The magnetic properties, structure defects of electrodeposited Fe-Ni-P alloys with various compositions and the thermostability at amorphous state have been studied by DSC, positron annihilation and electronic integra...The magnetic properties, structure defects of electrodeposited Fe-Ni-P alloys with various compositions and the thermostability at amorphous state have been studied by DSC, positron annihilation and electronic integrating instrument methods. The results show that the thermostability of amorphous Fe-Ni-P alloys increases with Fe content. Emergence and recrystallization of stable phases defer as the P content of the coating increases. The minimum H-c, B-r and P-h occur at 9.4 P (wt pet) content. Maximum H-c, B-r and P-h occur at the weight ratio of Fe to Ni equaling to 1/9.展开更多
Objective The distribution characteristics and formation mechanism of rearranged hopanes in hydrocarbon source rocks are affected by various geological conditions.Among these geological conditions,thermal action has a...Objective The distribution characteristics and formation mechanism of rearranged hopanes in hydrocarbon source rocks are affected by various geological conditions.Among these geological conditions,thermal action has an important influence on the formation of rearranged hopanes,which has been however little documented previously.展开更多
Residual electrical resistivity due to short-range order has been calculated for Cu100-xAlx (x=9.13,13.56, 14.5 and 14.76 in at pct) alloys using pseudopotential approach, and the results have been discussed in the li...Residual electrical resistivity due to short-range order has been calculated for Cu100-xAlx (x=9.13,13.56, 14.5 and 14.76 in at pct) alloys using pseudopotential approach, and the results have been discussed in the light of experimental studies of the local-order structure of these alloys. In case of Cu85.5Al14.5, change in the total residual electrical resistivity due to neutron-irradiation effects has been estimated by including contributions from the short-range order and static atomic displacement correction. Our results show a decrease in the residual resistivity in the irradiated Cu-Al solid solution as compared to the unirradiated sample. This is in accordance with the experimental results展开更多
The effect of seed oil of Korean pine (Pinus koraiensis) on the rats' blood-fat and its anti-ageing function was stud-ied for appraising the efficacy of the seed oil of Korean pine. Sixty experimental rats were ra...The effect of seed oil of Korean pine (Pinus koraiensis) on the rats' blood-fat and its anti-ageing function was stud-ied for appraising the efficacy of the seed oil of Korean pine. Sixty experimental rats were randomly divided into 5 groups (half males and half females in each group) as normal control group, high fat diet control group, and three groups (Group 1 Group 2, Group 3) that were fed with feedstuff with the contents of the seed oil of 2.0g/(kgd-1), 4.0g/(kgd-1) and 8.0g/(kgd-1), respec-tively. The indexes such as superoxide dismutase (SOD), glutathione peroxidase (GSH-PX) and anti-oxidation capacity (AOC) were measured by Reagent Kit method. It was found that the seed oil of the Korean pine could reduce the content of triglyc-eride and improve SOD as well as GSH-PX activity in serum. These indexes of the rats in Group 2 fed with Korean pine seed oil of 4.0 g/(kgd-1) reached the significant level and those of rats in Group 3 fed with the seed oil of 8.0 g/(kgd-1) reached the extremely significant level. The results indicated the seed oil of Korean pine had function of regulating the level of blood-fat and anti-ageing.展开更多
In the present paper the effects of additions of Zr and Y on the microstructure and mechanical properties for Ti-(6.0 approximately 6.5)Al-(2.0 approximately 3.0)Sn-(1.5 approximately 6.0)Zr-(0.8 approximately 1.0)Mo-...In the present paper the effects of additions of Zr and Y on the microstructure and mechanical properties for Ti-(6.0 approximately 6.5)Al-(2.0 approximately 3.0)Sn-(1.5 approximately 6.0)Zr-(0.8 approximately 1.0)Mo-1.0Nb-0.25Si alloys are reported. The experimental results shows that: with increasing of Zr content, tensile strength and creep resistance of the alloys increase, and reduction in area and thermal stability of the alloys decrease. Decrease in thermal stability of the alloys mainly caused by surface thermal unstability. After heat treatment Y addition can make grain size of the alloys refine. The reduction in area and thermal stability of the alloys with Y addition are improved, and tensile strength slightly decreases and creep resistance is essentially the same as the alloy without Y addition. These phenomena are explained in brief.展开更多
