Composite cathodes integrating Ni-rich layered oxides and oxide solid electrolytes are essential for highenergy all-solid-state lithium-ion batteries(ASSLBs),yet interfacial degradation during high-temperature co-sint...Composite cathodes integrating Ni-rich layered oxides and oxide solid electrolytes are essential for highenergy all-solid-state lithium-ion batteries(ASSLBs),yet interfacial degradation during high-temperature co-sintering(>600℃)remains a critical challenge.While surface passivation strategies mitigate reactions below 400℃,their effectiveness diminishes at elevated temperatures due to inability to counteract Li^(+)concentration gradients.Here,we introduce in situ lithium compensators,i.e.,LiOH/Li_(2)CO_(3),into NCM-LATP composite cathodes to dynamically replenish Li^(+)during co-sintering.These additives melt to form transient Li^(+)-rich phases that back-diffuse Li^(+)into NCM lattices,suppressing layered-to-rock salt transitions and stabilizing the interface.Quasi in situ XRD confirms retention of the layered structure at temperature up to 700℃,while electrochemical tests demonstrate a reversible capacity of 222.2 mA h g^(-1)—comparable to NCM before co-sintering—and an impressive 65.3% capacity retention improvement over100 cycles.In contrast,uncompensated cathodes exhibit severe degradation to 96.5 mA h g^(-1)due to Li depletion and resistive Li-Ti-O interphases.This strategy integrates sacrificial chemistry with scalable powder-mixing workflows,achieving a 93.4% reduction in interfacial impedance.By addressing Li^(+)flux homogenization and structural stability,this work provides a practical pathway toward industrialscale fabrication of high-performance ASSLBs.展开更多
In order to improve the Power Quality(PQ)of traction power supply system and reduce the power rating and operation cost of compensator,a Static VAR Compensator(SVC)integrated Railway Power Conditioner(RPC)is presented...In order to improve the Power Quality(PQ)of traction power supply system and reduce the power rating and operation cost of compensator,a Static VAR Compensator(SVC)integrated Railway Power Conditioner(RPC)is presented in this paper.RPC is a widely used device in the AC electrified railway systems to enhance the PQ indices of the main network.The next generation of this equipment is Active Power Quality Compensator(APQC).The major concern of these compensators is their high kVA rating.In this paper,a hybrid technique is proposed to solve aforementioned problems.A combination of SVC as an auxiliary device is employed together with the main compensators,i.e.,RPC and APQC that leads on to the reduction of power rating of the main compensators.The use of proposed scheme will cause to reduce significantly the initial investment cost of compensation system.The main compensators are only utilized to balance active powers of two adjacent feeder sections and suppress harmonic currents.The SVCs are used to compensate reactive power and suppress the third and fifth harmonic currents.In this paper firstly,the PQ compensation procedure in AC electrified railway is analyzed step by step.Then,the control strategies for SVC and the main compensators are presented.Finally,a simulation is fulfilled using Matlab/Simulink software to verify the effectiveness and validity of the proposed scheme and compensation strategy and also demonstrate that this technique could compensate all PQ problems.展开更多
Ca_(3-x)(PO_(4))_(2):xTb^(3+)(0.2≤x≤0.4),Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),0.35 A^(+)(A=Li,Na,K),and Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),yLi^(+)(0.35≤y≤0.455)phosphors were prepared by solid-state reaction.All the p...Ca_(3-x)(PO_(4))_(2):xTb^(3+)(0.2≤x≤0.4),Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),0.35 A^(+)(A=Li,Na,K),and Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),yLi^(+)(0.35≤y≤0.455)phosphors were prepared by solid-state reaction.All the prepared phosphors formed a rhombohedral unit cell with the R3c space group.To improve the photoluminescence(PL)properties of the Ca_(2.65)(PO_(4))_(2):0.35 Tb^(3+)phosphor,monovalent charge compensators such as Li^(+),NA^(+),and K^(+)were added to the Ca_(2.65)(PO_(4))_(2):0.35 Tb^(3+)phosphor.The charge compensators acted as fluxes,so they improved the crystallinity.The excitation and emission properties were significantly improved through the incorporation of charge compensators.In particular,among the charge compensators,Li^(+)ion substantially enhanced the emission intensity and color purity.Furthermore,considering the evaporation of Li_(2)CO_(3)during the annealing process,we optimized the concentration of Li^(+)charge compensator to enhance its PL performance.Impressively,the green emission intensity of the Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),0.385 Li^(+)phosphor was 260%higher than that of the Ca_(2.65)(PO_(4))_(2):0.35 Tb^(3+)phosphor.We believe that the effect of charge compensators on the PL properties and the optimum concentration of Li^(+)cha rge compensator are useful for the design of phosphors in light-emitting diodes.展开更多
Presents a systematic design method of reduced order dynamical compensator via the parametric representations of eigenstructure assignment for linear system, which provides maximum degree of freedom, and can be easily...Presents a systematic design method of reduced order dynamical compensator via the parametric representations of eigenstructure assignment for linear system, which provides maximum degree of freedom, and can be easily used for the design of a linear system with unknown inputs under some conditions. Even when these conditions are not satisfied, the lower order dynamical compensator can also be designed under some relaxed conditions. Some examples illustrate that the method is neat, simple and effective.展开更多
Chirped fibre Bragg gratings （CFBGs） are required to be concatenated to compensate the fibre dispersion in the dense wavelength-division multiplexing （DWDM） systems. When the channel spacing is small, the performa...Chirped fibre Bragg gratings （CFBGs） are required to be concatenated to compensate the fibre dispersion in the dense wavelength-division multiplexing （DWDM） systems. When the channel spacing is small, the performance of CFBGs is degraded, which restricts the usage of fibre gratings. The origin of the interactions between the gratings is analysed and methods of suppressing the interactions are also proposed.展开更多
A parameter that allows an evaluation of power quality transmitted, or distributed, between energy source and the final user is electric system power factor. Among other aspects, a bigger power factor, close to unit v...A parameter that allows an evaluation of power quality transmitted, or distributed, between energy source and the final user is electric system power factor. Among other aspects, a bigger power factor, close to unit value, relieves operational conditions of lines and cables, besides, it improves feeder＇s voltage behavior. Due to load variation along the day, the dynamic compensation of power factor allows maintaining this parameter close to the ideal. This paper brings a study about a reactive dynamic compensator based on the voltage control in a capacitive element, varying the reactive energy in accordance with the system demand, everything from the energy efficiency point of view. In distribution systems, the losses due to this variable compensation can be lower than in other compensation methods and also the voltage presents a better behavior, justifying its application.展开更多
With large-scale use of kinds of motors, oilfield drilling electrical system always accompanied by serious power quality problem, including reactive current, harmonics current and grid voltage distortion, which would ...With large-scale use of kinds of motors, oilfield drilling electrical system always accompanied by serious power quality problem, including reactive current, harmonics current and grid voltage distortion, which would greatly threaten the safety and proper working of the whole system. This paper focuses on a power quality improvement project to solve these problems. A hybrid compensating scheme, including an active compensator and a passive compensator, is carried out. Because of the specificity of oilfield drilling electrical system, compensators are redesigned against features of this application background. And then the current detection point arrangement of this hybrid system is also taken into consideration to build the whole system much more effective and reliable. Now the improvement project is already implemented in application field, and the power quality of the system is greatly improved.展开更多
The design of normal decentralized dynamic compensators for the internal properness and stability of singular decentralized control systems is investigated, and an effective sequential design approach is presented.
