The soil-bentonite(SB)cut-off wall has been widely considered a vertical barrier to effectively control the migration of pollutants in contaminated sites.Recently,active porous materials have been used as a promising ...The soil-bentonite(SB)cut-off wall has been widely considered a vertical barrier to effectively control the migration of pollutants in contaminated sites.Recently,active porous materials have been used as a promising candidate amendment for mitigating chemical degradation and improving the retardation capacity of the SB cut-off wall.In this study,the silty clay from a typical Cr(VI)contaminated site was selected as the body material of the SB cut-off wall,and zeolite and active carbon were used as the modifiers of the silty clay-bentonite backfills,respectively.The impact of the two modifiers on the engineering properties of the backfills was investigated through a series of slump tests,consolidation tests,hydraulic conductivity tests,and microstructure tests.The experimental results demonstrated that the slump curves closely exhibited a linear relationship between standard slump and moisture content.Meanwhile,bentonite could improve the optimum moisture content of the backfills,while the addition of the two modifiers yielded the opposite outcome.As the bentonite content increased,the compression index of the backfills significantly increased,while the hydraulic conductivity decreased.At a given bentonite content of 5%,the addition of zeolite or active carbon resulted in a reduction in the compression index and initial void ratio,while exhibiting minimal impact on the hydraulic conductivity.Scanning electron microscope(SEM)observations indicated that the silty clay-bentonite backfills became increasingly loose with increasing bentonite content,owing to the filling and expansion of dispersed bentonite layers.The amendment of zeolite or active carbon was able to decrease the backfill volume by promoting the agglomeration of layered bentonite.The findings of this study will be useful for the optimal selection of backfill materials and the performance evaluation of the cut-off wall.展开更多
Uneven lithium deposition leading to lithium dendrite growth severely hampers the application of lithium-metal batteries.Modifying the collector with lithiophilic materials helps improve lithium deposition.For lithoph...Uneven lithium deposition leading to lithium dendrite growth severely hampers the application of lithium-metal batteries.Modifying the collector with lithiophilic materials helps improve lithium deposition.For lithophilic materials to modify the collector,the choice of cut-off voltage is very important.While excessively high cut-off voltages may compromise the stability of the modified layer and consequently disrupt ordered lithium deposition,conventional approaches typically employ lower cut-off voltages(particularly 0.1 V)to maintain modification layer stability.However,the 0.1 V cut-off voltage results in incomplete lithium stripping from the lithiophilic material surface.This phenomenon significantly diminishes the lithiophilic properties of the modified layer and consequently leads to substantial nucleation overpotential.Here,we propose to use a moderate cut-voltage stimulation effect to slow down the interfacial shielding effect of residual lithium metal on lithiophilic materials.By optimizing the cut-off voltage for the Cu@Sb_(2)S_(3)collector,the stability of the modified layer can be preserved while enabling the complete stripping of lithium metal from the surface of the lithophilic material.The asymmetric cell received the highest Coulombic efficiency(CE)when the lithium stripping cut-off voltage was set at 0.5 V relative to 0.1 and 2.0 V.At a current density of 1 mA cm^(-2)and a deposition capacity of1 m A h cm^(-2),the CE remained 98.6% at a cut-off voltage of 0.5 V after 140 cycles in an ether electrolyte without lithium nitrate.展开更多
Because of actual requirement,shield machine always excavates with an inclined angle in longitudinal direction.Since many previous studies mainly focus on the face stability of the horizontal shield tunnel,the effects...Because of actual requirement,shield machine always excavates with an inclined angle in longitudinal direction.Since many previous studies mainly focus on the face stability of the horizontal shield tunnel,the effects of tensile strength cut-off and pore water pressure on the face stability of the longitudinally inclined shield tunnel are not well investigated.A failure mechanism of a longitudinally inclined shield tunnel face is constructed based on the spatial discretization technique and the tensile strength cut-off criterion is introduced to modify the constructed failure mechanism.The pore water pressure is introduced as an external force into the equation of virtual work and the objective function of the chamber pressure of the shield machine is obtained.Moreover,the critical chamber pressure of the longitudinally inclined shield tunnel is computed by optimal calculation.Parametric analysis indicates that both tensile strength cut-off and pore water pressure have a significant impact on the chamber pressure and the range of the collapse block.Finally,the theoretical results are compared with the numerical results calculated by FLAC3D software which proves that the proposed approach is effective.展开更多
