Coulomb drag refers to the phenomenon in which a current driven through one conducting layer induces a voltage nearby,electrically isolated layer sorely through interlayer Coulomb interactions between charge carriers....Coulomb drag refers to the phenomenon in which a current driven through one conducting layer induces a voltage nearby,electrically isolated layer sorely through interlayer Coulomb interactions between charge carriers.It has been extensively studied in various systems,including parallel nanowires,double quantum wells,and double-layer graphene.Here,we report the observation of Coulomb drag in a novel system consisting of two graphene layers separated laterally by a 30 nm gap within the material plane,exhibiting behavior distinct from that in vertical graphene heterostructures.Our experiments reveal pronounced negative drag resistances under an out-of-plane magnetic field at the quantum Hall edges,reaching a maximum when the carrier densities in both graphene layers are tuned to the charge neutrality point via gate voltages.Our work establish two separate and spatially closed quantum Hall edge modes as a new platform to explore electronic interaction physics between one dimensional systems.展开更多
Coal-derived hard carbon(HC)represents a promising anode material for sodium-ion batteries owing to its cost-effectiveness and high carbon yield.However,conventional carbonization induces excessive graphitization,yiel...Coal-derived hard carbon(HC)represents a promising anode material for sodium-ion batteries owing to its cost-effectiveness and high carbon yield.However,conventional carbonization induces excessive graphitization,yielding insufficient interlayer spacing(d_(002)<0.37 nm)and underdeveloped closed pores.Herein,we propose a dynamic crystallization control strategy through carbothermal shock treatment(1300°C,30 s)that decouples thermodynamic and kinetic constraints.This method precisely modulates graphite domain ordering kinetics,producing short-range ordered structures with expanded interlayer spacing(d_(002)=0.385 nm)and homogeneously distributed closed nanopores.Through combined in situ characterization and first-principles calculations,we elucidate a three-stage crystallization mechanism:(i)amorphous carbon transformation,(ii)open-pore collapse,and(iii)pseudo-graphitic ordering.The optimized HC achieves record performance with 88.6%initial Coulombic efficiency and 204 mA h g^(−1)plateau capacity,while its optimal interlayer spacing lowers Na+diffusion barriers to enable exceptional rate capability(221 mA h g^(−1)at 0.5C after 300 cycles).Practical pouch cells maintain 85%capacity retention after 100 cycles at−20°C and deliver 284 Wh kg^(−1)energy density.This work establishes a kinetic regulation paradigm for graphitization-prone precursors,advancing the rational design of high-performance HC anodes.展开更多
An MW6.0 earthquake struck Jishishan County in Linxia Prefecture,Gansu Province,on December 18,2023.In this research,Sentinel-1A satellite radar observations were used to obtain the field of coseismic deformation of t...An MW6.0 earthquake struck Jishishan County in Linxia Prefecture,Gansu Province,on December 18,2023.In this research,Sentinel-1A satellite radar observations were used to obtain the field of coseismic deformation of the Jishishan earthquake in 2023,and the geometric and fine slip distribution of the seismogenic fault were inverted using this as a constraint.The results show that the earthquake is characterized by thrust movement.The coseismic slip distribution results show that the maximum slip of this earthquake is 0.3 m.The Coulomb stress distribution shows that the whole section of the southern edge of Lajishan fault,the NWW trending segment of the northern edge of Lajishan fault and its NNW trending segment to the south of the epicenter,the northern edge of the West Qinling fault and the segment to the east of the epicenter of the Daotanghe Linxia fault are under stress loading,which indicates an increase in the potential risk of earthquakes.This research discussed the seismogenic characteristics of earthquakes and the tendency of faults.We speculate that the Jishishan earthquake is the result of the joint action of regional faults and tectonic stress.Based on the observation of seismic data,geodesy,and other geological and geophysical data,we believe that the earthquake was caused by the activation of weak areas under the crust by the local stress from the driving mechanism of the northeast expansion of Qinghai-Xizang Plateau.The seismogenic fault of this earthquake is more likely to be northeast dipping under the comprehensive consideration of various factors,which occurred on the concealed fault belonging to the eastern edge of the Jishishan fault zone.展开更多
Quantum dot systems emerge as promising platforms for studying nanoscale thermoelectric effects and quantum fluctuation phenomena.In this work,we investigate the thermodynamic performance of a Coulomb-blockaded quantu...Quantum dot systems emerge as promising platforms for studying nanoscale thermoelectric effects and quantum fluctuation phenomena.In this work,we investigate the thermodynamic performance of a Coulomb-blockaded quantum dot operating as a quantum heat engine using the quantum master equation approach.By incorporating full counting statistics,we analyze both average transport properties and current fluctuations in this nanoscale system.We demonstrate that electron-electron interactions significantly enhance thermoelectric performance by increasing both the output power and energy conversion efficiency.Furthermore,we show that Coulomb interactions suppress current fluctuations while preserving the validity of the thermodynamic uncertainty relation.Our results provide important insights into the interplay between quantum effects and thermodynamic principles in nanoscale heat engines.展开更多
Silicon(Si)is a promising high-capacity anode in lithium-ion batteries but suffers from chronic chemical degradation and capacity fading during calendar aging,greatly hindering its automobile applications.Electrolyte ...Silicon(Si)is a promising high-capacity anode in lithium-ion batteries but suffers from chronic chemical degradation and capacity fading during calendar aging,greatly hindering its automobile applications.Electrolyte engineering currently relies on conventional evaluation criteria of reducing coulombic consumption,which implicitly presume its equivalence to irreversible capacity loss and complicates battery development.We introduce the detrimental ratioρto quantify the fraction of parasitic species that permanently degrades active material.This metric is independent and crucially complements total coulombic consumption for accurate performance evaluation.We systematically investigate multiple electrolyte formulations using high-precision leakage current measurements,open-circuit-voltage experiments,and post-mortem characterizations.Although some electrolytes exhibit similarly low coulombic consumption,they diverge significantly in capacity retention andρ.Especially,dimethyl-carbonate-based localized-high concentration electrolyte can synergically achieve low coulombic consumption and detrimental ratioρduring calendar aging,owing to its chemically inert and structurally resilient solidelectrolyte interface with minimal isolated Si material.By contrast,increasing fluoroethylene carbonate(FEC)additive content suppresses electrolyte breakdown but suffers aggravated chemical degradation of more LixSi isolation for irreversible capacity loss with a risingρ.This study critically reveals that the chemistry-characteristic detrimental ratioρestablishes physically informed performance evaluation to pave the way for accelerating battery development.展开更多
