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The Effects of Different Ratios of Feldspathic Sandstone and Sand Compound Soil on Water-stable Aggregates in 4 Years Crop Planting 被引量:1
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作者 Tong ZHAO Jichang HAN +2 位作者 Yang ZHANG Huanyuan WANG Xian JI 《Asian Agricultural Research》 2017年第3期96-101,109,共7页
To study the formation process of feldspathic sandstone and sand compound soil in the Mu Us Desert,1∶ 1,1∶ 2 and 1∶ 5 ratios of feldspathic sandstone and sand were mixed to obtain compound soil to plant crops,and a... To study the formation process of feldspathic sandstone and sand compound soil in the Mu Us Desert,1∶ 1,1∶ 2 and 1∶ 5 ratios of feldspathic sandstone and sand were mixed to obtain compound soil to plant crops,and analyze the rules of changes in water-stable aggregates of the compound soil among the 4 years crops growing process. The results showed,before crop planting,the order of mass percent of> 0. 25 mm and 0. 25-2. 00 mm water-stable aggregates in three kinds of compound soil was 1∶ 1 > 1∶ 2 > 1∶ 5,showing that the overall content was low; the mass percent of > 0. 25 mm water-stable aggregates remained at 18. 38%-28. 22%; the mass percent of 0. 25-0. 50 mm,0. 50-2. 00 mm,2. 00-5. 00 mm,and > 5. 00 mm water-stable aggregates was close with each other in each kind of compound soil. After4 years of planting,the mass percent of > 0. 25 mm water-stable aggregates in 1∶ 2 compound soil increased significantly and exceeded other2 kinds of compound soil,reached 32. 34%; the main components of > 0. 25 mm water stable aggregates in 1∶ 1,1∶ 2,and 1∶ 5 compound soil were 0. 25-0. 50 mm( 53. 54%),0. 25-0. 50 mm( 59. 43%),0. 05-2. 00 mm( 52. 16%),aggregates; 0. 25-2. 00 mm aggregates increased significantly in all three kinds of compound soil,with the highest increase in 1∶ 2 compound soil; the organic matters of 1∶ 2 compound soil were significantly correlated with 0. 25-0. 50 mm and 0. 25-2. 00 mm water-stable aggregates. The results showed that the ratio of 0. 25-2. 00 mm aggregates in the three kinds of compound soil was increased after 4 years of crop planting and 1∶ 2 compound soil was most favorable for the formation of aggregates. 展开更多
关键词 Feldspathic sandstone and sand compound soil Water-stable aggregates CEMENTATION
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Enhanced photodegradation of phenolic compounds by adding TiO_2 to soil in a rotary reactor 被引量:2
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作者 WANG Jing-xian CHEN Shuo QUAN Xie ZHAO Hui-min ZHAO Ya-zhi 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2006年第6期1107-1112,共6页
Photodegradation ofpentachlorophenol (PCP) and p-nitrophenol (PNP) in soil was carried out in a designed rotary reactor, which can provide the soil particles with continually uniform irradiation, and on a series o... Photodegradation ofpentachlorophenol (PCP) and p-nitrophenol (PNP) in soil was carried out in a designed rotary reactor, which can provide the soil particles with continually uniform irradiation, and on a series of thin soil layers. TiO2, as a kind of environmental friendly photocatalyst, was introduced to the soil to enhance the processes. Compared with that on the soil layers, photodegradation of PCP at initial concentration of 60 mg/kg was improved dramatically in the rotary reactor no matter whether TiO2 was added, with an increase of 3.0 times in the apparent first-order rate constants. The addition of 1 wt% TiO2 furthered the improvement by 1.4 times. Without addition of TiO2, PNP (initial concentration of 60 mg/kg) photodegradation rate in the rotary reactor was similar to that on the soil layers. When 1 wt% additional TiO2 was added, PNP photodegradation was enhanced obviously, and the enhancement in the rotary reactor was 2 times of that on the soil layers, which may be attributed to the higher frequency of the contact between PNP on soil particles and the photocatalyst. The effect of soil pH and initial concentrations of the target compounds on the photodegradation in the rotary reactor was investigated. The order of the degradation rate at different soil pH was relative to the aggregation of soil particles during mixing in the rotary reactor. Photodegradation of PCP and PNP at different initial concentrations showed that addition of TiO2 to enhance the photodegradation was more suitable for contaminated soil with higher concentration of PCP, while was effective for contaminated soil at each PNP concentration tested in our study. 展开更多
关键词 TiO2 PHOTODEGRADATION phenolic compounds soil remediation
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Review and prospect of soil compound erosion 被引量:2
