrease in degree of polymerization of the polymers in the same polythiophene series. As shown by NMR and FTIR, the polyfluorinated group substituted polythiophenes have regular 2, 5-coupling in their main chains. The SEM micrographs of the polymer films exhibit that polymer (1)-poly [3-2, 2, 3, 3-tetrafluoro-propoxy) thiophene] possesses more regular structure than the other polymers do. Substitution of polythiophenes by fluorinated groups leads to the polymers with high electric, electrochemical and thermal stability. 展开更多
关键词 structural analysis environmental stability polyfluorinated substituent POLYTHIOPHENE
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Structural Types of Sea Embankment and Their Stability Analysis
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作者 Mao, CX Duan, XB Mao, PY 《China Ocean Engineering》 SCIE EI 1998年第3期333-352,共20页
In this paper based on investigation on the structural types of sea embankments in the southeast coastal area of China, as well as the related tidal stages, waves and strength of marine soils, the finite element metho... In this paper based on investigation on the structural types of sea embankments in the southeast coastal area of China, as well as the related tidal stages, waves and strength of marine soils, the finite element method (FEM) calculations for seepage flow stability, including the overall stability against sliding and local stability of sloping surface under the action of tidal stage and waves are carried out. A comparison of the computational results of FEM for single circular slip, composite circular slip and geogrid reinforcement against sliding shows that for calculation of stability against sliding of marine soft soil foundation it is even more reasonable to use the composite circular slip. The stability of sloping type sea embankment against sliding is slightly better than that of the vertical face type; for the combination of three defences (wave, scour and seepage defences) the sea embankment structural type of a composite cross section with a platform should be a good one, but it still should be suitable to local conditions. For the local stability of riprap slope blocks and wall face loose masonry blocks, according to the analyses of wave-induced seepage flow fields, calculating formulas are given and they are verified by model test on block stability of breakwaters. 展开更多
关键词 sea embankment structural type tidal stage variation wave stroke seepage flow stability analysis
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Data-Driven Structural Design Optimization for Petal-Shaped Auxetics Using Isogeometric Analysis 被引量:9
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作者 Yingjun Wang Zhongyuan Liao +2 位作者 Shengyu Shi Zhenpei Wang Leong Hien Poh 《Computer Modeling in Engineering & Sciences》 SCIE EI 2020年第2期433-458,共26页
Focusing on the structural optimization of auxetic materials using data-driven methods,a back-propagation neural network(BPNN)based design framework is developed for petal-shaped auxetics using isogeometric analysis.A... Focusing on the structural optimization of auxetic materials using data-driven methods,a back-propagation neural network(BPNN)based design framework is developed for petal-shaped auxetics using isogeometric analysis.Adopting a NURBSbased parametric modelling scheme with a small number of design variables,the highly nonlinear relation between the input geometry variables and the effective material properties is obtained using BPNN-based fitting method,and demonstrated in this work to give high accuracy and efficiency.Such BPNN-based fitting functions also enable an easy analytical sensitivity analysis,in contrast to the generally complex procedures of typical shape and size sensitivity approaches. 展开更多
关键词 data-driven BP neural network petal-shaped auxetics negative Poisson’s ratio structural design isogeometric analysis.
