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Analysis and engineering of coupled cavity waveguides based on coupled-mode theory
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作者 林旭升 陈雄文 兰胜 《Chinese Physics B》 SCIE EI CAS CSCD 2005年第10期2033-2040,共8页
The analytical expression for the transmission spectra of coupled cavity waveguides (CCWs) in photonic crystals (PCs) is derived based on the coupled-mode theory (CMT). Parameters in the analytical expression ca... The analytical expression for the transmission spectra of coupled cavity waveguides (CCWs) in photonic crystals (PCs) is derived based on the coupled-mode theory (CMT). Parameters in the analytical expression can be extracted by simple numerical simulations. We reveal that it is the phase shift between the two adjacent PC defects that uniquely determines the flatness of the impurity bands of CCWs. In addition, it is found that the phase shift also greatly affects the bandwidth of CCWs. Thus, the engineering of the impurity bands of CCWs can be realized through the adjustment of the phase shift. Based on the theoretical results, an interesting phenomenon in which a CCW acts as a single PC defect and its impurity band possesses a Lorentz lineshape is predicted. Very good agreement between the analytical results and the numerical simulations based on transfer matrix method has been achieved. 展开更多
关键词 photonic crystals coupled cavity waveguides coupled-mode theory phase shift
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Complete leaky mode coupling in dual-core photonic crystal fibre based on the coupled-mode theory
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作者 苑金辉 余重秀 +3 位作者 桑新柱 张锦龙 周桂耀 侯蓝田 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第6期237-242,共6页
This paper theoretically investigates the dependence of leaky mode coupling between inner core fundamental mode and outer core defect mode on phase and loss matching in pure silica dual-core photonic crystal fibres wi... This paper theoretically investigates the dependence of leaky mode coupling between inner core fundamental mode and outer core defect mode on phase and loss matching in pure silica dual-core photonic crystal fibres with the multi-pole method. The complete mode coupling can take place when both the phase and loss matching conditions are satisfied at the avoided anti-crossing wavelength. It shows the influences of cladding structure parameters including the diameters of cladding air holes d1, diameters of outer core holes d2 and hole to hole pitch A on the characteristics of leaky modes coupling. The coupled-mode theory is used to analyse the mode transition characteristics and the complete coupling can be clearly indicated by comparing the real and imaginary parts of propagation constant of the leaky modes. 展开更多
关键词 dual-core photonic crystal fibres complete leaky mode coupling multi-pole method coupled-mode theory
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Generalized Coupled-Mode Theory for Nonorthogonal Modes
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作者 钱景仁 《Science China Mathematics》 SCIE 1993年第4期504-512,共9页
A generalized theory of power-nonorthogonal coupled-modes in a lossless multi-waveguide structure is presented. A set of orthogonal eigenmodes in a multi-wave-guide structure with constant parameters is formed by comb... A generalized theory of power-nonorthogonal coupled-modes in a lossless multi-waveguide structure is presented. A set of orthogonal eigenmodes in a multi-wave-guide structure with constant parameters is formed by combining the nonorthogonal modes. In the waveguide structure with slowly varying parameters, however, the local modes formed by the same combination are still coupled. Finally, an example of two-waveguide coupler is given. 展开更多
关键词 coupled-mode dielectrie WAVEGUIDE
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Comparing Three of the Leadership Theories: Leader-Member Exchange Theory,transformational Leadership and Team Leadership
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作者 王子涵 《中国校外教育(上旬)》 2013年第S2期122-124,共3页
Leadership is a complex process.It is one of the most researched areas around the world.It has gained importance in every walk of life from politics to business and from education to social organizations.According to ... Leadership is a complex process.It is one of the most researched areas around the world.It has gained importance in every walk of life from politics to business and from education to social organizations.According to the study of"Leadership in Adult Education Venues",here has a much more clear recognition of leadership:leadership is a process whereby an individual influences a group of individuals to achieve a common goal.There are many approaches of leadership throughout the study of this class,the three theories of leadership I choose to describe in this paper are:Leader-Member Exchange(LMX)Theory,Transformational Leadership,and Team Leadership. 展开更多
