The effectiveness of horizontal well multi-stage and multi-cluster fracturing in the fractured soft coal seam roof for coalbed methane(CBM) extraction has been demonstrated.This study focuses on the geological charact...The effectiveness of horizontal well multi-stage and multi-cluster fracturing in the fractured soft coal seam roof for coalbed methane(CBM) extraction has been demonstrated.This study focuses on the geological characteristics of the No.5 and No.11 coal seams in the Hancheng Block,Ordos Basin,China.A multi-functional,variable-size rock sample mold capable of securing the wellbore was developed to simulate layered formations comprising strata of varying lithology and thicknesses.A novel segmented fracturing simulation method based on an expandable pipe plugging technique is proposed.Large-scale true triaxial experiments were conducted to investigate the effects of horizontal wellbore location,perforation strategy,roof lithology,and vertical stress difference on fracture propagation,hydraulic energy variation,and the stimulated reservoir volume in horizontal wells targeting the soft coal seam roof.The results indicate that bilateral downward perforation with a phase angle of 120° optimizes hydraulic energy conservation,reduces operational costs,enhances fracture formation,and prevents fracturing failure caused by coal powder generation and migration.This perforation mode is thus considered optimal for coal seam roof fracturing.When the roof consists of sandstone,each perforation cluster tends to initiate a single dominant fracture with a regular geometry.In contrast,hydraulic fractures formed in mudstone roofs display diverse morphology.Due to its high strength,the sandstone roof requires significantly higher pressure for crack initiation and propagation,whereas the mudstone roof,with its strong water sensitivity,exhibits lower fracturing pressures.To mitigate inter-cluster interference,cluster spacing in mudstone roofs should be greater than that in sandstone roofs.Horizontal wellbore placement critically influences fracturing effectiveness.For indirect fracturing in sandstone roofs,an optimal position is 25 mm away from the lithological interface.In contrast,the optimal location for indirect fracturing in mudstone roofs is directly at the lithological interface with the coal seam.Higher vertical stress coefficients lead to increased fractu ring pressures and promote vertical,layer-penetrating fractures.A coefficient of 0.5 is identified as optimal for achieving effective indirect fracturing.This study provides valuable insights for the design and optimization of staged fracturing in horizontal wells targeting crushed soft coal seam roofs.展开更多
Morphology characteristics of mix aggregates with crushed air-cooled blast furnace slag（SCR） and crushed limestone（LCR） with 5-20 mm and 20-40 mm gradation were represented by numerical parameters including angula...Morphology characteristics of mix aggregates with crushed air-cooled blast furnace slag（SCR） and crushed limestone（LCR） with 5-20 mm and 20-40 mm gradation were represented by numerical parameters including angularity number（AN） and index of aggregate particle shape and texture（IAPST）.The effect of mix aggregates containing SCR on compressive strength and splitting tensile strength of concrete was investigated.Fracture characteristics of concrete,interfacial structure between aggregates and matrix were analyzed.The experimental results show that porous and rough SCR increases contact area with matrix in concrete,concave holes and micro-pores on the surface of SCR are filled by mortar and hydrated cement paste,which may increase interlocking and mechanical bond between aggregate and matrix in concrete.SCR can be used to produce a high-strength concrete with better mechanical properties than corresponding concrete made with LCR.The increase of AN and IAPST of aggregate may enhance mechanical properties of concrete.展开更多
While the fully-mechanized longwall mining technology was employed in a shallow seam under a room mining goaf and overlained by thin bedrock and thick loose sands, the roadway pillars in the abandoned room mining goaf...While the fully-mechanized longwall mining technology was employed in a shallow seam under a room mining goaf and overlained by thin bedrock and thick loose sands, the roadway pillars in the abandoned room mining goaf were in a stress-concentrated state, which may cause abnormal roof weighting, violent ground pressure behaviours, even roof fall and hydraulic support crushed(HSC) accidents. In this case,longwall mining safety and efficiency were seriously challenged. Based on the HSC accidents occurred during the longwall mining of 3-1-2 seam, which locates under the intersection zone of roadway pillars in the room mining goaf of 3-1-1 seam, this paper employed ground rock mechanics to analyse the overlying strata structure movement rules and presented the main influence factors and determination methods for the hydraulic support working resistance. The FLAC3 D software was used to simulate the overlying strata stress and plastic zone distribution characteristics. Field observation was implemented to contrastively analyse the hydraulic support working resistance distribution rules under the roadway pillars in strike direction, normal room mining goaf, roadway pillars in dip direction and intersection zone of roadway pillars. The results indicate that the key strata break along with rotations and reactions of the coal pillars deliver a larger concentrated load to the hydraulic support under intersection zone of roadway pillars than other conditions. The ‘‘overburden strata-key strata-roadway pillars-immediate roof" integrated load has exceeded the yield load that leads to HSC accidents. Findings in HSC mechanism provide a reasonable basis for shallow seam mining, and have important significance for the implementation of safe and efficient mining.展开更多
The crushed rocks are used as a filling material in mined丒out areas of underground mining. Compared with the man-made filling materials, the crushed rocks exhibit higher compressibility and lower stability, which may...The crushed rocks are used as a filling material in mined丒out areas of underground mining. Compared with the man-made filling materials, the crushed rocks exhibit higher compressibility and lower stability, which may result in instability of surrounding rock and surface subsidence. To study the creep compaction behavior of crushed mudstones, a series of creep tests are conducted. The investigations show that the creep compaction behavior of crushed mudstones is highly dependent on the original grain composition and axial stress applied on the samples. The samples with more large particles are easier to deform at initial loading stage for more large voids existed in the samples, and exhibit greater stability than those with smaller particles when the axial stress less than the bearing capacity of uframework structure When the axial stress is higher than 20 MPa, the influences of grain composition on deformability of crushed mudstones are weakened after the samples experience repeated compression. At lower stress level, the creep behavior prefers to occur in the samples w.h smaller particles, which is mainly caused by particles flow without significant particle breakage. As the axial stress increases, the single-sized sample with smaller particle size and the well-graded sample with larger Talbol power exponent n present more unstable under the constant stress. In addition, the filling of the residual intergranular voids by small particles formed by crushing and splitting behavior is the main cause of creep deformation. Lastly, a creep equation of crushed mudstones is obtained in this paper, which can agree with the experimental results in good.展开更多