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作者 YANG Wenqian ZHANG Gangfeng +2 位作者 YANG Huimin LIN Degen SHI Peijun 《Journal of Arid Land》 SCIE CSCD 2023年第9期1007-1022,共16页
Soil erosion is one of the most serious environmental issues constraining the sustainable development of human society and economies.Soil compound erosion is the result of the alternation or interaction between two or... Soil erosion is one of the most serious environmental issues constraining the sustainable development of human society and economies.Soil compound erosion is the result of the alternation or interaction between two or more erosion forces.In recent years,fluctuations and extreme changes in climatic factors(air temperature,precipitation,wind speed,etc.)have led to an increase in the intensity and extent of compound erosion,which is increasingly considered in soil erosion research.First,depending on the involvement of gravity,compound erosion process can be divided into compound erosion with and without gravity.We systematically summarized the research on the mechanisms and processes of alternating or interacting soil erosion forces(wind,water,and freeze-thaw)considering different combinations,combed the characteristics of compound erosion in three typical regions,namely,high-elevation areas,high-latitude areas,and dry and wet transition regions,and reviewed soil compound erosion research methods,such as station observations,simulation experiments,prediction models,and artificial neural networks.The soil erosion model of wind,water,and freeze-thaw interaction is the most significant method for quantifying and predicting compound erosion.Furthermore,it is proposed that there are several issues such as unclear internal mechanisms,lack of comprehensive prediction models,and insufficient scale conversion methods in soil compound erosion research.It is also suggested that future soil compound erosion mechanism research should prioritize the coupling of compound erosion forces and climate change. 展开更多
关键词 soil compound erosion soil erosion gravity erosion wind and water erosion freeze-thaw erosion
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Compound pollution of Cd,Pb,Cu,Zn,As in plant-soil system and its prevention 被引量:3
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作者 Wu Yanyu Wang Xin Li Ying(Institute of Applied Ecology,Chinese Academy of Sciences,Shenyang 110015, China) 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 1996年第4期474-482,共9页
By means of both pot and field tests,this paper studied the contents of Cd,Pb,Cu,Zn and As and their ecological effects on plant-soil system.in tissues of crops and soil microorganisms.It was found that there exist sy... By means of both pot and field tests,this paper studied the contents of Cd,Pb,Cu,Zn and As and their ecological effects on plant-soil system.in tissues of crops and soil microorganisms.It was found that there exist synergistic effect among these five elements,especially for Cd in combination.The reclaniation of soil polluted by these elements in combination is rather difficult to be carried out.The distinctive ecological and chemical behaviors between Cd and As make various reclamation measures less applicable,and thus,further research measures are necessary. 展开更多
关键词 compound pollution plant-soil system heavy metals.
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Compound contamination and secondary ecological effects of Cd and As in soil-alfalfa ecosystems 被引量:21
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作者 Zhou Qixing Gao Zhengmin(Institute of Applied Ecology, Chinese academy of Sciences),Shenyang 10015,China) 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 1994年第3期330-336,共7页
d and As both have harmful effects on the growth,development and seed germination of alfalfa, especially in such a condition as the coexistence of Cd and As in soil environment The research using the pot-culture imita... d and As both have harmful effects on the growth,development and seed germination of alfalfa, especially in such a condition as the coexistence of Cd and As in soil environment The research using the pot-culture imitative method first found that if soil was simultaneously polluted by Cd and As,function of alfalfa absorbing Cd from soil may be promoted because of the existence of As,in conversely,Cd may inhibit alfalfa plant from absorbing As It was also found that secon- dary ecological effects were most likely to be brought out due to the coexistence of Cd and As. For example,alfalfa is passive to excessively absorb Cu and Pb .The harmful effects undoubtedly intensi- fy the contamination of alfalfa, The results showed that the mechanism of the interaction among Cd,As,Pb and Cu in soil-alfalfa ecosystems is very complicated. 展开更多
关键词 compound contamination ecological effects Cd AS soil.