We investigated the influence of historical earthquakes on the 2022 Luding M_(S)6.8 earthquake and its subsequent effects.We computed the viscoelastic Coulomb stress changes induced by these historical seismic events ...We investigated the influence of historical earthquakes on the 2022 Luding M_(S)6.8 earthquake and its subsequent effects.We computed the viscoelastic Coulomb stress changes induced by these historical seismic events using the rupture model of historical earthquakes and the layered Maxwell viscoelastic medium model.Our findings indicate that the Luding earthquake was brought forward approximately 29 years because of several historical earthquakes.Specifically,the 1923 Renda M_(S)7.3 earthquake,the 1933 Diexi M_(S)7.5 earthquake,the 1973 Luhuo M_(S)7.3 earthquake,the 2008 Kangding M_(S)5.1 earthquake,the 2008 Wenchuan M_(S)8.0 earthquake,the 2014 Kangding M_(S)6.3 earthquake,and the 2014 Kangding M_(S)5.8 earthquake advanced the occurrence of the event by 117.61,26.67,84.51,0.27,0.91,7.64,and 3.17 years,respectively.Conversely,the 1936 Mabian earthquake swarm,the 1948 Litang M_(S)7.3 earthquake,the 1955 Kangding M_(S)7.5 earthquake,and the 2013 Lushan M_(S)7.0 earthquake delayed its occurrence by 39.89,22.43,144.23,and 4.89 years,respectively.Furthermore,by employing the halfspace homogeneous elastic model and the rupture characteristics of the Luding earthquake,we computed the coseismic Coulomb stress changes in neighboring faults.Our results reveal increased Coulomb stress on the Xianshuihe fault(excluding its southern segment),the Anninghe fault,the Zemuhe fault,the Daliangshan fault,the southern segment of the Longmenshan fault,the northern segment of the Mabian-Yanjin fault,and the Xiaojinhe fault.Conversely,we observed stress decreases in the southern segment of the Jinshajiang fault,the central and eastern segments of the Longriba fault,the Mabian-Yanjin fault(excluding its northern segment),and the southern segment of the Xianshuihe fault.展开更多
Hard carbon is a vital anode material for sodium-ion batteries;however,the nonuniform growth of solid electrolyte interphase(SEI)film substantially diminishes its initial coulombic efficiency(ICE)and cycle life.The ch...Hard carbon is a vital anode material for sodium-ion batteries;however,the nonuniform growth of solid electrolyte interphase(SEI)film substantially diminishes its initial coulombic efficiency(ICE)and cycle life.The chemical and morphological properties of surface highly influence the electrode/electrolyte interfacial reactions.In this study,we have tuned orbital hybridization states forming an interface enriched with sp^(2) hybridized carbon(sp^(2)-C),which decreases the binding energy to solvent molecules and inhibits excessive solvent decomposition during SEI formation.Benefiting from successfully constructed inorganic-rich SEI,the ICE increased to 91%and sodium storage capacity reached 346 mAh/g.Besides,the capacity retention rate was 90.7%after 700 cycles at 1 A/g higher than pristine electrode(83.8%).展开更多
As an important index to measure the degree of entanglement in quantum systems,concurrence plays an important role in practical research.In this paper,we study the concurrence between two qubits in triangular triple q...As an important index to measure the degree of entanglement in quantum systems,concurrence plays an important role in practical research.In this paper,we study the concurrence between two qubits in triangular triple quantum dot structure.Through calculation and simulation,it is found that concurrence is mainly affected by the interdot coupling strength t,Coulomb interactionU,temperature T,and electrode coupling G.Through comparative studies with parallel triple quantum dot structures,we demonstrate that the triangular geometry exhibits significantly enhanced concurrence under identical conditions.In addition,under the condition that concurrence exceeds 0.9,the functional relationship between t and U is obtained through simulation,which provides theoretical support for quantum dot regulation under high entanglement.Finally,we demonstrate the feasibility of implementing a three-qubit quantum gate,using the Toffoli gate as a representative example,under the condition that the triangular triple quantum dot system maintains high entanglement.展开更多
Controlling surface chemistry is critically important for improving the initial Coulombic efficiency(ICE)and adsorption capacity of hard carbon anode used in Li/Na/K-ion batteries.However,accurately identifying the ty...Controlling surface chemistry is critically important for improving the initial Coulombic efficiency(ICE)and adsorption capacity of hard carbon anode used in Li/Na/K-ion batteries.However,accurately identifying the types and concentrations of hydrogen/oxygen terminated functional groups(HTFG/OTFGs)and distinguishing their functionalities remain challenge.Herein,we quantitatively investigated the surface chemistry on hard carbon via ultra-high temperature programed desorption measurements,and uncovered the role of HTFG/OTFGs in influencing ICE and adsorption capacity in Li/Na/K-ions cells.The C-H group is found to be dominant species on the surface of hard carbon,and presents a positive correlation with ICE values and adsorption capacity.The low reactivity of C-H group with both electrolyte salt and solvent results in the formation of thinner and highly conducive solid electrolyte interphase(SEI)layer,which benefit for the enhanced ICE and improved Li/Na/K-ions diffusion across SEI layer.Additionally,the pimping trapping effect of C-H groups allows the adsorbed Li/Na/K-ions to migrate into graphitic interlayer quickly,enhancing the slope capacity.By fabricating a C-H group-rich surface chemistry on hard carbon,a high ICE value and satisfactory specific capacity have been realized.These findings enrich our understanding of the surface chemistry-induced interfacial reaction,which effectively guides the rational design of high-performance hard carbon.展开更多
Raman spectroscopy offers a great power to detect,analyze and identify molecules,and monitor their temporal dynamics and evolution when combined with single-molecule surface-enhanced Raman scattering(SM-SERS)substrate...Raman spectroscopy offers a great power to detect,analyze and identify molecules,and monitor their temporal dynamics and evolution when combined with single-molecule surface-enhanced Raman scattering(SM-SERS)substrates.Here we present a SM-SERS scheme that involves simultaneously giant chemical enhancement from WS22D materials,giant electromagnetic enhancement from plasmonic nanogap hot spot,and inhibition of molecular fluorescence influence under near-infrared laser illumination.Remarkably we find Coulomb attraction between analyte and gold nanoparticle can trigger spontaneous formation of molecule-hotspot pairing with high precision,stability and robustness.The scheme has enabled realization of universal,robust,fast,and large-scale uniform SM-SERS detection for three Raman molecules of rhodamine B,rhodamine 6G,and crystal violet with a very low detection limit of 10−16 M and at a very fast spectrum acquisition time of 50 ms.展开更多
The isospin asymmetry and quadrupole deformation value of drip-line nuclei are investigated using the Weizsäcker-Skyrme nuclear mass formula.We observe that for heavy nuclei at the neutron drip line,the Coulomb e...The isospin asymmetry and quadrupole deformation value of drip-line nuclei are investigated using the Weizsäcker-Skyrme nuclear mass formula.We observe that for heavy nuclei at the neutron drip line,the Coulomb energy heightened by an aug-mented charge could not be mitigated completely by symmetry energy because of isospin asymmetry saturation but is resisted complementally by strong nuclear deformation.The positions of saltation for the difference in proton numbers between two neighboring nuclei at the neutron drip line,and the isospin asymmetry of the neutron drip-line nucleus as a function of the neutron number distinctly correspond to the known magic numbers,which can serve as a reference to verify the undeter-mined neutron magic number.Through fitting of the binding energy difference between mirror nuclei(BEDbMN),a set of Coulomb energy coefficients with greater accuracy is obtained.A high-precision description of the BEDbMN is useful for accurately determining the experimentally unknown mass of the nucleus close to the proton drip line if the mass of its mirror nucleus is measured experimentally.展开更多