It has been proven that crushed rock layers used in roadbed construction in permafrost regions have a cooling effect. The main reason is the existence of large porosity of the rock layers. However, due to the strong w...It has been proven that crushed rock layers used in roadbed construction in permafrost regions have a cooling effect. The main reason is the existence of large porosity of the rock layers. However, due to the strong winds, cold and high radiation conditions on the Qinghai-Tibet Plateau(QTP), both wind-blown sand and/or weathered rock debris blockage might reduce the porosity of the rock layers, resulting in weakening the cooling effect of the crushed rock layer(CRL) in the crushed rock embankment(CRE) of the Qinghai-Tibet Railway(QTR) in the permafrost regions. Such a process might warm the underlying permafrost, and further lead to potential threat to the QTR's integrity and stability. The different porosities corresponding to the different equivalent rock diameters were measured in the laboratory using water saturation method, and an empirical exponential equation between porosity and equivalent rock diameter was proposed based on the measured experimental data and an important finding is observed in our and other experiments that the larger size crushed rock tends to lead to the larger porosity when arbitrarily packing. Numerical tests were carried out to study impacts of porosity on permafrost degradation and differential thaw depths between the sunny and shady shoulders. The results show that the decrease in porosity due to wind-blown sand or weathered rock debris clogging can worsen the permafrost degradation and lead to the asymmetric thermal regime. In the traditional embankment(without the CRL within it), the largest differential thaw depth can reach up to 3.1 m. The optimized porosity appears in a range from 34% to 42% corresponding to equivalent rock diameter from 10 to 20.5 cm. The CRE with the optimized porosities can make underlying permafrost stable and 0 ℃ isotherms symmetric in the coming 50 years, even under the condition that the climate warming can lead to permafrost degradation under the CRE and the traditional embankment. Some practical implications were proposed to benefit the future design, construction and maintenance of CRE in permafrost regions.展开更多
Shale cuttings and cores recovered from the subsurface and stored for hours to decades tend to dry out and lose moisture and hydrocarbons,leading to an increase in the effective matrix permeability.Moisture loss in sh...Shale cuttings and cores recovered from the subsurface and stored for hours to decades tend to dry out and lose moisture and hydrocarbons,leading to an increase in the effective matrix permeability.Moisture loss in shale samples is a fundamental sample preservation problem which can be solved by applying a standard moisture equilibration procedure to restore lost moisture.Our aim was to investigate the relationship between permeability and variable moisture as-received,as-received moisture-equilibrated and saturated moisture-equilibrated samples.Samples were crushed to a series of particle sizes(0.6-2.0)mm and moisture equilibrated at 97% relative humidity.Results show that moisture equilibration in the samples was achieved after 72 h.The permeability of the saturated moisture-equilibrated and as-received moisture-equilibrated samples decreased exponentially with increase in moisture content.The high correlation coefficient between permeability and particle size(r = 0.96 and 0.97)for moisture-equilibrated samples compared to 0.76 for as-received samples indicates that moisture equilibration improves permeability measurements in crushed shale samples.Furthermore,permeability measurements are repeatable for moisture-equilibrated samples compared to samples that were not equilibrated(as-received).We conclude that moisture content affects permeability and moisture equilibration normalizes and improves the repeatability of permeability measurements in crushed shale.展开更多
The clayish crushed stone was used for making aerated concrete. Through studying hydro-thermal synthesis reaction, mix ratio, gas-forming and performance analysis, Grade-B05 and Grade-B06 aerated concrete were prepare...The clayish crushed stone was used for making aerated concrete. Through studying hydro-thermal synthesis reaction, mix ratio, gas-forming and performance analysis, Grade-B05 and Grade-B06 aerated concrete were prepared successfully. The proper mix ratio and key processing parameters were achieved. The microstructure of aerated concrete with crush stone was analyzed by means of XRD and SEM. The experimental results indicate that the hydration products are poorly crystalline C- S- H （ B ）, tobermorite and hydrogarnet. No componeat of clay was found. Unreacted SiO2 cart be in existence, and the structure system of aerated concrete is homogencous and dense.展开更多
Plasmonic nanostructure-mediated photothermal therapy(PTT) has proven to be a promising approach for cancer treatment,and new approaches for its effective delivery to tumor lesions are currently being developed.This s...Plasmonic nanostructure-mediated photothermal therapy(PTT) has proven to be a promising approach for cancer treatment,and new approaches for its effective delivery to tumor lesions are currently being developed.This study aimed to assess macrophage-mediated delivery of PTT using radioiodine-124-labeled gold nanoparticles with crushed gold shells(124I-Au@AuCBs) as a theranostic nanoplatform.124I-Au@AuCBs exhibited effective photothermal conversion effects both in vitro and in vivo and were efficiently taken up by macrophages without cytotoxicity.After the administration of 124I-Au@AuCB-labeled macrophages to colon tumors,intensive signals were observed at tumor lesions,and subsequent in vivo PTT with laser irradiation yielded potent antitumor effects.The results indicate the considerable potential of 124I-Au@AuCBs as novel theranostic nanomaterials and the prominent advantages of macrophage-mediated cellular therapies in treating cancer and other diseases.展开更多
Based on the analysis and comparison of soil temperature, thermal regime and permafrost table under the experimental embankment of crushed rock structures in Beiluhe, results show that crushed rock structures provide ...Based on the analysis and comparison of soil temperature, thermal regime and permafrost table under the experimental embankment of crushed rock structures in Beiluhe, results show that crushed rock structures provide an extensive cooling effect, which produces a rising permafrost table and decreasing soil temperatures. The rise of the permafrost table under the embankment ranges from an increase of 1.08 m to 1.67 m, with an average of 1.27 m from 2004 to 2007. Mean annual soil temperatures under the crushed rock layer embankment decreased significantly from 2005 to 2007, with average decreases of ?1.03 °C at the depth of 0.5 m, ?1.14 °C at the depth of 1.5 m, and ?0.5 °C at the depth of 5 m. During this period, mean annual soil temperatures under the crushed rock cover embankment showed a slight decrease at shallow depths, with an average decrease of ?0.2 °C at the depth of 0.5 m and 1.5 m, but a slight rise at the depth of 5 m. After the crushed rock structures were closed or crammed with sand, the cooling effect of the crushed rock layer embankment was greatly reduced and that of the crushed rock cover embankment was just slightly reduced.展开更多