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Stability Analysis of Rainfall-Triggered Toe-Cut Slopes and Effectiveness Evaluation of Pile-Anchor Structures 被引量:8
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作者 Xi Xu Yuanchuang Xing +1 位作者 Zhen Guo Yu Huang 《Journal of Earth Science》 SCIE CAS CSCD 2021年第5期1104-1112,共9页
Slope toe excavation strongly influences the stress balance of natural slopes and redistributes the stress of the slope body. Consequently, the sliding failure of toe-cut slopes is increasingly becoming more frequent,... Slope toe excavation strongly influences the stress balance of natural slopes and redistributes the stress of the slope body. Consequently, the sliding failure of toe-cut slopes is increasingly becoming more frequent, particularly in regions with persistent rainfall. The effects of external factors, namely, toe excavation and persistent rainfall, which lead to toe-cut slope failure were investigated through the numerical analysis of typical toe-cut slopes in the southeastern coastal region of China. Based on the grey relational theory, sensitivity analysis was carried out on the controlling factors to determine the degree of influence exerted by the external factors on the stability of toe-cut slopes. The stability analysis of toe-cut slopes reinforced by pileanchor structures under earthquake conditions was carried out using pseudo-static analysis. The safety factor of toe-cut slopes significantly decreases as the excavation height, rainfall duration, and rainfall intensity increase. The slope stability is more sensitive to the excavation height of a toe-cut slope than it is to rainfall. The stability of a toe-cut slope reinforced by a pile-anchor structure was also analyzed under rainfall and earthquake conditions using the limit equilibrium method and pseudo-static analysis, respectively. The slope stability significantly improved when the slope was reinforced by a pile-anchor structure, even when the slope was subjected to persistent rainfall and earthquakes. The findings of this study can provide important guidance for the prevention of geological disasters in mountainous areas. 展开更多
关键词 toe-cut slope pile-anchor structure slope stability limit equilibrium method pseudo-static analysis
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ANALYSIS OF DYNAMIC STABILITY OF SUBMERGED STRUCTURE 被引量:2
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作者 Qu Naisi , Yang Chunqiu and Tao Zhengguo Associate Professor, Dalian University of Technology, Dalian, Engineer, Wuxi 706 Research Institute, Wuxi 《China Ocean Engineering》 SCIE EI 1990年第2期209-220,共12页
The submerged structure is basically a large three-dimensional structure of few statically redundant members. The structure is subjected to vertical dead and live loads in addition to the wave forces. An analysis of d... The submerged structure is basically a large three-dimensional structure of few statically redundant members. The structure is subjected to vertical dead and live loads in addition to the wave forces. An analysis of dynamic stability of the submerged structure without damping has been made by J. Thomas and Abbas (1980). In this paper the analyses of dynamic stability of the sumberged structure with damping are conducted. The case structure with damping is more complicated 'than the case without it. According to the principle of perturbation, a new model for dynamic stability calculation in consideration of damping effect is developed. In this paper, the formulas are deduced, the computational program is compiled, the practical examples are analysed, and this problem is solved very satisfactorily. The computational results show that the shape and value of the regions of dynamic instability can be changed significantly by damping. So only by considering damping can the property of dynamic stability of the submerged structure be reflected correctly. 展开更多
关键词 analysis OF DYNAMIC stability OF SUBMERGED structurE
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Physics-based and data-driven modeling for stability evaluation of buried structures in natural clays 被引量:4
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作者 Fengwen Lai Jim Shiau +3 位作者 Suraparb Keawsawasvong Fuquan Chen Rungkhun Banyong Sorawit Seehavong 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第5期1248-1262,共15页