This study theoretically investigates chaos in a cavity optomechanical system with Coulomb coupling.The system consists of a Fabry-Pérot cavity with a movable mirror,where Coulomb interactions arise from charging...This study theoretically investigates chaos in a cavity optomechanical system with Coulomb coupling.The system consists of a Fabry-Pérot cavity with a movable mirror,where Coulomb interactions arise from charging the two movable mirrors.We examine the chaotic dynamics under the influence of both single and bichromatic laser fields.The single laser field represents a system driven exclusively by the pump field,whereas the bichromatic field represents simultaneous driving by both the pump and probe fields.In addition to conventional chaos-inducing methods through parameter variations,we demonstrate that increasing the Coulomb coupling strength enhances the system’s nonlinearity and induces chaotic behavior.Furthermore,we propose several strategies for generating and controlling chaos,while also identifying the parameter ranges necessary for the resonance of the two mechanical oscillators.Interestingly,when adjusting the driving power in a system driven solely by the pump field,we unexpectedly observe the emergence of high-order sidebands.These findings contribute to the development of chaotic behavior in future cavity optomechanical systems and provide a theoretical basis for applications in physical random number generation and secure communication.展开更多
The release of accumulated stress through earthquakes is known to devote to the mud volcanism occurrence,which may in turn affect subsequent regional seismicity.Mud volcanoes have been observed on the northeast contin...The release of accumulated stress through earthquakes is known to devote to the mud volcanism occurrence,which may in turn affect subsequent regional seismicity.Mud volcanoes have been observed on the northeast continental margin of the South China Sea as well.Based on the mud volcanoes and earthquakes catalogue,we measured the spatial and temporal distribution of z and b values,to explore the geodynamic process of the repeated eruptions of mud volcanoes influence on the regional seismicity.The results suggest a close correlation between the b-z values and mud volcanism occurrence in the SW Taiwan.Generally,the z-value anomalies in where the mud volcanoes eruptions show unchanged negative values and indicate seismic quiescence before a big earthquake,whereas the b-values often show periodicity fluctuations around the value of 0.5.This may indicate a mutual triggering relationship between the mud volcanoes and earthquakes.We infer that mud volcano eruptions help to partition and release part of the regional stress accumulation from the seismogenic structures,thus balancing the local stress and mitigating large-magnitude seismicity occurring probability.展开更多
In the context of future electron-ion collision experiments,particularly the Electron-Ion Collider(EIC)and the Electron-Ion Collider in China(EicC),investigating exclusive photoproduction processes is of paramount imp...In the context of future electron-ion collision experiments,particularly the Electron-Ion Collider(EIC)and the Electron-Ion Collider in China(EicC),investigating exclusive photoproduction processes is of paramount importance.These processes offer a distinctive opportunity to probe the gluon structure of nuclei across a broad range of Bjorken x,thereby enabling measurements of nuclear shadowing and facilitating the search for gluon saturation and color glass condensates.This study explores the potential of utilizing neutron tagging via the Coulomb excitation of nuclei to precisely determine the impact parameter for exclusive photoproduction in electron-ion collisions.By developing the equivalent photon approximation for fast electrons,this study incorporates a coordinate-space-dependent photon flux distribution to elucidate the relationship between the photon transverse momentum distribution and the collision impact parameter.Furthermore,the differential cross section for Coulomb excitation of nuclei is derived by leveraging the spatial information from the photon flux.Our calculations demonstrate that neutron tagging can significantly alter the impact parameter distributions,thereby providing a robust method for impact parameter manipulation in electron-ion collisions.This study provides valuable insights and strategies for exploring the impact parameter dependence of exclusive photoproduction,offering novel insights for experimental design and data analysis.Ultimately,it enhances our understanding of the gluon distribution within the nucleus.展开更多
On April 3,2024,an M 7.3 earthquake occurred in the offshore area of Hualien County,Taiwan,China.The seismogenic structure at the epicentral location was highly complex,and studying this earthquake is paramount for un...On April 3,2024,an M 7.3 earthquake occurred in the offshore area of Hualien County,Taiwan,China.The seismogenic structure at the epicentral location was highly complex,and studying this earthquake is paramount for understanding regional fault activity.In this study,we employed ascending and descending orbit Sentinel-1 Synthetic Aperture Radar(SAR)data and utilized differential interferometry(InSAR)technique to obtain the co-seismic deformation field of this event.The line-of-sight deformation field revealed that the main deformation caused by this earthquake was predominantly uplift,with maximum uplift values of approximately 38.8 cm and 46.1 cm for the ascending and descending orbits,respectively.By integrating the three-dimensional GNSS coseismic deformation field,we identified the seismogenic fault located in the offshore thrust zone east of Hualien,trending towards the northwest.The fault geometry parameters,obtained through the inversion of an elastic half-space homogeneous model,indicated an optimal fault strike of 196°,a dip angle of 30.9°,and an average strike-slip of 0.4 m and dip-slip of-2.6 m.This suggests that the predominant motion along the seismogenic fault is thrusting.The distribution of post-seismic Coulomb stress changes revealed that aftershocks mainly occurred in stress-loaded regions.However,stress loading was observed along the northern segment of the Longitudinal Valley Fault,with fewer aftershocks.This highlights the importance of closely monitoring the seismic hazard associated with this fault segment.展开更多
Rechargeable batteries are essential energy storage devices that power portable devices and electrical vehicles throughout the wo rld.In general,it is thought that the electrochemical performance of recha rgeable batt...Rechargeable batteries are essential energy storage devices that power portable devices and electrical vehicles throughout the wo rld.In general,it is thought that the electrochemical performance of recha rgeable batteries is mostly determined by the electrodes within them and that the electrolyte plays a relatively passive role.However,ion transport and storage can be greatly influenced by the electrolyte solution structure,specifically,ion solvation within the bulk and ion desolvation across the electrode/electrolyte interfaces.Herein,we studied the role of the electrolyte as an active component of electrochemical energy storage devices.We found that with an appropriate electrolyte formulation,ion storage in disordered carbonaceous anode materials can occur spontaneously without externally supplied electrical energy.Reduced graphene oxide(RGO)in an ether-based electrolyte demonstrates'spontaneous'ion storage behaviors of adsorbing and inserting the solvated ions utilizing facilitated permeability and wettability of RGO,which results in Coulombic efficiency of~145%due to additional charging capacity of~180 mAh g^(-1)during electrochemical processes.The unexpected spontaneous ion storage behavior was extensively investigated using a combination of electrochemical analyses and diagnostics,advanced characterizations,and computational simulation.We believe the spontaneous ion storage behavior offers a new way to further improve the energy efficiency of practical rechargeable batteries.展开更多
