The BiOCl/Bi12O17Cl2@MoS2(BOC-MS)composites were successfully synthesized by a facile method at room temperature.The physicochemical properties of the as-obtained samples were characterized by X-ray diffractometer(XRD...The BiOCl/Bi12O17Cl2@MoS2(BOC-MS)composites were successfully synthesized by a facile method at room temperature.The physicochemical properties of the as-obtained samples were characterized by X-ray diffractometer(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray photoelectron spectroscopy(XPS),ultraviolet–visible diffuse reflection spectra(UV–Vis DRS),photoluminescence(PL),Brunauer–Emmett–Teller–Barrett–Joyner–Halenda(BET–BJH),and electron spin resonance(ESR)in detail.Moreover,the in situ diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS)was applied to elucidate the adsorption and photocatalytic reaction mechanism.The optimized BOC-MS-1.0 composites exhibited excellent visible light photocatalytic capability(51.1%)and photochemical stability for removal of NO.Based on the DMPOESR spin trapping,the·O2-radicals andáOH radicals were identified as the main active species generated from BOCMS-1.0 under visible light irradiation.The enhanced photocatalytic performance can be ascribed to the positive synergetic effect of the MoS2 and the effective carrier separation ability.展开更多
The surface species formed in the reaction of NO and NO2 with pre-adsorbed NH 3 over a Fe-ZSM-5 catalyst(1.27 wt.%Fe,SiO2/Al2O3=25)at low temperature(140°C)were studied by in situ diffuse reflectance infrared Fou...The surface species formed in the reaction of NO and NO2 with pre-adsorbed NH 3 over a Fe-ZSM-5 catalyst(1.27 wt.%Fe,SiO2/Al2O3=25)at low temperature(140°C)were studied by in situ diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS).Through using a background spectrum of NH3-saturated Fe-ZSM-5,we clearly observed the formation of common intermediates resulting from the reaction of NO2 or NO+O2 with pre-adsorbed NH3.This presents strong evidence that the oxidation of NO to form surface nitrates and nitrites is the key step for standard SCR at low temperature.In addition,the results suggest that in the SCR reaction at low temperature,the NH^4+ions absorbed on Brønsted acid sites are less active than NH3 adsorbed on Lewis acid sites related to Fe species.展开更多
In situ diffusion reflectance infrared Fourier transform spectroscopy was used to study the water adsorption on mineral oxides （SiO2, a-Al2O3, MgO, Fe2O3, TiO2）. The results showed that all the water adsorption isot...In situ diffusion reflectance infrared Fourier transform spectroscopy was used to study the water adsorption on mineral oxides （SiO2, a-Al2O3, MgO, Fe2O3, TiO2）. The results showed that all the water adsorption isotherms were well fitted with the Brunauer-Emmett-Teller （BET）-Ⅲ type equation, with the calculated monolayers occurring at 24%-30% relative humidity. It showed that about 1-5 layers of water adsorbed on oxides surfaces in ambient relative humidity （20%-90%）. The measured deliquescence relative humidity of NaCl was （74 ± 1）%, which demonstrated that DRIFTS is a useful method for the study the hygroscopic behavior of mineral dust. In addition, the limits of DRIPTS were also discussed.展开更多
A facile hydrothermal method was applied to gain stably and highly efficient CuO-CeO_(2)(denoted as Cu1Ce2)catalyst for toluene oxidation.The changes of surface and inter properties on Cu1Ce2 were investigated compari...A facile hydrothermal method was applied to gain stably and highly efficient CuO-CeO_(2)(denoted as Cu1Ce2)catalyst for toluene oxidation.The changes of surface and inter properties on Cu1Ce2 were investigated comparing with pure CeO_(2)and pure CuO.The formation of Cu-Ce interface promotes the electron transfer between Cu and Ce through Cu^(2+)+Ce^(3+)↔Cu^(+)+Ce^(4+)and leads to high redox properties and mobility of oxygen species.Thus,the Cu1Ce2 catalyst makes up the shortcoming of CeO_(2)and CuO and achieved high catalytic performance with T_(50)=234°C and T_(99)=250°C(the temperature at which 50%and 90%C_(7)H_(8)conversion is obtained,respectively)for toluene oxidation.Different reaction steps and intermediates for toluene oxidation over Cu1Ce2,CeO_(2)and CuO were detected by in situ DRIFTS,the fast benzyl species conversion and preferential transformation of benzoates into carbonates through C=C breaking over Cu1Ce2 should accelerate the reaction.展开更多