Understanding composition effects is crucial for alloy design and development. To date, there is a lack of research comprehensively addressing the effect of alloy composition on dynamic precipitation, segregation and ...Understanding composition effects is crucial for alloy design and development. To date, there is a lack of research comprehensively addressing the effect of alloy composition on dynamic precipitation, segregation and grain refinement under severe-plastic-deformation processing. This research investigates Al-x Si alloys with x = 0.1, 0.5 and 1.0 at.% Si processed by high pressure torsion(HPT) at room temperature by using transmission electron microscopy, transmission Kikuchi diffraction and atom probe tomography. The alloys exhibit interesting composition-dependent grain refinement and fast dynamic decomposition under HPT processing. Si atoms segregate at dislocations and Si precipitates form at grain boundaries(GBs) depending on the Si content of the alloys. The growth of Si precipitates consumes most Si atoms segregating at GBs, hence the size and distribution of the Si precipitates become predominant factors in controlling the grain size of the decomposed Al-Si alloys after HPT processing. The hardness of the Al-Si alloys is well correlated with a combination of grain-refinement strengthening and the decomposition-induced softening.展开更多
Experimental obseryations show that quasi-isotropic materials, such as N-axial fibre-reinforced composites and woven materials . exhibit various degrees of anisotrpy in elasticity and strength, and the anisotropy i...Experimental obseryations show that quasi-isotropic materials, such as N-axial fibre-reinforced composites and woven materials . exhibit various degrees of anisotrpy in elasticity and strength, and the anisotropy in strengty is normally stronger than that in elasticity.In view of some available experimental data and based on the general formulation of the constitutive equations and .failure criteria of quasi-isotropic materials established by using the theory of repesentations for tensor functions, we postulate several applicable models of the constitutive equations and strength for 3and 4-axial quasi-isotropic materials to reveal the anisotropic effects In a continued work (Part II) the anisotropic effect in strength of an infintely large plate with a single elliptical hole or crack is studied. and the proposed stiffness and strength modelsare verified in terms of micro-mechanical analyses.展开更多
1 Introduction Shallow water delta in the middle-newborn Stratum Widely developed with huge oil and gas in China(Hu Shengwu et al.,2013).The control factors on the deltadevelopment like Climate,sea level,tectonic subs...1 Introduction Shallow water delta in the middle-newborn Stratum Widely developed with huge oil and gas in China(Hu Shengwu et al.,2013).The control factors on the deltadevelopment like Climate,sea level,tectonic subsidence,sediment supply(flow,type),the geometric characteristics of the upstream river,the energy(wave,展开更多
The existence of the sea surface is bound to affect the electromagnetic （EM） scattering from marine targets. When dealing with the composite scattering from targets over a sea surface by applying high-frequency EM t...The existence of the sea surface is bound to affect the electromagnetic （EM） scattering from marine targets. When dealing with the composite scattering from targets over a sea surface by applying high-frequency EM theories, the total scattering field can be decomposed into three parts in low sea states, namely, the direct scattering from the sea surface, the direct scattering from targets and the coupling scattering between the sea surface and targets. With regard to high sea states, breaking waves make the direct scattering from the sea surface and the coupling scattering more complicated. To solve this issue, a scattering model is proposed to analyze the composite scattering from a ship over a rough sea surface under high sea states. To consider the effect of breaking waves, a three dimensional geometric model is adopted together with Ufimtsev＇s theory of edge waves for the scattering from a breaker. In addition, the coupling scattering between targets and breaking waves is taken into account by considering all possible scattering paths. The simulated results indicate that the influence of breaking waves on the scattering field from the sea surface and on the coupling field is non-negligible, and the numerical results also show the effectiveness of the proposed scattering model.展开更多
The effects of positron diffusion on the measured S parameter have been investigated by a point-source diffusion model and a δ function method. Firstly, the theoretical analyses of the effects are presented for the s...The effects of positron diffusion on the measured S parameter have been investigated by a point-source diffusion model and a δ function method. Firstly, the theoretical analyses of the effects are presented for the samples of a homogeneous semi-infinite medium and a film of definite thickness. Then the results are used to analyze the S parameters in several composite systems and interface models.展开更多
The lattice constants of Sm-Co permanent magnet alloy have been determined by means of X-ray diffraction measurement. The lattice constants of R-Co alloy systems (R = rare earth) have been investigated with Bragg-will...The lattice constants of Sm-Co permanent magnet alloy have been determined by means of X-ray diffraction measurement. The lattice constants of R-Co alloy systems (R = rare earth) have been investigated with Bragg-williams (B-W) approximation and their expressions are given. It is pointed out that the lattice constants of RCo5 phase depend only on the alloy composition, and that the lattice constants of R2Co17 phase are related to the order parameter as well as the alloy composition. In this paper the relationship between the lattice constants of RCo5 and those of R2Co17 is discussed, and the values calculated by the expressions are compared with experimentally determined for Sm-Co alloys.展开更多