Permafrost （perennially frozen ground） appears widely in the Golmud-Lhasa section of the Qinghai-Tibet railway and is characterized by high ground temperature （≥1℃） and massive ground ice. Under the scenarios of...Permafrost （perennially frozen ground） appears widely in the Golmud-Lhasa section of the Qinghai-Tibet railway and is characterized by high ground temperature （≥1℃） and massive ground ice. Under the scenarios of global warming and human activity, the permafrost under the railway will gradually thaw and the massive ground ice will slowly melt, resulting in some thaw settlement hazards, which mainly include longitudinal and lateral cracks, and slope failure. The crushed rock layer has a thermal semiconductor effect under the periodic fluctuation of natural air. It can be used to lower the temperature of the underlying permafrost along the Qinghai-Tibet railway, and mitigate the thaw settlement hazards of the subgrade. In the present paper, the daily and annual changes in the thermal characteristics of the embankment with crushed rock side slope （ECRSS） were quantitatively simulated using the numerical method to study the cooling effect of the crushed rock layer and its mitigative ability. The results showed that the ECRSS absorbed some heat in the daytime in summer, but part of it was released at night, which accounted for approximately 20% of that absorbed. Within a year, it removed more heat from the railway subgrade in winter than that absorbed in summer. It can store approximately 20% of the ＂cold＂ energy in subgrade. Therefore, ECRSS is a better measure to mitigate thaw settlement hazards to the railway.展开更多
Crushed rock subgrade, as one of the roadbed-cooling methods, has been widely used in the Qinghai-Tibet Railway. Much attention has been paid on the cooling effect of crushed rock; however, the mechanical properties o...Crushed rock subgrade, as one of the roadbed-cooling methods, has been widely used in the Qinghai-Tibet Railway. Much attention has been paid on the cooling effect of crushed rock; however, the mechanical properties of crushed rock are somehow neglected. Based on the discrete element method, biaxial compression test condition for crushed rock is com- piled in FISH language in PFC2D, and the natural shape of crushed rock is simulated with super particle ＂cluster＂. The ef- fect of particle size, crushed rock strength and confining pressure level on overall mechanical properties of the crushed rock aggregate are respectively analyzed. Results show that crushed rock of large particle size plays an essential frame- work role, which is mainly responsible for the deformation of crushed rock aggregate. The strength of gravel has a great influence on overall mechanical properties which means that strength attenuation caused by the freeze thaw cycles cannot be ignored. The stress-strain curves can be divided into two stages including shear contraction and shear expansion at different confining pressures.展开更多
Based on data monitored in situ and theoretical analysis,the characteristics of the temperature field and mechanism of thermal conduction of a crushed rock embankment were studied along the Qinghai-Tibet Railway.The r...Based on data monitored in situ and theoretical analysis,the characteristics of the temperature field and mechanism of thermal conduction of a crushed rock embankment were studied along the Qinghai-Tibet Railway.The results of experi-ments in the field revealed that the cooling effect of a crushed rock embankment is influenced mainly by the natural con-vection in winter and shield effect in summer,the ventilation of crushed rocks,and the ground temperature regime be-neath the embankment.Consequently,these three factors should be taken into account in numerical simulations,but it is as a result of natural convection only.展开更多
An efficient technology of impregnation of carbonate crushed stone by oil-product based on SCF-impregnation process usage with propane/butane solvent was developed. Regular impregnation throughout the volume of crushe...An efficient technology of impregnation of carbonate crushed stone by oil-product based on SCF-impregnation process usage with propane/butane solvent was developed. Regular impregnation throughout the volume of crushed stone sample is achieved. As a result of the appliance of proposed technology, the humidity of the treated crushed stone samples decreased down to 0.54%.展开更多
This paper deals with a new type of crushed stone grouting pile with a rigid bearing plate. The load transfer characteristics were analyzed, and a settlement model of the composite foundation reinforced with crushed s...This paper deals with a new type of crushed stone grouting pile with a rigid bearing plate. The load transfer characteristics were analyzed, and a settlement model of the composite foundation reinforced with crushed stone grouting pile and rigid bearing plate was built by FEM program. The effects of replacement ratio of capping plate, replacement ratio of pile, replacement ratio of grout diffusion zone, pile-soil modulus ratio, and serous-soil modulus ratio, on the composite foundation settlement were discussed. It is concluded that the proposed crushed stone grouting pile with a rigid bearing plate is effective in decreasing the settlement of composite foundation.展开更多
Rational rock-explosive matching is of great importance to enhancing explosive energy effective utilization and improving rock fragmentation effect.The traditionally emphasized method of acoustic impedance matching is...Rational rock-explosive matching is of great importance to enhancing explosive energy effective utilization and improving rock fragmentation effect.The traditionally emphasized method of acoustic impedance matching is not rational.Based on blasting breakage mechanism,a new theory of rock-explosive matching in drilling and blasting is proposed.The new approach chooses explosive parameters by reasonable control of the size of crushed zone under the condition of fully fragmentation between adjacent blast holes.This method can directly reflect the blasting fragmentation effect and energy effective utilization,which is easy to implement.Also,a modified model is developed,taken adjacent blast hole blasting loading into account.As a result,explosive parameters of different grades of rock are given in full coupling on-site mixed explosive charge for different project objectives.展开更多
Physical properties and geometrical morphologies of crushed air-cooled blast furnace slag （SCR） and crushed limestone （LCR） were comparatively investigated. The shape, angularity, surface texture and internal pore...Physical properties and geometrical morphologies of crushed air-cooled blast furnace slag （SCR） and crushed limestone （LCR） were comparatively investigated. The shape, angularity, surface texture and internal pore structure of aggregate particles for different size and gradation were numerically represented by sphericity （ψ） and shape index （SI）, angularity number （AN）, index of aggregate particle shape and texture （IAPST）, porosity and pore size, respectively. The results show that SCR is a porous and rough aggregate. Apparent density, void, water absorption and smashing index of SCR are obviously higher than those of LCR with the same gradation, respectively. However, bulk density of SCR is lower than that of LCR with the same gradation. SI, AN, IAPST and porosity of SCR are obviously higher than those of LCR with the same gradation, respectively. The smaller particle size of SCR, the larger of its AN, IAPST and porosity.展开更多
With growing interest in resource recovery and/or reuse,wastematerials have been considered a promising alternative for phosphorus(P)adsorption because they are low-cost and easily accessible.Crushed autoclaved aerate...With growing interest in resource recovery and/or reuse,wastematerials have been considered a promising alternative for phosphorus(P)adsorption because they are low-cost and easily accessible.Crushed autoclaved aerated concrete(CAAC),as representative construction waste,has been extensively studied for P removal in ecological technologies such as treatment wetlands.However,most of the previous studies focused on the adsorption of orthophosphate,namely reactive phosphorus,and lacked attention to non-reactive phosphorus(NRP)which is widely present in sewage.This study presents the first investigation on the potential and mechanism of CAAC removing four model NRP compounds.Adsorption isotherm and kinetics of NRP onto CAAC indicate that the removal of NRP was a chemisorption process and also involved a two-step pore diffusion process.The desorption experiment shows that different NRP species showed varying degrees of desorption.Most NRP was irreversibly adsorbed on CAAC.Among the model compounds considered in this study,the adsorption capacity and hydrolysis rate of organophosphorus were much less than that of inorganic phosphorus.Moreover,the adsorption of different NRP species by CAAC in the mesocosm study was different from the results of laboratory adsorption experiments,and the possible biodegradation was essential for the conversion and removal of NRP.The findings confirmed the validity of CAAC for NRP removal and the potential advantages of CAAC in terms of costs and environmental impact.This study will contribute to a better understanding of NRP conversion and environmental fate and that can be the basis for a refined risk assessment.展开更多
