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Using crafted features and polar bear optimization algorithm for short-term electric load forecast syste 被引量:1
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作者 Mansi Bhatnagar Gregor Rozinaj Radoslav Vargic 《Energy and AI》 2025年第1期203-217,共15页
Short-term load forecasting(STLF)can be utilized to predict usage fluctuation in a short time period and accurate forecasting can save a big chunk of a country’s economic loss.This paper introduces the crafting of va... Short-term load forecasting(STLF)can be utilized to predict usage fluctuation in a short time period and accurate forecasting can save a big chunk of a country’s economic loss.This paper introduces the crafting of various features for hourly electric load forecasting on three different datasets using four different models XGBoost,LightGBM,Bi-LSTM,and Random Forest.The importance of crafted features over basic features was analysed by different evaluation metrics MAE,RMSE,R-squared,and MAPE.Evaluation metrics showed that prediction accuracy increased significantly with crafted features in comparison to basic features for all four models.We also showcased the ability of the Polar Bear Optimisation(PBO)algorithm for hyperparameter tuning of the machine learning models in STLF.Optimized hyperparameters with PBO effectively decreased RMSE,MAE,and MAPE and improved the model prediction,showcasing the capability of the PBO in hyperparameter tuning for STLF.PBO was compared with commonly used optimization algorithms like particle swarm optimization(PSO)and genetic algorithm(GA).GA was the least performing with XGBoost,LightGBM,and Random Forest.PSO and PBO were comparable with XGBoost LightGBM and Random Forest while PBO highly surpassed PSO with the Bi-LSTM model.Hence PBO was proved to be highly effective for hyperparameter tuning for implementation in short-term electric load forecasting. 展开更多
关键词 Machine learning crafted features Polar bear algorithms Short term load forecast Hyperparameter tunning
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The charm of handcrafted wood carving
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作者 徐静 《疯狂英语(新策略)》 2025年第9期65-65,共1页
I've always been interested in traditional crafts,so when my school organized a workshop on wood carving,an ancient Chinese art form,I signed up right away.The workshop was held in a small studio in the old town.A... I've always been interested in traditional crafts,so when my school organized a workshop on wood carving,an ancient Chinese art form,I signed up right away.The workshop was held in a small studio in the old town.As I walked in,I was greeted by the smell of wood and the sound made by carving wood.The teacher,Mr Zhang,was a master carver with over 30 years of experience.He showed us some of his works-beautiful sculptures of animals and flowers.I was amazed by the skill and patience it must have taken to create them. 展开更多
关键词 SKILL wood carvingan traditional crafts handcrafted PATIENCE carving woodthe Chinese art form wood carving
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CRAFT装置大口径15 T背场磁体偏心状态下可靠性分析
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作者 王智韬 吴永晟 +1 位作者 吴磊 施毅 《低温与超导》 北大核心 2026年第1期28-35,52,共9页
CRAFT核心实验平台导体性能研究平台背场磁体系统的六个分体线圈在制造和装配过程的偏差会造成磁心偏移,磁体磁心偏移在运行过程中会产生额外的电磁载荷,从而显著增加磁体结构件的应力,存在引发部件损坏的风险。本文针对偏心情况进行分... CRAFT核心实验平台导体性能研究平台背场磁体系统的六个分体线圈在制造和装配过程的偏差会造成磁心偏移,磁体磁心偏移在运行过程中会产生额外的电磁载荷,从而显著增加磁体结构件的应力,存在引发部件损坏的风险。本文针对偏心情况进行分类,计算得出额外电磁载荷与偏移量之间的关系,并采用有限元分析方法针对多种偏心载荷开展结构部件的强度分析以及对结构件的安全性进行评估。分析结果表明:在偏心情况下15 T背场磁体结构件具有可靠性。 展开更多