The lack of soft magnetic composites with high power density in MHz frequency range has become an obstacle in the efficient operation of the electrical and electronic equipments.Here,a promising method to increase the...The lack of soft magnetic composites with high power density in MHz frequency range has become an obstacle in the efficient operation of the electrical and electronic equipments.Here,a promising method to increase the cut-off frequency of iron-based soft magnetic composites to hundreds of MHz is reported.The cut-off frequency is increased from 10 MHz to 1 GHz by modulating the height of the ring,the distribution of particles,and the particle size.The mechanism of cut-off frequency and permeability is the coherent rotation of domain modulated by inhomogeneous field due to the eddy current effect.An empirical formula for the cut-off frequency in a magnetic ring composed of iron-based particles is established from experimental data.This work provides an effective approach to fabricate soft magnetic composites with a cut-off frequency in hundreds of MHz.展开更多
BACKGROUND Glycated hemoglobin A1c(HbA1c)is considered the most suitable for diabetes mellitus diagnosis due to its accuracy and convenience.However,the effect of HbA1c on diabetic retinopathy(DR)in the Han and Korean...BACKGROUND Glycated hemoglobin A1c(HbA1c)is considered the most suitable for diabetes mellitus diagnosis due to its accuracy and convenience.However,the effect of HbA1c on diabetic retinopathy(DR)in the Han and Korean populations in Jilin,China,remains inconclusive.AIM To determine the best cut-off of HbA1c for diagnosing DR among the Chinese.METHODS This cross-sectional study included 1933 participants from the Yanbian area of Jilin Province,China.Trained investigators employed a questionnaire-based survey,physical examination,laboratory tests,and fundus photography for the investigation.The best cut-off value for HbA1c was established via the receiver operating characteristic curve.The factors associated with HbA1c-associated risk factors were determined via linear regression.RESULTS The analysis included 887 eligible Chinese Han and Korean participants,591 of whom were assigned randomly to the training set and 296 to the validation set.The prevalence of DR was 3.27% in the total population.HbA1c of 6.2% was the best cut-off value in the training set,while it was 5.9% in the validation set.In both Chinese Han and Korean populations,an HbA1c level of 6.2% was the best cut-off value.The optimal cut-off values of fasting blood glucose(FBG)≥7 mmol/L and<7 mmol/L were 8.1% and 6.2% respectively in Han populations,while those in Korean populations were 6.9%and 5.3%,respectively.Age,body mass index,and FBG were determined as the risk factors impacting HbA1c levels.CONCLUSION HbA1c may serve as a useful diagnostic indicator for DR.An HbA1c level of 6.2% may be an appropriate cut-off value for DR detection in the Chinese population.展开更多
Nickel(Ni)-rich layered oxides have drawn great attention as cathode for lithium batteries due to their high capacity,high working voltage and competitive cost.Unfortunately,the operation of Ni-rich cathodes suffers f...Nickel(Ni)-rich layered oxides have drawn great attention as cathode for lithium batteries due to their high capacity,high working voltage and competitive cost.Unfortunately,the operation of Ni-rich cathodes suffers from the notorious structural degradation and interfacial side reactions with electrolytes and thus incurs premature failure,especially at high charge cut-off voltages(≥4.4 V).For this,various structural and interphase regulation strategies(such as coating modification,element doping,and electrolyte engineering)are developed to enhance the cycling survivability of Ni-rich cathodes.Among them,electrolyte engineering by changing solvation structure and introducing additives has been considered an efficient method for constructing robust cathode-electrolyte interphases(CEI),inhibiting the formation of harmful species(such as HF and H_(2)O)or restraining the dissolution of transition metal ions.However,there is still an absence of systematic guidelines for selecting and designing competitive electrolyte systems for Ni-rich layered cathodes.In this review,we comprehensively summarize the recent research progress on electrolyte engineering for Ni-rich layered cathodes according to their working mechanisms.Moreover,we propose future perspectives of improving the electrolyte performance,which will provide new insights for designing novel electrolytes toward high-performance Ni-rich layered cathodes.展开更多