关键词 Leader-Member EXCHANGE theory Transformational LEA
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问题与回答——Theorizing A New Agenda for Architecture,An Anthology of Architectural Theory,1965~1995一书引起的思考
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作者 张巍 王一平 《华中建筑》 2010年第3期4-6,共3页
内斯比特(KateNesbitt)在她的Theorizing A New Agenda for Architecture,An Anthology of Architectural Theory,1965~1995一书中较为全面地介绍了当代西方建筑理论界所关心的主要问题及其相关的思考。对于这些问题,国内建筑理论界也... 内斯比特(KateNesbitt)在她的Theorizing A New Agenda for Architecture,An Anthology of Architectural Theory,1965~1995一书中较为全面地介绍了当代西方建筑理论界所关心的主要问题及其相关的思考。对于这些问题,国内建筑理论界也有自己的认识。该文通过对两者的比较,试图理清建筑理论的基本意义,那就是提出问题并引起思考。 展开更多
关键词 问题 回答 理论的意义
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RENEWAL OF BASIC LAWS AND PRINCIPLES FOR POLAR CON-TINUUM THEORIES (Ⅱ)—MICROMORPHIC CONTINUUM THEORY AND COUPLE STRESS THEORY 被引量:2
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作者 戴天民 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2003年第10期1126-1133,共8页
The purpose is to reestablish the balance laws of momentum, angular momentum and energy and to derive the corresponding local and nonlocal balance equations for micromorphic continuum mechanics and couple stress theor... The purpose is to reestablish the balance laws of momentum, angular momentum and energy and to derive the corresponding local and nonlocal balance equations for micromorphic continuum mechanics and couple stress theory. The desired results for micromorphic continuum mechanics and couple stress theory are naturally obtained via direct transitions and reductions from the coupled conservation law of energy for micropolar continuum theory, respectively. The basic balance laws and equations for micromorphic continuum mechanics and couple stress theory are constituted by combining these results derived here and the traditional conservation laws and equations of mass and microinertia and the entropy inequality. The incomplete degrees of the former related continuum theories are clarified. Finally, some special cases are conveniently derived. 展开更多
关键词 micromorphic continuum couple stress theory COUPLED basic balance law balance equation
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ANALYSIS OF COUPLED-MODE FLUTTER OF PIPES CONVEYING FLUID ON THE ELASTIC FOUNDATION 被引量:1
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作者 王忠民 冯振宇 +1 位作者 赵凤群 刘宏昭 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2000年第10期1177-1186,共10页
The governing equation of solid-liquid couple vibration of pipe conveying fluid on the elastic foundation was derived. The critical velocity and complex frequency of pipe conveying fluid on Winkler elastic foundation ... The governing equation of solid-liquid couple vibration of pipe conveying fluid on the elastic foundation was derived. The critical velocity and complex frequency of pipe conveying fluid on Winkler elastic foundation and two-parameter foundation were calculated by po,ver series method. Compared,with pipe without considering elastic foundation, the numerical results show that elastic foundation can increase the critical flow velocity of static instability and dynamic instability of pipe. And the increase of foundation parameters may increase the critical flow velocity of static instability and dynamic instability of pipe, thereby delays the occurrence of divergence and flutter instability of pipe. For higher mass ratio beta, in the combination of certain foundation parameters, pipe behaves the phenomenon of restabilization and redivergence after the occurrence of static instability, and then coupled-mode flutter takes place. 展开更多
关键词 elastic foundation pipe conveying fluid coupled-mode flutter STABILITY power series method
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A three-dimensional coupled-mode model for the acoustic field in a two-dimensional waveguide with perfectly reflecting boundaries
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作者 骆文于 于晓林 +2 位作者 杨雪峰 张泽众 张仁和 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第12期57-68,共12页