关键词 背场磁体 CRAFT 导体平台 机械分析
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AIGC应用于会计学科教学创新实践与探索——基于PBL+OKR模式
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作者 黄晶 陈志勇 《黑龙江教育(高教研究与评估)》 2026年第4期36-40,共5页
面对生成式人工智能(AIGC)给教育领域带来的深刻变革,会计学亟须创新与之适配的教学模式。基于此,以布鲁姆分类法为指导重构教学目标,依托CRAFT框架,从文化、规则、机会、熟知度与信任五个维度构建支持生态,并结合PBL(问题导向学习法)与... 面对生成式人工智能(AIGC)给教育领域带来的深刻变革,会计学亟须创新与之适配的教学模式。基于此,以布鲁姆分类法为指导重构教学目标,依托CRAFT框架,从文化、规则、机会、熟知度与信任五个维度构建支持生态,并结合PBL(问题导向学习法)与OKR(目标与关键成果法)设计出“问题驱动—目标引领—结果评估”的闭环教学模式。此外,从师资与能力保障、技术与激励保障及持续改进机制三方面提出实施保障策略,为AIGC深度融入会计教学提供从理论设计到实践落地的完整解决方案,以助力培养具备高阶思维与数字化胜任力的新时代会计人才。 展开更多
关键词 AIGC 教学创新 CRAFT框架 PBL+OKR 会计学教学改革
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Cultivating a New Countryside--Smart farming and rural culture are powering revitalisation in Guangdong
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作者 CUI XIAOQIN 《ChinAfrica》 2026年第1期33-35,共3页
At dawn in Wufu Village,in Dinghu District of Zhaoqing City,Guangdong Province,the newly restored Chaoyangli Cultural Retreat is already welcoming its first visitors.A visitor surnamed Chen,who has travelled from Guan... At dawn in Wufu Village,in Dinghu District of Zhaoqing City,Guangdong Province,the newly restored Chaoyangli Cultural Retreat is already welcoming its first visitors.A visitor surnamed Chen,who has travelled from Guangzhou with his child,stops in front of the Chaxi Academy to admire local intangible cultural heritage crafts. 展开更多
关键词 rural culture chaoyangli cultural retreat Wufu Village smart farming chaxi academy intangible cultural heritage crafts revitalisation GUANGDONG
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CRAFT磁体平台6 kW@4.5 K氦制冷机大型卧式真空绝热冷箱设计与应力分析 被引量:1
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作者 李帅勇 张启勇 +1 位作者 陆小飞 何艺轩 《真空与低温》 2025年第4期428-436,共9页
聚变设施主机关键系统综合研究设施(CRAFT)是国家重大科技基础设施项目,超导磁体研究系统是该设施主要的建设和研究内容之一。为开展全尺寸超导磁体的低温性能测试,设计建设了一套6 kW@4.5 K大型氦制冷机,并对该氦制冷机的卧式真空绝热... 聚变设施主机关键系统综合研究设施(CRAFT)是国家重大科技基础设施项目,超导磁体研究系统是该设施主要的建设和研究内容之一。为开展全尺寸超导磁体的低温性能测试,设计建设了一套6 kW@4.5 K大型氦制冷机,并对该氦制冷机的卧式真空绝热冷箱进行了计算验证。根据氦制冷机的制冷流程及冷箱内各个设备尺寸,完成Φ3.8 m×14.5 m大型卧式冷箱三维模型和结构设计。定义了正常工况,分析了冷箱在正常工况下的应力、质量与壁厚的关系,结合国家标准确定了冷箱壁厚,使用有限元分析法计算得到了冷箱在正常工况下受到的应力和应变情况。定义了吊装工况,计算了冷箱在吊装工况下受到的应力与应变情况。对冷箱进行了模态分析,根据抗震标准,人工生成了一组地震波,最后用响应谱分析的方法模拟计算了复合载荷下冷箱外壳的地震响应。研究结果表明壁厚大小与应力应变大小呈非线性负相关,影响程度递减;地震复合载荷下冷箱径向变形很小,主要是轴向变形;本文设计的卧式真空绝热冷箱在不同情况下的结构强度满足6 kW@4.5 K氦制冷机使用要求。 展开更多
关键词 CRAFT 4.5 K氦制冷机 卧式冷箱 应力分析 地震响应谱
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CRAFT磁体测试平台过冷迫流冷却流程设计
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作者 何艺轩 陆小飞 +4 位作者 张启勇 成安义 罗浩 黄国权 程宣搏 《低温与超导》 北大核心 2025年第12期40-46,70,共8页
本文针对中国聚变工程实验堆(CFETR)发展需求,开展了CRAFT磁体测试平台辅助分配阀箱(ACB)的流程设计。设计目标包括为环向场(TF)磁体及其线圈盒提供稳定的超临界氦过冷迫流冷却,以及在无用户工况下具备模拟负荷与开展相关实验的能力。基... 本文针对中国聚变工程实验堆(CFETR)发展需求,开展了CRAFT磁体测试平台辅助分配阀箱(ACB)的流程设计。设计目标包括为环向场(TF)磁体及其线圈盒提供稳定的超临界氦过冷迫流冷却,以及在无用户工况下具备模拟负荷与开展相关实验的能力。基于HYSYS对4.5 K、3.8 K和3 K三种运行模式进行了流程计算与性能评估。结果表明,在现有制冷机和设备条件下,ACB流程能够满足磁体提出的冷量、流量和压头需求,并具备一定的负荷冗余能力。该设计不仅能够支撑CRAFT磁体测试任务,也为未来CFETR超导磁体的迫流冷却技术研发提供了工程基础。 展开更多
关键词 CRAFT 辅助冷箱 迫流冷却 超临界氦 低温技术
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Enchanting Copper Art from Datong
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作者 WANG RUYING 《China Today》 2025年第11期73-75,共3页
OVER 2,000 years ago,the bronze craftsmen in today’s Datong City,Shanxi Province,had already mastered the superb skills of copper production.Datong bronze-making craft was included in China’s state-level intangible ... OVER 2,000 years ago,the bronze craftsmen in today’s Datong City,Shanxi Province,had already mastered the superb skills of copper production.Datong bronze-making craft was included in China’s state-level intangible cultural heritage list in 2014.The craftsmanship which has been passed down through the millennia still shines brightly today after countless hammer blows and engravings. 展开更多
