Color plays an important role in the daily chemical product market,and transparent packaging of daily chemical products are loved by consumers,but it is difficult to avoid fading,discoloration or photodegradation of t...Color plays an important role in the daily chemical product market,and transparent packaging of daily chemical products are loved by consumers,but it is difficult to avoid fading,discoloration or photodegradation of the inner material of the product.UV light is a major contributor to colorant fading,which can affect color stability by damaging chromogenic groups and producing free radicals.In view of this,the combination of four ultraviolet absorbers DHHB,OS,OMC,and MCE was investigated,and the photostability of five common colorants in cosmetics was studied.After 28 days of photostability test,the pigment preservation rate was analyzed,and the results showed that 0.1%of the UV absorber compound could have a certain protective effect on the colorant,and 0.5%of the compound could significantly improve the photostability of the colorant.Adding ultraviolet absorbers to daily chemical products can significantly improve the fading,discoloration or photodegradation of colorants caused by ultraviolet rays.展开更多
With the public’s mature demand in recent times pressurized the textile industry for use of natural colorants,without any harmful effects on environment and aquatic ecosystem,and with more developed functionalities s...With the public’s mature demand in recent times pressurized the textile industry for use of natural colorants,without any harmful effects on environment and aquatic ecosystem,and with more developed functionalities simultaneously.Advanced developments for the natural bio-resources and their sustainable use for multifunctional clothing are gaining pace now.Present review highlights historical overview of natural colorants,classification and predominantly processing of colorants from sources,application on textiles surfaces with the functionalities provided by them.Chemistry of natural colorants on textiles also discussed with relevance to adsorption isotherms and kinetic models for dyeing of textiles.展开更多
In this work,the nano-g-C_(3)N_(4)/Ui O-66-NH_(2)composite was prepared by one-step solvothermal method.The as-prepared composite was characterized by scanning electron microscopy,Brunner-Emmet-Teller measurement,ener...In this work,the nano-g-C_(3)N_(4)/Ui O-66-NH_(2)composite was prepared by one-step solvothermal method.The as-prepared composite was characterized by scanning electron microscopy,Brunner-Emmet-Teller measurement,energy dispersive spectrometer,X-ray diffraction,and Fourier transform infrared spectroscopy.By using nano-g-C_(3)N_(4)/Ui O-66-NH_(2)composite as sorbent,a dispersive solid-phase extraction coupled with high-performance liquid chromatography was developed to sensitive analysis of food colorants including tartrazine,amaranth,carmine,sunset yellow,allura red and bright blue.The experiment parameters including the amount of sorbent,adsorption time,the p H of adsorption solution,desorption time,desorption solvent,the p H of desorption solution as well as the proportion between desorption solvent and buffer solvent were investigated.Under the optimized conditions,the limits of detection(S/N=3) and limits of quantitation (S/N=10) were determined in the ranges of 0.08-0.8 and 0.2-2.0 ng/m L,respectively.With the developed sample pretreatment method,carmine and brilliant blue were determined from blueberry juice by HPLC-DAD.The contents were calculated as 1.53μg/m L and0.17μg/mL,respectively.展开更多
In order to improve appetite,attract consumers and even conform to the food culture,food coloring has become one of the necessary links in modern food processing.For example,dried-tofu will be colored by adding artifi...In order to improve appetite,attract consumers and even conform to the food culture,food coloring has become one of the necessary links in modern food processing.For example,dried-tofu will be colored by adding artificial food colors(AFCs)such as sunset yellow,cochineal red A or other seasonings like soy sauce.However,the dispute persists about whether AFCs are harmful to health.Some studies indicate AFCs affect children’s intelligence and attention,cause hyperactivity,and allergy when children consumed≥50 mg.In addition,researches showed that chemical soy sauce produces a trace of methylglyoxal(MGO)in the manufacturing process,which is related to diseases such as oxidative stress,diabetes,and cognitive deterioration.Therefore,natural pigments are relatively new and promising strategy for replacing high-risk AFCs.Thus,the objective of this study was to use dried-tofu as a natural colorants coloring screening platform,through the concept of three primary colors to discuss the coloring effects of natural colorants in Taiwan in double–phase(liquid phase to solid phase)food coloring system and assess the effects of MGO on PC12 neuron cellular morphology and cell cycle at the dietary exposure in soy sauce.Our results showed that formula G:R=0.2:0.8 and C:R=0.08:0.92 were coloring by combined natural colorants had the same eye sensory quality acceptance of consumer and had the intention to purchase.Furthermore,the results from the PC12 cell suggested that dietary exposure of methylglyoxal(<50M)in soy sauce did not affect neuron cellular morphology and cell cycle significantly.Overall,Gardenia Yellow,Curcumin,and Radish Red could overcome the application restrictions in multiplephase food coloring system and simultaneously soy sauce as a coloring agent was safety.It showed the possibility of them as food colorants on dried-tofu.展开更多
A study was conducted to evaluate the genotoxicity, if any, of the permitted synthetic food colorants used in India. Eight synthetic food colorants namely Erythrosine （E 127）, Tartrazine （E 102）, Ponceau 4R （E 12...A study was conducted to evaluate the genotoxicity, if any, of the permitted synthetic food colorants used in India. Eight synthetic food colorants namely Erythrosine （E 127）, Tartrazine （E 102）, Ponceau 4R （E 124）, Sunset Yellow FCF （E 110）, Brilliant Blue FCF （E133）, Fast Green FCF （E143）, Carmoisine （E122） and Indigo Carmine （E132） and their combination are used in sweets namely Ladu, Jilebi and Halwa in Calicut and suburban areas of Kerala, in India. The genotoxicity of the colorants alone and in combinations at different concentrations were evaluated by Cytokinesis Block Micronucleus （CBMN） Assay. It was observed that all the above colorants and their combinations could cause genotoxicity to human lymphocytes even at the permissible concentration of 100 ppm as per PFA （Prevention of Food Adulteration） Act of India. The toxicity varied from dye to dye and was proportional to their concentration. Combination of colors showed more toxicity than the individual components. Toxicity could be reduced drastically by reducing the concentration of the dyes at least 50% below the permissible limit. Permitted synthetic food colorants even at the permissible limit should be used with caution. This study demonstrated the need for redefining the permissible limit of the food colorants based on Admissible Daily Intake （ADI） as being practiced in developed countries.展开更多