Haulage networks are vital to underground mining operations as they constitute the arteries through which blasted ore is transported to surface. In the sublevel stoping method and its variations, haulage drifts are ex...Haulage networks are vital to underground mining operations as they constitute the arteries through which blasted ore is transported to surface. In the sublevel stoping method and its variations, haulage drifts are excavated in advance near the ore block that will be mined out. Numerical modeling is a technique that is frequently employed to assess the redistribution of mining-induced stresses, and to compare the impact of different stope sequence scenarios on haulage network stability. In this study,typical geological settings in the Canadian Shield were replicated in a numerical model with a steeplydipping tabular orebody striking EW. All other formations trended in the same direction except for two dykes on either side of the orebody with a WNW-ESE strike. Rock mass properties and in situ stress measurements from a case study mine were used to calibrate the model. Drifts and crosscuts were excavated in the footwall and two stope sequence scenarios-a diminishing pillar and a center-out one-were implemented in 24 mining stages. A combined volumetric-numerical analysis was conducted for two active levels by comparing the extent of unstable rock mass at each stage using shear,compressive, and tensile instability criteria. Comparisons were made between the orebody and the host rock, between the footwall and hanging wall, and between the two stope sequence scenarios. It was determined that in general, the center-out option provided a larger volume of instability with the shear criterion when compared to the diminishing pillar one(625,477 m~3 compared to 586,774 m~3 in the orebody; 588 m~3 compared to 403 m~3 in the host rock). However, the reverse was true for tensile(134,298 m~3 compared to 128,834 m~3 in the orebody; 91,347 m~3 compared to 67,655 m~3 in the host rock)instability where the diminishing pillar option had the more voluminous share.展开更多
A series of Ba/CeO2 catalysts with different Ba loading amounts were prepared by incipient wetness impregnation. Their NOx adsorption behaviors under NO and NO＋O2 conditions were investigated by in situ DRIFTS. It wa...A series of Ba/CeO2 catalysts with different Ba loading amounts were prepared by incipient wetness impregnation. Their NOx adsorption behaviors under NO and NO＋O2 conditions were investigated by in situ DRIFTS. It was found that NOx was ad-sorbed and stored in the form of nitrites and nitrates on both Ba and Ce sites on the surface of the catalysts. The less thermally stable BaCO3 was suggested to be the main active phase for NOx trapping. Ceria served primarily as an oxygen supplier in the absence of O2, and the reaction from nitrites to nitrates on Ba sites was the key step in this case. In the presence of O2, however, gaseous O2 became the main oxygen source. The NOx adsorption capacity of the catalyst was dominated by the Ba content. Moreover, the stability of ni-trites and nitrates formed on Ce sites was found to be lower than those formed on Ba sites which existed in the form of the ionic bar-ium nitrate species.展开更多
In-situ DRIFTS was used to study the deep oxidation of propane, a side reaction during propane oxidative dehydrogenation to propene. Strong adsorption of propene was supposed to be the main reason for the deep oxidati...In-situ DRIFTS was used to study the deep oxidation of propane, a side reaction during propane oxidative dehydrogenation to propene. Strong adsorption of propene was supposed to be the main reason for the deep oxidation. It was found that gaseous oxygen in the feed and the reaction temperature had great influence on the reaction. To obtain a relative high selectivity to propene, the reaction temperature should be maintained at 150-250℃ with a proper content of gaseous oxygen in the feed for a certain catalyst and some modifiers which could weaken the adsorption of propene on the catalyst surface would be favorable.展开更多