关键词 bronze making craft bronze craftsmen hammer blows engravings copper art intangible cultural heritage millennia Datong
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Rediscovering the Charm of an Old Craft
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作者 LIU CHANG 《China Today》 2025年第7期66-69,共4页
A young artist reinvents an old sartorial skill from rural ethnic communities into globally recognized high fashion.LACKING a unified writing system,the ancestors of the Miao people,an ethnic group primarily living in... A young artist reinvents an old sartorial skill from rural ethnic communities into globally recognized high fashion.LACKING a unified writing system,the ancestors of the Miao people,an ethnic group primarily living in mountainous areas in central and southwestern China,encoded their history in the exquisite design of traditional clothing,especially embroidery.They express reverence for nature and appreciation of life with needles and threads. 展开更多
关键词 young artist reinventing high fashion Miao people traditional clothing needles threads old craft rediscovering
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Strengths use and thriving at work: The role of job crafting and job embeddedness
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作者 Zhong Li Xia Wang +1 位作者 Xixi Chu Run Guo 《Journal of Psychology in Africa》 2025年第2期173-178,共6页
This study explored the role of job crafting and job embeddedness in the relationship between employee strengths use and thriving at work.Participants were 260 nurses from Beijing,China(99.2%female,54.6%aged 26–35 ye... This study explored the role of job crafting and job embeddedness in the relationship between employee strengths use and thriving at work.Participants were 260 nurses from Beijing,China(99.2%female,54.6%aged 26–35 years,and 62%with a bachelor’s degree or above).Data were collected at two different time points,with a two-week interval between them.Regression analysis and path analysis were applied to test the hypotheses.Results showed that strengths use was associated with thriving at work.Job crafting partially mediated this relationship for higher thriving at work.Job embeddedness weakened the relationship between strengths use and job crafting,and also lowered job crafting effects on work thriving.These findings provide insights into the mechanisms by which strengths use influences thriving at work,highlighting the significance of job crafting and job embeddedness. 展开更多
关键词 strengths use job embeddedness job crafting thriving at work
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Six-Degree-of-Freedom Motion Analysis of High-Speed Craft Navigating through Variable Marine Environments
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作者 Xiaoyang Wu Wenchao Han +2 位作者 Min Kuang Xinqi Wang Wenhao Xie 《Fluid Dynamics & Materials Processing》 2025年第9期2201-2223,共23页
