Magnetic Fe3 O4@Cu/Ce microspheres were successfully prepared by one-step solvothermal approach and further utilized to remediate toxic arsenic(As(Ⅲ)) pollution. The effects of Cu/Ce elements co-doping on the crystal...Magnetic Fe3 O4@Cu/Ce microspheres were successfully prepared by one-step solvothermal approach and further utilized to remediate toxic arsenic(As(Ⅲ)) pollution. The effects of Cu/Ce elements co-doping on the crystal structure, catalytic oxidation and adsorption behaviors of magnetic microspheres were researched systematically. The results showed that with the aid of Cu/Ce elements, the grain size reduced, lattice defects increased, and the oxygen vacancies and surface hydroxyl groups were improved. Therefore, Cu/Ce elements endowed magnetic Fe3 O4@Cu/Ce microspheres with excellent As(III) removal performance, whose maximum adsorption capacity reached 139.19 mg/g. The adsorption mechanism mainly involved catalytic oxidant co-adsorption. This research developed a feasible strategy for the preparation of high efficiency magnetic adsorbent to enhance the removal of As(Ⅲ).展开更多
A series of the coconut activated carbons(CAC) based absorbents modified with Cu and Ce(Cu/CAC,Cu/Ce/CAC) were prepared by impregnation technology for carbon dioxide capture.The adsocrption equilibriums of CO2 on Cu/C...A series of the coconut activated carbons(CAC) based absorbents modified with Cu and Ce(Cu/CAC,Cu/Ce/CAC) were prepared by impregnation technology for carbon dioxide capture.The adsocrption equilibriums of CO2 on Cu/CAC and Cu/Ce/CAC were measured.The results showed that the adsorption capacity of CO2 onto the activated carbon modified with Cu/Ce increased with the decreasing temperature in the same pressure.The adsorption capacity of CO2 on Cu/CAC was higher than that of the blank CAC,and compared with the Cu/CAC,the adsorption capacity of CO2 of Cu/Ce/CAC with the mass ratio of Cu/Ce=30 was improved at 298 and 303 K.In addition,the adsorption equilibrium data for CO2 at various temperatures was fitted to Langmuir,Freundlich and D-R isotherm models.It was found that the D-R equation was the best model for fitting the adsorption data on Cu/Ce/CAC at different temperatures.展开更多
To obtain lightweight multicomponent magnesium alloys with high tensile strength,ductility,and stiffness,two extruded Mg_(92−5x)Al_(1.5+3x)Zn_(3)Cu_(3.5+x)Ce_(x)(x=0.5 and 1,labeled as C0.5 and C1)alloys were designed...To obtain lightweight multicomponent magnesium alloys with high tensile strength,ductility,and stiffness,two extruded Mg_(92−5x)Al_(1.5+3x)Zn_(3)Cu_(3.5+x)Ce_(x)(x=0.5 and 1,labeled as C0.5 and C1)alloys were designed.The results reveal that the ultimate tensile strength,yield strength(YS),and fracture strain of the C0.5 alloy are simultaneously improved compared to those of the C1 alloy,with values of 346 MPa,312 MPa,and 11.7%,respectively.This enhancement is primarily attributed to the refinement of numerous secondary phases(micron scale Al_(3)CuCe,micron scale MgZnCu,and nanoscale MgZnCu phases).The calculation of YS shows that the Orowan strengthening and coefficient of thermal expansion mismatch strengthening are the main strengthening mechanisms,and the contribution values of both to the YS are 28 and 70 MPa for C0.5 alloy.In addition,the C0.5 alloy has a greater plasticity than the C1 alloy because the<c+a>slip system is initiated.展开更多
基金Project(2018YFC1802204)supported by the National Key R&D Program of ChinaProject(51634010)supported by the Key Project of National Natural Science Foundation of ChinaProject(2018SK2026)supported by the Key R&D Program of Hunan Province,China。
文摘Magnetic Fe3 O4@Cu/Ce microspheres were successfully prepared by one-step solvothermal approach and further utilized to remediate toxic arsenic(As(Ⅲ)) pollution. The effects of Cu/Ce elements co-doping on the crystal structure, catalytic oxidation and adsorption behaviors of magnetic microspheres were researched systematically. The results showed that with the aid of Cu/Ce elements, the grain size reduced, lattice defects increased, and the oxygen vacancies and surface hydroxyl groups were improved. Therefore, Cu/Ce elements endowed magnetic Fe3 O4@Cu/Ce microspheres with excellent As(III) removal performance, whose maximum adsorption capacity reached 139.19 mg/g. The adsorption mechanism mainly involved catalytic oxidant co-adsorption. This research developed a feasible strategy for the preparation of high efficiency magnetic adsorbent to enhance the removal of As(Ⅲ).
基金Project supported by the National Great Water Pollution Control Project (2008ZX07105-002)Young and Middle-aged Academic and Tech-nical Back-up Personnel program of Yunnan Province (2007PY01-10)
文摘A series of the coconut activated carbons(CAC) based absorbents modified with Cu and Ce(Cu/CAC,Cu/Ce/CAC) were prepared by impregnation technology for carbon dioxide capture.The adsocrption equilibriums of CO2 on Cu/CAC and Cu/Ce/CAC were measured.The results showed that the adsorption capacity of CO2 onto the activated carbon modified with Cu/Ce increased with the decreasing temperature in the same pressure.The adsorption capacity of CO2 on Cu/CAC was higher than that of the blank CAC,and compared with the Cu/CAC,the adsorption capacity of CO2 of Cu/Ce/CAC with the mass ratio of Cu/Ce=30 was improved at 298 and 303 K.In addition,the adsorption equilibrium data for CO2 at various temperatures was fitted to Langmuir,Freundlich and D-R isotherm models.It was found that the D-R equation was the best model for fitting the adsorption data on Cu/Ce/CAC at different temperatures.
基金financially supported by the National Key Research and Development Program of China(No.2022YFB3709300)the Guangdong Major Project of Basic and Applied Basic Research,China(No.2020B0301030006)the Chongqing Special Project of Science and Technology Innovation,China(No.cstc2021yszx-jcyjX0007)。
文摘To obtain lightweight multicomponent magnesium alloys with high tensile strength,ductility,and stiffness,two extruded Mg_(92−5x)Al_(1.5+3x)Zn_(3)Cu_(3.5+x)Ce_(x)(x=0.5 and 1,labeled as C0.5 and C1)alloys were designed.The results reveal that the ultimate tensile strength,yield strength(YS),and fracture strain of the C0.5 alloy are simultaneously improved compared to those of the C1 alloy,with values of 346 MPa,312 MPa,and 11.7%,respectively.This enhancement is primarily attributed to the refinement of numerous secondary phases(micron scale Al_(3)CuCe,micron scale MgZnCu,and nanoscale MgZnCu phases).The calculation of YS shows that the Orowan strengthening and coefficient of thermal expansion mismatch strengthening are the main strengthening mechanisms,and the contribution values of both to the YS are 28 and 70 MPa for C0.5 alloy.In addition,the C0.5 alloy has a greater plasticity than the C1 alloy because the<c+a>slip system is initiated.