This study presents a hybrid framework to predict stability solutions of buried structures under active trapdoor conditions in natural clays with anisotropy and heterogeneity by combining physics-based and data-driven... This study presents a hybrid framework to predict stability solutions of buried structures under active trapdoor conditions in natural clays with anisotropy and heterogeneity by combining physics-based and data-driven modeling.Finite-element limit analysis(FELA)with a newly developed anisotropic undrained shear(AUS)failure criterion is used to identify the underlying active failure mechanisms as well as to develop a numerical(physics-based)database of stability numbers for both planar and circular trapdoors.Practical considerations are given for natural clays to three linearly increasing shear strengths in compression,extension,and direct simple shear in the AUS material model.The obtained numerical solutions are compared and validated with published solutions in the literature.A multivariate adaptive regression splines(MARS)algorithm is further utilized to learn the numerical solutions to act as fast FELA data-driven surrogates for stability evaluation.The current MARS-based modeling provides both relative importance index and accurate design equations that can be used with confidence by practitioners. 展开更多
关键词 Buried structures Natural clays Active trapdoor Undrained stability Multivariate adaptive regression splines (MARS) Finite element limit analysis(FELA)
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Stability analysis for main roof of roadway driving along next goaf 被引量:3
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作者 柏建彪 《Journal of Coal Science & Engineering(China)》 2003年第1期22-27,共6页
Focusing on the stability of surrounding rock around the roadway driving along next goaf with a narrow coal pillar, a mechanics model of the triangle block structure of main roof above the roadway is established, and ... Focusing on the stability of surrounding rock around the roadway driving along next goaf with a narrow coal pillar, a mechanics model of the triangle block structure of main roof above the roadway is established, and the sliding stability coefficient K 1 and the rotation stability coefficient K 2 are proposed to describe the stability of the triangle block structure quantitatively. The structure can keep a self stability before and after the roadway excavation, at the stage of mining induced effect, the stability of the structure is lowered, and the structure may become instability with decreasing the coal strength, increasing the mining height of working face and the mining depth. 展开更多
关键词 roadway driving along next goaf triangle block structure stability analysis
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3D stability analysis method of concave slope based on the Bishop method 被引量:6
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作者 Zhang Tianwen Cai Qingxiang +2 位作者 Han Liu Shu Jisen Zhou Wei 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2017年第2期365-370,共6页
In order to study the stability control mechanism of a concave slope with circular landslide, and remove the influence of differences in shape on slope stability, the limit analysis method of a simplified Bishop metho... In order to study the stability control mechanism of a concave slope with circular landslide, and remove the influence of differences in shape on slope stability, the limit analysis method of a simplified Bishop method was employed. The sliding body was divided into strips in a three-dimensional model, and the lateral earth pressure was put into mechanical analysis and the three-dimensional stability analysis methods applicable for circular sliding in concave slope were deduced. Based on geometric structure and the geological parameters of a concave slope, the influence rule of curvature radius and the top and bottom arch height on the concave slope stability were analyzed. The results show that the stability coefficient decreases after growth, first in the transition stage of slope shape from flat to concave, and it has been confirmed that there is a best size to make the slope stability factor reach a maximum. By contrast with average slope, the stability of a concave slope features a smaller range of ascension with slope height increase, which indicates that the enhancing effect of a concave slope is apparent only with lower slope heights. 展开更多
关键词 Bishop method Concave slope Three-dimensional structure stability analysis
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Stability Analysis of a Heterogeneous Periodic Fluid-Conveying Nanotube System 被引量:1
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作者 Jiayin Dai Yongshou Liu Guojun Tong 《Acta Mechanica Solida Sinica》 SCIE EI CSCD 2020年第6期756-769,共14页