Natural pigments and colorants are widely used in the world in many industries such as textile dying,food processing or cosmetic manufacturing.Among the natural products of interest are various compounds belonging to ...Natural pigments and colorants are widely used in the world in many industries such as textile dying,food processing or cosmetic manufacturing.Among the natural products of interest are various compounds belonging to carotenoids,anthocyanins,chlorophylls,melanins,betalains...The review emphasizes pigments with anthraquinoid skeleton and gives an overview on hydroxyanthraquinoids described in Nature,the first one ever published.Trends in consumption,production and regulation of natural food grade colorants are given,in the current global market.The second part focuses on the description of the chemical structures of the main anthraquinoid colouring compounds,their properties and their biosynthetic pathways.Main natural sources of such pigments are summarized,followed by discussion about toxicity and carcinogenicity observed in some cases.As a conclusion,current industrial applications of natural hydroxyanthraquinoids are described with two examples,carminic acid from an insect and Arpink red^(™)from a filamentous fungus.展开更多
The effects of three organic colorants on photo-initiated crosslinking and photo-oxidation degradation of polyethylene (PE) samples irradiated by microwave excited (MWE) UV lamp in the melt and the related mechanism h...The effects of three organic colorants on photo-initiated crosslinking and photo-oxidation degradation of polyethylene (PE) samples irradiated by microwave excited (MWE) UV lamp in the melt and the related mechanism have been studied by gel content and thermal extension rate determinations,X-ray photoelectron spectroscopy (XPS),mechanical property tests,UV spectroscopy,and light microscope.The data from the gel content and thermal extension rate determinations of photo-crosslinked polyethylene (XLPE) sample...展开更多
Food colorants are widely used in the food industry to maintain or enhance product color. However, as the use of these colorants can have negative impacts on health, it is essential to analyze the risks associated wit...Food colorants are widely used in the food industry to maintain or enhance product color. However, as the use of these colorants can have negative impacts on health, it is essential to analyze the risks associated with their consumption. This analysis requires, among other things, obtaining sufficient data on the presence of these colorants in foods, as well as their level of consumption. However, data on these colorants is often virtually non-existent in developing countries. The aim of this study was to determine the colorant profile of industrial products marketed in Senegal. Information on food additives was collected on 399 labels of different food product categories in shops located in Dakar. Data is recorded and processed using Excel software. Based on the Codex classification, analysis of the profile of additives identified on the labels of food samples revealed the presence of 31 colorants. The natural colorants identified are dominated by beta-carotene, widely present in beverages and dairy products, and paprika extract identified on cookies and industrial sauces. Artificial colors are dominated caramels present in several foods including bouillons, vinegars, sauces and hard candies. Secondly, there was a strong presence of the azo dye Sunset yellow FCF, widely found in samples of beverages, confectionery and cookies. The results of this case study enable us to appreciate the wide presence and diversity of colorants on the Senegalese market, and the importance of controlling them to guarantee consumer safety.展开更多
Nontoxic colorant from rare earths is expected to be put into full production in the current year in Baotou, the biggest city in the Inner Mongolia autonomous region, following a decision by the local government to up...Nontoxic colorant from rare earths is expected to be put into full production in the current year in Baotou, the biggest city in the Inner Mongolia autonomous region, following a decision by the local government to upgrade the rare earths industry to value-added processes against previously mining the raw materials. "Due to its perfect coloring and nontoxic properties the coloring agent, mainly for plastics and leathers, can replace most existing dyes in the market," said Zhang Hongjie, inventor of the colorant and member of the Chinese Academy of Sciences.展开更多
Ancellotta and Aspirant Bouchet,Vitis vinifera L.,are wines with a high anthocyanin concentration that have been used to increase color in high-quality red wines.This work was focused on the encapsulation of Ancellott...Ancellotta and Aspirant Bouchet,Vitis vinifera L.,are wines with a high anthocyanin concentration that have been used to increase color in high-quality red wines.This work was focused on the encapsulation of Ancellotta(ANCE)and Aspirant Bouchet(AB)wines by spray drying and obtaining wine powders(WP)with a high concentration of phenolic compounds.Spray drying conditions were optimized and the phenolic compounds in the WP were characterized.All WP were evaluated for moisture content,water activity,color parameters,anthocyanins,and flavan-3-ols composition.There was no significant difference in total anthocyanins content of ANCE and AB WP when inlet air temperature increased from 135 to 145°C with a fixed carrier concentration of 8%(w/w)but a decrease in the total anthocyanins was observed when carrier concentration increased to 10%(w/w).Regarding color evaluation,ANCE and AB WP corresponded to the fourth quadrant of color space CIELAB indicating blue-red color(348–357°),characteristic of anthocyanins and wine.In general,the values of hue angle were not affected at higher percentages of carrier agent,consequently,an increase in the ratio carrier-wine did not lead to a dilution of material.These results indicate that inlet air temperature(in the selected range)did not influence the anthocyanin profile in the WP and has allowed for optimization of the conditions to obtain phenolic-rich colored powders with potential use as natural antioxidants and food colorants.展开更多
A t-tone coloring of a graph assigns t distinct colors to each vertex with vertices at distance d having fewer than d colors in common.The t-tone chromatic number of a graph is the smallest number of colors used in al...A t-tone coloring of a graph assigns t distinct colors to each vertex with vertices at distance d having fewer than d colors in common.The t-tone chromatic number of a graph is the smallest number of colors used in all t-tone colorings of that graph.In this article,we study t-tone coloring of some finite planar lattices and obtain exact formulas for their t-tone chromatic number.展开更多