In the current work,a parallel comparison of the influence of Al,Mo and Ti,on the microstructure and strengthening of the CoCrFeNi alloy was conducted.To achieve this,inconsistencies on variables including the extent ...In the current work,a parallel comparison of the influence of Al,Mo and Ti,on the microstructure and strengthening of the CoCrFeNi alloy was conducted.To achieve this,inconsistencies on variables including the extent of alloying,thermomechanical processing and property-evaluation method were avoided.Microstructurally,following cold-rolling,annealing of the 4 at.%Al-doped alloys at 800-1000℃ did not result in phase separation;nevertheless,that of the 4 at.%Mo-and Ti-doped alloys led to the respective formation ofσandηphase and,consequently,caused extra strengthening through the Orowan dislocation bypassing mechanism.Our systematic qualitative analysis and DFT calculations showed that Al and Ti are more effective than Mo in reducing the stacking fault energy(SFE)of the CoCrFeNi alloy,because they can induce more considerable deformation of electronic density,making the gliding of atomic layers easier.Following identical thermomechnical processing,Al-,Mo-,and Ti-doping causes different extent of solid solution strengthening and grain boundary strengthening.Mo causes the most pronounced solid solution strengthening but does not benefit the grain boundary strengthening;in contrast,the effectiveness of grain boundary strengthening is boosted by the doping Al and Ti.Current analyses support that Labusch instead of Fleischer mechanism is applicable to explain the differences in solid solution strengthening,and the observed differences in grain boundary strengthening arise from the different tendency of Al,Mo and Ti to reduce the SFE of CoCrFeNi.In addition,we determined the value of the dimensionless parameter f in the Labusch model for CoCrFeNi-based alloys and observed a close relation between Hall-Petch slope and SFE.Although more in-depth studies are needed to provide full and mechanistic understandings,both these findings in fact presents significant values toward designing novel singlephase high-strength CoCrFeNi-based alloys through manipulating the solid solution and grain boundary strengthening by compositional tuning.展开更多
In this work, a flame-retardant polypropylene（PP）/ramie fiber（RF） composite was prepared. The ramie fibers were wrapped chemically by a phosphorus- and nitrogen-containing flame retardant（FR） produced via in sit...In this work, a flame-retardant polypropylene（PP）/ramie fiber（RF） composite was prepared. The ramie fibers were wrapped chemically by a phosphorus- and nitrogen-containing flame retardant（FR） produced via in situ condensation reaction so as to suppress their candlewick effect. Fourier transform infrared spectroscopy（FTIR）, X-ray photoelectron spectroscopy（XPS） and scanning electron microscopy（SEM） demonstrated that the ramie fibers wrapped chemically by FR（FR-RF） were obtained successfully. Thermogravimatric test showed that the PP/FR-RF composite had more residue and better thermal stability at high temperatures than the PP/RF composite. Cone calorimeter（CC） results indicated that the peak of heat release rate（PHRR） and total heat release（THR） correspondingly decreased by 23.4% and 12.5% compared with the values of neat PP/RF. The PP/FR-RF composite created a continuous and compact char layer after the combustion. Combining FTIR analysis of char residue after CC test with heat conduction coefficient results, it could be concluded that the charring of FR on RF greatly weakened the candlewick effect of RF, and more char residue in the RF domain facilitated the formation of more continuous and compact char layer in the whole combustion zone, consequently protected PP composites during combustion, resulting in the better flame retardancy of PP/FR-RF composite than that of PP/RF composite.展开更多
The panel-type structures used in aerospace engineering can be subjected to severe highfrequency acoustic loadings in service. This paper evaluates the frequency-dependent random fatigue of panel-type structures made ...The panel-type structures used in aerospace engineering can be subjected to severe highfrequency acoustic loadings in service. This paper evaluates the frequency-dependent random fatigue of panel-type structures made of ceramic matrix composites（CMCs） under acoustic loadings. Firstly, the high-frequency random responses from the broadband random excitation will result in more stress cycles in a deinite period of time. The probability density distributions of stress amplitudes will be different in different frequency bandwidths, though the peak stress estimations are identical. Secondly, the fatigue properties of CMCs can be highly frequency-dependent. The fatigue evaluation method for the random vibration case is adopted to evaluate the fatigue damage of a representative stiffened panel structure. The frequency effect through S-N curves on random fatigue damage is numerically veriied. Finally, a parameter is demonstrated to characterize the mean vibration frequency of a random process, and hence this parameter can further be considered as a reasonable loading frequency in the fatigue tests of CMCs to obtain more reliable S-N curves.Therefore, the inluence of vibration frequency can be incorporated in the random fatigue model from the two perspectives.展开更多
