Chlorine-based all-inorganic lead-free halide perovskites exhibit excellent properties in visible-blind ultraviolet detectors.However,the quality and size of these solution-grown single crystals are still far from mee...Chlorine-based all-inorganic lead-free halide perovskites exhibit excellent properties in visible-blind ultraviolet detectors.However,the quality and size of these solution-grown single crystals are still far from meeting commercial standards due to their low solubility,and a fundamental understanding of the underlying causes of low solubility is still lacking.Herein,the effects of the microscopic structure of solutions on the solubility have been systematically investigated,and it has been demonstrated that a hybrid solvent consisting of dimethyl sulfoxide and hydrochloric acid can significantly improve the solubility of the raw materials of Cs_(m)Sb_(n)Cl_(m+3n)(SbCl_(3)and CsCl).Centimeter-sized high-quality α-Cs_(3)Sb_(2)Cl_(9) and Cs_(5)Sb_(2)Cl_(11) single crystals are grown by the effective hybrid solvent.The low dark current density(91 pA cm^(-2)),excellent wavelength selectivity(R_(360)/R_(480)=150),and fast response speed(t_(r)=21.7 ms,t_(d)=104.4 ms)of the photodetector based on the Au/α-Cs_(3)Sb_(2)Cl_(9)/Au structure powerfully demonstrate the great potential of Cs_(m)Sb_(n)Cl_(m+3n) in ultraviolet applications.Furthermore,the method of using hybrid solvents to increase solubility can be extended to the growth of all inorganic chloride perovskite single crystals,thereby driving the exploration of their future optoelectronic applications.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.12175131)the Postdoctoral Research Foundation of China(Grant No.2021M692021)the Hebei Provincial Key Research Project(Grant No.20311009D).
文摘Chlorine-based all-inorganic lead-free halide perovskites exhibit excellent properties in visible-blind ultraviolet detectors.However,the quality and size of these solution-grown single crystals are still far from meeting commercial standards due to their low solubility,and a fundamental understanding of the underlying causes of low solubility is still lacking.Herein,the effects of the microscopic structure of solutions on the solubility have been systematically investigated,and it has been demonstrated that a hybrid solvent consisting of dimethyl sulfoxide and hydrochloric acid can significantly improve the solubility of the raw materials of Cs_(m)Sb_(n)Cl_(m+3n)(SbCl_(3)and CsCl).Centimeter-sized high-quality α-Cs_(3)Sb_(2)Cl_(9) and Cs_(5)Sb_(2)Cl_(11) single crystals are grown by the effective hybrid solvent.The low dark current density(91 pA cm^(-2)),excellent wavelength selectivity(R_(360)/R_(480)=150),and fast response speed(t_(r)=21.7 ms,t_(d)=104.4 ms)of the photodetector based on the Au/α-Cs_(3)Sb_(2)Cl_(9)/Au structure powerfully demonstrate the great potential of Cs_(m)Sb_(n)Cl_(m+3n) in ultraviolet applications.Furthermore,the method of using hybrid solvents to increase solubility can be extended to the growth of all inorganic chloride perovskite single crystals,thereby driving the exploration of their future optoelectronic applications.