In this paper,the stability of a periodic heterogeneous nanotube conveying fluid is investigated.The governing equations of the nanotube system are derived based on the nonlocal Euler-Bernoulli beam theory.The dynamic... In this paper,the stability of a periodic heterogeneous nanotube conveying fluid is investigated.The governing equations of the nanotube system are derived based on the nonlocal Euler-Bernoulli beam theory.The dynamic stiffness method is employed to analyze the natural frequencies and critical flow velocities of the heteronanotube.The results and discussions are presented from three aspects which reveal the influences of period number,material length ratio and boundary conditions.In particular,we make comparisons between the heterogeneous nanotubes with periodic structure and the homogeneous ones with the same integral values of material properties along the longitudinal direction to isolate the influences of periodic distribution.According to the simulation results,we can conclude that with a proper selection of period number in terms of length ratio,the stability of the constructed nanotube can be improved. 展开更多
关键词 Heterogeneous nanotube Dynamic stiffness method Periodic structure Nanotube conveying fluid stability analysis
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Numerical analysis on stability of surrounding rock mass around deep roadway 被引量:1
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作者 SU Cai-quan 《Journal of Coal Science & Engineering(China)》 2011年第4期377-381,共5页
Numerical simulations of the deep roadway were carried out through application of the strain-softening constitutive model. Differences between the deep and shallow roadway of the rock bearing structure were analyzed. ... Numerical simulations of the deep roadway were carried out through application of the strain-softening constitutive model. Differences between the deep and shallow roadway of the rock bearing structure were analyzed. Influences of the supporting resistance on the rock bearing structure at the deep roadway were discussed. The results show that there is alternation of strong and weak strength-softening region in the surrounding rock of deep roadway. However, the increase in the supporting resistance cuts down the size of strength-softening region of surrounding rock, decreases its strength-softening degree, and im- proves the stress distribution condition of the surrounding rock mass. It is concluded that the supporting resistance can raise the self-supporting ability of surrounding rock through controlling its strength-softening so as to make the rock bearing structure of deep roadway stable. 展开更多
关键词 numerical analysis stability surrounding rock deep roadway bearing structure
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Stability Analysis of Space Compcoite Structore and Its Ultimate Bearing Capacity 被引量:1
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作者 Zhao Lel Pen Junsheng Du Zhengguo (Department of Architectural Engineering,Southwest Jiaotong University)Chengdu610031, China 《Journal of Modern Transportation》 1995年第2期198-207,共10页
In this paper, using incremental equilibrium equation, the authors have studiedthe effeet of ultimate bearing capacity of every component on structuralstability, and discussed the stability analysis method for space c... In this paper, using incremental equilibrium equation, the authors have studiedthe effeet of ultimate bearing capacity of every component on structuralstability, and discussed the stability analysis method for space compositestructures. With the help of the test results for the concrete filled ateel tubeskeleton of the long-spen RC arch bridse, it is proved that the proposed methodis accurate and reliable. 展开更多
关键词 stability analysis ultimate bearing capacity space composite structure extremepoint collapse finite element method
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APPLICATION OF STOCHASTIC FINITE ELEMENT METHOD TO STRENGTH AND STABILITY ANALYSIS OF EARTH DAMS
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作者 Yongjian, Ren Guoqing, Wang +1 位作者 Derong, Wei Jizhong, Shi 《Acta Mechanica Solida Sinica》 SCIE EI 1994年第1期80-86,共7页
This paper applies the stochastic finite element method to analyse the statistics of stresses in earth dams and assess the safety and reliability of the dams. Formulations of the stochastic finite element method are b... This paper applies the stochastic finite element method to analyse the statistics of stresses in earth dams and assess the safety and reliability of the dams. Formulations of the stochastic finite element method are briefly reviewed and the procedure for assessing dam's strength and stability is described. As an example, a detailed analysis for an actual dam Nululin dam is performed. A practical method for studying built-dams based on the prototype observation data is described. 展开更多