The dynamic behavior of high-speed craft navigating through variable sea states plays a pivotal role in ensuring maritime safety.However,many existing simulation approaches rely on linear or overly simplified represen... The dynamic behavior of high-speed craft navigating through variable sea states plays a pivotal role in ensuring maritime safety.However,many existing simulation approaches rely on linear or overly simplified representations of the marine environment,thereby limiting the fidelity of motion predictions.This study explores the motion characteristics of a 4.5-t high-speed vessel by conducting fully coupled numerical simulations using the STAR-CCM+software.The analysis considers both calm and varying sea conditions,incorporating fluctuations in wave height,wavelength,and wind speed to reflect more realistic operating scenarios.Simulation results reveal that the vessel’s hydrodynamic response is highly sensitive to changes in sea state.As conditions deteriorate,the free surface becomes increasingly complex,with higher wave amplitudes and more pronounced interactions between the waves generated by the vessel and those imposed by the external environment.These effects lead to significant increases in roll,pitch,heave,and sway motions,thereby imposing greater demands on the vessel’s dynamic stability and operational safety.Furthermore,both hydrodynamic resistance and propulsive thrust exhibit notable dependence on sea state and vessel speed.Total resistance generally increases with rougher sea conditions,while thrust tends to rise with increasing forward speed.Under calm or mildly disturbed waters,a Froude number(Fr)of 0.5 appears to offer an optimal balance for initiating and controlling primary motions such as roll,pitch,heave,and sway.Conversely,in more challenging conditions-such as those represented by a Sea State 3-effective motion control is better achieved at a higher Froude number of approximately 1.0. 展开更多
关键词 High-speed craft sea conditions six degrees of freedom free navigation
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Polychrome Lacquer Painting with Gold Tracing and Inlay Techniques of Qing Dynasty Case Research
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作者 HUANG Yun LIN Hai-tao 《Journal of Literature and Art Studies》 2025年第11期866-871,共6页
The art of polychrome lacquer painting with gold tracing and inlay represents the culmination of traditional Chinese lacquer craftsmanship.It integrates four core techniques-lacquer application,polychrome painting,gol... The art of polychrome lacquer painting with gold tracing and inlay represents the culmination of traditional Chinese lacquer craftsmanship.It integrates four core techniques-lacquer application,polychrome painting,gold tracing,and inlay-embodying the pinnacle of ancient artisan ingenuity.This paper begins by outlining the historical origins,technical characteristics,and cultural significance of this art form.Subsequently,using a Qing Dynasty“Hanging Screen Inlaid with Boxwood and Coral Depicting the Scene of Sudhana Paying Homage to Guanyin,with Polychrome Lacquer Painting and Gold Tracing”as a case study,it offers an in-depth analysis of its craftsmanship,visual elements,thematic narrative,and cultural connotations.The study aims to unveil its artistic value and contemporary relevance as a form of“living cultural heritage.” 展开更多
关键词 LACQUER polychrome painting gold tracing INLAY Baibao Qian(Hundred-Treasure Inlay) arts and crafts
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Tracing the Past and Present:A Comprehensive Study of Chinese Incense Burner Culture with a Case Study of a Qing Dynasty Copper Ding-Style Incense Burner with Gold and Silver Inlay
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作者 ZHANG Mo-han LIN Hai-tao 《Journal of Literature and Art Studies》 2025年第12期941-944,共4页