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Aromatic compound degradation by iron reducing bacteria isolated from irrigated tropical paddy soils 被引量:6
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作者 W.Reichardt 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2008年第12期1487-1493,共7页
Forty-six candidate phenol/benzoate degrading-iron reducing bacteria were isolated from long term irrigated tropical paddy soils by enrichment procedures.Pure cultures and some prepared mixed cultures were examined fo... Forty-six candidate phenol/benzoate degrading-iron reducing bacteria were isolated from long term irrigated tropical paddy soils by enrichment procedures.Pure cultures and some prepared mixed cultures were examined for ferric oxide reduction and phenol/benzoate degradation.All the isolates were iron reducers,but only 56.5%could couple iron reduction to phenol and/or benzoate degradation,as evidenced by depletion of phenol and benzoate after one week incubation.Analysis of degradative capability using Biolog... 展开更多
关键词 aromatic compounds DEGRADATION iron reducing bacteria paddy soil
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Evaluation of Pesticide Toxicity and Chemical Compounds Revealed in Soils of Sikasso and Segou (Mali)
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作者 Vital Traoré Abdrahaman Sidibé +5 位作者 Ahoua Sika Edmond Alou Coulibaly Kalifa Keïta Drissa Samake Daniel Traoré Sergey Kotelevtsev 《Journal of Agricultural Chemistry and Environment》 2016年第1期35-44,共10页
The contaminants of the ground are potentially harmful agents and when they are released in this medium, their persistence becomes an important concern. Because of the expressed interest, a certain number of pesticide... The contaminants of the ground are potentially harmful agents and when they are released in this medium, their persistence becomes an important concern. Because of the expressed interest, a certain number of pesticides and important chemicals and their toxicity are described in this article. The studies went on the determination of the concentration, the lethal amount of the organochlorinated compounds, chemical organophosphates, carbamates and compounds. One summer recorded 3 pesticides in 5 samples of the grounds of Sikasso and Segou (Mali). Their concentration varies from 20 (atrazine) with 45 g/kg of ground. The lethal amounts of the revealed poisons variable from 338 for phtalates to 28.710 mg/kg for hexane (alkane) thus evaluate their impact on the food chain. Organophosphates and the carbamates (insecticidal) involve a reduction of 34.2% of the number of Cyprinus carpio of fresh water. The atrazine contaminates drinking water, but the diuron modifies the behavior and the reproduction of fish by deteriorating their system of olfactive perception of natural substances. Important mortalities of birds are noted around the corn fields of Bougouni treated by the carbofuran. The pesticides involve at the man a reduction in fruitfulness, an increase in the risk of miscarriage of premature birth, congenital malformations and cancers. 展开更多
关键词 EVALUATION TOXICITY PESTICIDES Chemical compounds soils of Sikasso and Segou
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Variation in Solvent-Extractable Lipids and n-Alkane Compound-Specific Carbon Isotopic Compositions with Depth in a Southern China Karst Area Soil 被引量:2
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作者 崔景伟 黄俊华 +3 位作者 Philip A Meyers 黄咸雨 李婧婧 刘文贵 《Journal of Earth Science》 SCIE CAS CSCD 2010年第4期382-391,共10页
Because literatures about the lipid compositions of modern soils in karst areas are scarce, we have studied the soil horizons overlying the Heshang (和尚) Cave that has provided paleoclimate records from speleothem ... Because literatures about the lipid compositions of modern soils in karst areas are scarce, we have studied the soil horizons overlying the Heshang (和尚) Cave that has provided paleoclimate records from speleothem lipid contents. Our analysis reveals a series of n-alkanes, free fatty acids, n-alkanols and n-alkan-2-ones distribution and relative abundance changing with the depth, and in which the ratios of the lower molecular weight to higher molecular weight n-alkanes, free fatty acids, n-alkanols and n-alkan-2-ones have a peak at a subsurface depth of 5 to 10 cm. An accompanying peakin 17β(H), 21β(H)-hop-22(29)-ene (diploptene) and a shift to less negative n-alkane carbon isotopic values also identify this layer in the karst soil. This pattern indicates the existence of a subsurface soil layer in which the microorgan- isms that produce these compounds are espe- cially abundant. The carbon isotopic values of individual plant wax n-alkanes are about 3%0 greater at the base of the 30- to 40-cm soil profile than in the surface layer, probably as a result ofselective microbial degradation of n-alkanes from different primary sources. The lipids and carbon iso- topic values of individual plant wax n-alkanes study of the overlying soil show a strong microbial activity in this karst soil and help in interpreting the lipid compositions and specific carbon isotopic value of n-alkanes of the stalagmites of the Heshang Cave for paleoenvironmental reconstructions. 展开更多
关键词 lipid biomarker modern soil karst area compound-specific carbon isotopic value n -alkan-2-one.