According to the morphological characteristics of crushed stone,the sphericity was introduced to establish the theoretical calculation model of volume fraction of interfacial transition zone(ITZ)around crushed stone.T...According to the morphological characteristics of crushed stone,the sphericity was introduced to establish the theoretical calculation model of volume fraction of interfacial transition zone(ITZ)around crushed stone.The sphericity of crushed stone was obtained by image processing technology and numerical statistics.The experimental results show that when the maximum particle size of coarse aggregate is less than 31.5 mm,the practical sphericity is generally around 0.75,while the sphericity of sand is generally above 0.85.And the closer to 1 the practical sphericity is,the smaller the ITZ volume fraction(V_(ITZ))is,that is,the closer to spherical shape the aggregate is,the lower the ITZ content in concrete is.The V_(ITZ) and ITZ thickness in concrete and mortar have a linear relationship,and the ITZ content in concrete is lower than that in mortar at the same aggregate volume fraction.展开更多
A series of undrained triaxial tests was conducted to investigate the effect of crushed mudstone with the immersion-induced degradation on the liquefaction and post-liquefaction properties,and the undrained shearing b...A series of undrained triaxial tests was conducted to investigate the effect of crushed mudstone with the immersion-induced degradation on the liquefaction and post-liquefaction properties,and the undrained shearing behavior without precedent cyclic-loading histories of sands containing crushed mudstone.The tested materials with a main particle diameter of 2-0.85 mm were prepared by mixing sands and crushed mudstone to reach the prescribed mudstone content defined by dry mass ranging from 0% to 50%.The mixtures were subjected to immersion under a certain stress level and were subsequently tested.In addition,one-dimensional compression tests were also supplementally performed to visually observe the immersion-induced degradation of crushed mudstone.The test results mainly showed that: (1) the liquefaction resistance,the post-liquefaction undrained strength,and the undrained strength without a precedent cyclic-loading history decreased significantly with increasing mudstone content,M c ,up to 20%;(2) even a small amount of crushed mudstone affected these strengths;(3) the above-mentioned large reductions in the strengths were attributed to the immersion-induced degradation of crushed mudstone;(4) at M_(c) >20%,the liquefaction resistance increased while the significant increase in the undrained static strengths with and without precedent cyclic-loading histories was not observed;and (5) the increase in the liquefaction resistance at M_(c) >20% may have been attributed to both the gradual increase in the plasticity and the formation of the soil aggregates among deteriorated crushed mudstone,while the increase in the specimen density did not play an important role in such behavior.展开更多
To contribute to the enhancement of unconventional local materials used for road construction,this study characterizes a crushed sand 0/5,a clayey soil and the litho-stabilized material without and with hydraulic bind...To contribute to the enhancement of unconventional local materials used for road construction,this study characterizes a crushed sand 0/5,a clayey soil and the litho-stabilized material without and with hydraulic binder and determines their use in accordance with some reference specifications(CEBTP 1984).It is shown that the different components are not usable alone in pavement base.Indeed,the plasticity index obtained for the clayey soil is 21%,a value higher than the imposed standards.In addition,the grading of the 0/5 crushed sand does not fit into the range proposed by CEBTP.A combination of these two(02)components is therefore considered to obtain a suitable material usable for the sub-base.This new material does not enter any class of the CEBTP lateritic soils.In order to be used in base layer,a treatment with hydraulic binder is carried out with the intention to improve its mechanical performances.The optimal dosage of hydraulic binder to achieve the desired mechanical performance is obtained by studying the evolution of the mechanical characteristics of the mixture.After this treatment,the Bearing Ratio index of the mix increases from 37 to 223 for the optimal dosage and the dry compaction density decreases from 2.11 to 2.06 g/cm3 while the optimal water content increases from 9%to 10.1%.展开更多
基金support from China National Natural Science Foundation (11672333)。
文摘The effectiveness of horizontal well multi-stage and multi-cluster fracturing in the fractured soft coal seam roof for coalbed methane(CBM) extraction has been demonstrated.This study focuses on the geological characteristics of the No.5 and No.11 coal seams in the Hancheng Block,Ordos Basin,China.A multi-functional,variable-size rock sample mold capable of securing the wellbore was developed to simulate layered formations comprising strata of varying lithology and thicknesses.A novel segmented fracturing simulation method based on an expandable pipe plugging technique is proposed.Large-scale true triaxial experiments were conducted to investigate the effects of horizontal wellbore location,perforation strategy,roof lithology,and vertical stress difference on fracture propagation,hydraulic energy variation,and the stimulated reservoir volume in horizontal wells targeting the soft coal seam roof.The results indicate that bilateral downward perforation with a phase angle of 120° optimizes hydraulic energy conservation,reduces operational costs,enhances fracture formation,and prevents fracturing failure caused by coal powder generation and migration.This perforation mode is thus considered optimal for coal seam roof fracturing.When the roof consists of sandstone,each perforation cluster tends to initiate a single dominant fracture with a regular geometry.In contrast,hydraulic fractures formed in mudstone roofs display diverse morphology.Due to its high strength,the sandstone roof requires significantly higher pressure for crack initiation and propagation,whereas the mudstone roof,with its strong water sensitivity,exhibits lower fracturing pressures.To mitigate inter-cluster interference,cluster spacing in mudstone roofs should be greater than that in sandstone roofs.Horizontal wellbore placement critically influences fracturing effectiveness.For indirect fracturing in sandstone roofs,an optimal position is 25 mm away from the lithological interface.In contrast,the optimal location for indirect fracturing in mudstone roofs is directly at the lithological interface with the coal seam.Higher vertical stress coefficients lead to increased fractu ring pressures and promote vertical,layer-penetrating fractures.A coefficient of 0.5 is identified as optimal for achieving effective indirect fracturing.This study provides valuable insights for the design and optimization of staged fracturing in horizontal wells targeting crushed soft coal seam roofs.