A novel SrSn(OH)_(6) photocatalyst with large plate and particle size were synthesized via a facile chemical precipitation method. The photocatalytic activity of the SrSn(OH)_(6) was evaluated by the removal of NO at ...A novel SrSn(OH)_(6) photocatalyst with large plate and particle size were synthesized via a facile chemical precipitation method. The photocatalytic activity of the SrSn(OH)_(6) was evaluated by the removal of NO at ppb level under UV light irradiation. Based on the ESR measurements, SrSn(OH)_(6) photocatalyst was found to have the ability to generate the main active species of O_(2)^(·-), ^(·)OH and ^(1)O_(2) during the photocatalytic process. Moreover, SrSn(OH)_(6) photocatalyst not only exhibits high photocatalytic activity for NO removal (79.6%), but also has good stability after five cycles. The in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) was used to investigate the NO_(x) transfer pathway and the intermediate products distribution during the adsorption and photocatalytic NO oxidation process. The present work not only provides an efficient material for air pollutants purification at room temperature but also in-depth understanding of the mechanism involved in the photocatalytic NO removal process.展开更多
This paper presents results of thermoanalytical and structural research on phenolic binder used in foundry for the preparation of moulding sand. The binder has been prepared based on resole type phenolic resin with th...This paper presents results of thermoanalytical and structural research on phenolic binder used in foundry for the preparation of moulding sand. The binder has been prepared based on resole type phenolic resin with the addition of ester hardener. The aim of the study was to determine the structural changes taking place in the phenolic binder under the influence of temperature. Results show that in the investigated range of temperatures, phenolic binder exhibits three exothermic thermal effects accompanying the decomposition process. The test results using the Diffuse Reflectance Infrared Fourier Transform Spectroscopy(DRIFTS) technique show that the addition of a hardener stabilizes the binder structure within methylene bridges. The reduction in the reaction rate observed in the DTA curve at about 330 °C can be associated with the formation of gaseous products by decomposition of the binder or, as suggested by the literature data, the formation of triple bonds and CN-HCN groups.展开更多
The effect of poloidal E × B and diamagnetic drifts in edge plasma of Small Size Divertor (SSD) Tokamak is studied with two-dimensional B2SO- LPS-0.5.2D fluid transport code. The simulation results show the follo...The effect of poloidal E × B and diamagnetic drifts in edge plasma of Small Size Divertor (SSD) Tokamak is studied with two-dimensional B2SO- LPS-0.5.2D fluid transport code. The simulation results show the following: 1) For normal toroidal magnetic field, the increasing of core plasma density leads to large divertor asymmetries due to poloidal E × B and diamagnetic drifts. 2) Switching on the E × B and diamagnetic drifts leads to large change in poloidal distribution of radial electric field and induced counter-clockwise circulation (flow) around the x-point. 3) Switching on the E × B and diamagnetic drifts leads to the structure of poloidal distribution of radial electric field is nonmonotonic which responsible for negative spikes. 4) Switching on the E × B and diamagnetic drifts in vicinity of separatrix leads to the structure of poloidal distribution of radial electric field that has viscous layer. 5) Switching on the E × B and diamagnetic drifts results in torque generation. This torque spins up the toroidal rotation. 6) The E × B drift velocity depends on the plasma temperature heating and doesn't depend on plasma density.展开更多