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Effects of Magnesium Compound with Fertilizer on Daylily (Hemerocallis citrina Baroni) Growth and Soil Nutrients 被引量:2
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作者 SUN Nan ZENG Xi-bai +2 位作者 LI Ju-mei GAO Ju-sheng WANG Bo-ren 《Agricultural Sciences in China》 CAS CSCD 2006年第2期123-129,共7页
Effects of two kinds of magnesium compound with fertilizer on Daylily (Hemerocallis citrina Baroni) growth, yield, and soil nutrients in red soil were studied. The results indicated that significant effects of magne... Effects of two kinds of magnesium compound with fertilizer on Daylily (Hemerocallis citrina Baroni) growth, yield, and soil nutrients in red soil were studied. The results indicated that significant effects of magnesium applied to soils were observed in increasing Daylily (Hemerocallis citrina Baroni) yield, improving its growth, and strengthening its antivirus property as well as increasing the amount of exchangeable Mg, N, P, and K in red soil. In particular, the effects of magnesium compound fertilizer Ⅱ (MCF2) with higher Mg content were better than that of the others, which increased Daylily (Hemerocallis citrina Baroni) yield by 57.4, 32.8, and 14.5% compared to that of control treatment (CK), chemical fertilizer with nitrogen, phosphorus, potassium treatment (CF), and magnesium compound fertilizer Ⅰ treatment (MCF1) with lower Mg content. It increased soil Alkali N, available P, exchangeable K, and exchangeable Mg by 94.9, 46.5, 31.1, and 35.3%, respectively, compared with that of CK treatment. Therefore, the application of magnesium compound with fertilizer is an optimum method for improving red soil quality. 展开更多
关键词 magnesium compound fertilizer Daylily (Hemerocallis citrina Baroni) GROWTH soil nutrient
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Sorption of Organic Compounds in Soil Organic Matter
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作者 XING Bao-shan,LIU Xiao-bing, SONG Chun-yu ( Heilongjiang Institute of Agricultural Modernization,Academia Sinica,Harbin, Heilongjiang 150040,P R C) ( Department of Plant and Soil Seinces, University of Massachussetts, Amherst, USA) 《Journal of Northeast Agricultural University(English Edition)》 CAS 2001年第1期72-80,共9页
Soil organic matter(SOM)is the predominant component for sorption of hydrophobic organic compouds in soil and sorption by SOM ultimately affects chemical fate and availability in soil,and the degree of remedia- tion s... Soil organic matter(SOM)is the predominant component for sorption of hydrophobic organic compouds in soil and sorption by SOM ultimately affects chemical fate and availability in soil,and the degree of remedia- tion success of contaminated soils. This paper summarizes the latest development on sorption of organic com- pounds in soil (natural) organic matter,addresses four sorption mechanisms: surface adsorption,solid - phase Partitioning,dual-mode sorption,and fixed-pore sorption model,and presents future research directions as well. 展开更多
关键词 SORPTION soil organic matter Sorption mechanism Organic compounds