This study analytically examines the ionization of atoms in strong near-circular laser fields.The classic Keldysh-Rutherford(KR)Coulomb-scattering(CS)model[Phys.Rev.Lett.121123201(2018)]successfully explained the atto...This study analytically examines the ionization of atoms in strong near-circular laser fields.The classic Keldysh-Rutherford(KR)Coulomb-scattering(CS)model[Phys.Rev.Lett.121123201(2018)]successfully explained the attoclock experimental curve for the H atom at lower laser intensities.Here,we develop a semiclassical model that includes the initial conditions related to the quantum properties of tunneling in the KR model at the beginning of the scattering process.This model is able to explain recent attoclock experimental curves over a wider range of laser and atomic parameters.Our results show the importance of system symmetry and quantum effects in attoclock measurements,suggesting the complex role of the Coulomb potential in strong-field ionization.展开更多
Pre-lithiation methods address the challenges of low initial coulombic efficiency(ICE)and reduced energy density in lithium-ion batteries(LIBs)by adding additional lithium sources to compensate for initial irreversibl...Pre-lithiation methods address the challenges of low initial coulombic efficiency(ICE)and reduced energy density in lithium-ion batteries(LIBs)by adding additional lithium sources to compensate for initial irreversible Li+losses.The direct contact pre-lithiation(DC-Pr)method has garnered extensive attention due to its simplicity,convenience as well as significant effects on the improved cycling durability.Considering the most important factors,i.e.,effectiveness and uniformity,this review focuses on the anode DC-Pr method for LIBs with the lithium sources from Li foil,stabilized lithium metal powder(SLMP),lithium-rich alloys,and physical vapor deposition of lithium metal.After summarizations and discussions,the review overviews the challenges and prospects for DC-Pr methods,aiming to provide guidance for the construction and developments of practical LIBs.展开更多
During 7th-15th October 2023,an earthquake sequence with four MW6.2-6.3 occurred in the Herat region,Afghanistan,causing damage to buildings,fire,and loss of life.The co-seismic deformation induced by the earthquake s...During 7th-15th October 2023,an earthquake sequence with four MW6.2-6.3 occurred in the Herat region,Afghanistan,causing damage to buildings,fire,and loss of life.The co-seismic deformation induced by the earthquake sequence helps us invert the rupture model of these earthquakes to constrain the geometric characteristics of the Herat fault system,and estimate the future seismic risk at this fault system.In this work,we utilized the line-of-sight(LOS)displacements from Interferometric Synthetic Aperture Radar(InSAR)observations to determine the optimal fault geometry and slip distribution of the 2023 Afghanistan earthquake sequence through a two-step inversion method.Our results indicated that these four MW6.2-6.3 earthquakes ruptured the western and northwestern segments of the Herat fault system,which are dominated by thrust motions.We identified two fault models from InSAR LOS displacement data,with two different strikes,and the same dip angle range of about 35-45°.The source model with the strike of 280.5°has a peak slip of about 2.2 m,a central rupture zone with about 25 km along-strike length,and a depth range of 5-10 km,corresponding to a MW6.67 earthquake.The following source model with the strike direction of about 240°has smaller rupture length and width,and a peak slip of about 2.5 m,corresponding to a MW6.65 earthquake.We also calculated the Coulomb Failure Stress of the Herat fault system around this rupture area caused by this earthquake sequence.Our results indicated that the stress loading at the western segment of the Herat Fault system is greater than the triggering threshold,suggesting that the future seismic risk in this area is at a relatively high stage.In summary,the rupture model of these earthquakes indicates that two unidentified thrust faults between the western and northwestern segments of the Herat fault system are in a compression-stress environment.展开更多
C/SiO_(x)anode with higher capacity and lower lithiation potential has been recognized as a nextgeneration alternative to graphite for high-energy-density lithium-ion batteries.However,C/SiO_(x)suffers from low initia...C/SiO_(x)anode with higher capacity and lower lithiation potential has been recognized as a nextgeneration alternative to graphite for high-energy-density lithium-ion batteries.However,C/SiO_(x)suffers from low initial Coulombic efficiency(ICE),which significantly hinders its practical application.Herein,we reported a straightforward iodine redox chemistry strategy to realize highly reversible Li storage behavior and remarkably enhanced ICE of high-capacity C/SiO_(x)anode toward long-life lithium-ion batteries.Specifically,I2is introduced into porous C/SiO_(x)via simple fumigation to synthesize their composite(C/SiO_(x)@I),in which I_(2)can effectively inhibit the irreversible lithiation reactions of SiO_(x)through redox reaction.Further,redox reaction intermediates of LiI_(3)and LiIO_(3)can inhibit the decomposition of electrolyte and LiPF6,thereby reducing the thickness of the solid-electrolyte interphase film.Consequently,the obtained C/SiO_(x)@I exhibits a considerable capacity of 1241 mAh g^(-1)with an improved ICE of 88.5%at 0.1 A g^(-1)and impressive cyclability,showing capacity retention of 95%after 700 cycles at5.0 A g^(-1).Besides,the C/SiO_(x)@I with a 12%addition ratio can greatly enhance the capacity of graphite from 352 to 454 mAh g^(-1),with negligible impact on its ICE.When the addition ratio is 9%,the energy density of the 18,650 cylindrical battery composed of graphite and Li[Ni_(0.8)Co_(0.1)Mn_(0.1)]O_(2)can be enhanced by approximately 25 Wh kg^(-1).This study opens a new avenue for developing high ICE in SiO_(x)-based anodes for high-energy-density lithium-ion batteries.展开更多
基金support from the National Key Projects for Research and Development of China(Grant Nos.2022YFA1204700,2021YFA1400400)National Natural Science Foundation of China(Grant No.12525403)+3 种基金Natural Science Foundation of Jiangsu Province(Grant Nos.BK20220066,BK20233001)Program for Innovative Talents and Entrepreneur in Jiangsu(Grant No.JSSCTD202101)support from the JSPS KAKENHI(Grant Numbers 21H05233 and 23H02052)World Premier International Research Center Initiative(WPI),MEXT,Japan.
文摘Coulomb drag refers to the phenomenon in which a current driven through one conducting layer induces a voltage nearby,electrically isolated layer sorely through interlayer Coulomb interactions between charge carriers.It has been extensively studied in various systems,including parallel nanowires,double quantum wells,and double-layer graphene.Here,we report the observation of Coulomb drag in a novel system consisting of two graphene layers separated laterally by a 30 nm gap within the material plane,exhibiting behavior distinct from that in vertical graphene heterostructures.Our experiments reveal pronounced negative drag resistances under an out-of-plane magnetic field at the quantum Hall edges,reaching a maximum when the carrier densities in both graphene layers are tuned to the charge neutrality point via gate voltages.Our work establish two separate and spatially closed quantum Hall edge modes as a new platform to explore electronic interaction physics between one dimensional systems.
基金supported by the Key Laboratory of Sichuan Province for Lithium Resources Comprehensive Utilization and New Lithium Based Materials for Advanced Battery Technology(LRMKF202405)the National Natural Science Foundation of China(52402226)the Natural Science Foundation of Sichuan Province(2024NSFSC1016).
