A new Pd-PEPPSI complex(2)with the bromo groups on the para-positions of N-aryl moieties of NHC has been synthesized and characterized by NMR and X-ray single-crystal diffraction.Complex 2 crystallizes in monoclinic,s...A new Pd-PEPPSI complex(2)with the bromo groups on the para-positions of N-aryl moieties of NHC has been synthesized and characterized by NMR and X-ray single-crystal diffraction.Complex 2 crystallizes in monoclinic,space group P2_(1)/c with a=11.8790(8),b=14.3038(10),c=15.9905(11)A,β=101.291(2)°,V=2664.4(3)A^(3),Z=4,D_(c)=1.722 Mg/m^(3),μ=3.913 mm^(-1),F(000)=1352,the final R=0.0682 and wR=0.1914 for 15113 observed reflections(I>2σ(I)),R(all data)=0.0970,w R(all data)=0.2115,completeness to theta of 25.00 is 100.0%and GOOF=1.035.Influenced by the electron-withdrawing bromo groups,the Pd-PEPPSI complex(2)showed high catalytic activity for the Suzuki-Miyaura cross-coupling reactions of aryl chlorides and arylboronic acids with a low catalyst loading(0.05 mol%)at room temperature in air.展开更多
This article introduces the design theory of ceramic waveguide filter and proposes a new type of negative coupling structure with a conical throughhole,which has fine-adjustment of negative coupling without significan...This article introduces the design theory of ceramic waveguide filter and proposes a new type of negative coupling structure with a conical throughhole,which has fine-adjustment of negative coupling without significantly increasing the insertion loss of the filter.Based on this,the article proposes an eightcavity ceramic waveguide filter design for 5G base stations.It also presents a detailed discussion on the influence of the cross-coupling slot lengths L2 and L4 on the transmission zeros positions during the filter optimization process and the relevant change rules.For the proposed optimized filter,the observed performance indicators include the center frequency of 3.5 GHz,working bandwidth of 200 MHz,an insertion loss of≤2.0 dB,return loss of≥19 dB,and out-of-band nearend suppression and out-of-band far-end suppression of≥39 dB and≥63 dB,respectively.The test performance results obtained for the sample,with structural parameters as per the simulation model,were in good agreement with the simulation results.展开更多
According to the basic idea of classical yin-yang complementarity and modem dual-complementarity, in a simple and unified new way proposed by Luo, the unconventional Hamilton-type variational principles for geometrica...According to the basic idea of classical yin-yang complementarity and modem dual-complementarity, in a simple and unified new way proposed by Luo, the unconventional Hamilton-type variational principles for geometrically nonlinear elastodynamics of orthogonal cable-net structures are established systematically, which can fully characterize the initial-boundary-value problem of this kind of dynamics. An ifnportant integral relation is made, which can be considered as the generalized principle of virtual work for geometrically nonlinear dynamics of orthogonal cable-net structures in mechanics. Based on such relationship, it is possible not only to obtain the principle of virtual work for geometrically nonlinear dynamics of orthogonal cable-net structures, but also to derive systematically the complementary functionals for five-field, four-field, three-field and two-field unconventional Hamilton-type variational principles, and the functional for the unconventional Hamilton-type variational principle in phase space and the potential energy functional for one-field unconventional Hamilton-type variational principle for geometrically nonlinear elastodynamics of orthogonal cable-net structures by the generalized Legendre transformation given in this paper, Furthermore, the intrinsic relationship among various principles can be explained clearly with this approach.展开更多
This article describes a new miniaturized omni-directional antenna with quasi-self-complementary structure for wireless communication applications. A novel ground structure composed of five rectangular plates is propo...This article describes a new miniaturized omni-directional antenna with quasi-self-complementary structure for wireless communication applications. A novel ground structure composed of five rectangular plates is proposed to enhance the impedance bandwidth and reduce the antenna size. The proposed antenna is comprised of two patches surrounded by the ground structure. Two metal patches of the antenna are located on two opposite sides of the dielectric substrate. The feed patch is used to excite the radiation patch. This unique design is realized by properly choosing the suitable feed patch shape, selecting similar slot shape on the radiation patch, and tuning their dimensions. The proposed antenna with an extremely small size of 6 mm × 9 mm has an operating impedance bandwidth ranging from 4.5 to 6.1 GHz for S<sub>11</sub> < -10 dB, which also covers the two IEEE 802.11a wireless local area network bands (5.15 - 5.35 GHz and 5.725 - 5.825 GHz). In addition to be very small in size, the antenna exhibits omni-directional radiation patterns in the entire operating bandwidth and low cross polarization. The distortionless time domain performance of the antenna is confirmed by investigation of the phase response and group delay. The obtained results in both frequency and time domain show that the proposed antenna is suitable for use in wireless communication systems.展开更多
基金Supported by the Natural Science Foundation of Tianjin(No.16JCYBJC19700)the National Natural Science Foundation of China(No.21771138)the Foundation of Development Program of Future Expert in Tianjin Normal University(No.WLQR201704)
文摘A new Pd-PEPPSI complex(2)with the bromo groups on the para-positions of N-aryl moieties of NHC has been synthesized and characterized by NMR and X-ray single-crystal diffraction.Complex 2 crystallizes in monoclinic,space group P2_(1)/c with a=11.8790(8),b=14.3038(10),c=15.9905(11)A,β=101.291(2)°,V=2664.4(3)A^(3),Z=4,D_(c)=1.722 Mg/m^(3),μ=3.913 mm^(-1),F(000)=1352,the final R=0.0682 and wR=0.1914 for 15113 observed reflections(I>2σ(I)),R(all data)=0.0970,w R(all data)=0.2115,completeness to theta of 25.00 is 100.0%and GOOF=1.035.Influenced by the electron-withdrawing bromo groups,the Pd-PEPPSI complex(2)showed high catalytic activity for the Suzuki-Miyaura cross-coupling reactions of aryl chlorides and arylboronic acids with a low catalyst loading(0.05 mol%)at room temperature in air.