关键词 Accident prevention Failure (mechanical) Finite element method Random processes RELIABILITY stability STATISTICS Strength of materials Stress analysis structural analysis Water levels
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An Optimal DF Based Method for Transient Stability Analysis
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作者 Z.A.Zaki Emad M.Ahmed +1 位作者 Ziad M.Ali Imran Khan 《Computers, Materials & Continua》 SCIE EI 2022年第2期3449-3471,共23页
The effect of energy on the natural environment has become increasingly severe as human consumption of fossil energy has increased.The capacity of the synchronous generators to keep working without losing synchronizat... The effect of energy on the natural environment has become increasingly severe as human consumption of fossil energy has increased.The capacity of the synchronous generators to keep working without losing synchronization when the system is exposed to severe faults such as short circuits is referred to as the power system’s transient stability.As the power system’s safe and stable operation and mechanism of action become more complicated,higher demands for accurate and rapid power system transient stability analysis are made.Current methods for analyzing transient stability are less accurate because they do not account formisclassification of unstable samples.As a result,this paper proposes a novel approach for analyzing transient stability.The key concept is to use deep forest(DF)and a neighborhood rough reduction approach together.Using the neighborhood rough sets,the original feature space is obtained by creating many optimal feature subsets at various granularity levels.Then,by deploying the DF cascade structure,the mapping connection between the transient stability state and the features is reinforced.The weighted voting technique is used in the learning process to increase the classification accuracy of unstable samples.When contrasted to current methods,simulation results indicate that the proposed approach outperforms them. 展开更多
关键词 Transient stability analysis power system cascade structure optimal power flow
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Study on Floating Properties and Stability of Air Floated Structures 被引量:11
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作者 BIE Shean(别社安) +5 位作者 JI Chunning(及春宁) REN Zengjin(任增金) LI Zengzhi(李增志) 《China Ocean Engineering》 SCIE EI 2002年第2期263-272,共10页
In this paper, the buoyancy, kinetic properties and stability of air floated structures have been studied by theoretical and experimental methods. The equations for calculation of the buoyancy of the air floated buoy ... In this paper, the buoyancy, kinetic properties and stability of air floated structures have been studied by theoretical and experimental methods. The equations for calculation of the buoyancy of the air floated buoy are derived according to the Boyler law and the equilibrium equations of the air floated structure are established. Through simplification of the air floated structure as a single freedom rigid body and spring system, the natural period of heaving and some kinetic properties are discussed. In the stability analysis, the formulas for calculation of the meta centric height are presented. The theoretical results are in good agreement with the data observed from the model test and prototype test. The air buoyancy decrease coefficient presented in this paper has a large influence on the floating state, stability and dynamic properties of the air floated structure. The stability of the air floated structure can also be judged by the parameter of meta centric height, and calculations show that the air floated structure is less stable than the conventional float. 展开更多
关键词 air buoyancy floating properties stability analysis floated structure model test
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Hydrothermal Synthesis,Crystal Structure and Thermal Stability of a Binuclear Copper(Ⅱ) Complex with 3-(Pyridin-2-yl)-1,2,4-triazole 被引量:7
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作者 李昶红 谭雄文 +1 位作者 李薇 杨颖群 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2011年第2期289-292,共4页