The impact of the size effect on the color and photoluminescence(PL)of quantum dots(QDs)has sparked a revolutionary field of research,culminating in the prestigious Nobel Prize in 2023.Prior to their widespread popula...The impact of the size effect on the color and photoluminescence(PL)of quantum dots(QDs)has sparked a revolutionary field of research,culminating in the prestigious Nobel Prize in 2023.Prior to their widespread popularization and large-scale commercialization,it is of paramount importance to effectively manipulate and optimize their optical properties.In this review,we place specific emphasis on the striking correlation between the optical characteristics of QDs and their size,structure,composition,and interface environment.We commence by tracing the evolution of quantum dot technology and subsequently categorizing QDs while outlining their typical synthesis methods.This is followed by a deep dive into the pivotal roles of size,composition,structure,and interfacial ligands in fine-tuning,optimizing,and enhancing the optical properties of QDs.Additionally,we illustrate the luminescence enhancement and charge transfer phenomena stemming from the heterojunction between semiconductor QDs and metal nanomaterials,which contribute to improved performance.Lastly,we introduce the burgeoning field of chiral QDs and their innovative applications.Armed with this knowledge,QDs can be readily tailored to exhibit adjustable luminous characteristics across the entire spectrum,boasting high luminous efficiency through multifaceted regulation.These advancements render QDs even more enticing and promising for a wide array of applications.展开更多
The nanometer MnO2 has outstanding electrochemical performance theoretically, but it is not suitable for actual utilization, which may result in capacity decrease and resource waste. In this study we have utilized the...The nanometer MnO2 has outstanding electrochemical performance theoretically, but it is not suitable for actual utilization, which may result in capacity decrease and resource waste. In this study we have utilized the characterizations of the nanometer material, synthesized a type of nanometer α-MnO2 through KMnO4 and KNO3 with hydrothermal method, and mixed the products into micron electrolytic manganese dioxide （EMD） to enhance the electrochemical performance of the electrode.The cyclic voltammogram and galvanostatical discharge measurements of the samples were investigated. It is found that the 50﹪ nanometer MnO2 mixed electrode has the best electrochemical performance. The electrochemical performance improvement mechanism of the sample nanometer MnO2 mixed into micron EMD was discussed. With the existence of electrolyte, the nanometer MnO2 particles filled into the interspaces of the micron EMD particles, the mass and charge transfer conditions of the electrode reaction were improved, and the electrode polarization was diminished.展开更多
The strengthening effect of a Zn alloy reinforced by SiC particulate was examined. Based on the results of SEM in-situ fracture observation and stress field analysis by finite element method, it is believed that the r...The strengthening effect of a Zn alloy reinforced by SiC particulate was examined. Based on the results of SEM in-situ fracture observation and stress field analysis by finite element method, it is believed that the reinforcing effect of this composite is due to the combination of strain and stress hardening in the matrix.展开更多
The longitudinal wave propagating in one-dimensional periodic piezoelectric composite rod with inter-coupling between different piezoelectric segments is investigated. The analytical formulae for such a structure are ...The longitudinal wave propagating in one-dimensional periodic piezoelectric composite rod with inter-coupling between different piezoelectric segments is investigated. The analytical formulae for such a structure are shown and the dispersion relation is calculated. The results show that, by introducing the inter-coupling between the different piezoelectric segments, which is accomplished by serially connecting every n piezoelectric segment into supercells, some tunable Bragg band gaps can accordingly be opened in the low frequency region. The investigation could provide a new guideline for the tunable phononic crystal under passive control.展开更多