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Volatile organic compound emissions from straw-amended agricultural soils and their relations to bacterial communities:A laboratory study 被引量:1
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作者 Juan Zhao Zhe Wang +6 位作者 Ting Wu Xinming Wang Wanhong Dai Yujie Zhang Ran Wang Yonggan Zhang Chengfei Shi 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2016年第7期257-269,共13页
A laboratory study was conducted to investigate volatile organic compound(VOC) emissions from agricultural soil amended with wheat straw and their associations with bacterial communities for a period of 66 days unde... A laboratory study was conducted to investigate volatile organic compound(VOC) emissions from agricultural soil amended with wheat straw and their associations with bacterial communities for a period of 66 days under non-flooded and flooded conditions. The results indicated that ethene, propene, ethanol, i-propanol, 2-butanol, acetaldehyde, acetone,2-butanone, 2-pentanone and acetophenone were the 10 most abundant VOCs, making up over 90% of the total VOCs released under the two water conditions. The mean emission of total VOCs from the amended soils under the non-flooded condition(5924 ng C/(kg·hr)) was significantly higher than that under the flooded condition(2211 ng C/(kg·hr)). One "peak emission window" appeared at days 0–44 or 4–44, and over 95% of the VOC emissions occurred during the first month under the two water conditions. Bacterial community analysis using denaturing gradient gel electrophoresis(DGGE) showed that a relative increase of Actinobacteria, Bacteroidetes, Firmicutes and γ-Proteobacteria but a relative decrease of Acidobacteria with time were observed after straw amendments under the two water conditions. Cluster analysis revealed that the soil bacterial communities changed greatly with incubation time, which was in line with the variation of the VOC emissions over the experimental period. Most of the above top 10 VOCs correlated positively with the predominant bacterial species of Bacteroidetes, Firmicutes and Verrucomicrobia but correlated negatively with the dominant bacterial species of Actinobacteria under the two water conditions. These results suggested that bacterial communities might play an important role in VOC emissions from straw-amended agricultural soils. 展开更多
关键词 Volatile organic compounds(VOCs) Emission fluxes Microbial communities Correlations Straw amendment Agricultural soils
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基于GC-MS结合多元统计方法分析野生地黄伴生土壤中挥发性有机物特征
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作者 刘雪 程梦娟 +5 位作者 王丰青 龚海燕 刘庆普 雷敬卫 张娟 谢彩侠 《中华中医药学刊》 北大核心 2026年第2期201-206,I0036-I0039,共10页
目的对不同产区野生地黄伴生土壤中挥发性有机物(Volatile organic compounds,VOCs)进行分析,为探讨地黄药材不同产区之间差异的成因提供理论依据。方法以道地与非道地产区的35批野生地黄伴生土壤作为研究对象,利用气相色谱-质谱联用(Ga... 目的对不同产区野生地黄伴生土壤中挥发性有机物(Volatile organic compounds,VOCs)进行分析,为探讨地黄药材不同产区之间差异的成因提供理论依据。方法以道地与非道地产区的35批野生地黄伴生土壤作为研究对象,利用气相色谱-质谱联用(Gas chromatography-mass spectrometry,GC-MS)方法分析其二氯甲烷及乙酸乙酯部位中的VOCs,结合SIMCA 14.1、SPSS 24等统计软件对归一化后的数据进行多元统计分析,确定道地与非道地野生地黄伴生土壤VOCs的差异性。结果35批野生地黄伴生土壤中二氯甲烷部位的VOCs主要有酯类、醇类、烷烃类、酚类成分,其中烷烃类、酚类、酯类的相对含量在道地与非道地产区中差异存在统计学意义;乙酸乙酯部位的VOCs主要为酯类、烷烃类、醇类、酚类、酰胺类、烯烃类成分,其中酯类、烷烃类、醇类、酚类、酰胺类、烯烃类的相对含量在道地与非道地产区中差异存在统计学意义;多元统计学分析表明,野生地黄土壤样品均按照道地产区与非道地产区各自聚为一类,烷烃类、酸类、酯类为引起两者特征差异的主要成分。结论道地与非道地野生地黄土壤中所含的VOCs种类相似,但含量特征差异较大,烷烃类、酸类、酯类为主要差异性成分。 展开更多