The Chinese incense burner,a cornerstone of material culture,embodies distinguished craftsmanship and reflects sociocultural evolution across ritual,religious,and domestic life.Through analysis of a Qing-dynasty coppe... The Chinese incense burner,a cornerstone of material culture,embodies distinguished craftsmanship and reflects sociocultural evolution across ritual,religious,and domestic life.Through analysis of a Qing-dynasty copper Ding-style censer with gold and silver inlay,this paper examines its antique form,masterly technique,and decorative motifs.It demonstrates how such objects synthesize the cultural ethos of the Kang-Qian era by uniting Ming-Song literati classicism with consummate imperial artistry.This case study thus provides a focused lens on the critical interplay between elite taste and technical execution in the history of Chinese craftsmanship. 展开更多
关键词 Chinese incense burner Ding-style censer Qing Dynasty crafts gold and silver inlay material culture
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Review of the“New Crafts”International Exhibition of Arts and Crafts:Focusing on an Integrated Innovation Perspective
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作者 Ji Dong 《Journal of Contemporary Educational Research》 2025年第3期55-60,共6页
This article explores the transformative process of the philosophical concepts in new craft arts,along with the interactive relationship between technological logic and cultural expression,within the context of digita... This article explores the transformative process of the philosophical concepts in new craft arts,along with the interactive relationship between technological logic and cultural expression,within the context of digital intelligence empowerment.Through an analysis of specific artworks,it aims to reveal the potential value of digital intelligence technologies in shaping contemporary craft arts,particularly in terms of artistic expression,cultural heritage,and social responsibility. 展开更多
关键词 Traditional craft innovation Academic exhibition Integrated innovation
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Enhanced Fractional-Order Nonsingular Terminal Sliding Mode Control for Fully Submerged Hydrofoil Craft with Actuator Saturation
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作者 Hongmin Niu Shiquan Zhao +1 位作者 Cristina I.Muresan Clara Mihaela Ionescu 《哈尔滨工程大学学报(英文版)》 2025年第6期1264-1278,共15页
This study introduces an enhanced adaptive fractional-order nonsingular terminal sliding mode controller(AFONTSMC)tailored for stabilizing a fully submerged hydrofoil craft(FSHC)under external disturbances,model uncer... This study introduces an enhanced adaptive fractional-order nonsingular terminal sliding mode controller(AFONTSMC)tailored for stabilizing a fully submerged hydrofoil craft(FSHC)under external disturbances,model uncertainties,and actuator saturation.A novel nonlinear disturbance observer modified by fractional-order calculus is proposed for flexible and less conservative estimation of lumped disturbances.An enhanced adaptive fractional-order nonsingular sliding mode scheme augmented by disturbance estimation is also introduced to improve disturbance rejection.This controller design only necessitates surpassing the estimation error rather than adhering strictly to the disturbance upper bound.Additionally,an adaptive fast-reaching law with a hyperbolic tangent function is incorporated to enhance the responsiveness and convergence rates of the controller,thereby reducing chattering.Furthermore,an auxiliary actuator compensator is developed to address saturation effects.The resultant closed system of the FSHC with the designed controller is globally asymptotically stable. 展开更多