Natural pigments are widely utilized as food additives nowadays to impart color or improve the taste of the food products.These pigments are significant food compounds used in the food industry due to their diverse nu...Natural pigments are widely utilized as food additives nowadays to impart color or improve the taste of the food products.These pigments are significant food compounds used in the food industry due to their diverse nutritional and functional attributes.Color is the essential part of any food as it affects the consumer acceptability of the products.Recently consumer interest has shifted towards natural pigments as food colorants due to their high safety margins.Food industries prefer the use of natural pigments for foods and drinks owing to the harmful and undesirable effects of artificial pigments.These pigments include betalains-betaxanthin,betacyanin,flavonoids-anthocyanins,carotenoids-lutein,zeaxanthin,β-carotene,and chlorophylls-chlorophyllins,etc.There are some restrictions associated with the use of natural pigments based on the source of the pigment,quantity,and product nature.This review illustrates applications of permitted pigments in diversified food models and highlights their advantages as food ingredients.展开更多
It is of great scientific significance to construct a 3D dynamic structural color with a special color effect based on the microlens array.However,the problems of imperfect mechanisms and poor color quality need to be...It is of great scientific significance to construct a 3D dynamic structural color with a special color effect based on the microlens array.However,the problems of imperfect mechanisms and poor color quality need to be solved.A method of 3D structural color turning on periodic metasurfaces fabricated by the microlens array and self-assembly technology was proposed in this study.In the experiment,Polydimethylsiloxane(PDMS)flexible film was used as a substrate,and SiO2 microspheres were scraped into grooves of the PDMS film to form 3D photonic crystal structures.By adjusting the number of blade-coated times and microsphere concentrations,high-saturation structural color micropatterns were obtained.These films were then matched with microlens arrays to produce dynamic graphics with iridescent effects.The results showed that by blade-coated two times and SiO2 microsphere concentrations of 50%are the best conditions.This method demonstrates the potential for being widely applied in the anticounterfeiting printing and ultra-high-resolution display.展开更多
Pepper(Capsicum annuum L.)is a typical self-pollinating crop with obvious heterosis in hybrids.Consequently,the use of morphological markers during the pepper seedling stage is crucial for pepper breeding.The color of...Pepper(Capsicum annuum L.)is a typical self-pollinating crop with obvious heterosis in hybrids.Consequently,the use of morphological markers during the pepper seedling stage is crucial for pepper breeding.The color of hypocotyl is widely used as a phenotypic marker in crossing studies of pepper.Pepper accessions generally have purple hypocotyls,which are mainly due to the anthocyanin accumulation in seedlings,and green hypocotyls are rarely observed in pepper.Here we reported the characterization of a green hypocotyl mutant of pepper,Cha1,which was identified from a pepper ethyl methanesulfonate(EMS)mutant library.Fine mapping revealed that the causal gene,CaTTG1,belonging to the WD40 repeat family,controlled the green hypocotyl phenotype of the mutant.Virus-induced gene silencing(VIGS)confirmed that CaTTG1 regulated anthocyanin accumulation.RNA-seq data showed that expression of structural genes CaDFR,CaANS,and CaUF3GT in the anthocyanin biosynthetic pathway was significantly decreased in Cha1 compared to the wild type.Yeast two-hybrid(Y2H)experiments also confirmed that CaTTG1 activated the synthesis of anthocyanin structural genes by forming a MBW complex with CaAN1 and CaGL3.In summary,this study provided a green hypocotyl mutant of pepper,and the Kompetitive Allele Specific PCR(KASP)marker developed based on the mutation site of the underlying gene would be helpful for pepper breeding.展开更多
Super-fine electrohydrodynamic inkjet(SIJ)printing of perovskite nanocrystal(PNC)colloid ink exhibits significant potential in the fabrication of high-resolution color conversion microstructures arrays for fullcolor m...Super-fine electrohydrodynamic inkjet(SIJ)printing of perovskite nanocrystal(PNC)colloid ink exhibits significant potential in the fabrication of high-resolution color conversion microstructures arrays for fullcolor micro-LED displays.However,the impact of solvent on both the printing process and the morphology of SIJ-printed PNC color conversion microstructures remains underexplored.In this study,we prepared samples of CsPbBr3PNC colloid inks in various solvents and investigated the solvent's impact on SIJ printed PNC microstructures.Our findings reveal that the boiling point of the solvent is crucial to the SIJ printing process of PNC colloid inks.Only does the boiling point of the solvent fall in the optimal range,the regular positioned,micron-scaled,conical PNC microstructures can be successfully printed.Below this optimal range,the ink is unable to be ejected from the nozzle;while above this range,irregular positioned microstructures with nanoscale height and coffee-ring-like morphology are produced.Based on these observations,high-resolution color conversion PNC microstructures were effectively prepared using SIJ printing of PNC colloid ink dispersed in dimethylbenzene solvent.展开更多
Full-color imaging is essential in digital pathology for accurate tissue analysis.Utilizing advanced optical modulation and phase retrieval algorithms,Fourier ptychographic microscopy(FPM)offers a powerful solution fo...Full-color imaging is essential in digital pathology for accurate tissue analysis.Utilizing advanced optical modulation and phase retrieval algorithms,Fourier ptychographic microscopy(FPM)offers a powerful solution for high-throughput digital pathology,combining high resolution,large field of view,and extended depth of field(DOF).However,the full-color capabilities of FPM are hindered by coherent color artifacts and reduced computational efficiency,which significantly limits its practical applications.Color-transferbased FPM(CFPM)has emerged as a potential solution,theoretically reducing both acquisition and reconstruction threefold time.Yet,existing methods fall short of achieving the desired reconstruction speed and colorization quality.In this study,we report a generalized dual-color-space constrained model for FPM colorization.This model provides a mathematical framework for model-based FPM colorization,enabling a closed-form solution without the need for redundant iterative calculations.Our approach,termed generalized CFPM(gCFPM),achieves colorization within seconds for megapixel-scale images,delivering superior colorization quality in terms of both colorfulness and sharpness,along with an extended DOF.Both simulations and experiments demonstrate that gCFPM surpasses state-of-the-art methods across all evaluated criteria.Our work offers a robust and comprehensive workflow for high-throughput full-color pathological imaging using FPM platforms,laying a solid foundation for future advancements in methodology and engineering.展开更多