Urbanization alters vegetation productivity by both direct(ωd)and indirect(ω_(i))effects.The direct effect is from the change of vegetated area indicated by impervious surface intensity(ISI),while indirect effects a...Urbanization alters vegetation productivity by both direct(ωd)and indirect(ω_(i))effects.The direct effect is from the change of vegetated area indicated by impervious surface intensity(ISI),while indirect effects arise from changes in urban environmental factors,such as near-surface air temperatures,precipitation,urban heat island(UHI)intensity,and population density(POP).The respective contributions ofω_(d) andω_(i) to vegetation net primary productivity(NPP)under various phases of urbanization are not well quantified.Using multisource remote-sensing data from 1990 to 2020,we analyzed the spatiotemporal variation in urban expansion and the effect thatω_(d) andω_(i) had on NPP in the megalopolis of Beijing,China,over 5-year intervals.During this period,Beijing underwent significant planar expansion rates of about 58.9 km^(2)/yr.Annual mean loss of NPP byω_(d) was estimated to be about 77.1 g C/(m^(2)·yr)during the 1990-2020 period,while annual mean improvement to NPP byω_(i) amounted to an increase of 28.9 g C/(m^(2)·yr).The NPP losses were partially offset by NPP improvements in the order of 18.6%-69.3%.The impact of forcing variables on NPP varied spatially.Air temperature,precipitation,UHI,POP,and ISI explained about 13.8%,23.2%,23.7%,14.7%,and 24.6%of the spatial variation in NPP.The impact of air temperature on NPP was related to available moisture,negatively affecting NPP in regions with water deficits.Our findings demonstrate the dual impact of urbanization on vegetation and underscore the necessity for spatially adaptive ecological management strategies in regions experiencing rapid urban growth.展开更多
Achieving multi-electron reaction at high operation voltage is the key to increase the energy density of Na_(3)V_(2)(PO_(4))_(3)(NVP)cathode.However,the motivated V^(4+)/V^(5+)redox usually shows inferior reversibilit...Achieving multi-electron reaction at high operation voltage is the key to increase the energy density of Na_(3)V_(2)(PO_(4))_(3)(NVP)cathode.However,the motivated V^(4+)/V^(5+)redox usually shows inferior reversibility and causes serious volume changes.Herein,this article proposes a local electronic interaction mechanism which achieves highly reversible multi-electron reaction of NVP.Particularly,Al-Sn co-doped and carbon coated NVP(Na_(3)Al_(0.1)Sn_(0.1)V_(1.8)(PO_(4))_(3)@C,abbreviated as NASVP@C-2)was prepared by sol-gel method.The doped-Al can activate the redox of V^(4+)/V^(5+)and generate the"pinning effect"to stabilize the crystal structure,and the Sn acts as localized electronic reservoir for charge compensation of V redox.The localized electronic interaction mechanism between Sn and V is revealed by multi ex-situ characterizations.Kinetics tests and density functional theory(DFT)calculations suggest that the Al-Sn co-doping enhances the electronic conductivity and reduces the Na^(+)diffusion barrier in NVP.An extremely low volumetric variation(1.07%)is detected in NASVP@C-2 during cycling.As a result,the highly reversible multielectron(2.53)reaction is achieved in NASVP@C-2,which releases a high capacity of 147.6 mAh g^(-1) at1 C and exhibits exceptional cycle stability and rate capability.This work provides a new strategy to design high energy density and durable NASICON cathode.展开更多
In this study,the mechanism and characteristics of the responseαparticles and the damage caused by them in CMOS active pixel(APS)sensors were investigated.A detection and compensation algorithm for dead pixels caused...In this study,the mechanism and characteristics of the responseαparticles and the damage caused by them in CMOS active pixel(APS)sensors were investigated.A detection and compensation algorithm for dead pixels caused byαparticle ionizing radiation was proposed,and the effects of dead-pixel compensation algorithms were compared and analyzed under different parameter conditions.The experimental results show thatαparticle response signal has highest accuracy at 9 dB gain,with an obvious“target-ring”distribution.With increasing cumulative dose,the CMOS APS pedestal tends to saturation while dead pixels continue increasing.Though some pixel damage recovers through natural annealing,the dead-to-noise ratio increases with irradiation time,reaching 32.54%after 72 h.A hierarchical clustering dead-pixel detection method is proposed,categorizing pixels into two types:those within and outside the response event.A classification compensation strategy combining mean and majority filtering is proposed.This compensation algorithm can address dead-pixel interference without affectingαparticle radiation response data.When iterated multiple times and with integration time exceeding 6.31 ms,the number of dead pixels can be effectively reduced.展开更多
This study aims to explore how the Wei River Basin can enhance the efficiency of horizontal ecological compensation to promote high-quality and sustainable development in the Yellow River Basin.To achieve this,a four-...This study aims to explore how the Wei River Basin can enhance the efficiency of horizontal ecological compensation to promote high-quality and sustainable development in the Yellow River Basin.To achieve this,a four-stage DEA(Data Envelopment Analysis)method was employed to evaluate the efficiency of ecological compensation in six prefecture-level cities within the Wei River Basin from 2001 to 2022.In addition,the K-prototype clustering analysis method was integrated to assess the regional differences in ECE(ecological compensation efficiency).The findings indicate:(1)the ecological compensation efficiency in the upstream areas of the Wei River Basin is significantly higher than in the downstream regions;(2)the influence of factors such as the proportion of the tertiary industry,population density and residents’disposable income on the efficiency of ecological compensation is significant;(3)after excluding environmental factors,the overall ecological compensation efficiency showed a significant improvement.Based on these insights,it is recommended that the provinces of Shaanxi and Gansu further establish a robust compensation fund operation mechanism,build a cross-regional ecological compensation upstream-downstream coordination system,and strengthen inter-basin economic cooperation mechanisms to promote dual-driven development through technological advancement and scale benefits,thereby advancing ecological protection and sustainable development in the Wei River Basin.展开更多
In an ultraprecision turning process for small-diameter optical aspheric workpieces,tool-profile errors induce mid-frequency errors in the workpiece profile,limiting further improvements in precision.In this study,an ...In an ultraprecision turning process for small-diameter optical aspheric workpieces,tool-profile errors induce mid-frequency errors in the workpiece profile,limiting further improvements in precision.In this study,an XZB three-axis linkage ultraprecision machining method is proposed,and the effects of tool-center errors are analyzed.To address residual errors in Z-direction profile-error compensation,a workpiece normal-profile-error compensation method is proposed.After XZB three-axis linkage turning and compensation,the workpiece profile error(PV)reaches 0.086μm,surpassing the precision of XZ two-axis machining,and mid-frequency errors are reduced.Compared with Z-direction profile-error compensation,which results in a profile error of 0.092μm,normal-profile-error compensation reduces PV to 0.047μm,considerably improving aspheric accuracy.Experimental results demonstrate that XZB three-axis linkage machining significantly improves the aspheric workpiece profile,enhancing both its accuracy and surface quality.This method reduces mid-frequency errors,and the subsequent application of normal-profile-error compensation further refines the profile,achieving higher overall accuracy.展开更多
In order to solve the problems of slow dynamic response and difficult multi-source coordination of solar electric vehicle charging stations under intermittent renewable energy,this paper proposes a hardware-algorithm ...In order to solve the problems of slow dynamic response and difficult multi-source coordination of solar electric vehicle charging stations under intermittent renewable energy,this paper proposes a hardware-algorithm co-design framework:the T-type three-level bidirectional converter(100 kHz switching frequency)based on silicon carbide(SiC)MOSFET is deeply integrated with fuzzy model predictive control(Fuzzy-MPC).At the hardware level,the switching trajectory and resonance suppression circuit(attenuation resonance peak 18 dB)are optimized,and the total loss is reduced by 23%compared with the traditional silicon-based IGBT.At the algorithm level,the adaptive parameter update mechanism and multi-objective rolling optimization are adopted,and the 5 ms level dynamic power allocation is realized by relying on edge computing.Experiments on 800 V DC microgrid(including 600 kW photovoltaic and 150 A·h energy storage)built based on MATLAB/Simulink hardware-in-the-loop(HIL)platform show that the system shortens the battery charging time from 42 to 28 min(the charging speed is increased by 33%).Through the 78%valley power utilization rate,the power purchase cost of high-priced power grids was significantly reduced,and the levelized electricity price decreased by 10.3%;Under the irradiation fluctuation,the renewable energy consumption rate increases by 10.1%,and the DC bus voltage fluctuation is stable within±10 V when the load step is±30%.The co-design provides an economically feasible and dynamically robust solution for the efficient integration of PV-ESG-EV in the smart grid.展开更多
The Grassland Ecological Compensation Policy(GECP)is a large-scale project that has been investing in China since 2011.Despite the significant investment and long duration of the GECP,its impact on carbon sequestratio...The Grassland Ecological Compensation Policy(GECP)is a large-scale project that has been investing in China since 2011.Despite the significant investment and long duration of the GECP,its impact on carbon sequestration in grasslands remains unclear.Based on panel data from prefecture-level cities in the Yellow River Basin(YRB)from 2000 to 2020,this study explored the effects of the GECP on grassland carbon sequestration in the YRB and its heterogeneity using a time-varying difference-in-differences(TV-DID)model.Subsequently,we predicted changes in carbon sequestration in grasslands under the influence of the GECP from 2021 to 2040 using a simulation.The main conclusions are as follows:First,the implementation of the GECP promoted carbon sequestration in grasslands.This conclusion was validated after conducting a series of robustness tests.Moreover,the effects of the GECP were heterogeneous across different geographical locations,highway densities,and grassland areas.Finally,the simulation results indicated that over the next 20 years,grassland carbon sequestration will generally increase but exhibit cyclical changes.The government should align the principles and objectives of the GECP with local geographic conditions,resource availability,and socio-economic development.It must formulate and implement tailored policies that maximize the ecological protection benefits of the GECP and promote carbon sequestration in the grasslands of the YRB.展开更多
O3-types layered cathode materials in sodium-ion batteries(SIBs)suffer from the obvious lattice distortion induced by the complex phase transitions during Na^(+)intercalation/deintercalation process,leading to severe ...O3-types layered cathode materials in sodium-ion batteries(SIBs)suffer from the obvious lattice distortion induced by the complex phase transitions during Na^(+)intercalation/deintercalation process,leading to severe structural collapse and performance degradation.Herein,a series of high valence tantalum(Ta^(5+))doped Na(Ni_(0.4)Fe_(0.2)Mn_(0.4))_(1−x)Ta_(x)O_(2)(x=0/0.0025/0.005/0.01)secondary spherical particles are firstly developed,where Ta^(5+)doping enables the refined primary grain with a tightly stacked rod-like morphology.Comprehensive structural analysis via Neutron powder diffraction(NPD)and Synchrotron radiation X-ray diffraction(SXRD)reveals an expanded NaO_(2)slab and a reduction in Na site vacancy.The potential charge compensation mechanism is further illustrated by X-ray absorption spectroscopy(XAS)and X-ray photoelectron spectroscopy(XPS),unveiling a partial reduction from Ni^(3+)to Ni^(2+)with Ta^(5+)doping.In situ X-ray diffraction(in situ XRD)suggests that the decorated sample undergoes a volume change as low as 0.8%,in contrast with the pristine one(1.5%).Thus,the optimized sample with x=0.005 retains an enhanced capacity retention up to 70.4%at 1 C after 300 cycles in half-cell and delivers a high energy density of 251 Wh kg^(-1)(0.1 C)and with a good capacity retention of 81.0%at 1 C after 200 cycles in full-cell.Our findings provide new insights into the mechanism of high valence Ta^(5+)doping in stabilizing layered oxides cathode materials for SIBs.展开更多
In real industrial microgrids(MGs),the length of the primary delivery feeder to the connection point of the main substation is sometimes long.This reduces the power factor and increases reactive power absorption along...In real industrial microgrids(MGs),the length of the primary delivery feeder to the connection point of the main substation is sometimes long.This reduces the power factor and increases reactive power absorption along the primary delivery feeder from the external network.Besides,the giant induction electro-motors as the working horse of industries requires remarkable amounts of reactive power for electro-mechanical energy conversions.To reduce power losses and operating costs of the MG as well as to improve the voltage quality,this study aims at providing an insightful model for optimal placement and sizing of reactive power compensation capacitors in an industrial MG.In the presented model,the objective function considers voltage profile and network power factor improvement at the MG connection point.Also,it realizes power flow equations within which all operational security constraints are considered.Various reactive power compensation strategies including distributed group compensation,centralized compensation at the main substation,and distributed compensation along the primary delivery feeder are scrutinized.A real industrial MG,say as Urmia Petrochemical plant,is considered in numerical validations.The obtained results in each scenario are discussed in depth.As seen,the best performance is obtained when the optimal location and sizing of capacitors are simultaneously determined at the main buses of the industrial plants,at the main substation of the MG,and alongside the primary delivery feeder.In this way,74.81%improvement in power losses reduction,1.3%lower active power import from the main grid,23.5%improvement in power factor,and 37.5%improvement in network voltage deviation summation are seen in this case compared to the base case.展开更多
Measuring cross sections of nuclear reactions,such as the so-called“Holy Grail”reaction,^(12)C(σ,γ)^(16)O,is essential for understanding stellar nucleosynthesis but presents significant challenges due to extremely...Measuring cross sections of nuclear reactions,such as the so-called“Holy Grail”reaction,^(12)C(σ,γ)^(16)O,is essential for understanding stellar nucleosynthesis but presents significant challenges due to extremely low cross sections.Key challenges include significant energy loss as ions penetrate the target material,limiting measurements to thin target layers.To overcome these obstacles,we propose a novel method,the in-target energy loss compensating(eLOC)method,specifically designed for gas targets,which utilizes a gas-filled magnetic field and accelerating electric fields to compensate for ion energy loss in the target.Simulations show that this approach significantly enhances the effective target thickness by over 140 times in the case of the“Holy Grail”reaction with an inverse-kinematics setup.This eLOC method may provide a powerful new tool for obtaining critical data in nuclear astrophysics,thereby advancing our understanding of stellar nucleosynthesis and the origins of elements in the universe,as well as benefiting other related fields such as isotope production.展开更多
With the increasing penetration of renewable energy,the coordination of energy storage with thermal power for frequency regulation has become an effective means to enhance grid frequency security.Addressing the challe...With the increasing penetration of renewable energy,the coordination of energy storage with thermal power for frequency regulation has become an effective means to enhance grid frequency security.Addressing the challenge of improving the frequency regulation performance of a thermal-storage primary frequency regulation system while reducing its associated losses,this paper proposes a multi-dimensional cooperative optimization strategy for the control parameters of a combined thermal-storage system,considering regulation losses.First,the frequency regulation losses of various components within the thermal power unit are quantified,and a calculation method for energy storage regulation loss is proposed,based on Depth of Discharge(DOD)and C-rate.Second,a thermal-storage cooperative control method based on series compensation is developed to improve the system’s frequency regulation performance.Third,targeting system regulation loss cost and regulation output,and considering constraints on output overshoot and system parameters,an improved Particle Swarm Optimization(PSO)algorithm is employed to tune the parameters of the low-pass filter and the series compensator,thereby reducing regulation losses while enhancing performance.Finally,simulation results demonstrate that the total loss cost of the proposed control strategy is comparable to that of a system with only thermal power participation.However,the thermal power loss cost is reduced by 42.16%compared to the thermal-only case,while simultaneously improving system frequency stability.Thus,the proposed strategy effectively balances system frequency stability and economic efficiency.展开更多
Relieving network congestions is a critical goal for the safe and flexible operation of modern power systems, especially in the presence of intermittent renewables or distributed generation. This paper deals with the ...Relieving network congestions is a critical goal for the safe and flexible operation of modern power systems, especially in the presence of intermittent renewables or distributed generation. This paper deals with the real-time coordinated operation of distributed static series compensators(DSSCs) to remove network congestions by suitable modifications of the branch reactance. Several objective functions are considered and discussed to minimize the number of the devices involved in the control actions, the total losses or the total reactive power exchanged, leading to a non-convex mixed-integer non-linear programming problem. Then, a heuristic methodology combining the solution of a regular NLP with k-means clustering algorithm is proposed to get rid of the binary variables, in an attempt to reduce the computational cost. The proposed coordinated operation strategy of the DSSCs is tested on several benchmark systems, providing feasible and sufficiently optimal solutions in a reasonable time frame for practical systems.展开更多
基金financially supported by the National Natural Science Foundation of China(52102206)the Natural Science Foundation of Beijing Municipality-Shunyi Innovation Collaborative Joint Fund(L247018)+2 种基金the Natural Science Foundation of Beijing Municipality(2254076 and 2252024)the Central Guidance on Local Science and Technology Development Fund of Hebei Province(246Z4412G)the Fundamental Research Funds for the Central Universities(2025MS022,North China Electric Power University)。
文摘Composite cathodes integrating Ni-rich layered oxides and oxide solid electrolytes are essential for highenergy all-solid-state lithium-ion batteries(ASSLBs),yet interfacial degradation during high-temperature co-sintering(>600℃)remains a critical challenge.While surface passivation strategies mitigate reactions below 400℃,their effectiveness diminishes at elevated temperatures due to inability to counteract Li^(+)concentration gradients.Here,we introduce in situ lithium compensators,i.e.,LiOH/Li_(2)CO_(3),into NCM-LATP composite cathodes to dynamically replenish Li^(+)during co-sintering.These additives melt to form transient Li^(+)-rich phases that back-diffuse Li^(+)into NCM lattices,suppressing layered-to-rock salt transitions and stabilizing the interface.Quasi in situ XRD confirms retention of the layered structure at temperature up to 700℃,while electrochemical tests demonstrate a reversible capacity of 222.2 mA h g^(-1)—comparable to NCM before co-sintering—and an impressive 65.3% capacity retention improvement over100 cycles.In contrast,uncompensated cathodes exhibit severe degradation to 96.5 mA h g^(-1)due to Li depletion and resistive Li-Ti-O interphases.This strategy integrates sacrificial chemistry with scalable powder-mixing workflows,achieving a 93.4% reduction in interfacial impedance.By addressing Li^(+)flux homogenization and structural stability,this work provides a practical pathway toward industrialscale fabrication of high-performance ASSLBs.
文摘In order to improve the Power Quality(PQ)of traction power supply system and reduce the power rating and operation cost of compensator,a Static VAR Compensator(SVC)integrated Railway Power Conditioner(RPC)is presented in this paper.RPC is a widely used device in the AC electrified railway systems to enhance the PQ indices of the main network.The next generation of this equipment is Active Power Quality Compensator(APQC).The major concern of these compensators is their high kVA rating.In this paper,a hybrid technique is proposed to solve aforementioned problems.A combination of SVC as an auxiliary device is employed together with the main compensators,i.e.,RPC and APQC that leads on to the reduction of power rating of the main compensators.The use of proposed scheme will cause to reduce significantly the initial investment cost of compensation system.The main compensators are only utilized to balance active powers of two adjacent feeder sections and suppress harmonic currents.The SVCs are used to compensate reactive power and suppress the third and fifth harmonic currents.In this paper firstly,the PQ compensation procedure in AC electrified railway is analyzed step by step.Then,the control strategies for SVC and the main compensators are presented.Finally,a simulation is fulfilled using Matlab/Simulink software to verify the effectiveness and validity of the proposed scheme and compensation strategy and also demonstrate that this technique could compensate all PQ problems.
基金financially supported by the Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning(KETEP)grant funded by the Korea government Ministry of Trade,Industry&Energy(No.20184030202260)。
文摘Ca_(3-x)(PO_(4))_(2):xTb^(3+)(0.2≤x≤0.4),Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),0.35 A^(+)(A=Li,Na,K),and Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),yLi^(+)(0.35≤y≤0.455)phosphors were prepared by solid-state reaction.All the prepared phosphors formed a rhombohedral unit cell with the R3c space group.To improve the photoluminescence(PL)properties of the Ca_(2.65)(PO_(4))_(2):0.35 Tb^(3+)phosphor,monovalent charge compensators such as Li^(+),NA^(+),and K^(+)were added to the Ca_(2.65)(PO_(4))_(2):0.35 Tb^(3+)phosphor.The charge compensators acted as fluxes,so they improved the crystallinity.The excitation and emission properties were significantly improved through the incorporation of charge compensators.In particular,among the charge compensators,Li^(+)ion substantially enhanced the emission intensity and color purity.Furthermore,considering the evaporation of Li_(2)CO_(3)during the annealing process,we optimized the concentration of Li^(+)charge compensator to enhance its PL performance.Impressively,the green emission intensity of the Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),0.385 Li^(+)phosphor was 260%higher than that of the Ca_(2.65)(PO_(4))_(2):0.35 Tb^(3+)phosphor.We believe that the effect of charge compensators on the PL properties and the optimum concentration of Li^(+)cha rge compensator are useful for the design of phosphors in light-emitting diodes.
文摘Presents a systematic design method of reduced order dynamical compensator via the parametric representations of eigenstructure assignment for linear system, which provides maximum degree of freedom, and can be easily used for the design of a linear system with unknown inputs under some conditions. Even when these conditions are not satisfied, the lower order dynamical compensator can also be designed under some relaxed conditions. Some examples illustrate that the method is neat, simple and effective.
文摘Chirped fibre Bragg gratings （CFBGs） are required to be concatenated to compensate the fibre dispersion in the dense wavelength-division multiplexing （DWDM） systems. When the channel spacing is small, the performance of CFBGs is degraded, which restricts the usage of fibre gratings. The origin of the interactions between the gratings is analysed and methods of suppressing the interactions are also proposed.
文摘A parameter that allows an evaluation of power quality transmitted, or distributed, between energy source and the final user is electric system power factor. Among other aspects, a bigger power factor, close to unit value, relieves operational conditions of lines and cables, besides, it improves feeder＇s voltage behavior. Due to load variation along the day, the dynamic compensation of power factor allows maintaining this parameter close to the ideal. This paper brings a study about a reactive dynamic compensator based on the voltage control in a capacitive element, varying the reactive energy in accordance with the system demand, everything from the energy efficiency point of view. In distribution systems, the losses due to this variable compensation can be lower than in other compensation methods and also the voltage presents a better behavior, justifying its application.
文摘With large-scale use of kinds of motors, oilfield drilling electrical system always accompanied by serious power quality problem, including reactive current, harmonics current and grid voltage distortion, which would greatly threaten the safety and proper working of the whole system. This paper focuses on a power quality improvement project to solve these problems. A hybrid compensating scheme, including an active compensator and a passive compensator, is carried out. Because of the specificity of oilfield drilling electrical system, compensators are redesigned against features of this application background. And then the current detection point arrangement of this hybrid system is also taken into consideration to build the whole system much more effective and reliable. Now the improvement project is already implemented in application field, and the power quality of the system is greatly improved.
文摘The design of normal decentralized dynamic compensators for the internal properness and stability of singular decentralized control systems is investigated, and an effective sequential design approach is presented.
基金supported by the National Key Research and Develop-ment Program of China(No.2020YFA0608100)the National Nat-ural Science Foundation of China(Nos.32071842 and 32101588).
文摘Urbanization alters vegetation productivity by both direct(ωd)and indirect(ω_(i))effects.The direct effect is from the change of vegetated area indicated by impervious surface intensity(ISI),while indirect effects arise from changes in urban environmental factors,such as near-surface air temperatures,precipitation,urban heat island(UHI)intensity,and population density(POP).The respective contributions ofω_(d) andω_(i) to vegetation net primary productivity(NPP)under various phases of urbanization are not well quantified.Using multisource remote-sensing data from 1990 to 2020,we analyzed the spatiotemporal variation in urban expansion and the effect thatω_(d) andω_(i) had on NPP in the megalopolis of Beijing,China,over 5-year intervals.During this period,Beijing underwent significant planar expansion rates of about 58.9 km^(2)/yr.Annual mean loss of NPP byω_(d) was estimated to be about 77.1 g C/(m^(2)·yr)during the 1990-2020 period,while annual mean improvement to NPP byω_(i) amounted to an increase of 28.9 g C/(m^(2)·yr).The NPP losses were partially offset by NPP improvements in the order of 18.6%-69.3%.The impact of forcing variables on NPP varied spatially.Air temperature,precipitation,UHI,POP,and ISI explained about 13.8%,23.2%,23.7%,14.7%,and 24.6%of the spatial variation in NPP.The impact of air temperature on NPP was related to available moisture,negatively affecting NPP in regions with water deficits.Our findings demonstrate the dual impact of urbanization on vegetation and underscore the necessity for spatially adaptive ecological management strategies in regions experiencing rapid urban growth.
基金financially supported by the National Natural Science Foundation of China(52462030,52464034,52364038,12464049 and 52474330)Outstanding Youth Funding program of Hunan Province(No.2023JJ10033)+5 种基金Excellent Youth Foundation of Hunan Provincial Education Department(No.23B0527,23B0528)the Natural Science Foundation of Hunan Province(No.2024JJ7399,No.2024JJ7398)Aid Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Provincethe Hunan Provincial Undergraduate Innovation Training Program General Project(Grant No.S202410531041,No.S202310531052)the Postgraduate Research Innovation Program of Jishou University([2024]11-82)the Postgraduate Graduate Research Project of Jishou University(2023-53)。
文摘Achieving multi-electron reaction at high operation voltage is the key to increase the energy density of Na_(3)V_(2)(PO_(4))_(3)(NVP)cathode.However,the motivated V^(4+)/V^(5+)redox usually shows inferior reversibility and causes serious volume changes.Herein,this article proposes a local electronic interaction mechanism which achieves highly reversible multi-electron reaction of NVP.Particularly,Al-Sn co-doped and carbon coated NVP(Na_(3)Al_(0.1)Sn_(0.1)V_(1.8)(PO_(4))_(3)@C,abbreviated as NASVP@C-2)was prepared by sol-gel method.The doped-Al can activate the redox of V^(4+)/V^(5+)and generate the"pinning effect"to stabilize the crystal structure,and the Sn acts as localized electronic reservoir for charge compensation of V redox.The localized electronic interaction mechanism between Sn and V is revealed by multi ex-situ characterizations.Kinetics tests and density functional theory(DFT)calculations suggest that the Al-Sn co-doping enhances the electronic conductivity and reduces the Na^(+)diffusion barrier in NVP.An extremely low volumetric variation(1.07%)is detected in NASVP@C-2 during cycling.As a result,the highly reversible multielectron(2.53)reaction is achieved in NASVP@C-2,which releases a high capacity of 147.6 mAh g^(-1) at1 C and exhibits exceptional cycle stability and rate capability.This work provides a new strategy to design high energy density and durable NASICON cathode.
基金supported by the National Natural Science Foundation of China(No.11905102)Hunan Provincial Postgraduate Research and Innovation Project(No.QL20230234)。
文摘In this study,the mechanism and characteristics of the responseαparticles and the damage caused by them in CMOS active pixel(APS)sensors were investigated.A detection and compensation algorithm for dead pixels caused byαparticle ionizing radiation was proposed,and the effects of dead-pixel compensation algorithms were compared and analyzed under different parameter conditions.The experimental results show thatαparticle response signal has highest accuracy at 9 dB gain,with an obvious“target-ring”distribution.With increasing cumulative dose,the CMOS APS pedestal tends to saturation while dead pixels continue increasing.Though some pixel damage recovers through natural annealing,the dead-to-noise ratio increases with irradiation time,reaching 32.54%after 72 h.A hierarchical clustering dead-pixel detection method is proposed,categorizing pixels into two types:those within and outside the response event.A classification compensation strategy combining mean and majority filtering is proposed.This compensation algorithm can address dead-pixel interference without affectingαparticle radiation response data.When iterated multiple times and with integration time exceeding 6.31 ms,the number of dead pixels can be effectively reduced.
基金funded by the Gansu Soft Science Planning Project(Grant No.25JRZA170).
文摘This study aims to explore how the Wei River Basin can enhance the efficiency of horizontal ecological compensation to promote high-quality and sustainable development in the Yellow River Basin.To achieve this,a four-stage DEA(Data Envelopment Analysis)method was employed to evaluate the efficiency of ecological compensation in six prefecture-level cities within the Wei River Basin from 2001 to 2022.In addition,the K-prototype clustering analysis method was integrated to assess the regional differences in ECE(ecological compensation efficiency).The findings indicate:(1)the ecological compensation efficiency in the upstream areas of the Wei River Basin is significantly higher than in the downstream regions;(2)the influence of factors such as the proportion of the tertiary industry,population density and residents’disposable income on the efficiency of ecological compensation is significant;(3)after excluding environmental factors,the overall ecological compensation efficiency showed a significant improvement.Based on these insights,it is recommended that the provinces of Shaanxi and Gansu further establish a robust compensation fund operation mechanism,build a cross-regional ecological compensation upstream-downstream coordination system,and strengthen inter-basin economic cooperation mechanisms to promote dual-driven development through technological advancement and scale benefits,thereby advancing ecological protection and sustainable development in the Wei River Basin.
基金supported by the National Natural Science Foundation of China(Grant No.52130503)the Science and Technology Innovation Program of Hunan Province(Grants Nos.2023RC1046 and 2023GK2008)+2 种基金the Hunan Provincial Science and Technology Department(Grant No.2021JC0005)the Postgraduate Scientific Research Innovation Project of Hunan Province(Grant No.QL20220088)the Shenzhen Undertakes Major National Science and Technology Projects(Grant No.CJGJZD20220517142406015).
文摘In an ultraprecision turning process for small-diameter optical aspheric workpieces,tool-profile errors induce mid-frequency errors in the workpiece profile,limiting further improvements in precision.In this study,an XZB three-axis linkage ultraprecision machining method is proposed,and the effects of tool-center errors are analyzed.To address residual errors in Z-direction profile-error compensation,a workpiece normal-profile-error compensation method is proposed.After XZB three-axis linkage turning and compensation,the workpiece profile error(PV)reaches 0.086μm,surpassing the precision of XZ two-axis machining,and mid-frequency errors are reduced.Compared with Z-direction profile-error compensation,which results in a profile error of 0.092μm,normal-profile-error compensation reduces PV to 0.047μm,considerably improving aspheric accuracy.Experimental results demonstrate that XZB three-axis linkage machining significantly improves the aspheric workpiece profile,enhancing both its accuracy and surface quality.This method reduces mid-frequency errors,and the subsequent application of normal-profile-error compensation further refines the profile,achieving higher overall accuracy.
基金Jiangsu Provincial College Student Innovation and Entrepreneurship Program(Grant No.SJCX25_2184)—“Multi-energy Complementary Optimization and Vehicle-Storage Bidirectional Interaction Technology Driven by Novel 5E Framework”(Principal Investigator:Yuan-Yuan ShiFunding Agency:Jiangsu Provincial Education Department)+3 种基金Huaian Natural Science Research Project(Grant No.HAB2024046)—“Optimal Control of Flexible Cold-Heat-Power Integrated System with Source-Grid-Load-Storage Coordination”(Principal Investigator:Jie JiFunding Agency:Huaian Science and Technology Bureau)Huaiyin Institute of TechnologyUniversity-funded Project(GrantNo.HGYK202511)—“Data-driven CooperativeOptimization Dispatch for Source-Grid-Load Systems”(Principal Investigator:Chu-Tong ZhangFunding Agency:Huaiyin Institute of Technology).
文摘In order to solve the problems of slow dynamic response and difficult multi-source coordination of solar electric vehicle charging stations under intermittent renewable energy,this paper proposes a hardware-algorithm co-design framework:the T-type three-level bidirectional converter(100 kHz switching frequency)based on silicon carbide(SiC)MOSFET is deeply integrated with fuzzy model predictive control(Fuzzy-MPC).At the hardware level,the switching trajectory and resonance suppression circuit(attenuation resonance peak 18 dB)are optimized,and the total loss is reduced by 23%compared with the traditional silicon-based IGBT.At the algorithm level,the adaptive parameter update mechanism and multi-objective rolling optimization are adopted,and the 5 ms level dynamic power allocation is realized by relying on edge computing.Experiments on 800 V DC microgrid(including 600 kW photovoltaic and 150 A·h energy storage)built based on MATLAB/Simulink hardware-in-the-loop(HIL)platform show that the system shortens the battery charging time from 42 to 28 min(the charging speed is increased by 33%).Through the 78%valley power utilization rate,the power purchase cost of high-priced power grids was significantly reduced,and the levelized electricity price decreased by 10.3%;Under the irradiation fluctuation,the renewable energy consumption rate increases by 10.1%,and the DC bus voltage fluctuation is stable within±10 V when the load step is±30%.The co-design provides an economically feasible and dynamically robust solution for the efficient integration of PV-ESG-EV in the smart grid.
基金supported by the National Natural Science Foundation of China[Grant No.71773091]the Graduate Student Science and Technology Innovation Program of College of Economics and Management[Grant No.JGYJSCXXM202308].
文摘The Grassland Ecological Compensation Policy(GECP)is a large-scale project that has been investing in China since 2011.Despite the significant investment and long duration of the GECP,its impact on carbon sequestration in grasslands remains unclear.Based on panel data from prefecture-level cities in the Yellow River Basin(YRB)from 2000 to 2020,this study explored the effects of the GECP on grassland carbon sequestration in the YRB and its heterogeneity using a time-varying difference-in-differences(TV-DID)model.Subsequently,we predicted changes in carbon sequestration in grasslands under the influence of the GECP from 2021 to 2040 using a simulation.The main conclusions are as follows:First,the implementation of the GECP promoted carbon sequestration in grasslands.This conclusion was validated after conducting a series of robustness tests.Moreover,the effects of the GECP were heterogeneous across different geographical locations,highway densities,and grassland areas.Finally,the simulation results indicated that over the next 20 years,grassland carbon sequestration will generally increase but exhibit cyclical changes.The government should align the principles and objectives of the GECP with local geographic conditions,resource availability,and socio-economic development.It must formulate and implement tailored policies that maximize the ecological protection benefits of the GECP and promote carbon sequestration in the grasslands of the YRB.
基金supported by the National Natural Science Foundation of China (52402298, 52172224, 52202228, 22479112)the Science and Technology Correspondent Project of Tianjin(24YDTPJC00240)+3 种基金Science Research Project of Hebei Education Department (BJK2022011)Central Funds Guiding the Local Science and Technology Development of Hebei Province (236Z4404G)the Beijing Tianjin Hebei Basic Research Cooperation Special Project(E2024202273)Tianjin Sci.&Tech. Program (22YFYSHZ00220)
文摘O3-types layered cathode materials in sodium-ion batteries(SIBs)suffer from the obvious lattice distortion induced by the complex phase transitions during Na^(+)intercalation/deintercalation process,leading to severe structural collapse and performance degradation.Herein,a series of high valence tantalum(Ta^(5+))doped Na(Ni_(0.4)Fe_(0.2)Mn_(0.4))_(1−x)Ta_(x)O_(2)(x=0/0.0025/0.005/0.01)secondary spherical particles are firstly developed,where Ta^(5+)doping enables the refined primary grain with a tightly stacked rod-like morphology.Comprehensive structural analysis via Neutron powder diffraction(NPD)and Synchrotron radiation X-ray diffraction(SXRD)reveals an expanded NaO_(2)slab and a reduction in Na site vacancy.The potential charge compensation mechanism is further illustrated by X-ray absorption spectroscopy(XAS)and X-ray photoelectron spectroscopy(XPS),unveiling a partial reduction from Ni^(3+)to Ni^(2+)with Ta^(5+)doping.In situ X-ray diffraction(in situ XRD)suggests that the decorated sample undergoes a volume change as low as 0.8%,in contrast with the pristine one(1.5%).Thus,the optimized sample with x=0.005 retains an enhanced capacity retention up to 70.4%at 1 C after 300 cycles in half-cell and delivers a high energy density of 251 Wh kg^(-1)(0.1 C)and with a good capacity retention of 81.0%at 1 C after 200 cycles in full-cell.Our findings provide new insights into the mechanism of high valence Ta^(5+)doping in stabilizing layered oxides cathode materials for SIBs.
文摘In real industrial microgrids(MGs),the length of the primary delivery feeder to the connection point of the main substation is sometimes long.This reduces the power factor and increases reactive power absorption along the primary delivery feeder from the external network.Besides,the giant induction electro-motors as the working horse of industries requires remarkable amounts of reactive power for electro-mechanical energy conversions.To reduce power losses and operating costs of the MG as well as to improve the voltage quality,this study aims at providing an insightful model for optimal placement and sizing of reactive power compensation capacitors in an industrial MG.In the presented model,the objective function considers voltage profile and network power factor improvement at the MG connection point.Also,it realizes power flow equations within which all operational security constraints are considered.Various reactive power compensation strategies including distributed group compensation,centralized compensation at the main substation,and distributed compensation along the primary delivery feeder are scrutinized.A real industrial MG,say as Urmia Petrochemical plant,is considered in numerical validations.The obtained results in each scenario are discussed in depth.As seen,the best performance is obtained when the optimal location and sizing of capacitors are simultaneously determined at the main buses of the industrial plants,at the main substation of the MG,and alongside the primary delivery feeder.In this way,74.81%improvement in power losses reduction,1.3%lower active power import from the main grid,23.5%improvement in power factor,and 37.5%improvement in network voltage deviation summation are seen in this case compared to the base case.
基金supported by the the National Key R&D Program of China (Grant Nos.2023YFA1606900 and 2022YFA1602301)the National Natural Science Foundation of China (Grant Nos.12235003,12435010,and 12147101)+3 种基金the Guangdong Major Project of Basic and Applied Basic Research (Grant No.2020B0301030008)the STCSM (Grant No.23590780100)the Natural Science Foundation of Shanghai (Grant No.23JC1400200)the China Postdoctoral Science Foundation (Grant No.2024M760483)。
文摘Measuring cross sections of nuclear reactions,such as the so-called“Holy Grail”reaction,^(12)C(σ,γ)^(16)O,is essential for understanding stellar nucleosynthesis but presents significant challenges due to extremely low cross sections.Key challenges include significant energy loss as ions penetrate the target material,limiting measurements to thin target layers.To overcome these obstacles,we propose a novel method,the in-target energy loss compensating(eLOC)method,specifically designed for gas targets,which utilizes a gas-filled magnetic field and accelerating electric fields to compensate for ion energy loss in the target.Simulations show that this approach significantly enhances the effective target thickness by over 140 times in the case of the“Holy Grail”reaction with an inverse-kinematics setup.This eLOC method may provide a powerful new tool for obtaining critical data in nuclear astrophysics,thereby advancing our understanding of stellar nucleosynthesis and the origins of elements in the universe,as well as benefiting other related fields such as isotope production.
基金supported by the Science and Technology Development Project of Jilin Province(Project No.YDZJ202301ZYTS284).
文摘With the increasing penetration of renewable energy,the coordination of energy storage with thermal power for frequency regulation has become an effective means to enhance grid frequency security.Addressing the challenge of improving the frequency regulation performance of a thermal-storage primary frequency regulation system while reducing its associated losses,this paper proposes a multi-dimensional cooperative optimization strategy for the control parameters of a combined thermal-storage system,considering regulation losses.First,the frequency regulation losses of various components within the thermal power unit are quantified,and a calculation method for energy storage regulation loss is proposed,based on Depth of Discharge(DOD)and C-rate.Second,a thermal-storage cooperative control method based on series compensation is developed to improve the system’s frequency regulation performance.Third,targeting system regulation loss cost and regulation output,and considering constraints on output overshoot and system parameters,an improved Particle Swarm Optimization(PSO)algorithm is employed to tune the parameters of the low-pass filter and the series compensator,thereby reducing regulation losses while enhancing performance.Finally,simulation results demonstrate that the total loss cost of the proposed control strategy is comparable to that of a system with only thermal power participation.However,the thermal power loss cost is reduced by 42.16%compared to the thermal-only case,while simultaneously improving system frequency stability.Thus,the proposed strategy effectively balances system frequency stability and economic efficiency.
基金supported by the Spanish Ministry of Economy and Competitiveness (No. ENE2017-84813-R)the CERVERA research program of the Spanish Industrial and Technological Development Centre (CDTI) under the research project HySGrid+(CER-20191019)Junta de Andalucía (No. P18-TP-3655)。
文摘Relieving network congestions is a critical goal for the safe and flexible operation of modern power systems, especially in the presence of intermittent renewables or distributed generation. This paper deals with the real-time coordinated operation of distributed static series compensators(DSSCs) to remove network congestions by suitable modifications of the branch reactance. Several objective functions are considered and discussed to minimize the number of the devices involved in the control actions, the total losses or the total reactive power exchanged, leading to a non-convex mixed-integer non-linear programming problem. Then, a heuristic methodology combining the solution of a regular NLP with k-means clustering algorithm is proposed to get rid of the binary variables, in an attempt to reduce the computational cost. The proposed coordinated operation strategy of the DSSCs is tested on several benchmark systems, providing feasible and sufficiently optimal solutions in a reasonable time frame for practical systems.
