The cyclomercurated ferrocenylimines containing heterocyclic ring were prepared by the condensation of cyclomercuration of acylferrocene with the appropriate heterocyclic amine. This procedure provides an efficient m...The cyclomercurated ferrocenylimines containing heterocyclic ring were prepared by the condensation of cyclomercuration of acylferrocene with the appropriate heterocyclic amine. This procedure provides an efficient method for the synthesis of cyclomerucurated ferroceny- limines containing heterocyclic ring which are difficultly synthesized by the conventional method. The reaction mechanism is proposed.展开更多
S A new cyclomercurated ferrocenylketimine containing pyridyl ring ([HgCl(5- C5H3C(CH3)=N-3-C5H4N)Fe(5-C5H5)]紺H2Cl2, Mr = 581.66) was synthesized and its molecular structure has been confirmed by IR, elemental analys...S A new cyclomercurated ferrocenylketimine containing pyridyl ring ([HgCl(5- C5H3C(CH3)=N-3-C5H4N)Fe(5-C5H5)]紺H2Cl2, Mr = 581.66) was synthesized and its molecular structure has been confirmed by IR, elemental analysis, 1H-NMR and X-ray crystal structure analysis. It is of monoclinic system, space group P21/c with a = 9.213(2), b = 17.479(4), c = 11.510(2) ? b = 100.32(3)o, V = 1823.7(6) 3, Z = 4, C17.5H16Cl2FeHgN2, Dc = 2.119 g/cm3, m = 9.497 mm-1, F(000) = 1100, R = 0.0436 and wR = 0.0987. The independent reflections are 3527, of which 3153 with I ≥ 2s(I) were observed. The compound contains a five-membered metallocycle. The mercury atom is bonded with the 2-position of substituted cyclopentadienyl ring (Cp), and coordinated weakly to the N atom of imino group. The pyridyl ring is almost perpendicular to the substituted Cp which is nearly coplanar with the metallocycle. The Hg(1)C(1) and Hg(1)Cl(1) bond lengths are 2.050(8) and 2.321(2) ? respectively.展开更多
基金We are grateful to the National Natural Science Foundation of China(project 20072034)the Natural Science Foundation of Henan Province for the financial support.
文摘The cyclomercurated ferrocenylimines containing heterocyclic ring were prepared by the condensation of cyclomercuration of acylferrocene with the appropriate heterocyclic amine. This procedure provides an efficient method for the synthesis of cyclomerucurated ferroceny- limines containing heterocyclic ring which are difficultly synthesized by the conventional method. The reaction mechanism is proposed.
基金This work was supported by NNSFC (No. 20072034) and NSF of Henan province
文摘S A new cyclomercurated ferrocenylketimine containing pyridyl ring ([HgCl(5- C5H3C(CH3)=N-3-C5H4N)Fe(5-C5H5)]紺H2Cl2, Mr = 581.66) was synthesized and its molecular structure has been confirmed by IR, elemental analysis, 1H-NMR and X-ray crystal structure analysis. It is of monoclinic system, space group P21/c with a = 9.213(2), b = 17.479(4), c = 11.510(2) ? b = 100.32(3)o, V = 1823.7(6) 3, Z = 4, C17.5H16Cl2FeHgN2, Dc = 2.119 g/cm3, m = 9.497 mm-1, F(000) = 1100, R = 0.0436 and wR = 0.0987. The independent reflections are 3527, of which 3153 with I ≥ 2s(I) were observed. The compound contains a five-membered metallocycle. The mercury atom is bonded with the 2-position of substituted cyclopentadienyl ring (Cp), and coordinated weakly to the N atom of imino group. The pyridyl ring is almost perpendicular to the substituted Cp which is nearly coplanar with the metallocycle. The Hg(1)C(1) and Hg(1)Cl(1) bond lengths are 2.050(8) and 2.321(2) ? respectively.