One novel binuclear copper(Ⅱ) complex [Cu 2 (Hpt) 2 (CO 3) 2 (H 2 O) 2 ]·H 2 O with copper carbonate and 3-(pyridin-2-yl)-1,2,4-triazole (Hpt) was hydrothermally synthesized and characterized by IR a... One novel binuclear copper(Ⅱ) complex [Cu 2 (Hpt) 2 (CO 3) 2 (H 2 O) 2 ]·H 2 O with copper carbonate and 3-(pyridin-2-yl)-1,2,4-triazole (Hpt) was hydrothermally synthesized and characterized by IR and X-ray diffraction analysis.The complex crystallizes in triclinic,space group P2 1 /n with a=0.6862(1),b=0.7805(1),c=1.1983(2) nm,α=72.03(2),β=107.72(3),γ=75.28(2)o,V=0.5884 nm 3,D c=2.105 g/cm 3,Z=1,F(000)=357,GOOF=1.041,the final R=0.01859 and wR=0.04348.The whole molecule is composed of two cooper ions,two Hpt molecules,two carbonate and three water molecules,forming a binuclear structure.The crystal structure shows that the cooper ion is coordinated with three nitrogen atoms from two Hpt molecules,two oxygen atoms from one carbonic acid and one water molecule,forming a distorted square pyramidal geometry.The TG analysis result shows that the title complex is stable under 131.0 ℃. 展开更多
关键词 copper(Ⅱ) complex hydrothermal synthesis crystal structure thermal stability analysis
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Synthesis,Crystal Structure and Thermal Stability of a One-dimensional Chain Cobalt Coordination Polymer [Co(4,4'-bipy)(2,4,6-TMBA)_2(CH_3CH_2OH)_2]_n 被引量:4
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作者 LI Wei LI Chang-Hong +4 位作者 YANG Ying-Qun CHEN Zhi-Min KUANG Dai-Zhi ZHANG Chun-Hua KANG Yun-Fei 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2006年第7期878-882,共5页
A one-dimensional chain cobalt(Ⅱ) coordination polymer with 2,4,6-trimethyl- benzoic acid, 4,4′-bipyridine and cobalt perchlorate anhydrous has been synthesized and characterized in the mixture solvent of water an... A one-dimensional chain cobalt(Ⅱ) coordination polymer with 2,4,6-trimethyl- benzoic acid, 4,4′-bipyridine and cobalt perchlorate anhydrous has been synthesized and characterized in the mixture solvent of water and alcohol. Crystal data for this complex: monoclinic, space group C2/c, a = 2.3805(8), b = 1.1464(4), c = 1.5807(5) nm, y = 128.435(4)°, V= 3.3791(18) nm^3, Dc = 1.246 g/cm^3, Z = 4, F(000) = 1340, final GooF = 1.009, R = 0.0504 and wR = 0.1287. Structural analysis shows that the cobalt ion is coordinated with two nitrogen atoms of one 4,4′- bipyridine molecule and four oxygen atoms from two 2,4,6-trimethylbenzoic acid molecules and two alcohol molecules, giving a distorted octahedral coordination geometry. The result of TG analysis indicates that the title complex is stable till 200 ℃. 展开更多
关键词 cobalt(Ⅱ) complex crystal structure thermal stability analysis
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Synthesis, Crystal Structure and Thermal Stability of a Nickel(Ⅱ) Complex with Bicycle[2.2.1]-2-hepten-5,6-dicarboxylic Acid 被引量:5
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作者 李薇 李玉林 +1 位作者 李昶红 谭雄文 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2011年第9期1279-1282,共4页
The nickel complex {Ni(2,2-bipy)(H2O)3[C8H11O2(COO)]}(H2O)3 with bicycle-[2.2.1]-2-hepten-5,6-dicarboxylic acid [C7H8(COOH)2] and 2,2'-bipyridine (bipy) as ligands has been synthesized and characterized. ... The nickel complex {Ni(2,2-bipy)(H2O)3[C8H11O2(COO)]}(H2O)3 with bicycle-[2.2.1]-2-hepten-5,6-dicarboxylic acid [C7H8(COOH)2] and 2,2'-bipyridine (bipy) as ligands has been synthesized and characterized. It crystallizes in monoclinic, space group P , with a = 0.74975(3), b = 1.20309(4), c = 1.30593(4) nm, α = 109.861(2), β = 98.519(2), γ = 90.575(2)o, V = 1.09337(7) nm3, Dc = 1.552 g/cm3, Z = 2, F(000) = 524, the final GOOF = 1.064, R = 0.0397 and wR = 0.1171. The crystal structure shows that the nickel ion is coordinated with four oxygen atoms from one bicycle[2.2.1]-2-hepten-5,6-dicarboxylic acid molecule and three water molecules and two nitrogen atoms from the 2,2′-bipyridine molecule, forming a distorted octahedral coordination geometry. The result of TG analysis shows that the title complex is stable under 200.0 ℃. 展开更多
关键词 nickel(Ⅱ) complex crystal structure thermal stability analysis
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Structure and Thermal Stability of a One-dimensional Chain Cobalt Coordination Polymer [Co(phen)(2,4,6-TMBA)_2(H_2O)]_n 被引量:3
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作者 YANG Ying-Qun LI Chang-Hong +3 位作者 LI Wei ZHANG Chun-Hua GUO Dong-Cai KANG Yun-Fei 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2006年第6期752-756,共5页