The ＂Old drifts＂ faces the problem of old-age pension under the double background of leaving the country and relocatingfrom the place of migration. And with the increase in the number of ＂old drifting families.＂ t...The ＂Old drifts＂ faces the problem of old-age pension under the double background of leaving the country and relocatingfrom the place of migration. And with the increase in the number of ＂old drifting families.＂ the situation continues to grow. Through the analysis of the personal reasons and social system reasons of the＂ Old Floating Clan＂ pension gurus, the author proposes that the ＂Old Clan＂ old-age pension will be effective by realizing the economic foundation, actively re-socializing, promoting social co-ordination, introducing additional insurance types, and participating in multiple subjects, way, In order to protect the ＂old drift＂ off-farm elderly rights and interests.展开更多
A new detector array characterized by compact structure and large solid-angle coverage was designed for radioactive ion beam(RIB)experiments and measuring multi-particle correlations.A Monte Carlo simulation was perfo...A new detector array characterized by compact structure and large solid-angle coverage was designed for radioactive ion beam(RIB)experiments and measuring multi-particle correlations.A Monte Carlo simulation was performed to explore the effects of beam drifts in different directions and distances on the angular distribution of the Rutherford scattering,as measured by the detector array.The results indicate that when the beam drift distance is less than 2.0 mm,the symmetry of the detector array can maintain a count error of less than 5%.This confirms the property of the detector array for RIB experiments.Furthermore,the simulation was validated through the elastic scattering angular distributions of 6;7 Li measured by the detector array in 6;7Li t209 Bi experiments at different energies.展开更多
In order to seek the economical, practical and effective method of obtaining the thickness of broken rock zone, an emerging intelligent prediction method with adaptive neuro-fuzzy inference system (ANFIS) was introduc...In order to seek the economical, practical and effective method of obtaining the thickness of broken rock zone, an emerging intelligent prediction method with adaptive neuro-fuzzy inference system (ANFIS) was introduced into the thickness prediction. And the software with functions of creating and applying prediction systems was devel- oped on the platform of MATLAB6.5. The software was used to predict the broken rock zone thickness of drifts at Li- angbei coal mine, Xinlong Company of Coal Industry in Xuchang city of Henan province. The results show that the predicted values accord well with the in situ measured ones. Thereby the validity of the software is validated and it provides a new approach to obtaining the broken zone thickness.展开更多
The effects of radial and poloidal E×B drifts in the scrape-off layer （SOL） of a limiter tokamak are studied with a one-dimensional fluid code. The transport equations are solved in the poloidal direction with ...The effects of radial and poloidal E×B drifts in the scrape-off layer （SOL） of a limiter tokamak are studied with a one-dimensional fluid code. The transport equations are solved in the poloidal direction with the radial influxes as the source terms. The simulation results show that in the high recycling regime, the effect of the radial E×B drift on plasma density tends to be stronger than that of the poloidal E × B drift. In the sheath-limited regime, the effects of the radial E × B drift and poloidal E × B drift on plasma density are almost equally important. Considering the influence on the electron temperature, the poloidal E × B drift tends to be more important than the radial E × B drift in both the high recycling regime and sheath-limited regime. For the normal By, the poloidal E × B drift tends to raise the pressure at the low field side while the radial E × B drift favours the high field side. The simulation results also show that the E × B drift influences the asymmetries on the parameter distributions at the high field side and low field side, and the distributions are much more symmetric with the field reversal.展开更多
The stability of the magnetic fields is of vital importance to the success of the precision experiments conducted in the experimental Cooler Storage Ring(CSRe)in Lanzhou.In the CSRe,the electromagnets are cooled using...The stability of the magnetic fields is of vital importance to the success of the precision experiments conducted in the experimental Cooler Storage Ring(CSRe)in Lanzhou.In the CSRe,the electromagnets are cooled using room-temperature water.We monitored the magnetic field strength B of one of the dipole magnets,as well as the DC current I of the power supply and the temperature T of the cooling water for a long term.展开更多