This paper presents a three-dimensional (3D) coupled-mode model using the direct-global-matrix technique as well as Fourier synthesis. This model is a full wave, two-way three-dimensional model, and is therefore cap... This paper presents a three-dimensional (3D) coupled-mode model using the direct-global-matrix technique as well as Fourier synthesis. This model is a full wave, two-way three-dimensional model, and is therefore capable of providing ac- curate acoustic field solutions. Because the problem of sound propagation excited by a point source in an ideal wedge with perfectly reflecting boundaries is one of a few three-dimensional problems with analytical solutions, the ideal wedge prob- lem is chosen in this work to validate the presented three-dimensional model. Numerical results show that the field results by analytical solutions and those by the presented model are in excellent agreement, indicating that the presented model can serve as a benchmark model for three-dimensional sound propagation problems involving a planar two-dimensional geometry as well as a point source. 展开更多
关键词 coupled-mode method wedge-shaped waveguide direct-global-matrix approach 3D acousticfield
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Three-dimensional coupled-mode model and characteristics of low-frequency sound propagation in ocean waveguide with seamount topography
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作者 Ya-Xiao Mo Chao-Jin Zhang +1 位作者 Li-Cheng Lu Sheng-Ming Guo 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第8期453-462,共10页
Large-scale topography, such as a seamount, substantially impacts low-frequency sound propagation in an ocean waveguide, limiting the application of low-frequency acoustic detecting techniques. A three-dimensional(3D)... Large-scale topography, such as a seamount, substantially impacts low-frequency sound propagation in an ocean waveguide, limiting the application of low-frequency acoustic detecting techniques. A three-dimensional(3D) coupledmode model is developed to calculate the acoustic field in an ocean waveguide with seamount topography and analyze the3D effect. In this model, a correction is introduced in the bottom boundary, theoretically making the acoustic field satisfy the energy conservation. Furthermore, a large azimuth angle calculation range is obtained by using the operator theory and higher-order Pade approximation. Additionally, the model has advantages related to the coupling mode and parabolic equation theory. The couplings corresponding to the effects of range-dependent environment are fully considered, and the numerical implementation is kept feasible. After verifying the accuracy and reliability of the model, low-frequency sound propagation characteristics in the seamount environment are analyzed. The results indicate lateral variability in bathymetry can lead to out-of-plane effects such as the horizontal refraction phenomenon, while the coupling effect tends to restore the abnormal sound field and produces acoustic field diffraction behind the seamount. This model effectively considers the effects of the horizontal refraction and coupling, which are proportional to the scale of the seamount. 展开更多
关键词 coupled-mode model three-dimensional sound propagation seamount topography horizontal interference structure
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BASIC EQUATIONS, THEORY AND PRINCIPLE OF COMPUTATIONAL STOCK MARKET (Ⅲ)—BASIC THEORIES
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作者 云天铨 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2000年第8期861-868,共8页
By basic equations, two basic theories are presented: 1.Theory of stock's value v *(t)=v *(0) exp (ar * 2t); 2. Theory of conservation of stock's energy. Let stock's energy be defined as a q... By basic equations, two basic theories are presented: 1.Theory of stock's value v *(t)=v *(0) exp (ar * 2t); 2. Theory of conservation of stock's energy. Let stock's energy be defined as a quadratic function of stock's price v and its derivative , =Av 2+ Bv+C 2+Dv, under the constraint of basic equation, the problem was reduced to a problem of constrained optimization along optimal path. Using Lagrange multiplier and Euler equation of variation method, it can be proved that keeps conservation for any v,. The application of these equations and theories on judgement and analysis of tendency of stock market are given, and the judgement is checked to be correct by the recorded tendency of Shenzhen and Shanghai stock markets. 展开更多
关键词 political economics theory of value of goods variational method Euler equation conservation law
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About the Conflicts between the Unitary Quantum Theory and the Special and General Relativity Theories