文摘Coal-derived hard carbon(HC)represents a promising anode material for sodium-ion batteries owing to its cost-effectiveness and high carbon yield.However,conventional carbonization induces excessive graphitization,yielding insufficient interlayer spacing(d_(002)<0.37 nm)and underdeveloped closed pores.Herein,we propose a dynamic crystallization control strategy through carbothermal shock treatment(1300°C,30 s)that decouples thermodynamic and kinetic constraints.This method precisely modulates graphite domain ordering kinetics,producing short-range ordered structures with expanded interlayer spacing(d_(002)=0.385 nm)and homogeneously distributed closed nanopores.Through combined in situ characterization and first-principles calculations,we elucidate a three-stage crystallization mechanism:(i)amorphous carbon transformation,(ii)open-pore collapse,and(iii)pseudo-graphitic ordering.The optimized HC achieves record performance with 88.6%initial Coulombic efficiency and 204 mA h g^(−1)plateau capacity,while its optimal interlayer spacing lowers Na+diffusion barriers to enable exceptional rate capability(221 mA h g^(−1)at 0.5C after 300 cycles).Practical pouch cells maintain 85%capacity retention after 100 cycles at−20°C and deliver 284 Wh kg^(−1)energy density.This work establishes a kinetic regulation paradigm for graphitization-prone precursors,advancing the rational design of high-performance HC anodes.
基金National Natural Science Foundation of China(Grant Nos.41930101 and 42101096)the China Postdoctoral Science Foundation(No.2019M660091XB)+8 种基金the Key Research and Development Project of Ecological Civilization Construction in Gansu Province(No.24YFFA054)the Natural Science Foundation of Gansu Province(Grant Nos.23JRRA857,23JRRG0015,and 21JR7RA317)the Gansu Province Higher Education Institutions Young Doctor(2024QB-046)the Open Fund of Wuhan,Gravitational Field and Solid Tides,National Field Observation and Research Station(WHYWZ202403)the National Cryosphere Desert Data Center(No.E01Z790201/2021kf07)the Lanzhou Talent Innovation and Entrepreneurship(No.2022-RC-73)the Experimental Teaching Reform Project of Lanzhou Jiaotong University(2024002)the Undergraduate Teaching Reform Project of Lanzhou Jiaotong University(JGY202416)"Young Scientific and Technological Talents Supporting Project"Project of Gansu Province(Li Wei)。
文摘An MW6.0 earthquake struck Jishishan County in Linxia Prefecture,Gansu Province,on December 18,2023.In this research,Sentinel-1A satellite radar observations were used to obtain the field of coseismic deformation of the Jishishan earthquake in 2023,and the geometric and fine slip distribution of the seismogenic fault were inverted using this as a constraint.The results show that the earthquake is characterized by thrust movement.The coseismic slip distribution results show that the maximum slip of this earthquake is 0.3 m.The Coulomb stress distribution shows that the whole section of the southern edge of Lajishan fault,the NWW trending segment of the northern edge of Lajishan fault and its NNW trending segment to the south of the epicenter,the northern edge of the West Qinling fault and the segment to the east of the epicenter of the Daotanghe Linxia fault are under stress loading,which indicates an increase in the potential risk of earthquakes.This research discussed the seismogenic characteristics of earthquakes and the tendency of faults.We speculate that the Jishishan earthquake is the result of the joint action of regional faults and tectonic stress.Based on the observation of seismic data,geodesy,and other geological and geophysical data,we believe that the earthquake was caused by the activation of weak areas under the crust by the local stress from the driving mechanism of the northeast expansion of Qinghai-Xizang Plateau.The seismogenic fault of this earthquake is more likely to be northeast dipping under the comprehensive consideration of various factors,which occurred on the concealed fault belonging to the eastern edge of the Jishishan fault zone.
基金supported by the National Natural Science Foundation of China(Grant No.12305050)the Natural Science Foundation of Jiangsu Higher Education Institutions of China(Grant No.23KJB140017)the Zhejiang Provincial Natural Science Foundation of China(Grant No.LZ25A050001)。
文摘Quantum dot systems emerge as promising platforms for studying nanoscale thermoelectric effects and quantum fluctuation phenomena.In this work,we investigate the thermodynamic performance of a Coulomb-blockaded quantum dot operating as a quantum heat engine using the quantum master equation approach.By incorporating full counting statistics,we analyze both average transport properties and current fluctuations in this nanoscale system.We demonstrate that electron-electron interactions significantly enhance thermoelectric performance by increasing both the output power and energy conversion efficiency.Furthermore,we show that Coulomb interactions suppress current fluctuations while preserving the validity of the thermodynamic uncertainty relation.Our results provide important insights into the interplay between quantum effects and thermodynamic principles in nanoscale heat engines.
基金supported by the U.S.Department of Energy(DOE),Office of Energy Efficiency and Renewable Energy(EERE),Vehicle Technologies Office(VTO)under the Silicon Consortium Seedling project received by Z.H.Coperated for the DOE Office of Science by UChicago Argonne,LLC,under Contract DE-AC02-06CH11357+2 种基金Pacific Northwest National Laboratory(PNNL)was supported by the U.S.DOE,Office of Advanced Research Projects Agency-Energy(ARPA-E)under the EVs4ALL Program with the contract number DE-AC05-76RL01830operated by Battelle for the DOE under Contract DE-AC0576RL01830performed at the Oak Ridge National Laboratory(GMV)and supported by U.S.DOE’s VTO under the Silicon Consortium Program received by G.M.V.and directed by Carine Steinway,Nicolas Eidson Thomas,Thomas Do。
文摘Silicon(Si)is a promising high-capacity anode in lithium-ion batteries but suffers from chronic chemical degradation and capacity fading during calendar aging,greatly hindering its automobile applications.Electrolyte engineering currently relies on conventional evaluation criteria of reducing coulombic consumption,which implicitly presume its equivalence to irreversible capacity loss and complicates battery development.We introduce the detrimental ratioρto quantify the fraction of parasitic species that permanently degrades active material.This metric is independent and crucially complements total coulombic consumption for accurate performance evaluation.We systematically investigate multiple electrolyte formulations using high-precision leakage current measurements,open-circuit-voltage experiments,and post-mortem characterizations.Although some electrolytes exhibit similarly low coulombic consumption,they diverge significantly in capacity retention andρ.Especially,dimethyl-carbonate-based localized-high concentration electrolyte can synergically achieve low coulombic consumption and detrimental ratioρduring calendar aging,owing to its chemically inert and structurally resilient solidelectrolyte interface with minimal isolated Si material.By contrast,increasing fluoroethylene carbonate(FEC)additive content suppresses electrolyte breakdown but suffers aggravated chemical degradation of more LixSi isolation for irreversible capacity loss with a risingρ.This study critically reveals that the chemistry-characteristic detrimental ratioρestablishes physically informed performance evaluation to pave the way for accelerating battery development.
基金supported by the National Natural Science Foundation of China(Nos.42174074,and 41674055).