Consider the following McKean-Vlasov SDE:dXt=√2dWt+∫R_(d)K(t,Xt-y)μX_(t)(dy)dt,X_(0)=X,whereμXt stands forthedistributionof Xt and K(t,x):R_(+)×R^(d)→is a time-dependent divergence free vector field.Under th...Consider the following McKean-Vlasov SDE:dXt=√2dWt+∫R_(d)K(t,Xt-y)μX_(t)(dy)dt,X_(0)=X,whereμXt stands forthedistributionof Xt and K(t,x):R_(+)×R^(d)→is a time-dependent divergence free vector field.Under the assumption K∈L_(x)^(p)with weak solutions to the above SDE.As an application,we provide a new proof for the existence of weak solutions to 2D Navier-Stokes equations with measure as initial vorticity.展开更多
基金financially supported by the National Natural Science Foundation of China (Nos. 51708078 and 41801063)the Natural Science Foundation of Chongqing (No. 2018jcyjA1040)
文摘The BiOCl/Bi12O17Cl2@MoS2(BOC-MS)composites were successfully synthesized by a facile method at room temperature.The physicochemical properties of the as-obtained samples were characterized by X-ray diffractometer(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray photoelectron spectroscopy(XPS),ultraviolet–visible diffuse reflection spectra(UV–Vis DRS),photoluminescence(PL),Brunauer–Emmett–Teller–Barrett–Joyner–Halenda(BET–BJH),and electron spin resonance(ESR)in detail.Moreover,the in situ diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS)was applied to elucidate the adsorption and photocatalytic reaction mechanism.The optimized BOC-MS-1.0 composites exhibited excellent visible light photocatalytic capability(51.1%)and photochemical stability for removal of NO.Based on the DMPOESR spin trapping,the·O2-radicals andáOH radicals were identified as the main active species generated from BOCMS-1.0 under visible light irradiation.The enhanced photocatalytic performance can be ascribed to the positive synergetic effect of the MoS2 and the effective carrier separation ability.
基金This work was financially supported by the National Natural Science Foundation of China(Nos.21777174 and 21637005).
文摘The surface species formed in the reaction of NO and NO2 with pre-adsorbed NH 3 over a Fe-ZSM-5 catalyst(1.27 wt.%Fe,SiO2/Al2O3=25)at low temperature(140°C)were studied by in situ diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS).Through using a background spectrum of NH3-saturated Fe-ZSM-5,we clearly observed the formation of common intermediates resulting from the reaction of NO2 or NO+O2 with pre-adsorbed NH3.This presents strong evidence that the oxidation of NO to form surface nitrates and nitrites is the key step for standard SCR at low temperature.In addition,the results suggest that in the SCR reaction at low temperature,the NH^4+ions absorbed on Brønsted acid sites are less active than NH3 adsorbed on Lewis acid sites related to Fe species.
基金supported by the National Natural Science Foundation of China (No.20877084,20937004)the Chinese Academy of Sciences (No.KZCX2-YW-Q02-03)
文摘In situ diffusion reflectance infrared Fourier transform spectroscopy was used to study the water adsorption on mineral oxides （SiO2, a-Al2O3, MgO, Fe2O3, TiO2）. The results showed that all the water adsorption isotherms were well fitted with the Brunauer-Emmett-Teller （BET）-Ⅲ type equation, with the calculated monolayers occurring at 24%-30% relative humidity. It showed that about 1-5 layers of water adsorbed on oxides surfaces in ambient relative humidity （20%-90%）. The measured deliquescence relative humidity of NaCl was （74 ± 1）%, which demonstrated that DRIFTS is a useful method for the study the hygroscopic behavior of mineral dust. In addition, the limits of DRIPTS were also discussed.
基金financially supported by the China Postdoctoral Science Foundation(No.2018M643090)the National Natural Science Foundation of China(No.52000077)+3 种基金the National Key Research and Development Project of Research(No.2017YFC0212805)the National Natural Science Foundation of China(No.51878292)the Natural Science Foundation of Guangdong Province,China(No.2015B020236002)the China Postdoctoral Science Foundation(No.2020M682715).