关键词 Fully submerged hydrofoil craft Longitudinal motion control Fractional-order terminal sliding mode control Disturbance observer Saturation compensation
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超临界氦循环泵隔热结构热设计及热沉位置的热分析
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作者 朱迎秋 张子健 +1 位作者 张启勇 成安义 《真空与低温》 2025年第1期74-79,共6页
聚变堆主机关键系统综合研究设施(Comprehensive Research Facility for Fusion Technology,CRAFT)超临界氦阀箱内的超临界氦循环泵为超导磁体提供大流量超临界氦,根据功能要求对超临界氦泵体的隔热区域进行了隔热设计。确定了氦循环泵... 聚变堆主机关键系统综合研究设施(Comprehensive Research Facility for Fusion Technology,CRAFT)超临界氦阀箱内的超临界氦循环泵为超导磁体提供大流量超临界氦,根据功能要求对超临界氦泵体的隔热区域进行了隔热设计。确定了氦循环泵的隔热结构,计算分析了热沉位置范围,对氦循环泵的漏热量进行了核算;采用仿真软件ANSYS,数值分析了氦循环泵的隔热性能和热沉位置对泵体漏热的影响,结果显示热沉位置H为0.064 m时,可保证液氦质量流量,泵体漏热达到最小值8.71 W,满足此值小于10 W的指标要求。 展开更多
关键词 CRAFT超导磁体平台 超临界氦泵 隔热结构 热沉
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路易斯酸用量对POE/PS间Friedel-Crafts烷基化反应及共混物力学性能的影响 被引量:13
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作者 徐建平 承民联 +2 位作者 龚方红 刘建忠 陈建定 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2006年第6期145-148,共4页
用IR,DSC,GPC研究了聚苯乙烯(PS)与聚烯烃弹性体(POE)大分子之间的F riede l-crafts烷基化反应。结果表明:在无水A lC l3催化作用下,PS与POE间可发生质子取代反应生成接枝共聚物POE-g-PS,其接枝百分比随A lC l3用量增加先上升后下降;过... 用IR,DSC,GPC研究了聚苯乙烯(PS)与聚烯烃弹性体(POE)大分子之间的F riede l-crafts烷基化反应。结果表明:在无水A lC l3催化作用下,PS与POE间可发生质子取代反应生成接枝共聚物POE-g-PS,其接枝百分比随A lC l3用量增加先上升后下降;过量的催化剂会导致聚合物降解;接枝共聚物对POE/PS共混物具有明显的就地增容作用,对于POE/PS/A lC l3=50/50/0.2(质量比)共混物,其拉伸强度与简单共混体系相比,提高了4倍,断裂伸长率提高了10倍。 展开更多
关键词 聚烯烃弹性体(POE) 聚苯乙烯(PS) Friedel—crafts烷基化反应 就地增容
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2-羟基-4-甲氧基-3′-氨基二苯甲酮与其烷基化物合成研究 被引量:5
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作者 孙岩峰 宫国梁 +1 位作者 盛学斌 赵德丰 《大连理工大学学报》 EI CAS CSCD 北大核心 2006年第6期792-796,共5页
以间苯二甲醚(1)与间硝基苯甲酰氯(2)为原料,经F riede l-C rafts反应得到2-羟基-4-甲氧基-3′-硝基二苯甲酮(3).以CH2C l2为溶剂,40℃,回流反应3 h,n(A lC l3)∶n(间苯二甲醚)∶n(间硝基苯甲酰氯)=3∶1.1∶1时,产品的收率为71.8%.化合... 以间苯二甲醚(1)与间硝基苯甲酰氯(2)为原料,经F riede l-C rafts反应得到2-羟基-4-甲氧基-3′-硝基二苯甲酮(3).以CH2C l2为溶剂,40℃,回流反应3 h,n(A lC l3)∶n(间苯二甲醚)∶n(间硝基苯甲酰氯)=3∶1.1∶1时,产品的收率为71.8%.化合物3用5%Pd/C催化氢化得到对应的氨基物4,收率为90.2%.最后,用对甲基苯磺酸酯做烷基化试剂,又得到化合物4的单烷基化产物(91.4%)与双烷基化产物(88.9%).利用IR、1H NM R及M S等手段对合成的最终产物及一些关键中间体进行了结构表征,结果正确. 展开更多
关键词 Friedel—Crafts反应 二苯甲酮 紫外吸收剂 染料中间体
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AlCl_3催化合成长链烷基萘产物分析与反应机理研究 被引量:6
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作者 郭海涛 乔卫红 李宗石 《大连理工大学学报》 EI CAS CSCD 北大核心 2003年第4期424-427,共4页
详细考察了AlCl3催化下萘与溴代正己烷的物质的量比、反应时间、反应温度对反应产物的影响.通过GC-MS联机分析反应结果,找出制备异构体直链单己基萘与直链双己基萘的最佳反应条件,同时给予了机理上的解释.在最佳反应条件下,直链单己基... 详细考察了AlCl3催化下萘与溴代正己烷的物质的量比、反应时间、反应温度对反应产物的影响.通过GC-MS联机分析反应结果,找出制备异构体直链单己基萘与直链双己基萘的最佳反应条件,同时给予了机理上的解释.在最佳反应条件下,直链单己基萘与直链双己基萘的纯度可分别达到98%、99%. 展开更多
关键词 己基萘 AlCl3催化剂 长直链烷基萘 产物分析 反应机理 反应条件 Friedel—Crafts反应
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芳基取代四甲基环戊二烯基铼羰基化合物的合成、晶体结构及催化性能(英文) 被引量:4
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作者 马志宏 李战伟 +4 位作者 秦玫 李素贞 韩占刚 郑学忠 林进 《无机化学学报》 SCIE CAS CSCD 北大核心 2017年第6期1074-1080,共7页
芳基取代的四甲基环戊二烯C5HMe4Ar(Ar=Ph,4-CH_3Ph,4-OCH_3Ph,4-ClPh,4-BrPh)分别与Re2(CO)10在二甲苯中加热回流,得到了5个单核配合物[(η5-C5Me4Ar)Re(CO)3](Ar=Ph(1),4-CH_3Ph(2),4-OCH_3Ph(3),4-ClPh(4),4-BrPh(5))。通过元素分析... 芳基取代的四甲基环戊二烯C5HMe4Ar(Ar=Ph,4-CH_3Ph,4-OCH_3Ph,4-ClPh,4-BrPh)分别与Re2(CO)10在二甲苯中加热回流,得到了5个单核配合物[(η5-C5Me4Ar)Re(CO)3](Ar=Ph(1),4-CH_3Ph(2),4-OCH_3Ph(3),4-ClPh(4),4-BrPh(5))。通过元素分析、红外光谱、核磁共振氢谱对配合物1~5的结构进行了表征,用X射线单晶衍射法测定了配合物的结构。同时,研究了这五种配合物在芳香族化合物Friedel-Crafts烷基化反应中的催化活性。 展开更多
关键词 合成 单核铼羰基配合物 Friedel—Crafts烷基化反应:催化
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