Rechargeable alkali metal-sulfur(M-S)batteries,including Li/Na/K-S chemistries,have the potential to utilize abundant and low-cost sulfur cathodes yet offer high theoretical energy densities.However,their practical el...Rechargeable alkali metal-sulfur(M-S)batteries,including Li/Na/K-S chemistries,have the potential to utilize abundant and low-cost sulfur cathodes yet offer high theoretical energy densities.However,their practical electrochemical performance is fundamentally limited by the polysulfide shuttle effect.This challenge is particularly exacerbated in Na-S and K-S systems owing to larger metal-ion radii,weaker solvation energies,slower redox kinetics,and greater electrolyte-electrode incompatibilities compared to Li-S batteries.This review presents a comparative analysis of interface engineering strategies designed to suppress the shuttle effect across these three systems.Following a summary of sulfur cathode properties and reaction mechanisms,we systematically examine the origins of polysulfide shuttling.Our analysis progresses from functional separator design and interlayer enhancements to the implementation of solid-state electrolytes for root-cause inhibition.By evaluating interface engineering research specific to Na-S and K-S batteries,we elucidate both shared principles and unique challenges inherent to alkali M-S systems.Finally,we propose multifaceted solutions to achieve shuttlefree operation and enhance overall battery performance,thereby establishing a foundation for future advancements.展开更多
Abstract-Common spatial pattern （CSP） algorithm is a successful tool in feature estimate of brain-computer interface （BCI）. However, CSP is sensitive to outlier and may result in poor outcomes since it is based on...Abstract-Common spatial pattern （CSP） algorithm is a successful tool in feature estimate of brain-computer interface （BCI）. However, CSP is sensitive to outlier and may result in poor outcomes since it is based on pooling the covariance matrices of trials. In this paper, we propose a simple yet effective approach, named common spatial pattern ensemble （CSPE） classifier, to improve CSP performance. Through division of recording channels, multiple CSP filters are constructed. By projection, log-operation, and subtraction on the original signal, an ensemble classifier, majority voting, is achieved and outlier contaminations are alleviated. Experiment results demonstrate that the proposed CSPE classifier is robust to various artifacts and can achieve an average accuracy of 83.02%.展开更多
In order to achieve the data exchanging and sharing in complex hospital information systems, the patients, the hospitals and the doctors were put into an integration platform, and improve the regional healthcare incor...In order to achieve the data exchanging and sharing in complex hospital information systems, the patients, the hospitals and the doctors were put into an integration platform, and improve the regional healthcare incorporating and collaborating, the operators, such as the patients, the regional healthcare departments and community operators were put an uniform platform, the study focused on the design of common interface based on the EMR （electronic medical records） system so as to get the uniform information from anywhere at anytime. In the hospital, we set up the common interface based on the HL7 （health level seven） criterion to connect the different models and among the regional healthcare departments, we set up the common interface based on the middleware technology to connect the different medical management information systems. The design of common interface based on the HL7 engine integrated the platform of all the hospital models, and middleware completed the collaboration applications among the regional healthcare departments. The common interfaces based on HL7 and middleware satisfied the requirements of data and formed in different medical information systems, and complemented the regional healthcare information sharing by the integration platform. It is a feasible solution that supports the mobile nursing and smarter healthcare by the theory analysis and practice application.展开更多
Self-supported nanoarrays have emerged as a promising alternative electrocatalyst for alkaline H_(2)O splitting,owing to their accessible active sites and strongly coupled interfaces with current collectors for improv...Self-supported nanoarrays have emerged as a promising alternative electrocatalyst for alkaline H_(2)O splitting,owing to their accessible active sites and strongly coupled interfaces with current collectors for improved mass transfer and stability.Herein,self-supported crystalline/amorphous NiO/Ni(OH)_(2)nanosheet arrays on nickel foam(NF)are fabricated via an in-situ dissolution-deposition hydrothermal growing of Ni(OH)_(2)nanosheets without additional metal sources assisted by a common Lewis base,EDTA,followed by a rapid calcination at 300℃in air.The as-prepared EDTA-NF-12 h exhibits high OER and HER performance under alkaline conditions,requiring 235 mV and 158 mV,respectively,to reach 10 mA cm^(-2),and the decent performance can be maintained for 24 h without obvious degradation.The dual interfaces,i.e.,the dense crystalline/amorphous interfaces within the NiO/Ni(OH)_(2)nanosheet arrays,as well as the intimate interfaces between nanoarrays and NF,both serve as reaction active sites,facilitate electron transfer,and endow the catalyst with high activity and stability.Furthermore,by applying EDTA-Ni^(2+)and other Lewis bases with varying basicities instead of EDTA,the interfaces with the NF substrate are found to promote the formation of crystalline/amorphous interfaces within the nanosheets.This study offers appealing opportunities for tailoring the electrocatalytic performance of self-supported electrodes via dual interface engineering.展开更多
基金supported by the National Natural Science Foundation of China(52371131)the 10th Youth Talent Lifting Project of the China Association for Science and Technology.