基金Funded by the National Basic Research Program of China(2009CB623105)the Natural Science Foundation of Education Agency of Anhui Province (KJ2012A052)+1 种基金the Anhui Provincial Natural ScienceFoundation(1208085ME82)the Doctor Fund of Anhui University of Architecture(20123302)
文摘Morphology characteristics of mix aggregates with crushed air-cooled blast furnace slag（SCR） and crushed limestone（LCR） with 5-20 mm and 20-40 mm gradation were represented by numerical parameters including angularity number（AN） and index of aggregate particle shape and texture（IAPST）.The effect of mix aggregates containing SCR on compressive strength and splitting tensile strength of concrete was investigated.Fracture characteristics of concrete,interfacial structure between aggregates and matrix were analyzed.The experimental results show that porous and rough SCR increases contact area with matrix in concrete,concave holes and micro-pores on the surface of SCR are filled by mortar and hydrated cement paste,which may increase interlocking and mechanical bond between aggregate and matrix in concrete.SCR can be used to produce a high-strength concrete with better mechanical properties than corresponding concrete made with LCR.The increase of AN and IAPST of aggregate may enhance mechanical properties of concrete.
基金financially supported by the Fundamental Research Funds for the Central Universities of China(NO.2015XKMS002)the Priority Academic Program Development of Jiangsu Higher Education Institutions of Chinagratefully acknowledge financial support of the above-mentioned agencies
文摘While the fully-mechanized longwall mining technology was employed in a shallow seam under a room mining goaf and overlained by thin bedrock and thick loose sands, the roadway pillars in the abandoned room mining goaf were in a stress-concentrated state, which may cause abnormal roof weighting, violent ground pressure behaviours, even roof fall and hydraulic support crushed(HSC) accidents. In this case,longwall mining safety and efficiency were seriously challenged. Based on the HSC accidents occurred during the longwall mining of 3-1-2 seam, which locates under the intersection zone of roadway pillars in the room mining goaf of 3-1-1 seam, this paper employed ground rock mechanics to analyse the overlying strata structure movement rules and presented the main influence factors and determination methods for the hydraulic support working resistance. The FLAC3 D software was used to simulate the overlying strata stress and plastic zone distribution characteristics. Field observation was implemented to contrastively analyse the hydraulic support working resistance distribution rules under the roadway pillars in strike direction, normal room mining goaf, roadway pillars in dip direction and intersection zone of roadway pillars. The results indicate that the key strata break along with rotations and reactions of the coal pillars deliver a larger concentrated load to the hydraulic support under intersection zone of roadway pillars than other conditions. The ‘‘overburden strata-key strata-roadway pillars-immediate roof" integrated load has exceeded the yield load that leads to HSC accidents. Findings in HSC mechanism provide a reasonable basis for shallow seam mining, and have important significance for the implementation of safe and efficient mining.
基金This research was supported by the National Natural Science Foundation of China (Grant No. 51479195)the National Key Research and Development Plan of China (2016YFC0600901)+1 种基金the Special Fund of Basic Research and Operating of China University of Mining and Technology, Beijing (Grant No. 2009QL06)the State Scholarship Fund of China.
文摘The crushed rocks are used as a filling material in mined丒out areas of underground mining. Compared with the man-made filling materials, the crushed rocks exhibit higher compressibility and lower stability, which may result in instability of surrounding rock and surface subsidence. To study the creep compaction behavior of crushed mudstones, a series of creep tests are conducted. The investigations show that the creep compaction behavior of crushed mudstones is highly dependent on the original grain composition and axial stress applied on the samples. The samples with more large particles are easier to deform at initial loading stage for more large voids existed in the samples, and exhibit greater stability than those with smaller particles when the axial stress less than the bearing capacity of uframework structure When the axial stress is higher than 20 MPa, the influences of grain composition on deformability of crushed mudstones are weakened after the samples experience repeated compression. At lower stress level, the creep behavior prefers to occur in the samples w.h smaller particles, which is mainly caused by particles flow without significant particle breakage. As the axial stress increases, the single-sized sample with smaller particle size and the well-graded sample with larger Talbol power exponent n present more unstable under the constant stress. In addition, the filling of the residual intergranular voids by small particles formed by crushing and splitting behavior is the main cause of creep deformation. Lastly, a creep equation of crushed mudstones is obtained in this paper, which can agree with the experimental results in good.