A one-dimensional chain cobalt(Ⅱ) coordination polymer with 2,4,6-trimethylbenzoic acid, 1,10-phenanthroline and cobalt perchlorate anhydrous has been synthesized in the solvent mixture of water/methanol and charac... A one-dimensional chain cobalt(Ⅱ) coordination polymer with 2,4,6-trimethylbenzoic acid, 1,10-phenanthroline and cobalt perchlorate anhydrous has been synthesized in the solvent mixture of water/methanol and characterized. Crystal data for this complex: tetragonal, space group I41, a = 2.0356(2), c = 1.3779(3) nm, V= 5.7096(15) nm^3, Mr= 581.51,μ(MoKa) = 0.644, Dc = 1.353 g/cm^3, Z = 8, F(000) = 2424, final S = 1.005, R = 0.0404 and wR = 0.0865. The crystal structure shows that the cobalt ion is coordinated with two nitrogen atoms of one 1,10-phenanthroline molecule, three oxygen atoms from three 2,4,6-trimethylbenzoic acid molecules and one water molecule, giving a distorted octahedral coordination geometry. The result of TG analysis indicates that the title complex is stable till 200 ℃. 展开更多
关键词 cobalt(Ⅱ) complex crystal structure thermal stability analysis
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Synthesis,Crystal Structure and Thermal Stability Properties of a Binuclear Copper(Ⅱ) Coordination Polymer {[Cu_2(4,4'-bipy)_2(o-ABA)_4(H_2O)_2][(H_2O)_2]}_n 被引量:3
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作者 刘停 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2010年第2期195-198,共4页
One-dimensional chain copper(Ⅱ) coordination polymer has been synthesized and characterized in the solvent mixture of water and alcohol with o-acetamidobenzoic acid,4,4'-bipyridine and copper perchlorate.It is of ... One-dimensional chain copper(Ⅱ) coordination polymer has been synthesized and characterized in the solvent mixture of water and alcohol with o-acetamidobenzoic acid,4,4'-bipyridine and copper perchlorate.It is of tetragonal,space group P41212 with a=1.57756(10),b= 1.57756(10),c=2.1438(3)nm,V=5.3352(8) nm^3,Dc=1.524 g/cm^3,Z=4,F(000)=2536,R= 0.0479 and wR=0.0979.The crystal structure shows two coordination modes.The copper(1) is coordinated with two nitrogen atoms of one 4,4'-bipyridine molecule and two oxygen atoms from two o-acetamidobenzoic acid molecules,forming a distorted tetrahedral coordination geometry; the copper(2) is coordinated with two nitrogen atoms of one 4,4'-bipyridine molecule,four oxygen atoms from two o-acetamidobenzoic acid molecules and two water molecules,generating a distorted octahedral coordination geometry.The result of TG analysis shows that the title complex is stable below 180.0 ℃. 展开更多
关键词 copper(Ⅱ) coordination polymer crystal structure thermal stability analysis
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Numerical Analysis of Three-Layer Deep Tunnel Composite Structure 被引量:3
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作者 Weiwei Sun Hongping Min +3 位作者 Jianzhong Chen Chao Ruan Yanjun Zhang Lei Wang 《Computer Modeling in Engineering & Sciences》 SCIE EI 2021年第4期223-239,共17页
To date,with the increasing attention of countries to urban drainage system,more and more regions around the world have begun to build water conveyance tunnels,sewage pressure deep tunnels and so on.However,the suffic... To date,with the increasing attention of countries to urban drainage system,more and more regions around the world have begun to build water conveyance tunnels,sewage pressure deep tunnels and so on.However,the sufficient bearing capacity and corrosion resistance of the structure,which can ensure the actual service life and safety of the tunnel,remain to be further improved.Glass Fiber Reinforced Plastics(GFRP)pipe,with light weight,high strength and corrosion resistance,has the potential to be applied to the deep tunnel structure.This paper proposed a new composite structure of deep tunnel lined with GFRP pipe,which consisted of three layers of concrete segment,cement paste and GFRP pipe.A new pipe-soil spring element model was proposed for the pipesoil interaction with gaps.Based on the C3D8R solid model and the Combin39 spring model,the finite element numerical analysis of the internal pressure status and external pressure stability of the structure was carried out.Combined with the checking calculation of the theoretical formula,the reliability of the two finite element models was confirmed.A set of numerical analysis methods for the design and optimization of the three-layer structure was established.The results showed that from the internal GFRP pipe to the outer concrete pipe,the pressure decreased from 0.5 to 0.32 MPa,due to the internal pressure was mainly undertaken by the inner GFRP pipe.The allowable buckling pressure of GFRP pipe under the cover of 5 GPa high modulus cement paste was 2.66 MPa.The application of GFRP pipe not only improves the overall performance of the deep tunnel structure but also improves the construction quality and safety.The three-layer structure built in this work is safe and economical. 展开更多
关键词 GFRP pipe deep tunnel structure finite element analysis internal pressure external pressure stability pipe-soil interaction
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