Although lithium-ion batteries are widely recognized as a new generation of energy storage devices,their large-scale application is severely hampered by their low energy density and restricted cyclic stability.Herein,...Although lithium-ion batteries are widely recognized as a new generation of energy storage devices,their large-scale application is severely hampered by their low energy density and restricted cyclic stability.Herein,an ingenious dual-modified interface,where the F-doping and fluorocarbon coating co-existed on Li[Ni_(0.8)Co_(0.1)Mn_(0.1)]O_(2)surface,is rationally constructed to elevate its energy density and structural stability attributed to F-grafting between the bulk material and the coating utilizing a robust super-conformal fluorocarbon coating structural framework and more stable F-doped system under high charge/discharge cut-off voltage.In comparison with a single carbon-coated modified Li[Ni_(0.8)Co_(0.1)Mn_(0.1)]O_(2),the dual-modified sample overcomes the fatal disadvantage of carbon coating stripping during long-period cycles ascribed to the“TM-F-multifunctional coating”connector which firmly combines the bulk material with the coating with a strong interaction force,exhibiting a more stable-reversible structure and excellent comprehensive electrochemical performance under high cut-off voltage.Concomitantly,the F-transition metal bonds with stronger bond energies improve its structural reversibility during the processes of charge/discharge under high voltage.Furthermore,the fluorocarbon coating enhances its charge transfer ability and effectively restrains the interfacial side reactions.Additionally,the climbing nudged elastic band methodology is used to calculate the diffusion energy barrier of lithium-ions in the matrix material,which confirms the fundamental reason for its superior lithium-ion diffusion ability.The high pseudocapacitance contribution ratio is perfectly explained by calculating the adsorption capacity on the surface of the dual-modified sample.Consequently,experiments and theoretical calculations unequivocally confirm its distinguished electrochemical properties under high cut-off voltage.展开更多
The consistency of the dynamic behavior of the mechanical equivalent model of high-speed pantographs with that of actual high-speed pantographs under service conditions is crucial for the correctness and accuracy of t...The consistency of the dynamic behavior of the mechanical equivalent model of high-speed pantographs with that of actual high-speed pantographs under service conditions is crucial for the correctness and accuracy of the numerical simulation results of the pantograph-catenary interaction.Firstly,based on experimental data and the finite element method,models of a mass-point frame and reduced pan head were established,which can simulate the rolling and pitching motion characteristics of the dual-strip pan head.The correctness of the finite element numerical simulation of the pantograph-catenary system based on the model was verified through an industry standard and line tests.Then,the variation law of the standard deviation of the contact force(SDCF)in the speed range of 240-450 km/h was studied,and the mechanism of large fluctuation in SDCF was explained from the perspective of pantograph-catenary resonance.Finally,the influence of pan head degree of freedom and low-pass filtering frequency of the contact force time-domain signal on SDCF was studied,and the applicable speed level of the traditional three-mass model and 20 Hz filtering were provided.展开更多
Understanding the quantum critical phenomena is one of the most important and challenging tasks in condensed matter physics and the two-impurity Anderson model(TIAM) is a good starting point for this exploration. To t...Understanding the quantum critical phenomena is one of the most important and challenging tasks in condensed matter physics and the two-impurity Anderson model(TIAM) is a good starting point for this exploration. To this end,we employ the algebraic equation of motion approach to calculate the TIAM and analytically obtain the explicit singleparticle impurity Green function under the soft cut-off approximation(SCA). This approach effectively incorporates the impurity spacing as an intrinsic parameter. By solving the pole equations of the Green function, we have, for the first time, qualitatively calculated the spectral weight functions of the corresponding low-energy excitations. We find that when the impurity spacing is less than one lattice distance, the dynamic Rudermann–Kittel–Kasuya–Yosida(RKKY) interaction effectively enters, resulting in a rapid increase in the spectral weights of the RKKY phase, which ultimately surpass those of the Kondo phase;while the spectral weights of the Kondo phase are strongly suppressed. From the perspective of spectral weights, we further confirm the existence of a crossover from the Kondo phase to the RKKY phase in the TIAM. Based on these results, the reasons for the phenomenon of the Kondo resonance splitting are also discussed.展开更多