Objective To investigate the effect of the implant composite of poly lactide-co-glycolide(PLGA)and bone mesenchymal stem cells (BMSCs) modified by basic fibroblast growth factor (bFGF) on injured spinal cord in rats.M...Objective To investigate the effect of the implant composite of poly lactide-co-glycolide(PLGA)and bone mesenchymal stem cells (BMSCs) modified by basic fibroblast growth factor (bFGF) on injured spinal cord in rats.Methods Two hundred and展开更多
III-V Semiconductors containing a small amount of Bi, known as dilute bismides, have attracted great interest in recent years, due to the large band-gap reduction and other unique properties [1,2]. Previous studies ha...III-V Semiconductors containing a small amount of Bi, known as dilute bismides, have attracted great interest in recent years, due to the large band-gap reduction and other unique properties [1,2]. Previous studies have been pri- marily focused on the growth and optical properties of the GaAs-based bismuthides [3], while the properties of other dilute bismides are less well understood. Berding et al. [4] theoretically predicted that InPBi is expected to be an attractive candidate for narrow-gap applications. Experimentally, the InPBi alloy with good single crystal quality has been successfully synthesized recently and exhibits strong and broad photoluminescence at room temperature [5,6]. However, the electric transport characteristics of the InPBi alloy are poorly understood. In this work, we systematically investigate the effect of Bi incorporation on electric transport properties of the InP1-xBix alloys.展开更多
文摘The magnetic properties, structure defects of electrodeposited Fe-Ni-P alloys with various compositions and the thermostability at amorphous state have been studied by DSC, positron annihilation and electronic integrating instrument methods. The results show that the thermostability of amorphous Fe-Ni-P alloys increases with Fe content. Emergence and recrystallization of stable phases defer as the P content of the coating increases. The minimum H-c, B-r and P-h occur at 9.4 P (wt pet) content. Maximum H-c, B-r and P-h occur at the weight ratio of Fe to Ni equaling to 1/9.
基金supported by the National Natural Science Foundation of China (grant No.41272170)the National Oil and Gas Major Project (grant No.2016ZX05007-001)
文摘Objective The distribution characteristics and formation mechanism of rearranged hopanes in hydrocarbon source rocks are affected by various geological conditions.Among these geological conditions,thermal action has an important influence on the formation of rearranged hopanes,which has been however little documented previously.
文摘Residual electrical resistivity due to short-range order has been calculated for Cu100-xAlx (x=9.13,13.56, 14.5 and 14.76 in at pct) alloys using pseudopotential approach, and the results have been discussed in the light of experimental studies of the local-order structure of these alloys. In case of Cu85.5Al14.5, change in the total residual electrical resistivity due to neutron-irradiation effects has been estimated by including contributions from the short-range order and static atomic displacement correction. Our results show a decrease in the residual resistivity in the irradiated Cu-Al solid solution as compared to the unirradiated sample. This is in accordance with the experimental results
文摘The effect of seed oil of Korean pine (Pinus koraiensis) on the rats' blood-fat and its anti-ageing function was stud-ied for appraising the efficacy of the seed oil of Korean pine. Sixty experimental rats were randomly divided into 5 groups (half males and half females in each group) as normal control group, high fat diet control group, and three groups (Group 1 Group 2, Group 3) that were fed with feedstuff with the contents of the seed oil of 2.0g/(kgd-1), 4.0g/(kgd-1) and 8.0g/(kgd-1), respec-tively. The indexes such as superoxide dismutase (SOD), glutathione peroxidase (GSH-PX) and anti-oxidation capacity (AOC) were measured by Reagent Kit method. It was found that the seed oil of the Korean pine could reduce the content of triglyc-eride and improve SOD as well as GSH-PX activity in serum. These indexes of the rats in Group 2 fed with Korean pine seed oil of 4.0 g/(kgd-1) reached the significant level and those of rats in Group 3 fed with the seed oil of 8.0 g/(kgd-1) reached the extremely significant level. The results indicated the seed oil of Korean pine had function of regulating the level of blood-fat and anti-ageing.
文摘In the present paper the effects of additions of Zr and Y on the microstructure and mechanical properties for Ti-(6.0 approximately 6.5)Al-(2.0 approximately 3.0)Sn-(1.5 approximately 6.0)Zr-(0.8 approximately 1.0)Mo-1.0Nb-0.25Si alloys are reported. The experimental results shows that: with increasing of Zr content, tensile strength and creep resistance of the alloys increase, and reduction in area and thermal stability of the alloys decrease. Decrease in thermal stability of the alloys mainly caused by surface thermal unstability. After heat treatment Y addition can make grain size of the alloys refine. The reduction in area and thermal stability of the alloys with Y addition are improved, and tensile strength slightly decreases and creep resistance is essentially the same as the alloy without Y addition. These phenomena are explained in brief.