关键词 野生地黄 伴生土壤 挥发性有机物 气质联用
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耐低温复合菌剂HT20作用下秸秆还田对土壤胞外酶活性及细菌群落结构的影响
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作者 孙建平 李皓 +2 位作者 赵子婧 刘雅辉 戴相林 《山东农业科学》 北大核心 2026年第1期93-103,共11页
为探明冀东稻区耐低温复合菌剂HT20作用下秸秆还田对土壤生物性状的影响,以无秸秆还田(CK)为对照,设置未施菌剂秸秆还田(J0)和配施HT20秸秆还田(JH)两个处理,利用高通量测序技术,荧光光度法和实时荧光定量PCR法,研究不同处理对土壤胞外... 为探明冀东稻区耐低温复合菌剂HT20作用下秸秆还田对土壤生物性状的影响,以无秸秆还田(CK)为对照,设置未施菌剂秸秆还田(J0)和配施HT20秸秆还田(JH)两个处理,利用高通量测序技术,荧光光度法和实时荧光定量PCR法,研究不同处理对土壤胞外酶、纤维素分解基因和细菌群落结构及功能的影响。结果表明,与JH处理相比,CK和J0处理在部分生育期内显著抑制了土壤胞外酶活性以及纤维素分解基因cbhI和GH48的丰度(P<0.05)。具体而言,α-葡萄糖苷酶活性在移栽期分别降低19.52%和26.12%,成熟期分别降低19.79%与9.02%;β-葡萄糖苷酶活性在分蘖期分别降低23.58%与18.74%;β-木糖苷酶活性在移栽期分别降低39.70%和2.96%,分蘖期分别降低59.89%和25.09%,成熟期分别降低20.53%和25.33%;cbhI基因丰度在移栽期分别降低83.33%和44.93%,孕穗期分别降低53.28%和15.86%,乳熟期分别降低66.03%和25.80%,成熟期分别降低72.53%和41.93%;GH48基因丰度在移栽期分别降低71.83%和69.51%,分蘖期分别降低65.36%和56.28%,乳熟期分别降低68.43%和42.71%。JH处理改变了土壤细菌群落结构及表型功能特征,主要组成为放线菌门、变形菌门、厚壁菌;LEfSe分析表明,土壤中差异指示物种JH处理有4个,J0处理有2个,CK有8个;BugBase表型功能预测显示,JH处理在革兰氏阳性、生物膜形成、减少致病性和厌氧方面表现突出。研究结果从分子角度解释了HT20在水田中加速秸秆腐解的原因,可为优化创制新型低温腐熟剂提供理论指导。 展开更多
关键词 耐低温复合菌剂HT20 秸秆还田 土壤胞外酶 纤维素分解基因 微生物功能
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Assessment of the Level of Metal(loid)s Pollution and Bioactive Compounds Screening of Anthill Soil
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作者 Graça K. Kandanda Festus S. Shafodino +1 位作者 Simeon I. Ambuga Lamech M. Mwapagha 《Open Journal of Soil Science》 2023年第11期474-489,共16页
The anthill soil is used by hypertensive elderly and teenagers from Oshikoto region (Namibia) and many of them testified stabilization of their blood pressure to normal after consuming the anthill soil-derived aqueous... The anthill soil is used by hypertensive elderly and teenagers from Oshikoto region (Namibia) and many of them testified stabilization of their blood pressure to normal after consuming the anthill soil-derived aqueous extracts. This study therefore investigated and/or assessed the physicochemical parameters, the contents of some metal(loid)s (and their associated potential health risks) and the qualitative composition of bioactive compounds of this anthill soil. The homogenous soil sample collected from various anthill soils in the Oshikoto region was used to obtain the measurements of physiochemical parameters. The elemental contents were determined (using an Inductively Coupled Plasma Optical Emission Spectrophotometer) after acid digestion in accordance with the EPA method 350B and their potential health risk assessments were performed. Methanol, aqueous methanol, and aqueous-based extracts were generated via maceration extraction process prior to the screening of bioactive compounds using standard diagnostic assays. The oxidation reduction potential (164.4 ± 16.6 mV) was the only physicochemical parameter whose value was within the World Health Organization limits for drinking water whereas, total dissolved solids (23 ± 5.5 mg/L), electrical conductivity (44 ± 10.1 uS/cm) and pH (5.35 ± 0.33) were out of specifications. Phenolic compounds, flavonoids, terpenoids, and cardiac glycosides were present in anthill soil (with respect to the extractants used) to which its antihypertensive properties can be attributed in addition to some of the studied mineral components. With respect to the pH, TDS and EC, and the contents of most metal(loid)s in relation to their health risk assessment values, the results suggest that aqueous extracts derived from this anthill soil can be deemed unsuitable for human consumption. 