Obesity is an independent risk factor for chronic diseases such as diabetes, cardiovascular diseases and certain cancers. Early detection of abdominal obesity followed by appropriate interventions will prevent associa...Obesity is an independent risk factor for chronic diseases such as diabetes, cardiovascular diseases and certain cancers. Early detection of abdominal obesity followed by appropriate interventions will prevent associated diseases. The objective was to determine optimal waist circumference (WC) cut-off points predictive of at least one other component of metabolic syndrome in Benin adults. This longitudinal and observational study included at the baseline 541 apparently healthy subjects aged 25 - 60 years randomly selected in the largest city of Cotonou (n = 200), the smaller-size city of Ouidah (n = 171) and rural surroundings of Ouidah (n = 170) in Benin. Components of the metabolic syndrome considered along with abdominal obesity were high blood pressure, high fasting glycaemia, low HDL-cholesterol and high triglycerides as defined by the Joint Interim Statement. After the baseline survey, the subjects were followed-up for four years. Complete data at baseline and four years later were available in 416 subjects. The receiver operating characteristic (ROC) curve for waist circumference to predict at least one other component of the metabolic syndrome was plotted and the Youden index was used to define the optimal cut-offs of WC. At the baseline of the study, the optimal WC cut-off point to predict the presence of at least one other component of the metabolic syndrome was 80 cm for men (sensitivity = 0.62, specificity = 0.65);the area under the ROC curve was 0.67 (IC 95%: 0.61-0.74). In women, the optimal WC cut-off point was 90 cm (sensitivity = 0.54, specificity = 0.80), and the area under the ROC curve was 0.68 (IC 95%: 0.62-0.75). These optimal cut-offs were similar four years later. Optimum WC cut-off points for both men and women in Benin differ from those currently recommended for sub-Saharan Africans. Therefore, waist circumference cut-off points for abdominal obesity need to be reconsidered for these populations.展开更多
Single-crystalline Ni-rich cathodes can provide high energy density and capacity retention rates for lithium-ion batteries(LIBs).However,single-crystalline Ni-rich cathodes experience severe transition metal dissoluti...Single-crystalline Ni-rich cathodes can provide high energy density and capacity retention rates for lithium-ion batteries(LIBs).However,single-crystalline Ni-rich cathodes experience severe transition metal dissolution,irreversible phase transitions,and reduced structural stability during prolonged cycling at high voltage,which will significantly hinder their practical application.Herein,a Li4TeO5surface coating along with bulk Te-gradient doping strategy is proposed and developed to solve these issues for single-crystalline Ni-rich LiNi_(0.90)Co_(0.05)Mn_(0.05)O_(2)cathode(LTeO-1.0).It has been found that the bulk Te^(6+)gradient doping can lead to the formation of robust Te-O bonds that effectively inhibit H_(2)-H3 phase transformations and reinforce the lattice framework,and the in-situ Li4TeO5coating layer can act as a protective layer that suppresses the parasitic reactions and grain fragmentation.Besides,the modified material exhibits a higher Young's modulus,which will be conducive to maintaining significant structural and electrochemical stability under high-voltage conditions,Especially,the LTeO-1.0 electrode shows the improved Li^(+)diffusion kinetics and thermodynamic stability as well as high capacity retention of 95.83%and 82.12%after 200 cycles at the cut-off voltage of 4.3 and 4,5 V.Therefore,the efficacious dualmodification strategy will definitely contribute to enhancing the structural and electrochemical stability of single-crystalline Ni-rich cathodes and developing their application in LIBs.展开更多
The cut-off wall in a clay-core rockfill dam built on a thick overburden layer is subjected to a large compressive pressure under the action of the loads such as the dead weight of both the dam and the overburden laye...The cut-off wall in a clay-core rockfill dam built on a thick overburden layer is subjected to a large compressive pressure under the action of the loads such as the dead weight of both the dam and the overburden layer, the frictional force induced by the differential settlement between the cut-off wall and surrounding soils, and the water pressure. Thus, reduction of the stress of the cut-off wall has become one of the main problems for consideration in engineering design. In this paper, numerical analysis of a core rockfill dam built on a thick overburden layer was conducted and some factors influencing the stress-strain behaviors of the cut-off wall were investigated. The factors include the improvement of the overburden layer, the modeling approach for interfacial contact between the cut-off wall and surrounding soils, the modulus of the cut-off wall concrete, and the connected pattern between the cut-off wall and the clay core. The result shows that improving the overburden layer,selecting plastic concrete with a low modulus and high strength, and optimizing the connection between the cut-off wall and the clay core of the dam are effective measures of reducing the deformations and compressive stresses of the cut-off wall. In addition, both the Goodman element and the mud-layer element are suitable for simulating the interfacial contact between the cut-off wall and surrounding soils.展开更多
基金the National Natural Science Foundation of China (Grant Nos.42072318 and 42207227)Central South University Innovation-Driven Research Program (Grant No.2023CXQD044).