基金funded by the financial support of the National Natural Science Foundation of China (No.51751120 and No.51604156)support and the assistance of Material Characterization and Research Center of Nanjing University of Science and Technology。
文摘Understanding composition effects is crucial for alloy design and development. To date, there is a lack of research comprehensively addressing the effect of alloy composition on dynamic precipitation, segregation and grain refinement under severe-plastic-deformation processing. This research investigates Al-x Si alloys with x = 0.1, 0.5 and 1.0 at.% Si processed by high pressure torsion(HPT) at room temperature by using transmission electron microscopy, transmission Kikuchi diffraction and atom probe tomography. The alloys exhibit interesting composition-dependent grain refinement and fast dynamic decomposition under HPT processing. Si atoms segregate at dislocations and Si precipitates form at grain boundaries(GBs) depending on the Si content of the alloys. The growth of Si precipitates consumes most Si atoms segregating at GBs, hence the size and distribution of the Si precipitates become predominant factors in controlling the grain size of the decomposed Al-Si alloys after HPT processing. The hardness of the Al-Si alloys is well correlated with a combination of grain-refinement strengthening and the decomposition-induced softening.
文摘Experimental obseryations show that quasi-isotropic materials, such as N-axial fibre-reinforced composites and woven materials . exhibit various degrees of anisotrpy in elasticity and strength, and the anisotropy in strengty is normally stronger than that in elasticity.In view of some available experimental data and based on the general formulation of the constitutive equations and .failure criteria of quasi-isotropic materials established by using the theory of repesentations for tensor functions, we postulate several applicable models of the constitutive equations and strength for 3and 4-axial quasi-isotropic materials to reveal the anisotropic effects In a continued work (Part II) the anisotropic effect in strength of an infintely large plate with a single elliptical hole or crack is studied. and the proposed stiffness and strength modelsare verified in terms of micro-mechanical analyses.
文摘1 Introduction Shallow water delta in the middle-newborn Stratum Widely developed with huge oil and gas in China(Hu Shengwu et al.,2013).The control factors on the deltadevelopment like Climate,sea level,tectonic subsidence,sediment supply(flow,type),the geometric characteristics of the upstream river,the energy(wave,
基金Supported by the National Natural Science Foundation of China under Grant No 61372004the Fundamental Research Funds for the Central Universitiesthe Foundation of Science and Technology on Electromagnetic Scattering Laboratory
文摘The existence of the sea surface is bound to affect the electromagnetic （EM） scattering from marine targets. When dealing with the composite scattering from targets over a sea surface by applying high-frequency EM theories, the total scattering field can be decomposed into three parts in low sea states, namely, the direct scattering from the sea surface, the direct scattering from targets and the coupling scattering between the sea surface and targets. With regard to high sea states, breaking waves make the direct scattering from the sea surface and the coupling scattering more complicated. To solve this issue, a scattering model is proposed to analyze the composite scattering from a ship over a rough sea surface under high sea states. To consider the effect of breaking waves, a three dimensional geometric model is adopted together with Ufimtsev＇s theory of edge waves for the scattering from a breaker. In addition, the coupling scattering between targets and breaking waves is taken into account by considering all possible scattering paths. The simulated results indicate that the influence of breaking waves on the scattering field from the sea surface and on the coupling field is non-negligible, and the numerical results also show the effectiveness of the proposed scattering model.
文摘The effects of positron diffusion on the measured S parameter have been investigated by a point-source diffusion model and a δ function method. Firstly, the theoretical analyses of the effects are presented for the samples of a homogeneous semi-infinite medium and a film of definite thickness. Then the results are used to analyze the S parameters in several composite systems and interface models.
文摘The lattice constants of Sm-Co permanent magnet alloy have been determined by means of X-ray diffraction measurement. The lattice constants of R-Co alloy systems (R = rare earth) have been investigated with Bragg-williams (B-W) approximation and their expressions are given. It is pointed out that the lattice constants of RCo5 phase depend only on the alloy composition, and that the lattice constants of R2Co17 phase are related to the order parameter as well as the alloy composition. In this paper the relationship between the lattice constants of RCo5 and those of R2Co17 is discussed, and the values calculated by the expressions are compared with experimentally determined for Sm-Co alloys.
