The behavior of resistance high-g impact of EMC （epoxy molding compound） with two package models, small outline package （POS） and Globtop, was evaluated by experimental method used Hopkinson bar. At 120,000 g （ge...The behavior of resistance high-g impact of EMC （epoxy molding compound） with two package models, small outline package （POS） and Globtop, was evaluated by experimental method used Hopkinson bar. At 120,000 g （generated in the Hopkinson bar with widths about 70 μs） no damage in either the POS devices or the Globtop devices was observed. In order to enhance the EMC＇s ability of resistance high-g impact, buffering effect of epoxy resin was also studied. The experimental results above all show that EMC has a better performance of impact resistance at about 120,000 g, and epoxy resin can absorb the stress wave to have the protected ability. The study of this paper could serve as a basis for selection packaging materials and enhance its reliability in high-g impact environment.展开更多
Low pressure sheet molding compound （LPMC,1.0-3.0 MPa,95-103 ℃） is a new kind of thermosetting material with crystalline polyester as a physical thickenner.LPMC is different from conventional SMC using an earth oxi...Low pressure sheet molding compound （LPMC,1.0-3.0 MPa,95-103 ℃） is a new kind of thermosetting material with crystalline polyester as a physical thickenner.LPMC is different from conventional SMC using an earth oxide thickening agent （e.g.MgO） as chemical thickenner,it relies on the physical thickening of crystalline polyester.Crystalline polyester resin is the key material to mold LPMC parts.Currently there was no report about the thickening mechanism of crystalline polyester in LPMC.In this article,crystalline polyester resins,whose melting points were between 45 ℃ and 89 ℃,were synthesized by a two-step esterification.The melt points of crystalline polyesters are controlled by regulating the mol ratio of the two glycols and the two acids.And by means of varying the content of crystalline polyester resin,the thickening effect on resin paste is investigated.In addition,the thickening mechanism of crystalline polyester in LPMC was investigated by FTIR and DSC analysis.The effects of the diameters and viscosity of crystalline polyester on the rheological property and fiber distribution of LPMC sheets were studied,too.Results show that the thickening effect is excellent when the weight content of crystalline polyester resin is 3%.And there exists three kinds of functions acting in the process of thickening：swelling,hydrogen bonds and induction crystallization.During the preparing process of resin paste in LPMC,the temperature of resin paste must be kept at 90 ℃.In addition,crystalline polyester make LPMC have a perfect fluid property.When the viscosity of LPMC sheet is beyond 1 kPa s,the fiber orientation is not obvious.But when the viscosity of LPMC sheet is about 500 Pa s,the fiber shows a certain degree of orientation.Moreover the study of physical and chemical thickening mechanism of crystalline polyester and the rheological discipline of LPMC sheets in the hot mould will provide the researchers and enterprises with theory guidance.展开更多
Based on generalized Hele-Shaw (GHS) model, a numerical simulation of phenolic sheet molding compound (P-SMC) in compression molding is realized by finite element step-by-step computing method. Finite elemental comput...Based on generalized Hele-Shaw (GHS) model, a numerical simulation of phenolic sheet molding compound (P-SMC) in compression molding is realized by finite element step-by-step computing method. Finite elemental computing and post analysis programs have been written. The compression mold filling process, time and pressure requirements of P-SMC in a closed mold are predicted, and a good agreement is shown when compared with experiments. It will be of theoretical significance for the mold design and the optimization of the technological parameters in the compression molding of sheet molding compound.展开更多