基金Project(2012CB026101)supported by the National Key Basic Research Program of China(973 Program)Project(41121061)supported by the Program for Innovative Research Group of Natural Science Foundation of China+2 种基金Project(143GKDA007)supported by the Science and Technology Major Project of the Gansu ProvinceProject(SKLFSE-ZY-16)supported by the State Key Laboratory of Frozen Soil Engineering,ChinaProject supported by the West Light Foundation of CAS for G.Y.Li
文摘It has been proven that crushed rock layers used in roadbed construction in permafrost regions have a cooling effect. The main reason is the existence of large porosity of the rock layers. However, due to the strong winds, cold and high radiation conditions on the Qinghai-Tibet Plateau(QTP), both wind-blown sand and/or weathered rock debris blockage might reduce the porosity of the rock layers, resulting in weakening the cooling effect of the crushed rock layer(CRL) in the crushed rock embankment(CRE) of the Qinghai-Tibet Railway(QTR) in the permafrost regions. Such a process might warm the underlying permafrost, and further lead to potential threat to the QTR's integrity and stability. The different porosities corresponding to the different equivalent rock diameters were measured in the laboratory using water saturation method, and an empirical exponential equation between porosity and equivalent rock diameter was proposed based on the measured experimental data and an important finding is observed in our and other experiments that the larger size crushed rock tends to lead to the larger porosity when arbitrarily packing. Numerical tests were carried out to study impacts of porosity on permafrost degradation and differential thaw depths between the sunny and shady shoulders. The results show that the decrease in porosity due to wind-blown sand or weathered rock debris clogging can worsen the permafrost degradation and lead to the asymmetric thermal regime. In the traditional embankment(without the CRL within it), the largest differential thaw depth can reach up to 3.1 m. The optimized porosity appears in a range from 34% to 42% corresponding to equivalent rock diameter from 10 to 20.5 cm. The CRE with the optimized porosities can make underlying permafrost stable and 0 ℃ isotherms symmetric in the coming 50 years, even under the condition that the climate warming can lead to permafrost degradation under the CRE and the traditional embankment. Some practical implications were proposed to benefit the future design, construction and maintenance of CRE in permafrost regions.
基金supported in part by Grants-in-Aid Fund from the American Association of Petroleum Geologists and National Association of Black Geoscientists
文摘Shale cuttings and cores recovered from the subsurface and stored for hours to decades tend to dry out and lose moisture and hydrocarbons,leading to an increase in the effective matrix permeability.Moisture loss in shale samples is a fundamental sample preservation problem which can be solved by applying a standard moisture equilibration procedure to restore lost moisture.Our aim was to investigate the relationship between permeability and variable moisture as-received,as-received moisture-equilibrated and saturated moisture-equilibrated samples.Samples were crushed to a series of particle sizes(0.6-2.0)mm and moisture equilibrated at 97% relative humidity.Results show that moisture equilibration in the samples was achieved after 72 h.The permeability of the saturated moisture-equilibrated and as-received moisture-equilibrated samples decreased exponentially with increase in moisture content.The high correlation coefficient between permeability and particle size(r = 0.96 and 0.97)for moisture-equilibrated samples compared to 0.76 for as-received samples indicates that moisture equilibration improves permeability measurements in crushed shale samples.Furthermore,permeability measurements are repeatable for moisture-equilibrated samples compared to samples that were not equilibrated(as-received).We conclude that moisture content affects permeability and moisture equilibration normalizes and improves the repeatability of permeability measurements in crushed shale.
文摘The clayish crushed stone was used for making aerated concrete. Through studying hydro-thermal synthesis reaction, mix ratio, gas-forming and performance analysis, Grade-B05 and Grade-B06 aerated concrete were prepared successfully. The proper mix ratio and key processing parameters were achieved. The microstructure of aerated concrete with crush stone was analyzed by means of XRD and SEM. The experimental results indicate that the hydration products are poorly crystalline C- S- H （ B ）, tobermorite and hydrogarnet. No componeat of clay was found. Unreacted SiO2 cart be in existence, and the structure system of aerated concrete is homogencous and dense.
基金supported by National Research Foundation of Korea(NRF) grants funded by the Korea Government(MSIP)a grant from the Korea Health Technology R&D Project through the Korea Health Industry Development Institute(KHIDI) funded by the Ministry of Health&Welfare,Republic of Korea(HI16C1501)+1 种基金a grant from the Medical Cluster R&D Support Project through the Daegu-Gyeongbuk Medical Innovation Foundation(DGMIF) funded by the Ministry of Health and Welfare(HT16C0001,HT16C0002,HT17C0009)a National Research Foundation of Korea(NRF) Grant funded by the Korea Government(MSIP)(2014R1A1A1003323,2017R1D1A1B03028340,2018R1D1AB07047417)
文摘Plasmonic nanostructure-mediated photothermal therapy(PTT) has proven to be a promising approach for cancer treatment,and new approaches for its effective delivery to tumor lesions are currently being developed.This study aimed to assess macrophage-mediated delivery of PTT using radioiodine-124-labeled gold nanoparticles with crushed gold shells(124I-Au@AuCBs) as a theranostic nanoplatform.124I-Au@AuCBs exhibited effective photothermal conversion effects both in vitro and in vivo and were efficiently taken up by macrophages without cytotoxicity.After the administration of 124I-Au@AuCB-labeled macrophages to colon tumors,intensive signals were observed at tumor lesions,and subsequent in vivo PTT with laser irradiation yielded potent antitumor effects.The results indicate the considerable potential of 124I-Au@AuCBs as novel theranostic nanomaterials and the prominent advantages of macrophage-mediated cellular therapies in treating cancer and other diseases.