A laser-induced periodic surface structure(LIPSS),which can be easily produced by femtosecond laser ablation,is a unique nanostructure with a visible refractive color that can be controlled by altering its orientation...A laser-induced periodic surface structure(LIPSS),which can be easily produced by femtosecond laser ablation,is a unique nanostructure with a visible refractive color that can be controlled by altering its orientation and uniformity,making it suitable for use in colorful marking,camouflage,and anticounterfeiting measures.However,single-mode information camouflage can no longer meet increasingly higher-level security requirements.Therefore,metasurfaces offer revolutionary solutions.In this study,conceptual metasurfaces of pure tungsten are theoretically proposed and verified using hierarchical LIPSS/nanoparticle(NP)nanostructures as meta-atoms.The anisotropy of the LIPSS nanostructure enables polarization-sensitive optical modulation,whereas the spatial configuration,NPs size,and period of LIPSS in the LIPSS/NP meta-atoms provide flexibility for tailoring broadband optical responses.In xpolarization,the LIPSS/NP meta-atom system provides more visible colors and divergent infrared absorption(emission)than in y-polarized and unpolarized modes,paving the way for vividly colorful polarization-sensitive displays and information camouflage in infrared bands.A simplified rendition of the world-famous painting“The Starry Night”by Van Gogh is used as a proof-of-concept.Preliminary experimental results are presented,based on which the feasibility and challenges for laser nanomanufacturing of the proposed conceptual metasurfaces are discussed,aiming to provide inspiration for the development of novel metasurfaces through interdisciplinary studies.展开更多
Peel color is an important appearance quality of melons that significantly affects consumer preferences.In this study,a near-isogenic line NIL-G(dark green peel)was generated from B8(grey-green peel)and B15(white peel...Peel color is an important appearance quality of melons that significantly affects consumer preferences.In this study,a near-isogenic line NIL-G(dark green peel)was generated from B8(grey-green peel)and B15(white peel).The F_2 population constructed by crossing NIL-G and B15 was used to study the inheritance pattern of peel color,and bulked-segregant analysis sequencing(BSA-seq)was employed to identify the interval in which the target gene was located.Genetic analysis showed that a dominant gene controls the dark green peel trait at maturity.BSAseq and molecular markers were used to localize the candidate gene in a 263.7 kb interval of chromosome 4,which contained the CmAPRR2 gene with known functions.Moreover,allelic sequence analysis revealed four SNP variations of the CmAPRR2 gene in B15,of which SNP.G614331A was located at the junction of the 6th exon and 6th intron.The G-to-A mutation caused alternative splicing of the transcript of CmAPRR2 in B15,generating two transcripts(CmAPRR2-A and CmAPRR2-B)with premature termination codons.Furthermore,the Kompetitive Allele Specific PCR(KASP)marker,APRR2-G/A,was developed based on this SNP and shown to co-segregate with the peel color phenotype in the F_(2) population.Compared to white-peel B15,the expression level of CmAPRR2 in dark green peel NIL-G was higher at each growth stage.Therefore,CmAPRR2 may be the key gene controlling the fruit color of melons.This study identified a novel allelic variant of CmAPRR2 that leads to white peel formation in mature melons.We also provides a theoretical basis for further research on the gene regulatory mechanism of melon peel colors,which promotes using molecular marker-assisted selection to modify melon peel colors in the future.展开更多
Textile dyeing is a significant reason of colored wastewater.If this wastewater is discharged directly into natural water sources,it can be detrimental to the ecosystem.Supercritical anhydrous dyeing technology provid...Textile dyeing is a significant reason of colored wastewater.If this wastewater is discharged directly into natural water sources,it can be detrimental to the ecosystem.Supercritical anhydrous dyeing technology provides a solution to this challenge.Supercritical fluids possess both liquid and gaseous properties,enabling them to dissolve materials and penetrate substances.展开更多
Cholesteric liquid crystals(CLCs)exhibit unique helical superstructures that selectively reflect circularly polarized light,enabling them to dynamically respond to environmental changes with tunable structural colors....Cholesteric liquid crystals(CLCs)exhibit unique helical superstructures that selectively reflect circularly polarized light,enabling them to dynamically respond to environmental changes with tunable structural colors.This dynamic color-changing capability is crucial for applications that require adaptable optical properties,positioning CLCs as key materials in advanced photonic technologies.This review focuses on the mechanisms of dynamic color tuning in CLCs across various forms,including small molecules,cholesteric liquid crystal elastomers(CLCEs),and cholesteric liquid crystal networks(CLCNs),and emphasizes the distinct responsive coloration each structure provides.Key developments in photochromic mechanisms based on azobenzene,dithienylethene,and molecular motor switches,are discussed for their roles in enhancing the stability and tuning range of CLCs.We examine the color-changing behaviors of CLCEs under mechanical stimuli and CLCNs under swelling,highlighting the advantages of each form.Following this,applications of dynamic color-tuning CLCs in information encryption,adaptive camouflage,and smart sensing technologies are explored.The review concludes with an outlook on current challenges and future directions in CLC research,particularly in biomimetic systems and dynamic photonic devices,aiming to broaden their functional applications and impact.展开更多
文摘Color plays an important role in the daily chemical product market,and transparent packaging of daily chemical products are loved by consumers,but it is difficult to avoid fading,discoloration or photodegradation of the inner material of the product.UV light is a major contributor to colorant fading,which can affect color stability by damaging chromogenic groups and producing free radicals.In view of this,the combination of four ultraviolet absorbers DHHB,OS,OMC,and MCE was investigated,and the photostability of five common colorants in cosmetics was studied.After 28 days of photostability test,the pigment preservation rate was analyzed,and the results showed that 0.1%of the UV absorber compound could have a certain protective effect on the colorant,and 0.5%of the compound could significantly improve the photostability of the colorant.Adding ultraviolet absorbers to daily chemical products can significantly improve the fading,discoloration or photodegradation of colorants caused by ultraviolet rays.