基金supported by the National Natural Science Fund Joint Fund Project(No.U21B2068)the Major Science and Technology Innovation Project of WenZhou(No.ZG2021014).
文摘This article introduces the design theory of ceramic waveguide filter and proposes a new type of negative coupling structure with a conical throughhole,which has fine-adjustment of negative coupling without significantly increasing the insertion loss of the filter.Based on this,the article proposes an eightcavity ceramic waveguide filter design for 5G base stations.It also presents a detailed discussion on the influence of the cross-coupling slot lengths L2 and L4 on the transmission zeros positions during the filter optimization process and the relevant change rules.For the proposed optimized filter,the observed performance indicators include the center frequency of 3.5 GHz,working bandwidth of 200 MHz,an insertion loss of≤2.0 dB,return loss of≥19 dB,and out-of-band nearend suppression and out-of-band far-end suppression of≥39 dB and≥63 dB,respectively.The test performance results obtained for the sample,with structural parameters as per the simulation model,were in good agreement with the simulation results.
基金Project supported by the National Natural Science Foundation of China(No.10172097)the Doctoral Foundation of Ministry of Education of China(No.20030558025)
文摘According to the basic idea of classical yin-yang complementarity and modem dual-complementarity, in a simple and unified new way proposed by Luo, the unconventional Hamilton-type variational principles for geometrically nonlinear elastodynamics of orthogonal cable-net structures are established systematically, which can fully characterize the initial-boundary-value problem of this kind of dynamics. An ifnportant integral relation is made, which can be considered as the generalized principle of virtual work for geometrically nonlinear dynamics of orthogonal cable-net structures in mechanics. Based on such relationship, it is possible not only to obtain the principle of virtual work for geometrically nonlinear dynamics of orthogonal cable-net structures, but also to derive systematically the complementary functionals for five-field, four-field, three-field and two-field unconventional Hamilton-type variational principles, and the functional for the unconventional Hamilton-type variational principle in phase space and the potential energy functional for one-field unconventional Hamilton-type variational principle for geometrically nonlinear elastodynamics of orthogonal cable-net structures by the generalized Legendre transformation given in this paper, Furthermore, the intrinsic relationship among various principles can be explained clearly with this approach.
文摘This article describes a new miniaturized omni-directional antenna with quasi-self-complementary structure for wireless communication applications. A novel ground structure composed of five rectangular plates is proposed to enhance the impedance bandwidth and reduce the antenna size. The proposed antenna is comprised of two patches surrounded by the ground structure. Two metal patches of the antenna are located on two opposite sides of the dielectric substrate. The feed patch is used to excite the radiation patch. This unique design is realized by properly choosing the suitable feed patch shape, selecting similar slot shape on the radiation patch, and tuning their dimensions. The proposed antenna with an extremely small size of 6 mm × 9 mm has an operating impedance bandwidth ranging from 4.5 to 6.1 GHz for S<sub>11</sub> < -10 dB, which also covers the two IEEE 802.11a wireless local area network bands (5.15 - 5.35 GHz and 5.725 - 5.825 GHz). In addition to be very small in size, the antenna exhibits omni-directional radiation patterns in the entire operating bandwidth and low cross polarization. The distortionless time domain performance of the antenna is confirmed by investigation of the phase response and group delay. The obtained results in both frequency and time domain show that the proposed antenna is suitable for use in wireless communication systems.