Reference materials for quantitative determination of regulated heavy metals, such as Pb and Cd in electronic components, were designed and investigated in terms of stability and homogeneity. Reference materials with ...Reference materials for quantitative determination of regulated heavy metals, such as Pb and Cd in electronic components, were designed and investigated in terms of stability and homogeneity. Reference materials with two concentration levels of heavy metals were prepared by spiking Pb and Cd compounds to epoxy molding compounds made by mixing silica powders and epoxy resin. The concentration changes of the reference materials during stability test for 1 a were not observed. In the homogeneity assessment, the as-prepared reference materials were studied by using three different analytical tools, inductively coupled plasma atomic emission spectrometry (ICP-AES), X-ray fluoroescence spectrometry (XRF) and laser ablation ICP mass. The results show different homogeneities by the characteristics of analytical tools and the materials.展开更多
We present comparative life-cycle assessments of three fiber-reinforced sheet molding compounds （SMCs） using kenaf fiber, glass fiber and soy protein resin. Sheet molding compounds for automotive applications are ty...We present comparative life-cycle assessments of three fiber-reinforced sheet molding compounds （SMCs） using kenaf fiber, glass fiber and soy protein resin. Sheet molding compounds for automotive applications are typically made of unsaturated polyester and glass fibers. Replacing these with kenaf fiber or soy protein offers potential environmental benefits. A soy-based resin, maleated acrylated epoxidized soy oil （MAESO）, was synthesized from refined soybean oil. Kenaf fiber and polyester resins were used to make SMC 1 composites, while SMC2 composites were made from kenaf fiber and a resin blend of 20% MASEO and 80% unsaturated polyester. Both exhibited good physical and mechanical properties, though neither was as strong as glass fiber reinforced polyester SMC. The functional unit was defined as mass to achieve equal stiffness and stability for the manufacture of interior parts for automobiles. The life-cycle assessments were done on SMCI, SMC2 and glass fiber reinforced SMC. The material and energy balances from producing one functional unit of three composites were collected from lab experiments and the literature. Key environmental measures were computed using SimaPro software. Kenaf fiber-reinforced SMC composites （SMC1 and SMC2） performed better than glass fiber-reinforced SMC in every environmental category. The global warming potentials of kenaf fiber-reinforced SMC （SMCI） and kenaf soy resin-based SMC （SMC2） were 45% and 58%, respectively, of glass fiber-reinforced SMC. Thus, we have demonstrated significant ecological benefit from replacing glass fiber reinforced SMC with soy-based resin and natural fiber.展开更多
Si C器件的高功率密度与封装微型化趋势,使得环氧塑封料(EMC)的热-机械性能成为决定器件性能与可靠性的关键因素。在先进的扇出型板级封装(FOPLP)中,这一挑战尤为突出,因为EMC不仅承担绝缘任务,更是结构机械支撑与阻碍散热的主体。为探...Si C器件的高功率密度与封装微型化趋势,使得环氧塑封料(EMC)的热-机械性能成为决定器件性能与可靠性的关键因素。在先进的扇出型板级封装(FOPLP)中,这一挑战尤为突出,因为EMC不仅承担绝缘任务,更是结构机械支撑与阻碍散热的主体。为探究不同EMC对FOPLP热-机械性能的具体影响规律,以2种不同填料体系的商用EMC为研究对象,系统表征了其关键热-机械物性,随后通过热阻与热翘曲实验,揭示了材料差异对封装性能变化的影响。同时,建立了FOPLP结构的热-机械耦合有限元(FEA)仿真模型,进行仿真验证,分析了不同EMC对封装性能的最终影响,并验证了所构建的FEA仿真模型的准确性。研究结果表明Al2O3填充EMC在热阻与热翘曲方面优于SiO2填充EMC,所构建的FEA模型能高精度地预测封装的热机械行为,证实了此实验-仿真综合评估方法的有效性。展开更多
基金Funded by the State Key Laboratory Foundation of China (No.9140C120704060C12)the Science and Technology Development Project of Universiti-esin of Shanxi Province
文摘The behavior of resistance high-g impact of EMC （epoxy molding compound） with two package models, small outline package （POS） and Globtop, was evaluated by experimental method used Hopkinson bar. At 120,000 g （generated in the Hopkinson bar with widths about 70 μs） no damage in either the POS devices or the Globtop devices was observed. In order to enhance the EMC＇s ability of resistance high-g impact, buffering effect of epoxy resin was also studied. The experimental results above all show that EMC has a better performance of impact resistance at about 120,000 g, and epoxy resin can absorb the stress wave to have the protected ability. The study of this paper could serve as a basis for selection packaging materials and enhance its reliability in high-g impact environment.