文摘With the public’s mature demand in recent times pressurized the textile industry for use of natural colorants,without any harmful effects on environment and aquatic ecosystem,and with more developed functionalities simultaneously.Advanced developments for the natural bio-resources and their sustainable use for multifunctional clothing are gaining pace now.Present review highlights historical overview of natural colorants,classification and predominantly processing of colorants from sources,application on textiles surfaces with the functionalities provided by them.Chemistry of natural colorants on textiles also discussed with relevance to adsorption isotherms and kinetic models for dyeing of textiles.
基金sponsored by the National Nature Science Foundation of China (No.22076038)Natural Science Foundation of Henan (No.202300410044)。
文摘In this work,the nano-g-C_(3)N_(4)/Ui O-66-NH_(2)composite was prepared by one-step solvothermal method.The as-prepared composite was characterized by scanning electron microscopy,Brunner-Emmet-Teller measurement,energy dispersive spectrometer,X-ray diffraction,and Fourier transform infrared spectroscopy.By using nano-g-C_(3)N_(4)/Ui O-66-NH_(2)composite as sorbent,a dispersive solid-phase extraction coupled with high-performance liquid chromatography was developed to sensitive analysis of food colorants including tartrazine,amaranth,carmine,sunset yellow,allura red and bright blue.The experiment parameters including the amount of sorbent,adsorption time,the p H of adsorption solution,desorption time,desorption solvent,the p H of desorption solution as well as the proportion between desorption solvent and buffer solvent were investigated.Under the optimized conditions,the limits of detection(S/N=3) and limits of quantitation (S/N=10) were determined in the ranges of 0.08-0.8 and 0.2-2.0 ng/m L,respectively.With the developed sample pretreatment method,carmine and brilliant blue were determined from blueberry juice by HPLC-DAD.The contents were calculated as 1.53μg/m L and0.17μg/mL,respectively.
基金This study was supportedby the Ministry of Science and Technology[105-2320-B-002-031-MY3,105-2628-B-002-003-MY3].
文摘In order to improve appetite,attract consumers and even conform to the food culture,food coloring has become one of the necessary links in modern food processing.For example,dried-tofu will be colored by adding artificial food colors(AFCs)such as sunset yellow,cochineal red A or other seasonings like soy sauce.However,the dispute persists about whether AFCs are harmful to health.Some studies indicate AFCs affect children’s intelligence and attention,cause hyperactivity,and allergy when children consumed≥50 mg.In addition,researches showed that chemical soy sauce produces a trace of methylglyoxal(MGO)in the manufacturing process,which is related to diseases such as oxidative stress,diabetes,and cognitive deterioration.Therefore,natural pigments are relatively new and promising strategy for replacing high-risk AFCs.Thus,the objective of this study was to use dried-tofu as a natural colorants coloring screening platform,through the concept of three primary colors to discuss the coloring effects of natural colorants in Taiwan in double–phase(liquid phase to solid phase)food coloring system and assess the effects of MGO on PC12 neuron cellular morphology and cell cycle at the dietary exposure in soy sauce.Our results showed that formula G:R=0.2:0.8 and C:R=0.08:0.92 were coloring by combined natural colorants had the same eye sensory quality acceptance of consumer and had the intention to purchase.Furthermore,the results from the PC12 cell suggested that dietary exposure of methylglyoxal(<50M)in soy sauce did not affect neuron cellular morphology and cell cycle significantly.Overall,Gardenia Yellow,Curcumin,and Radish Red could overcome the application restrictions in multiplephase food coloring system and simultaneously soy sauce as a coloring agent was safety.It showed the possibility of them as food colorants on dried-tofu.
文摘A study was conducted to evaluate the genotoxicity, if any, of the permitted synthetic food colorants used in India. Eight synthetic food colorants namely Erythrosine （E 127）, Tartrazine （E 102）, Ponceau 4R （E 124）, Sunset Yellow FCF （E 110）, Brilliant Blue FCF （E133）, Fast Green FCF （E143）, Carmoisine （E122） and Indigo Carmine （E132） and their combination are used in sweets namely Ladu, Jilebi and Halwa in Calicut and suburban areas of Kerala, in India. The genotoxicity of the colorants alone and in combinations at different concentrations were evaluated by Cytokinesis Block Micronucleus （CBMN） Assay. It was observed that all the above colorants and their combinations could cause genotoxicity to human lymphocytes even at the permissible concentration of 100 ppm as per PFA （Prevention of Food Adulteration） Act of India. The toxicity varied from dye to dye and was proportional to their concentration. Combination of colors showed more toxicity than the individual components. Toxicity could be reduced drastically by reducing the concentration of the dyes at least 50% below the permissible limit. Permitted synthetic food colorants even at the permissible limit should be used with caution. This study demonstrated the need for redefining the permissible limit of the food colorants based on Admissible Daily Intake （ADI） as being practiced in developed countries.