基金financially supported by the National Natural Science Foundation of China(No.51901077)the Science and Technology Innovation Platform and Talent Plan of Hunan Province(No.2019RS1020)+1 种基金the open project of State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body(No.71865003)Hunan University,Changsha,China.YG acknowledges support from NSF DMR 1809640。
文摘In the current work,a parallel comparison of the influence of Al,Mo and Ti,on the microstructure and strengthening of the CoCrFeNi alloy was conducted.To achieve this,inconsistencies on variables including the extent of alloying,thermomechanical processing and property-evaluation method were avoided.Microstructurally,following cold-rolling,annealing of the 4 at.%Al-doped alloys at 800-1000℃ did not result in phase separation;nevertheless,that of the 4 at.%Mo-and Ti-doped alloys led to the respective formation ofσandηphase and,consequently,caused extra strengthening through the Orowan dislocation bypassing mechanism.Our systematic qualitative analysis and DFT calculations showed that Al and Ti are more effective than Mo in reducing the stacking fault energy(SFE)of the CoCrFeNi alloy,because they can induce more considerable deformation of electronic density,making the gliding of atomic layers easier.Following identical thermomechnical processing,Al-,Mo-,and Ti-doping causes different extent of solid solution strengthening and grain boundary strengthening.Mo causes the most pronounced solid solution strengthening but does not benefit the grain boundary strengthening;in contrast,the effectiveness of grain boundary strengthening is boosted by the doping Al and Ti.Current analyses support that Labusch instead of Fleischer mechanism is applicable to explain the differences in solid solution strengthening,and the observed differences in grain boundary strengthening arise from the different tendency of Al,Mo and Ti to reduce the SFE of CoCrFeNi.In addition,we determined the value of the dimensionless parameter f in the Labusch model for CoCrFeNi-based alloys and observed a close relation between Hall-Petch slope and SFE.Although more in-depth studies are needed to provide full and mechanistic understandings,both these findings in fact presents significant values toward designing novel singlephase high-strength CoCrFeNi-based alloys through manipulating the solid solution and grain boundary strengthening by compositional tuning.
基金financially supported by the National Natural Science Foundation of China(Nos.50933005 and 51121001)the Program for Changjiang Scholars and Innovative Research Team in Universities(IRT1026)
文摘In this work, a flame-retardant polypropylene（PP）/ramie fiber（RF） composite was prepared. The ramie fibers were wrapped chemically by a phosphorus- and nitrogen-containing flame retardant（FR） produced via in situ condensation reaction so as to suppress their candlewick effect. Fourier transform infrared spectroscopy（FTIR）, X-ray photoelectron spectroscopy（XPS） and scanning electron microscopy（SEM） demonstrated that the ramie fibers wrapped chemically by FR（FR-RF） were obtained successfully. Thermogravimatric test showed that the PP/FR-RF composite had more residue and better thermal stability at high temperatures than the PP/RF composite. Cone calorimeter（CC） results indicated that the peak of heat release rate（PHRR） and total heat release（THR） correspondingly decreased by 23.4% and 12.5% compared with the values of neat PP/RF. The PP/FR-RF composite created a continuous and compact char layer after the combustion. Combining FTIR analysis of char residue after CC test with heat conduction coefficient results, it could be concluded that the charring of FR on RF greatly weakened the candlewick effect of RF, and more char residue in the RF domain facilitated the formation of more continuous and compact char layer in the whole combustion zone, consequently protected PP composites during combustion, resulting in the better flame retardancy of PP/FR-RF composite than that of PP/RF composite.
基金supports from the National Natural Science Foundation of China (No. 11572086 , No. 11402052 )the New Century Excellent Talent in University (NCET-11-0086)+3 种基金the Natural Science Foundation of Jiangsu province (No. BK20140616 )the Fundamental Research Funds for the Central Universities and the Scientiic Research Innovation Program of Jiangsu Province College Postgraduates (KYLX_0093, KYLX15_0092)the China Scholarship Council ( 201506090047 )the Ministry of Education, Science and Technological Development of Republic of Serbia ( TR 35011 and ON 74001 )
文摘The panel-type structures used in aerospace engineering can be subjected to severe highfrequency acoustic loadings in service. This paper evaluates the frequency-dependent random fatigue of panel-type structures made of ceramic matrix composites（CMCs） under acoustic loadings. Firstly, the high-frequency random responses from the broadband random excitation will result in more stress cycles in a deinite period of time. The probability density distributions of stress amplitudes will be different in different frequency bandwidths, though the peak stress estimations are identical. Secondly, the fatigue properties of CMCs can be highly frequency-dependent. The fatigue evaluation method for the random vibration case is adopted to evaluate the fatigue damage of a representative stiffened panel structure. The frequency effect through S-N curves on random fatigue damage is numerically veriied. Finally, a parameter is demonstrated to characterize the mean vibration frequency of a random process, and hence this parameter can further be considered as a reasonable loading frequency in the fatigue tests of CMCs to obtain more reliable S-N curves.Therefore, the inluence of vibration frequency can be incorporated in the random fatigue model from the two perspectives.