文摘The soil-bentonite(SB)cut-off wall has been widely considered a vertical barrier to effectively control the migration of pollutants in contaminated sites.Recently,active porous materials have been used as a promising candidate amendment for mitigating chemical degradation and improving the retardation capacity of the SB cut-off wall.In this study,the silty clay from a typical Cr(VI)contaminated site was selected as the body material of the SB cut-off wall,and zeolite and active carbon were used as the modifiers of the silty clay-bentonite backfills,respectively.The impact of the two modifiers on the engineering properties of the backfills was investigated through a series of slump tests,consolidation tests,hydraulic conductivity tests,and microstructure tests.The experimental results demonstrated that the slump curves closely exhibited a linear relationship between standard slump and moisture content.Meanwhile,bentonite could improve the optimum moisture content of the backfills,while the addition of the two modifiers yielded the opposite outcome.As the bentonite content increased,the compression index of the backfills significantly increased,while the hydraulic conductivity decreased.At a given bentonite content of 5%,the addition of zeolite or active carbon resulted in a reduction in the compression index and initial void ratio,while exhibiting minimal impact on the hydraulic conductivity.Scanning electron microscope(SEM)observations indicated that the silty clay-bentonite backfills became increasingly loose with increasing bentonite content,owing to the filling and expansion of dispersed bentonite layers.The amendment of zeolite or active carbon was able to decrease the backfill volume by promoting the agglomeration of layered bentonite.The findings of this study will be useful for the optimal selection of backfill materials and the performance evaluation of the cut-off wall.
基金support from the National Natural Science Foundation of China(22179006)the National Key Research and Development Program of China(2024YFF0505900)+1 种基金the Key Research and Development Program of Henan province,China(231111242500)the SINOPEC project(223128)。
文摘Uneven lithium deposition leading to lithium dendrite growth severely hampers the application of lithium-metal batteries.Modifying the collector with lithiophilic materials helps improve lithium deposition.For lithophilic materials to modify the collector,the choice of cut-off voltage is very important.While excessively high cut-off voltages may compromise the stability of the modified layer and consequently disrupt ordered lithium deposition,conventional approaches typically employ lower cut-off voltages(particularly 0.1 V)to maintain modification layer stability.However,the 0.1 V cut-off voltage results in incomplete lithium stripping from the lithiophilic material surface.This phenomenon significantly diminishes the lithiophilic properties of the modified layer and consequently leads to substantial nucleation overpotential.Here,we propose to use a moderate cut-voltage stimulation effect to slow down the interfacial shielding effect of residual lithium metal on lithiophilic materials.By optimizing the cut-off voltage for the Cu@Sb_(2)S_(3)collector,the stability of the modified layer can be preserved while enabling the complete stripping of lithium metal from the surface of the lithophilic material.The asymmetric cell received the highest Coulombic efficiency(CE)when the lithium stripping cut-off voltage was set at 0.5 V relative to 0.1 and 2.0 V.At a current density of 1 mA cm^(-2)and a deposition capacity of1 m A h cm^(-2),the CE remained 98.6% at a cut-off voltage of 0.5 V after 140 cycles in an ether electrolyte without lithium nitrate.
基金Projects(52278395,52208409) supported by the National Natural Science Foundation of ChinaProject(2022JJ40531) supported by the Natural Science Foundation of Hunan Province,China。
文摘Because of actual requirement,shield machine always excavates with an inclined angle in longitudinal direction.Since many previous studies mainly focus on the face stability of the horizontal shield tunnel,the effects of tensile strength cut-off and pore water pressure on the face stability of the longitudinally inclined shield tunnel are not well investigated.A failure mechanism of a longitudinally inclined shield tunnel face is constructed based on the spatial discretization technique and the tensile strength cut-off criterion is introduced to modify the constructed failure mechanism.The pore water pressure is introduced as an external force into the equation of virtual work and the objective function of the chamber pressure of the shield machine is obtained.Moreover,the critical chamber pressure of the longitudinally inclined shield tunnel is computed by optimal calculation.Parametric analysis indicates that both tensile strength cut-off and pore water pressure have a significant impact on the chamber pressure and the range of the collapse block.Finally,the theoretical results are compared with the numerical results calculated by FLAC3D software which proves that the proposed approach is effective.