文摘Natural pigments and colorants are widely used in the world in many industries such as textile dying,food processing or cosmetic manufacturing.Among the natural products of interest are various compounds belonging to carotenoids,anthocyanins,chlorophylls,melanins,betalains...The review emphasizes pigments with anthraquinoid skeleton and gives an overview on hydroxyanthraquinoids described in Nature,the first one ever published.Trends in consumption,production and regulation of natural food grade colorants are given,in the current global market.The second part focuses on the description of the chemical structures of the main anthraquinoid colouring compounds,their properties and their biosynthetic pathways.Main natural sources of such pigments are summarized,followed by discussion about toxicity and carcinogenicity observed in some cases.As a conclusion,current industrial applications of natural hydroxyanthraquinoids are described with two examples,carminic acid from an insect and Arpink red^(™)from a filamentous fungus.
基金the National Natural Science Foundation of China (No.20704040).
文摘The effects of three organic colorants on photo-initiated crosslinking and photo-oxidation degradation of polyethylene (PE) samples irradiated by microwave excited (MWE) UV lamp in the melt and the related mechanism have been studied by gel content and thermal extension rate determinations,X-ray photoelectron spectroscopy (XPS),mechanical property tests,UV spectroscopy,and light microscope.The data from the gel content and thermal extension rate determinations of photo-crosslinked polyethylene (XLPE) sample...
文摘Food colorants are widely used in the food industry to maintain or enhance product color. However, as the use of these colorants can have negative impacts on health, it is essential to analyze the risks associated with their consumption. This analysis requires, among other things, obtaining sufficient data on the presence of these colorants in foods, as well as their level of consumption. However, data on these colorants is often virtually non-existent in developing countries. The aim of this study was to determine the colorant profile of industrial products marketed in Senegal. Information on food additives was collected on 399 labels of different food product categories in shops located in Dakar. Data is recorded and processed using Excel software. Based on the Codex classification, analysis of the profile of additives identified on the labels of food samples revealed the presence of 31 colorants. The natural colorants identified are dominated by beta-carotene, widely present in beverages and dairy products, and paprika extract identified on cookies and industrial sauces. Artificial colors are dominated caramels present in several foods including bouillons, vinegars, sauces and hard candies. Secondly, there was a strong presence of the azo dye Sunset yellow FCF, widely found in samples of beverages, confectionery and cookies. The results of this case study enable us to appreciate the wide presence and diversity of colorants on the Senegalese market, and the importance of controlling them to guarantee consumer safety.
文摘Nontoxic colorant from rare earths is expected to be put into full production in the current year in Baotou, the biggest city in the Inner Mongolia autonomous region, following a decision by the local government to upgrade the rare earths industry to value-added processes against previously mining the raw materials. "Due to its perfect coloring and nontoxic properties the coloring agent, mainly for plastics and leathers, can replace most existing dyes in the market," said Zhang Hongjie, inventor of the colorant and member of the Chinese Academy of Sciences.
基金supported in Spain by the Spanish Ministry of Economy and Competitiveness(MINECO,project ref PID2021-127126OB-C21 cofounded by FEDER)by Junta de Castilla y Le´on-FEDER Programme(project ref SA0093P20)+2 种基金We also thank Junta de Castilla y Le´on-FEDER Programme for the Strategic Research Programs for Units of Excellence(Escalera de Excelencia CLU-2O18-04)This work was supported in Argentina by Facultad de Ingeniería y Ciencias Agrarias,Pontificia Universidad Cat´olica ArgentinaEstaci´on Experimental Agropecuaria Mendoza,Instituto Nacional de Tecnología Agropecuaria(EEA Mendoza INTA).
文摘Ancellotta and Aspirant Bouchet,Vitis vinifera L.,are wines with a high anthocyanin concentration that have been used to increase color in high-quality red wines.This work was focused on the encapsulation of Ancellotta(ANCE)and Aspirant Bouchet(AB)wines by spray drying and obtaining wine powders(WP)with a high concentration of phenolic compounds.Spray drying conditions were optimized and the phenolic compounds in the WP were characterized.All WP were evaluated for moisture content,water activity,color parameters,anthocyanins,and flavan-3-ols composition.There was no significant difference in total anthocyanins content of ANCE and AB WP when inlet air temperature increased from 135 to 145°C with a fixed carrier concentration of 8%(w/w)but a decrease in the total anthocyanins was observed when carrier concentration increased to 10%(w/w).Regarding color evaluation,ANCE and AB WP corresponded to the fourth quadrant of color space CIELAB indicating blue-red color(348–357°),characteristic of anthocyanins and wine.In general,the values of hue angle were not affected at higher percentages of carrier agent,consequently,an increase in the ratio carrier-wine did not lead to a dilution of material.These results indicate that inlet air temperature(in the selected range)did not influence the anthocyanin profile in the WP and has allowed for optimization of the conditions to obtain phenolic-rich colored powders with potential use as natural antioxidants and food colorants.
基金Supported by the National Natural Science Foundation of China(Grant No.12271210)the Scientific Research Foundation of Jimei University(Grant No.Q202201).
文摘A t-tone coloring of a graph assigns t distinct colors to each vertex with vertices at distance d having fewer than d colors in common.The t-tone chromatic number of a graph is the smallest number of colors used in all t-tone colorings of that graph.In this article,we study t-tone coloring of some finite planar lattices and obtain exact formulas for their t-tone chromatic number.