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作者 Leo G. Sapogin V. A. Dzhanibekov +3 位作者 M. A. Moкulsky Yu. A. Ryabov Yu. P. Savin V. I. Utchastkin 《Journal of Modern Physics》 2015年第6期780-785,共6页
The authors discuss contradictions between the principal branches of the modern physical picture of the universe. Space and time have been shown in the Unitary Quantum Theory (UQT) not to be connected one with the oth... The authors discuss contradictions between the principal branches of the modern physical picture of the universe. Space and time have been shown in the Unitary Quantum Theory (UQT) not to be connected one with the other, unlike in the Special Theory of Relativity. In UQT, time becomes Newtonian again, and the growth of the particle’s mass with growing speed proceeds from other considerations of physics. Unlike the quantum theory, the modern gravitation theory (the general theory of relativity) is not confirmed by experiments and needs to be considerably revised. 展开更多
关键词 UNITARY Quantum theory General RELATIVITY SPECIAL RELATIVITY Maxwell Equations LORENTZ TRANSFORMATIONS
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Nursing interventions based on Snyder’s hope theory for depression following percutaneous coronary interventions:A clinical study 被引量:4
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作者 Xiao Wang Hai-Feng Song Si-Min Zhang 《World Journal of Psychiatry》 2025年第2期33-40,共8页
BACKGROUND Patients with depression following coronary heart disease often exhibit insufficient psychological resilience and self-care abilities;therefore,emphasis must be placed on nursing interventions.AIM To analyz... BACKGROUND Patients with depression following coronary heart disease often exhibit insufficient psychological resilience and self-care abilities;therefore,emphasis must be placed on nursing interventions.AIM To analyze the application value of problem-oriented education combined with nursing interventions based on the Snyder hope theory model in depressed patients after percutaneous coronary intervention(PCI).METHODS This study included 150 patients diagnosed with PCI postoperative depression because of coronary heart disease between February 2022 and February 2024.Participants were divided into two groups:A control group(n=75)receiving problem-oriented education and an observation group(n=75)receiving combined nursing interventions based on the Snyder hope theory model.Depression status,psychological resilience,self-care ability,and quality of life were compared between the two groups.RESULTS Before nursing interventions,there were no significant differences between the two groups(P>0.05).After the interventions,depression scores decreased while psychological resilience,self-care ability,and quality of life scores increased significantly in the observation group compared to that in the control group,with statistically significant differences noted(P<0.05).This combined approach can enhance psychological resilience,improve self-care abilities,and elevate the overall quality of life,warranting further promotion in clinical practice.CONCLUSION Combination of problem-oriented education and nursing interventions based on the Snyder hope theory model effectively alleviates depression in patients following PCI for coronary heart disease. 展开更多
关键词 Problem-oriented education Snyder hope theory model Coronary heart disease DEPRESSION Psychological resilience Self-care ability
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Bubble Theory and its Applications in Underwater Explosion, Marine Cavitation, and Seismic Exploration 被引量:1
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作者 Runze Xu Shiping Wang +1 位作者 Hemant J.Sagar Haikun Wang 《哈尔滨工程大学学报(英文版)》 2025年第2期255-284,共30页
Bubbles play crucial roles in various fields,including naval and ocean engineering,chemical engineering,and biochemical engineering.Numerous theoretical analyses,numerical simulations,and experimental studies have bee... Bubbles play crucial roles in various fields,including naval and ocean engineering,chemical engineering,and biochemical engineering.Numerous theoretical analyses,numerical simulations,and experimental studies have been conducted to reveal the mysteries of bubble motion and its mechanisms.These efforts have significantly advanced research in bubble dynamics,where theoretical study is an efficient method for bubble motion prediction.Since Lord Rayleigh introduced the theoretical model of single-bubble motion in incompressible fluid in 1917,theoretical studies have been pivotal in understanding bubble dynamics.This study provides a comprehensive review of the development and applicability of theoretical studies in bubble dynamics using typical theoretical bubble models across different periods as a focal point and an overview of bubble theory applications in underwater explosion,marine cavitation,and seismic exploration.This study aims to serve as a reference and catalyst for further advancements in theoretical analysis and practical applications of bubble theory across marine fields. 展开更多