基金the National Natural Science Foun-dation of China(Grant Nos.91963201 and 12174163)the 111 Project(Grant No.B20063).
文摘The lack of soft magnetic composites with high power density in MHz frequency range has become an obstacle in the efficient operation of the electrical and electronic equipments.Here,a promising method to increase the cut-off frequency of iron-based soft magnetic composites to hundreds of MHz is reported.The cut-off frequency is increased from 10 MHz to 1 GHz by modulating the height of the ring,the distribution of particles,and the particle size.The mechanism of cut-off frequency and permeability is the coherent rotation of domain modulated by inhomogeneous field due to the eddy current effect.An empirical formula for the cut-off frequency in a magnetic ring composed of iron-based particles is established from experimental data.This work provides an effective approach to fabricate soft magnetic composites with a cut-off frequency in hundreds of MHz.
基金Supported by National Key R&D Program of China,No.2016YFC1305700.
文摘BACKGROUND Glycated hemoglobin A1c(HbA1c)is considered the most suitable for diabetes mellitus diagnosis due to its accuracy and convenience.However,the effect of HbA1c on diabetic retinopathy(DR)in the Han and Korean populations in Jilin,China,remains inconclusive.AIM To determine the best cut-off of HbA1c for diagnosing DR among the Chinese.METHODS This cross-sectional study included 1933 participants from the Yanbian area of Jilin Province,China.Trained investigators employed a questionnaire-based survey,physical examination,laboratory tests,and fundus photography for the investigation.The best cut-off value for HbA1c was established via the receiver operating characteristic curve.The factors associated with HbA1c-associated risk factors were determined via linear regression.RESULTS The analysis included 887 eligible Chinese Han and Korean participants,591 of whom were assigned randomly to the training set and 296 to the validation set.The prevalence of DR was 3.27% in the total population.HbA1c of 6.2% was the best cut-off value in the training set,while it was 5.9% in the validation set.In both Chinese Han and Korean populations,an HbA1c level of 6.2% was the best cut-off value.The optimal cut-off values of fasting blood glucose(FBG)≥7 mmol/L and<7 mmol/L were 8.1% and 6.2% respectively in Han populations,while those in Korean populations were 6.9%and 5.3%,respectively.Age,body mass index,and FBG were determined as the risk factors impacting HbA1c levels.CONCLUSION HbA1c may serve as a useful diagnostic indicator for DR.An HbA1c level of 6.2% may be an appropriate cut-off value for DR detection in the Chinese population.
基金supported by the National Key Research and Development Program of China(2021YFF0500600)National Natural Science Foundation of China(Nos.U2001220,52203298 and 523B2022)+2 种基金National Science Fund for Distinguished Young Scholars(No.52325206)Shenzhen Technical Plan Project(Nos.RCJC20200714114436091,JCYJ20220530143012027,JCYJ20220818101003008 and JCYJ20220818101003007)Tsinghua Shenzhen International Graduate School-Shenzhen Pengrui Young Faculty Program of Shenzhen Pengrui Foundation(No.SZPR2023006).
文摘Nickel(Ni)-rich layered oxides have drawn great attention as cathode for lithium batteries due to their high capacity,high working voltage and competitive cost.Unfortunately,the operation of Ni-rich cathodes suffers from the notorious structural degradation and interfacial side reactions with electrolytes and thus incurs premature failure,especially at high charge cut-off voltages(≥4.4 V).For this,various structural and interphase regulation strategies(such as coating modification,element doping,and electrolyte engineering)are developed to enhance the cycling survivability of Ni-rich cathodes.Among them,electrolyte engineering by changing solvation structure and introducing additives has been considered an efficient method for constructing robust cathode-electrolyte interphases(CEI),inhibiting the formation of harmful species(such as HF and H_(2)O)or restraining the dissolution of transition metal ions.However,there is still an absence of systematic guidelines for selecting and designing competitive electrolyte systems for Ni-rich layered cathodes.In this review,we comprehensively summarize the recent research progress on electrolyte engineering for Ni-rich layered cathodes according to their working mechanisms.Moreover,we propose future perspectives of improving the electrolyte performance,which will provide new insights for designing novel electrolytes toward high-performance Ni-rich layered cathodes.
基金support from the Natural Science Foundation of Fujian Province,China(No.2021H0028)the Natural Science Foundation of China(No.21975212)+1 种基金Open Fund of Fujian Provincial Key Laboratory of Functional Materials and Applications(No.fma2023003)the Science and Technology Planning Project of Xiamen City(No.2022CXY0409).