基金supported by The Outstanding Youth Foundation Project, National Natural Science Foundation of China (Grant No. 40625004) the grant of the Western Project Program of the Chinese Academy of Sciences (No. KZCX2-XB2-10)
文摘Based on the analysis and comparison of soil temperature, thermal regime and permafrost table under the experimental embankment of crushed rock structures in Beiluhe, results show that crushed rock structures provide an extensive cooling effect, which produces a rising permafrost table and decreasing soil temperatures. The rise of the permafrost table under the embankment ranges from an increase of 1.08 m to 1.67 m, with an average of 1.27 m from 2004 to 2007. Mean annual soil temperatures under the crushed rock layer embankment decreased significantly from 2005 to 2007, with average decreases of ?1.03 °C at the depth of 0.5 m, ?1.14 °C at the depth of 1.5 m, and ?0.5 °C at the depth of 5 m. During this period, mean annual soil temperatures under the crushed rock cover embankment showed a slight decrease at shallow depths, with an average decrease of ?0.2 °C at the depth of 0.5 m and 1.5 m, but a slight rise at the depth of 5 m. After the crushed rock structures were closed or crammed with sand, the cooling effect of the crushed rock layer embankment was greatly reduced and that of the crushed rock cover embankment was just slightly reduced.
基金supported by the National Natural Science Foundation of China(Grant Nos 40801022 and 40821001)the Chinese Academy of Sciences(CAS) Knowledge Innovation Key Directional Program(Grant Nos KZCX2-YW-Q03-04 and KZCX2-YW-311)+2 种基金CAS Western Project(Grant No.KZCX2-XB2-10)China Postdoctoral Science Foundation(No.20080430110)CAS 100-Talent Programs"Stability of Linear Engineering Foundations in Warm Permafrost Regions under a Changing Climate"and"Deformation and Stability of Roadbed in Permafrost Regions",CAS West Light Foundation for PhD G.Y.Li,Funds of the State Key Laboratory of Frozen Soils Engineering,CAS(Grant Nos SKLFSE-ZQ-02 and SKLFSE-ZY-03)
文摘Permafrost （perennially frozen ground） appears widely in the Golmud-Lhasa section of the Qinghai-Tibet railway and is characterized by high ground temperature （≥1℃） and massive ground ice. Under the scenarios of global warming and human activity, the permafrost under the railway will gradually thaw and the massive ground ice will slowly melt, resulting in some thaw settlement hazards, which mainly include longitudinal and lateral cracks, and slope failure. The crushed rock layer has a thermal semiconductor effect under the periodic fluctuation of natural air. It can be used to lower the temperature of the underlying permafrost along the Qinghai-Tibet railway, and mitigate the thaw settlement hazards of the subgrade. In the present paper, the daily and annual changes in the thermal characteristics of the embankment with crushed rock side slope （ECRSS） were quantitatively simulated using the numerical method to study the cooling effect of the crushed rock layer and its mitigative ability. The results showed that the ECRSS absorbed some heat in the daytime in summer, but part of it was released at night, which accounted for approximately 20% of that absorbed. Within a year, it removed more heat from the railway subgrade in winter than that absorbed in summer. It can store approximately 20% of the ＂cold＂ energy in subgrade. Therefore, ECRSS is a better measure to mitigate thaw settlement hazards to the railway.
基金supported by National 973 Project of China (No. 2012CB026104)National Natural Science Foundation of China (Nos. 41171064, 41371081)the Fundamental Research Funds for the Central Universities (No. 2011JBZ009)
文摘Crushed rock subgrade, as one of the roadbed-cooling methods, has been widely used in the Qinghai-Tibet Railway. Much attention has been paid on the cooling effect of crushed rock; however, the mechanical properties of crushed rock are somehow neglected. Based on the discrete element method, biaxial compression test condition for crushed rock is com- piled in FISH language in PFC2D, and the natural shape of crushed rock is simulated with super particle ＂cluster＂. The ef- fect of particle size, crushed rock strength and confining pressure level on overall mechanical properties of the crushed rock aggregate are respectively analyzed. Results show that crushed rock of large particle size plays an essential frame- work role, which is mainly responsible for the deformation of crushed rock aggregate. The strength of gravel has a great influence on overall mechanical properties which means that strength attenuation caused by the freeze thaw cycles cannot be ignored. The stress-strain curves can be divided into two stages including shear contraction and shear expansion at different confining pressures.
基金supported in part by the grant of the Western Project Program of the Chinese Academy of Sciences (KZCX2-XB2-10)the Program for Innovative Research Group of Natural Science Foundation of China (No. 40821001)
文摘Based on data monitored in situ and theoretical analysis,the characteristics of the temperature field and mechanism of thermal conduction of a crushed rock embankment were studied along the Qinghai-Tibet Railway.The results of experi-ments in the field revealed that the cooling effect of a crushed rock embankment is influenced mainly by the natural con-vection in winter and shield effect in summer,the ventilation of crushed rocks,and the ground temperature regime be-neath the embankment.Consequently,these three factors should be taken into account in numerical simulations,but it is as a result of natural convection only.
文摘An efficient technology of impregnation of carbonate crushed stone by oil-product based on SCF-impregnation process usage with propane/butane solvent was developed. Regular impregnation throughout the volume of crushed stone sample is achieved. As a result of the appliance of proposed technology, the humidity of the treated crushed stone samples decreased down to 0.54%.
文摘This paper deals with a new type of crushed stone grouting pile with a rigid bearing plate. The load transfer characteristics were analyzed, and a settlement model of the composite foundation reinforced with crushed stone grouting pile and rigid bearing plate was built by FEM program. The effects of replacement ratio of capping plate, replacement ratio of pile, replacement ratio of grout diffusion zone, pile-soil modulus ratio, and serous-soil modulus ratio, on the composite foundation settlement were discussed. It is concluded that the proposed crushed stone grouting pile with a rigid bearing plate is effective in decreasing the settlement of composite foundation.
基金Foundation items： National Science Fund for Distinguished Young Scholars, China （No. 51125037） Natio- nal Basic Research Program of China （No. 2011CB013501） National Natural Science Foundation of China （No. 51279135）
文摘Rational rock-explosive matching is of great importance to enhancing explosive energy effective utilization and improving rock fragmentation effect.The traditionally emphasized method of acoustic impedance matching is not rational.Based on blasting breakage mechanism,a new theory of rock-explosive matching in drilling and blasting is proposed.The new approach chooses explosive parameters by reasonable control of the size of crushed zone under the condition of fully fragmentation between adjacent blast holes.This method can directly reflect the blasting fragmentation effect and energy effective utilization,which is easy to implement.Also,a modified model is developed,taken adjacent blast hole blasting loading into account.As a result,explosive parameters of different grades of rock are given in full coupling on-site mixed explosive charge for different project objectives.