关键词 Bubble theory Underwater explosion Marine cavitation Seismic exploration
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Mole-inspired Forepaw Design and Optimization Based on Resistive Force Theory 被引量:1
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作者 Tao Zhang Zhaofeng Liang +8 位作者 Hongmin Zheng Zibiao Chen Kunquan Zheng Ran Xu Jiabin Liu Haifei Zhu Yisheng Guan Kun Xu Xilun Ding 《Journal of Bionic Engineering》 2025年第1期171-180,共10页
Moles exhibit highly effective capabilities due to their unique body structures and digging techniques,making them ideal models for biomimetic research.However,a major challenge for mole-inspired robots lies in overco... Moles exhibit highly effective capabilities due to their unique body structures and digging techniques,making them ideal models for biomimetic research.However,a major challenge for mole-inspired robots lies in overcoming resistance in granular media when burrowing with forelimbs.In the absence of effective forepaw design strategies,most robotic designs rely on increased power to enhance performance.To address this issue,this paper employs Resistive Force Theory to optimize mole-inspired forepaws,aiming to enhance burrowing efficiency.By analyzing the relationship between geometric parameters and burrowing forces,we propose several forepaw design variations.Through granular resistance assessments,an effective forepaw configuration is identified and further refined using parameters such as longitudinal and transverse curvature.Subsequently,the Particle Swarm Optimization algorithm is applied to determine the optimal forepaw design.In force-loading tests,the optimized forepaw demonstrated a 79.44%reduction in granular lift force and a 22.55%increase in propulsive force compared with the control group.In robotic burrowing experiments,the optimized forepaw achieved the longest burrow displacement(179.528 mm)and the lowest burrowing lift force(0.9355 mm/s),verifying its effectiveness in reducing the lift force and enhancing the propulsive force. 展开更多
关键词 Resistive force theory Mole-inspired forepaw design Structural optimization Bioinspired robot
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Element Transfer Reaction theory:Scientific connotation and its applications in chemical industry 被引量:1
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作者 Hongen Cao Xinrui Xiao +2 位作者 Xu Zhang Yiyang Zhang Lei Yu 《Chinese Chemical Letters》 2025年第9期4-7,共4页
Element Transfer Reaction(ETR)theory is a new fundamental theory guiding the design of synthetic routes.It analyses problems from a brand-new perspective of element circulation,decomposing the factors affecting synthe... Element Transfer Reaction(ETR)theory is a new fundamental theory guiding the design of synthetic routes.It analyses problems from a brand-new perspective of element circulation,decomposing the factors affecting synthetic efficiency into three elements:element sources,driving force,and output.Different from the retrosynthetic analysis method and the atom economy theory,the ETR theory places more emphasis on examining the problem as a whole and comprehensively considering various factors involved in industrial applications.This perspective intends to elaborate on the scientific connotation of the ETR theory and explore its characteristics by discussing the practical application cases. 展开更多
关键词 Element Transfer Reaction theory Element source Driving force OUTPUT Energy conservation Atom economy
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On the Lebesgue Integral and the Lebesgue Measure: Mathematical Applications in Some Sectors of Chern-Simons Theory and Yang-Mills Gauge Theory and Mathematical Connections with Some Sectors of String Theory and Number Theory
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作者 Michele Nardelli 《Journal of Modern Physics》 2025年第1期93-132,共40页