文摘Natural pigments are widely utilized as food additives nowadays to impart color or improve the taste of the food products.These pigments are significant food compounds used in the food industry due to their diverse nutritional and functional attributes.Color is the essential part of any food as it affects the consumer acceptability of the products.Recently consumer interest has shifted towards natural pigments as food colorants due to their high safety margins.Food industries prefer the use of natural pigments for foods and drinks owing to the harmful and undesirable effects of artificial pigments.These pigments include betalains-betaxanthin,betacyanin,flavonoids-anthocyanins,carotenoids-lutein,zeaxanthin,β-carotene,and chlorophylls-chlorophyllins,etc.There are some restrictions associated with the use of natural pigments based on the source of the pigment,quantity,and product nature.This review illustrates applications of permitted pigments in diversified food models and highlights their advantages as food ingredients.
文摘It is of great scientific significance to construct a 3D dynamic structural color with a special color effect based on the microlens array.However,the problems of imperfect mechanisms and poor color quality need to be solved.A method of 3D structural color turning on periodic metasurfaces fabricated by the microlens array and self-assembly technology was proposed in this study.In the experiment,Polydimethylsiloxane(PDMS)flexible film was used as a substrate,and SiO2 microspheres were scraped into grooves of the PDMS film to form 3D photonic crystal structures.By adjusting the number of blade-coated times and microsphere concentrations,high-saturation structural color micropatterns were obtained.These films were then matched with microlens arrays to produce dynamic graphics with iridescent effects.The results showed that by blade-coated two times and SiO2 microsphere concentrations of 50%are the best conditions.This method demonstrates the potential for being widely applied in the anticounterfeiting printing and ultra-high-resolution display.
基金supported by grants from the Special Funds for Construction of Innovative Provinces in Hunan Province(Grant No.2021NK1006)the Science and Technology Innovation Program of Hunan Province(Grant No.2021JC0007)+2 种基金China Agriculture Research System of MOF and MARA(Grant No.CARS-24-A-15)National Natural Science Foundation of China(Grant No.32130097)National Natural Science Foundation of China(Grant No.U19A2028)。
文摘Pepper(Capsicum annuum L.)is a typical self-pollinating crop with obvious heterosis in hybrids.Consequently,the use of morphological markers during the pepper seedling stage is crucial for pepper breeding.The color of hypocotyl is widely used as a phenotypic marker in crossing studies of pepper.Pepper accessions generally have purple hypocotyls,which are mainly due to the anthocyanin accumulation in seedlings,and green hypocotyls are rarely observed in pepper.Here we reported the characterization of a green hypocotyl mutant of pepper,Cha1,which was identified from a pepper ethyl methanesulfonate(EMS)mutant library.Fine mapping revealed that the causal gene,CaTTG1,belonging to the WD40 repeat family,controlled the green hypocotyl phenotype of the mutant.Virus-induced gene silencing(VIGS)confirmed that CaTTG1 regulated anthocyanin accumulation.RNA-seq data showed that expression of structural genes CaDFR,CaANS,and CaUF3GT in the anthocyanin biosynthetic pathway was significantly decreased in Cha1 compared to the wild type.Yeast two-hybrid(Y2H)experiments also confirmed that CaTTG1 activated the synthesis of anthocyanin structural genes by forming a MBW complex with CaAN1 and CaGL3.In summary,this study provided a green hypocotyl mutant of pepper,and the Kompetitive Allele Specific PCR(KASP)marker developed based on the mutation site of the underlying gene would be helpful for pepper breeding.
基金supported by the National Natural Science Foundation of China(No.62374142)Fundamental Research Funds for the Central Universities(Nos.20720220085 and 20720240064)+2 种基金External Cooperation Program of Fujian(No.2022I0004)Major Science and Technology Project of Xiamen in China(No.3502Z20191015)Xiamen Natural Science Foundation Youth Project(No.3502Z202471002)。
文摘Super-fine electrohydrodynamic inkjet(SIJ)printing of perovskite nanocrystal(PNC)colloid ink exhibits significant potential in the fabrication of high-resolution color conversion microstructures arrays for fullcolor micro-LED displays.However,the impact of solvent on both the printing process and the morphology of SIJ-printed PNC color conversion microstructures remains underexplored.In this study,we prepared samples of CsPbBr3PNC colloid inks in various solvents and investigated the solvent's impact on SIJ printed PNC microstructures.Our findings reveal that the boiling point of the solvent is crucial to the SIJ printing process of PNC colloid inks.Only does the boiling point of the solvent fall in the optimal range,the regular positioned,micron-scaled,conical PNC microstructures can be successfully printed.Below this optimal range,the ink is unable to be ejected from the nozzle;while above this range,irregular positioned microstructures with nanoscale height and coffee-ring-like morphology are produced.Based on these observations,high-resolution color conversion PNC microstructures were effectively prepared using SIJ printing of PNC colloid ink dispersed in dimethylbenzene solvent.
基金supported by the National Natural Science Foundation of China(Grant Nos.12104500 and 82430062)the Key Research and Development Projects of Shaanxi Province(Grant No.2023-YBSF-263),the Shenzhen Engineering Research Centre(Grant No.XMHT20230115004)the Shenzhen Science and Technology Innovation Commission(Grant No.KCXFZ20201221173207022).
文摘Full-color imaging is essential in digital pathology for accurate tissue analysis.Utilizing advanced optical modulation and phase retrieval algorithms,Fourier ptychographic microscopy(FPM)offers a powerful solution for high-throughput digital pathology,combining high resolution,large field of view,and extended depth of field(DOF).However,the full-color capabilities of FPM are hindered by coherent color artifacts and reduced computational efficiency,which significantly limits its practical applications.Color-transferbased FPM(CFPM)has emerged as a potential solution,theoretically reducing both acquisition and reconstruction threefold time.Yet,existing methods fall short of achieving the desired reconstruction speed and colorization quality.In this study,we report a generalized dual-color-space constrained model for FPM colorization.This model provides a mathematical framework for model-based FPM colorization,enabling a closed-form solution without the need for redundant iterative calculations.Our approach,termed generalized CFPM(gCFPM),achieves colorization within seconds for megapixel-scale images,delivering superior colorization quality in terms of both colorfulness and sharpness,along with an extended DOF.Both simulations and experiments demonstrate that gCFPM surpasses state-of-the-art methods across all evaluated criteria.Our work offers a robust and comprehensive workflow for high-throughput full-color pathological imaging using FPM platforms,laying a solid foundation for future advancements in methodology and engineering.