文摘A facile hydrothermal method was applied to gain stably and highly efficient CuO-CeO_(2)(denoted as Cu1Ce2)catalyst for toluene oxidation.The changes of surface and inter properties on Cu1Ce2 were investigated comparing with pure CeO_(2)and pure CuO.The formation of Cu-Ce interface promotes the electron transfer between Cu and Ce through Cu^(2+)+Ce^(3+)↔Cu^(+)+Ce^(4+)and leads to high redox properties and mobility of oxygen species.Thus,the Cu1Ce2 catalyst makes up the shortcoming of CeO_(2)and CuO and achieved high catalytic performance with T_(50)=234°C and T_(99)=250°C(the temperature at which 50%and 90%C_(7)H_(8)conversion is obtained,respectively)for toluene oxidation.Different reaction steps and intermediates for toluene oxidation over Cu1Ce2,CeO_(2)and CuO were detected by in situ DRIFTS,the fast benzyl species conversion and preferential transformation of benzoates into carbonates through C=C breaking over Cu1Ce2 should accelerate the reaction.
基金financially supported by the Natural Science and Engineering Research Council of Canada(NSERC) with grant No.223079
文摘Haulage networks are vital to underground mining operations as they constitute the arteries through which blasted ore is transported to surface. In the sublevel stoping method and its variations, haulage drifts are excavated in advance near the ore block that will be mined out. Numerical modeling is a technique that is frequently employed to assess the redistribution of mining-induced stresses, and to compare the impact of different stope sequence scenarios on haulage network stability. In this study,typical geological settings in the Canadian Shield were replicated in a numerical model with a steeplydipping tabular orebody striking EW. All other formations trended in the same direction except for two dykes on either side of the orebody with a WNW-ESE strike. Rock mass properties and in situ stress measurements from a case study mine were used to calibrate the model. Drifts and crosscuts were excavated in the footwall and two stope sequence scenarios-a diminishing pillar and a center-out one-were implemented in 24 mining stages. A combined volumetric-numerical analysis was conducted for two active levels by comparing the extent of unstable rock mass at each stage using shear,compressive, and tensile instability criteria. Comparisons were made between the orebody and the host rock, between the footwall and hanging wall, and between the two stope sequence scenarios. It was determined that in general, the center-out option provided a larger volume of instability with the shear criterion when compared to the diminishing pillar one(625,477 m~3 compared to 586,774 m~3 in the orebody; 588 m~3 compared to 403 m~3 in the host rock). However, the reverse was true for tensile(134,298 m~3 compared to 128,834 m~3 in the orebody; 91,347 m~3 compared to 67,655 m~3 in the host rock)instability where the diminishing pillar option had the more voluminous share.
基金supported by National Natural Science Foundation of China(51202116)
文摘A series of Ba/CeO2 catalysts with different Ba loading amounts were prepared by incipient wetness impregnation. Their NOx adsorption behaviors under NO and NO＋O2 conditions were investigated by in situ DRIFTS. It was found that NOx was ad-sorbed and stored in the form of nitrites and nitrates on both Ba and Ce sites on the surface of the catalysts. The less thermally stable BaCO3 was suggested to be the main active phase for NOx trapping. Ceria served primarily as an oxygen supplier in the absence of O2, and the reaction from nitrites to nitrates on Ba sites was the key step in this case. In the presence of O2, however, gaseous O2 became the main oxygen source. The NOx adsorption capacity of the catalyst was dominated by the Ba content. Moreover, the stability of ni-trites and nitrates formed on Ce sites was found to be lower than those formed on Ba sites which existed in the form of the ionic bar-ium nitrate species.