文摘Although lithium-ion batteries are widely recognized as a new generation of energy storage devices,their large-scale application is severely hampered by their low energy density and restricted cyclic stability.Herein,an ingenious dual-modified interface,where the F-doping and fluorocarbon coating co-existed on Li[Ni_(0.8)Co_(0.1)Mn_(0.1)]O_(2)surface,is rationally constructed to elevate its energy density and structural stability attributed to F-grafting between the bulk material and the coating utilizing a robust super-conformal fluorocarbon coating structural framework and more stable F-doped system under high charge/discharge cut-off voltage.In comparison with a single carbon-coated modified Li[Ni_(0.8)Co_(0.1)Mn_(0.1)]O_(2),the dual-modified sample overcomes the fatal disadvantage of carbon coating stripping during long-period cycles ascribed to the“TM-F-multifunctional coating”connector which firmly combines the bulk material with the coating with a strong interaction force,exhibiting a more stable-reversible structure and excellent comprehensive electrochemical performance under high cut-off voltage.Concomitantly,the F-transition metal bonds with stronger bond energies improve its structural reversibility during the processes of charge/discharge under high voltage.Furthermore,the fluorocarbon coating enhances its charge transfer ability and effectively restrains the interfacial side reactions.Additionally,the climbing nudged elastic band methodology is used to calculate the diffusion energy barrier of lithium-ions in the matrix material,which confirms the fundamental reason for its superior lithium-ion diffusion ability.The high pseudocapacitance contribution ratio is perfectly explained by calculating the adsorption capacity on the surface of the dual-modified sample.Consequently,experiments and theoretical calculations unequivocally confirm its distinguished electrochemical properties under high cut-off voltage.
基金supported by the Major Project of China Railway Co.,Ltd.(Grant No.K2021J004-A)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB22020201)。
文摘The consistency of the dynamic behavior of the mechanical equivalent model of high-speed pantographs with that of actual high-speed pantographs under service conditions is crucial for the correctness and accuracy of the numerical simulation results of the pantograph-catenary interaction.Firstly,based on experimental data and the finite element method,models of a mass-point frame and reduced pan head were established,which can simulate the rolling and pitching motion characteristics of the dual-strip pan head.The correctness of the finite element numerical simulation of the pantograph-catenary system based on the model was verified through an industry standard and line tests.Then,the variation law of the standard deviation of the contact force(SDCF)in the speed range of 240-450 km/h was studied,and the mechanism of large fluctuation in SDCF was explained from the perspective of pantograph-catenary resonance.Finally,the influence of pan head degree of freedom and low-pass filtering frequency of the contact force time-domain signal on SDCF was studied,and the applicable speed level of the traditional three-mass model and 20 Hz filtering were provided.
基金Project supported by the National Natural Science Foundation of China (Grant No. 11974420)。
文摘Understanding the quantum critical phenomena is one of the most important and challenging tasks in condensed matter physics and the two-impurity Anderson model(TIAM) is a good starting point for this exploration. To this end,we employ the algebraic equation of motion approach to calculate the TIAM and analytically obtain the explicit singleparticle impurity Green function under the soft cut-off approximation(SCA). This approach effectively incorporates the impurity spacing as an intrinsic parameter. By solving the pole equations of the Green function, we have, for the first time, qualitatively calculated the spectral weight functions of the corresponding low-energy excitations. We find that when the impurity spacing is less than one lattice distance, the dynamic Rudermann–Kittel–Kasuya–Yosida(RKKY) interaction effectively enters, resulting in a rapid increase in the spectral weights of the RKKY phase, which ultimately surpass those of the Kondo phase;while the spectral weights of the Kondo phase are strongly suppressed. From the perspective of spectral weights, we further confirm the existence of a crossover from the Kondo phase to the RKKY phase in the TIAM. Based on these results, the reasons for the phenomenon of the Kondo resonance splitting are also discussed.