基金financial support received from the Shanghai Pujiang Program(23PJ1406500).
文摘A laser-induced periodic surface structure(LIPSS),which can be easily produced by femtosecond laser ablation,is a unique nanostructure with a visible refractive color that can be controlled by altering its orientation and uniformity,making it suitable for use in colorful marking,camouflage,and anticounterfeiting measures.However,single-mode information camouflage can no longer meet increasingly higher-level security requirements.Therefore,metasurfaces offer revolutionary solutions.In this study,conceptual metasurfaces of pure tungsten are theoretically proposed and verified using hierarchical LIPSS/nanoparticle(NP)nanostructures as meta-atoms.The anisotropy of the LIPSS nanostructure enables polarization-sensitive optical modulation,whereas the spatial configuration,NPs size,and period of LIPSS in the LIPSS/NP meta-atoms provide flexibility for tailoring broadband optical responses.In xpolarization,the LIPSS/NP meta-atom system provides more visible colors and divergent infrared absorption(emission)than in y-polarized and unpolarized modes,paving the way for vividly colorful polarization-sensitive displays and information camouflage in infrared bands.A simplified rendition of the world-famous painting“The Starry Night”by Van Gogh is used as a proof-of-concept.Preliminary experimental results are presented,based on which the feasibility and challenges for laser nanomanufacturing of the proposed conceptual metasurfaces are discussed,aiming to provide inspiration for the development of novel metasurfaces through interdisciplinary studies.
基金supported by the Innovation and Development Program of Beijing Vegetable Research Center,China(KYCX202301)the Construction of Cucurbits Collaboration and Innovation Center,China(XTCX202301)+3 种基金the Youth Research Fund of Beijing Academy of Agriculture and Forestry Sciences,China(QNJJ202426)the National Natural Science Foundation of China(U21A20229 and 32102397)the Scientific Research Foundation of the Higher Education Institutions for Distinguished Young Scholars in Anhui Province,China(2022AH020037)and the Key Research and Development Projects of Anhui Province,China(2023z04020019)。
文摘Peel color is an important appearance quality of melons that significantly affects consumer preferences.In this study,a near-isogenic line NIL-G(dark green peel)was generated from B8(grey-green peel)and B15(white peel).The F_2 population constructed by crossing NIL-G and B15 was used to study the inheritance pattern of peel color,and bulked-segregant analysis sequencing(BSA-seq)was employed to identify the interval in which the target gene was located.Genetic analysis showed that a dominant gene controls the dark green peel trait at maturity.BSAseq and molecular markers were used to localize the candidate gene in a 263.7 kb interval of chromosome 4,which contained the CmAPRR2 gene with known functions.Moreover,allelic sequence analysis revealed four SNP variations of the CmAPRR2 gene in B15,of which SNP.G614331A was located at the junction of the 6th exon and 6th intron.The G-to-A mutation caused alternative splicing of the transcript of CmAPRR2 in B15,generating two transcripts(CmAPRR2-A and CmAPRR2-B)with premature termination codons.Furthermore,the Kompetitive Allele Specific PCR(KASP)marker,APRR2-G/A,was developed based on this SNP and shown to co-segregate with the peel color phenotype in the F_(2) population.Compared to white-peel B15,the expression level of CmAPRR2 in dark green peel NIL-G was higher at each growth stage.Therefore,CmAPRR2 may be the key gene controlling the fruit color of melons.This study identified a novel allelic variant of CmAPRR2 that leads to white peel formation in mature melons.We also provides a theoretical basis for further research on the gene regulatory mechanism of melon peel colors,which promotes using molecular marker-assisted selection to modify melon peel colors in the future.
文摘Textile dyeing is a significant reason of colored wastewater.If this wastewater is discharged directly into natural water sources,it can be detrimental to the ecosystem.Supercritical anhydrous dyeing technology provides a solution to this challenge.Supercritical fluids possess both liquid and gaseous properties,enabling them to dissolve materials and penetrate substances.
基金financially supported by the National Natural Science Foundation of China(Nos.52233001,51927805,and 52173110)the Innovation Program of Shanghai Municipal Education Commission(No.2023ZKZD07)the Shanghai Rising-Star Program(No.22QA1401200)。
文摘Cholesteric liquid crystals(CLCs)exhibit unique helical superstructures that selectively reflect circularly polarized light,enabling them to dynamically respond to environmental changes with tunable structural colors.This dynamic color-changing capability is crucial for applications that require adaptable optical properties,positioning CLCs as key materials in advanced photonic technologies.This review focuses on the mechanisms of dynamic color tuning in CLCs across various forms,including small molecules,cholesteric liquid crystal elastomers(CLCEs),and cholesteric liquid crystal networks(CLCNs),and emphasizes the distinct responsive coloration each structure provides.Key developments in photochromic mechanisms based on azobenzene,dithienylethene,and molecular motor switches,are discussed for their roles in enhancing the stability and tuning range of CLCs.We examine the color-changing behaviors of CLCEs under mechanical stimuli and CLCNs under swelling,highlighting the advantages of each form.Following this,applications of dynamic color-tuning CLCs in information encryption,adaptive camouflage,and smart sensing technologies are explored.The review concludes with an outlook on current challenges and future directions in CLC research,particularly in biomimetic systems and dynamic photonic devices,aiming to broaden their functional applications and impact.