基金supported by the National Natural Science Foundation of China (20576045)the Program for New Century Excellent Talentsin University (NCET-06-740)
文摘In-situ DRIFTS was used to study the deep oxidation of propane, a side reaction during propane oxidative dehydrogenation to propene. Strong adsorption of propene was supposed to be the main reason for the deep oxidation. It was found that gaseous oxygen in the feed and the reaction temperature had great influence on the reaction. To obtain a relative high selectivity to propene, the reaction temperature should be maintained at 150-250℃ with a proper content of gaseous oxygen in the feed for a certain catalyst and some modifiers which could weaken the adsorption of propene on the catalyst surface would be favorable.
基金financially supported by the National Natural Science Foundation of China (No. 51708078)the Science and Technology Research Program of Chongqing Municipal Education Commission (No. KJZD-K201900502)+1 种基金the Natural Science Foundation of Chongqing (No. 2018jcyj A1040)the Innovative Research Team of Chongqing (No. CQYC201903221)。
文摘A novel SrSn(OH)_(6) photocatalyst with large plate and particle size were synthesized via a facile chemical precipitation method. The photocatalytic activity of the SrSn(OH)_(6) was evaluated by the removal of NO at ppb level under UV light irradiation. Based on the ESR measurements, SrSn(OH)_(6) photocatalyst was found to have the ability to generate the main active species of O_(2)^(·-), ^(·)OH and ^(1)O_(2) during the photocatalytic process. Moreover, SrSn(OH)_(6) photocatalyst not only exhibits high photocatalytic activity for NO removal (79.6%), but also has good stability after five cycles. The in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) was used to investigate the NO_(x) transfer pathway and the intermediate products distribution during the adsorption and photocatalytic NO oxidation process. The present work not only provides an efficient material for air pollutants purification at room temperature but also in-depth understanding of the mechanism involved in the photocatalytic NO removal process.
文摘This paper presents results of thermoanalytical and structural research on phenolic binder used in foundry for the preparation of moulding sand. The binder has been prepared based on resole type phenolic resin with the addition of ester hardener. The aim of the study was to determine the structural changes taking place in the phenolic binder under the influence of temperature. Results show that in the investigated range of temperatures, phenolic binder exhibits three exothermic thermal effects accompanying the decomposition process. The test results using the Diffuse Reflectance Infrared Fourier Transform Spectroscopy(DRIFTS) technique show that the addition of a hardener stabilizes the binder structure within methylene bridges. The reduction in the reaction rate observed in the DTA curve at about 330 °C can be associated with the formation of gaseous products by decomposition of the binder or, as suggested by the literature data, the formation of triple bonds and CN-HCN groups.
文摘The effect of poloidal E × B and diamagnetic drifts in edge plasma of Small Size Divertor (SSD) Tokamak is studied with two-dimensional B2SO- LPS-0.5.2D fluid transport code. The simulation results show the following: 1) For normal toroidal magnetic field, the increasing of core plasma density leads to large divertor asymmetries due to poloidal E × B and diamagnetic drifts. 2) Switching on the E × B and diamagnetic drifts leads to large change in poloidal distribution of radial electric field and induced counter-clockwise circulation (flow) around the x-point. 3) Switching on the E × B and diamagnetic drifts leads to the structure of poloidal distribution of radial electric field is nonmonotonic which responsible for negative spikes. 4) Switching on the E × B and diamagnetic drifts in vicinity of separatrix leads to the structure of poloidal distribution of radial electric field that has viscous layer. 5) Switching on the E × B and diamagnetic drifts results in torque generation. This torque spins up the toroidal rotation. 6) The E × B drift velocity depends on the plasma temperature heating and doesn't depend on plasma density.
文摘The ＂Old drifts＂ faces the problem of old-age pension under the double background of leaving the country and relocatingfrom the place of migration. And with the increase in the number of ＂old drifting families.＂ the situation continues to grow. Through the analysis of the personal reasons and social system reasons of the＂ Old Floating Clan＂ pension gurus, the author proposes that the ＂Old Clan＂ old-age pension will be effective by realizing the economic foundation, actively re-socializing, promoting social co-ordination, introducing additional insurance types, and participating in multiple subjects, way, In order to protect the ＂old drift＂ off-farm elderly rights and interests.