In this paper, in Section 1, we have described some equations and theorems concerning the Lebesgue integral and the Lebesgue measure. In Section 2, we have described the possible mathematical applications, of Lebesgue... In this paper, in Section 1, we have described some equations and theorems concerning the Lebesgue integral and the Lebesgue measure. In Section 2, we have described the possible mathematical applications, of Lebesgue integration, in some equations concerning various sectors of Chern-Simons theory and Yang-Mills gauge theory, precisely the two dimensional quantum Yang-Mills theory. In conclusion, in Section 3, we have described also the possible mathematical connections with some sectors of String Theory and Number Theory, principally with some equations concerning the Ramanujan’s modular equations that are related to the physical vibrations of the bosonic strings and of the superstrings, some Ramanujan’s identities concerning π and the zeta strings. 展开更多
关键词 Lebesgue Integral Chern-Simons theory Yang-Mills Gauge theory String theory Number theory
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Galerkin-Vlasov approach for bending analysis of flexoelectric doubly-curved sandwich nanoshells with piezoelectric/FGP/piezoelectric layers using the nonlocal strain theory 被引量:1
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作者 Tran Van Ke Do Van Thom +2 位作者 Nguyen Thai Dung Nguyen Van Chinh Phung Van Minh 《Acta Mechanica Sinica》 2025年第2期7-40,共34页
Flexoelectricity refers to the link between electrical polarization and strain gradient fields in piezoelectric materials,particularly at the nano-scale.The present investigation aims to comprehensively focus on the s... Flexoelectricity refers to the link between electrical polarization and strain gradient fields in piezoelectric materials,particularly at the nano-scale.The present investigation aims to comprehensively focus on the static bending analysis of a piezoelectric sandwich functionally graded porous(FGP)double-curved shallow nanoshell based on the flexoelectric effect and nonlocal strain gradient theory.Two coefficients that reduce or increase the stiffness of the nanoshell,including nonlocal and length-scale parameters,are considered to change along the nanoshell thickness direction,and three different porosity rules are novel points in this study.The nanoshell structure is placed on a Pasternak elastic foundation and is made up of three separate layers of material.The outermost layers consist of piezoelectric smart material with flexoelectric effects,while the core layer is composed of FGP material.Hamilton’s principle was used in conjunction with a unique refined higher-order shear deformation theory to derive general equilibrium equations that provide more precise outcomes.The Navier and Galerkin-Vlasov methodology is used to get the static bending characteristics of nanoshells that have various boundary conditions.The program’s correctness is assessed by comparison with published dependable findings in specific instances of the model described in the article.In addition,the influence of parameters such as flexoelectric effect,nonlocal and length scale parameters,elastic foundation stiffness coefficient,porosity coefficient,and boundary conditions on the static bending response of the nanoshell is detected and comprehensively studied.The findings of this study have practical implications for the efficient design and control of comparable systems,such as micro-electromechanical and nano-electromechanical devices. 展开更多
关键词 Analytical solution Flexoelectric effect Nonlocal strain gradient theory Static bending of nanoshell
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Exploring artificial intelligence approaches for predicting synergistic effects of active compounds in traditional Chinese medicine based on molecular compatibility theory 被引量:1
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作者 Yiwen Wang Tong Wu +5 位作者 Xingyu Li Qilan Xu Heshui Yu Shixin Cen Yi Wang Zheng Li 《Chinese Journal of Natural Medicines》 2025年第11期1409-1424,共16页
Due to its synergistic effects and reduced side effects,combination therapy has become an important strategy for treating complex diseases.In traditional Chinese medicine(TCM),the“monarch,minister,assistant,envoy”co... Due to its synergistic effects and reduced side effects,combination therapy has become an important strategy for treating complex diseases.In traditional Chinese medicine(TCM),the“monarch,minister,assistant,envoy”compatibilities theory provides a systematic framework for drug compatibility and has guided the formation of a large number of classic formulas.However,due to the complex compositions and diverse mechanisms of action of TCM,it is difficult to comprehensively reveal its potential synergistic patterns using traditional methods.Synergistic prediction based on molecular compatibility theory provides new ideas for identifying combinations of active compounds in TCM.Compared to resource-intensive traditional experimental methods,artificial intelligence possesses the ability to mine synergistic patterns from multi-omics and structural data,providing an efficient means for modeling and optimizing TCM combinations.This paper systematically reviews the application progress of AI in the synergistic prediction of TCM active compounds and explores the challenges and prospects of its application in modeling combination relationships,thereby contributing to the modernization of TCM theory and methodological innovation. 展开更多