基金supported by National Natural Science Foundation of China (Grant No. 50473013)National Hi-tech Research and Development Program of China (863 Program,Grant No. 2003AA333070)+1 种基金Hubei Provincial Natural Science Foundation of China (Grant No.2009CDA037)Researching Foundation of Hubei Automotive Industries Institute of China (Grant No. BK201001)
文摘Low pressure sheet molding compound （LPMC,1.0-3.0 MPa,95-103 ℃） is a new kind of thermosetting material with crystalline polyester as a physical thickenner.LPMC is different from conventional SMC using an earth oxide thickening agent （e.g.MgO） as chemical thickenner,it relies on the physical thickening of crystalline polyester.Crystalline polyester resin is the key material to mold LPMC parts.Currently there was no report about the thickening mechanism of crystalline polyester in LPMC.In this article,crystalline polyester resins,whose melting points were between 45 ℃ and 89 ℃,were synthesized by a two-step esterification.The melt points of crystalline polyesters are controlled by regulating the mol ratio of the two glycols and the two acids.And by means of varying the content of crystalline polyester resin,the thickening effect on resin paste is investigated.In addition,the thickening mechanism of crystalline polyester in LPMC was investigated by FTIR and DSC analysis.The effects of the diameters and viscosity of crystalline polyester on the rheological property and fiber distribution of LPMC sheets were studied,too.Results show that the thickening effect is excellent when the weight content of crystalline polyester resin is 3%.And there exists three kinds of functions acting in the process of thickening：swelling,hydrogen bonds and induction crystallization.During the preparing process of resin paste in LPMC,the temperature of resin paste must be kept at 90 ℃.In addition,crystalline polyester make LPMC have a perfect fluid property.When the viscosity of LPMC sheet is beyond 1 kPa s,the fiber orientation is not obvious.But when the viscosity of LPMC sheet is about 500 Pa s,the fiber shows a certain degree of orientation.Moreover the study of physical and chemical thickening mechanism of crystalline polyester and the rheological discipline of LPMC sheets in the hot mould will provide the researchers and enterprises with theory guidance.
文摘Based on generalized Hele-Shaw (GHS) model, a numerical simulation of phenolic sheet molding compound (P-SMC) in compression molding is realized by finite element step-by-step computing method. Finite elemental computing and post analysis programs have been written. The compression mold filling process, time and pressure requirements of P-SMC in a closed mold are predicted, and a good agreement is shown when compared with experiments. It will be of theoretical significance for the mold design and the optimization of the technological parameters in the compression molding of sheet molding compound.
基金Project(2010-0008-276) supported by NCRC (National Core Research Center) program through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology
文摘Reference materials for quantitative determination of regulated heavy metals, such as Pb and Cd in electronic components, were designed and investigated in terms of stability and homogeneity. Reference materials with two concentration levels of heavy metals were prepared by spiking Pb and Cd compounds to epoxy molding compounds made by mixing silica powders and epoxy resin. The concentration changes of the reference materials during stability test for 1 a were not observed. In the homogeneity assessment, the as-prepared reference materials were studied by using three different analytical tools, inductively coupled plasma atomic emission spectrometry (ICP-AES), X-ray fluoroescence spectrometry (XRF) and laser ablation ICP mass. The results show different homogeneities by the characteristics of analytical tools and the materials.
文摘We present comparative life-cycle assessments of three fiber-reinforced sheet molding compounds （SMCs） using kenaf fiber, glass fiber and soy protein resin. Sheet molding compounds for automotive applications are typically made of unsaturated polyester and glass fibers. Replacing these with kenaf fiber or soy protein offers potential environmental benefits. A soy-based resin, maleated acrylated epoxidized soy oil （MAESO）, was synthesized from refined soybean oil. Kenaf fiber and polyester resins were used to make SMC 1 composites, while SMC2 composites were made from kenaf fiber and a resin blend of 20% MASEO and 80% unsaturated polyester. Both exhibited good physical and mechanical properties, though neither was as strong as glass fiber reinforced polyester SMC. The functional unit was defined as mass to achieve equal stiffness and stability for the manufacture of interior parts for automobiles. The life-cycle assessments were done on SMCI, SMC2 and glass fiber reinforced SMC. The material and energy balances from producing one functional unit of three composites were collected from lab experiments and the literature. Key environmental measures were computed using SimaPro software. Kenaf fiber-reinforced SMC composites （SMC1 and SMC2） performed better than glass fiber-reinforced SMC in every environmental category. The global warming potentials of kenaf fiber-reinforced SMC （SMCI） and kenaf soy resin-based SMC （SMC2） were 45% and 58%, respectively, of glass fiber-reinforced SMC. Thus, we have demonstrated significant ecological benefit from replacing glass fiber reinforced SMC with soy-based resin and natural fiber.