基金the National Natural Science Foundation of China(Nos.11635015,U1832130,and 11975040)the State Key Laboratory of Software Development Environment(SKLSDE-2020ZX-16)+1 种基金the Continuous Basic Scientific Research Project(No.WDJC-2019-13)the Leading Innovation Project(Nos.LC192209000701 and LC202309000201).
文摘A new detector array characterized by compact structure and large solid-angle coverage was designed for radioactive ion beam(RIB)experiments and measuring multi-particle correlations.A Monte Carlo simulation was performed to explore the effects of beam drifts in different directions and distances on the angular distribution of the Rutherford scattering,as measured by the detector array.The results indicate that when the beam drift distance is less than 2.0 mm,the symmetry of the detector array can maintain a count error of less than 5%.This confirms the property of the detector array for RIB experiments.Furthermore,the simulation was validated through the elastic scattering angular distributions of 6;7 Li measured by the detector array in 6;7Li t209 Bi experiments at different energies.
基金Projects 50474063 and 50490273 supported by National Natural Science Foundation of China
文摘In order to seek the economical, practical and effective method of obtaining the thickness of broken rock zone, an emerging intelligent prediction method with adaptive neuro-fuzzy inference system (ANFIS) was introduced into the thickness prediction. And the software with functions of creating and applying prediction systems was devel- oped on the platform of MATLAB6.5. The software was used to predict the broken rock zone thickness of drifts at Li- angbei coal mine, Xinlong Company of Coal Industry in Xuchang city of Henan province. The results show that the predicted values accord well with the in situ measured ones. Thereby the validity of the software is validated and it provides a new approach to obtaining the broken zone thickness.
基金supported by National Natural Science Foundation of China (No. 10135020)
文摘The effects of radial and poloidal E×B drifts in the scrape-off layer （SOL） of a limiter tokamak are studied with a one-dimensional fluid code. The transport equations are solved in the poloidal direction with the radial influxes as the source terms. The simulation results show that in the high recycling regime, the effect of the radial E×B drift on plasma density tends to be stronger than that of the poloidal E × B drift. In the sheath-limited regime, the effects of the radial E × B drift and poloidal E × B drift on plasma density are almost equally important. Considering the influence on the electron temperature, the poloidal E × B drift tends to be more important than the radial E × B drift in both the high recycling regime and sheath-limited regime. For the normal By, the poloidal E × B drift tends to raise the pressure at the low field side while the radial E × B drift favours the high field side. The simulation results also show that the E × B drift influences the asymmetries on the parameter distributions at the high field side and low field side, and the distributions are much more symmetric with the field reversal.
基金CAS Young Scholar of Regional Development([2023]15)CAS Project for Young Scientists in Basic Research(YSBR-002)。
文摘The stability of the magnetic fields is of vital importance to the success of the precision experiments conducted in the experimental Cooler Storage Ring(CSRe)in Lanzhou.In the CSRe,the electromagnets are cooled using room-temperature water.We monitored the magnetic field strength B of one of the dipole magnets,as well as the DC current I of the power supply and the temperature T of the cooling water for a long term.
基金supported by NNSFC Grant of China(No.11731009,12131019)the DFG through the CRC 1283“Taming uncertainty and profiting from randomness and low regularity in analysis,stochastics and their applications”.
文摘Consider the following McKean-Vlasov SDE:dXt=√2dWt+∫R_(d)K(t,Xt-y)μX_(t)(dy)dt,X_(0)=X,whereμXt stands forthedistributionof Xt and K(t,x):R_(+)×R^(d)→is a time-dependent divergence free vector field.Under the assumption K∈L_(x)^(p)with weak solutions to the above SDE.As an application,we provide a new proof for the existence of weak solutions to 2D Navier-Stokes equations with measure as initial vorticity.