关键词 Molecular compatibility theory Synergy prediction of TCM compounds Molecular drugs combination prediction Artificial intelligence
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Gravitational Collapse and Expansion in the Newton Theory and General Relativity
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作者 Valery V. Vasiliev Leonid V. Fedorov 《Journal of Modern Physics》 2025年第2期294-309,共16页
The paper is devoted to the study of the gravitational collapse within the framework of the spherically symmetric problem in the Newton theory and general relativity on the basis of the pressure-free model of the cont... The paper is devoted to the study of the gravitational collapse within the framework of the spherically symmetric problem in the Newton theory and general relativity on the basis of the pressure-free model of the continuum. In application to the Newton gravitation theory, the analysis consists of three stages. First, we assume that the gravitational force is determined by the initial sphere radius and constant density and does not change in the process of the sphere collapse. The obtained analytical solution allows us to find the collapse time in the first approximation. Second, we construct the step-by-step process in which the gravitational force at a given time moment depends on the current sphere radius and density. The obtained numerical solution specifies the collapse time depending on the number of steps. Third, we find the exact value of the collapse time which is the limit of the step-by-step solutions and study the collapse and the expansion processes in the Newton theory. In application to general relativity, we use the space model corresponding to the special four-dimensional space which is Euclidean with respect to space coordinates and Riemannian with respect to the time coordinate only. The obtained solution specifies two possible scenarios. First, sphere contraction results in the infinitely high density with the finite collapse time, which does not coincide with the conventional result corresponding to the Schwarzschild geometry. Second, sphere expansion with the velocity which increases with a distance from the sphere center and decreases with time. 展开更多
关键词 Gravitational Collapse Newton Gravitation theory General Relativity
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A series of iridium(Ⅲ)complexes with fluorophenyl isoquinoline ligand and low-efficiency roll-off properties:A density functional theory study
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作者 QIN Zhengkun PAN Zicong +2 位作者 TIAN Hui ZHANG Wanyi SONG Mingxing 《无机化学学报》 北大核心 2025年第6期1235-1244,共10页
We have examined the theoretical implications of combining two main and three auxiliary ligands to form several Ir(Ⅲ)complexes featuring a transition metal as their core atom to identify some appropriate organic ligh... We have examined the theoretical implications of combining two main and three auxiliary ligands to form several Ir(Ⅲ)complexes featuring a transition metal as their core atom to identify some appropriate organic lightemitting diode(OLED)materials.By utilizing electronic structure,frontier molecular orbitals,minimum single-line absorption,triplet excited states,and emission spectral data derived from the density functional theory,the usefulness of these Ir(Ⅲ)complexes,including(piq)_(2)Ir(acac),(piq)_(2)Ir(tmd),(piq)_(2)Ir(tpip),(fpiq)_(2)Ir(acac),(fpiq)_(2)Ir(tmd),and(fpiq)_(2)Ir(tpip),in OLEDs was examined,where piq=1-phenylisoquinoline,fpiq=1-(4-fluorophenyl)isoquinoline,acac=(3Z)-4-hydroxypent-3-en-2-one,tmd=(4Z)-5-hydroxy-2,2,6,6-tetramethylhept-4-en-3-one,and tpip=tetraphenylimido-diphosphonate.These complexes all have low-efficiency roll-off properties,especially(fpiq)_(2)Ir(tpip).Some researchers have successfully synthesized complexes extremely similar to(piq)_(2)Ir(acac)through the Suzuki-Miyaura coupling reaction. 展开更多
关键词 density functional theory organic light-emitting diodes luminescent materials Ir(Ⅲ)complexes
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