基金Funded by the National Basic Research Program of China(No.2009CB623105)the Natural Science Foundation of Education Agency of Anhui Province(No.KJ2012A052)+1 种基金the Anhui Provincial Natural Science Foundation(No.1208085ME82)the Doctor Fund of Anhui University of Architecture(No.20123302)
文摘Physical properties and geometrical morphologies of crushed air-cooled blast furnace slag （SCR） and crushed limestone （LCR） were comparatively investigated. The shape, angularity, surface texture and internal pore structure of aggregate particles for different size and gradation were numerically represented by sphericity （ψ） and shape index （SI）, angularity number （AN）, index of aggregate particle shape and texture （IAPST）, porosity and pore size, respectively. The results show that SCR is a porous and rough aggregate. Apparent density, void, water absorption and smashing index of SCR are obviously higher than those of LCR with the same gradation, respectively. However, bulk density of SCR is lower than that of LCR with the same gradation. SI, AN, IAPST and porosity of SCR are obviously higher than those of LCR with the same gradation, respectively. The smaller particle size of SCR, the larger of its AN, IAPST and porosity.
基金supported by the Major Science and Technology Program for Water Pollution Control and Treatment in China(No.2017ZX07202004)。
文摘With growing interest in resource recovery and/or reuse,wastematerials have been considered a promising alternative for phosphorus(P)adsorption because they are low-cost and easily accessible.Crushed autoclaved aerated concrete(CAAC),as representative construction waste,has been extensively studied for P removal in ecological technologies such as treatment wetlands.However,most of the previous studies focused on the adsorption of orthophosphate,namely reactive phosphorus,and lacked attention to non-reactive phosphorus(NRP)which is widely present in sewage.This study presents the first investigation on the potential and mechanism of CAAC removing four model NRP compounds.Adsorption isotherm and kinetics of NRP onto CAAC indicate that the removal of NRP was a chemisorption process and also involved a two-step pore diffusion process.The desorption experiment shows that different NRP species showed varying degrees of desorption.Most NRP was irreversibly adsorbed on CAAC.Among the model compounds considered in this study,the adsorption capacity and hydrolysis rate of organophosphorus were much less than that of inorganic phosphorus.Moreover,the adsorption of different NRP species by CAAC in the mesocosm study was different from the results of laboratory adsorption experiments,and the possible biodegradation was essential for the conversion and removal of NRP.The findings confirmed the validity of CAAC for NRP removal and the potential advantages of CAAC in terms of costs and environmental impact.This study will contribute to a better understanding of NRP conversion and environmental fate and that can be the basis for a refined risk assessment.
基金Funded by the National Natural Science Foundations of China(No.52178237)the Graduate Innovation Fund of Shijiazhuang Tie Dao University(YC2021064)。
文摘According to the morphological characteristics of crushed stone,the sphericity was introduced to establish the theoretical calculation model of volume fraction of interfacial transition zone(ITZ)around crushed stone.The sphericity of crushed stone was obtained by image processing technology and numerical statistics.The experimental results show that when the maximum particle size of coarse aggregate is less than 31.5 mm,the practical sphericity is generally around 0.75,while the sphericity of sand is generally above 0.85.And the closer to 1 the practical sphericity is,the smaller the ITZ volume fraction(V_(ITZ))is,that is,the closer to spherical shape the aggregate is,the lower the ITZ content in concrete is.The V_(ITZ) and ITZ thickness in concrete and mortar have a linear relationship,and the ITZ content in concrete is lower than that in mortar at the same aggregate volume fraction.
基金financially supported by JSPS KAKENHI Grant Number JP19K15083.
文摘A series of undrained triaxial tests was conducted to investigate the effect of crushed mudstone with the immersion-induced degradation on the liquefaction and post-liquefaction properties,and the undrained shearing behavior without precedent cyclic-loading histories of sands containing crushed mudstone.The tested materials with a main particle diameter of 2-0.85 mm were prepared by mixing sands and crushed mudstone to reach the prescribed mudstone content defined by dry mass ranging from 0% to 50%.The mixtures were subjected to immersion under a certain stress level and were subsequently tested.In addition,one-dimensional compression tests were also supplementally performed to visually observe the immersion-induced degradation of crushed mudstone.The test results mainly showed that: (1) the liquefaction resistance,the post-liquefaction undrained strength,and the undrained strength without a precedent cyclic-loading history decreased significantly with increasing mudstone content,M c ,up to 20%;(2) even a small amount of crushed mudstone affected these strengths;(3) the above-mentioned large reductions in the strengths were attributed to the immersion-induced degradation of crushed mudstone;(4) at M_(c) >20%,the liquefaction resistance increased while the significant increase in the undrained static strengths with and without precedent cyclic-loading histories was not observed;and (5) the increase in the liquefaction resistance at M_(c) >20% may have been attributed to both the gradual increase in the plasticity and the formation of the soil aggregates among deteriorated crushed mudstone,while the increase in the specimen density did not play an important role in such behavior.
文摘To contribute to the enhancement of unconventional local materials used for road construction,this study characterizes a crushed sand 0/5,a clayey soil and the litho-stabilized material without and with hydraulic binder and determines their use in accordance with some reference specifications(CEBTP 1984).It is shown that the different components are not usable alone in pavement base.Indeed,the plasticity index obtained for the clayey soil is 21%,a value higher than the imposed standards.In addition,the grading of the 0/5 crushed sand does not fit into the range proposed by CEBTP.A combination of these two(02)components is therefore considered to obtain a suitable material usable for the sub-base.This new material does not enter any class of the CEBTP lateritic soils.In order to be used in base layer,a treatment with hydraulic binder is carried out with the intention to improve its mechanical performances.The optimal dosage of hydraulic binder to achieve the desired mechanical performance is obtained by studying the evolution of the mechanical characteristics of the mixture.After this treatment,the Bearing Ratio index of the mix increases from 37 to 223 for the optimal dosage and the dry compaction density decreases from 2.11 to 2.06 g/cm3 while the optimal water content increases from 9%to 10.1%.