基金supported by the National High Technology Research and Development Program of China(No.2021YFF1200200)the Peiyang Talents Project of Tianjin University.
文摘The impact of the size effect on the color and photoluminescence(PL)of quantum dots(QDs)has sparked a revolutionary field of research,culminating in the prestigious Nobel Prize in 2023.Prior to their widespread popularization and large-scale commercialization,it is of paramount importance to effectively manipulate and optimize their optical properties.In this review,we place specific emphasis on the striking correlation between the optical characteristics of QDs and their size,structure,composition,and interface environment.We commence by tracing the evolution of quantum dot technology and subsequently categorizing QDs while outlining their typical synthesis methods.This is followed by a deep dive into the pivotal roles of size,composition,structure,and interfacial ligands in fine-tuning,optimizing,and enhancing the optical properties of QDs.Additionally,we illustrate the luminescence enhancement and charge transfer phenomena stemming from the heterojunction between semiconductor QDs and metal nanomaterials,which contribute to improved performance.Lastly,we introduce the burgeoning field of chiral QDs and their innovative applications.Armed with this knowledge,QDs can be readily tailored to exhibit adjustable luminous characteristics across the entire spectrum,boasting high luminous efficiency through multifaceted regulation.These advancements render QDs even more enticing and promising for a wide array of applications.
基金This paper is supported by Chenguang Program for Young Scientists of Wuhan, Hubei Province (No. 20065004116-22).
文摘The nanometer MnO2 has outstanding electrochemical performance theoretically, but it is not suitable for actual utilization, which may result in capacity decrease and resource waste. In this study we have utilized the characterizations of the nanometer material, synthesized a type of nanometer α-MnO2 through KMnO4 and KNO3 with hydrothermal method, and mixed the products into micron electrolytic manganese dioxide （EMD） to enhance the electrochemical performance of the electrode.The cyclic voltammogram and galvanostatical discharge measurements of the samples were investigated. It is found that the 50﹪ nanometer MnO2 mixed electrode has the best electrochemical performance. The electrochemical performance improvement mechanism of the sample nanometer MnO2 mixed into micron EMD was discussed. With the existence of electrolyte, the nanometer MnO2 particles filled into the interspaces of the micron EMD particles, the mass and charge transfer conditions of the electrode reaction were improved, and the electrode polarization was diminished.
基金This project is supported by the National Natural Science Foundation of China(No.59971017).
文摘The strengthening effect of a Zn alloy reinforced by SiC particulate was examined. Based on the results of SEM in-situ fracture observation and stress field analysis by finite element method, it is believed that the reinforcing effect of this composite is due to the combination of strain and stress hardening in the matrix.
基金Supported by the National Natural Science Foundation of China under Grant No 11274121
文摘The longitudinal wave propagating in one-dimensional periodic piezoelectric composite rod with inter-coupling between different piezoelectric segments is investigated. The analytical formulae for such a structure are shown and the dispersion relation is calculated. The results show that, by introducing the inter-coupling between the different piezoelectric segments, which is accomplished by serially connecting every n piezoelectric segment into supercells, some tunable Bragg band gaps can accordingly be opened in the low frequency region. The investigation could provide a new guideline for the tunable phononic crystal under passive control.
文摘Objective To investigate the effect of the implant composite of poly lactide-co-glycolide(PLGA)and bone mesenchymal stem cells (BMSCs) modified by basic fibroblast growth factor (bFGF) on injured spinal cord in rats.Methods Two hundred and
基金supported by the National Basic Research Program of China(Grant No.2014CB643900)the National Natural Science Foundation of China(Grant Nos.61225021,11474272,11204296,and 11474247)
文摘III-V Semiconductors containing a small amount of Bi, known as dilute bismides, have attracted great interest in recent years, due to the large band-gap reduction and other unique properties [1,2]. Previous studies have been pri- marily focused on the growth and optical properties of the GaAs-based bismuthides [3], while the properties of other dilute bismides are less well understood. Berding et al. [4] theoretically predicted that InPBi is expected to be an attractive candidate for narrow-gap applications. Experimentally, the InPBi alloy with good single crystal quality has been successfully synthesized recently and exhibits strong and broad photoluminescence at room temperature [5,6]. However, the electric transport characteristics of the InPBi alloy are poorly understood. In this work, we systematically investigate the effect of Bi incorporation on electric transport properties of the InP1-xBix alloys.