文摘We investigated the influence of historical earthquakes on the 2022 Luding M_(S)6.8 earthquake and its subsequent effects.We computed the viscoelastic Coulomb stress changes induced by these historical seismic events using the rupture model of historical earthquakes and the layered Maxwell viscoelastic medium model.Our findings indicate that the Luding earthquake was brought forward approximately 29 years because of several historical earthquakes.Specifically,the 1923 Renda M_(S)7.3 earthquake,the 1933 Diexi M_(S)7.5 earthquake,the 1973 Luhuo M_(S)7.3 earthquake,the 2008 Kangding M_(S)5.1 earthquake,the 2008 Wenchuan M_(S)8.0 earthquake,the 2014 Kangding M_(S)6.3 earthquake,and the 2014 Kangding M_(S)5.8 earthquake advanced the occurrence of the event by 117.61,26.67,84.51,0.27,0.91,7.64,and 3.17 years,respectively.Conversely,the 1936 Mabian earthquake swarm,the 1948 Litang M_(S)7.3 earthquake,the 1955 Kangding M_(S)7.5 earthquake,and the 2013 Lushan M_(S)7.0 earthquake delayed its occurrence by 39.89,22.43,144.23,and 4.89 years,respectively.Furthermore,by employing the halfspace homogeneous elastic model and the rupture characteristics of the Luding earthquake,we computed the coseismic Coulomb stress changes in neighboring faults.Our results reveal increased Coulomb stress on the Xianshuihe fault(excluding its southern segment),the Anninghe fault,the Zemuhe fault,the Daliangshan fault,the southern segment of the Longmenshan fault,the northern segment of the Mabian-Yanjin fault,and the Xiaojinhe fault.Conversely,we observed stress decreases in the southern segment of the Jinshajiang fault,the central and eastern segments of the Longriba fault,the Mabian-Yanjin fault(excluding its northern segment),and the southern segment of the Xianshuihe fault.
基金support from the Heilongjiang Province"Double First Class"Discipline Collaborative Innovation Project(No.LJGXCG2023-061).
文摘Hard carbon is a vital anode material for sodium-ion batteries;however,the nonuniform growth of solid electrolyte interphase(SEI)film substantially diminishes its initial coulombic efficiency(ICE)and cycle life.The chemical and morphological properties of surface highly influence the electrode/electrolyte interfacial reactions.In this study,we have tuned orbital hybridization states forming an interface enriched with sp^(2) hybridized carbon(sp^(2)-C),which decreases the binding energy to solvent molecules and inhibits excessive solvent decomposition during SEI formation.Benefiting from successfully constructed inorganic-rich SEI,the ICE increased to 91%and sodium storage capacity reached 346 mAh/g.Besides,the capacity retention rate was 90.7%after 700 cycles at 1 A/g higher than pristine electrode(83.8%).
文摘As an important index to measure the degree of entanglement in quantum systems,concurrence plays an important role in practical research.In this paper,we study the concurrence between two qubits in triangular triple quantum dot structure.Through calculation and simulation,it is found that concurrence is mainly affected by the interdot coupling strength t,Coulomb interactionU,temperature T,and electrode coupling G.Through comparative studies with parallel triple quantum dot structures,we demonstrate that the triangular geometry exhibits significantly enhanced concurrence under identical conditions.In addition,under the condition that concurrence exceeds 0.9,the functional relationship between t and U is obtained through simulation,which provides theoretical support for quantum dot regulation under high entanglement.Finally,we demonstrate the feasibility of implementing a three-qubit quantum gate,using the Toffoli gate as a representative example,under the condition that the triangular triple quantum dot system maintains high entanglement.
基金financially supported by the National Key Research and Development Program of China(2022YFE0206300)the National Natural Science Foundation of China(U21A2081,22075074,22209047)+4 种基金the National College Students Innovation and Entrepreneurship Training Program(S202410532594,S202410532357)the Macao Science and Technology Development Fund(File No.0013/2021/AMJ)the Foundation of Yuelushan Center for Industrial Innovation(2023YCII0119)JST SICORP(JPMJSC2112)JST PRESTO(JPMJPR23QA)。
文摘Controlling surface chemistry is critically important for improving the initial Coulombic efficiency(ICE)and adsorption capacity of hard carbon anode used in Li/Na/K-ion batteries.However,accurately identifying the types and concentrations of hydrogen/oxygen terminated functional groups(HTFG/OTFGs)and distinguishing their functionalities remain challenge.Herein,we quantitatively investigated the surface chemistry on hard carbon via ultra-high temperature programed desorption measurements,and uncovered the role of HTFG/OTFGs in influencing ICE and adsorption capacity in Li/Na/K-ions cells.The C-H group is found to be dominant species on the surface of hard carbon,and presents a positive correlation with ICE values and adsorption capacity.The low reactivity of C-H group with both electrolyte salt and solvent results in the formation of thinner and highly conducive solid electrolyte interphase(SEI)layer,which benefit for the enhanced ICE and improved Li/Na/K-ions diffusion across SEI layer.Additionally,the pimping trapping effect of C-H groups allows the adsorbed Li/Na/K-ions to migrate into graphitic interlayer quickly,enhancing the slope capacity.By fabricating a C-H group-rich surface chemistry on hard carbon,a high ICE value and satisfactory specific capacity have been realized.These findings enrich our understanding of the surface chemistry-induced interfacial reaction,which effectively guides the rational design of high-performance hard carbon.
基金financial support from Science and Technology Project of Guangdong(2020B010190001)National Natural Science Foundation(12434016).
文摘Raman spectroscopy offers a great power to detect,analyze and identify molecules,and monitor their temporal dynamics and evolution when combined with single-molecule surface-enhanced Raman scattering(SM-SERS)substrates.Here we present a SM-SERS scheme that involves simultaneously giant chemical enhancement from WS22D materials,giant electromagnetic enhancement from plasmonic nanogap hot spot,and inhibition of molecular fluorescence influence under near-infrared laser illumination.Remarkably we find Coulomb attraction between analyte and gold nanoparticle can trigger spontaneous formation of molecule-hotspot pairing with high precision,stability and robustness.The scheme has enabled realization of universal,robust,fast,and large-scale uniform SM-SERS detection for three Raman molecules of rhodamine B,rhodamine 6G,and crystal violet with a very low detection limit of 10−16 M and at a very fast spectrum acquisition time of 50 ms.
基金supported by the Ministry of Science and Technology of China(No.2022YFE0103400)Natural Science Foundation of Guangxi Province(No.2021GXNSFAA196052)National Natural Science Foundation of China(No.11965004).
文摘The isospin asymmetry and quadrupole deformation value of drip-line nuclei are investigated using the Weizsäcker-Skyrme nuclear mass formula.We observe that for heavy nuclei at the neutron drip line,the Coulomb energy heightened by an aug-mented charge could not be mitigated completely by symmetry energy because of isospin asymmetry saturation but is resisted complementally by strong nuclear deformation.The positions of saltation for the difference in proton numbers between two neighboring nuclei at the neutron drip line,and the isospin asymmetry of the neutron drip-line nucleus as a function of the neutron number distinctly correspond to the known magic numbers,which can serve as a reference to verify the undeter-mined neutron magic number.Through fitting of the binding energy difference between mirror nuclei(BEDbMN),a set of Coulomb energy coefficients with greater accuracy is obtained.A high-precision description of the BEDbMN is useful for accurately determining the experimentally unknown mass of the nucleus close to the proton drip line if the mass of its mirror nucleus is measured experimentally.