文摘Obesity is an independent risk factor for chronic diseases such as diabetes, cardiovascular diseases and certain cancers. Early detection of abdominal obesity followed by appropriate interventions will prevent associated diseases. The objective was to determine optimal waist circumference (WC) cut-off points predictive of at least one other component of metabolic syndrome in Benin adults. This longitudinal and observational study included at the baseline 541 apparently healthy subjects aged 25 - 60 years randomly selected in the largest city of Cotonou (n = 200), the smaller-size city of Ouidah (n = 171) and rural surroundings of Ouidah (n = 170) in Benin. Components of the metabolic syndrome considered along with abdominal obesity were high blood pressure, high fasting glycaemia, low HDL-cholesterol and high triglycerides as defined by the Joint Interim Statement. After the baseline survey, the subjects were followed-up for four years. Complete data at baseline and four years later were available in 416 subjects. The receiver operating characteristic (ROC) curve for waist circumference to predict at least one other component of the metabolic syndrome was plotted and the Youden index was used to define the optimal cut-offs of WC. At the baseline of the study, the optimal WC cut-off point to predict the presence of at least one other component of the metabolic syndrome was 80 cm for men (sensitivity = 0.62, specificity = 0.65);the area under the ROC curve was 0.67 (IC 95%: 0.61-0.74). In women, the optimal WC cut-off point was 90 cm (sensitivity = 0.54, specificity = 0.80), and the area under the ROC curve was 0.68 (IC 95%: 0.62-0.75). These optimal cut-offs were similar four years later. Optimum WC cut-off points for both men and women in Benin differ from those currently recommended for sub-Saharan Africans. Therefore, waist circumference cut-off points for abdominal obesity need to be reconsidered for these populations.
基金supported by the National Natural Science Foundation of China(U19A2018)the Natural Science Foundation of Hunan Province(2021JJ30651)the Postgraduate Scientific Research Innovation Project of Hunan Province(CX20230643).
文摘Single-crystalline Ni-rich cathodes can provide high energy density and capacity retention rates for lithium-ion batteries(LIBs).However,single-crystalline Ni-rich cathodes experience severe transition metal dissolution,irreversible phase transitions,and reduced structural stability during prolonged cycling at high voltage,which will significantly hinder their practical application.Herein,a Li4TeO5surface coating along with bulk Te-gradient doping strategy is proposed and developed to solve these issues for single-crystalline Ni-rich LiNi_(0.90)Co_(0.05)Mn_(0.05)O_(2)cathode(LTeO-1.0).It has been found that the bulk Te^(6+)gradient doping can lead to the formation of robust Te-O bonds that effectively inhibit H_(2)-H3 phase transformations and reinforce the lattice framework,and the in-situ Li4TeO5coating layer can act as a protective layer that suppresses the parasitic reactions and grain fragmentation.Besides,the modified material exhibits a higher Young's modulus,which will be conducive to maintaining significant structural and electrochemical stability under high-voltage conditions,Especially,the LTeO-1.0 electrode shows the improved Li^(+)diffusion kinetics and thermodynamic stability as well as high capacity retention of 95.83%and 82.12%after 200 cycles at the cut-off voltage of 4.3 and 4,5 V.Therefore,the efficacious dualmodification strategy will definitely contribute to enhancing the structural and electrochemical stability of single-crystalline Ni-rich cathodes and developing their application in LIBs.
基金the National Natural Science Foundation of China (Grant No.51379066)the Fundamental Research Funds for the Central Universities (Grant No.2016B03514)+1 种基金the National Key Technology Support Program (Grant No.2015BAB07B05)the Key Laboratory of Earth-Rock Dam Failure Mechanism and Safety Control Techniques (Grant No.YK913007).
文摘The cut-off wall in a clay-core rockfill dam built on a thick overburden layer is subjected to a large compressive pressure under the action of the loads such as the dead weight of both the dam and the overburden layer, the frictional force induced by the differential settlement between the cut-off wall and surrounding soils, and the water pressure. Thus, reduction of the stress of the cut-off wall has become one of the main problems for consideration in engineering design. In this paper, numerical analysis of a core rockfill dam built on a thick overburden layer was conducted and some factors influencing the stress-strain behaviors of the cut-off wall were investigated. The factors include the improvement of the overburden layer, the modeling approach for interfacial contact between the cut-off wall and surrounding soils, the modulus of the cut-off wall concrete, and the connected pattern between the cut-off wall and the clay core. The result shows that improving the overburden layer,selecting plastic concrete with a low modulus and high strength, and optimizing the connection between the cut-off wall and the clay core of the dam are effective measures of reducing the deformations and compressive stresses of the cut-off wall. In addition, both the Goodman element and the mud-layer element are suitable for simulating the interfacial contact between the cut-off wall and surrounding soils.
