The reactions of lithiated 2-ferrocenyl-1,3-dithiane with alkyl carbonyl compounds are studied. Fifteen of title compounds which are new ferrocene derivatives were synthesized and structurally characterized by element...The reactions of lithiated 2-ferrocenyl-1,3-dithiane with alkyl carbonyl compounds are studied. Fifteen of title compounds which are new ferrocene derivatives were synthesized and structurally characterized by elemental analysis, IR and 1H NMR spectra. The 1H NMR spectra of the dithiane compounds are briefly discussed.展开更多
There has been now a lot of work done on the 1,3-dithianes chemistry. As a synthetic reagent, 1,3-dithiane has been widely applied to organic syntheses. But no report has been found in literature on the synthesis of d...There has been now a lot of work done on the 1,3-dithianes chemistry. As a synthetic reagent, 1,3-dithiane has been widely applied to organic syntheses. But no report has been found in literature on the synthesis of derivatives of ferrocene by this versatile method, except that by Reuter et al. In our work a series of new ferrocenyl derivatives, 2-ferrocenyl-2-(1-hydroxyalkyl)-1, 3-dithianes have been synthesized through the following synthetic route:展开更多
基金Supported by the National Natural Science Foundation of China
文摘The reactions of lithiated 2-ferrocenyl-1,3-dithiane with alkyl carbonyl compounds are studied. Fifteen of title compounds which are new ferrocene derivatives were synthesized and structurally characterized by elemental analysis, IR and 1H NMR spectra. The 1H NMR spectra of the dithiane compounds are briefly discussed.
文摘There has been now a lot of work done on the 1,3-dithianes chemistry. As a synthetic reagent, 1,3-dithiane has been widely applied to organic syntheses. But no report has been found in literature on the synthesis of derivatives of ferrocene by this versatile method, except that by Reuter et al. In our work a series of new ferrocenyl derivatives, 2-ferrocenyl-2-(1-hydroxyalkyl)-1, 3-dithianes have been synthesized through the following synthetic route:
