Composite cathodes integrating Ni-rich layered oxides and oxide solid electrolytes are essential for highenergy all-solid-state lithium-ion batteries(ASSLBs),yet interfacial degradation during high-temperature co-sint...Composite cathodes integrating Ni-rich layered oxides and oxide solid electrolytes are essential for highenergy all-solid-state lithium-ion batteries(ASSLBs),yet interfacial degradation during high-temperature co-sintering(>600℃)remains a critical challenge.While surface passivation strategies mitigate reactions below 400℃,their effectiveness diminishes at elevated temperatures due to inability to counteract Li^(+)concentration gradients.Here,we introduce in situ lithium compensators,i.e.,LiOH/Li_(2)CO_(3),into NCM-LATP composite cathodes to dynamically replenish Li^(+)during co-sintering.These additives melt to form transient Li^(+)-rich phases that back-diffuse Li^(+)into NCM lattices,suppressing layered-to-rock salt transitions and stabilizing the interface.Quasi in situ XRD confirms retention of the layered structure at temperature up to 700℃,while electrochemical tests demonstrate a reversible capacity of 222.2 mA h g^(-1)—comparable to NCM before co-sintering—and an impressive 65.3% capacity retention improvement over100 cycles.In contrast,uncompensated cathodes exhibit severe degradation to 96.5 mA h g^(-1)due to Li depletion and resistive Li-Ti-O interphases.This strategy integrates sacrificial chemistry with scalable powder-mixing workflows,achieving a 93.4% reduction in interfacial impedance.By addressing Li^(+)flux homogenization and structural stability,this work provides a practical pathway toward industrialscale fabrication of high-performance ASSLBs.展开更多
为提高提高多机电力系统的暂态稳定性,该文首先建立了静止无功补偿器(static var compensator,SVC)系统的一个含有时变参数不确定性的二阶非线性动态模型,然后在SVC动态模型的基础上,利用自适应控制技术和鲁棒控制技术设计了SVC系统的...为提高提高多机电力系统的暂态稳定性,该文首先建立了静止无功补偿器(static var compensator,SVC)系统的一个含有时变参数不确定性的二阶非线性动态模型,然后在SVC动态模型的基础上,利用自适应控制技术和鲁棒控制技术设计了SVC系统的控制器。为了验证所设计的控制器的有效性,以一个经典的三机九母线电力系统作为测试系统,对鲁棒自适应SVC控制器与PID SVC控制器和反馈线性化SVC控制器分别进行了比较研究。仿真结果表明,与PID SVC控制器和反馈线性化SVC控制器相比,所提出的鲁棒自适应SVC控制器具有良好的性能。展开更多
在电力系统仿真软件DIgSILENT/PowerFactory中建立了静止无功补偿器(static var compensator,SVC)补偿型定速风电机组的模型,分析了其稳态和暂态特性以及由SVC补偿型风电机组组成的风电场对电网的影响,分别采用上述风电机组模型和用电...在电力系统仿真软件DIgSILENT/PowerFactory中建立了静止无功补偿器(static var compensator,SVC)补偿型定速风电机组的模型,分析了其稳态和暂态特性以及由SVC补偿型风电机组组成的风电场对电网的影响,分别采用上述风电机组模型和用电容器组进行补偿的普通定速风电机组模型进行仿真实验,比较结果表明SVC补偿型风电机组具有快速调节无功功率的能力,当系统故障时,该风电机组可快速恢复系统电压,且风电机组启动过程对系统的冲击较小。展开更多
基金financially supported by the National Natural Science Foundation of China(52102206)the Natural Science Foundation of Beijing Municipality-Shunyi Innovation Collaborative Joint Fund(L247018)+2 种基金the Natural Science Foundation of Beijing Municipality(2254076 and 2252024)the Central Guidance on Local Science and Technology Development Fund of Hebei Province(246Z4412G)the Fundamental Research Funds for the Central Universities(2025MS022,North China Electric Power University)。
文摘Composite cathodes integrating Ni-rich layered oxides and oxide solid electrolytes are essential for highenergy all-solid-state lithium-ion batteries(ASSLBs),yet interfacial degradation during high-temperature co-sintering(>600℃)remains a critical challenge.While surface passivation strategies mitigate reactions below 400℃,their effectiveness diminishes at elevated temperatures due to inability to counteract Li^(+)concentration gradients.Here,we introduce in situ lithium compensators,i.e.,LiOH/Li_(2)CO_(3),into NCM-LATP composite cathodes to dynamically replenish Li^(+)during co-sintering.These additives melt to form transient Li^(+)-rich phases that back-diffuse Li^(+)into NCM lattices,suppressing layered-to-rock salt transitions and stabilizing the interface.Quasi in situ XRD confirms retention of the layered structure at temperature up to 700℃,while electrochemical tests demonstrate a reversible capacity of 222.2 mA h g^(-1)—comparable to NCM before co-sintering—and an impressive 65.3% capacity retention improvement over100 cycles.In contrast,uncompensated cathodes exhibit severe degradation to 96.5 mA h g^(-1)due to Li depletion and resistive Li-Ti-O interphases.This strategy integrates sacrificial chemistry with scalable powder-mixing workflows,achieving a 93.4% reduction in interfacial impedance.By addressing Li^(+)flux homogenization and structural stability,this work provides a practical pathway toward industrialscale fabrication of high-performance ASSLBs.
文摘为提高提高多机电力系统的暂态稳定性,该文首先建立了静止无功补偿器(static var compensator,SVC)系统的一个含有时变参数不确定性的二阶非线性动态模型,然后在SVC动态模型的基础上,利用自适应控制技术和鲁棒控制技术设计了SVC系统的控制器。为了验证所设计的控制器的有效性,以一个经典的三机九母线电力系统作为测试系统,对鲁棒自适应SVC控制器与PID SVC控制器和反馈线性化SVC控制器分别进行了比较研究。仿真结果表明,与PID SVC控制器和反馈线性化SVC控制器相比,所提出的鲁棒自适应SVC控制器具有良好的性能。
基金中国风电项目（wind power research and training,CWPP）的资助
文摘在电力系统仿真软件DIgSILENT/PowerFactory中建立了静止无功补偿器(static var compensator,SVC)补偿型定速风电机组的模型,分析了其稳态和暂态特性以及由SVC补偿型风电机组组成的风电场对电网的影响,分别采用上述风电机组模型和用电容器组进行补偿的普通定速风电机组模型进行仿真实验,比较结果表明SVC补偿型风电机组具有快速调节无功功率的能力,当系统故障时,该风电机组可快速恢复系统电压,且风电机组启动过程对系统的冲击较小。