展开更多
关键词 Anthill soil Physicochemical Parameters Metal(loid)s Contamination ANTIHYPERTENSIVE Bioactive compounds
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土壤VOCs固相微萃取-色谱质谱筛查研究
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作者 王鹏 高烁 +2 位作者 冉卓 邹佳洁 魏明秋 《化工管理》 2026年第3期38-41,共4页
为了建立适用于复杂土壤基质中挥发性有机污染物的高效筛查方法,研究采用固相微萃取-气相色谱质谱联用技术,系统优化萃取纤维类型、温度、时间及搅拌方式,并在选择离子监测模式下实现多组分VOCs的快速分离与准确定量。结果表明,PDMS/DV... 为了建立适用于复杂土壤基质中挥发性有机污染物的高效筛查方法,研究采用固相微萃取-气相色谱质谱联用技术,系统优化萃取纤维类型、温度、时间及搅拌方式,并在选择离子监测模式下实现多组分VOCs的快速分离与准确定量。结果表明,PDMS/DVB涂层纤维在50℃、40 min萃取条件下表现出最佳响应,检测限低至0.09μg/kg,加标回收率在86.3%~104.7%之间,RSD小于6.8%。实际样品分析反映出典型VOCs的空间差异性及污染指向性,验证了该方法的适用性与稳定性。 展开更多
关键词 固相微萃取 气相色谱质谱 挥发性有机物 土壤污染
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Ralstonia生物炭菌剂对重金属污染菜地土壤细菌群落结构及氮磷钾碳含量的影响
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作者 黄家庆 叶菁 +1 位作者 罗施行 王义祥 《中国农业大学学报》 北大核心 2026年第1期146-162,共17页
为阐明西红柿秸秆生物炭及Ralstonia生物炭菌剂(Ralstonia-inoculated biochar)对蔬菜种植园土壤细菌群落多样性和养分含量的影响,以盆栽种植芥菜为研究对象,盆栽土为菜地土壤和重金属复合污染土壤,分别设置重金属污染、西红柿秸秆生物... 为阐明西红柿秸秆生物炭及Ralstonia生物炭菌剂(Ralstonia-inoculated biochar)对蔬菜种植园土壤细菌群落多样性和养分含量的影响,以盆栽种植芥菜为研究对象,盆栽土为菜地土壤和重金属复合污染土壤,分别设置重金属污染、西红柿秸秆生物炭和Ralstonia生物炭菌剂的共13种不同处理,每个处理3个重复,在芥菜收获期测定不同处理下土壤的细菌群落结构、差异菌群数量和氮磷钾碳含量等,探究西红柿秸秆生物炭和Ralstonia生物炭菌剂对菜地土壤优势细菌丰度、外源菌Ralstonia存活和土壤供肥能力的影响,以及改善重金属复合污染菜地土壤的能力。结果表明:西红柿秸秆经过高温碳化得到热解生物炭和水热生物炭在性质和官能团方面差异较大,均能与Ralstonia菌体固定化制备成Ralstonia生物炭菌剂;西红柿秸秆生物炭+Ralstonia有效提高菜地土壤的细菌丰富度,增加优势菌Proteobacteria(门水平,47.92%~72.44%)和Rhodanobacter(属水平,24.11%~51.18%)的相对丰度,并提高差异菌群数量(8~12个)和维持外源菌Ralstonia长期存活(0.32%~1.23%);与此同时,Ralstonia生物炭菌剂增加菜地土壤的碱解氮(7.53%~35.44%)、硝态氮(1.57%~22.24%)、有效磷(1.46%~50.04%)、速效钾(1.03%~6.57%)和有机炭(129.20%~239.45%),并减少铵态氮残留(19.69%~49.45%);与单施西红柿秸秆生物炭(热解生物炭和水热生物炭)或Ralstonia相比,Ralstonia生物炭菌剂高效改善菜地土壤及重金属复合污染土壤的细菌群落结构和氮磷钾碳含量,并能缓解西红柿秸秆生物炭或Ralstonia对菜地土壤细菌菌群生长的抑制。综上,Ralstonia西红柿秸秆生物炭菌剂兼具不同类型西红柿秸秆生物炭和外源菌Ralstonia的优点,能有效改善菜地土壤及重金属复合污染土壤的细菌丰富度、优势菌丰度、差异菌群数量和氮磷钾碳含量,对促进西红柿秸秆资源化利用和改良蔬菜种植园土壤肥力具有重要的应用潜力。 展开更多
关键词 罗尔斯通氏菌 外源菌固定化 西红柿秸秆生物炭 重金属复合污染 细菌群落结构 菜地土壤养分
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气相色谱-串联质谱法测定土壤中64种半挥发性有机物的含量
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作者 林顶 杨天福 《理化检验(化学分册)》 北大核心 2026年第1期69-78,共10页
取经冷冻干燥处理并过筛后的土壤样品10 g,加入10 g硅藻土,混匀,加入2-氟联苯、4,4″-三联苯-d_(14)的质量浓度为10 mg·L^(-1)的替代物混合标准溶液50μL,置于加压流体萃取仪中,以体积比1∶1的正己烷-丙酮混合溶液为萃取溶剂,在温... 取经冷冻干燥处理并过筛后的土壤样品10 g,加入10 g硅藻土,混匀,加入2-氟联苯、4,4″-三联苯-d_(14)的质量浓度为10 mg·L^(-1)的替代物混合标准溶液50μL,置于加压流体萃取仪中,以体积比1∶1的正己烷-丙酮混合溶液为萃取溶剂,在温度100℃、压力10.34 MPa下静态萃取8 min,循环萃取2次。萃取液于30℃氮吹浓缩至近干,用正己烷定容至1.0 mL。在活化好的硅酸镁小柱中加入0.5 g铜粉,再加入上述待净化液,保持5 min,用5 mL体积比2∶8的异丙醇-正己烷混合溶液洗涤浓缩装置,洗涤液一并转入硅酸镁小柱,依次用10 mL体积比1∶9的丙酮-正己烷混合溶液、8 mL体积比2∶8的异丙醇-正己烷混合溶液洗脱,收集洗脱液,于30℃氮吹浓缩至0.80 mL,加入萘-d_(8)、菲-d_(10)、䓛-d_(12)、苝-d_(12)和十氯联苯的质量浓度为10 mg·L^(-1)的混合同位素内标溶液50μL,用正己烷定容至1.0 mL,采用气相色谱-串联质谱法测定溶液中64种半挥发性有机物的含量。在色谱分析中,以HP-5MS色谱柱为固定相,在柱升温程序下分离;在质谱分析中,以电子轰击离子源电离,多反应监测模式检测,内标法定量。结果显示,64种目标物的质量浓度均在20~1000μg·L^(-1)内与其内标质量浓度的比值和对应的定量离子对响应值与内标定量离子对响应值的比值呈线性关系,检出限(3.143s)为0.19~2.89μg·kg^(-1)。按照标准加入法进行回收试验,回收率为63.4%~125%,测定值的相对标准偏差(n=6)为1.4%~14%。按照试验方法分析4份土壤样品,64种目标物均有检出,检出量为3.41~1606952μg·kg^(-1)。 展开更多