文摘Rechargeable alkali metal-sulfur(M-S)batteries,including Li/Na/K-S chemistries,have the potential to utilize abundant and low-cost sulfur cathodes yet offer high theoretical energy densities.However,their practical electrochemical performance is fundamentally limited by the polysulfide shuttle effect.This challenge is particularly exacerbated in Na-S and K-S systems owing to larger metal-ion radii,weaker solvation energies,slower redox kinetics,and greater electrolyte-electrode incompatibilities compared to Li-S batteries.This review presents a comparative analysis of interface engineering strategies designed to suppress the shuttle effect across these three systems.Following a summary of sulfur cathode properties and reaction mechanisms,we systematically examine the origins of polysulfide shuttling.Our analysis progresses from functional separator design and interlayer enhancements to the implementation of solid-state electrolytes for root-cause inhibition.By evaluating interface engineering research specific to Na-S and K-S batteries,we elucidate both shared principles and unique challenges inherent to alkali M-S systems.Finally,we propose multifaceted solutions to achieve shuttlefree operation and enhance overall battery performance,thereby establishing a foundation for future advancements.
基金supported by the National Natural Science Foundation of China under Grant No. 30525030, 60701015, and 60736029.
文摘Abstract-Common spatial pattern （CSP） algorithm is a successful tool in feature estimate of brain-computer interface （BCI）. However, CSP is sensitive to outlier and may result in poor outcomes since it is based on pooling the covariance matrices of trials. In this paper, we propose a simple yet effective approach, named common spatial pattern ensemble （CSPE） classifier, to improve CSP performance. Through division of recording channels, multiple CSP filters are constructed. By projection, log-operation, and subtraction on the original signal, an ensemble classifier, majority voting, is achieved and outlier contaminations are alleviated. Experiment results demonstrate that the proposed CSPE classifier is robust to various artifacts and can achieve an average accuracy of 83.02%.
文摘In order to achieve the data exchanging and sharing in complex hospital information systems, the patients, the hospitals and the doctors were put into an integration platform, and improve the regional healthcare incorporating and collaborating, the operators, such as the patients, the regional healthcare departments and community operators were put an uniform platform, the study focused on the design of common interface based on the EMR （electronic medical records） system so as to get the uniform information from anywhere at anytime. In the hospital, we set up the common interface based on the HL7 （health level seven） criterion to connect the different models and among the regional healthcare departments, we set up the common interface based on the middleware technology to connect the different medical management information systems. The design of common interface based on the HL7 engine integrated the platform of all the hospital models, and middleware completed the collaboration applications among the regional healthcare departments. The common interfaces based on HL7 and middleware satisfied the requirements of data and formed in different medical information systems, and complemented the regional healthcare information sharing by the integration platform. It is a feasible solution that supports the mobile nursing and smarter healthcare by the theory analysis and practice application.
基金the foundation of Guangdong Engineering Technology Research Center for Hydrogen Energy and Fuel Cells,the Guangdong Provincial Department of Education Innovation Project(No.2022KQNCX056)the Guangdong Basic and Applied Basic Research Foundation(Nos.2022A1515110354 and 2021A1515110582)。
文摘Self-supported nanoarrays have emerged as a promising alternative electrocatalyst for alkaline H_(2)O splitting,owing to their accessible active sites and strongly coupled interfaces with current collectors for improved mass transfer and stability.Herein,self-supported crystalline/amorphous NiO/Ni(OH)_(2)nanosheet arrays on nickel foam(NF)are fabricated via an in-situ dissolution-deposition hydrothermal growing of Ni(OH)_(2)nanosheets without additional metal sources assisted by a common Lewis base,EDTA,followed by a rapid calcination at 300℃in air.The as-prepared EDTA-NF-12 h exhibits high OER and HER performance under alkaline conditions,requiring 235 mV and 158 mV,respectively,to reach 10 mA cm^(-2),and the decent performance can be maintained for 24 h without obvious degradation.The dual interfaces,i.e.,the dense crystalline/amorphous interfaces within the NiO/Ni(OH)_(2)nanosheet arrays,as well as the intimate interfaces between nanoarrays and NF,both serve as reaction active sites,facilitate electron transfer,and endow the catalyst with high activity and stability.Furthermore,by applying EDTA-Ni^(2+)and other Lewis bases with varying basicities instead of EDTA,the interfaces with the NF substrate are found to promote the formation of crystalline/amorphous interfaces within the nanosheets.This study offers appealing opportunities for tailoring the electrocatalytic performance of self-supported electrodes via dual interface engineering.