基金supported by Young Talents from Longyuan,Gansu Province(Liwei Liu),the Fundamental Research Funds for the Central Universities,Northwest Minzu University(Grant No.31920230134)Teaching Achievement Cultivation Project of Gansu Province Department of Education(Grant No.2022GSJXCGPY-46)+1 种基金Special research topic on curriculum and teaching materials for primary,secondary and higher schools,Gansu Province Department of Education(Grant No.GSJC-Y2024204)Quality improvement project for undergraduate talent training,Northwest Minzu University(Grant Nos.2024YBJG-04 and 2024FCTD-03).
文摘This study theoretically investigates chaos in a cavity optomechanical system with Coulomb coupling.The system consists of a Fabry-Pérot cavity with a movable mirror,where Coulomb interactions arise from charging the two movable mirrors.We examine the chaotic dynamics under the influence of both single and bichromatic laser fields.The single laser field represents a system driven exclusively by the pump field,whereas the bichromatic field represents simultaneous driving by both the pump and probe fields.In addition to conventional chaos-inducing methods through parameter variations,we demonstrate that increasing the Coulomb coupling strength enhances the system’s nonlinearity and induces chaotic behavior.Furthermore,we propose several strategies for generating and controlling chaos,while also identifying the parameter ranges necessary for the resonance of the two mechanical oscillators.Interestingly,when adjusting the driving power in a system driven solely by the pump field,we unexpectedly observe the emergence of high-order sidebands.These findings contribute to the development of chaotic behavior in future cavity optomechanical systems and provide a theoretical basis for applications in physical random number generation and secure communication.
基金supported by the Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(No.SML2021SP318)the National Postdoctoral Program for Innovative Talents(No.BX20190391)+1 种基金the Guangdong Province Introduced Innovative R&D Team of Geological Processes and Natural Disasters around the South China Sea founded by the Science and Technology Department of Guangdong Province(No.2016ZT06N331)the Guangdong Basic and Applied Basic Research Foundation(Nos.2019A1515110305,2021A1515011130,2021A1515110288)。
文摘The release of accumulated stress through earthquakes is known to devote to the mud volcanism occurrence,which may in turn affect subsequent regional seismicity.Mud volcanoes have been observed on the northeast continental margin of the South China Sea as well.Based on the mud volcanoes and earthquakes catalogue,we measured the spatial and temporal distribution of z and b values,to explore the geodynamic process of the repeated eruptions of mud volcanoes influence on the regional seismicity.The results suggest a close correlation between the b-z values and mud volcanism occurrence in the SW Taiwan.Generally,the z-value anomalies in where the mud volcanoes eruptions show unchanged negative values and indicate seismic quiescence before a big earthquake,whereas the b-values often show periodicity fluctuations around the value of 0.5.This may indicate a mutual triggering relationship between the mud volcanoes and earthquakes.We infer that mud volcano eruptions help to partition and release part of the regional stress accumulation from the seismogenic structures,thus balancing the local stress and mitigating large-magnitude seismicity occurring probability.
基金supported in part by the National Key Research and Development Program of China under Contract No.2022YFA1604900the National Natural Science Foundation of China(NSFC)under Contract No.12175223 and 12005220+1 种基金W.Zha is supported by Anhui Provincial Natural Science Foundation No.2208085J23Youth Innovation Promotion Association of Chinese Academy of Science.
文摘In the context of future electron-ion collision experiments,particularly the Electron-Ion Collider(EIC)and the Electron-Ion Collider in China(EicC),investigating exclusive photoproduction processes is of paramount importance.These processes offer a distinctive opportunity to probe the gluon structure of nuclei across a broad range of Bjorken x,thereby enabling measurements of nuclear shadowing and facilitating the search for gluon saturation and color glass condensates.This study explores the potential of utilizing neutron tagging via the Coulomb excitation of nuclei to precisely determine the impact parameter for exclusive photoproduction in electron-ion collisions.By developing the equivalent photon approximation for fast electrons,this study incorporates a coordinate-space-dependent photon flux distribution to elucidate the relationship between the photon transverse momentum distribution and the collision impact parameter.Furthermore,the differential cross section for Coulomb excitation of nuclei is derived by leveraging the spatial information from the photon flux.Our calculations demonstrate that neutron tagging can significantly alter the impact parameter distributions,thereby providing a robust method for impact parameter manipulation in electron-ion collisions.This study provides valuable insights and strategies for exploring the impact parameter dependence of exclusive photoproduction,offering novel insights for experimental design and data analysis.Ultimately,it enhances our understanding of the gluon distribution within the nucleus.
基金supported by Shaanxi Province Natural Science Foundation Research Program[Grant number 2023JC-QN-0296]。
文摘On April 3,2024,an M 7.3 earthquake occurred in the offshore area of Hualien County,Taiwan,China.The seismogenic structure at the epicentral location was highly complex,and studying this earthquake is paramount for understanding regional fault activity.In this study,we employed ascending and descending orbit Sentinel-1 Synthetic Aperture Radar(SAR)data and utilized differential interferometry(InSAR)technique to obtain the co-seismic deformation field of this event.The line-of-sight deformation field revealed that the main deformation caused by this earthquake was predominantly uplift,with maximum uplift values of approximately 38.8 cm and 46.1 cm for the ascending and descending orbits,respectively.By integrating the three-dimensional GNSS coseismic deformation field,we identified the seismogenic fault located in the offshore thrust zone east of Hualien,trending towards the northwest.The fault geometry parameters,obtained through the inversion of an elastic half-space homogeneous model,indicated an optimal fault strike of 196°,a dip angle of 30.9°,and an average strike-slip of 0.4 m and dip-slip of-2.6 m.This suggests that the predominant motion along the seismogenic fault is thrusting.The distribution of post-seismic Coulomb stress changes revealed that aftershocks mainly occurred in stress-loaded regions.However,stress loading was observed along the northern segment of the Longitudinal Valley Fault,with fewer aftershocks.This highlights the importance of closely monitoring the seismic hazard associated with this fault segment.