关键词 气相色谱-串联质谱法 土壤 半挥发性有机物 加压流体萃取
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赤壁市典型砖茶种植区土壤中氟的分布特征及污染来源研究
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作者 李泉 李杨 +7 位作者 刘莉 李治刚 王茜 陈仪 龙澳归 何贝 王丽 夏国平 《江西农业学报》 2026年第2期99-107,共9页
茶树是氟的超富集植物,茶树中氟的积累与外部氟浓度之间呈现线性相关性。茶叶中的氟主要来源于土壤,而土壤中氟的有效性是由水溶性氟形态含量决定的,极易被茶树吸收累积于茶叶中。土壤样品分析结果显示,成土母质是影响土壤全氟含量的决... 茶树是氟的超富集植物,茶树中氟的积累与外部氟浓度之间呈现线性相关性。茶叶中的氟主要来源于土壤,而土壤中氟的有效性是由水溶性氟形态含量决定的,极易被茶树吸收累积于茶叶中。土壤样品分析结果显示,成土母质是影响土壤全氟含量的决定性因素,茶园不同类型土壤表层含氟量分布规律表现为棕红壤>幼年红壤>黄红壤,该种植区表层土壤含氟量总体呈现由北到南逐渐降低的变化趋势。在土壤呈酸性条件下,pH值变化对土壤中水溶性氟含量影响较小。外源氟样品分析结果显示,土壤中氟主要来源于地层及长期大量施用的洋丰、西洋复合肥,大气沉降、茶园灌溉水及农药施用均非茶园表层土壤氟元素的物质来源,建议后期茶园增施有机肥、氮肥,减少复合肥的使用,有利于降低砖茶含氟量。 展开更多
关键词 土壤 砖茶 地层 复合肥
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Studies on Heavy Metal Pollution in Soil-Plant System:A Review 被引量:9
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作者 Wang Haiyan Sun XiangyangCollege of Soil and Water Conservation, Beijing Forestry University, Beijing 100083, P.R. China 《Forestry Studies in China》 CAS 2003年第1期55-62,共8页
Heavy metal pollution in soil-plant system is of major environmental concern on a world scale and in China in particular with the rapid development of industry. The heavy metal pollution status in soil-plant system in... Heavy metal pollution in soil-plant system is of major environmental concern on a world scale and in China in particular with the rapid development of industry. The heavy metal pollution status in soil-plant system in China, the research progress on the bioavailability of heavy metals (affecting factors, extraction methods, free-ion activity model, adsorption model, multivariate regression model, Q-I relationship, and compound pollution), and soil remediation are reviewed in the paper. Future research and monitoring is also discussed. 展开更多
关键词 heavy metal pollution soil-plant system BIOAVAILABILITY free-ion activity model adsorption model multivariate regression model compound pollution soil remediation
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基于毛竹林地土壤高效溶磷细菌组合的复合菌肥构建及其促生机制研究
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作者 李悦 贾婧怡 +2 位作者 朱迎 沈越 史文辉 《西南林业大学学报(自然科学)》 北大核心 2026年第1期39-48,共10页
通过盆栽试验及不同载体培养接种比较试验,在毛竹苗生长季末期(T_(1))和翌年快速生长期末期(T_(2))取样进行各项指标测定,验证高效溶磷细菌菌株组合在毛竹幼苗生长过程中的功能效应,进一步构建菌株组合特异性载体,观测分析其对毛竹苗生... 通过盆栽试验及不同载体培养接种比较试验,在毛竹苗生长季末期(T_(1))和翌年快速生长期末期(T_(2))取样进行各项指标测定,验证高效溶磷细菌菌株组合在毛竹幼苗生长过程中的功能效应,进一步构建菌株组合特异性载体,观测分析其对毛竹苗生长及土壤磷养分环境的影响。结果表明:细菌组合的冻干菌剂和液体菌剂对毛竹幼苗生长和养分积累起到显著促生作用,其中液体菌剂在T_(1)时期促生效果好,根生物量和根系全氮含量分别较CK显著增加103%和15.65%;冻干菌剂在T_(2)时期促生效果好,土壤全氮含量和有效磷含量分别较CK显著增加了16.11%和1105%,总生物量及全氮全磷含量较CK显著增加91.49%、76.32%和122.58%。花生壳与甘蔗渣1∶1等体积混合适宜作为细菌组合的载体。添加该载体构建的固态溶磷细菌组合菌肥1 a后,土壤有效磷显著增加了408%;且接种处理后,T_(1)时期毛竹苗根系、地上生物量较CK分别增加8.7%和41.9%,T_(2)时期毛竹苗根系、地上生物量较CK分别增加32.3%和746%。 展开更多
关键词 土壤 有效磷 溶磷微生物 微生物 复合菌肥 幼苗
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