基金supported by the faculty research fund of Sejong Universityfunding from the National Research Foundation of Korea(NRF)under grant number NRF-2022R1F1A1071444+2 种基金funding from NRF under grant numbers NRF-2022R1A2B5B03001781Funding provided by the Department of Energy Office of Energy EfficiencyRenewable Energy Vehicles Technology Office。
文摘Rechargeable batteries are essential energy storage devices that power portable devices and electrical vehicles throughout the wo rld.In general,it is thought that the electrochemical performance of recha rgeable batteries is mostly determined by the electrodes within them and that the electrolyte plays a relatively passive role.However,ion transport and storage can be greatly influenced by the electrolyte solution structure,specifically,ion solvation within the bulk and ion desolvation across the electrode/electrolyte interfaces.Herein,we studied the role of the electrolyte as an active component of electrochemical energy storage devices.We found that with an appropriate electrolyte formulation,ion storage in disordered carbonaceous anode materials can occur spontaneously without externally supplied electrical energy.Reduced graphene oxide(RGO)in an ether-based electrolyte demonstrates'spontaneous'ion storage behaviors of adsorbing and inserting the solvated ions utilizing facilitated permeability and wettability of RGO,which results in Coulombic efficiency of~145%due to additional charging capacity of~180 mAh g^(-1)during electrochemical processes.The unexpected spontaneous ion storage behavior was extensively investigated using a combination of electrochemical analyses and diagnostics,advanced characterizations,and computational simulation.We believe the spontaneous ion storage behavior offers a new way to further improve the energy efficiency of practical rechargeable batteries.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.12174239,12347165,and 12404330)Shaanxi Fundamental Science Research Project for Mathematics and Physics(Grant No.23JSY022)+2 种基金Natural Science Basic Research Program of Shaanxi(Grant No.2022JM-015)Hebei Natural Science Foundation(Grant No.A2022205002)Science and Technology Project of Hebei Education Department(Grant No.QN2022143)。
文摘This study analytically examines the ionization of atoms in strong near-circular laser fields.The classic Keldysh-Rutherford(KR)Coulomb-scattering(CS)model[Phys.Rev.Lett.121123201(2018)]successfully explained the attoclock experimental curve for the H atom at lower laser intensities.Here,we develop a semiclassical model that includes the initial conditions related to the quantum properties of tunneling in the KR model at the beginning of the scattering process.This model is able to explain recent attoclock experimental curves over a wider range of laser and atomic parameters.Our results show the importance of system symmetry and quantum effects in attoclock measurements,suggesting the complex role of the Coulomb potential in strong-field ionization.
基金sponsored by the financial support from Shanghai Oriental Talent ProgramOn-campus Scene Verification Project of Tongji University(kh0170020242359)+4 种基金Shanghai Research Institute of China Shenhua Coal-to-Liquids Chemical Co.,LtdNational Natural Science Foundation of China(52307249)the National Science Foundation of Shanghai Province(23ZR1465900)the Fundamental Research Funds for the Central Universities at Tongji University(PA2022000668,22120220426)the Nanchang Automotive Institute of Intelligence&New Energy of Tongji University(TPD-TC202211-02,20212CCH_(4)5004)。
文摘Pre-lithiation methods address the challenges of low initial coulombic efficiency(ICE)and reduced energy density in lithium-ion batteries(LIBs)by adding additional lithium sources to compensate for initial irreversible Li+losses.The direct contact pre-lithiation(DC-Pr)method has garnered extensive attention due to its simplicity,convenience as well as significant effects on the improved cycling durability.Considering the most important factors,i.e.,effectiveness and uniformity,this review focuses on the anode DC-Pr method for LIBs with the lithium sources from Li foil,stabilized lithium metal powder(SLMP),lithium-rich alloys,and physical vapor deposition of lithium metal.After summarizations and discussions,the review overviews the challenges and prospects for DC-Pr methods,aiming to provide guidance for the construction and developments of practical LIBs.
基金funded by the PhD Starting Research Fund in East China Jiaotong University,Grant No.2003423017the National Natural Science Foundation of China(Grant Nos.42304009)。
文摘During 7th-15th October 2023,an earthquake sequence with four MW6.2-6.3 occurred in the Herat region,Afghanistan,causing damage to buildings,fire,and loss of life.The co-seismic deformation induced by the earthquake sequence helps us invert the rupture model of these earthquakes to constrain the geometric characteristics of the Herat fault system,and estimate the future seismic risk at this fault system.In this work,we utilized the line-of-sight(LOS)displacements from Interferometric Synthetic Aperture Radar(InSAR)observations to determine the optimal fault geometry and slip distribution of the 2023 Afghanistan earthquake sequence through a two-step inversion method.Our results indicated that these four MW6.2-6.3 earthquakes ruptured the western and northwestern segments of the Herat fault system,which are dominated by thrust motions.We identified two fault models from InSAR LOS displacement data,with two different strikes,and the same dip angle range of about 35-45°.The source model with the strike of 280.5°has a peak slip of about 2.2 m,a central rupture zone with about 25 km along-strike length,and a depth range of 5-10 km,corresponding to a MW6.67 earthquake.The following source model with the strike direction of about 240°has smaller rupture length and width,and a peak slip of about 2.5 m,corresponding to a MW6.65 earthquake.We also calculated the Coulomb Failure Stress of the Herat fault system around this rupture area caused by this earthquake sequence.Our results indicated that the stress loading at the western segment of the Herat Fault system is greater than the triggering threshold,suggesting that the future seismic risk in this area is at a relatively high stage.In summary,the rupture model of these earthquakes indicates that two unidentified thrust faults between the western and northwestern segments of the Herat fault system are in a compression-stress environment.
基金financially supported by the National Natural Science Foundation of China(No.51962027,and 52262039)the Major Science and Technology Project of Inner Mongolia Autonomous Region(2021ZD0016)+3 种基金the National Key R&D Program of China(2020YFC1909105)the Fundamental Research Funds for Inner Mongolia University of Science&Technology(NO.2024QNJS071,2023QNJS052 and 2024QNJS064)the Program for Young Talents of Science and Technology in Universities of Inner Mongolia Autonomous Region(No.NJYT24002)the Central Guidance Fund for Local Scientific and Technological Development(2024ZY0012)。
文摘C/SiO_(x)anode with higher capacity and lower lithiation potential has been recognized as a nextgeneration alternative to graphite for high-energy-density lithium-ion batteries.However,C/SiO_(x)suffers from low initial Coulombic efficiency(ICE),which significantly hinders its practical application.Herein,we reported a straightforward iodine redox chemistry strategy to realize highly reversible Li storage behavior and remarkably enhanced ICE of high-capacity C/SiO_(x)anode toward long-life lithium-ion batteries.Specifically,I2is introduced into porous C/SiO_(x)via simple fumigation to synthesize their composite(C/SiO_(x)@I),in which I_(2)can effectively inhibit the irreversible lithiation reactions of SiO_(x)through redox reaction.Further,redox reaction intermediates of LiI_(3)and LiIO_(3)can inhibit the decomposition of electrolyte and LiPF6,thereby reducing the thickness of the solid-electrolyte interphase film.Consequently,the obtained C/SiO_(x)@I exhibits a considerable capacity of 1241 mAh g^(-1)with an improved ICE of 88.5%at 0.1 A g^(-1)and impressive cyclability,showing capacity retention of 95%after 700 cycles at5.0 A g^(-1).Besides,the C/SiO_(x)@I with a 12%addition ratio can greatly enhance the capacity of graphite from 352 to 454 mAh g^(-1),with negligible impact on its ICE.When the addition ratio is 9%,the energy density of the 18,650 cylindrical battery composed of graphite and Li[Ni_(0.8)Co_(0.1)Mn_(0.1)]O_(2)can be enhanced by approximately 25 Wh kg^(-1).This study opens a new avenue for developing high ICE in SiO_(x)-based anodes for high-energy-density lithium-ion batteries.
